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Vestiges of an Iapetan rift basin in the New Jersey Highlands: Implfications for the Neoproterozoic Laurentian margin

Thin, discontinuous remnants of Neoproterozoic intracratonic rift-basin deposits of the Chestnut Hill Formation occur in the western New Jersey Highlands. These deposits form an important link between well-documented Iapetan rift-basins in both the northern and southern Appalachians. The close spatial relations of Chestnut Hill rocks to Paleozoic sedimentary rocks open the possibility that additional Iapetan rift-basins could be concealed beneath the rocks of the Valley and Ridge Province to the west indicating a much broader zone of rifting than has been previously proposed. The Chestnut Hill Formation is intermittently exposed along a 100 km-long band that extends northeast from Pennsylvania nearly to New York State. The lower part of the Chestnut Hill Formation is composed of interbedded lithic pebble- to boulder-conglomerate and feldspathic sandstone grading upward into interbedded phyllite, feldspathic and quartz sandstone, local paleosaprolite, quartz-pebble conglomerate, thin limestone lenses, volcanic, and volcaniclasic rocks, abundant bedded ironstone (hematite ore), and ultimately into diamictites that are interpreted as possible tilloids and containing rounded intra and extrabasinal clasts of the other lithologies. Extensive soft-sediment deformation, cross bedding, and clastic dikes are common in all but the lowest and upper facies. Banded hematite layers occur preferentially in fine-grained tuffs and tuffaceous sediments, but hematitization has affected most lithologies. Volcanic rocks consist of altered rhyolitic tuffs and lapilli tuffs that are interbedded with sediments. The Chestnut Hill Formation is interpreted to have been deposited in early alluvial, and later a complex of fluvial, lacustrine and deltaic environments. Provenance studies based upon petrographic and geochemical analysis of clastic rocks indicate that the sediments are predominantly immature and reflect derivation from local uplifted felsic basement sources in a rifted-margin tectonic setting. Low to moderate weathering of the source rocks is indicated by the geochemistry of most samples, as is the locally intense effect of hydrothermal alteration. Most occurrences of the Chestnut Hill Formation are associated with major faults that exhibit normal movement of apparent Neoproterozoic age. Rocks from the Morgan Hill fault near Easton, Pennsylvania display consistent normal shear sense and vary from low temperature S-C mylonites to breccia that contains deformed pieces of Chestnut Hill Formation. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics↗

Testing a high-resolution satellite interpretation technique for crop area monitoring in developing countries

District-level crop area (CA) is a highly uncertain term in food production equations, which are used to allocate food aid and implement appropriate food security initiatives. Remote sensing studies typically overestimate CA and production, as subsistence plots are exaggerated at coarser resolution, which leads to overoptimistic food reports. In this study, medium-resolution (MR) Landsat 7 Enhanced Thematic Mapper Plus (ETM+) images were manually classified for Niger and corrected using CA estimates derived from high-resolution (HR) sample image, topographic and socioeconomic data. A logistic model with smoothing splines was used to compute the block-average (0.1°) probability of an area being cropped. Livelihood zones and elevation explained 75% of the deviance in CA, while MR did not add explanatory power. The model overestimates CA when compared to the national inventory, possibly because of temporal changes in intercropping and the exclusion of some staple crops in the national inventory.

International Journal of Remote Sensing↗

The crystal structure of cesium biuranyl trisulphate, Cs2(UO2)2(SO4)3

The crystal structure of the new compound Cs(UO 2 ) 2 (SO 4 ) 3 has been determined by X-ray diffraction methods. The compound is tetragonal, space group P 4 2 1 m "> P42 1 m ( D 2 d 3 ), with a = 9·62 ± 0·02, c = 8·13 ± 0·01 A ̊ "> c = 8·13 ± 0·01Å , and Z = 2; s.g. (calc.) = 4·80 ± 0·03, s.g. (obs.) = 4·74 ± 0·05. The compound forms plates parallel to (001) bounded by the form (110). Intensity data were obtained from Buerger precession photographs of the ( hk 0) and (0 kl ) reciprocal lattice nets. No corrections for absorption were made. The co-ordinates of the U and Cs atoms were obtained by interpretation of the Patterson projections normal to (001) and (100) and a plausible structure was derived from electron density projections. The final parameters of the structure were determined from subtraction electron density maps, least squares analysis of the structure factors, and spatial considerations. The compound has a layer structure consisting of (UO 2 ) 2 (SO 4 ) 3 ] n 2 n − sheets paralle to (001), tied together by cesium ions. The UO 2 2+ group is co-ordinated by five sulphate oxygens which form a nearly plane pentagon approximately normal to the uranyl axis. The Cs 2 atom is co-ordinated by twelve oxygen atoms and the Cs 1 atom by eight oxygen atoms. X-ray and optical data are also given for the compound Rb 2 UO 2 (SO 4 ) 2 ·2H 2 O.

Journal of Inorganic and Nuclear Chemistry↗

Tar yields from low-temperature carbonization of coal facies from the Powder River Basin, Wyoming, USA

Tar yields from low-temperature carbonization correlate with the amount of crypto-eugelinite in samples selected to represent petrographically distinct coal facies of the Wyodak-Anderson coal zone. Tar yields from Fischer Assay range from <1 to 11 wt.% on a dry basis and correspond ( r = 0.72) to crypto-eugelinite contents of the coal that range from 15 to 60 vol.%. Core and highwall samples were obtained from active surface mines in the Gillette field, Powder River Basin, Wyoming. Because the rank of the samples is essentially the same, differences in low-temperature carbonization yields are interpreted from compositional differences, particularly the crypto-eugelinite content. In the Wyodak-Anderson coal zone, crypto-eugelinite probably was derived from degraded humic matter which absorbed decomposition products from algae, fungi, bacteria, and liptinitic plant parts (materials possibly high in hydrogen). Previous modeling of the distribution of crypto-eugelinite in the discontinuous Wyodak-Anderson coal zone indicated that tar yields should be greater from coal composing the upper part and interior areas than from coal composing the lower parts and margins of the individual coal bodies. It is possible that hydrocarbon yields from natural coalification processes would be similar to yields obtained from laboratory pyrolysis. If so, the amount of crypto-eugelinite may also be an important characteristic when evaluating coal as source rock for migrated hydrocarbons.

Wyoming↗

Development of web-based organic petrology photomicrograph atlases and internet resources for professionals and students

With advances in web applications, organic petrography and other related disciplines are in need of updated online resources and educational tools to aid professionals and students in the identification and interpretation of macerals. The U.S. Geological Survey (USGS) Organic Petrology Laboratory along with USGS Eastern Energy Resources Science Center Information Technology staff have developed five web atlases containing images of organic matter in geologic materials: 1. an American Society for Testing and Materials (ASTM) Atlas, 2. an Organic Petrology Taxonomy for International Classification (OPTIC) of Coal Macerals Atlas, 3. an Interactive Gulf Coast Photomicrograph Web Atlas (I-Map), 4. an Organic Material in Shales Atlas (Shale), and 5. an interactive Blue/White/Ultraviolet (UV) Light Atlas (Light). Each web atlas contains images of macerals with associated sample and petrographic data collected by the USGS. These webpages will provide means to preserve and circulate petrographic data collected by the USGS for coal and shale samples from all over the world.

International Journal of Coal Geology↗

Interferometric synthetic aperture radar study of recent eruptive activity at Shrub mud volcano, Alaska

Shrub mud volcano is one of three large mud volcanoes that comprise the Klawasi Group in the Copper River Basin of southcentral Alaska. Except for minor discharges in the mid-1950s when the group was first described, Shrub was dormant prior to its reactivation in summer 1996. From 1997 to 1999, Shrub vigorously erupted more than 5 x 105 cubic meters of saline mud and carbon dioxide-rich gas at temperatures as high as 54 degrees C. Thereafter, activity waned but continued at least through 2015. We analyzed 192 interferograms derived from 106 synthetic aperture radar (SAR) images acquired by the JERS-1 (L-band), ERS-1/2 (C-band), RADARSAT-1 (C-band), and ALOS PALSAR (L-band) satellites to characterize ground deformation at Shrub before, during, and after its reactivation. Collectively, the interferograms span 1992–2000 and 2006–2011. We fit the observations with two deformation sources: a deflating, steeply dipping, pipe-like body under the summit area and an inflating, shallow-dipping, sill-like body under the southwest flank. Both sources are shallow, with centroids less than 1 km beneath the summit. Prior to reactivation, the flank source inflated ~0.35 x 105 cubic meters per year from July 1992 to May 1996. During eruptive activity, the summit source deflated at higher rates that peaked at ~8.71 x 105 cubic meters per year during May–November 1997 and continued at ~0.95 x 105 cubic meters per year during the 2006–2011 observation window. Cumulative source-volume loss is comparable to the volume of mud erupted. We interpret the summit source as the volcano’s feeder conduit that pressurized prior to the first SAR observation in 1992. Also before 1992, the conduit ruptured to feed a lateral intrusion of mud under the southwest flank, perhaps along a bedding plane in underlying glaciolacustrine deposits. The growing sill caused the southwest flank to inflate while it accommodated the mud supply from depth, which explains why we observed pre-eruptive inflation of the flank but not the summit. The summit began deflating when the conduit ruptured to the surface at the onset of eruptive activity. The flank source did not deflate concurrently because the weight of the thin overburden was insufficient to collapse the sill. There is a suggestion in the modern topography that lateral intrusions under Shrub’s southwest flank are a common feature of activity there.

Alaska↗

Scientific results of the Hydrate-01 Stratigraphic Test Well Program, Western Prudhoe Bay Unit, Alaska North Slope

The United States Department of Energy, the MH21-S Research Consortium of Japan, and the United States Geological Survey are collaborating to enable gas hydrate scientific drilling and extended-duration reservoir response testing on the Alaska North Slope. To feasibly execute such a test, a location is required that is accessible from existing roads and gravel pads and that can be occupied without disrupting ongoing industry operations. A review of potential locations meeting these criteria determined the likely occurrence of gas hydrate in two fine-grained marginal-marine sands of Tertiary age in the vicinity of the inactive “Kuparuk State 7-11-12” exploration pad in the western Prudhoe Bay Unit (PBU). Existing well and seismic data for that site were insufficient to preclude the potential for free gas occurrence within the deeper (and most prospective) target sand. Therefore, with support from the PBU Working Interest Owners, Alaska Department of Natural Resources, and Petrotechnical Resources Alaska, the Hydrate-01 Stratigraphic Test Well (STW) was drilled in December 2018 to confirm the suitability of the site for future gas hydrate scientific testing. The Hydrate-01 well was successfully drilled to −3290 ft (1003 m) subsea vertical depth at a bottom hole location of approximately 900 ft (∼275 m) east of the surface location. The drilling program featured acquisition of a full suite of logging while drilling data, the collection of side-wall pressure cores, and the installation of distributed temperature and distributed acoustic sensor fiber-optic cables. The log data acquired confirmed the occurrence of gas hydrate at high saturation in two target sands. Integrated evaluation of log and sidewall core data provide petrophysical and geomechanical property information that allow for potential reservoir response to depressurization to be simulated. The deeper “B1 sand” is deemed to be most favorable for reservoir response testing as a result of confirmed gas hydrate occurrence in sediments of high intrinsic permeability, location within 100 ft (30 m) of the base of gas hydrate stability, and minimal risk for direct communication with permeable water-bearing (hydrate-free) zones. The shallower “D1 sand” provides a secondary target that is differentiated by colder in situ temperatures and the interpreted direct hydraulic communication to a lower section of non-hydrate-bearing, water-saturated sand. The Hydrate-01 log data also confirm the occurrence of at least one sub-seismic fault in close proximity to the B1 sand reservoir. To better image the distribution of the gas-hydrate-bearing reservoir sections and associated faults, a three-dimensional (3D) vertical seismic profile was conducted in early 2019 using the distributed acoustic sensors installed as part of the Hydrate-01 STW completion. Detailed two-dimensional (2D) and 3D geologic models have been constructed to enable numerical simulations to inform the planning for potential future scientific tests of reservoir response to depressurization at the site.

Alaska↗

Paleoproterozoic metamorphism in the northern Wyoming province: Implications for the assembly of Laurentia

U-Pb ages measured on zircons from the Tobacco Root Mountains and monazite from the Highland Mountains indicate that the northwestern Wyoming province experienced an episode of high-grade metamorphism at ???1.77 Ga. Leucosome emplaced in Archean gneisses from the Tobacco Root Mountains contains a distinctive population of zircons with an age of 1.77 Ga but also contains zircons to ???3.5 Ga; it is interpreted to have been derived primarily by anatexis of nearby Archean schist. A granulite facies mafic dike that cuts across Archean gneissic banding in the Tobacco Root Mountains contains two distinct populations of zircons. A group of small (<50 ??m) nonprismatic grains is interpreted to be metamorphic and yields an age of 1.76 Ga; a group of slightly larger prismatic grains yields an age of 2.06 Ga, which is interpreted to be the time of crystallization of the dike. Monazite from a leucogranite from the Highland Mountains yields a well-defined age of 1.77 Ga, which is interpreted as the time of partial melting and emplacement of the leucogranite. These results suggest that the northwestern Wyoming province, which largely lies within the western part of the Great Falls tectonic zone, experienced a metamorphic maximum at 1.77 Ga. This age is ???100 m.yr. younger than the proposed time of Wyoming-Hearne collision in the central Great Falls tectonic zone (1.86 Ga) and suggests that the northwestern Wyoming province may have been involved in a separate, younger collisional event at ???1.77 Ga. An event at this time is essentially coeval with collisions proposed for the eastern and southeastern margins of the province and suggests a multiepisodic model for the incorporation of the Wyoming craton into Laurentia. ?? 2005 by The University of Chicago. All rights reserved.

Journal of Geology↗

Telescoping metamorphic isograds: Evidence from 40Ar/39A dating in the Orange-Milford belt, southern Connecticut

New 40 Ar/ 39 Ar ages for hornblende and muscovite from the Orange-Milford belt in southern Connecticut reflect cooling from Acadian amphibolite facies metamorphism between ∼380 to 360 Ma followed by retrograde recrystallization of fabric-forming muscovite and chlorite during lower greenschist facies Alleghanian transpression at ∼280 Ma. Reported field temperature and pressure gradients are improbably high for these rocks and a NW metamorphic field gradient climbing from chlorite-grade to staurolite-grade occurs over less than 5 km. Simple tilting cannot account for this compressed isograd spacing given the geothermal gradient of ∼20 °C/km present at the time of regional metamorphism. However, post-metamorphic transpression could effectively telescope the isograds by stretching the belt at an oblique angle to the isograd traces. Textures in the field and in thin section reveal several older prograde schistosities overprinted by lower greenschist facies fabrics. The late cleavages commonly occur at the scale of ∼100 μm and these samples contain multiple age populations of white mica. 40 Ar/ 39 Ar analysis of these poly-metamorphic samples with mixed muscovite populations yield climbing or U-shaped age spectra. The ages of the low temperature steps are late Paleozoic, while the ages of the older steps are late Devonian. These results support our petrologic interpretation that the younger cleavage developed under metamorphic conditions below the closure temperature for Ar diffusion in muscovite, that is, in the lower greenschist facies. The correlation of a younger regionally reproducible age population with a pervasive retrograde muscovite ± chlorite cleavage reveals an Alleghanian (∼280 Ma) overprint on the Acadian metamorphic gradient (∼380 Ma). Outcrop-scale structures including drag folds and imbricate boudins suggest that Alleghanian deformation and cleavage development occurred in response to dextral transpression along a northeast striking boundary. Alleghanian oblique collision of accreting terranes from the northeast would have resulted in northeast-southwest dextral transpression against the New York promontory. This deformation was responsible for crystallization of pervasive retrograde muscovite + chlorite cleavages and associated telescoping of the Acadian metamorphic isograds in southern Connecticut at ∼280 Ma.

Connecticut↗

An automated approach to detecting signals in electroantennogram data

Coupled gas chromatography/electroantennographic detection (GC-EAD) is a widely used method for identifying insect olfactory stimulants present in mixtures of volatiles, and it can greatly accelerate the identification of insect semiochemicals. In GC-EAD, voltage changes across an insect's antenna are measured while the antenna is exposed to compounds eluting from a gas chromatograph. The antenna thus serves as a selective GC detector whose output can be compared to that of a "general" GC detector, commonly a flame ionization detector. Appropriate interpretation of GC-EAD results requires that olfaction-related voltage changes in the antenna be distinguishable from background noise that arises inevitably from antennal preparations and the GC-EAD-associated hardware. In this paper, we describe and compare mathematical algorithms for discriminating olfaction-generated signals in an EAD trace from background noise. The algorithms amplify signals by recognizing their characteristic shape and wavelength while suppressing unstructured noise. We have found these algorithms to be both powerful and highly discriminatory even when applied to noisy traces where the signals would be difficult to discriminate by eye. This new methodology removes operator bias as a factor in signal identification, can improve realized sensitivity of the EAD system, and reduces the number of runs required to confirm the identity of an olfactory stimulant. ?? 2007 Springer Science+Business Media, LLC.

Journal of Chemical Ecology↗

Remotely sensed geology from lander-based to orbital perspectives: Results of FIDO rover May 2000 field tests

Blind field tests of the Field Integration Design and Operations (FIDO) prototype Mars rover were carried out 7-16 May 2000. A Core Operations Team (COT), sequestered at the Jet Propulsion Laboratory without knowledge of test site location, prepared command sequences and interpreted data acquired by the rover. Instrument sensors included a stereo panoramic camera, navigational and hazard-avoidance cameras, a color microscopic imager, an infrared point spectrometer, and a rock coring drill. The COT designed command sequences, which were relayed by satellite uplink to the rover, and evaluated instrument data. Using aerial photos and Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data, and information from the rover sensors, the COT inferred the geology of the landing site during the 18 sol mission, including lithologic diversity, stratigraphic relationships, environments of deposition, and weathering characteristics. Prominent lithologic units were interpreted to be dolomite-bearing rocks, kaolinite-bearing altered felsic volcanic materials, and basalt. The color panoramic camera revealed sedimentary layering and rock textures, and geologic relationships seen in rock exposures. The infrared point spectrometer permitted identification of prominent carbonate and kaolinite spectral features and permitted correlations to outcrops that could not be reached by the rover. The color microscopic imager revealed fine-scale rock textures, soil components, and results of coring experiments. Test results show that close-up interrogation of rocks is essential to investigations of geologic environments and that observations must include scales ranging from individual boulders and outcrops (microscopic, macroscopic) to orbital remote sensing, with sufficient intermediate steps (descent images) to connect in situ and remote observations.

Journal of Geophysical Research E: Planets↗

Preeruptive inflation and surface interferometric coherence characteristics revealed by satellite radar interferometry at Makushin Volcano, Alaska: 1993-2000

Pilot reports in January 1995 and geologic field observations from the summer of 1996 indicate that a relatively small explosive eruption of Makushin, one of the more frequently active volcanoes in the Aleutian arc of Alaska, occurred on 30 January 1995. Several independent radar interferograms that each span the time period from October 1993 to September 1995 show evidence of ???7 cm of uplift centered on the volcano's east flank, which we interpret as preeruptive inflation of a ???7-km-deep magma source (??V = 0.022 km3). Subsequent interferograms for 1995-2000, a period that included no reported eruptive activity, show no evidence of additional ground deformation. Interferometric coherence at C band is found to persist for 3 years or more on lava flow and other rocky surfaces covered with short grass and sparsely distributed tall grass and for at least 1 year on most pyroclastic deposits. On lava flow and rocky surfaces with dense tall grass and on alluvium, coherence lasts for a few months. Snow and ice surfaces lose coherence within a few days. This extended timeframe of coherence over a variety of surface materials makes C band radar interferometry an effective tool for studying volcano deformation in Alaska and other similar high-latitude regions.

Journal of Geophysical Research B: Solid Earth↗

A seismic refraction survey of the Imperial Valley Region, California

The U.S. Geological Survey conducted an extensive seismic refraction survey in the Imperial Valley region of California in 1979. The Imperial Valley is located in the Salton Trough, an active rift between the Pacific and North American plates. Forty shots fired at seven shot points were recorded by 100 portable seismic instruments at typical spacing of 0.5–1 km. More than 1300 recording locations were occupied, and more than 3000 usable seismograms were obtained. We analyzed five profiles using a standard ray‐tracing program, constructed a contour map of reduced travel times from our most widely recorded shot point, and modeled an existing gravity profile across the Salton Trough. Results are itemized: (1) All models have in common a sedimentary layer ( V p = 1.8–5.0 km/s), a “transition zone” ( V p = 5.0–5.65 km/s), a basement ( V p = 5.65 km/s in the Imperial Valley, 5.9 km/s on the bordering mesas), and subbasement ( V p = 7.2 km/s). (2) The sedimentary layer ranges in thickness along the axis of the Salton Trough from 3.7 km (Salton Sea) to 4.8 km (U.S.‐Mexican border). On the bordering mesas it is quite variable in thickness. (3) The “transition” zone is about 1 km thick in most places. In the Imperial Valley there are no marked velocity discontinuities in this zone between the sedimentary layer and basement. On the bordering mesas, however, there is a discontinuity at the top of this zone. (4) There are apparently two types of basement. On the bordering mesas, basement is crystalline igneous and metamorphic rocks. In the Imperial Valley, basement is mostly lower‐greenshist‐facies sedimentary rocks, based primarily on the smooth transition in character from sediment to basement arrivals, the low value of basement velocity, and the fact that deep (4 km) wells in the valley penetrate only the upper part of the known Cenozoic stratigraphic column for the Salton Trough. (5) The subbasement, or intermediate crustal layer, ranges in depth along the axis of the Salton Trough from 16 km (Salton Sea) to 10 km (U.S.‐Mexican border). Gravity modeling requires that this layer deepen and/or pinch out beneath the bordering mesas and mountain ranges. Based on its high velocity and the presence of intrusive basaltic rocks in the sedimentary section in the Imperial Valley, the subbasement is thought to be a mafic intrusive complex similar to oceanic middle crust. (6) Several structures are seen that affect basement, transition zone, and deeper parts of the sedimentary layer. They include a scarp along the Imperial fault, as much as 1 km down to the northeast, and a scarp passing roughly along the topographic boundary between the Imperial Valley and the bordering mesa to the west, as much as 3½ km down to the east. We interpret the latter scarp to be the suture, or rift boundary, between the older crystalline basement on the mesa and the younger metasedimentary basement in the Imperial Valley. (7) On a contour map of reduced travel time from our most widely recorded shot point, subtle patches of early arrivals among otherwise late arrivals in the central Imperial Valley correlate well with known geothermal resource areas having reservoir temperatures of more than 150°C. Apparently the Salton Trough is a location where new crust is being generated. As the rift opens, mafic intrusive rocks fill it from below as sedimentary rocks fill it from above. Rifting and intrusion produce high heat flow that metamorphoses the sedimentary rocks to shallow depth (metasedimentary basement in the Imperial Valley) and thus consolidates the new crust.

California↗

Geochemical and Pb isotopic characterization of soil, groundwater, human hair, and corn samples from the Domizio Flegreo and Agro Aversano area (Campania region, Italy)

A geochemical survey was carried out to investigate metal contamination in the Domizio Littoral and Agro Aversano area (Southern Italy) by means of soil, groundwater, human hair and corn samples. Pb isotope ratios were also determined to identify the sources of metals. Specifically, the investigation focused on topsoils ( n = 1064), groundwater ( n = 26), 25 human hair ( n = 24) and corn samples ( n = 13). Topsoils have been sampled and analysed in a previous study for 53 elements (including potentially harmful ones), and determined by ICP-MS after dissolving with aqua regia. Groundwater was analysed for 72 elements by ICP-MS and by ICP-ES. Samples of human hair were prepared and analysed for 16 elements by ICP-MS. Dried corn collected at several farms were also analysed for 53 elements by ICP-MS. The isotopic ratios of 206 Pb/ 207 Pb and 208 Pb/ 207 Pb in selected topsoil ( n = 24), groundwater ( n = 9), human hair ( n = 9) and corn ( n = 4) samples were analysed from both eluates and residues to investigate possible anthropogenic contamination and geogenic contributions. All data were processed and mapped by ArcGis software to produce interpolated maps and contamination factor maps of potentially harmful elements, in accordance with Italian Environmental Law (Legislative Decree 152/06). Results show that soil sampling sites are characterized by As, Cd, Co, Cr, Cu, Hg, Pb, Se, and Zn contents exceeding the action limits established for residential land use (RAL) and, in some cases, also the action limits for industrial land use (IAL) as established by Legislative Decree 152/06. A map of contamination factors and a map showing the degrees of contamination indicate that the areas in the municipalities of Acerra, Casoria and Giugliano have been affected by considerable anthropogenic-related pollution. To interpret the isotopic data and roughly estimate proportion of Pb from an anthropogenic source we broadly defined possible natural and anthropogenic Pb end-member fields based on literature data. For example, we summarized data for Vesuvius and Campi Flegrei volcanic rocks, gasoline, and aerosol deposits. Lead isotope data show mixing between geogenic and anthropogenic sources. Topsoil, groundwater, human hair and corn samples show a greater contribution from geogenic sources like the Yellow Tuff (from Campi Flegrei) and volcanic rocks from Mt. Vesuvius. Aerosols, fly ash and gasoline (anthropogenic sources) have also been contributors. In detail, 46% of the topsoil residues, 96% of topsoil leachates, 88% of groundwater, 90% of human hair, and 25% of corn samples indicate that > 50% percent of the lead in this area can be ascribed to anthropogenic activity.

Campania region↗

Fine scale habitat use by age-1 stocked muskellunge and wild northern pike in an upper St. Lawrence River bay

Radio telemetry of stocked muskellunge ( n = 6) and wild northern pike ( n = 6) was used to track late summer and fall movements from a common release point in a known shared nursery bay to test the hypothesis that age-1 northern pike and stocked muskellunge segregate and have different habitat affinities. Water depth, temperature, substrate and aquatic vegetation variables were estimated for each muskellunge ( n = 103) and northern pike ( n = 131) position and nested ANOVA comparisons by species indicated differences in habitat use. Muskellunge exhibited a greater displacement from the release point and used habitat in shallower water depths (mean = 0.85 m, SE = 0.10) than northern pike (mean = 1.45 m, SE = 0.08). Both principal components analysis (PCA) and principal components ordination (PCO) were used to interpret underlying gradients relative to fish positions in two-dimensional space. Our analysis indicated that a separation of age-1 northern pike and muskellunge occurred 7 d post-release. This first principal component explained 48% of the variation in habitat use. Northern pike locations were associated with deeper habitats that generally had softer silt substrates and dense submersed vegetation. Muskellunge locations post-acclimation showed greater association with shallower habitats containing firmer sandy and clay substrates and emergent vegetation. The observed differences in habitat use suggest that fine-scale ecological separation occurred between these stocked muskellunge and wild northern pike, but small sample sizes and potential for individual variation limit extension of these conclusions. Further research is needed to determine if these patterns exist between larger samples of fishes over a greater range of habitats.

Journal of Great Lakes Research↗

Geomorphic evidence for former lobate debris aprons at low latitudes on Mars: Indicators of the Martian paleoclimate

Circumferential depressions enclosing mesas and plateaus in the northern Kasei Valles and in the Tartarus Colles regions of Mars are interpreted as indicators of the former extent of lobate debris aprons, thought to be mixtures of ice and elastic particles. These former lobate debris aprons existed about 1 Ga ago and were embayed by lavas or other flow deposits. After the lobate debris aprons had been removed by sublimation and deflation, topographic depressions with a depth of 50 m and a width of several kilometers were left behind between the mesa or plateau scarp and the solidified flow materials. These depressions or moats are located equatorward of ??30?? at significantly lower latitudes than generally observed for occurrences of modem, intact lobate debris aprons. This observation provides evidence that the paleoclimate at that time was different than today, probably due to a higher averaged obliquity of the planet's rotational axis. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Validation of a side-scan sonar method for quantifying walleye spawning habitat availability in the littoral zone of northern Wisconsin Lakes

Previous research has generally ignored the potential effects of spawning habitat availability and quality on recruitment of Walleye Sander vitreus , largely because information on spawning habitat is lacking for many lakes. Furthermore, traditional transect-based methods used to describe habitat are time and labor intensive. Our objectives were to determine if side-scan sonar could be used to accurately classify Walleye spawning habitat in the nearshore littoral zone and provide lakewide estimates of spawning habitat availability similar to estimates obtained from a transect–quadrat-based method. Based on assessments completed on 16 northern Wisconsin lakes, interpretation of side-scan sonar images resulted in correct identification of substrate size-class for 93% (177 of 191) of selected locations and all incorrect classifications were within ± 1 class of the correct substrate size-class. Gravel, cobble, and rubble substrates were incorrectly identified from side-scan images in only two instances (1% misclassification), suggesting that side-scan sonar can be used to accurately identify preferred Walleye spawning substrates. Additionally, we detected no significant differences in estimates of lakewide littoral zone substrate compositions estimated using side-scan sonar and a traditional transect–quadrat-based method. Our results indicate that side-scan sonar offers a practical, accurate, and efficient technique for assessing substrate composition and quantifying potential Walleye spawning habitat in the nearshore littoral zone of north temperate lakes.

Wisconsin↗

Petrology of lower crustal and upper mantle xenoliths from the Cima Volcanic Field, California

Basaltic rocks of the Cima volcanic field in the southern Basin and Range province contain abundant gabbro, pyroxenite, and peridotite xenoliths. Composite xenoliths containing two or more rock types show that upper-mantle spinel peridotite was enriched by multiple dike intrusions in at least three episodes; the mantle was further enriched by intergranular and shear-zone melt infiltration in at least two episodes. The oldest dikes, now metamorphosed, are Cr-diopside websterite. Dikes of intermediate age are most abundant at Cima and consist of igneous-textured websterite and two-pyroxene gabbro and microgabbro of tholeiitic or calcalkalic parentage. The youngest dikes are igneous-textured clinopyroxenite, gabbro, and olivine microgabbro of alkalic parentage. The dikes in peridotite are interpreted as parts of a system of conduits through which tholeiitic (or calcalkalic) and alkalic magmas fed lower-crustal intrusions, which are represented by abundant xenoliths of the same igneous rock types as observed in the dikes. Mineral assemblages of dikes in peridotite indicate that an enriched uppermost mantle zone no thicker than 15 km could have been sampled. Because of their high densities, the gabbros and pyroxenites can occupy the zone immediately above the present Moho (modeled on seismic data as 10-13 km thick, with V p 6.8 km/s) only if their seismic velocities are reduced by the joints, partial melts, and fluid inclusions that occur in them. Alternatively, these xenoliths may have been derived entirely from beneath the Moho, in which case the Moho is not the local crust-mantle boundary.

Journal of Petrology↗