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At least 73 records · Page 4Linked to original sources

Colored dissolved organic matter in shallow estuaries: relationships between carbon sources and light attenuation

Light availability is of primary importance to the ecological function of shallow estuaries. For example, benthic primary production by submerged aquatic vegetation is contingent upon light penetration to the seabed. A major component that attenuates light in estuaries is colored dissolved organic matter (CDOM). CDOM is often measured via a proxy, fluorescing dissolved organic matter (fDOM), due to the ease of in situ fDOM sensor measurements. Fluorescence must be converted to CDOM absorbance for use in light attenuation calculations. However, this CDOM–fDOM relationship varies among and within estuaries. We quantified the variability in this relationship within three estuaries along the mid-Atlantic margin of the eastern United States: West Falmouth Harbor (MA), Barnegat Bay (NJ), and Chincoteague Bay (MD/VA). Land use surrounding these estuaries ranges from urban to developed, with varying sources of nutrients and organic matter. Measurements of fDOM (excitation and emission wavelengths of 365 nm (±5 nm) and 460 nm (±40 nm), respectively) and CDOM absorbance were taken along a terrestrial-to-marine gradient in all three estuaries. The ratio of the absorption coefficient at 340 nm (m −1 ) to fDOM (QSU) was higher in West Falmouth Harbor (1.22) than in Barnegat Bay (0.22) and Chincoteague Bay (0.17). The CDOM : fDOM absorption ratio was variable between sites within West Falmouth Harbor and Barnegat Bay, but consistent between sites within Chincoteague Bay. Stable carbon isotope analysis for constraining the source of dissolved organic matter (DOM) in West Falmouth Harbor and Barnegat Bay yielded δ 13 C values ranging from −19.7 to −26.1 ‰ and −20.8 to −26.7 ‰, respectively. Concentration and stable carbon isotope mixing models of DOC (dissolved organic carbon) indicate a contribution of 13 C-enriched DOC in the estuaries. The most likely source of 13 C-enriched DOC for the systems we investigated is Spartina cordgrass. Comparison of DOC source to CDOM : fDOM absorption ratios at each site demonstrates the relationship between source and optical properties. Samples with 13 C-enriched carbon isotope values, indicating a greater contribution from marsh organic material, had higher CDOM : fDOM absorption ratios than samples with greater contribution from terrestrial organic material. Applying a uniform CDOM : fDOM absorption ratio and spectral slope within a given estuary yields errors in modeled light attenuation ranging from 11 to 33 % depending on estuary. The application of a uniform absorption ratio across all estuaries doubles this error. This study demonstrates that light attenuation coefficients for CDOM based on continuous fDOM records are highly dependent on the source of DOM present in the estuary. Thus, light attenuation models for estuaries would be improved by quantification of CDOM absorption and DOM source identification.

Biogeosciences

Performance metrics for the assessment of satellite data products: An ocean color case study

Performance assessment of ocean color satellite data has generally relied on statistical metrics chosen for their common usage and the rationale for selecting certain metrics is infrequently explained. Commonly reported statistics based on mean squared errors, such as the coefficient of determination (r 2 ), root mean square error, and regression slopes, are most appropriate for Gaussian distributions without outliers and, therefore, are often not ideal for ocean color algorithm performance assessment, which is often limited by sample availability. In contrast, metrics based on simple deviations, such as bias and mean absolute error, as well as pair-wise comparisons, often provide more robust and straightforward quantities for evaluating ocean color algorithms with non-Gaussian distributions and outliers. This study uses a SeaWiFS chlorophyll-a validation data set to demonstrate a framework for satellite data product assessment and recommends a multi-metric and user-dependent approach that can be applied within science, modeling, and resource management communities.

Optics Express

Advantages and limitations to the use of optical measurements to study sediment properties

Measurements of optical properties have been used for decades to study particle distributions in the ocean. They are useful for estimating suspended mass concentration as well as particle-related properties such as size, composition, packing (particle porosity or density), and settling velocity. Measurements of optical properties are, however, biased, as certain particles, because of their size, composition, shape, or packing, contribute to a specific property more than others. Here, we study this issue both theoretically and practically, and we examine different optical properties collected simultaneously in a bottom boundary layer to highlight the utility of such measurements. We show that the biases we are likely to encounter using different optical properties can aid our studies of suspended sediment. In particular, we investigate inferences of settling velocity from vertical profiles of optical measurements, finding that the effects of aggregation dynamics can seldom be ignored.

MDPI - Applied Sciences

Optically stimulated luminescence dating of late Holocene raised strandplain sequences adjacent to Lakes Michigan and Superior, Upper Peninsula, Michigan, USA

This study evaluates the accuracy of optically stimulated luminescence to date well-preserved strandline sequences at Manistique/Thompson bay (Lake Michigan), and Tahquamenon and Grand Traverse Bays (Lake Superior) that span the past ∼4500 yr. The single aliquot regeneration (SAR) method is applied to produce absolute ages for littoral and eolian sediments. SAR ages are compared against AMS and conventional 14 C ages on swale organics. Modern littoral and eolian sediments yield SAR ages <100 yr indicating near, if not complete, solar resetting of luminescence prior to deposition. Beach ridges that yield SAR ages <2000 yr show general agreement with corresponding 14 C ages on swale organics. Significant variability in 14 C ages >2000 cal yr B.P. complicates comparison to SAR ages at all sites. However, a SAR age of 4280 ± 390 yr (UIC913) on ridge77 at Tahquamenon Bay is consistent with regional regression from the high lake level of the Nipissing II phase ca. 4500 cal yr B.P. SAR ages indicate a decrease in ridge formation rate after ∼1500 yr ago, likely reflecting separation of Lake Superior from lakes Huron and Michigan. This study shows that SAR is a credible alternative to 14 C methods for dating littoral and eolian landforms in Great Lakes and other coastal strandplains where 14 C methods prove problematic.

Quaternary Research

The Missoula and Bonneville floods—A review of ice-age megafloods in the Columbia River basin

The Channeled Scabland of eastern Washington State, USA, brought megafloods to the scientific forefront. A 30,000-km2 landscape of coulees and cataracts carved into the region’s loess-covered basalt attests to overwhelming volumes of energetic water. The scarred landscape, garnished by huge boulder bars and far-travelled ice-rafted erratics, spurred J Harlen Bretz’s vigorously disputed flood hypothesis in the 1920s. First known as the Spokane flood, it was rebranded the Missoula flood once understood that the water came from glacial Lake Missoula, formed when the Purcell Trench lobe of the last-glacial Cordilleran ice sheet dammed the Clark Fork valley in northwestern Idaho with ice a kilometer thick. Bretz’s flood evidence in the once-remote Channeled Scabland, widely seen and elaborated by the 1950s, eventually swayed consensus for cataclysmic flooding. Missoula flood questions then turned to some that continue today: how many? when? how big? what routes? what processes? The Missoula floods passed through eastern Washington by a multitude of valleys, coulees and scabland tracts, some contemporaneously, some sequentially. Which routings and their timing depended on the positions of various lobes of the multi-pronged Cordilleran ice sheet and the erosional development of the channels themselves. The first floods mostly followed the big bend of Columbia valley looping through north-central Washington. But the south-advancing Okanogan ice lobe soon blocked that path, forming long-lasting glacial Lake Columbia in the impounded Columbia valley. Missoula floods into this lake were diverted south out of the Columbia valley and into eastern Washington coulees and scabland tracts. At least four floods entered Moses Coulee, but then as the Okanogan lobe advanced over and blocked the head of that coulee, more eastern paths took the water, including Grand Coulee and the Telford-Crab-Creek and Cheney-Palouse scabland tracts. Flood routing also depended on the erosion of the coulees. At some point, headward erosion of upper Grand Coulee lowered the divide saddle between the west-running Columbia valley and the deep and wide Grand Coulee heading southwest. Still uncertain is when this happened and the consequences with respect to the stage and extent of glacial Lake Columbia and to flood access to the other, higher, flood routes. Downstream, all flood routes converged onto Pasco Basin, flowed through Wallula Gap and the Columbia River Gorge into the Pacific Ocean, following submarine canyons and depositing sediment layers on abyssal plains. Stratigraphic studies indicate dozens—likely more than a hundred—separate Missoula floods during the last glacial period. Over the length of the flood route, backwater areas and depositional basins preserve multiple flood beds, many of which are separated by signs of time, including volcanic ash layers and soil development in subaerial environments; and varve-like beds and pelagic mud layers in lacustrine and marine settings. Evidence also comes from the glacial Lake Missoula basin, where stratigraphy indicates dozens of filling and emptying cycles. Varve counts in conjunction of radiocarbon dating and paleomagnetic secular variation show the repeated filling-and-release cycles of glacial Lake Missoula had intervals possibly as long as 100 years early in the lake’s history but diminished to just one or two years for the last few floods. This behavior accords with jökulhlaup-style floods released by subglacial drainage from a self-dumping ice-dammed lake. But not yet clear is whether such a mechanism applies to all the floods or if some emptied more cataclysmically as hypothesized by some. Radiocarbon dating of sparse organic materials remains key to defining flood chronology but has been lately bolstered by analyses of terrestrial cosmogenic nuclides and optically stimulated luminescence. Varve counts and paleomagnetic secular variation studies help to define durations and intervals represented by sequences of flood beds. The ~16 ka Mount St. Helens Set S tephra is commonly interbedded within flood deposits, enabling correlation of deposits among sites. Tephra from the 13.7–13.4 ka eruption of Glacier Peak overlies all glacial Lake Missoula and Missoula flood deposits, defining an end time. Overall conclusions are that glacial Lake Missoula was extant and producing floods for at least 3–4 ky during 20–14 ka. At least ~75 floods preceded Mount St Helens Set S, followed by 30 or more after the tephra fall. Most floods entered glacial Lake Columbia, impounded by the Okanogan lobe, for 2–5 ky between about 18.5 and 15 ka. Glacial Lake Columbia outlived Lake Missoula by >200–400 yr but may have been born later since at least one flood came down the Columbia valley before the Okanogan ice lobe blocked the Columbia valley at 18.5–18 ka. The maximum extent of the Okanogan and Purcell Trench lobes, many Missoula floods, substantial erosion of upper Grand Coulee, and the widespread tephra falls from Mount St. Helens eruptions all happened about 17–15 ka. People, in the area since 16.6–15.3 ka, almost certainly witnessed the last of the Missoula floods and later large floods from other ice-dammed lakes in the Columbia River basin. Quantitative flow analyses give peak discharge estimates and support understanding of erosional and depositional processes. The first flow assessments were simple cross-section calculations but recent assessments employ two-dimensional hydrodynamic models. The general finding is that emplacement of the maximum stage evidence requires about 20 million m3/s near the Lake Missoula outlet and about 5–15 million m3/s through Wallula Gap and downstream in the Columbia River Gorge. These hydraulic analyses raise still-unresolved questions regarding canyon erosion and possible additional water sources. The large Pleistocene Bonneville flood entered the Columbia River system from the southeast from pluvial Lake Bonneville, the Pleistocene predecessor to Great Salt Lake in the eastern Great Basin. During the last glacial, the lake basin filled, covering >50,000 km2 with 10,400 km3 of water before reaching its maximum possible stage governed by Red Rock Pass, the lowest divide separating the basin from the Snake River basin to the north. The overtopping lake rapidly incised 108–125 m into the Red Rock Pass outlet, spilling half of its total lake volume. G.K. Gilbert described the essential sequence in the 1870s, but the flood was mostly forgotten until the late 1950s when Harold Malde linked the spectacular scabland topography and bouldery “melon gravel” on the Snake River Plain to the Lake Bonneville overflow. The Bonneville flood appears to have been a singular event at about 18 ka. No evidence of multiple or pre-last-glacial spillovers has yet been found. Its total volume was about twice that of a maximum Lake Missoula flood yet its peak discharge was ~1 million m3/s, less than a tenth of the largest Missoula floods. Its comparatively simple flow path and much steadier flow make the Bonneville flood ideal for new studies of erosional and depositional processes. At least two floods seem to have passed down the Columbia valley after the last of the Missoula floods, including a large flood about ~14 ka likely from cataclysmic demise of the thinning Okanogan ice lobe dam impounding glacial Lake Columbia. Floods from earlier glacial ages left scant yet clear evidence in the Channeled Scabland and Columbia valley. But their source, timing, and magnitudes are little understood. Some deposits are paleomagnetically reversed, thus older than ~800 ka. Last-glacial floods and perhaps older ones affected the Snake River Plain, some likely sourced in lakes dammed by alpine glaciers in central Idaho.

Idaho, Oregon, Washington

Remote sensing of river bathymetry: Evaluating a range of sensors, platforms, and algorithms on the upper Sacramento River, California, USA

Remote sensing has become an increasingly viable tool for characterizing fluvial systems. In this study, we used field measurements from a 1.6 km reach of the upper Sacramento River, CA, to evaluate the potential of mapping water depths from a range of platforms, sensors, and depth retrieval methods. Field measurements of water column optical properties also were compared to similar data sets from other rivers to provide context for our results. We considered field spectra, a multispectral satellite image, hyperspectral data collected from conventional and unmanned aircraft, and a bathymetric LiDAR and applied a generalized version of Optimal Band Ratio Analysis (OBRA) and the K nearest neighbors regression (KNN) machine learning algorithm. Linear, quadratic, exponential, power, and lowess OBRA models enabled more flexible curve-fitting in calibrating spectrally based quantities to depth; an exponential formulation avoided artifacts associated with other model types. KNN increased observed vs. predicted R2 values, particularly for the satellite image; we also found that pre-processing of satellite images was unnecessary and that a basic data product could be used for depth retrieval. Bathymetric LiDAR was highly accurate and precise in shallow water, but a lack of bottom returns from areas greater than 2 m deep resulted in large gaps in coverage. The maximum detectable depth imposes an important constraint on fluvial remote sensing and a hybrid approach combined with field surveys of deep areas might be a more realistic operational strategy for bathymetric mapping. Future work will focus on scaling up from short reaches to long river segments.

California

Validation of the ASTER instrument level 1A scene geometry

An independent assessment of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument geometry was undertaken by the U.S. ASTER Team, to confirm the geometric correction parameters developed and applied to Level 1A (radiometrically and geometrically raw with correction parameters appended) ASTER data. The goal was to evaluate the geometric quality of the ASTER system and the stability of the Terra spacecraft. ASTER is a 15-band system containing optical instruments with resolutions from 15- to 90-meters; all geometrically registered products are ultimately tied to the 15-meter Visible and Near Infrared (VNIR) sub-system. Our evaluation process first involved establishing a large database of Ground Control Points (GCP) in the mid-western United States; an area with features of an appropriate size for spacecraft instrument resolutions. We used standard U.S. Geological Survey (USGS) Digital Orthophoto Quads (DOQS) of areas in the mid-west to locate accurate GCPs by systematically identifying road intersections and recording their coordinates. Elevations for these points were derived from USGS Digital Elevation Models (DEMS). Road intersections in a swath of nine contiguous ASTER scenes were then matched to the GCPs, including terrain correction. We found no significant distortion in the images; after a simple image offset to absolute position, the RMS residual of about 200 points per scene was less than one-half a VNIR pixel. Absolute locations were within 80 meters, with a slow drift of about 10 meters over the entire 530-kilometer swath. Using strictly simultaneous observations of scenes 370 kilometers apart, we determined a stereo angle correction of 0.00134 degree with an accuracy of one microradian. The mid-west GCP field and the techniques used here should be widely applicable in assessing other spacecraft instruments having resolutions from 5 to 50-meters. ?? 2008 American Society for Photogrammetry and Remote Sensing.

Photogrammetric Engineering and Remote Sensing

Luminescence dating of hydrothermal explosions in the Yellowstone Plateau volcanic field

Hydrothermal explosions are a significant geological hazard in some active volcanic systems; however, the timing and triggering mechanisms of these explosions are poorly constrained. This study applies luminescence dating techniques to hydrothermal explosion deposits in the Yellowstone Plateau volcanic field to constrain explosion chronologies and evaluate potential triggering mechanisms. We tested four luminescence dating techniques: K-feldspar post-infrared infrared stimulated luminescence (pIRIR225), quartz blue light optically stimulated luminescence (BLOSL), quartz blue thermoluminescence (BTL), and quartz red thermoluminescence (RTL). The pIRIR225 and RTL protocols produce consistent age estimates that agree with independent radiocarbon ages and with the timing of the Pinedale deglaciation. This study focuses on two craters, Mary Bay, along the northern shore of Yellowstone Lake, and Pocket Basin in Lower Geyser Basin. The mean pIRIR225 ages from Mary Bay deposits (11.99 ± 0.68 ka) agree with previous radiocarbon constraints. The mean pIRIR225 results from Pocket Basin deposits (13.44 ± 1.06 ka) suggest a history of explosion following Pinedale deglaciation, followed by recent hydrothermal alteration. Luminescence dating techniques are a promising tool for reconstructing the timing of hydrothermal explosions in the Late Pleistocene and Holocene, helping to constrain recurrence intervals of the largest hydrothermal systems, informing risk, and improving hazard assessments.

Idaho, Montana, Wyoming

Analysis of barium and strontium in sediments by dc plasma emission spectrometry

The dc plasma arc is suited to analysis of barium and strontium in a wide range of sedimentary rock matrices, from sands, shales, and carbonates, to ferromanganese nodules. Samples containing 10 ppm to more than 3000 ppm barium and strontium were studied. Both alkali (3500 ppm lithium borate, from a preliminary fusion) and lanthanum salts (1%) in the final solution are needed to achieve freedom from systematic effects due to extreme variation in matrix. In the absence of La, neither Li, Na, K, nor Cs totally eliminated effects of Al and other constituents on emission. Silica addition to the fusion helps achieve proper flux viscosity to aid removal of fused beads from graphite crucibles. The effect of refractory-substance formers such as aluminum with calcium can be reduced or removed by selection of a portion of the arc for emission measurement. However, it was decided not to pursue this approach because of loss in analytical sensitivity and need for greater precision in optical adjustment. Analysis of standard rock samples showed generally satisfactory agreement with precision methods of analysis, and some new standard rock data are reported.

Applied Spectroscopy

The removal kinetics of dissolved organic matter and the optical clarity of groundwater

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d −1 ), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d −1 ). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L −1 ) and ultraviolet absorption coefficient values ( a 254 < 5 m −1 ) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.

California, Colorado, Connecticut, Georgia, Illino

Synthesis of geochronologic research on Late Pliocene to Holocene emergent shorelines in the lower Savannah River area of southeastern Georgia, USA

Emergent late Pliocene and Pleistocene shoreline deposits, morphologically identifiable Pleistocene shoreline units, and seaward-facing scarps characterize the easternmost Atlantic Coastal Plain (ACP) of the United States of America. In some areas of the ACP, these deposits, units, and scarps have been studied in detail. Within these areas, temporal and spatial data are sufficient for time-depositional frameworks for shoreline-evolution to have been developed and published. For other areas, such as the southeastern Atlantic Coastal Plain (SEACP), available data are conflicting and (or) insufficient to develop such a framework, or to make shoreline correlations. Differential epeirogenic uplift and shoreline deformation, resulting from mantle-flow and climate-induced isostatic adjustments, complicate regional shoreline correlations. In the SEACP, the topographically prominent Orangeburg Scarp (hereafter, the Scarp) rises tens of meters in elevation from southeastern Georgia to southeastern North Carolina. The degree to which the Scarp and shoreline units seaward of the Scarp are deformed continues to be debated, but there is general agreement that the lower Savannah River area (LSRA) of Georgia and South Carolina is the least deformed area of the SEACP. This paper synthesizes published and previously unpublished numerical age and stratigraphic data for emergent Pliocene and younger shoreline deposits in the LSRA in Georgia. Age data are applied to these shoreline deposits as they are delineated (map units) on the 1976 geologic map of Georgia by Lawton and others. Age assignments are based on stratigraphic position, fossil content, soil and weathering diagnostic properties, and numerical ages as determined by meteoric Beryllium‑10 paleosol residence time ( 10 BePRT), optically stimulated luminescence (OSL), uranium disequilibrium series (U-series), amino acid racemization (AAR), and radiocarbon ( 14 C) analyses. These data provide a preliminary Pliocene-Pleistocene geochronology for the Orangeburg Scarp and shoreline deposits seaward of the Scarp in the LSRA of Georgia. Minimum ages and age ranges indicate the following: the Orangeburg Scarp formed sometime in the late Pliocene and early Pleistocene, between 3 Ma and 1 Ma; three, and possibly four, shoreline complexes were deposited in the middle Pleistocene; two shoreline complexes were deposited in the late middle and the late Pleistocene; deposition of the youngest shoreline complex began in the late Pleistocene and continues to the present; each shoreline complex was modified by multiple sea level highstands over time periods that lasted tens of thousands to hundreds of thousands of years; and Pleistocene shoreline chronology differs in part from modeled global sea level highstands.

Georgia, South Carolina

The sensitized luminescence of manganese-activated calcite

Synthetic manganese-activated calcites are shown to be practically inert to ultraviolet excitation in the range 2000-3500A, while they are luminescent under cathode-ray excitation. The incorporation of small amounts of an auxiliary impurity along with the manganese produces the strong response to ultraviolet radiation hitherto ascribed to CaCO3:Mn itself. Three such impurities have been studied: lead, thallium, and cerium. The first two induce excitation in the neighborhood of the mercury resonance line, while the cerium introduces a response principally to longer wave ultraviolet. The strong response to 2537A excitation shown by some natural calcites is likewise found to be due to the presence of lead along with the manganese, rather than to the manganese alone. The data do not warrant ascribing the longer wave-length ultraviolet-excited luminescence of all natural calcites to the action of an auxiliary impurity. The essential identity of the cathode-ray excited luminescence spectra of CaCO 3:Mn, CaCO3: (Pb+Mn), CaCO3:(Tl+Mn), and CaCO3:(Ce+Mn) with the 2537A-excited spectra of the latter three is evidence that the luminescent center in all cases is the manganese ion or the MnO6 group. It is shown that a "cascade" mechanism for the action of the auxiliary impurities, lead, thallium, and cerium, is incorrect; and that the phenomenon must be considered as a case of sensitized luminescence. Owing to the nature of cathode-ray excitation, the manganese activator can be excited by this agent even in the absence of a second impurity. For optical excitation, however, an absorption band for the ultraviolet must be established by building into the CaCO3:Mn a second impurity or "sensitizer.".

Journal of Applied Physics

Remote measurement of river discharge using thermal particle image velocimetry (PIV) and various sources of bathymetric information

Although river discharge is a fundamental hydrologic quantity, conventional methods of streamgaging are impractical, expensive, and potentially dangerous in remote locations. This study evaluated the potential for measuring discharge via various forms of remote sensing, primarily thermal imaging of flow velocities but also spectrally-based depth retrieval from passive optical image data. We acquired thermal image time series from bridges spanning five streams in Alaska and observed strong agreement between velocities measured in situ and those inferred by Particle Image Velocimetry (PIV), which quantified advection of thermal features by the flow. The resulting surface velocities were converted to depth-averaged velocities by applying site-specific, calibrated velocity indices. Field spectra from three clear-flowing streams provided strong relationships between depth and reflectance, suggesting that, under favorable conditions, spectrally-based bathymetric mapping could complement thermal PIV in a hybrid approach to remote sensing of river discharge; this strategy would not be applicable to larger, more turbid rivers, however. A more flexible and efficient alternative might involve inferring depth from thermal data based on relationships between depth and integral length scales of turbulent fluctuations in temperature, captured as variations in image brightness. We observed moderately strong correlations for a site-aggregated data set that reduced station-to-station variability but encompassed a broad range of depths. Discharges calculated using thermal PIV-derived velocities were within 15% of in situ measurements when combined with depths measured directly in the field or estimated from field spectra and within 40% when the depth information also was derived from thermal images. The results of this initial, proof-of-concept investigation suggest that remote sensing techniques could facilitate measurement of river discharge.

Journal of Hydrology

Improving hydroacoustic methods for monitoring suspended-sand flux and grain size in sediment-laden rivers

Suspended-sand concentration and grain-size data in rivers provide valuable information on the catchment's dynamics for scientists and river managers. Producing continuous measurements of suspended-sand concentrations remains a scientific challenge due to their high spatial and temporal variability. Traditional methods such as sediment-rating curves may be highly uncertain, and optical turbidity is insensitive to coarse particles when there are many fine particles. Surrogate hydroacoustic methods aim to improve sand concentration measurements. These single- or dual-frequency acoustic methods use acoustic attenuation and/or backscatter to estimate fine-sediment (i.e., silt and clay) and/or sand concentration and possibly grain size. New methods have recently been developed and applied in rivers exhibiting a wide range of sediment conditions in North America but not independently tested elsewhere by other researchers. In this article, we apply, adapt and evaluate hydroacoustic methods to continuously estimate suspended-sand concentration and grain size in an Alpine river with high suspended-sediment concentrations. From the example of the River Isère at Grenoble Campus, France, we show that the hydroacoustic methods adapted to local conditions may yield valuable sand concentration estimates consistent with traditional measurements. Compared with prior knowledge, limited additional information on the grain size can be obtained due to high uncertainties. Hydroacoustic concentration estimates are more sensitive to real changes in concentration at the event scale than traditional rating-curve methods that relate concentration to discharge only. These findings open the perspective for facilitated sand concentration monitoring at a higher temporal resolution with decreased field work.

Grenoble Campus

Evaluating drivers of environmental change in a lake sediment core: Insights from spectroscopic metrics of water-extractable organic matter and stable carbon isotopes

Freshwater lakes play a critical role in the global carbon cycle by storing and transforming organic matter (OM) from both terrestrial and aquatic sources. Small lakes in northern temperate regions, despite their limited surface area, disproportionately influence regional carbon budgets. Buried sediments integrate OM inputs over time and archive ecosystem responses to natural and anthropogenic disturbances. However, the direction and magnitude of recent environmental changes on sediment carbon (C) dynamics remain poorly understood. A 23-cm core was collected from a small temperate lake in northeastern USA to evaluate sediment OM content and composition over timescales relevant to historical land-use change, damming, and recovery from acid deposition. Patterns in OM burial and source contributions were revealed via elemental and isotopic analyses of bulk OM and ultraviolet-visible spectrophotometry of water-extractable organic matter (WEOM). The optical metrics expanded observations of likely OM sources beyond the information gained from bulk carbon metrics (total carbon, δ 13 C). The aromaticity of WEOM increased downcore, which is consistent with a shift from increased terrestrial inputs during early logging and damming activity (pre ∼1920) to more microbial-derived OM in recent surficial sediments. Future applications of WEOM optical properties as complements to traditional geochemical metrics can enhance interpretations of lake ecosystem responses recorded in lake sediments to environmental perturbations in temperate lakes.

New York

Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows . This study explored a mass-balance field-based computation of consumptive use in a residential setting at the scale of a sanitary sewer service area (sewershed). In addition, the feasibility (cost and difficulty) and relative uncertainties (accuracies) associated with applying the approach at this scale were evaluated. The study was conducted during 2011&ndash;13 within a 3.5-square mile (mi 2 ) sewershed confined to a predominantly residential area of Elk Grove Village, Illinois. Following background evaluation of the geohydrologic setting, sewershed infrastructure, and possible components of supplied and returned water, the identified primary components were 1. public water deliveries by the Elk Grove Village Department of Public Works, 2. self-served groundwater withdrawals in an included unincorporated neighborhood with public sanitary sewer service, 3. return flows to the sanitary sewer system, and 4. direct return of water discharged from swimming pools to Salt Creek. Water volumes principally were reported for deliveries, measured for sanitary sewer returns by using an acoustic Doppler current-velocity meter, and estimated for domestic withdrawals and swimming pool discharges to storm sewers. All water volumes required some degree of estimation. Observation wells were installed adjacent to sewer pipelines (lines) to determine the depth of the water table relative to that of the sewer lines and to collect water samples for detection of optical brighteners, as they are routinely discharged as clotheswashing waste to sanitary sewers. These data provided qualitative information on gains (inflow and infiltration) and losses (exfiltration) of sewer flow by pipe leakage, which might otherwise not be considered in the sewer flow return measurements. Hydrographs of sewer flow also were evaluated to identify and estimate storm-associated inputs to sewer flow. The volume of sanitary sewer return flow (778 million gallons per year [Mgal/yr]) was determined to substantially exceed the volume of supplied water (566 Mgal/yr), thus, for this study setting, voiding the utility of the applied mass-balance approach for estimating consumptive water use. Mass-balance components, including sanitary sewer flow and supplied-water use, were estimated within reasonable limits of uncertainty. Evidence of a water table that is typically shallower than the area&rsquo;s sewer lines, yet is sometimes depressed near more deeply buried sewer lines, suggests groundwater infiltration into the sewers contributes to the excess volume of return flow. Technical obstacles and project resources precluded accurate quantification of infiltration volumes and other gains and losses to sanitary sewer flow. As estimated from various simplified methods, a minimum of 26 percent of return flow measured in the sanitary sewer represented groundwater infiltration and stormwater inflow; separately, about 2 percent of return flow was estimated as inflow. On the basis of the alternative winter base-rate method, consumptive use in the sewershed was estimated as 13 percent, which compares favorably with that used by the State of Illinois for Lake Michigan allocation accounting (10 percent) and other States and Canadian Provinces in the Great Lakes region (generally 10-15 percent). The study also provided other findings considered useful to studies of water use and to performance evaluation of sanitary sewer infrastructure. In urban residential settings, the comparatively small volumes of nonpublic sources of water (self-supplied) and direct (nonsanitary) return flow potentially can be ignored in the estimation of consumptive use. An acoustic Doppler current-velocity meter can be used in sanitary sewers to accurately measure discharge and reasonably estimate storm-associated inflows. Hourly to daily patterns of water use can be readily identified and quantified in the return flow record for the sanitary sewers. Relative volumes of infiltration gains (and exfiltration losses) can be substantial, even in sewer systems of communities making significant investments in system upgrades to limit sewer line leakage. Monitoring of optical brighteners in groundwater (and potentially in sanitary sewer flow) can provide a useful means of identifying probable leakage from (and to) sewer lines. Accurate quantification of gains and losses to sanitary sewer flow at the sewershed scale will require additional research effort and technical advances. Under ideal conditions, accurate quantification of consumptive use at the sewershed scale by the described mass-balance approach might be possible. Under most prevailing conditions, quantification likely would be more costly and time consuming than that of the present study, given the freely contributed technical support of the host community and relatively appropriate conditions of the study area. Essentials to quantification of consumptive use are a fully cooperative community, storm and sanitary sewers that are separate, and newer sewer infrastructure and (or) a robust program for limiting infiltration, exfiltration, and inflow.

Illinois

Compositing multitemporal remote sensing data sets

To eliminate cloud and atmosphere-affected pixels, the compositing of multi temporal remote sensing data sets is done by selecting the maximum vale of the normalized different vegetation index (NDVI) within a compositing period. The NDVI classifier, however, is strongly affected by surface type and anisotropic properties, sensor viewing geometries, and atmospheric conditions. Consequently, the composited, multi temporal, remote sensing data contain substantial noise from these external conditions. Consequently, the composited, multi temporal, remote sensing data contain substantial noise from these external effects. To improve the accuracy of compositing products, two key approaches can be taken: one is to refine the compositing classifier (NDVI) and the other is to improve existing compositing algorithms. In this project, an alternative classifier was developed and an alternative pixel selection criterion was proposed for compositing. The new classifier and the alternative compositing algorithm were applied to an advanced very high resolution radiometer data set of different biome types in the United States. The results were compared with the maximum value compositing and the best index slope extraction algorithms. The new approaches greatly reduced the high frequency noises related to the external factors and repainted more reliable data. The results suggest that the geometric-optical canopy properties of specific biomes may be needed in compositing. Limitations of the new approaches include the dependency of pixel selection on the length of the composite period and data discontinuity.

Pecora 12 Symposium

Overview of selected surrogate technologies for continuous suspended-sediment monitoring

Surrogate technologies for inferring selected characteristics of suspended sediments in surface waters are being tested by the U.S. Geological Survey and several partners with the ultimate goal of augmenting or replacing traditional monitoring methods. Optical properties of water such as turbidity and optical backscatter are the most commonly used surrogates for suspended-sediment concentration, but use of other techniques such as those based on acoustic backscatter, laser diffraction, digital photo-optic, and pressure-difference principles is increasing for concentration and, in some cases, particle-size distribution and flux determinations. The potential benefits of these technologies include acquisition of automated, continuous, quantifiably accurate data obtained with increased safety and at less expense. When suspended-sediment surrogate data meet consensus accuracy criteria and appropriate sediment-record computation techniques are applied, these technologies have the potential to revolutionize the way fluvial-sediment data are collected, analyzed, and disseminated.

Conference Paper