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Thermodynamics and kinetics of reactions involving vanadium in natural systems: Accumulation of vanadium in sedimentary rocks

A critical review of thermodynamic data for aqueous and solid V species is presented to evaluate dissolution, transport, and precipitation of V under natural conditions. Emphasis is given to results of experimental studies of V chemistry, especially those for which the experimental conditions are near those found in nature. Where possible, data are obtained for or corrected to the reference conditions of 298.15K, 1 atm (1.01325 bar) and zero ionic strength. Vanadium [IV] (V IV ) and vanadium[V] (V V ) are the most soluble forms of V in nature, and their complexes with fluoride, sulfate, and oxalate may act to increase V solubility under oxidizing conditions. Because redox behavior is of fundamental importance to understanding natural V chemistry, the kinetics of reduction of V IV to V III H 2 S were studied. Although H 2 S is predicted from thermodynamic data to be capable of reducing V IV to V III , this reaction has not been demonstrated experimentally. Experiments were carried out under conditions of temperature (45°C), pH (3.6–6.8), ionic strength (0.05–0.1 m), and V concentrations (9.8–240 μmolar) likely to be found in nature. Because the reaction is very slow, H 2 S concentrations in excess of natural conditions were used (8.1 × 10 −4 to 0.41 atm). The results show that V IV is reduced to V III under a variety of conditions. The rate increases with increasing pH, but is not appreciably affected by ionic strength (as represented by the concentration of KCl, which was used as the supporting electrolyte in all cases). Prior to initiation of the reaction, there is an induction period, the length of which increases with increasing KCl concentration or decreasing pH. Attempts to model the reaction mechanism by numerical methods have failed to produce a satisfying fit of the results, indicating partial reaction orders, a complex mechanism, or involvement of a variety of intermediate species. The results of the thermodynamic and kinetic studies were applied to understanding the genesis of V deposits such as those commonly found on the Colorado Plateau. Vanadium in these sandstone-hosted deposits is present mostly in the reduced oxidation state, V III . Because of the insolubility of V III oxyhydroxides, it is likely that a more oxidized form of V (either [IV] or [V]) was transported to the site of mineralization, and that the V was reduced in situ and subsequently precipitated. A probable reductant is hydrogen sulfide; the presence of pyrite cogenetic with the V minerals documents the presence of H 2 S during mineralization. The experiments described here show that H 2 S could have reduced V IV to V III , and thus led to the formation of these deposits.

Geochimica et Cosmochimica Acta↗

Probabilistic tsunami hazard analysis: Multiple sources and global applications

Applying probabilistic methods to infrequent but devastating natural events is intrinsically challenging. For tsunami analyses, a suite of geophysical assessments should be in principle evaluated because of the different causes generating tsunamis (earthquakes, landslides, volcanic activity, meteorological events, and asteroid impacts) with varying mean recurrence rates. Probabilistic Tsunami Hazard Analyses (PTHAs) are conducted in different areas of the world at global, regional, and local scales with the aim of understanding tsunami hazard to inform tsunami risk reduction activities. PTHAs enhance knowledge of the potential tsunamigenic threat by estimating the probability of exceeding specific levels of tsunami intensity metrics (e.g., run-up or maximum inundation heights) within a certain period of time (exposure time) at given locations (target sites); these estimates can be summarized in hazard maps or hazard curves. This discussion presents a broad overview of PTHA, including (i) sources and mechanisms of tsunami generation, emphasizing the variety and complexity of the tsunami sources and their generation mechanisms, (ii) developments in modeling the propagation and impact of tsunami waves, and (iii) statistical procedures for tsunami hazard estimates that include the associated epistemic and aleatoric uncertainties. Key elements in understanding the potential tsunami hazard are discussed, in light of the rapid development of PTHA methods during the last decade and the globally distributed applications, including the importance of considering multiple sources, their relative intensities, probabilities of occurrence, and uncertainties in an integrated and consistent probabilistic framework.

Reviews of Geophysics↗

Acidification of Earth: An assessment across mechanisms and scales

In this review article, anthropogenic activities that cause acidification of Earth’s air, waters, and soils are examined. Although there are many mechanisms of acidification, the focus is on the major ones, including emissions from combustion of fossil fuels and smelting of ores, mining of coal and metal ores, and application of nitrogen fertilizer to soils, by elucidating the underlying biogeochemical reactions as well as assessing the magnitude of the effects. These widespread activities have resulted in (1) increased CO 2 concentration in the atmosphere that acidifies the oceans; (2) acidic atmospheric deposition that acidifies soils and bodies of freshwater; (3) acid mine drainage that acidifies bodies of freshwater and groundwaters; and (4) nitrification that acidifies soils. Although natural geochemical reactions of mineral weathering and ion exchange work to buffer acidification, the slow reaction rates or the limited abundance of reactant phases are overwhelmed by the onslaught of anthropogenic acid loading. Relatively recent modifications of resource extraction and usage in some regions of the world have begun to ameliorate local acidification, but expanding use of resources in other regions is causing environmental acidification in previously unnoticed places. World maps of coal consumption, Cu mining and smelting, and N fertilizer application are presented to demonstrate the complex spatial heterogeneity of resource consumption as well as the overlap in acidifying potential derived from distinctly different phenomena. Projected population increase by country over the next four decades indicates areas with the highest potential for acidification, so enabling anticipation and planning to offset or mitigate the deleterious environmental effects associated with these global shifts in the consumption of energy, mineral, and food resources.

Applied Geochemistry↗

Statistical methods in water resources

Preface This book began as class notes for a course we teach on applied statistical methods to hydrologists of the Water Resources Division, U. S. Geological Survey (USGS). It reflects our attempts to teach statistical methods which are appropriate for analysis of water resources data. As interest in this course has grown outside of the USGS, incentive grew to develop the material into a textbook. The topics covered are those we feel are of greatest usefulness to the practicing water resources scientist. Yet all topics can be directly applied to many other types of environmental data. This book is not a stand-alone text on statistics, or a text on statistical hydrology. For example, in addition to this material we use a textbook on introductory statistics in the USGS training course. As a consequence, discussions of topics such as probability theory required in a general statistics textbook will not be found here. Derivations of most equations are not presented. Important tables included in all general statistics texts, such as quantiles of the normal distribution, are not found here. Neither are details of how statistical distributions should be fitted to flood data -- these are adequately covered in numerous books on statistical hydrology. We have instead chosen to emphasize topics not always found in introductory statistics textbooks, and often not adequately covered in statistical textbooks for scientists and engineers. Tables included here, for example, are those found more often in books on nonparametric statistics than in books likely to have been used in college courses for engineers. This book points the environmental and water resources scientist to robust and nonparametric statistics, and to exploratory data analysis. We believe that the characteristics of environmental (and perhaps most other 'real') data drive analysis methods towards use of robust and nonparametric methods. Exercises are included at the end of chapters. In our course, students compute each type of analysis (t-test, regression, etc.) the first time by hand. We choose the smaller, simpler examples for hand computation. In this way the mechanics of the process are fully understood, and computer software is seen as less mysterious. We wish to acknowledge and thank several other scientists at the U. S. Geological Survey for contributing ideas to this book. In particular, we thank those who have served as the other instructors at the USGS training course. Ed Gilroy has critiqued and improved much of the material found in this book. Tim Cohn has contributed in several areas, particularly to the sections on bias correction in regression, and methods for data below the reporting limit. Richard Alexander has added to the trend analysis chapter, and Charles Crawford has contributed ideas for regression and ANOVA. Their work has undoubtedly made its way into this book without adequate recognition. Professor Ken Potter (University of Wisconsin) and Dr. Gary Tasker (USGS) reviewed the manuscript, spending long hours with no reward except the knowledge that they have improved the work of others. For that we are very grateful. We also thank Madeline Sabin, who carefully typed original drafts of the class notes on which the book is based. As always, the responsibility for all errors and slanted thinking are ours alone.

Techniques of Water-Resources Investigations↗

Segmentation and supercycles: A catalog of earthquake rupture patterns from the Sumatran Sunda Megathrust and other well-studied faults worldwide

After more than 100 years of earthquake research, earthquake forecasting, which relies on knowledge of past fault rupture patterns, has become the foundation for societal defense against seismic natural disasters. A concept that has come into focus more recently is that rupture segmentation and cyclicity can be complex, and that a characteristic earthquake model is too simple to adequately describe much of fault behavior. Nevertheless, recognizable patterns in earthquake recurrence emerge from long, high resolution, spatially distributed chronologies. Researchers now seek to discover the maximum, minimum, and typical rupture areas; the distribution, variability, and spatial applicability of recurrence intervals; and patterns of earthquake clustering in space and time. The term “supercycle” has been used to describe repeating longer periods of elastic strain accumulation and release that involve multiple fault ruptures. However, this term has become very broadly applied, lumping together several distinct phenomena that likely have disparate underlying causes. We divide earthquake cycle behavior into four major classes that have different implications for seismic hazard and fault mechanics: 1) quasi-periodic similar ruptures, 2) clustered similar ruptures, 3) clustered complementary ruptures/rupture cascades, and 4) superimposed cycles. “Segmentation” is likewise an ambiguous term; we identify “master segments” and “asperities” as defined by barriers to fault rupture. These barriers may be persistent (rarely or never traversed), frequent (occasionally traversed), or ephemeral (changing location from cycle to cycle). We compile a catalog of the historical and paleoseismic evidence that currently exists for each of these types of behavior on major well-studied faults worldwide. Due to the unique level of paleoseismic and paleogeodetic detail provided by the coral microatoll technique, the Sumatran Sunda megathrust provides one of the most complete records over multiple earthquake rupture cycles. Long historical records of earthquakes along the South American and Japanese subduction zones are also vital contributors to our catalog, along with additional data compiled from subduction zones in Cascadia, Alaska, and Middle America, as well as the North Anatolian and Dead Sea strike-slip faults in the Middle East. We find that persistent and frequent barriers, rupture cascades, superimposed cycles, and quasi-periodic similar ruptures are common features of most major faults. Clustered similar ruptures do not appear to be common, but broad overlap zones between neighboring segments do occur. Barrier regions accommodate slip through reduced interseismic coupling, slow slip events, and/or smaller more localized ruptures, and are frequently associated with structural features such as subducting seafloor relief or fault trace discontinuities. This catalog of observations provides a basis for exploring and modeling root causes of rupture segmentation and cycle behavior. We expect that researchers will recognize similar behavior styles on other major faults around the world.

Quaternary Science Reviews↗

The fate of cyanide in leach wastes at gold mines: an environmental perspective

This paper reviews the basic chemistry of cyanide, methods by which cyanide can be analyzed, and aspects of cyanide behavior that are most relevant to environmental considerations at mineral processing operations associated with gold mines. The emphasis is on research results reported since 1999 and on data gathered for a series of U.S. Geological Survey studies that began in the late 1990s. Cyanide is added to process solutions as the CN − anion, but ore leaching produces numerous other cyanide-containing and cyanide-related species in addition to the desired cyanocomplex of gold. These can include hydrogen cyanide (HCN); cyanometallic complexes of iron, copper, zinc, nickel, and many other metals; cyanate (CNO − ); and thiocyanate (SCN − ). The fate of these species in solid wastes and residual process solutions that remain once gold recovery activities are terminated and in any water that moves beyond the ore processing facility dictates the degree to which cyanide poses a risk to aquatic organisms and aquatic-dependent organisms in the local environment. Cyanide-containing and cyanide-related species are subject to attenuation mechanisms that lead to dispersal to the atmosphere, chemical transformation to other carbon and nitrogen species, or sequestration as cyanometallic precipitates or adsorbed species on mineral surfaces. Dispersal to the atmosphere and chemical transformation amount to permanent elimination of cyanide, whereas sequestration amounts to storage of cyanide in locations from which it can potentially be remobilized by infiltrating waters if conditions change. From an environmental perspective, the most significant cyanide releases from gold leach operations involve catastrophic spills of process solutions or leakage of effluent to the unsaturated or saturated zones. These release pathways are unfavorable for two important cyanide attenuation mechanisms that tend to occur naturally: dispersal of free cyanide to the atmosphere and sunlight-catalyzed dissociation of strong cyanometallic complexes, which produces free cyanide that can then disperse to the atmosphere. The widest margins of environmental safety will be achieved where mineral processing operations are designed so that time for offgassing, aeration, and sunlight exposure are maximized in the event that cyanide-bearing solutions are released inadvertently.

Applied Geochemistry↗

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids, acidity, alkalinity, Cl - , F - and SO 4 2- found in receiving streams, rivers, and lakes are affected by all of these factors and their interactions. Remediation of mine sites is an engineering concern but to design a remediation plan without understanding the hydrogeochemical processes of contaminant mobilization can lead to ineffective and excessively costly remediation. Furthermore, remediation needs a goal commensurate with natural background conditions rather than water-quality standards that might bear little relation to conditions of a highly mineralized terrain. This paper reviews hydrogeochemical generalizations, primarily from US Geological Survey research, that enhance our understanding of the origin, transport, and fate of contaminants released from mined and mineralized areas. Mobility of potential or actual contaminants from mining and mineral processing activities depends on (1) occurrence : is the mineral source of the contaminant actually present? (2) abundance : is the mineral present in sufficient quantity to make a difference? (3) reactivity : what are the energetics, rates, and mechanisms of sorption and mineral dissolution and precipitation relative to the flow rate of the water? and (4) hydrology : what are the main flow paths for contaminated water? Estimates of relative proportions of minerals dissolved and precipitated can be made with mass-balance calculations if minerals and water compositions along a flow path are known. Combined with discharge, these mass-balance estimates quantify the actual weathering rate of pyrite mineralization in the environment and compare reasonably well with laboratory rates of pyrite oxidation except when large quantities of soluble salts and evaporated mine waters have accumulated underground. Quantitative mineralogy with trace-element compositions can substantially improve the identification of source minerals for specific trace elements through mass balances. Post-dissolution sorption and precipitation (attenuation) reactions depend on the chemical behavior of each element, solution composition and pH, aqueous speciation, temperature, and contact-time with mineral surfaces. For example, little metal attenuation occurs in waters of low pH (<3.5) and metals tend to maintain element ratios indicative of the main mineral or group of minerals from which they dissolved, except Fe, SiO 2 , and redox-sensitive oxyanions (As, Sb, Se, Mo, Cr, V). Once dissolved, metal and metalloid concentrations are strongly affected by redox conditions and pH. Iron is the most reactive because it is rapidly oxidized by bacteria and archaea and Fe(III) hydrolyzes and precipitates at low pH (1&ndash;3) which is related directly to its first hydrolysis constant, pK 1 = 2.2. Several insoluble sulfate minerals precipitate at low pH including anglesite, barite, jarosite, alunite and basaluminite. Aluminum hydrolyzes near pH 5 (pK 1 = 5.0) and provides buffering and removal of Al by mineral precipitation from pH 4&ndash;5.5. Dissolved sulfate behaves conservatively because the amount removed from solution by precipitation is usually too small relative to the high concentrations in the water column and relative to the flow rate of the water.

Applied Geochemistry↗

Effects of biodiversity on ecosystem functioning: a consensus of current knowledge

Humans are altering the composition of biological communities through a variety of activities that increase rates of species invasions and species extinctions, at all scales, from local to global. These changes in components of the Earth's biodiversity cause concern for ethical and aesthetic reasons, but they also have a strong potential to alter ecosystem properties and the goods and services they provide to humanity. Ecological experiments, observations, and theoretical developments show that ecosystem properties depend greatly on biodiversity in terms of the functional characteristics of organisms present in the ecosystem and the distribution and abundance of those organisms over space and time. Species effects act in concert with the effects of climate, resource availability, and disturbance regimes in influencing ecosystem properties. Human activities can modify all of the above factors; here we focus on modification of these biotic controls. The scientific community has come to a broad consensus on many aspects of the relationship between biodiversity and ecosystem functioning, including many points relevant to management of ecosystems. Further progress will require integration of knowledge about biotic and abiotic controls on ecosystem properties, how ecological communities are structured, and the forces driving species extinctions and invasions. To strengthen links to policy and management, we also need to integrate our ecological knowledge with understanding of the social and economic constraints of potential management practices. Understanding this complexity, while taking strong steps to minimize current losses of species, is necessary for responsible management of Earth's ecosystems and the diverse biota they contain. Based on our review of the scientific literature, we are certain of the following conclusions: 1) Species' functional characteristics strongly influence ecosystem properties. Functional characteristics operate in a variety of contexts, including effects of dominant species, keystone species, ecological engineers, and interactions among species (e.g., competition, facilitation, mutualism, disease, and predation). Relative abundance alone is not always a good predictor of the ecosystem-level importance of a species, as even relatively rare species (e.g., a keystone predator) can strongly influence pathways of energy and material flows. 2) Alteration of biota in ecosystems via species invasions and extinctions caused by human activities has altered ecosystem goods and services in many well-documented cases. Many of these changes are difficult, expensive, or impossible to reverse or fix with technological solutions. 3) The effects of species loss or changes in composition, and the mechanisms by which the effects manifest themselves, can differ among ecosystem properties, ecosystem types, and pathways of potential community change. 4) Some ecosystem properties are initially insensitive to species loss because (a) ecosystems may have multiple species that carry out similar functional roles, (b) some species may contribute relatively little to ecosystem properties, or (c) properties may be primarily controlled by abiotic environmental conditions. 5) More species are needed to insure a stable supply of ecosystem goods and services as spatial and temporal variability increases, which typically occurs as longer time periods and larger areas are considered. We have high confidence in the following conclusions: 1) Certain combinations of species are complementary in their patterns of resource use and can increase average rates of productivity and nutrient retention. At the same time, environmental conditions can influence the importance of complementarity in structuring communities. Identification of which and how many species act in a complementary way in complex communities is just beginning. 2) Susceptibility to invasion by exotic species is strongly influenced by species composition and, under similar environmental conditions, generally decreases with increasing species richness. However, several other factors, such as propagule pressure, disturbance regime, and resource availability also strongly influence invasion success and often override effects of species richness in comparisons across different sites or ecosystems. 3) Having a range of species that respond differently to different environmental perturbations can stabilize ecosystem process rates in response to disturbances and variation in abiotic conditions. Using practices that maintain a diversity of organisms of different functional effect and functional response types will help preserve a range of management options. Uncertainties remain and further research is necessary in the following areas: 1) Further resolution of the relationships among taxonomic diversity, functional diversity, and community structure is important for identifying mechanisms of biodiversity effects. 2) Multiple trophic levels are common to ecosystems but have been understudied in biodiversity/ecosystem functioning research. The response of ecosystem properties to varying composition and diversity of consumer organisms is much more complex than responses seen in experiments that vary only the diversity of primary producers. 3) Theoretical work on stability has outpaced experimental work, especially field research. We need long-term experiments to be able to assess temporal stability, as well as experimental perturbations to assess response to and recovery from a variety of disturbances. Design and analysis of such experiments must account for several factors that covary with species diversity. 4) Because biodiversity both responds to and influences ecosystem properties, understanding the feedbacks involved is necessary to integrate results from experimental communities with patterns seen at broader scales. Likely patterns of extinction and invasion need to be linked to different drivers of global change, the forces that structure communities, and controls on ecosystem properties for the development of effective management and conservation strategies. 5) This paper focuses primarily on terrestrial systems, with some coverage of freshwater systems, because that is where most empirical and theoretical study has focused. While the fundamental principles described here should apply to marine systems, further study of that realm is necessary. Despite some uncertainties about the mechanisms and circumstances under which diversity influences ecosystem properties, incorporating diversity effects into policy and management is essential, especially in making decisions involving large temporal and spatial scales. Sacrificing those aspects of ecosystems that are difficult or impossible to reconstruct, such as diversity, simply because we are not yet certain about the extent and mechanisms by which they affect ecosystem properties, will restrict future management options even further. It is incumbent upon ecologists to communicate this need, and the values that can derive from such a perspective, to those charged with economic and policy decision-making.

Ecological Monographs↗

Managed aquifer recharge in snow-fed river basins: What, why and how?

What does climate change mean for snow-fed river basins? Climate change poses unique challenges in snow-fed river basins across the western United States because the majority of water supply originates as snow (Dettinger, Udall, & Georgakakos, 2015). In the Sierra Nevada, recent observations include changes in snow accumulation and snowmelt, and shifts in peak streamflow timing (Barnhart et al., 2016; Hatchett et al., 2017; Kim & Jain, 2010; McCabe, Wolock, & Valentin, 2018; Mote, Li, Lettenmaier, Xiao, & Engel, 2018). Such changes upstream alter surface water deliveries downstream, as well as groundwater recharge utilized as both primary and supplemental water supply (Godsey et al., 2014; Harpold, 2016; Jasechko et al., 2014). basin where snowmelt runoff produces substantial water supply to meet diverse agricultural, environmental and urban water demand (Figure 1). The East and West Forks join at the confluence of the Carson River near the north end of the Carson Valley, a rich agricultural region (40,000 acres) that grows primarily alfalfa hay. The majority of irrigators rely on surface water delivered through a network of earthen ditches constructed in the mid-19th and early 20th centuries. Flow through these earthen networks and the practice of flood irrigation contribute significantly to groundwater recharge. Because no upstream surface water reservoirs exist, snowpack that accumulates through winter and melts slowly through spring has acted as a “natural” reservoir, providing ample supply through the summer irrigati agricultural, environmental and urban water demand (Figure 1). The East and West Forks join at the confluence of the Carson River near the north end of the season. Some irrigators have permitted access to supplemental groundwater that is useful during periods of drought for augmenting shortfalls in surface water delivery. Groundwater is the primary source of municipal and industrial water supply for surrounding communities (e.g., Carson City, Minden, Gardnerville, Dayton). Across the basin, water use is highly regulated through federal, tribal, state and local water-sharing agreements based on prior appropriation doctrine (Wilds, 2014). Carson River surface water allocations follow the Alpine Decree, initiated by the United States Department of Interior in 1925 and signed into law in 1980, following 55 years of litigation, to adjudicate surface water rights to individual parties (NDWP, 1999). The Alpine Decree acknowledges return flows to lower river segments, and thus each river segment is distributed autonomously. This means that the most junior water right on an upper segment can be fulfilled before considering the most senior water right on a lower segment. Ultimately, the ruling is at the discretion of the Federal Water Master to satisfy the needs of each water right Downstream of Carson Valley, surface water flows are stored in Lahontan Reservoir, the nation’s first desert reclamation project (est. 1906), where releases are managed to meet the Newland’s Project irrigation water demand and for environmental use on the Stillwater National Wildlife Refuge. Flows from the Carson River are supplemented through diversions from the Truckee River via the Truckee Canal, resulting in a trans-basin water supply system. How is the Water for the Seasons research program informing snow-fed river basin communities? In the Truckee-Carson River System, researchers and local water managers are working together to assess climate change impacts to water supply and explore how model simulations can produce useful information to support local climate adaptation. Twelve key water managers represent agricultural, environmental, urban and regulatory water-use communities, and bring to the table diverse input and perspectives on how to adapt to climate change. Hydrologists use this input to craft scenarios and simulations that meet the information needs of local water managers. Biannual workshops provide an opportunity for information exchange, where researchers and key water managers generate new knowledge of river system function. That is, researchers share results of models that examine the physical potential, and managers validate the on-the-ground potential, further informing the research process. Coincident to this research program, the region faced a prolonged drought period (2012-2016) with historically low snowpack, followed by a historic wet year (2017) that brought winter and spring flooding as a result of atmospheric river storm events (Sterle et al., 2019). For the Carson River, an important observation made by managers was that peak streamflow that had traditionally coincided with peak irrigation demands, had shifted to earlier in the spring, with summer baseflow also decreasing (Sterle & Singletary, 2017). Managers shared with researchers concerns over potential future impacts that changing snowpack will have on surface water deliveries and reliance on groundwater, as the region’s population and economy continue to grow. During workshops that occurred over this period, local water managers and researchers discussed ways to evaluate water distribution and use that honors the existing legal framework and accounts for changing snowpack regimes (amount, rain versus snow, timing). In response to managers growing interest, researchers introduced the concept of managed aquifer recharge as one potential strategy to adapt and enhance regional water sustainability. What is managed aquifer recharge? Simply stated, managed aquifer recharge is the intentional recharge of structures to spread water over agricultural lands, allowing water to naturally infiltrate into the groundwater system (Bouwer, 1999; Niswonger et al., 2017). The latter may occur during the irrigation season by applying excess water, or during the nonirrigation season when evapotranspiration losses are low. Figure 2 illustrates managed aquifer recharge in a snow-fed river basin, where streamflow generated from snowmelt runoff is diverted to agricultural lands to recharge the aquifer. Such flood irrigation practices, including water delivery through earthen ditch networks, provide incidental but significant aquifer recharge through seepage and deep drainage beneath fields (Niswonger, Allander, & Jeton, 2014). The effects of managed aquifer recharge can vary depending on the location and intensity of practice. For example, implementing managed aquifer recharge water into the groundwater system (Dillon, 2009). This differs from the incidental recharge that may occur as part of normal irrigation practices. Managed recharge may occur by injection into the aquifer through existingwells, or by using existing conveyance adjacent to/along the river’s floodplain has the potential to enhance late-season instream flows due to increased return flows, resulting in greater downstream deliveries as well as improving ecological conditions (Niswonger et al., 2017). Implementing managed aquifer recharge away from the river’s floodplain has the potential to enhance groundwater supply which is increasingly relied upon during surface water shortage (Green et al., 2011), by storing water in available aquifer space in the deep aquifer. At the basin scale, managed aquifer recharge may lead to regional groundwater sustainability. Is the Carson River Basin a candidate for managed aquifer recharge? The physical limitations to implementing managed aquifer recharge in the Carson River Basin hinges on three key factors. The first factor relates to the physical connectivity between rivers and streams, and the irrigation delivery network of canals and ditches that divert water to agricultural lands (Niswonger et al., 2017). In the Carson River Basin the mechanisms for getting water to fields is already in place. Thus, intentionally routing high flows that occur in wet years through this system during the nonirrigation season would mimic what occurs naturally during the irrigation season. The second factor relates to the occurrence of atmospheric river storm events that deliver large amounts of precipitation to the region, much greater than average (Dettinger et al., 2015). With increased frequency and intensity projected under a warmer climate, such events have the potential to produce excess water over short periods of time that could be stored through mechanisms such as managed aquifer recharge (Niswonger et al., 2017). The third factor relates to the change in snowpack accumulation and shifts in snowmelt timing observed elsewhere in the Sierra Nevada (e.g., Godsey et al., 2014; Mote et al., 2018). Having a mechanism in place to maximize use of earlier snowmelt and shifts in streamflow timing could be advantageous and enhance regional groundwater sustainability. As part of the Water for the Seasons study, a hypothetical scenario was developed to determine the feasibility of managed aquifer recharge in the Carson River Basin, assuming no legal constraints. During “wet” or above-average water years, irrigators in the Upper Carson Valley would divert high flows and spread water over agricultural lands during the nonirrigation season. Assuming flows are abundant and “early,” diversions would begin prior to the growing season, when water would otherwise flow downstream to the Lahontan Reservoir. During “dry” years or drought periods, when surface water availability is less, irrigators in the Upper Carson Valley could augment surface water shortages with groundwater, allowing available surface water flows to flow downstream. Researchers hypothesize the amount of water has the potential to boost baseflow to support environmental instream flows, for example. What concerns have local water managers expressed? The hypothetical managed aquifer recharge scenario was presented to water managers in a workshop setting. Presentations included an overview of the hydrologic and operations modeling tools used to evaluate managed aquifer recharge by simulating the timing and distribution of water in the upper watershed. Specifically, in the Upper Carson Valley, a hydrologic model (GSFLOW) simulates streamflow driven by snowmelt, and surface and groundwater interactions, while a river basin operations model (MODSIM) allocates water according to the prior appropriation doctrine in the basin (see Figure 1) (Morway, Niswonger, & Triana, 2016; Niswonger et al., 2017). Integrating these two modeling tools advances the evaluation of climate impacts on water availability in agricultural communities and the resulting impacts of alternative management strategies (Morway et al., 2016). When asked about the viability of managed aquifer recharge, the perspectives of 11 managers varied (Figure 3). Regardless of rating, all managers questioned, “How would thisreally work?” Several managers questioned whether models could simulate the connectivity between surface and groundwater to accurately quantify changes to instream flow. Others raised concerns that managed aquifer recharge violates the Alpine Decree and Nevada Water Law. Still others requested researchers consider alternatives that could work within the confines of current (2019) water law. Managers posed specific questions that should be considered when evaluating the potential for managed aquifer recharge. For example: What triggers implementation of managed aquifer recharge?How “high” or “low” must annual flows be to initiate managed aquifer recharge? When in the water year is this determined? Where exactly in the Carson Valley is managed aquiferre charge possible? For example, what areas away from the floodplain could ensure long-term storage? Can model simulations quantify potential benefits and consequences system-wide?Would this information support decision-making, such as permitting of additional supplemental groundwater rights? How are researchers going to address managers’ research questions? Managers’ perspectives help to validate the on-the-ground potential of particular strategies and further refine alternative management scenarios. For example, understanding that managers are concerned with oversaturated fields helps researchers to define conditions in the model, such as what defines a wet versus “too” wet type of year and where to focus irrigation for managed aquifer recharge. Incorporating these nuances provides more accurate quantification of the potential benefits and consequences for users across the basin. Modeling is underway to simulate managed aquifer recharge scenarios and explore basin-wide implications. Researchers and local water managers will convene to collaboratively review results and further assess whether this or other strategies could work under the confines of existing water law. Subsequent fact sheets will present these findings.

Nevada↗