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USGS1995

Effects of two contrasting agricultural land uses on shallow groundwater quality in the San Joaquin Valley, California; design and preliminary interpretation

From 1992 through 1994, the San Joaquin-Tulare Basins Study team of the USGS National Water Quality Assessment program investigated the occurrence and distribution of water quality constituents in shallow groundwater underlying two areas of different agricultural land uses: almond orchards and vineyards. The study was restricted to the alluvial fans of the eastern San Joaquin Valley, the area of most groundwater use in the valley. A geographic information system (GIS) was used to delineate the distribution of the two target land uses, to evaluate ancillary data, and to select candidate wells that fit prescribed criteria. Twenty domestic water supply wells were sampled in each of the two areas. In addition, pairs of observation wells were installed and sampled at five of the sites in each area to evaluate whether the water quality in the domestic wells reflects that of the shallow groundwater underlying the target land use. A preliminary evaluation of the results shows that nitrate concentrations in the shallow groundwater are significantly higher in the almond orchard areas than in the vineyard area (p=0.005). In contrast, concentrations of 1,2-dibromo-3-chloropropane (DBCP) were higher in the vineyard area than in the almond orchard area (p=0.032). The most frequently detected pesticides in groundwater underlying both areas were simazine, atrazine, and desethylatrazine (an atrazine degradation product). These observations are explained, in part, by differences in chemical application and hydrogeologic factors.

California↗

USGS1989

Functional requirements of computer systems for the U.S. Geological Survey, Water Resources Division, 1988-97

Investigating the occurrence, quantity, quality, distribution, and movement of the Nation 's water resources is the principal mission of the U.S. Geological Survey 's Water Resources Division. Reports of these investigations are published and available to the public. To accomplish this mission, the Division requires substantial computer technology to process, store, and analyze data from more than 57,000 hydrologic sites. The Division 's computer resources are organized through the Distributed Information System Program Office that manages the nationwide network of computers. The contract that provides the major computer components for the Water Resources Division 's Distributed information System expires in 1991. Five work groups were organized to collect the information needed to procure a new generation of computer systems for the U. S. Geological Survey, Water Resources Division. Each group was assigned a major Division activity and asked to describe its functional requirements of computer systems for the next decade. The work groups and major activities are: (1) hydrologic information; (2) hydrologic applications; (3) geographic information systems; (4) reports and electronic publishing; and (5) administrative. The work groups identified 42 functions and described their functional requirements for 1988, 1992, and 1997. A few new functions such as Decision Support Systems and Executive Information Systems, were identified, but most are the same as performed today. Although the number of functions will remain about the same, steady growth in the size, complexity, and frequency of many functions is predicted for the next decade. No compensating increase in the Division 's staff is anticipated during this period. To handle the increased workload and perform these functions, new approaches will be developed that use advanced computer technology. The advanced technology is required in a unified, tightly coupled system that will support all functions simultaneously. The new approaches and expanded use of computers will require substantial increases in the quantity and sophistication of the Division 's computer resources. The requirements presented in this report will be used to develop technical specifications that describe the computer resources needed during the 1990's. (USGS)

Open-File Report↗

USGS2012

A science plan for a comprehensive assessment of water supply in the region underlain by fractured rock in Maryland

The fractured rock region of Maryland, which includes land areas north and west of the Interstate 95 corridor, is the source of water supply for approximately 4.4 million Marylanders, or approximately 76 percent of the State's population. Whereas hundreds of thousands of residents rely on wells (both domestic and community), millions rely on surface-water sources. In this region, land use, geology, topography, water withdrawals, impoundments, and other factors affect water-flow characteristics. The unconfined groundwater systems are closely interconnected with rivers and streams, and are affected by seasonal and climatic variations. During droughts, groundwater levels drop, thereby decreasing well yields, and in some cases, wells have gone dry. Low ground-water levels contribute to reduced streamflows, which in turn, can lead to reduced habitat for aquatic life. Increased demand, over-allocation, population growth, and climate change can affect the future sustainability of water supplies in the region of Maryland underlain by fractured rock. In response to recommendations of the 2008 Advisory Committee on the Management and Protection of the State's Water Resources report, the Maryland Department of the Environment's Water Supply Program, the Maryland Geological Survey, the Maryland Department of Natural Resources, Monitoring and Non-Tidal Assessment (MANTA) Division, and the U.S. Geological Survey have developed a science plan for a comprehensive assessment that will provide new scientific information, new data analysis, and new tools for the State to better manage water resources in the fractured rock region of Maryland. The science plan lays out five goals for the comprehensive assessment: (1) develop tools for the improved management and investigation of groundwater and surface-water resources; (2) characterize factors affecting reliable yields of individual groundwater and surface-water supplies; (3) investigate impacts on nearby water withdrawal users caused by groundwater and surface-water withdrawals; (4) assess the role of streamflow and water withdrawals on the ecological integrity of streams; and (5) improve understanding of the distribution of water-quality conditions in fractured rock aquifers. To accomplish these goals, accurate data collection, review, and analysis are needed, including the study of "Research Watersheds" that can provide detailed information about the potential effects that climate change and water withdrawals may have on groundwater, streamflow, and aquatic life. The assessment planning started in 2009 and is being conducted with close interagency coordination. A Fractured Rock Aquifer Information System is currently (2012) undergoing initial development. Other major tasks that will be performed include the development of work plans for each science goal, the estimation of daily streamflow at ungaged streams, and the design and implementation of Research Watersheds. Finally, scenarios will be modeled to evaluate current water allocation permitting methodologies, investigate effects on nearby water withdrawal users caused by groundwater and surface-water withdrawals, and assess the potential impacts of climate change on water resources. Desktop and Web-based tools will be developed in order to meet the diverse research needs of the assessment. These tools, including the Fractured Rock Aquifer Information System will be continuously improved during the assessment to store relevant groundwater and surface-water data in spatially referenced databases, estimate streamflows, locate higher-yielding wells, estimate the impacts of withdrawals on nearby users, and assess the cumulative impacts of withdrawals on the aquatic resource. Tools will be developed to serve the needs of many audiences, including water resource managers, water suppliers, planners, policymakers, and other scientific investigators.

Maryl↗

USGS1998

Recharge-area delineation and hydrology, McCraken Springs, Fort Knox Military Reservation, Meade County, Kentucky

McCraken Springs, consisting of three perennial springs - Main, Bat Cave, and Rocky Springs—and several intermittent springs, are used as a source of public water by the Fort Knox Military Reservation in Meade County, Ky. The water supply provided by McCraken Springs is potentially vulnerable to natural and induced stresses on the karst aquifer and to degradation by contaminants introduced by stormwater entering sinkholes and a large sinking stream in the Springs' recharge area. The U.S. Department of the Army is preparing a spring-basin protection plan for McCraken Springs, in accordance with State water-supply regulations and as specified under U.S. Environmental Protection Agency Guidelines for the Wellhead Protection Program (U.S. Environmental Protection Agency, 1991). In order to provide the information needed to prepare the plan, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army Corps of Engineers, conducted a hydrogeologic study of the McCraken Springs in 1997-98. This report presents the results of that investigation. Ground-water-tracer tests and the results of potentiometric-surface mapping were used to identify ground-water basins drained by major perennial springs and to delineate the approximate boundaries of the recharge area for McCraken Springs. Additional hydrologic data were collected to determine the discharge and recharge characteristics of the Springs. Karst aquifers and springs are widely recognized as being more sensitive to degradation to point- and nonpoint-source contamination than most granular and fractured-rock aquifers (Field, 1990). Delineation of the geographic area contributing recharge to a water-supply spring is a principal step in identifying potential sources of ground-water contamination and developing a strategy to ensure the availability and protect the sustainability of the water supply. Conventional methods of aquifer testing and numerical modeling are not sufficient to determine the flow boundaries of ground-water basins in conduit-dominated karst aquifers. Previous studies published by Quinlan and Ewers (1989); Mull and others (1990); Bayless and others (1994); and Schindel and others (1995) demonstrate the utility of ground-water tracer tests, used in combination with potentiometric-surface mapping, to identify flow directions in karst aquifers, and to delineate karst ground-water-basin boundaries.

Kentucky↗

USGS2014

Caution on the use of NBS 30 biotite for hydrogen-isotope measurements with on-line high-temperature conversion systems

RATIONALE The supply of NBS 30 biotite is nearly exhausted. During measurements of NBS 30 and potential replacements, reproducible δ 2 H VSMOW-SLAP values could not be obtained by three laboratories using high-temperature conversion (HTC) systems. The cause of this issue has been investigated using the silver-tube technique for hydrogen-isotope measurements of water. METHODS The δ 2 H VSMOW-SLAP values of NBS 30 biotite, other biotites, muscovites, and kaolinite with different particle sizes, along with IAEA-CH-7 polyethylene, and reference waters and NBS 22 oil that were sealed in silver-tube segments, were measured. The effect of absorbed water on mineral surfaces was investigated with waters both enriched and depleted in 2 H. The quantitative conversion of hydrogen from biotite into gaseous hydrogen as a function of mass and particle size was also investigated. RESULTS The δ 2 H VSMOW-SLAP values of NBS 30 obtained by three laboratories were as much as 21 ‰ too high compared with the accepted value of −65.7 ‰, determined by conventional off-line measurements. The experiments showed a strong correlation between grain size and the δ 2 H VSMOW-SLAP value of NBS 30 biotite, but not of biotites with lower iron content. The δ 2 H VSMOW-SLAP values of NBS 30 as a function of particle size show a clear trend toward −65.7 ‰ with finer grain size. CONCLUSIONS Determination of the δ 2 H VSMOW-SLAP values of hydrous minerals and of NBS 30 biotite by on-line HTC systems coupled to isotope-ratio mass spectrometers may be unreliable because hydrogen in this biotite may not be converted quantitatively into molecular hydrogen. Extreme caution in the use and interpretation of δ 2 H VSMOW-SLAP on-line measurements of hydrous minerals is recommended.

Rapid Communications in Mass Spectrometry↗

USGS2005

Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada

n investigation of a childhood leukemia cluster by US Centers for Disease Control and Prevention revealed that residents of the Carson Desert, Nevada, are exposed to high levels of W and this prompted an investigation of W in aquifers used as drinking water sources. Tungsten concentrations in 100 ground water samples from all aquifers used as drinking water sources in the area ranged from 0.27 to 742 μg/l. Ground water in which W concentrations exceed 50 μg/l principally occurs SE of Fallon in a geothermal area. The principal sources of W in ground water are natural and include erosion of W-bearing mineral deposits in the Carson River watershed upstream of Fallon, and, possibly, upwelling geothermal waters. Ground water in the Fallon area is strongly reducing and reductive dissolution of Fe and Mn oxyhydroxides may be releasing W; however, direct evidence that the metal oxides contain W is not available. Although W and Cl concentrations in the Carson River, a lake, and water from many wells, appear to be controlled by evaporative concentration, evaporation alone cannot explain the elevated W concentrations found in water from some of the wells. Concentrations of W exceeding 50 μg/l are exclusively associated with Na – HCO 3 "> Na–HCO3 and Na–Cl water types and pH > 8.0; in these waters, geochemical modeling indicates that W exhibits <10% adsorption. Tungsten concentrations are strongly and positively correlated with As, B, F, and P, indicating either common sources or common processes controlling their concentrations. Geochemical modeling indicates W concentrations are consistent with pH-controlled adsorption of W. The geochemical model PHREEQC was used to calculate IAP values, which were compared with published Ksp values for primary W minerals. FeWO 4 , MnWO 4 , Na 2 WO 4 , and MgWO 4 were undersaturated and CaWO 4 and SrWO 4 were approaching saturation. These conclusions are tentative because of uncertainty in the thermodynamic data. The similar behavior of As and W observed in this study suggests ground water in areas where elevated As concentrations are present also may contain elevated W concentrations, particularly if there is a mineral or geothermal source of W and reducing conditions develop in the aquifer.

Nevada↗

USGS1995

Water levels in the Calumet aquifer and their relation to surface-water levels in northern Lake County, Indiana, 1985-92

The U.S. Geological Survey made 2,328 water-level measurements at a total of 96 ground-water and surface-water sites in northern Lake County, Indiana, from August 1985 through September 1992. This report lists and summarizes the significance of the measurements. Northern Lake County is on the southern shore of Lake Michigan and includes the cities of East Chicago, Gary, Hammond, and Whiting. The study area is underlain by the unconfined Calumet aquifer and receives about 36 inches of precipitation per year. The U.S. Geological Survey investigated ground-water levels and flow in the Calumet aquifer and the effect of Lake Michigan levels on ground-water and surface-water levels throughout the study area. Summary statistics of the water-level data were computed for each site. Ground-water levels annually reach a maximum in June or July and a minimum in September or October. Measured groundwater fluctuations in the Calumet aquifer during the study period ranged from 0.40 to 5.01 feet, and the mean ground-water fluctuation was about 2.3 feet The largest surface-water fluctuations were affected by record setting Lake Michigan levels. Midmonth daily averages for the data-collection period show that Lake Michigan fluctuated 4.14 feet Water-level fluctuations on the Grand Calumet River were from 1.06 to 2.45 feet. Analysis of water-level data indicates that the 1988 drought did not substantially affect water levels in the Calumet aquifer, but the deficit in precipitation reversed vertical flow gradients in ground water at three paired deep and shallow wells. High water levels in Lake Michigan during 1985-87 created long-term backwater effects on the Grand Calumet River as far as 11.0 miles upstream from Lake Michigan. Analysis of water-level data from the data-collection network indicates that the water table normally slopes toward streams, ditches, sewers, the Indiana Harbor Canal, and Lake Michigan. The slope of the water table toward the Grand Calumet River is greatest in the winter and can decrease to being almost horizontal in the summer. Wells near streams respond quickly to nearby surface-water-level changes. Water-table maps indicate that sewers and dewatering systems are lowering ground-water levels in large areas. Ditches, the Grand Calumet River, and the Indiana Harbor Canal connect the Lake Michigan water level to large parts of the study area. The surface-water stage in the Indiana Harbor Canal, which functions as a ditch, can equal Lake Michigan's stage up to 3.75 miles inland from the lakeshore. Human activity, the stage of Lake Michigan, and the storage capacity of the Calumet aquifer combine to reduce vertical changes in the water table in the study area.

Indiana↗

USGS2006

Water-quality characteristics and contaminants in the rural karst-dominated Spring Mill Lake watershed, southern Indiana

The Spring Mill Lake watershed is located in the Mitchell Plateau, a karst area that developed on Mississippian carbonates in southern Indiana. Spring Mill Lake is a reservoir built in the late 1930s and is located in Spring Mill State Park. Within the park, groundwater from subsurface conduits issues as natural springs and then flows in surface streams to the lake. From 1998 to 2002, surface and subsurface hydrology and water quality were investigated to determine the types and sources of potential contaminants entering the lake. Water samples collected during base flow and a February 2000 storm event were analyzed for selected cations, anions, trace elements, selected U.S. Environmental Protection Agency (EPA) primary and secondary drinkingwater contaminants, nitrogen isotopes, suspended solids, Escherichia coli, and pesticides. All of the water samples met the EPA drinking-water standards for inorganic constituents, except those collected at five sites in August 1999 during a drought. Nitrate nitrogen (NO 3 -N) concentrations were highest during base-flow conditions and displayed a dilutional trend during peak-flow periods. The NO 3 -N concentrations in water samples collected during the 2001 spring fertilizer applications tended to increase from early to late spring. All of the ?? 15 N values were low, which is indicative of either an inorganic source or soil organic matter. Storm discharge contained increased concentrations of total suspended solids; thus, storms are responsible for most of the sediment accumulation in the lake. E. coli levels in 24% of the samples analyzed contained a most probable number (MPN) greater than 235/100 mL, which is the maximum acceptable level set for recreational waters in Indiana. E. coli does appear to be a potential health risk, particularly at Rubble spring. The sources of E. coli found at this spring may include barnyard runoff from a horse barn or wastes from a wastewater treatment facility. The pesticides atrazine, metolachlor, acetochlor, and simazine were detected during the spring of 2001. Atrazine, metolachlor, acetochlor, and simazine are used to suppress weeds during corn and soybean production. Additional sources of atrazine and simazine may result from application to right-of-ways, orchards, and managed forest areas. ?? 2006 Geological Society of America.

Special Paper of the Geological Society of America↗

USGS2006

Some aspects of sampling salty ground water in coastal aquifers

Investigations of the fluctuations of chloride content in wells that tap the zone of diffusion between fresh and salt water show that the salty well water behaves erratically when the well is pumped. Frequently, a static distribution of chloride content that ranges from less than 1,000 ppm at the top to more than 10,000 ppm at the bottom is present in the open‐hole part of a well. When the well is pumped, the discharge water tends to come from the upper part of the open hole because less energy is expended by removal of low‐density water from this region than by removal of high‐density water from the lower part of the open hole. Where the permeability of strata in the deep part of the open hole is greater than that in the shallow part, the tendency for natural selection of the less dense, shallow water is suppressed, and practically all the water in the blend comes from the deep part. As a result of this complex interrelation of hydraulics, distribution and density of the salt water , and permeability, the depth at which the pumped water enters the well bore is indeterminate. This deficiency leads to the use of multiple‐depth‐bottle, windshield‐wiper, and electrical‐conductivity sampling techniques for collection of data used in constructing maps and cross sections that show the areal‐depth relations of salt water in the Biscayne aquifer of the Miami area, Florida.

Groundwater↗

USGS1994

Sources of trends in water-quality data for selected streams in Texas, 1975-89 water years

Sources of trends in water-quality data for selected streams in Texas for the 1975-89 water years were investigated in this study. The investigation of sources was confined to distinct geographic patterns in the trend indicators for one constituent or for a group of related constituents. The probable source of trend patterns in nutrients and measures of oxygen in the Trinity River Basin was changes in the wastewater treatment facilities in the Dallas-Fort Worth metropolitan area. A pattern of increased concentrations of inorganic constituents in the upper Colorado River Basin resulted from emergency releases of water from the Natural Darn Lake, a salinity control structure. Trend patterns in inorganic constituents in the Rio Grande Basin were a result of increasing concentrations in the Pecos River and, to a lesser extent, the Rio Grande above the Amistad Reservoir, combined with the effects of reservoir regulation. A pattern of increasing concentrations of organic plus ammonia nitrogen and ammonia nitrogen was detected for the 1975-86 water years for stations with low concentrations (generally less than 5 milligrams per liter) of these nitrogen species. The trends were no longer evident when the period of trend analysis was extended to the 1989 water year. A positive bias in the data caused by the addition of mercuric chloride tablets to preserve nutrient samples during 1980-86 was the probable source of this trend pattern. A pattern of increasing concentrations in dissolved sulfate in the eastern part of the State was a result of a positive bias in the analytical results of a turbidimetric method of sulfate analysis. The source of a statewide pattern of increased pH in streams could not be identified.

Texas↗

USGS1973

Hydrologic Data of the Neponset and Weymouth River Basins, Massachusetts

The Neponset, Weymouth Fore, and Weymouth Back River basins occupy an area of 183 square miles in eastern Massachusetts south of Boston and Braintree, Brockton, Canton, Dedham, Dover, Foxborough, Hingham, Holbrook, Medfield, Milton, Norwood, Quincy, Randolph, Rockland, Sharon, Stoughton, Walpole, Westwood, and Weymouth. Hydrologic data presented in this report were collected during an investigation of the water resources in the areas of these basins that are upstream from tide effect or heavy urbanization. This investigation was conducted by the U.S. Geological Survey in cooperation with the Massachusetts Water Resources Commission. The data are released in order to make available to the public basic hydrologic and related information that will facilitate the planning of water-resources development and will complement an interpretive report, "Hydrology and water resources of the Neoponset and Weymouth River basins, Massachusetts" (HA-484). The well and boring data contained herein were selected from a larger group of data in order to minimize redundancy of information for intensely drilled areas. All of the data are on filed and available for inspection at the office of the U.S. Geological Survey, Water Resources Division, Boston, Massachusetts.

Massachusetts↗

USGS1995

Ground-water flow and water quality in the sand aquifer of Long Beach Peninsula, Washington

This report describes an investigation of ground-water flow and water quality in the sand aquifer of the Long Beach Peninsula. The peninsula is located in the southwestern corner of the State of Washington, is about 27 miles long, and has an average width of about 1.5 miles. It is surrounded by seawater, by the Pacific Ocean on the west and Willapa Bay on the east. Water supplies on the peninsula are derived mostly from a local water-table aquifer composed largely of sand. The recent growth of population on the peninsula and the projected future growth have created concerns about the quantity and quality of the ground-water resource. Some issues include declining ground-water levels from increased pumpage, and ground-water contamination from seawater intrusion, pesticides or fertilizers from cranberrygrowing areas, and septic-system effluent. The ground-water system of the Long Beach Peninsula consists of a sand aquifer with some lenses of silt and clay that may act as confining beds in local areas. Data are lacking or inconsistent to define a confining bed that extends throughout the peninsula. Hydraulic conductivity calculated from slug tests in 58 shallow wells ranged from 10 to 37 feet per day with a median of 22 feet per day. Average annual ground-water recharge by infiltration and percolation of precipitation is estimated to be about 58 inches or 111,000 acre-feet, which is 72 percent of the average annual precipitation of 80 inches. Average annual ground-water discharge is estimated to be about 30,200 acre-feet to the Pacific Ocean, 56,000 acre-feet to Willapa Bay, and 24,800 acre-feet to surface-water drainage channels. Ground-water movement is generally perpendicular to the spine of the peninsula. A ground-water divide occurs along a north-south line and ground water flows west or east from the divide toward the Pacific Ocean or Willapa Bay. There does not appear to have been any long-term decline of the water table of the sand aquifer from 1974-92. Ground-water levels measured at three east-west cross sections in 1974-75 were at about the same altitude as water levels measured in 1992. Relatively accurate individual regression relations were developed at 45 wells with ground-water altitude as a response variable and cumulative precipitation for 4 months as an explanatory variable. The average coefficient of determination for all individual relations was 0.77, with a range of 0.11 to 0.89. Some empirical frequency or probability relations for precipitation and ground-water levels were used to estimate how often the maximum water levels measured in this study would be expected to occur in the future. These water levels reflected the lower-than-average precipitation that occurred during the study. Assuming that the annual maximum precipitation for 4 consecutive months is random and independent, the historical record of precipitation is representative of the future distribution of precipitation, and the relation between precipitation and water levels is accurate and stationary; a probability analysis of the historical record indicates that in any one year in the future there is a probability of 70 percent that the maximum water levels measured in wells during the winter of 1991-92 would be equaled or exceeded. The shallow ground water had generally low dissolved-solids concentrations in July 1992, with a median concentration of 92 milligrams per liter (mg/L) and a range of 56 to 218 mg/L. Sodium was the dominant cation and bicarbonate was the dominant anion. The distribution of hardness of the water samples was 84 percent with soft water and 16 percent with moderately hard water. The water quality of the shallow ground water was generally good, with a few small to moderate problems. A natural problem is locally high concentrations of dissolved iron. About 30 percent of the water samples had dissolved-iron concentrations of greater than 0.3 mg/L, which is the secondary maximum contaminant level established by the U.S. Environmental Protection Agency. No appreciable amount of seawater has intruded into the sand aquifer. The samples of shallow ground water collected in July 1992 had a median chloride concentration of 15 mg/L and a maximum concentration of 52 mg/L. The heavy average annual precipitation of about 80 inches, large average annual ground-water recharge of about 58 inches or 111,000 acre-feet, and small ground-water withdrawal rate (about 780 acre-feet per year in 1992) combine to maintain a thick freshwater lens of ground water that prevents seawater intrusion throughout the year. Agricultural activities do not appear to have appreciably affected the quality of shallow ground water on the Long Beach Peninsula. The concentration of nitrate in ground water was not significantly higher near cranberry-growing areas, and no sample of ground water or surface water had concentrations of selected pesticides or associated compounds that were above the analytical detection limits. Of the seven ground-water samples in which bacteria were detected, only one sample appeared to be related to agriculture; that sample was from a well located in an area where cattle graze for part of the year. Septic systems probably caused an increase in the concentration of nitrate in shallow ground water in areas of higher population density. Concentrations of nitrate were significantly related to population density. However, the concentrations were not generally high; median concentrations of nitrate increased from less than 0.05 mg/L in areas of low population density to 0.74 mg/L in areas of high density. Septic systems did not cause regional bacterial contamination of the ground water. Bacteria were detected in seven ground-water samples; however, only two of those samples were from wells that are close to septic systems. A limited amount of historical water-quality data is available for the peninsula; therefore, it is difficult to assess long-term changes. From 1968-92, chloride concentrations and values of specific conductance appear to have remained stable. Likewise, it appears that nitrate concentrations did not change from 1987-92.

Washington↗

USGS1998

Methods for comparing water-quality conditions among National Water-Quality Assessment Study Units, 1992-1995

The National Water-Quality Assessment is based on intensive investigations of stream and ground-water quality in selected major hydrologic basins (study units) of the United States. One objective of the national assessment is to comparatively evaluate water-quality conditions within and among the different study units. Methods were developed to compare the water-quality conditions of 20 study units that were studied during 1992-1995. Two approaches were taken: (1) water-quality conditions for each study unit were ranked in relation to the findings for all study units, and (2) water-quality conditions for each study unit were compared to established criteria for the protection of human health and aquatic life. Separate rankings were developed for several major characteristics of water quality by using selected combinations of measured values for individual constituents or properties. The water-quality characteristics that were evaluated for streams were nutrients and pesticides in water, organochlorine pesticides and polychlorinated biphenyls in bed sediment and tissue, semivolatile organic compounds and trace elements in bed sediment, fish community degradation, and stream habitat degradation. The water-quality characteristics that were evaluated for ground water were nitrate, pesticides, volatile organic compounds, dissolved solids, and radon. The water-quality rankings are relative strictly to the distribution of conditions measured at sampling sites included in developing the method. Sites in the first 20 National Water-Quality Assessment study units include a broad range of environmental settings, but are not a statistically representative sample of the Nation. > To supplement the relative rankings, established water-quality criteria were used to indicate where particular constituents may have adverse effects, and thus merit further investigation. Established water-quality criteria, which provide consistent benchmarks for national comparisons of individual constituents, were selected from a variety of sources and applied to specific constituents in the specific medium (water or sediment) appropriate for each criterion.

Open-File Report↗

USGS1983

Hydrology of an abandoned coal-mining area near McCurtain, Haskell County, Oklahoma

Water quality was investigated from October 1980 to May 1983 in an area of abandoned coal mines in Haskell county, Oklahoma. Bedrock in the area is shale, siltstone, sandstone, and the McAlester (Stigler) and Hartshorne coals of the McAlester Formation and Hartshorne Sandstone of Pennsylvanian age. The two coal beds, upper and lower Hartshorne, associated with the Hartshorne Sandstone converge or are separated by a few feet or less of bony coal or shale in the McCurtain area. Many small faults cut the Hartshorne coal in all the McCurtain-area mines. The main avenues of water entry to and movement through the bedrock are the exposed bedding-plane openings between layers of sandstone, partings between laminae of shale, fractures and joints developed during folding and faulting laminae of shale, fractures and joints developed during folding and faulting of the brittle rocks, and openings caused by surface mining--the overburden being shattered and broken to form spoil. Water-table conditions exist in bedrock and spoil in the area. Mine pond water is in direct hydraulic connections with water in the spoil piles and the underlying Hartshorne Sandstone. Sulfate is the best indicator of the presence of coal-mine drainage in both surface and ground water in the Oklahoma coal field. Median sulfate concentrations for four sites on Mule Creek ranged from 26 to 260 milligrams per liter. Median sulfate concentrations increased with increased drainage from unreclaimed mined areas. The median sulfate concentration in Mule Creek where it drains the reclaimed area is less than one-third of that at the next site downstream where the stream begins to drain abandoned (unreclaimed) mine lands. Water from Mule Creek predominantly is a sodium sulfate type. Maximum and median values for specific conductance and concentrations of calcium, magnesium, sodium, sulfate, chloride, dissolved solids, and alkalinity increase as Mule Creek flows downstream and drains increasing areas of abandoned (unreclaimed) mining lands. Constituent concentrations in Mule Creek, except those for dissolved solids, iron, manganese, and sulfate, generally do not exceed drinking-water limits. Reclamation likely would result in decreased concentrations of dissolved solids, calcium, magnesium, sodium, sulfate, and alkalinity in Mule Creek in the vicinity of the reclaimed area. Ground water in the area is moderately hard to very hard alkaline water with a median pH of 7.2 to 7.6. It predominately is a sodium sulfate type and, except for dissolved solids, iron manganese, and sulfate, constituent concentrations generally do not exceed drinking-water limits. Ground-water quality would likely be unchanged by reclamation. The quality of water in the two mine ponds is quite similar to that of the shallow ground water in the area. Constituents in water from both ponds generally do not exceed drinking-water limits and the water quality is unlikely to be changed by reclamation in the area.

Water-Resources Investigations Report↗

USGS2006

Use of DNA markers for investigating sources of bacteria in contaminated ground water: Wooster Township, Wayne County, Ohio

In 2004, a public-health nuisance was declared by the Wayne County Board of Health in the Scenic Heights Drive-Batdorf Road area of Wooster Township, Wayne County, Ohio, because of concerns about the safety of water from local wells. Repeated sampling had detected the presence of fecal-indicator bacteria and elevated nitrate concentrations. In June 2006, the U.S. Geological Survey (USGS), in cooperation with the Ohio Environmental Protection Agency (Ohio EPA), collected and analyzed samples from some of the affected wells to help investigate the possibility of human-origin bacterial contamination. Water samples from 12 wells and 5 home sewage-treatment systems (HSTS) were collected. Bromide concentrations were determined in samples from the 12 wells. Samples from 5 of the 12 wells were analyzed for wastewater compounds. Total coliform, enterococci and Escherichia coli (E. coli) bacteria concentrations were determined for samples from 8 of the 12 wells. In addition, two microbial source-tracking tools that employ DNA markers were used on samples from several wells and a composite sample of water from five septic tanks. The DNA markers from the Enterococcus faecium species and the order Bacteroidales are associated with specific sources, either human or ruminant sources. Bromide concentrations ranged from 0.04 to 0.18 milligrams per liter (mg/L). No wastewater compounds were detected at concentrations above the reporting limits. Samples from the 12 wells also were collected by Ohio EPA and analyzed for chloride and nitrate. Chloride concentrations ranged from 12.6 to 61.6 mg/L and nitrate concentrations ranged from 2.34 to 11.9 mg/L (as N). Total coliforms and enterococci were detected in samples from 8 wells, at concentrations from 2 to 200 colony-forming units per 100 milliliters (CFU/100 mL) and 0.5 to 17 CFU/100 mL, respectively. E. coli were detected in samples from three of the eight wells, at concentrations of 1 or 2 CFU/100 mL. Tests for the human-specific marker of enterococci, the esp gene, were negative in the seven samples tested, including the composite sample of HSTS water. DNA with the general Bacteroidales marker was detected in samples from four wells, but the tests for both the human- and ruminant-associated markers were negative. The presence of the PCR (polymerase chain reaction) -detectable DNA for the general fecal Bacteroidales marker is indicative of fecal contamination and recently recharged water.

Ohio↗

USGS1962

Data on wells in the Edwards Air Force Base area, California

The data presented In this report were collected by the U.S. Geological Survey as a phase of the investigation of ground-water geology and hydrology of the Edwards Air Force Base area. The study was made in cooperation with the Department of the Air Force but also was coincident with the U.S. Geological Survey investigation of water wells and general hydrologic conditions throughout much of the desert region of southern California. The overall study of general hydrologic conditions in the desert is part of a cooperative program with the California Department of Water Resources.

California↗

USGS2008

Application of multiple isotopic and geochemical tracers for investigation of recharge, salinization, and residence time of water in the Souss-Massa aquifer, southwest of Morocco

Groundwater and surface water in Souss-Massa basin in the west-southern part of Morocco is characterized by a large variation in salinity, up to levels of 37 g L-1. The high salinity coupled with groundwater level decline pose serious problems for current irrigation and domestic water supplies as well as future exploitation. A combined hydrogeologic and isotopic investigation using several chemical and isotopic tracers such as Br/Cl, ??18O, ??2H, 3H, 87Sr/86Sr, ??11B, and 14C was carried out in order to determine the sources of water recharge to the aquifer, the origin of salinity, and the residence time of water. Stable isotope, 3H and 14C data indicate that the high Atlas mountains in the northern margin of the Souss-Massa basin with high rainfall and low ??18O and ??2H values (-6 to -8??? and -36 to -50???) is currently constitute the major source of recharge to the Souss-Massa shallow aquifer, particularly along the eastern part of the basin. Localized stable isotope enrichments offset meteoric isotopic signature and are associated with high nitrate concentrations, which infer water recycling via water agricultural return flows. The 3H and 14C data suggest that the residence time of water in the western part of the basin is in the order of several thousands of years; hence old water is mined, particularly in the coastal areas. The multiple isotope analyses and chemical tracing of groundwater from the basin reveal that seawater intrusion is just one of multiple salinity sources that affect the quality of groundwater in the Souss-Massa aquifer. We differentiate between modern seawater intrusion, salinization by remnants of seawater entrapped in the middle Souss plains, recharge of nitrate-rich agricultural return flow, and dissolution of evaporate rocks (gypsum and halite minerals) along the outcrops of the high Atlas mountains. The data generated in this study provide the framework for a comprehensive management plan in which water exploitation should shift toward the eastern part of the basin where current recharge occurs with young and high quality groundwater. In contrast, we argued that the heavily exploited aquifer along the coastal areas is more vulnerable given the relatively longer residence time of the water and salinization processes in this part of the aquifer. ?? 2008 Elsevier B.V. All rights reserved.

Journal of Hydrology↗

USGS2002

Dynamic interpretation of slug tests in highly permeable aquifers

Considerable progress has been made in developing a theoretical framework for modeling slug test responses in formations with high hydraulic conductivity K . However, several questions of practical significance remain unresolved. Given the rapid and often oscillatory nature of test responses, the traditional hydrostatic relationship between the water level and the transducer‐measured head in the water column may not be appropriate. A general dynamic interpretation is proposed that describes the relationship between water level response and transducer‐measured head. This theory is utilized to develop a procedure for transforming model‐generated water level responses to transducer readings. The magnitude of the difference between the actual water level position and the apparent position based on the transducer measurement is a function of the acceleration and velocity of the water column, test geometry, and depth of the transducer. The dynamic approach explains the entire slug test response, including the often‐noted discrepancy between the actual initial water level displacement and that measured by a transducer in the water column. Failure to use this approach can lead to a significant underestimation of K when the transducer is a considerable distance below the static water level. Previous investigators have noted a dependence of test responses on the magnitude of the initial water level displacement and have developed various approximate methods for analyzing such data. These methods are re‐examined and their limitations clarified. Practical field guidelines are proposed on the basis of findings of this work. The soundness of the dynamic approach is demonstrated through a comparison of K profiles from a series of multilevel slug tests with those from dipole‐flow tests performed in the same wells.

Water Resources Research↗