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USGS2015

Mars Reconnaissance Orbiter and Opportunity observations of the Burns formation: crater hopping at Meridiani Planum

Compact Reconnaissance Imaging Spectrometer for Mars hyperspectral (1.0–2.65 µm) along-track oversampled observations covering Victoria, Santa Maria, Endeavour, and Ada craters were processed to 6 m/pixel and used in combination with Opportunity observations to detect and map hydrated Mg and Ca sulfate minerals in the Burns formation. The strongest spectral absorption features were found to be associated with outcrops that are relatively young and fresh (Ada) or preferentially scoured of dust, soil, and coatings by prevailing winds. At Victoria and Santa Maria, the scoured areas are on the southeastern rims and walls, opposite to the sides where wind-blown sands extend out of the craters. At Endeavour, the deepest absorptions are in Botany Bay, a subdued and buried rim segment that exhibits high thermal inertias, extensive outcrops, and is interpreted to be a region of enhanced wind scour extending up and out of the crater. Ada, Victoria, and Santa Maria outcrops expose the upper portion of the preserved Burns formation and show spectral evidence for the presence of kieserite. In contrast, gypsum is pervasive spectrally in the Botany Bay exposures. Gypsum, a relatively insoluble evaporative mineral, is interpreted to have formed close to the contact with the Noachian crust as rising groundwaters brought brines close to and onto the surface, either as a direct precipitate or during later diagenesis. The presence of kieserite at the top of the section is hypothesized to reflect precipitation from evaporatively concentrated brines or dehydration of polyhydrated sulfates.

Journal of Geophysical Research E: Planets↗

USGS2015

Context of ancient aqueous environments on Mars from in situ geologic mapping at Endeavour Crater

Using the Mars Exploration Rover Opportunity , we have compiled one of the first field geologic maps on Mars while traversing the Noachian terrain along the rim of the 22 km diameter Endeavour Crater (Latitude −2°16′33″, Longitude −5°10′51″). In situ mapping of the petrographic, elemental, structural, and stratigraphic characteristics of outcrops and rocks distinguishes four mappable bedrock lithologic units. Three of these rock units predate the surrounding Burns formation sulfate-rich sandstones and one, the Matijevic Formation, represents conditions on early Mars predating the formation of Endeavour Crater. The stratigraphy assembled from these observations includes several geologic unconformities. The differences in lithologic units across these unconformities record changes in the character and intensity of the Martian aqueous environment over geologic time. Water circulated through fractures in the oldest rocks over periods long enough that texturally and elementally significant alteration occurred in fracture walls. These oldest pre-Endeavour rocks and their network of mineralized and altered fractures were preserved by burial beneath impact ejecta and were subsequently exhumed and exposed. The alteration along joints in the oldest rocks and the mineralized veins and concentrations of trace metals in overlying lithologic units is direct evidence that copious volumes of mineralized and/or hydrothermal fluids circulated through the early Martian crust. The wide range in intensity of structural and chemical modification from outcrop to outcrop along the crater rim shows that the ejecta of large (>8 km in diameter) impact craters is complex. These results imply that geologic complexity is to be anticipated in other areas of Mars where cratering has been a fundamental process in the local and regional geology and mineralogy.

Journal of Geophysical Research E: Planets↗

USGS2015

Evolution of Mars’ Northern Polar Seasonal CO 2 deposits: variations in surface brightness and bulk density

Small scale variations of seasonal ice are explored at different geomorphic units on the Northern Polar Seasonal Cap (NPSC). We use seasonal rock shadow measurements, combined with visible and thermal observations, to calculate density over time. The coupling of volume density and albedo allows us to determine the microphysical state of the seasonal CO 2 ice. We find two distinct endmembers across the NPSC: 1) Snow deposits may anneal to form an overlying slab layer that fractures. These low density deposits maintain relatively constant densities over springtime. 2) Porous slab deposits likely anneal rapidly in early spring and fracture in late spring. These high density deposits dramatically increase in density over time. The endmembers appear to be correlated with latitude.

Journal of Geophysical Research E: Planets↗

USGS2015

Examining spectral variations in localized lunar dark mantle deposits

The localized lunar dark mantle deposits (DMDs) in Alphonsus, J. Herschel, and Oppenheimer craters were analyzed using visible-near-infrared spectroscopy data from the Moon Mineralogy Mapper. Spectra of these localized DMDs were analyzed for compositional and mineralogical variations within the deposits and were compared with nearby mare basalt units. Spectra of the three localized DMDs exhibited mafic absorption features indicating iron-rich compositions, although the DMDs were spectrally distinct from nearby mare basalts. All of the DMDs contained spectral signatures of glassy materials, suggesting the presence of volcanic glass in varying concentrations across the individual deposits. In addition, the albedo and spectral signatures were variable within the Alphonsus and Oppenheimer crater DMDs, suggesting variable deposit thickness and/or variations in the amount of mixing with the local substrate. Two previously unidentified localized DMDs were discovered to the northeast of Oppenheimer crater. The identification of high concentrations of volcanic glass in multiple localized DMDs in different locations suggests that the distribution of volcanic glass across the lunar surface is much more widespread than has been previously documented. The presence of volcanic glass implies an explosive, vulcanian eruption style for localized DMDs, as this allows volcanic glass to rapidly quench, inhibiting crystallization, compared to the larger hawaiian-style eruptions typical of regional DMD emplacement where black beads indicate a higher degree of crystallization. Improved understanding of the local and global distributions of volcanic glass in lunar DMDs will further constrain lunar degassing and compositional evolution throughout lunar volcanic history.

Journal of Geophysical Research E: Planets↗

USGS2015

Limited role for thermal erosion by turbulent lava in proximal Athabasca Valles, Mars

The Athabasca Valles flood lava is among the most recent (<50 Ma) and best preserved effusive lava flows on Mars and was probably emplaced turbulently. The Williams et al. (2005) model of thermal erosion by lava has been applied to what we term “proximal Athabasca,” the 75 km long upstream portion of Athabasca Valles. For emplacement volumes of 5000 and 7500 km 3 and average flow thicknesses of 20 and 30 m, the duration of the eruption varies between ~11 and ~37 days. The erosion of the lava flow substrate is investigated for three eruption temperatures (1270°C, 1260°C, and 1250°C), and volatile contents equivalent to 0–65 vol % bubbles. The largest erosion depths of ~3.8–7.5 m are at the lava source, for 20 m thick and bubble-free flows that erupted at their liquidus temperature (1270°C). A substrate containing 25 vol % ice leads to maximum erosion. A lava temperature 20°C below liquidus reduces erosion depths by a factor of ~2.2. If flow viscosity increases with increasing bubble content in the lava, the presence of 30–50 vol % bubbles leads to erosion depths lower than those relative to bubble-free lava by a factor of ~2.4. The presence of 25 vol % ice in the substrate increases erosion depths by a factor of 1.3. Nevertheless, modeled erosion depths, consistent with the emplacement volume and flow duration constraints, are far less than the depth of the channel (~35–100 m). We conclude that thermal erosion does not appear to have had a major role in excavating Athabasca Valles.

Journal of Geophysical Research E: Planets↗

USGS2016

The geologic history of Margaritifer basin, Mars

In this study, we investigate the fluvial, sedimentary, and volcanic history of Margaritifer basin and the Uzboi-Ladon-Morava (ULM) outflow channel system. This network of valleys and basins spans more than 8000 km in length, linking the fluvially dissected southern highlands and Argyre Basin with the northern lowlands via Ares Vallis. Compositionally, thermophysically, and morphologically distinct geologic units are identified and are used to place critical relative stratigraphic constraints on the timing of geologic processes in Margaritifer basin. Our analyses show that fluvial activity was separated in time by significant episodes of geologic activity, including the widespread volcanic resurfacing of Margaritifer basin and the formation of chaos terrain. The most recent fluvial activity within Margaritifer basin appears to terminate at a region of chaos terrain, suggesting possible communication between surface and subsurface water reservoirs. We conclude with a discussion of the implications of these observations on our current knowledge of Martian hydrologic evolution in this important region.

Journal of Geophysical Research E: Planets↗

USGS2016

Geologic context of recurring slope lineae in Melas and Coprates Chasmata, Mars

One of the major Mars discoveries of recent years is the existence of recurring slope lineae (RSL), which suggests that liquid water occurs on or near the surface of Mars today. These dark and narrow features emerge from steep, rocky exposures and incrementally grow, fade, and reform on a seasonal basis and are detected in images from the High Resolution Imaging Science Experiment camera. RSL are known to occur at scattered midlatitude and equatorial sites with little spatial connection to one another. One major exception is the steep, low-albedo slopes of Melas and Coprates Chasmata, in Valles Marineris where RSL are detected among diverse geologic surfaces (e.g., bedrock and talus) and landforms (e.g., inselbergs and landslides). New images show topographic changes including sediment deposition on active RSL slopes. Midwall locations in Coprates and Melas appear to have more areally extensively abundant RSL and related fans as compared with other RSL sites found on Mars. Water budget estimates for regional RSL are on the order of 10 5 to 10 6 m 3 of fluid, for depths of 10 to 100mm, and suggest that a significant amount of near-surface watermight be present. Many RSL are concentrated near local topographic highs, such as ridge crests or peaks, which is challenging to explain via groundwater or ice without a recharge mechanism. Collectively, results provide additional support for the notion that significant amounts of near-surface water can be found on Mars today and suggest that a widespread mechanism, possibly related to the atmosphere, is recharging RSL sources.

Journal of Geophysical Research E: Planets↗

USGS2017

Effects of lava heating on volatile-rich slopes on Io

The upper crust of Io may be very rich in volatile sulfur and SO2. The surface is also highly volcanically active, and slopes may be warmed by radiant heat from the lava. This is particularly the case in paterae, which commonly host volcanic eruptions and long-lived lava lakes. Paterae slopes are highly variable, but some are greater than 70°. I model the heating of a volatile slope for two end-member cases: instantaneous emplacement of a large sheet flow, and persistent heating by a long-lived lava lake. In general, single flows can briefly raise sulfur to the melting temperature, or drive a modest amount of sublimation of SO2. Persistently lava-covered surfaces will drive much more significant geomorphic effects, with potentially significant sublimation and slope retreat. In addition to the direct effects, heating is likely to weaken slope materials and may trigger mass wasting. Thus, if the upper crust of Io is rich in these volatile species, future missions with high-resolution imaging are likely to observe actively retreating slopes around lava lakes and other locations of frequent eruptions.

Journal of Geophysical Research E: Planets↗

USGS2017

Geologic overview of the Mars Science Laboratory rover mission at the Kimberley, Gale crater, Mars

The Mars Science Laboratory (MSL) Curiosity rover completed a detailed investigation at the Kimberley waypoint within Gale crater from sols 571-634 using its full science instrument payload. From orbital images examined early in the Curiosity mission, the Kimberley region had been identified as a high-priority science target based on its clear stratigraphic relationships in a layered sedimentary sequence that had been exposed by differential erosion. Observations of the stratigraphic sequence at the Kimberley made by Curiosity are consistent with deposition in a prograding, fluvio-deltaic system during the late Noachian to early Hesperian, prior to the existence of most of Mt. Sharp. Geochemical and mineralogic analyses suggest that sediment deposition likely took place under cold conditions with relatively low water-to-rock ratios. Based on elevated K2O abundances throughout the Kimberley formation, an alkali feldspar protolith is likely one of several igneous sources from which the sediments were derived. After deposition, the rocks underwent multiple episodes of diagenetic alteration with different aqueous chemistries and redox conditions, as evidenced by the presence of Ca-sulfate veins, Mn-oxide fracture-fills, and erosion-resistant nodules. More recently, the Kimberley has been subject to significant aeolian abrasion and removal of sediments to create modern topography that slopes away from Mt. Sharp, a process that has continued to the present day.

Journal of Geophysical Research E: Planets↗

USGS2017

A probabilistic approach to remote compositional analysis of planetary surfaces

Reflected light from planetary surfaces provides information, including mineral/ice compositions and grain sizes, by study of albedo and absorption features as a function of wavelength. However, deconvolving the compositional signal in spectra is complicated by the nonuniqueness of the inverse problem. Trade-offs between mineral abundances and grain sizes in setting reflectance, instrument noise, and systematic errors in the forward model are potential sources of uncertainty, which are often unquantified. Here we adopt a Bayesian implementation of the Hapke model to determine sets of acceptable-fit mineral assemblages, as opposed to single best fit solutions. We quantify errors and uncertainties in mineral abundances and grain sizes that arise from instrument noise, compositional end members, optical constants, and systematic forward model errors for two suites of ternary mixtures (olivine-enstatite-anorthite and olivine-nontronite-basaltic glass) in a series of six experiments in the visible-shortwave infrared (VSWIR) wavelength range. We show that grain sizes are generally poorly constrained from VSWIR spectroscopy. Abundance and grain size trade-offs lead to typical abundance errors of ≤1 wt % (occasionally up to ~5 wt %), while ~3% noise in the data increases errors by up to ~2 wt %. Systematic errors further increase inaccuracies by a factor of 4. Finally, phases with low spectral contrast or inaccurate optical constants can further increase errors. Overall, typical errors in abundance are <10%, but sometimes significantly increase for specific mixtures, prone to abundance/grain-size trade-offs that lead to high unmixing uncertainties. These results highlight the need for probabilistic approaches to remote determination of planetary surface composition.

Journal of Geophysical Research E: Planets↗

USGS2013

Photometric properties of Mars soils analogs

We have measured the bidirectional reflectance of analogs of dry, wet, and frozen Martian soils over a wide range of phase angles in the visible spectral range. All samples were produced from two geologic samples: the standard JSC Mars-1 soil simulant and Hawaiian basaltic sand. In a first step, experiments were conducted with the dry samples to investigate the effects of surface texture. Comparisons with results independently obtained by different teams with similar samples showed a satisfying reproducibility of the photometric measurements as well as a noticeable influence of surface textures resulting from different sample preparation procedures. In a second step, water was introduced to produce wet and frozen samples and their photometry investigated. Optical microscope images of the samples provided information about their microtexture. Liquid water, even in relatively low amount, resulted in the disappearance of the backscattering peak and the appearance of a forward-scattering peak whose intensity increases with the amount of water. Specular reflections only appeared when water was present in an amount large enough to allow water to form a film at the surface of the sample. Icy samples showed a wide variability of photometric properties depending on the physical properties of the water ice. We discuss the implications of these measurements in terms of the expected photometric behavior of the Martian surface, from equatorial to circum-polar regions. In particular, we propose some simple photometric criteria to improve the identification of wet and/or icy soils from multiple observations under different geometries.

Journal of Geophysical Research E: Planets↗

USGS1999

Soil-like deposits observed by Sojourner, the Pathfinder rover

Most of the soil-like materials at the Pathfinder landing site behave like moderately dense soils on Earth with friction angles near 34°-39° and are called cloddy deposits. Cloddy deposits appear to be poorly sorted with dust-sized to granule-sized mineral or rock grains; they may contain pebbles, small rock fragments, and clods. Thin deposits of porous, compressible drifts with friction angles near 26°-28° are also present. Drifts are fine grained. Cohesions of both types of deposits are small. There may be indurated soil-like deposits and/or coated or crusted rocks. Cloddy deposits may be fluvial sediments of the Ares-Tiu floods, but other origins, such as ejecta from nearby impact craters, should be considered. Drifts are probably dusts that settled from the Martian atmosphere. Remote-sensing signatures of the deposits inferred from rover observations are consistent with those observed from orbit and Earth.

Journal of Geophysical Research E: Planets↗

USGS1999

Digital mapping of the Mars Pathfinder landing site: Design, acquisition, and derivation of cartographic products for science applications

The Imager for Mars Pathfinder (IMP) acquired more than 16,000 images and provided panoramic views of the surface of Mars at the Mars Pathfinder landing site in Ares Vallis. This paper describes the stereoscopic, multispectral IMP imaging sequences and focuses on their use for digital mapping of the landing site and for deriving cartographic products to support science applications of these data. Two‐dimensional cartographic processing of IMP data, as performed via techniques and specialized software developed for ISIS (the U.S. Geological Survey image processing software package), is emphasized. Cartographic processing of IMP data includes ingestion, radiometric correction, establishment of geometric control, coregistration of multiple bands, reprojection, and mosaicking. Photogrammetric processing, an integral part of this cartographic work which utilizes the three‐dimensional character of the IMP data, supplements standard processing with geometric control and topographic information [ Kirk et al. , this issue]. Both cartographic and photogrammetric processing are required for producing seamless image mosaics and for coregistering the multispectral IMP data. Final, controlled IMP cartographic products include spectral cubes, panoramic (360° azimuthal coverage) and planimetric (top view) maps, and topographic data, to be archived on four CD‐ROM volumes. Uncontrolled and semicontrolled versions of these products were used to support geologic characterization of the landing site during the nominal and extended missions. Controlled products have allowed determination of the topography of the landing site and environs out to ∼60 m, and these data have been used to unravel the history of large‐ and small‐scale geologic processes which shaped the observed landing site. We conclude by summarizing several lessons learned from cartographic processing of IMP data.

Journal of Geophysical Research E: Planets↗

USGS1999

Assessment of Mars Pathfinder landing site predictions

Remote sensing data at scales of kilometers and an Earth analog were used to accurately predict the characteristics of the Mars Pathfinder landing site at a scale of meters. The surface surrounding the Mars Pathfinder lander in Ares Vallis appears consistent with orbital interpretations, namely, that it would be a rocky plain composed of materials deposited by catastrophic floods. The surface and observed maximum clast size appears similar to predictions based on an analogous surface of the Ephrata Fan in the Channeled Scabland of Washington state. The elevation of the site measured by relatively small footprint delay-Doppler radar is within 100 m of that determined by two-way ranging and Doppler tracking of the spacecraft. The nearly equal elevations of the Mars Pathfinder and Viking Lander 1 sites allowed a prediction of the atmospheric conditions with altitude (pressure, temperature, and winds) that were well within the entry, descent, and landing design margins. High-resolution (~38 m/pixel) Viking Orbiter 1 images showed a sparsely cratered surface with small knobs with relatively low slopes, consistent with observations of these features from the lander. Measured rock abundance is within 10% of that expected from Viking orbiter thermal observations and models. The fractional area covered by large, potentially hazardous rocks observed is similar to that estimated from model rock distributions based on data from the Viking landing sites, Earth analog sites, and total rock abundance. The bulk and fine-component thermal inertias measured from orbit are similar to those calculated from the observed rock size-frequency distribution. A simple radar echo model based on the reflectivity of the soil (estimated from its bulk density), and the measured fraction of area covered by rocks was used to approximate the quasi-specular and diffuse components of the Earth-based radar echos. Color and albedo orbiter data were used to predict the relatively dust free or unweathered surface around the Pathfinder lander compared to the Viking landing sites. Comparisons with the experiences of selecting the Viking landing sites demonstrate the enormous benefit the Viking data and its analyses and models had on the successful predictions of the Pathfinder site. The Pathfinder experience demonstrates that, in certain locations, geologic processes observed in orbiter data can be used to infer surface characteristics where those processes dominate over other processes affecting the Martian surface layer. Copyright 1999 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS1999

Retention of an atmosphere on early Mars

The presence of valley networks and indications of high erosion rates in ancient terrains on Mars suggest that Mars was warm and wet during heavy bombardment. Various processes that could occur on early Mars were integrated into a self-consistent model to determine what circumstances might lead to warm temperatures during and at the end of heavy bombardment. Included were weathering and burial of CO 2 as carbonates, impact erosion, sputtering, and recycling of CO 2 back into the atmosphere by burial and heating. The models suggest that despite losses from the atmosphere by weathering and impact erosion, Mars could retain a 0.5 to 1 bar atmosphere at the end of heavy bombardment partly because weathering temporarily sequesters CO 2 in the ground and protects it from impact erosion while the impact rate is declining and impact erosion is becoming less effective. Because of the low output of the early Sun, surface temperatures can be above freezing only for a very efficient greenhouse, such as that suggested by Forget and Pierrehumbert [1997]. With weak greenhouse models, temperatures are below freezing throughout heavy bombardment, and such a large amount of CO 2 is left in the atmosphere at the end of heavy bombardment that it is difficult to eliminate subsequently to arrive at the present surface inventory. With strong greenhouse models, temperatures are well above freezing during heavy bombardment and drop to close to freezing at the end of heavy bombardment, at which time the atmosphere contains 0.5 to 1 bar of CO 2 . This can be largely eliminated subsequently by sputtering and low-temperature weathering. Such a model is consistent with the change in erosion rate and the declining rate of valley formation at the end of heavy bombardment. Conditions that favor warm temperatures at the end of heavy bombardment are an efficient greenhouse, low weathering rates, low impact erosion rates, and a smaller fraction of heat lost by conduction as opposed to transport of lava to the surface.

Journal of Geophysical Research E: Planets↗

USGS2000

Mineralogic and compositional properties of Martian soil and dust: results from Mars Pathfinder

Mars Pathfinder obtained multispectral, elemental, magnetic, and physical measurements of soil and dust at the Sagan Memorial Station during the course of its 83 sol mission. We describe initial results from these measurements, concentrating on multispectral and elemental data, and use these data, along with previous Viking, SNC meteorite, and telescopic results, to help constrain the origin and evolution of Martian soil and dust. We find that soils and dust can be divided into at least eight distinct spectral units, based on parameterization of Imager for Mars Pathfinder (IMP) 400 to 1000 nm multispectral images. The most distinctive spectral parameters for soils and dust are the reflectivity in the red, the red/blue reflectivity ratio, the near-IR spectral slope, and the strength of the 800 to 1000 nm absorption feature. Most of the Pathfinder spectra are consistent with the presence of poorly crystalline or nanophase ferric oxide(s), sometimes mixed with small but varying degrees of well-crystalline ferric and ferrous phases. Darker soil units appear to be coarser-grained, compacted, and/or mixed with a larger amount of dark ferrous materials relative to bright soils. Nanophase goethite, akaganeite, schwertmannite, and maghemite are leading candidates for the origin of the absorption centered near 900 nm in IMP spectra. The ferrous component in the soil cannot be well-constrained based on IMP data. Alpha proton X-ray spectrometer (APXS) measurements of six soil units show little variability within the landing site and show remarkable overall similarity to the average Viking-derived soil elemental composition. Differences exist between Viking and Pathfinder soils, however, including significantly higher S and Cl abundances and lower Si abundances in Viking soils and the lack of a correlation between Ti and Fe in Pathfinder soils. No significant linear correlations were observed between IMP spectral properties and APXS elemental chemistry. Attempts at constraining the mineralogy of soils and dust using normative calculations involving mixtures of smectites and silicate and oxide minerals did not yield physically acceptable solutions. We attempted to use the Pathfinder results to constrain a number of putative soil and dust formation scenarios, including palagonitization and acid-fog weathering. While the Pathfinder soils cannot be chemically linked to the Pathfinder rocks by palagonitization, this study and McSween et al. [1999] suggest that palagonitic alteration of a Martian basaltic rock, plus mixture with a minor component of locally derived andesitic rock fragments, could be consistent with the observed soil APXS and IMP properties.

Journal of Geophysical Research E: Planets↗

USGS2000

Compositional analyses of small lunar pyroclastic deposits using Clementine multispectral data

Clementine ultraviolet-visible (UVVIS) data are used to examine the compositions of 18 pyroclastic deposits (15 small, three large) at 13 sites on the Moon. Compositional variations among pyroclastic deposits largely result from differing amounts of new basaltic (or juvenile) material and reworked local material entrained in their ejecta upon eruption. Characterization of pyroclastic deposit compositions allows us to understand the mechanisms of lunar explosive volcanism. Evidence for compositional differences between small pyroclastic deposits at a single site is observed at Atlas crater. At all sites, compositional variation among the small pyroclastic deposits is consistent with earlier classification based on Earth-based spectra: three compositional groups can be observed, and the trend of increasing mafic absorption band strength from Group 1 to Group 2 to Group 3 is noted. As redefined here, Group 1 deposits include those of Alphonsus West, Alphonsus Southeast, Alphonsus Northeast 2, Atlas South, Crüger, Franklin, Grimaldi, Lavoisier, Oppenheimer, Orientale, and Riccioli. Group 1 deposits resemble lunar highlands, with weak mafic bands and relatively high UV/VIS ratios. Group 2 deposits include those of Alphonsus Northeast 1, Atlas North, Eastern Frigoris East and West, and Aristarchus Plateau; Group 2 deposits are similar to mature lunar maria, with moderate mafic band depths and intermediate UV/VIS ratios. The single Group 3 deposit, J. Herschel, has a relatively strong mafic band and a low UV/VIS ratio, and olivine is a likely juvenile component. Two of the deposits in these groups, Orientale and Aristarchus, are large pyroclastic deposits. The third large pyroclastic deposit, Apollo 17/Taurus Littrow, has a very weak mafic band and a high UV/VIS ratio and it does not belong to any of the compositional groups for small pyroclastic deposits. The observed compositional variations indicate that highland and mare materials are also present in many large and small pyroclastic deposits, and they suggest that volcanic glasses or spheres may not be dominant juvenile components in all large pyroclastic deposits.

Journal of Geophysical Research E: Planets↗

USGS2000

Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets↗