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1,231 records · Page 4Linked to original sources
USGS2025

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis↗
USGS2025

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming↗
USGS2026

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2026

Emergent headwater types for watershed monitoring, research, and planning

Headwaters—that is headwater streams and the watersheds they drain—strongly influence water quality, ecosystem services, and hydrologic connectivity, yet remain poorly mapped, monitored, and understood at large spatial scales. Using available spatial data to classify headwater “types” could therefore enhance the utility of sparse monitoring data to advance research and watershed planning—and help update literature-based perceptual models of headwaters as steep, forested, and minimally disturbed watersheds. Here, we analyze headwaters across the contiguous United States to quantify how their attributes (climate, topography, land cover, soils) vary regionally and differ from their downstream watersheds. Our analysis (a) identified seven dominant headwater types with distinct combinations of biophysical and climatic attributes and (b) revealed systematic contrasts with downstream watersheds, with strongest differences in attributes representing potential flowpath depth. Our findings offer a transferable framework for classifying, modeling, and managing these critical yet understudied components of the hydrologic network.

conterminous United States↗
USGS2025

Mechanics and statistics of postseismic shaking

Analysis of two weeks of continuous post-seismic shaking after the 2019 M7.1 Ridgecrest, CA earthquake sequence using 4 nearby borehole seismometers reveals that continuous ground motions decay as Omori’s law in time and follow the Gutenberg-Richter distribution in logarithmic amplitude. The measured temporal decay in amplitudes agrees with predictions of the rate-and-state framework and indicates shaking amplitudes are proportional to the velocity of afterslip. Our ground motion-based statistical framework provides a basis to forecast shaking intensity in the minutes to hours after a large earthquake.

California↗
USGS2025

New constraints on location and timing of the Great Lakes tectonic zone, central Upper Peninsula, Michigan, USA

The Great Lakes tectonic zone (GLTZ) forms the boundary between the Wawa–Abitibi and Minnesota River Valley subprovinces within the Archean Superior Province. The GLTZ is concealed for all of its 1100 km length, except for a segment in the central Upper Peninsula of Michigan. There, it is exposed as a northwest-striking mylonite zone along a 11 km segment, extending to the onlap of Paleozoic rocks to the east. Farther east, its location has been unknown. Here, we use aeromagnetic and gravity data to develop interpretations of the expression of the GLTZ and to define its extent under cover. Aeromagnetic gradients over the mylonite zone are interpreted to be produced by structurally juxtaposed rocks with varying magnetizations. Gravity data show a regional gradient along the GLTZ, produced by the juxtaposition of a dense greenstone belt on the north against lower-density gneisses and granites on the south. The GLTZ is interpreted to extend ∼55 km under cover to the east. The GLTZ is terminated on the east by the buried eastern arm of the ca. 1100 Ma Midcontinent Rift. An undeformed granitic dike that cuts the mylonitic foliation produces a U–Pb apatite age of 2523 ± 33 Ma, implying no major post-Archean shearing occurred, and is at odds with previous interpretations of major Proterozoic reactivation. A granite intrusion in the Minnesota River Valley subprovince produces a Pb–Pb zircon age of 2606.9 ± 3.6/7.4 Ma. This suggests that magmatism related to the Sacred Heart orogeny, previously known in Minnesota, extended to Michigan.

Michigan↗
USGS2025

S/P amplitude ratios with Distributed Acoustic Sensing and application to earthquake focal mechanisms

Distributed acoustic sensing (DAS), which transforms a fiber optic cable into an array of high frequency strainmeters, has the potential to help us characterize earthquakes with a dense sampling of measurements. While earthquake focal mechanisms are frequently determined using P -wave polarities and S / P amplitude ratios with inertial seismometers, the dense sampling of DAS over potentially large portions of the focal sphere can aid our solutions. Here, we consider ∼200 regional earthquakes and thousands of S / P measurements on a DAS cable colocated with a network of inertial seismometers near Arcata, California. We demonstrate the S / P ratio measurements made on DAS are similar to those made on the inertial seismometers and can be used to constrain focal mechanism solutions.

California↗
USGS2024

GRAPES: Earthquake early warning by passing seismic vectors through the grapevine

Estimating an earthquake's magnitude and location may not be necessary to predict shaking in real time; instead, wavefield-based approaches predict shaking with few assumptions about the seismic source. Here, we introduce GRAph Prediction of Earthquake Shaking (GRAPES), a deep learning model trained to characterize and propagate earthquake shaking across a seismic network. We show that GRAPES’ internal activations, which we call “seismic vectors”, correspond to the arrival of distinct seismic phases. GRAPES builds upon recent deep learning models applied to earthquake early warning by allowing for continuous ground motion prediction with seismic networks of all sizes. While trained on earthquakes recorded in Japan, we show that GRAPES, without modification, outperforms the ShakeAlert earthquake early warning system on the 2019 M7.1 Ridgecrest, CA earthquake.

Shimane/HiroshimaPrefectures↗
USGS2025

Airborne geophysical analysis to decipher salinization for coastal Louisiana

Coastal Louisiana is known for saltwater intrusion that threatens wetlands, aquifers, and rivers. However, the extent of saltwater intrusion is not well understood. This study develops an innovative framework with airborne electromagnetic (AEM) data to map chloride concentration distributions for wetlands in the Mississippi River deltaic plain and Chenier plain as well as for the Mississippi River Valley alluvial aquifer (MRVA) and Chicot aquifer. Moreover, the framework maps chloride concentrations along the Mississippi River and Atchafalaya River. Key components in the framework include the establishment of resistivity-to-chloride concentration transformation, 3D resistivity architecture building through geostatistics, and the employment of a lithologic model. The transformation functions correlate AEM resistivity data with porewater salinity measurements and groundwater and river chloride samples. The results show that AEM data reliably infers soil water chloride concentrations and correlates well with the distribution of various marsh types. AEM data reveals extensive saltwater presence at depth and near the coast, originating from salt domes and the Gulf of Mexico, respectively. The saltwater upconing pattern in the Chicot aquifer is likely due to excessive groundwater withdrawals. The AEM data also confirms a distinct tongue of saltwater intruding into the Atchafalaya Basin from the Gulf. The AEM data helps to identify faults that are obscured or eroded at the surface, which appear as leaky barriers in the subsurface where dramatic changes in chloride concentration are apparent. Finally, this study uses the AEM data to infer the presence of an extensive seawater wedge in the Mississippi River and Atchafalaya River.

Louisiana↗
USGS2025

The role of bedrock circulation depth and porosity in mountain streamflow response to prolonged drought

Quantitative understanding is lacking on how the depth of active groundwater circulation in bedrock affects mountain streamflow response to a multi‐year drought. We use an integrated hydrological model to explore the sensitivity of a variety of streamflow metrics to bedrock circulation depth and porosity under a plausible extreme drought scenario lasting up to 5 years. Endmember depth versus hydraulic conductivity relationships and porosity values for fractured crystalline rock are simulated. With drought, a deeper circulation system with higher drainable porosity more effectively buffers minimum flow and significantly limits perennial stream loss in comparison to a shallow circulation system. Streamflow buffering is accomplished through extensive groundwater storage loss. However, deeper circulation systems experience prolonged recovery from drought in comparison to storage‐limited shallow systems. Research highlights the importance of characterizing the deeper bedrock hydrogeology in mountainous watersheds to better understand and predict drought impacts on stream ecosystem health and water resource sustainability.

Colorado↗
USGS2025

Multi-scale predictors of Northern Long-eared Bat (Myotis septentrionalis) occupancy in the United States

Historically, Myotis septentrionalis (Northern Long eared Bat) was among the most common forest-interior species in North America. Largely due to high mortality from white-nose syndrome, this species has experienced severe population declines across its range. To create an updated species distribution map representing summer occupancy probabilities from 2017 to 2022, we integrated stationary acoustic data with live-capture data from the database of the North American Bat Monitoring Program into a multi-scale, multi-method occupancy modeling framework. Our results provide data-driven predictions with quantified uncertainty for summer occupancy probabilities for Northern Long-eared Bats at 2 spatial scales across the range of the species, while also accounting for inherent observation biases (e.g., imperfect detection).

Journal of North American Bat Research↗
USGS2026

Decadal shifts in groundwater age detected by environmental tracers across California, USA

Groundwater age offers important insight into recharge, storage, and contamination risk. Although models predict age changes can be driven by pumping and climate variability, direct observational evidence remains limited. Here, we analyzed paired environmental tracer suites (tritium, carbon-14, and tritiogenic helium-3) collected a decade apart from 268 wells across California to assess the prevalence of groundwater age transience. Travel-time distribution models and statistical tests indicated age transience at 29% of sites, occurring most often in agricultural regions, such as the San Joaquin Valley and Southern Coast Ranges, where large carbon-14 changes coincided with substantial nitrate and chloride shifts. Sites with tritiogenic helium-3 data showed more frequent age transience, underscoring the value of multi-tracer data sets. These results provide the first regional evidence of widespread groundwater age change and a method for detecting changing water balances with implications for groundwater sustainability and water quality.

California↗
USGS2025

Anomalous shear stress variation in wet granular medium: Implications for landslide lateral faults

Landslide assessments typically focus on the mechanical properties of the basal shear zone, but lateral faults are frequently overlooked, possibly due to their lower normal stresses and variably saturated conditions. Using double-cylinder shear experiments on wet granular systems as analogs for landslide lateral faults, we observe anomalous shear stress variations with fluid volume fractions, defying an expected unimodal relationship associated with capillary cohesion. At low fluid volume fractions, shear strength weakens as the wet grain assembly experiences reduced lateral pressure and increased boundary slip. This boundary slip subsequently vanishes, with an abrupt strengthening due to the dilation of the grain assembly against fluid surface tension as saturation approaches. Strike-slip motion and confinement in this system explain the strength anomaly, highlighting a critical role of lateral faults in landslide stability, particularly in cases where dynamics cannot be adequately explained by monitored pore-water pressure or basal friction.

Geophysical Research Letters↗
USGS2025

Land application of drill waste: A scope analysis

Drilling fluid waste land application, a process where drilling wastes are spread and tilled into the land surface, has become common in some petroleum-producing states, however, the potential benefits and risks of this practice are not well studied. Drilling fluids can be water- or oil-based and can have high concentrations of total soluble salts and total petroleum hydrocarbons. Comprehensive chemical characterization of these fluids is not well documented in the literature, and the extent of land application is largely unknown. We hypothesized that the land application of drill waste would fluctuate over time due to economic factors. To begin to understand the extent of historical and potential future land application, we analyzed data from over 5,800 drilling fluid land application permits collected by the Oklahoma Corporation Commission for years 2000, 2005, 2010, and 2015–2020. During the years studied, drilling fluid wastes were applied to more than 250,000 acres in Oklahoma, with over 54,000 thousand barrels (Mbbl) of liquids and nearly 21,000 Mbbl of solids applied. Land application is widespread (occurring in 59/77 counties), however recent drilling activity, land availability, and the economics of transportation have created conditions favorable for land application specifically in the Anadarko Basin. Land application can co-occur with sensitive areas, such as important groundwater and surface-water drinking sources and agricultural fields used for subsistence or feed crop production. Our approach for quantifying the extent of land application, along with further chemical characterization studies, can aid operators and land managers who are considering this practice in assessing the associated benefits and risks.

Oklahoma↗
USGS2025

Surface-wave relocation and characterization of the October 2023 tsunamigenic seismic unrest near Sofugan volcano, Izu Islands, Japan

A moderate-magnitude earthquake swarm occurred in the remote Izu Islands region of Japan between October 1 and 8, 2023. The swarm included 151 shallow earthquakes cataloged by the U.S. Geological Survey, which notably included a roughly 2.5-hr episode of 15 successive magnitude (M) < 5.5 earthquakes. Origin times were coincident with regionally recorded tsunami waves, but tsunamigenesis for moderate-magnitude earthquakes is uncommon, indicating that volcanic activity generated the ocean displacements. Leveraging a surface-wave relative relocation approach, we estimate precise epicentroid locations for the remote swarm. Final epicentroids and caldera analogs indicate a three-stage model to explain swarm activity: (a) caldera pressurization due to magma intrusion, (b) depressurization via dike propagation away from the caldera, and (c) eruption corresponding with caldera reactivation either by collapse or additional intrusion.

Sofugan volcano, Izu Islands↗
USGS2021

Remote sensing-based actual evapotranspiration assessment in a data-scarce area of Brazil: A case study of the Urucuia Aquifer System

The large groundwater reserves of the Urucuia Aquifer System (UAS) enabled agricultural development and economic growth in the western Bahia State, in northeastern Brazil. Over the last several years, concern has grown around the aquifer’s diminishing water levels, and water balance (WB) studies are in demand. Considering the lack of measured actual evapotranspiration (ET a ), a major component of the water cycle, this work uses the Operational Simplified Surface Energy Balance (SSEBop) model to estimate ET a , and compares it to basin-scale estimates from the Soil Moisture Accounting Procedure (SMAP) monthly model and from an annual WB closure method, based on gridded meteorological data and the Gravity Recovery and Climate Experiment (GRACE) product. Additionally, a comparative assessment of different versions of the SSEBop parameterization was performed. Moderate Resolution Imaging Spectroradiometer (MODIS) imagery was used to implement eight different versions of the SSEBop algorithm over the UAS between 2000 and 2013. SSEBop and SMAP ET a yielded similar seasonal patterns, with correlation coefficient (r) up to 0.65, mean difference (MD) of 0.8 mm/month and mean absolute difference (MAD) of 18.5 mm/month. Comparison of SSEBop annual ET a estimates to annual SMAP and WB closure estimates yielded low MD (12.1 and −7.3 mm/year, respectively) and MAD (82.5 and 82.8 mm/year, respectively), but also low r values (0.00 and 0.37, respectively). The comparison of the different SSEBop versions indicated the need to incorporate a calibration step of the aerodynamic heat resistance (r ah ) parameter. SSEBop results were also used for land cover and drought monitoring. Analysis indicates that agriculture, associated with an increasing trend of atmospheric evaporative demand, is responsible for the decrease in groundwater levels and streamflow in the studied time period.

Urucuia Aquifer System↗
USGS2026

Asynchronous landslide seasonality across the United States

Mid-range landslide outlooks can facilitate weather-related landslide preparedness and disaster response planning, but seasonal landslide activity remains poorly quantified at continental scales. Leveraging >55,000 reported landslides from across the United States (U.S.), we used circular statistics to quantify landslide seasonality in 67 National Weather Service County Warning Areas (CWAs). We found regional differences in landslide season timing and duration, with transitions between domains variably corresponding to climate class or river basin. We assessed differences in seasonality by movement type for slides, flows, and falls, detecting apparent, but uncertain, differences between slide and fall seasonalities in 27 of 35 (77%) of CWAs with both types reported. In the Pacific Northwest, where long records exist, we found a credible shift toward a later mean landslide season in western Washington from 1990 to 2020, but no trend in western Oregon. Our results can provide emergency planners a resource to assess seasonal landslide probability nationwide.

Geophysical Research Letters↗
USGS2026

Ice sheet dynamics drive pronounced changes in the subsurface freshwater-saltwater interface

Saltwater is migrating into freshwater aquifers globally with water quality and biogeochemical implications, yet saltwater intrusion in glaciated regions is sparsely investigated. Field observations suggest that groundwater head in glaciated systems is influenced by ice sheet forcings and provides evidence that seawater infiltrated into offshore aquifers during past deglaciation events. To understand links between ice sheet dynamics, groundwater head, and saltwater intrusion, we use numerical models to explore the effects of deglaciation on nearshore head and salinity distributions. We find that ice sheet thinning diminishes groundwater head, and the resulting shift in subsurface pressure gradients drives rapid landward movement of the subsurface freshwater-saltwater interface up to 4.0 km or 1.3 m per m ice sheet loss. Results highlight an overlooked saltwater intrusion mechanism that aligns with field observations and affects glaciated coastlines undergoing ice sheet retreat, underscoring the need to consider this mechanism in studies of contemporary coastal water quality.

Geophysical Research Letters↗