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Lithium in sediments and brines--how, why and where to search

The possibility of using lithium in batteries to power electric vehicles and as fuel for thermonuclear power has focused attention on the limited resources of lithium other than in pegmatite minerals. The Clayton Valley, Nev., subsurface lithium brine has been the major source of lithium carbonate since about 1967, but the life of this brine field is probably limited to several more decades at the present rate of production. Lithium is so highly soluble during weathering and in sedimentary environments that no lithium-rich sedimentary minerals other than clays have been identified to date. The known deposits of lithium, such as the clay mineral hectorite and the lithium-rich brines, occur in closed desert basins of the Southwest in association with nonmarine evaporites. However, the ultimate source for the lithium in these deposits may be from hydrothermal solutions. The search for previously unreported deposits of nonpegmatitic lithium should consider its probable association, not only with nonmarine evaporite minerals, but also with recent volcanic and tectonic activity, as well as with deposits of boron, beryllium, fluorine, manganese, and possibly phosphate.

Journal of Research of the U.S. Geological Survey

Deformation in the Yakataga seismic gap, Southern Alaska, 1980-1986

A 60-by-40-km trilateration network in the Yakataga seismic gap was surveyed in 1980, 1982, 1984, and 1986 with precise electro-optical distance-measuring equipment to measure strain accumulation. The overall deformation is roughly approximated by a 0.24±0.03 µstrain/yr N32°W±2.4° uniaxial contraction that is uniform in time. However, the spatial distribution of deformation shows some concentration of convergence in the neighborhood of the Chugach-St. Elias fault and of right-lateral shear across the Contact fault. A simple dislocation model of the plate interaction in the Yakataga gap fits the observed deformation reasonably well but seems to require that the motion of the Pacific plate relative to the North American plate be directed more nearly N36°W than N15°W, the generally accepted direction of relative motion for this location. However, the direction of plate motion inferred from the dislocation model depends upon details of the interaction at the plate boundary that may not have been modeled accurately. A nearby but smaller trilateration network at Icy Bay was surveyed in 1982, 1984, and 1986. This network spans the southwest corner of the rupture zone of the 1979 St. Elias earthquake. The deformation at Icy Bay consists of left-lateral shear across a northeast trending zone. The relation of this deformation to strain accumulation in the Yakataga gap, postseismic relaxation associated with the 1979 earthquake, or rebound from the unloading associated with the rapid recession of the Guyot glacier is not understood.

Journal of Geophysical Research Solid Earth

Geochemistry of waters in the Valley of Ten Thousand Smokes region, Alaska

Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8??C in early summer and from 15 to 17??C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area. Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953-1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation. ?? 1992.

Journal of Volcanology and Geothermal Research

Marine turtles of the Galapagos Islands and adjacent areas of the eastern Pacific on the basis of observations made by J.R. Slevin 1905-1906

The field notes of J. R. Slevin written during the expedition of the California Academy of Sciences to the Galapagos Islands in 1905-1096 contain previously unavailable data on the marine turtles of the eastern Pacific. 'Land basking' by green turtles in Galapagos was predominately, if not exclusively, a female behavior. These terrestrial emergences were not concentrated in the major reproductive season of Galapagos turtles. Female Chelonia were also collected on shore during daylight hours on Socorro Island southwest of Baja California, Mexico. Chelonia, green turtles, were observed to feed on seaweed, the leaves and shoots of mangrove trees, and the leaves of another unidentified shoreline shrub. Comparative data on the gonads of dark and yellow turtles indicated that the latter did not breed in Galapagos during Slevin's stay. Lepidochelys olivacea, the olive ridley, was recorded in Galapagos waters and fed on fish eggs

Journal of Herpetology

Stress transfer by the 1988-1989 M=5.3 and 5.4 Lake Elsman foreshocks to the Loma Prieta fault: Unclamping at the site of peak mainshock slip

We study the stress transferred by the June 27, 1988, M = 5.3 and August 8, 1989, M = 5.4 Lake Elsman earthquakes, the largest events to strike within 15 km of the future Loma Prieta rupture zone during 74 years before the 1989 M = 6.9 Loma Prieta earthquake. We find that the first Lake Elsman event brought the rupture plane of the second event 0.3–1.6 bars (0.03–0.16 MPa) closer to Coulomb failure but that the Lake Elsman events did not bring the future Loma Prieta hypocentral zone closer to failure. Instead, the Lake Elsman earthquakes are calculated to have reduced the normal stress on (or “undamped”) the Loma Prieta rupture surface by 0.5–1.0 bar (0.05–0.10 MPa) at the site where the greatest slip subsequently occurred in the Loma Prieta earthquake. This association between the sites of peak unclamping and slip suggests that the Lake Elsman events did indeed influence the Loma Prieta rupture process. Unclamping the fault would have locally lowered the resistance to sliding. Such an effect could have been enhanced if the lowered normal stress permitted fluid infusion into the undamped part of the fault. Although less well recorded, the M L = 5.0 1964 and M L = 5.3 1967 Corralitos events struck within 10 km of the southwest end of the future Loma Prieta rupture. No similar relationship between the normal stress change and subsequent Loma Prieta slip is observed, although the high-slip patch southwest of the Loma Prieta epicenter corresponds roughly to the site of calculated Coulomb stress increase for a low coefficient of friction. The Lake Elsman-Loma Prieta result is similar to that for the 1987 M = 6.2 Elmore Ranch and M = 6.7 Superstition Hills earthquakes, suggesting that foreshocks might influence the distribution of mainshock slip rather than the site of mainshock nucleation.

Journal of Geophysical Research B: Solid Earth

Pleistocene Brawley and Ocotillo Formations: Evidence for initial strike-slip deformation along the San Felipe and San Jacinto fault zonez, Southern California

We examine the Pleistocene tectonic reorganization of the Pacific-North American plate boundary in the Salton Trough of southern California with an integrated approach that includes basin analysis, magnetostratigraphy, and geologic mapping of upper Pliocene to Pleistocene sedimentary rocks in the San Felipe Hills. These deposits preserve the earliest sedimentary record of movement on the San Felipe and San Jacinto fault zones that replaced and deactivated the late Cenozoic West Salton detachment fault. Sandstone and mudstone of the Brawley Formation accumulated between ???1.1 and ???0.6-0.5 Ma in a delta on the margin of an arid Pleistocene lake, which received sediment from alluvial fans of the Ocotillo Formation to the west-southwest. Our analysis indicates that the Ocotillo and Brawley formations prograded abruptly to the east-northeast across a former mud-dominated perennial lake (Borrego Formation) at ???1.1 Ma in response to initiation of the dextral-oblique San Felipe fault zone. The ???25-km-long San Felipe anticline initiated at about the same time and produced an intrabasinal basement-cored high within the San Felipe-Borrego basin that is recorded by progressive unconformities on its north and south limbs. A disconformity at the base of the Brawley Formation in the eastern San Felipe Hills probably records initiation and early blind slip at the southeast tip of the Clark strand of the San Jacinto fault zone. Our data are consistent with abrupt and nearly synchronous inception of the San Jacinto and San Felipe fault zones southwest of the southern San Andreas fault in the early Pleistocene during a pronounced southwestward broadening of the San Andreas fault zone. The current contractional geometry of the San Jacinto fault zone developed after ???0.5-0.6 Ma during a second, less significant change in structural style. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology

Cretaceous mafic conglomerate near Gualala offset 350 miles by San Andreas fault from oceanic crustal source near Eagle Rest Peak, California

Upper Cretaceous mafic conglomerate and quartz-plagioclase arkose that crop out on the southwest side of the San Andreas fault near Gualala, Calif., may have been eroded from a gabbroic terrane that now lies about 350 miles to the southeast, on the opposite side of the San Andreas fault. The plagioclase arkose near Gualala contains little or no K-feldspar, and the conglomerate is characterized by quartz-bearing mafic rocks that lack K-feldspar volcanic rocks, diabase, and diorite to gabbro. Hornblendes from these clasts yield K/Ar ages of 141±4,175±7, and 186±7 m.y. The arkose and conglomerate appear to have been eroded from a chert-poor ophiolite (oceanic crust) sequence that, according to paleocurrent evidence, lay east of the present San Andreas fault. Near Eagle Rest Peak, 350 miles southeast of Gualala, similar mafic quartz-bearing volcanic rocks, diabase, and gabbro are exposed in a small structurally isolated area that abuts the San Andreas fault on the southwest. These rocks yield hornblende K/Ar ages of 134±4, 165±4, and 207±10 m.y. They may also be the source of two small fault slivers of similar mafic rocks, which yield hornblende K/Ar ages between 144 and 172 m.y. These slivers now lie 100 and 200 miles to the northwest along the San Andreas fault at Gold Hill and Logan.

California

Thermal areas on Kilauea and Mauna Loa Volcanoes, Hawaii

Active thermal areas are concentrated in three areas on Mauna Loa and three areas on Kilauea. High-temperature fumaroles (115-362°C) on Mauna Loa are restricted to the summit caldera, whereas high-temperature fumaroles on Kilauea are found in the upper East Rift Zone (Mauna Ulu summit fumaroles, 562°C), middle East Rift Zone (1977 eruptive fissure fumaroles), and in the summit caldera. Solfataric activity that has continued for several decades occurs along border faults of Kilauea caldera and at Sulphur Cone on the southwest rift zone of Mauna Loa. Solfataras that are only a few years old occur along recently active eruptive fissures in the summit caldera and along the rift zones of Kilauea. Steam vents and hot-air cracks also occur at the edges of cooling lava ponds, on the summits of lava shields, along faults and graben fractures, and in diffuse patches that may reflect shallow magmatic intrusions.

Hawaii

Validation of a stream and riparian habitat assessment protocol using stream salamanders in the southwest Virginia coalfields

Within the central Appalachia Coalfields, the aquatic impacts of large-scale land uses, such as surface mining, are of particular ecological concern. Identification and quantification of land use impacts to aquatic ecosystems are a necessary first step to aid in mitigation of negative consequences to biota. However, quantifying physical environmental quality such as stream and riparian habitat often can be quite difficult, particularly when there is time or fiscal limitations. As such, standard protocols such as the U.S. EPA’s Stream Habitat Rapid Bioassessment Protocol have been established to be cost- and time-effective. This protocol estimates ten different stream and riparian conditions on a scale of 0 to 20. Unfortunately, using estimations can be problematic because of large potential variation in the scoring depending on differences in training, experience, and opinion of the personnel doing the estimations. In order to help negate these biases and provide a simplified process, the U.S. Army Corps of Engineers (USACE) developed a functional assessment for streams that measures 11 stream and riparian variables along with watershed land use to calculate three different scores, a hydrology score, biogeochemical score, and habitat score. In our study, we examined the correlation of stream salamander presence and abundance to the three USACE scores. In the summer of 2013, we visited 70 sites in the southwest Virginia Coalfields multiple times to collect salamanders and quantify stream and riparian microhabitat parameters. Using occupancy and abundance analyses, we found strong relationships among three Desmognathus spp. and the USACE Habitat FCI score. Accordingly, the Habitat FCI score provides a reasonable assessment of physical instream and riparian conditions that may serve as a surrogate for understanding the community composition and integrity of aquatic salamander in the region.

Virginia

The Bishop Tuff: New insights from eruptive stratigraphy

The 0.76 Ma Bishop Tuff, from Long Valley caldera in eastern California, consists of a widespread fall deposit and voluminous partly welded ignimbrite. The fall deposit (F), exposed over an easterly sector below and adjacent to the ignimbrite, is divided into nine units (F1‐F9), with no significant time breaks, except possibly between F8 and F9. Maximum clast sizes are compared with other deposits where accumulation rates are known or inferred to estimate an accumulation time for F1‐F8 as ca. 90 hrs. The ignimbrite (Ig) is divided into chronologically and/or geographically distinct packages of material. Earlier packages (Ig1) were emplaced mostly eastward, are wholly intraplinian (coeval with fall units F2‐F8), Lack phenocrystic pyroxenes, and contain few or no Glass Mountain‐derived rhyolite lithic fragments. Earlier packages (Ig2) were erupted mostly to the north and east, are at least partly intraplinian (interbedded with fall unit F9 to the east), contain pyroxenes, and have lithic fractions rich in Glass Mountain‐derived rhyolite or other lithologies exposed on the northern caldera rim. Recognition of the intraplinian nature of Ig1 east of the caldera and use of the fall deposit chronometry yields accumulation estimates of ca. 25 hrs for an earlier, less‐welded subpackage and ca. 36 hrs for a later, mostly welded subpackage. Average accumulation rates range up to ≥1 mm/s of dense‐welded massive ignimbrite, equivalent to ≥2.5 mm/s of non‐welded material. Comparisons of internal stratification in Ig1 and northern Ig2 lobes suggest the thickest northern ignimbrite accumulated in ≥35 hrs. Identifiable vent positions migrated from an initial site previously proposed in the south‐central part of the caldera (F1‐8, Ig1) in complex fashion; one vent set (for eastern Ig2) migrated east and north toward Glass Mountain, while another set (for northern Ig2) opened from west to east across the northern caldera margin. Vent locations for Ig1 and Ig2 southwest of the caldera have not been identified. The new stratigraphic framework shows that much of the Bishop ignimbrite is intraplinian in nature, and that fall deposits and ignimbrite units previously inferred to be sequential are largely or wholly coeval. Fundamental reassessment is therefore required of all existing models for the eruption dynamics and the nature and causes of pre‐eruptive zonations in trace elements, volatiles, and isotopes in the parental magma chamber.

California

Sr, Nd, Hf and Pb isotope geochemistry of Early Miocene shoshonitic lavas from the South Fiji Basin: Note

We present new Sr, Nd, Hf and Pb isotope data for Early Miocene shoshonitic and high-K lavas dredged from seamounts in the South Fiji Basin, southwest Pacific Ocean. Our analyses provide a useful reference dataset for this distinctive compositional suite. The shoshonitic lavas formed in an intra-oceanic back-arc basin setting and are broadly coeval with nearby arc and back-arc basin lavas. Further work in the region will be needed before the tectonic implications of the shoshonitic and high-K lavas are fully understood.

New Zealand Journal of Geology and Geophysics

Seasonal precipitation influences streamflow vulnerability to the 2015 drought in the western United States

Streamflow was exceptionally low in the spring and summer of 2015 across much of the western United States because of a regional drought that exploited the sensitivity of both snow- and rain-dominant rivers. Streamflow during 2015 was examined at 324 gauges in the region to assess its response to the amount, form, and seasonal timing of precipitation and the viability of using spatially aggregated, normative models to assess streamflow vulnerability to drought. Seasonal rain and spring snowmelt had the strongest effects on runoff during the same season, but their effects persisted into subsequent seasons as well. Below-normal runoff in the spring of 2015 was pervasive across the region, while distinct seasonal responses were evident in different hydroclimatic settings: January–March (winter) runoff was above normal in most snow-dominant rivers and runoff in all seasons was above normal for much of the desert Southwest. Summer precipitation contributed to summer runoff in both the Pacific Northwest and desert Southwest. A first-order model that presumes runoff is a constant fraction of precipitation (the precipitation elasticity of runoff, E = 1) could be used for assessing and forecasting runoff responses to precipitation deficits across the region, but runoff generally is more vulnerable to drought (E > 1) than predicted by a first-order model. Uncertainty in spring and summer precipitation forecasts remain critical issues for forecasting and predicting summer streamflow vulnerability to drought across much of the western United States.

Journal of Hydrometeorology

The Sargent-Berrocal Fault Zone and its relation to the San Andreas Fault system in the southern San Francisco Bay region and Santa Clara Valley, California

The Sargent-Berrocal fault zone is a belt of thrust faults extending for about 58 mi (94 km) southeastward from the vicinity of Los Altos to San Juan Bautista, Calif. The fault zone generally dips southwestward toward the adjacent San Andreas fault at low to steep angles, and the southwest block has moved upward and northeastward. Thrusting across the fault zone has produced large-scale offset, which may increase to the southeast. If strike-slip movement has occurred, it has probably been minor. Offset Quaternary strata, physiographic features, and recent seismic activity all indicate that the Sargent-Berrocal fault zone has been active in the last one million years and that some clastic strain is currently being released along the northwest and southeast parts of the fault zone.

California

Reinterpretation of the stratigraphy and structure of the Rancho Las Norias area, central Sonora, Mexico

New geologic mapping and fossil data in the vicinity of Rancho Las Norias, 30 km east of Hermosillo, Sonora, Mexico, show that rocks previously mapped as Precambrian instead are Paleozoic. Previous geologic maps of the Rancho Las Norias area show northeast-directed, southwest-dipping reverse or thrust faults deforming both Precambrian and Paleozoic rocks. The revised stratigraphy requires reinterpretation of some of these faults as high-angle normal or oblique-slip faults and the elimination of other faults. We agree with earlier geologic map interpretations that compressional structures have affected the Paleozoic rocks in the area, but our mapping suggests that the direction of compression is from southeast to northwest. Published by Elsevier Ltd.

Journal of South American Earth Sciences

Early and middle(?) Cambrian metazoan and protistan fossils from West Africa

Supposed Upper Proterozoic strata in the southwest Taoudeni Basin, Guinea and Senegal, and from the Mauritanide fold belt, Mauritania, have yielded mostly poorly preserved small skeletal fossils of metazoan and protistan origin. Problematic, but possible echinoderm material and spicules of the heteractinid sponge Eiffelia dominate the Taoudeni Basin assemblage. The age of the material is not certain but the paleontologic data suggest an Early Cambrian age for the stratigraphically lowest faunas, and a Middle Cambrian age is possible for the stratigraphically highest collections.

Journal of Paleontology

Middle Tertiary extension recorded by lacustrine fan-delta deposits, Plush Ranch Basin, western Transverse Ranges, California

The Plush Ranch Formation (upper Oligocene and lower Miocene) consists of more than 1800 m of nonmarine sedimentary and volcanic rocks that record the history of an extensional basin referred to here as the Plush Ranch basin. Distinctive depositional facies, provenance, and sediment transport directions along each basin margin suggest an asymmetric basin shape that is consistent with a half-graben origin. The northern basin margin consists of sandstone-dominated alluvial-plain deposits (0.1-1.5 m thick, normally graded, lenticular sandstone beds). Small deltaic sequences 1-2 m thick were formed where these alluvial systems flowed southward into a lake. Lenses of massive, boulder-rich granitic breccia that represent rockslide deposits derived from a nearby northern granitic provenance interfinger with the alluvial-plain facies. In contrast to the northern margin, the southern basin margin is represented by coarse-grained fan-delta deposits. Matrix- and clast-supported lenticular conglomerate beds 0.2-5 m thick with interbedded trough-cross-bedded pebbly sandstone represent braided-stream and flood-flow and/or noncohesive debris-flow deposits of alluvial fans that drained a highland area to the south. The alluvial-fan deposits interfinger to the north with several types of subaqueous sediment-gravity-flow facies including turbidite sandstone beds and matrix-supported debris-flow conglomerate. Each of the basin-margin depositional systems grades basinward and to the east into lacustrine deposits that include organic-rich dark shale, evaporite, and limestone. The lacustrine deposits represent the central and eastern parts of the Plush Ranch basin, which received little coarse siliciclastic sediment. Basalt deposits that are at least 50 m thick in the west and thicken eastward are interbedded mainly with the lacustrine facies. The southern margin of the Plush Ranch basin formed along a north-dipping, normal-slip fault along which dip separation increased toward the southwest; the northern margin developed on the tilted hanging-wall block of this fault. This fault was later reactivated in post-middle Miocene time as the present left-lateral strike-slip Big Pine fault. The Plush Ranch is one of several extensional and transtensional basins that formed in southern California and western Arizona about 25-20 Ma as a response to the change from a convergent to a strikeslip tectonic regime along western North America.

California

Seismic response of transamerica building. II. System identification

A detailed analysis of the recorded seismic response of the Transamerica Building during the October 17, 1989 Loma Prieta earthquake is presented. The system identification algorithm used for the analysis is based on the discrete-time linear filtering approach with least-squares approximation, and assumes a multi-input, single-output model for the building. Fifteen modes in the north-south direction, and 18 modes in the east-west direction are identified from the records. The analysis shows that the building's response to the earthquake was dominated by a coupled mode of vibration at 0.28 Hz in the southwest-northeast direction, which is almost parallel to one of the diagonals in the building's square cross section. The reason for this behavior is the symmetry of the building's structural characteristics, as well as the strong polarization of the S-waves of the earthquake. Several higher modes of the building were excited during the strong-motion part of the earthquake. The results also show a significant amount of rocking in the building at a frequency of 2.15 Hz.

Journal of Structural Engineering

High-level plateaus of the southeastern Beartooth Mountains, Montana and Wyoming: remnants of an exhumed sub-Cambrian marine plain

The Beartooth Mountains of south-central Montana and northwestern Wyoming are a northwesterly trending high rugged range made up mainly of Precambrian metamorphic rocks. The southeastern part of the range is characterized by extensive high-altitude flat or gently rolling plateaus separated by deep glaciated canyons. The plateaus along the crest of the range are at altitudes of more than 3,350 metres (11,000 ft), whereas those on the flanks of the range are much lower. They are almost entirely on Precambrian rocks, and only small patches of Cambrian sedimentary rocks still remain at a few places in the high mountains. Topographic profiles across the southeastern Beartooth Mountains show that: (1) plateaus bearing the sedimentary remnants lie very close to the position of the sub-Cambrian depositional surface as projected from known occurrences of that surface along the south side of the mountains; (2) other plateaus on the crest and southwest flank also lie near this projected position; and (3) high plateaus and other summits on the northeast slope in areas distant from known or projected positions of the sub-Cambrian surface are markedly accordant. We believe the plateaus along the crest and southwest flank of the range to be remnants of an exhumed marine plain of Early Cambrian or Precambrian age, and those on the northeast flank may possibly have a similar origin. The sub-Cambrian depositional surface was protected until early Tertiary time by a cover of Paleozoic sedimentary rocks, and parts of it probably were covered until Pliocene time by Eocene volcanic rocks. The surface subsequently has been profoundly modified by fluvial and glacial erosion and by mass wasting.

Montana, Wyoming