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At least 703 records · Page 39Linked to original sources

Use of Doppler velocity radars to monitor and predict debris and flood wave velocities and travel times in post-wildfire basins

The magnitude and timing of extreme events such as debris and floodflows (collectively referred to as floodflows) in post-wildfire basins are difficult to measure and are even more difficult to predict. To address this challenge, a sensor ensemble consisting of noncontact, ground-based (near-field), Doppler velocity (velocity) and pulsed (stage or gage height) radars, rain gages, and a redundant radio communication network was leveraged to monitor flood wave velocities, to validate travel times, and to compliment observations from NEXRAD weather radar. The sensor ensemble (DEbris and Floodflow Early warNing System, DEFENS) was deployed in Waldo Canyon, Pike National Forest, Colorado, USA, which was burned entirely (100 percent burned) by the Waldo Canyon fire during the summer of 2012 ( MTBS, 2020 ). Surface velocity, stage, and precipitation time series collected during the DEFENS deployment on 10 August 2015 were used to monitor and predict flood wave velocities and travel times as a function of stream discharge (discharge; streamflow). The 10 August 2015 event exhibited spatial and temporal variations in rainfall intensity and duration that resulted in a discharge equal to 5.01 cubic meters per second (m 3 /s). Discharge was estimated post-event using a slope-conveyance indirect discharge method and was verified using velocity radars and the probability concept algorithm. Mean flood wave velocities – represented by the kinematic celerity ( c k = 2.619 m e t e r s p e r s e c o n d , m / s ± 0.556 p e r c e n t "> 𝑐 𝑘 = 2.619 𝑚𝑒𝑡𝑒𝑟𝑠 𝑝𝑒𝑟 𝑠𝑒𝑐𝑜𝑛𝑑, m/s ± 0.556 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and dynamic celerity ( c d = 3.533 m / s ± 0.181 p e r c e n t a n d t h e i r u n c e r t a i n t i e s "> 𝑐 𝑑 = 3.533 m/s ± 0.181 𝑝𝑒𝑟𝑐𝑒𝑛𝑡) and their uncertainties were computed. L-moments were computed to establish probability density functions (PDFs) and associated statistics for each of the at-a-section hydraulic parameters to serve as a workflow for implementing alert networks in hydrologically similar basins that lack data. Measured flood wave velocities and travel times agreed well with predicted values. Absolute percent differences between predicted and measured flood wave velocities ranged from 1.6 percent to 49 percent and varied with water slope, hydraulic radius, and depth. The kinematic celerity was a better predictor for steep slopes and wide flood plains associated with the Upper Waldo and Middle Waldo radar streamgages; whereas, the dynamic celerity was a better surrogate for shallow slopes and incised channels such as the Lower Waldo radar streamgage. The method demonstrates the potential extensibility of a post-wildfire warning system by (1) leveraging multiple systems (i.e., weather radar, near-field velocity and stage radars, and rain gages) for accurate and timely warnings of debris and floodflows, (2) establishing an order of operations to site, install, and operate near-field radars and conventional rain gages to record floodflows, forecast travel times, and document geomorphic change in this basin and hydrologically similar basins that lack data, and (3) communicating data operationally with the Colorado Department of Transportation engineering staff, National Weather Service forecasters, and emergency managers.

Colorado↗

Spatial and temporal statistical analysis of bycatch data: Patterns of sea turtle bycatch in the North Atlantic

Loggerhead (Caretta caretta) and leatherback (Dermochelys coriacea) sea turtle distributions and movements in offshore waters of the western North Atlantic are not well understood despite continued efforts to monitor, survey, and observe them. Loggerhead and leatherback sea turtles are listed as endangered by the World Conservation Union, and thus anthropogenic mortality of these species, including fishing, is of elevated interest. This study quantifies spatial and temporal patterns of sea turtle bycatch distributions to identify potential processes influencing their locations. A Ripley's K function analysis was employed on the NOAA Fisheries Atlantic Pelagic Longline Observer Program data to determine spatial, temporal, and spatio-temporal patterns of sea turtle bycatch distributions within the pattern of the pelagic fishery distribution. Results indicate that loggerhead and leatherback sea turtle catch distributions change seasonally, with patterns of spatial clustering appearing from July through October. The results from the space-time analysis indicate that sea turtle catch distributions are related on a relatively fine scale (30-200 km and 1-5 days). The use of spatial and temporal point pattern analysis, particularly K function analysis, is a novel way to examine bycatch data and can be used to inform fishing practices such that fishing could still occur while minimizing sea turtle bycatch. ?? 2008 NRC.

Canadian Journal of Fisheries and Aquatic Sciences↗

Predictions of turbidity due to enhanced sediment resuspension resulting from sea-level rise on a fringing Coral Reef: Evidence from Molokai, Hawaii

Accelerating sea-level rise associated with global climate change will affect sedimentary processes on coral reefs and other shoreline environments by increasing energy and sediment resuspension. On reefs, sedimentation is known to increase coral stress and bleaching as particles that settle on coral surfaces interfere with photosynthesis and feeding, and turbidity induced by suspended sediment reduces incident light levels. Using relationships developed from observations of wave orbital velocity, water-surface elevation, and suspended-sediment concentration on a fringing reef flat of Molokai, Hawaii, predictions of the average daily maximum in suspended-sediment concentration increase from ~11 mg/l to ~20 mg/l with 20 cm sea-level rise. The duration of time concentrations exceeds 10 mg/l increases from 9 to 37. An evaluation of the reduction of wave energy flux through breaking and frictional dissipation across the reef flat shows an increase of ~80 relative to the present will potentially reach the shoreline as sea level increases by 20 cm. Where the shoreline exists on low, flat terrain, the increased energy could cause significant erosion of the shoreline. Considering the sediment budget, the sediment flux is predicted to increase and removal of fine-grained sediment may be expedited on some fringing reefs, and sediment in storage on the inner reef could ultimately be reduced. However, increased shoreline erosion may add sediment and offset removal from the reef flat. The shifts in sediment availability and transport that will occur as result of a modest increase in sea level have wide application to fringing coral reefs elsewhere, as well as other shoreline environments. ?? 2010 the Coastal Education & Research Foundation (CERF).

Journal of Coastal Research↗

Estimated trichloroethene transformation rates due to naturally occurring biodegradation in a fractured-rock aquifer

Rates of trichloroethene (TCE) mass transformed by naturally occurring biodegradation processes in a fractured rock aquifer underlying a former Naval Air Warfare Center (NAWC) site in West Trenton, New Jersey, were estimated. The methodology included (1) dividing the site into eight elements of equal size and vertically integrating observed concentrations of two daughter products of TCE biodegradation– cis -dichloroethene ( cis -DCE) and chloride–using water chemistry data from a network of 88 observation wells; (2) summing the molar mass of cis -DCE, the first biodegradation product of TCE, to provide a probable underestimate of reductive biodegradation of TCE, (3) summing the molar mass of chloride, the final product of chlorinated ethene degradation, to provide a probable overestimate of overall biodegradation. Finally, lower and higher estimates of aquifer porosities and groundwater residence times were used to estimate a range of overall transformation rates. The highest TCE transformation rates estimated using this procedure for the combined overburden and bedrock aquifers was 945 kg/yr, and the lowest was 37 kg/yr. However, hydrologic considerations suggest that approximately 100 to 500 kg/yr is the probable range for overall TCE transformation rates in this system. Estimated rates of TCE transformation were much higher in shallow overburden sediments (approximately 100 to 500 kg/yr) than in the deeper bedrock aquifer (approximately 20 to 0.15 kg/yr), which reflects the higher porosity and higher contaminant mass present in the overburden. By way of comparison, pump-and-treat operations at the NAWC site are estimated to have removed between 1,073 and 1,565 kg/yr of TCE between 1996 and 2009.

New Jersey↗

Molecular-level evidence provided by ultrahigh resolution mass spectrometry for oil-derived doc in groundwater at Bemidji, Minnesota

Dissolved organic matter samples extracted from ground water at the USGS Bemidji oil spill site in Minnesota were investigated by ultrahigh resolution mass spectrometry. Principle component analysis (PCA) of the elemental composition assignments of the samples showed that the score plots for the contaminated sites were well separated from those for the uncontaminated sites. Additionally, spectra obtained from the same sampling site 7 and 19 years after the spill were grouped together in the score plot, strongly suggesting a steady state of contamination within the 12 year interval. The double bond equivalence (DBE) of O x class compounds was broader for the samples from the contaminated sites, because of the complex nature of oil and the consequent formation of compounds with saturated and/or aromatic structures from the oxygenated products of oil. In addition, O x class compounds with a relatively smaller number of x (x < 8; x = number of oxygen) and O x S 1 class compounds were more abundant in the samples from the contaminated sites, because of the lower oxygen and higher sulfur contents of the oil compared to humic substances. The molecular-level signatures presented here can be a fundamental basis for in-depth analysis of oil contamination.

Minnesota↗

Analysis of aquifer mineralization by paleodrainage channels

Mineralization of groundwater resources is a problem in south-central Kansas, due to the penetration of saline water from Permian bedrock formations into the overlying alluvial aquifer. One of the mechanisms involved in the mineralization involves small bedrock features of high permeability located in places occupied by streams and rivers in past geological eras. These geological features are termed 'paleodrainage channels'. The permeability of the overlying aquifer can be significantly smaller than that of the channel fill material. The comparatively fast migration of saline water through these channels of high permeability is associated with the transfer of minerals into the overlying freshwater aquifer. This study applies a set of boundary layer approaches to quantify the process of mineral transfer from the channels into the aquifer. The methods used in the present study provide quick estimation and evaluation of the dilution of the channel flow, as well as mineral concentration profile changes in the mineralized zone created in the overlying aquifer. More generally, the method can also be useful for the analysis and evaluation of various types of groundwater contamination in heterogeneous aquifers. The application of the method is exemplified by a complete set of calculations characterizing the possible mineralization process at a specific channel in south central Kansas. Sensitivity analyses are performed and provide information about the importance of the various parameters that affect the mineralization process. Some possible scenarios for the aquifer mineralization phenomena are described and evaluated. It is shown that the channel mineralization may create either several stream tubes of the aquifer with high mineral concentration, or many stream tubes mineralized to a lesser extent. Characteristics of these two patterns of aquifer mineralization are quantified and discussed. ?? 2003 Published by Elsevier Science B.V.

Journal of Hydrology↗

Prominent pancreatic endocrinopathy and altered control of food intake disrupt energy homeostasis in prion diseases

Prion diseases are fatal neurodegenerative diseases that can induce endocrinopathies. The basis of altered endocrine function in prion diseases is not well understood, and the purpose of this study was to investigate the spatiotemporal relationship between energy homeostasis and prion infection in hamsters inoculated with either the 139H strain of scrapie agent, which induces preclinical weight gain, or the HY strain of transmissible mink encephalopathy (TME), which induces clinical weight loss. Temporal changes in body weight, feed, and water intake were measured as well as both non-fasted and fasted concentrations of serum glucose, insulin, glucagon, ??-ketones, and leptin. In 139H scrapie-infected hamsters, polydipsia, hyperphagia, non-fasted hyperinsulinemia with hyperglycemia, and fasted hyperleptinemia were found at preclinical stages and are consistent with an anabolic syndrome that has similarities to type II diabetes mellitus and/or metabolic syndrome X. In HY TME-infected hamsters, hypodipsia, hypersecretion of glucagon (in both non-fasted and fasted states), increased fasted ??-ketones, fasted hypoglycemia, and suppressed non-fasted leptin concentrations were found while feed intake was normal. These findings suggest a severe catabolic syndrome in HY TME infection mediated by chronic increases in glucagon secretion. In both models, alterations of pancreatic endocrine function were not associated with PrPSc deposition in the pancreas. The results indicate that prominent endocrinopathy underlies alterations in body weight, pancreatic endocrine function, and intake of food. The prion-induced alterations of energy homeostasis in 139H scrapie- or HY TME-infected hamsters could occur within areas of the hypothalamus that control food satiety and/or within autonomic centers that provide neural outflow to the pancreas. ?? 2008 Society for Endocrinology.

Journal of Endocrinology↗

Analysis and visualization of coastal ocean model data in the cloud

The traditional flow of coastal ocean model data is from High Performance Computing (HPC) centers to the local desktop, or to a file server where just the data needed can be extracted via services such as OPeNDAP. Analysis and visualization is then conducted using local hardware and software. This requires moving large amounts of data across the internet as well as acquiring and maintaining local hardware, software and support personnel. Further, as data sets increase in size, the traditional workflow may not be scalable. Alternatively, recent advances make it possible to move data from HPC to the Cloud and perform interactive, scalable, data-proximate analysis and visualization, with simply a web browser user interface. We use the framework advanced by the NSF-funded Pangeo project, a free, open-source Python system which provides multi-user login via JupyterHub and parallel analysis via Dask, both running in Docker containers orchestrated by Kubernetes. Data is stored in the Zarr format, a Cloud-friendly ndarray format that allows performant extraction of data by anyone without relying on data services like OPeNDAP. Interactive visual exploration of data on massive model grids is made possible by new tools in the Python PyViz ecosystem, which can render maps at screen resolution, dynamically updating on pan and zoom operations. Two example are given: (1) calculating the maximum water level at each grid cell from a 53GB, 720 time step, 9 million node triangular mesh ADCIRC simulation of Hurricane Ike; (2) creating a dashboard for visualizing data from the curvilinear orthogonal COAWST/ROMS forecast model.

Journal of Marine Science and Engineering↗

Estimating regional-scale permeability–depth relations in a fractured-rock terrain using groundwater-flow model calibration

The trend of decreasing permeability with depth was estimated in the fractured-rock terrain of the upper Potomac River basin in the eastern USA using model calibration on 200 water-level observations in wells and 12 base-flow observations in subwatersheds. Results indicate that permeability at the 1–10 km scale (for groundwater flowpaths) decreases by several orders of magnitude within the top 100 m of land surface. This depth range represents the transition from the weathered, fractured regolith into unweathered bedrock. This rate of decline is substantially greater than has been observed by previous investigators that have plotted in situ wellbore measurements versus depth. The difference is that regional water levels give information on kilometer-scale connectivity of the regolith and adjacent fracture networks, whereas in situ measurements give information on near-hole fractures and fracture networks. The approach taken was to calibrate model layer-to-layer ratios of hydraulic conductivity (LLKs) for each major rock type. Most rock types gave optimal LLK values of 40–60, where each layer was twice a thick as the one overlying it. Previous estimates of permeability with depth from deeper data showed less of a decline at <300 m than the regional modeling results. There was less certainty in the modeling results deeper than 200 m and for certain rock types where fewer water-level observations were available. The results have implications for improved understanding of watershed-scale groundwater flow and transport, such as for the timing of the migration of pollutants from the water table to streams.

Hydrogeology Journal↗

Genome-wide genetic diversity may help identify fine-scale genetic structure among lake whitefish spawning groups in Lake Erie

In Lake Erie, lake whitefish Coregonus clupeaformis supported lucrative fisheries before populations were decimated by overfishing and water quality degradation. In recent years, there has been a renewed interest in lake whitefish and management of the fishery they support. Lake whitefish spawn on several reefs throughout Lake Erie, but the relative recruitment dynamics and contributions of spawning groups to the fishery are not well understood. Modern high-throughput sequencing approaches offer new opportunities to census population diversity and to identify subtle differences among closely related populations. We used high-throughput sequencing data to evaluate the genetic structure and diversity of lake whitefish collected opportunistically across broad spatial scales in Lake Erie. Using RAD-capture (Rapture), we sequenced and genotyped individuals (N = 88) from the west, central, and east basin of Lake Erie at 120,268 single nucleotide polymorphisms (SNPs). Lake whitefish from Niagara and Crib Reefs (west basin) diverged from the three collections. Interestingly, these were the only lake whitefish collected during the act of spawning (late November), and all other fish were collected pre-spawn (August-early November). These results suggest that some lake whitefish spawning reefs may be reproductively isolated, though definition of these groups into stocks will require more intentional sampling during the act of spawning.

Michigan, New York, Ohio, Ontario, Pennsylvania↗

Consideration of vertical uncertainty in elevation-based sea-level rise assessments: Mobile Bay, Alabama case study

The accuracy with which coastal topography has been mapped directly affects the reliability and usefulness of elevationbased sea-level rise vulnerability assessments. Recent research has shown that the qualities of the elevation data must be well understood to properly model potential impacts. The cumulative vertical uncertainty has contributions from elevation data error, water level data uncertainties, and vertical datum and transformation uncertainties. The concepts of minimum sealevel rise increment and minimum planning timeline, important parameters for an elevation-based sea-level rise assessment, are used in recognition of the inherent vertical uncertainty of the underlying data. These concepts were applied to conduct a sea-level rise vulnerability assessment of the Mobile Bay, Alabama, region based on high-quality lidar-derived elevation data. The results that detail the area and associated resources (land cover, population, and infrastructure) vulnerable to a 1.18-m sea-level rise by the year 2100 are reported as a range of values (at the 95% confidence level) to account for the vertical uncertainty in the base data. Examination of the tabulated statistics about land cover, population, and infrastructure in the minimum and maximum vulnerable areas shows that these resources are not uniformly distributed throughout the overall vulnerable zone. The methods demonstrated in the Mobile Bay analysis provide an example of how to consider and properly account for vertical uncertainty in elevation-based sea-level rise vulnerability assessments, and the advantages of doing so.

Alabama↗

Survival of lake trout eggs on reputed spawning grounds in Lakes Huron and Superior: In situ incubation, 1987-1988

Lake trout reproduce widely in Lake Superior but little in Lake Huron. We examined whether survival of lake trout eggs and fry in either lake was reduced by physical disturbances and swim-up mortality. Eggs were collected from feral lake trout in Lake Superior and placed in 108 plastic incubators. A total of 48 incubators was set at Partridge Island Reef in southern Lake Superior, 48 were set at Port Austin Reef in southern Lake Huron, and 12 were held as controls inflowing well water at a laboratory. Survival-to-hatching of these eggs at Partridge Island Reef (18%) was significantly different from that at Port Austin Reef (43%) and significantly different in the laboratory (88%) from that at either reef (P < 0.05). During egg-fry incubation from 28 October 1987 to 5 May 1988, 11&ndash;18 cm of sediment accumulated in sediment traps placed on the reefs but < 1 cm of sediment was present on each reef in May 1988. Analysis showed that 44% of the eggs at Port Austin Reef and 28% of those at Partridge Island Reef were buried and killed by sediments. During the first week after deployment, mean wave energy was 90% higher at Partridge Island Reef and significantly different from that at Port Austin Reef. Wave energy may be a habitat condition that makes Partridge Island Reef less suitable than Port Austin Reef for incubation of lake trout eggs. Fry from eggs incubated at all three sites experienced no swim-up mortality. We conclude that in 1987&ndash;88 habitat conditions required for survival of lake trout eggs were more suitable at Port Austin Reef than at Partridge Island Reef.

Journal of Great Lakes Research↗

Metabolically diverse microorganisms mediate methylmercury formation under nitrate-reducing conditions in a dynamic hydroelectric reservoir

Brownlee Reservoir is a mercury (Hg)-impaired hydroelectric reservoir that exhibits dynamic hydrological and geochemical conditions and is located within the Hells Canyon Complex in Idaho, USA. Methylmercury (MeHg) contamination in fish is a concern in the reservoir. While MeHg production has historically been attributed to sulfate-reducing bacteria and methanogenic archaea, microorganisms carrying the hgcA gene are taxonomically and metabolically diverse and the major biogeochemical cycles driving mercury (Hg) methylation are not well understood. In this study, Hg speciation and redox-active compounds were measured throughout Brownlee Reservoir across the stratified period in four consecutive years (2016–2019) to identify the location where and redox conditions under which MeHg is produced. Metagenomic sequencing was performed on a subset of samples to characterize the microbial community with hgcA and identify possible links between biogeochemical cycles and MeHg production. Biogeochemical profiles suggested in situ water column Hg methylation was the major source of MeHg. These profiles, combined with genome-resolved metagenomics focused on hgcA -carrying microbes, indicated that MeHg production occurs in this system under nitrate- or manganese-reducing conditions, which were previously thought to preclude Hg-methylation. Using this multidisciplinary approach, we identified the cascading effects of interannual variability in hydrology on the redox status, microbial metabolic strategies, abundance and metabolic diversity of Hg methylators, and ultimately MeHg concentrations throughout the reservoir. This work expands the known conditions conducive to producing MeHg and suggests that the Hg-methylation mitigation efforts by nitrate or manganese amendment may be unsuccessful in some locations.

Idaho↗

Herbicides and herbicide degradation products in upper midwest agricultural streams during august base-flow conditions

Herbicide concentrations in streams of the U.S. Midwest have been shown to decrease through the growing season due to a variety of chemical and physical factors. The occurrence of herbicide degradation products at the end of the growing season is not well known. This study was conducted to document the occurrence of commonly used herbicides and their degradation products in Illinois, Iowa, and Minnesota streams during base-flow conditions in August 1997. Atrazine, the most frequently detected herbicide (94%), was present at relatively low concentrations (median 0.17 &mu;g L &minus;1 ). Metolachlor was detected in 59% and cyanazine in 37% of the samples. Seven of nine compounds detected in more than 50% of the samples were degradation products. The total concentration of the degradation products (median of 4.4 &mu;g L &minus;1 ) was significantly greater than the total concentration of parent compounds (median of 0.26 &mu;g L &minus;1 ). Atrazine compounds were present less frequently and in significantly smaller concentrations in streams draining watersheds with soils developed on less permeable tills than in watersheds with soils developed on more permeable loess. The detection and concentration of triazine compounds was negatively correlated with antecedent rainfall (April&ndash;July). In contrast, acetanalide compounds were positively correlated with antecedant rainfall in late spring and early summer that may transport the acetanalide degradates into ground water and subsequently into nearby streams. The distribution of atrazine degradation products suggests regional differences in atrazine degradation processes.

Midwest region↗

The 2014–2015 Holuhraun lava flow-field in Iceland as a planetary analog for young volcanic terrains in Elysium Planitia, Mars

Elysium Planitia is the youngest volcanic terrain on Mars, and the only region that exhibits evidence of ongoing magmatic activity today. This makes Elysium Planitia crucial for understanding the tectonic, magmatic, volcanic, and thermal state of the planet. The 2014–2015 Holuhraun eruption in the Icelandic Highland provides a unique opportunity to study a large-volume, fissure-fed eruption—with associated lava–water interactions—that serves as a terrestrial analog for volcanic terrains in Elysium Planitia. Here, we detail the key similarities between the Holuhraun and Elysium Planitia sites, including their geological settings, prominent lava morphologies, and implications for inferring eruption dynamics. Even in the absence of global plate tectonics on Mars, both locations exhibit young fissure systems, indicating an extensional tectonic setting. Detailed investigations of lava morphologies offer valuable insights into the dynamics and evolution of fissure-fed eruptions. Of particular importance are “transitional” lavas, which, at the Holuhraun site, are associated with different effusion rates and eruption stages. The presence of inflation features with disrupted surfaces in Elysium Planitia supports the interpretation that these are rubbly lava flows formed in association with high local strain rates, implying an initial high effusion rate. However, both locations exhibit polygonal terrain, which is indicative of low strain rate conditions, implying a change to cooling under broadly stagnant conditions. Due to its variety of recent geologic processes, including volcanic and potentially aqueous flows, the presence of pristine surfaces, as well as associated tectonic and magmatic activity, Elysium Planitia is a compelling target for future exploration.

Elysium Planitia, Mars↗

Hydrologic conditions and terrestrial laser scanning of post-firedebris flows in the San Gabriel Mountains, CA, U.S.A

To investigate rainfall-runoff conditions that generate post-wildfire debris flows, we instrumented and surveyed steep, small watersheds along the tectonically active front of the San Gabriel Mountains, California. Fortuitously, we recorded runoff-generated debris-flows triggered by one spatially restricted convective event with 28 mm of rainfall falling over 62 minutes. Our rain gages, nested hillslope overland-flow sensors and soil-moisture probes, as well as a time series of terrestrial laser scanning (TLS) revealed the effects of the storm. Hillslope overland-flow response, along two ~10-m long flow lines perpendicular to and originating from a drainage divide, displayed only a 10 to 20 minute delay from the onset of rainfall with accumulated totals of merely 5-10 mm. Depth-stratified soil-moisture probes displayed a greater time delay, roughly 20- 30 minutes, indicating that initial overland flow was Hortonian. Furthermore, a downstream channel-monitoring array recorded a pronounced discharge peak generated by the passage of a debris flow after 18 minutes of rainfall. At this time, only four of the eleven hillslope overland flow sensors confirmed the presence of surface-water flow. Repeat TLS and detailed field mapping using GPS document how patterns of rainsplash, overland-flow scour, and rilling contributed to the generation of metter-scale debris flows. In response to a single small storm, the debris flows deposited irregular levees and lobate terminal snouts on hillslopes and caused wide- spread erosion of the valley axis with ground surface lowering exceeding 1.5 m.

California↗

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234 U/ 238 U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.

Arizona↗

Reconnaissance of pharmaceuticals and wastewater indicators in streambed sediments of the lower Columbia River basin, Oregon and Washington

One by-product of advances in modern chemistry is the accumulation of synthetic chemicals in the natural environment. These compounds include contaminants of emerging concern (CECs), some of which are endocrine disrupting compounds (EDCs) that can have detrimental reproductive effects. The role of sediments in accumulating these types of chemicals and acting as a source of exposure for aquatic organisms is not well understood. Here we present a small-scale reconnaissance of CECs in bed sediments of the lower Columbia River and several tributaries and urban streams. Surficial bed sediment samples were collected from the Columbia River, the Willamette River, the Tualatin River, and several small urban creeks in Oregon. Thirty-nine compounds were detected at concentrations ranging from <1 to >1,000 ng [g sediment] -1 dry weight basis. Columbia River mainstem, suggesting a higher risk of exposure to aquatic life in lower order streams. Ten known or suspected EDCs were detected during the study. At least one EDC was detected at 21 of 23 sites sampled; several EDCs were detected in sediment from most sites. This study is the first to document the occurrence of a large suite of CECs in the sediments of the Columbia River basin. A better understanding of the role of sediment in the fate and effects of emerging contaminants is needed.

Oregon;Washington↗