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A decision support system for prioritizing forested wetland restoration in the Yazoo Backwater Area, Mississippi

A working prototype decision support system (DSS) was developed for the Yazoo Backwater Area, Mississippi, to help planners and managers prioritize, plan, conduct, and optimize forested wetland restoration activities. The DSS comprises geographic information system (GIS) spatial data themes, application programs that provide a cumulative analysis of the relative ability of sites to function as wetlands, and output data that are specific to a given restoration analysis scenario. The DSS input includes GIS data themes such as geomorphology, soils, land use, elevation, farmed wetlands, flood frequency, topographic depressions, streams, public lands, roads, and permanent water bodies, which can be used as spatial templates to define areal hydrologic settings. These GIS data themes can then be ranked and combined to estimate the relative suitability of a potential wetland restoration site, thereby, determining relative wetland equivalence on the landscape. The GIS applications used in this DSS perform the following three functions: assess the ecology (the Eco-Assessor); reclassify land-use in areas selected for restoration (the Tree-Translator); and generate output data to compare restoration scenarios (the Parameter-Generator). Areas selected for reforestation are translated (in the GIS) into ?forested? land use, and the tree species that are ?planted? on the landscape (in the DSS) either compose an ecologically optimal or an economically optimal community of tree species. Output from the DSS can be compared and analyzed by using economic, statistical, graphical, and tabular methods. Output data for seven selected scenarios were generated for the Yazoo Backwater Area and are presented as examples to illustrate the flexibility of the DSS to identify areas that meet restoration objectives.

Water-Resources Investigations Report↗

Water resources of Monroe County, New York, water years 1994-96, with emphasis on water quality in the Irondequoit Creek basin: Atmospheric deposition, ground water, streamflow, trends in water quality, and chemical loads to Irondequoit Bay

Irondequoit Creek drains 169 square miles in the eastern part of Monroe County. Nutrients transported by Irondequoit Creek to Irondequoit Bay on Lake Ontario have contributed to the eutrophication of the Bay. Sewage-treatment-plant effluent, a major source of nutrients to the creek and its tributaries, was eliminated from the basin in 1979 by diversion to a regional wastewater-treatment facility, but sediment and contaminants from nonpoint sources continue to enter the creek and Irondequoit Bay. This report analyzes data from five surface-water monitoring sites in the Irondequoit Creek basin. Irondequoit Creek at Railroad Mills, East Branch Allen Creek at Pittsford, Allen Creek near Rochester, Irondequoit Creek at Blossom Road, and Irondequoit Creek at Empire Boulevard. It is the third in a series of reports that present interpretive analyses of the hydrologic data collected in Monroe County since 1984. Also included are data from a site on Northrup Creek, which drains a 23.5-square-mile basin west of the Genesee River in western Monroe County, to provide information on surface-water quality in a stream west of the Genesee River and on loads of nutrients delivered to Long Pond, a small eutrophic embayment of Lake Ontario, and data from the Genesee River for comparison of historical water-quality conditions with 1994-96 conditions. Water-level and water-quality data from nine observation wells in Ellison Park, and atmospheric-deposition data from Mendon Ponds, also are included. Average annual yields of chemical constituents from atmospheric deposition for 1994-96 were generally similar to those for the previous 10 years (1984-93), except for dissolved sodium, dissolved potassium, total phosphorus, and orthophosphate, which ranged from 42 percent (dissolved sodium) to 275 percent (dissolved potassium) greater than during 1984-93, and dissolved sulfate and ammonia, which were about 30 percent less than in 1984-93. Loads of all nutrients deposited in the Irondequoit Creek basin from atmospheric sources during water years 1994-96 exceeded those removed by Irondequoit Creek at Blossom Road—ammonia by 5,600 percent, orthophosphate by 2,500 percent, ammonia + organic nitrogen by 350 percent, total phosphorus by 300 percent and nitrite + nitrate by 140 percent. Average yields of dissolved chloride and dissolved sulfate from atmospheric deposition were much less than those transported in streamflow—yields of dissolved chloride from atmospheric sources were only 1.9 percent, and yields of sulfate were only 9.2 percent, of those transported in streamflow at Blossom Road. Concentrations of several chemical constituents in streams of the Irondequoit Creek basin showed statistically significant trends from the beginning of their period of record through 1996. The constituents that showed the greatest number of statistically significant trends were dissolved chloride, ammonia, and ammonia + organic nitrogen. Dissolved chloride showed an upward trend at Blossom Road, Allen Creek, and Empire Boulevard and a downward trend at Railroad Mills. Ammonia showed downward trends at Allen Creek, Blossom Road and Railroad Mills. Ammonia + organic nitrogen showed a downward trend at Allen Creek, Blossom Road, and Empire Boulevard. Nitrite + nitrate showed a downward trend at Allen Creek, and orthophosphate showed an upward trend at that site. Turbidity and total suspended solids showed a downward trend at Empire Boulevard. Neither total phosphorus nor volatile suspended solids showed statistically significant trends in concentration at any of the Irondequoit basin sites. Northrup Creek showed a downward trend in total suspended solids and ammonia + organic nitrogen, and an upward trend in dissolved chloride. The Genesee River showed a downward trend in ammonia + organic nitrogen and chloride, and an upward trend in orthophosphate. Most constituents for the 1994-96 water years showed lower average yields at Blossom Road than for the 1989-93 water years, but dissolved chloride showed higher yields for the 1994-96 water years at all sites except Blossom Road. Ammonia + organic nitrogen and total phosphorus showed a decrease in yield at all sites after 1993, and nitrite + nitrate showed slightly higher yields for 1994-96 at the upstream, predominantly rural sites, and lower yields at the downstream, more urban sites, than during 1989-93. The trends and changes in surface-water quality after 1993 can be attributed to several factors within the basin, including land-use changes, annual and seasonal variations in streamflow, and year-to-year variations in the application of deicing salts on area roads. Statistical analyses of long-term (9 years or more) streamflow records of three unregulated streams in Monroe County indicate that annual mean flows for water years 1994-96 were in the normal range (75th to 25th percentile), although Allen Creek showed a statistically significant downward trend in monthly mean streamflow over the 1984-96 water years.

New York↗

Pesticides in surface water measured at select sites in the Sacramento River basin, California, 1996-1998

Pesticides were measured in one urban stream, one agricultural stream, one site on the Sacramento River, and one large flood control channel over a period of 18 months during 1996-1998. All sites were located within the Sacramento River Basin of California. Measurements were made on 83 pesticides or pesticide transformation products by either gas chromatography/mass spectrometry or by high performance liquid chromatography with ultraviolet light spectrometry. Some pesticides were detected frequently at the agricultural stream and downstream in the Sacramento River and at the flood control channel of the Sacramento River. These were pesticides related to rice farming (molinate, carbofuran, thiobencarb, and bentazon); herbicides used both agriculturally or for roadside maintenance (diuron, simazine, and metolachlor); or insecticides used on orchards and row corps (diazinon and chlorpyrifos). No pesticide concen-trations above enforceable water quality criteria were measured at either the agricultural site or the Sacramento River sites. In contrast to the agricul-tural site, insecticides used for household, lawn, or garden maintenance were the most frequently detected pesticides at the urban site. Diazinon, an organophosphate insecticide, exceeded recom-mended criteria for the protection of aquatic life, and the diazinon levels were frequently above known toxic levels for certain zooplankton species at the urban site. Because of the low discharge of the urban stream, pesticide concentrations were greatly diluted upon mixing with Sacramento River water.

California↗

Simulation of the interaction of karstic lakes Magnolia and Brooklyn with the upper Floridan Aquifer, southwestern Clay County, Florida

The stage of Lake Brooklyn, in southwestern Clay County, Florida, has varied over a range of 27 feet since measurements by the U.S. Geological Survey began in July 1957. The large stage changes have been attributed to the relation between highly transient surface-water inflow to the lake and subsurface conduits of karstic origin that permit a high rate of leakage from the lake to the Upper Floridan aquifer. After the most recent and severe stage decline (1990-1994), the U.S. Geological Survey began a study that entailed the use of numerical ground-water flow models to simulate the interaction of the lake with the Upper Floridan aquifer and the large fluctuations of stage that were a part of that process. A package (set of computer programs) designed to represent lake/aquifer interaction in the U.S. Geological Survey Modular Finite-Difference Ground-Water Flow Model (MODFLOW-96) and the Three-Dimensional Method-of-Characteristics Solute-Transport Model (MOC3D) simulators was prepared as part of this study, and a demonstration of its capability was a primary objective of the study. (Although the official names are Brooklyn Lake and Magnolia Lake (Florida Geographic Names), in this report the local names, Lake Brooklyn and Lake Magnolia, are used.) In the simulator of lake/aquifer interaction used in this investigation, the stage of each lake in a simulation is updated in successive time steps by a budget process that takes into account ground-water seepage, precipitation upon and evaporation from the lake surface, stream inflows and outflows, overland runoff inflows, and augmentation or depletion by artificial means. The simulator was given the capability to simulate both the division of a lake into separate pools as lake stage falls and the coalescence of several pools into a single lake as the stage rises. This representational capability was required to simulate Lake Brooklyn, which can divide into as many as 10 separate pools at sufficiently low stage. In the first of two calibrated models, recharge to the water table, specified as a monthly rate, was set equal to 40 percent of the monthly rainfall rate. The specified rate of inflow to the uppermost stream segment was set equal to outflows from Lake Lowry estimated from lake stage and the 1994-97 rating table. Leakage to the intermediate and Upper Floridan aquifers was assumed to occur from the surficial aquifer system through the confining layers directly beneath deeper parts of the lake bottom. A leakance coefficient value of 0.001 feet per day per foot of thickness was used beneath Lake Magnolia, and a value of 0.005 feet per day per foot of thickness was used beneath most of Lake Brooklyn. With these values, the conductance through the confining layers beneath Lake Brooklyn was about 19 times that beneath Lake Magnolia. The simulated stages of Lake Brooklyn matched the measured stages reasonably well in the early (1957-72) and later (1990-98) parts of the simulation time period, but the match was unsatisfactory in an intermediate time period (1973-89). To resolve this discrepancy, the hypothesis was proposed that undocumented losses of water from Alligator Creek upstream from Lake Brooklyn or from the lake itself occurred between 1973 and 1989 when there was sufficient streamflow. The resulting simulation of lake stages matched the measured lake stages accurately during the entire simulation time period. The model was then revised to incorporate the assumption that only 20 percent of precipitation recharged the water table (the second calibrated model). Recalibration of the model required that leakance values for the confining units under deeper parts of the lakes also be reduced by nearly 50 percent. The stages simulated with the new parameter assumptions, but retaining the assumption of surface-water losses, were an excellent match of the measured values. The stage of Lake Magnolia was also simulated accurately. The results of sensitivity analyses show that simulated streamflow between Lakes Magnolia and Brooklyn tends to be water-budget controlled, and is not appreciably affected by the specified outflow altitude or channel characteristics of the receiving stream. To match heads measured in observation wells of the surficial aquifer network, the assigned hydraulic conductivity values were zoned, and ranged from a minimum of 4 feet per day to a maximum of 400 feet per day in the first calibrated model. These values were reduced by about 50 percent in the second calibrated model. Differences between observation wells were noted in the abruptness of changes of measured head values, and in the relation of the timing of peak measured heads and simulated peak heads. These differences seemed to be correlated with the depth of the water table below land surface. Spatially uniform values of transmissivity were specified for the intermediate (10,000 feet squared per day) and Upper Floridan (100,000 feet squared per day) aquifers. Simulated heads in the Upper Floridan aquifer layer follow the trend of the heads measured in a long-term observation well with data beginning in 1960. This result suggests that the observed head decline could be explained entirely in terms of the stage decline in Lake Brooklyn and may not indicate a regional trend.

Florida↗

Preliminary effects of streambank fencing of pasture land on the quality of surface water in a small watershed in Lancaster County, Pennsylvania

The use of fencing to exclude pastured animals from streams has been recognized as an agricultural best-management practice. Streambank fencing was installed in a small basin within the Mill Creek Watershed of Lancaster County, Pa., during summer 1997 to evaluate the effectiveness of fencing on surface-water quality. A preliminary review of data collected during a pre-treatment, or calibration period (October 1993 through June 1997), and part of the post-treatment period (July 1997 through November 1998) has identified a varied instream nutrient response to streambank fencing. Concentrations of total nitrogen (N) during low-flow periods were significantly reduced by 20 to 31 percent at treated relative to untreated sites, but the yield of total N during low-flow conditions did not change significantly. Low-flow concentrations and yields of total phosphorus (P) did not change significantly at the outlet of the treatment basin, but data from a tributary site (T-2) in the treatment basin showed a 19- to 79-percent increase in the concentration and yield of total P relative to those at untreated sites. The total-P increase was due to increased concentrations of dissolved P. The processes causing the decrease in the concentration of total N and an increase in the concentration of total P were related to stream discharge, which declined after fencing to about one-third lower than the period-of-record mean. Declines in stream discharge after fence installation were caused by lower than normal precipitation. As concentrations of dissolved oxygen decreased in the stream channel as flows decreased, there was increased potential for instream denitrification and solubilization of P from sediments in the stream channel. Vegetative uptake of nitrate could also have contributed to decreased N concentrations. There were few significant changes in concentrations and yields of nutrients during stormflow except for significant reductions of 16 percent for total-N concentrations and 26 percent for total-P concentrations at site T-2 relative to the site at the outlet of the control basin. Suspended-sediment concentrations in the stream were significantly reduced by fencing. These reductions were partially caused by reduced cow access to the stream and hence reduced potential for the cows to destabilize streambanks through trampling. Development of a vegetative buffer along the stream channel after fence installation also helped to retain soil eroding from upgradient land. Reductions in suspended sediment during low flow ranged from 17 to 26 percent; stormflow reductions in suspended sediment ranged from 21 to 54 percent at treated relative to untreated sites. Suspended-sediment yields, however, were significantly reduced only at site T-2, where low-flow and stormflow yields were reduced by about 25 and 10 percent, respectively, relative to untreated sites. Benthic-macroinvertebrate sampling has identified increased number of taxa in the treatment basin after fence installation. Relative to the control basin, there was about a 30-percent increase in the total number of taxa. This increase was most likely related to improved instream habitat as a result of channel revegetation.

Water-Resources Investigations Report↗

Potentiometric surfaces of aquifers in the Cockfield Formation in southeastern Arkansas and the Wilcox Group in southern and northeastern Arkansas, 2000

The Cockfield and lower Wilcox aquifers are sources of water for local use in southern and northeastern Arkansas, where in 1995 more than 51 million gallons per day of water was withdrawn. During January through April 2000, 54 water-level measurements were made in wells completed in the Cockfield aquifer, 13 water-level measurements were made in wells completed in the lower Wilcox aquifer in southern Arkansas, and 43 water-level measurements were made in wells completed in the lower Wilcox aquifer in northeastern Arkansas. The potentiometric surface data reveal spatial trends in both aquifers across the study areas. The regional direction of ground-water flow of the Cockfield aquifer is generally toward the east and south, away from the outcrop area, except in areas of intense ground-water withdrawals. The configuration of the potentiometric surface indicates that heavy pumpage has probably altered or reversed the natural direction of flow in these areas. A potentiometric low caused by the pumpage near Greenville, Mississippi, extends into Chicot, Desha, and Drew Counties. Water levels in five wells showed average declines between 0.5 and 0.8 foot per year. The regional direction of ground-water flow in the lower Wilcox aquifers is generally east and south, away from the outcrop, except in areas of intense ground-water withdrawals. Potentiometric depressions, where flow is toward centers of pumping, indicate that heavy pumpage has probably altered or reversed the natural direction of flow. Two potentiometric depressions are centered in the vicinity of Paragould and West Memphis, Arkansas, where ground-water withdrawals probably have altered the natural direction of flow. Long-term hydrographs of seven wells show water-level declines in the lower Wilcox aquifer in northeastern Arkansas. The average water-level decline in two wells was between 0.8 and 1.0 foot per year and in five wells was between 1.2 and 1.8 foot per year.

Arkansas↗

Hydrothermal activity and carbon-dioxide discharge at Shrub and upper Klawasi mud volcanoes, Wrangell Mountains, Alaska

Shrub mud volcano, one of three mud volcanoes of the Klawasi group in the Copper River Basin, Alaska, has been discharging warm mud and water and CO2?rich gas since 1996. A field visit to Shrub in June 1999 found the general level of hot-spring discharge to be similar, but somewhat more widespread, than in the previous two years. Evidence of recent animal and vegetation deaths from CO2 exposure were confined to localized areas around various gas and fluid vents. Maximum fluid temperatures in each of three main discharge areas, ranging from 48-54?C, were equal to or higher than those measured in the two previous years; such temperatures are significantly higher than those observed intermittently over the past 30 years. At Upper Klawasi mud volcano, measured temperatures of 23-26?C and estimated rates of gas and water discharge in the summit crater lake were also similar to those observed in the previous two years. Gas discharging at Shrub and Upper Klawasi is composed of over 98% CO2 and minor amounts of meteoric gases (N2, O2, Ar) and gases partly of deeper origin (CH4 and He). The rate of CO2 discharge from spring vents and pools at Shrub is estimated to be ~10 metric tonnes per day. This discharge, together with measured concentrations of bicarbonate, suggest that a total CO2 upflow from depth of 20-40 metric tonnes per day at Shrub.Measurements were made of diffuse degassing rates from soil at one ~300 m2 area near the summit of Shrub that included vegetation kill suggestive of high CO2 concentrations in the root zone. Most of measured gas flow rates in this area were significantly higher than background values, and a CO2 concentration of 26 percent was measured at a depth of 10 cm where the gas flow rate was highest. Although additional measurements of diffuse gas flow were made elsewhere at Shrub, no other areas of vegetation kill related to diffuse degassing and high soil-gas CO2 concentrations could be seen from the air.Chemical and isotopic compositions of the gas and water discharging at Shrub and Upper Klawasi indicate derivation from a combination of mantle (magmatic) and crustal (marine sedimentary rock) sources and suggest a common fluid reservoir at depth. In particular, both the total dissolved carbon and values of 13C in CO2 are similar for fluids and gas sampled at each area, and do not appear to have changed with the onset of increased spring temperatures and fluid discharge at Shrub. This suggests that the underlying cause of the recent changes in discharge rate and temperature at Shrub is not an increase in the rate of input of magmatic heat and volatiles, but rather increases in the permeability of the upflow conduits that connect the gas-rich reservoir to the surface.

Water-Resources Investigations Report↗

Reconnaissance of the hydrology, water quality, and sources of bacterial and nutrient contamination in the Ozark Plateaus aquifer system and Cave Springs Branch of Honey Creek, Delaware County, Oklahoma, March 1999-March 2000

A reconnaissance investigation of hydrology and water quality was conducted to evaluate possible sources of bacteria and nutrient contamination in the Cave Springs Branch basin and the underlying karstic Ozark Plateau aquifer system. Objectives were to: (1) determine the directions of ground-water flow in the basin and determine whether Cave Springs Branch interacts with ground water, (2) compare water quality in Cave Springs Branch with water quality in nearby wells to determine whether the stream is contaminating nearby wells, and (3) determine sources of fecal coliform bacteria and nitrate contamination in Cave Springs Branch and ground water. Potential sources of bacteria and nitrate in the area include cultivated agriculture, cow and horse on pasture, poultry production, households, and wildlife. Presence of fecal coliform and fecal streptococcal bacteria directly indicate fecal contamination and the potential for the presence of other pathogenic organisms in a water supply. Nitrate in drinking water poses health risks and may indicate the presence of additional contaminants. Fecal coliform bacteria colony counts were least in wells, intermediate in the poultry-processing plant wastewater outfall and Honey Creek above the confluence with Cave Springs Branch, and greatest in Cave Springs Branch. Bacteria strains and resistance to antibiotics by some bacteria indicate that livestock may have been sources of some bacteria in the water samples. Multiple antibiotic resistances were not present in the isolates from the water samples, indicating that the bacteria may not be from human or poultry sources. Ribotyping indicates that Escherichia coli bacteria in water samples from the basin were from bird, cow, horse, dog, deer, and human sources. The presence of multiple ribotypes from each type of animal source except bird indicates that most of the bacteria are from multiple populations of source animals. Identifiable sources of bacteria in Cave Springs Branch at the state line were dominantly cow and horse with one ribotype from bird. Escherichia coli was detected in only one well sample. Bacterial ribotypes in water from that upgradient well indicated human and dog feces as sources for bacteria, and that on site wastewater treatment may not always be adequate in these highly permeable soils. Greater concentrations of nitrate in Cave Springs Branch and O'Brien Spring relative to the poultry-processing plant wastewater outfall may be due, in part, to conversion of ammonia from poultry processing plant wastewater. The poultry-processing plant wastewater outfall sample collected in March 2000 contained greater concentrations of ammonia and total organic nitrogen plus ammonia than the spring, stream, and well samples collected during August 1999. Cave Springs Branch and Honey Creek contributed approximately equal loads of nitrogen to Honey Creek below the confluence and the greatest loads of nitrogen were introduced to Cave Springs Branch by the poultry processing plant wastewater outfall and O'Brien Spring. Nitrate concentrations in upgradient well samples ranged from 0.38 to 4.60 milligrams per liter, indicating that there are sources of ground-water nitrogen other than Cave Springs Branch, such as animal waste, fertilizer, or human waste. Nitrogen compounds in water from wells downgradient of Cave Springs Branch may be from Cave Springs Branch, fertilizers, animal waste, or human waste.

Oklahoma↗

Unconsolidated Aquifers in Tompkins County, New York

Unconsolidated aquifers consisting of saturated sand and gravel are capable of supplying large quantities of good-quality water to wells in Tompkins County, but little published geohydrologic inform ation on such aquifers is available. In 1986, the U.S.Geological Survey (USGS) began collecting geohydrologic information and well data to construct an aquifer map showing the extent of unconsolidated aquifers in Tompkins county. Data sources included (1) water-well drillers. logs; (2) highway and other construction test-boring logs; (3) well data gathered by the Tompkins County Department of Health, (4) test-well logs from geohydrologic consultants that conducted projects for site-specific studies, and (5) well data that had been collected during past investigations by the USGS and entered into the National Water Information System (NWIS) database. In 1999, the USGS, in cooperation with the Tompkins County Department of Planning, compiled these data to construct this map. More than 600 well records were entered into the NWIS database in 1999 to supplement the 350 well records already in the database; this provided a total of 950 well records. The data were digitized and imported into a geographic information system (GIS) coverage so that well locations could be plotted on a map, and well data could be tabulated in a digital data base through ARC/INFO software. Data on the surficial geology were used with geohydrologic data from well records and previous studies to delineate the extent of aquifers on this map. This map depicts (1) the extent of unconsolidated aquifers in Tompkins County, and (2) locations of wells whose records were entered into the USGS NWIS database and made into a GIS digital coverage. The hydrologic information presented here is generalized and is not intended for detailed site evaluations. Precise locations of geohydrologic-unit boundaries, and a description of the hydrologic conditions within the units, would require additional detailed, site-specific information.

Water-Resources Investigations Report↗

Regional evaluation of evapotranspiration in the Everglades

Nine sites in the Florida Everglades were selected and instrumented for collection of data necessary for evapotranspiration-determination using the Bowen-ratio energy-budget method. The sites were selected to represent the sawgrass or cattail marshes, wet prairie, and open-water areas that constitute most of the natural Everglades system. At each site, measurements necessary for evapotranspiration (ET) calculation and modeling were automatically made and stored on-site at 15- or 30-minute intervals. Data collected included air temperature and humidity at two heights, wind speed and direction, incoming solar radiation, net solar radiation, water level and temperature, soil moisture content, soil temperature, soil heat flux, and rainfall. Data summarized in this report were collected from January 1996 through December 1997, and the development of site-specific and regional models of ET for this period is described. Latent heat flux is the energy flux density equivalent of the ET rate. Modified Priestley-Taylor models of latent heat flux as a function of selected independent variables were developed at each site. These models were used to fill in periods of missing latent heat flux measurement, and to develop regional models of the entire Everglades region. The regional models may be used to estimate ET in wet prairie, sawgrass or cattail marsh, and open-water portions of the natural Everglades system. The models are not applicable to forested areas or to the brackish areas adjacent to Florida Bay. Two types of regional models were developed. One type of model uses measurements of available energy at a site, together with incoming solar energy and water depth, to estimate hourly ET. This available-energy model requires site data for net radiation, water heat storage, and soil heat flux, as well as data for incoming solar radiation and water depth. The other type of model requires only incoming solar energy, air temperature, and water depth data to provide estimates of hourly ET. The second model thus uses data that are more readily available than the data required for the available-energy model. Computed ET mean annual totals for all nine sites for the 1996-97 period ranged from 42.4 inches per year at a site where the water level is below land surface for several months each year to 57.4 inches per year at an open-water site with no emergent vegetation. Although the density of photosynthetically-active plant leaves has been shown to relate directly to ET in some studies, it does not appear to relate directly to ET in the Everglades, based on comparison of annual ET data with leaf-area index, defined as the Normalized Difference Vegetation Index (NDVI), data from satellite imagery. NDVI and ET appear to be inversely related in the Everglades. The greatest ET rates occurred at open-water sites where the NDVI data indicated the lowest leaf-area index. Among the remaining vegetated sites, there is no clear relation between ET and NDVI, though the highest ET rate corresponded to the lowest NDVI and one of the lowest ET rates corresponded to the highest NDVI value. The variation in ET follows a seasonal pattern, with lowest monthly ET totals occurring in December through February, and highest ET occurring in May through August. The greatest range in monthly ET among all nine sites for the 2-year period occurred at site 3: from 1.81 inches in December 1997 to 6.84 inches in July 1996. A study to compare the Bowen-ratio/energy balance method of ET measurement with the eddy-correlation method was done at one site from June 22, 1998, through September 28, 1998. This comparison indicated that both methods gave comparable values of the Bowen ratio, but there was a considerable difference in available energy measured by the two methods. The mean of all 30-minute measured turbulent heat fluxes from the eddy-correlation apparatus for June 22 through September 29, 1998, was 137.4 watts per square meter, and the mean of the corresponding measured energy was 163.6 watts per square meter, or about 20 percent greater. The disagreement in mean energy fluxes measured by the two methods is problematical and is not fully understood. Although the difference seems to be related to friction velocity, and is practically non-existent at values of friction velocity greater than 0.3 meter per second, the "correctness" of either method cannot be determined with the data available.

Florida↗

Factors affecting nutrient trends in major rivers of the Chesapeake Bay Watershed

Trends in nutrient loads and flow-adjusted concentrations in the major rivers entering Chesapeake Bay were computed on the basis of water-quality data collected between 1985 and 1998 at 29 monitoring stations in the Susquehanna, Potomac, James, Rappahannock, York, Patuxent, and Choptank River Basins. Two computer models-the Chesapeake Bay Watershed Model (WSM) and the U.S. Geological Survey's 'Spatially Referenced Regressions on Watershed attributes' (SPARROW) Model-were used to help explain the major factors affecting the trends. Results from WSM simulations provided information on temporal changes in contributions from major nutrient sources, and results from SPARROW model simulations provided spatial detail on the distribution of nutrient yields in these basins. Additional data on nutrient sources, basin characteristics, implementation of management practices, and ground-water inputs to surface water were analyzed to help explain the trends. The major factors affecting the trends were changes in nutrient sources and natural variations in streamflow. The dominant source of nitrogen and phosphorus from 1985 to 1998 in six of the seven tributary basins to Chesapeake Bay was determined to be agriculture. Because of the predominance of agricultural inputs, changes in agricultural nutrient sources such as manure and fertilizer, combined with decreases in agricultural acreage and implementation of best management practices (BMPs), had the greatest impact on the trends in flow-adjusted nutrient concentrations. Urban acreage and population, however, were noted to be increasing throughout the Chesapeake Bay Watershed, and as a result, delivered loads of nutrients from urban areas increased during the study period. Overall, agricultural nutrient management, in combination with load decreases from point sources due to facility upgrades and the phosphate detergent ban, led to downward trends in flow-adjusted nutrient concentrations atmany of the monitoring stations in the watershed. The loads of nutrients, however, were not reduced significantly at most of the monitoring stations. This is due primarily to higher streamflow in the latter years of the monitoring period, which led to higher loading in those years. Results of this study indicate a need for more detailed information on BMP effectiveness under a full range of hydrologic conditions and in different areas of the watershed; an internally consistent fertilizer data set; greater consideration of the effects of watershed processes on nutrient transport; a refinement of current modeling efforts; and an expansion of the non-tidal monitoring network in the Chesapeake Bay Watershed.

Delaware, Maryland, New York, Pennsylvania, Virgin↗

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida↗

Water-quality characteristics for selected streams in Lawrence County, South Dakota, 1988-92

During the 1980’s, significant economic development and population growth began to occur in Lawrence County in the northern part of the Black Hills of western South Dakota. Rising gold prices and heap-leach extraction methods allowed the economic recovery of marginal gold ore deposits, resulting in development of several large-scale, open-pit gold mines in Lawrence County. There was increasing local concern regarding potential impacts on the hydrologic system, especially relating to the quantity and quality of water in the numerous streams and springs of Lawrence County. In order to characterize the water quality of selected streams within Lawrence County, samples were collected from 1988 through 1992 at different times of the year and under variable hydrologic conditions. During the time of this study, the Black Hills area was experiencing a drought; thus, most samples were collected during low-flow conditions. Streamflow and water-quality characteristics in Lawrence County are affected by both geologic conditions and precipitation patterns. Most streams that cross outcrops of the Madison Limestone and Minnelusa Formation lose all or large part of their streamflow to aquifer recharge. Streams that are predominantly spring fed have relatively stable streamflow, varying slightly with dry and wet precipitation cycles. Most streams in Lawrence County generally have calcium magnesium bicarbonate type waters. The sites from the mineralized area of central Lawrence County vary slightly from other streams in Lawrence County by having higher concentrations of sodium, less bicarbonate, and more sulfate. False Bottom Creek near Central City has more sulfate than bicarbonate. Nitrogen, phosphorous, and cyanide concentrations were at or near the laboratory reporting limits for most sites and did not exceed any of the water-quality standards. Nitrite plus nitrate concentrations at Annie Creek near Lead, Whitetail Creek at Lead, Squaw Creek near Spearfish, and Spearfish Creek below Robison Gulch were somewhat higher than at other sites. Mining activity, agricultural activity, and domestic development are possible sources of nitrogen to the streams. Increased mining activities were identified as the probable cause of increased nitrogen concentrations in Annie Creek. In the mineralized area of the northern Black Hills, detectable concentrations of trace elements are common in stream water, occasionally exceeding beneficial-use and aquatic-life criteria. In addition, many basins have been disturbed by both historical and recent mining operations and cleanup activities. The maximum dissolved arsenic concentration at Annie Creek near Lead (48 micrograms per liter) approached the current arsenic drinking-water standard. Concentrations at or greater than 5 micrograms per liter were found in samples from Annie Creek near Lead, Spearfish Creek above Spearfish, Whitetail Creek at Lead, and False Bottom Creek near Spearfish. Bear Butte Creek near Deadwood had one sample with a dissolved copper concentration that exceeded acute and chronic aquatic-life criteria. Bear Butte Creek near Deadwood had several manganese concentrations that exceeded the secondary maximum contaminant level of 50 micrograms per liter. Bed-sediment and water-quality data from selected sites in small drainage basins were used to determine if factors such as pH, arsenic concentrations in bed sediments, and calcite saturation control dissolved arsenic concentrations. Arsenic solubility is controlled by adsorption, mainly on ferrihydrite. In addition, adsorption/desorption of arsenic is controlled by the pH of the stream, with high arsenic concentrations appearing only at higher pH conditions (above 8). There are significant arsenic sources available to almost all the small streams of the northern Black Hills mining area, but arsenic is less mobile in streams that are not influenced to the higher pH values by calcite. Streams where arsenic is more mobile have lower iron concentrations in their bed sediments, and they have relatively high concentrations of calcite Additional water-quality data have been collected as part of other studies or monitoring programs by the South Dakota Department of Environment and Natural Resources, U.S. Environmental Protection Agency, U.S. Forest Service, and the U.S. Geological Survey. Summaries of selected data from these other sources are included as additional information.

South Dakota↗

Potential errors associated with stage-discharge relations for selected streamflow-gaging stations, Maricopa County, Arizona

Potential errors were derived for individual discharge measurements and stage-discharge relations for 17 streamflow-gaging stations in Maricopa County. Information presented primarily consists of stage and discharge data that were used to develop the stage-discharge relations that were in effect for water year 1998. Accuracy of the discharge measurements directly relate to accuracy of the stage-discharge relation developed for each site. Stage-discharge relations generally are developed using direct measurements of stage and discharge, indirect measurements of peak discharge, and theoretical weir and culvert computations. Accuracy of current-meter measurements of discharge (direct measurements) depends on factors such as the number of subsections in the measurement, stability of the channel, changes in flow conditions, and accuracy of the equipment. Accuracy of indirect measurements of peak discharge is determined by the accuracy of discharge coefficients and flow type selected for the computations. The accuracy of indirect peak-discharge computations generally is less than the accuracy associated with current-meter measurements. Current-meter measurements, indirect measurements of discharge, weir and culvert computations, and step-backwater computations are graphically represented on plots of the stage-discharge relations. Potential errors associated with the discharge measurements at selected sites are depicted as error bars on the plots. Potential errors derived for discharge measurements at 17 sites range from 5 to 25 percent. Errors generally are greater for measurements of large flows in channels having unstable controls using indirect methods.

Arizona↗

Ground-water flow and contributing areas to public-supply wells in Kingsford and Iron Mountain, Michigan

The cities of Kingsford and Iron Mountain are in the southwestern part of Dickinson County in the Upper Peninsula of Michigan. Residents and businesses in these cites rely primarily on ground water from aquifers in glacial deposits. Glacial deposits generally consist of an upper terrace sand-and-gravel unit and a lower outwash sand-and-gravel unit, separated by lacustrine silt and clay and eolian silt layers. These units are not regionally continuous, and are absent in some areas. Glacial deposits overlie Precambrian bedrock units that are generally impermeable. Precambrian bedrock consists of metasedimentary (Michigamme Slate, Vulcan Iron Formation, and Randville Dolomite) and metavolcanic (Badwater Greenstone and Quinnesec Formation) rocks. Where glacial deposits are too thin to compose an aquifer usable for public or residential water supply, Precambrian bedrock is relied upon for water supply. Typically a few hundred feet of bedrock must be open to a wellbore to provide adequate water for domestic users. Ground-water flow in the glacial deposits is primarily toward the Menominee River and follows the direction of the regional topographic slope and the bedrock surface. To protect the quality of ground water, Kingsford and Iron Mountain are developing Wellhead Protection Plans to delineate areas that contribute water to public-supply wells. Because of the complexity of hydrogeology in this area and historical land-use practices, a steady-state ground-water-flow model was prepared to represent the ground-water-flow system and to delineate contributing areas to public-supply wells. Results of steady-state simulations indicate close agreement between simulated and observed water levels and between water flowing into and out of the model area. The 10-year contributing areas for Kingsford's public-supply wells encompass about 0.11 square miles and consist of elongated areas to the east of the well fields. The 10-year contributing areas for Iron Mountain's public-supply wells encompass about 0.09 square miles and consist of elongate areas to the east of the well field.

Michigan↗

Preliminary hydraulic analysis and implications for restoration of Noyes Slough, Fairbanks, Alaska

The present-day channels of the Chena River and Noyes Slough in downtown Fairbanks, Alaska, were formed as sloughs of the Tanana River, and part of the flow of the Tanana River occupied these waterways. Flow in these channels was reduced after the completion of Moose Creek Dike in 1945, and flow in the Chena River was affected by regulation from the Chena River Lakes Flood Control Project, which was completed in 1980. In 1981, flow in the Chena River was regulated for the first time by Moose Creek Dam, located about 20 miles upstream from Fairbanks. Constructed as part of the Chena River Lakes Flood Control Project, the dam was designed to reduce maximum flows to 12,000 cubic feet per second in downtown Fairbanks. Cross-section measurements made near the entrance to Noyes Slough show that the channel bed of the Chena River has been downcutting, thereby reducing the magnitude and duration of flow in the slough. Consequently the slough slowly is drying up. Residents of the community wish to restore flow in Noyes Slough to create a clean, flowing waterway during normal summer flows. The desire is to enhance the slough as a fishery and habitat for other wildlife and for recreational boating.

Alaska↗

Occurrence and distribution of methyl tert-butyl ether and other volatile organic compounds in drinking water in the Northeast and Mid-Atlantic regions of the United States, 1993-98

Data on volatile organic compounds (VOCs) in drinking water supplied by 2,110 randomly selected community water systems (CWSs) in 12 Northeast and Mid-Atlantic States indicate 64 VOC analytes were detected at least once during 1993-98. Selection of the 2,110 CWSs inventoried for this study targeted 20 percent of the 10,479 active CWSs in the region and represented a random subset of the total distribution by State, source of water, and size of system. The data include 21,635 analyses of drinking water collected for compliance monitoring under the Safe Drinking Water Act; the data mostly represent finished drinking water collected at the pointof- entry to, or at more distal locations within, each CWS?s distribution system following any watertreatment processes. VOC detections were more common in drinking water supplied by large systems (serving more than 3,300 people) that tap surface-water sources or both surface- and groundwater sources than in small systems supplied exclusively by ground-water sources. Trihalomethane (THM) compounds, which are potentially formed during the process of disinfecting drinking water with chlorine, were detected in 45 percent of the randomly selected CWSs. Chloroform was the most frequently detected THM, reported in 39 percent of the CWSs. The gasoline additive methyl tert-butyl ether (MTBE) was the most frequently detected VOC in drinking water after the THMs. MTBE was detected in 8.9 percent of the 1,194 randomly selected CWSs that analyzed samples for MTBE at any reporting level, and it was detected in 7.8 percent of the 1,074 CWSs that provided MTBE data at the 1.0-?g/L (microgram per liter) reporting level. As with other VOCs reported in drinking water, most MTBE concentrations were less than 5.0 ?g/L, and less than 1 percent of CWSs reported MTBE concentrations at or above the 20.0-?g/L lower limit recommended by the U.S. Environmental Protection Agency?s Drinking-Water Advisory. The frequency of MTBE detections in drinking water is significantly related to high- MTBE-use patterns. Detections are five times more likely in areas where MTBE is or has been used in gasoline at greater than 5 percent by volume as part of the oxygenated or reformulated (OXY/RFG) fuels program. Detection frequencies of the individual gasoline compounds (benzene, toluene, ethylbenzene, and xylenes (BTEX)) were mostly less than 3 percent of the randomly selected CWSs, but collectively, BTEX compounds were detected in 8.4 percent of CWSs. BTEX concentrations also were low and just three drinkingwater samples contained BTEX at concentrations exceeding 20 ?g/L. Co-occurrence of MTBE and BTEX was rare, and only 0.8 percent of CWSs reported simultaneous detections of MTBE and BTEX compounds. Low concentrations and cooccurrence of MTBE and BTEX indicate most gasoline contaminants in drinking water probably represent nonpoint sources. Solvents were frequently detected in drinking water in the 12-State area. One or more of 27 individual solvent VOCs were detected at any reporting level in 3,080 drinking-water samples from 304 randomly selected CWSs (14 percent) and in 206 CWSs (9.8 percent) at concentrations at or above 1.0 ?g/L. High co-occurrence among solvents probably reflects common sources and the presence of transformation by-products. Other VOCs were relatively rarely detected in drinking water in the 12-State area. Six percent (127) of the 2,110 randomly selected CWSs reported concentrations of 16 VOCs at or above drinking-water criteria. The 127 CWSs collectively serve 2.6 million people. The occurrence of VOCs in drinking water was significantly associated (p<0.0001) with high population- density urban areas. New Jersey, Massachusetts, and Rhode Island, States with substantial urbanization and high population density, had the highest frequency of VOC detections among the 12 States. More than two-thirds of the randomly selected CWSs in New Jersey reported detecting VOC concentrations in drinking water at or above 1

Water-Resources Investigations Report↗