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Visitor and community survey results for Prime Hook National Wildlife Refuge: Completion report

This study was commissioned by the Northeast Region of the U.S. Fish and Wildlife Service (USFWS) in support of the Comprehensive Conservation Planning at Prime Hook National Wildlife Refuge (Prime Hook NWR or Refuge). The National Wildlife Refuge Improvement Act of 1997 (Public Law 105-57, USC668dd) mandates a Comprehensive Conservation Plan (CCP) for every refuge in the system. A refuge CCP outlines goals, objectives, and management strategies for all refuge programs over the next 15 years, while providing opportunities for compatible, wildlifedependent public uses. The plan evaluates refuge wildlife, habitat, land protection, and visitor service priorities during the planning process. The National Environmental Policy Act (NEPA; Public Law 91-190:852-859.42, U.S.C. and as Amended (P.L. 94-52 and P.L. 94-83) 42 U.S.C. 4321-4347) mandates that the CCP for each refuge must contain an analysis of social and economic conditions (the affected environment) and evaluate social and economic results from likely management scenarios. In addition, public review and comment on alternatives for future management is required. To that end, this research was conducted by the Policy Analysis and Science Assistance Branch (PASA) of the U.S. Geological Survey/Fort Collins Science Center in order to determine how current and proposed CCP planning strategies for Prime Hook NWR could affect: Visitor use Visitor experiences Visitor spending Community residents’ perceptions and opinions Data for this study were collected using a survey administered to visitors to Prime Hook NWR and individuals living in the communities surrounding the Refuge. Surveys were randomly distributed to both consumptive and nonconsumptive use visitors over a one year period (September 2004 to September 2005) to account for seasonal variation in Refuge use. Three hundred thirty-two visitor surveys were returned for a response rate of 80 percent with a confidence interval of ± 5.4. Surveys were also distributed to a stratified random sample of community members in adjacent and surrounding areas (Slaughter Beach, Broadkill Beach, Prime Hook Beach, Milton, Lewes, Milford, and surrounding communities). Four hundred ninety-one surveys from the overall community sample were returned for a response rate of 39 percent with a ± 4.4 confidence interval. Community member results were weighted by U.S. Census Bureau data to correct for age and gender bias, and for community proportionality.

Delaware↗

Stratigraphic sections of the Phosphoria formation in Idaho

The first of a series of reports giving detailed stratigraphic sections of the Phosphoria formation in the Western phosphate field as measured and described by the Geological Survey will be released as Circulars within the next few months. Because of the needs of industry for many of these data during the 1951 field season, and in view of the unavoidable delays attendant on publication, the tabular data to be included in these Circulars are hereby placed on open file in simple reproduction form (prepared by Ozalid from photographic negatives) and without explanatory text so that immediate use may be made of the data. The tables include data on sections in four states: Montana, Idaho, Wyoming, and Utah; and the tables for each of these states are bound together as individual reports. The tables include name and location of section measured, brief description of geologic setting, acknowledgments for field and analytical work, abstract data on the sections (bed number, rock name, sample number, and thickness), and analytical data on the samples. The analytical data include reports on P 2 O 5 and acid insoluble for all samples and additional analyses, such as Al 2 0 3 , Fe 7 0 3 , loss on ignition, F, and V 2 O 5 , for selected samples. Spectrographic analyses for a large number of elements are included samples from selected localities, and special analyses have been made of a few samples. These reports are placed on open file at the offices of the Geological Survey in Washington, D. C., Spokane, Washington, Salt Lake City, Utah, and Montpelier, Idaho, and at the offices of the Idaho Bureau of Mines and Geology, Moscow, Idaho, the Montana Bureau of Mines and Geology, Butte, Montana, and the Wyoming Geological Survey, Laramie, Wyoming, and the University of Utah, Salt Lake City, Utah.

Idaho↗

Stratigraphic sections of the Phosphoria formation in Utah

The first of a series of reports giving detailed stratigraphic sections of the Phosphoria formation in the Western phosphate field as measured and described by the Geological Survey will be released as Circulars within the next few months. Because of the needs of industry for many of these data during the 1951 field season, and in view of the unavoidable delays attendant on publication: the tabular data to be included in these Circulars are hereby placed on open file in simple reproduction form (prepared by Ozalid from photographic negatives) and without explanatory text so that immediate use may be made of the data. The tables include data on sections in four states: Montana, Idaho, Wyoming, and Utah; and the tables for each of these states are bound together as individual reports. The tables include name and location of section measured, brief description of geologic setting, acknowledgments for field and analytical work, abstract data on the sections (bed number, rock name, sample number, and thickness), and analytical data or the samples. The analytical data include reports on P 2 O 5 and acid insoluble for all samples and additional analyses, such as Al 2 0 3 , Fe 7 0 3 , loss on ignition, F, and V 2 O 5 , for selected samples. Spectrographic analyses for a large number of elements are included for samples from selected localities, and special analyses have been made of a few samples. These reports are placed on open file at the offices of the Geological Survey in Washington, D. C., Spokane, Washington, Salt Lake City, Utah, and Montpelier, Idaho, and at the offices of the Idaho Bureau of Mines and Geology, Moscow, Idaho, the Montana Bureau of Mines and Geology, Butte, Montana, and the Wyoming Geological Survey, Laramie, Wyoming, and the University of Utah, Salt Lake City, Utah.

Utah↗

ASPECTS OF ARCTIC SEA ICE OBSERVABLE BY SEQUENTIAL PASSIVE MICROWAVE OBSERVATIONS FROM THE NIMBUS-5 SATELLITE.

Observations made from 1972 to 1976 with the Electrically Scanning Microwave Radiometer on board the Nimbus-5 satellite provide sequential synoptic information of the Arctic sea ice cover. This four-year data set was used to construct a fairly continuous series of three-day average 19-GHz passive microwave images which has become a valuable source of polar information, yielding many anticipated and unanticipated discoveries of the sea ice canopy observed in its entirety through the clouds and during the polar night. Short-term, seasonal, and annual variations of key sea ice parameters, such as ice edge position, ice types, mixtures of ice types, ice concentrations, and snow melt on the ice, are presented for various parts of the Arctic.

Conference Paper↗

Protocol for monitoring forest-nesting birds in National Park Service parks

These documents detail the protocol for monitoring forest-nesting birds in National Park Service parks in the National Capital Region Network (NCRN). In the first year of sampling, counts of birds should be made at 384 points on the NCRN spatially randomized grid, developed to sample terrestrial resources. Sampling should begin on or about May 20 and continue into early July; on each day the sampling period begins at sunrise and ends five hours later. Each point should be counted twice, once in the first half of the field season and once in the second half, with visits made by different observers, balancing the within-season coverage of points and their spatial coverage by observers, and allowing observer differences to be tested. Three observers, skilled in identifying birds of the region by sight and sound and with previous experience in conducting timed counts of birds, will be needed for this effort. Observers should be randomly assigned to ‘routes’ consisting of eight points, in close proximity and, ideally, in similar habitat, that can be covered in one morning. Counts are 10 minutes in length, subdivided into four 2.5-min intervals. Within each time interval, new birds (i.e., those not already detected) are recorded as within or beyond 50 m of the point, based on where first detected. Binomial distance methods are used to calculate annual estimates of density for species. The data are also amenable to estimation of abundance and detection probability via the removal method. Generalized linear models can be used to assess between-year changes in density estimates or unadjusted count data. This level of sampling is expected to be sufficient to detect a 50% decline in 10 years for approximately 50 bird species, including 14 of 19 species that are priorities for conservation efforts, if analyses are based on unadjusted count data, and for 30 species (6 priority species) if analyses are based on density estimates. The estimates of required sample sizes are based on the mean number of individuals detected per 10 minutes in available data from surveys in three NCRN parks. Once network-wide data from the first year of sampling are available, this and other aspects of the protocol should be re-assessed, and changes made as desired or necessary before the start of the second field season. Thereafter, changes should not be made to the field methods, and sampling should be conducted annually for at least ten years. NCRN staff should keep apprised of new analytical methods developed for analysis of point-count data.

Report↗

Genetic assignment of fisheries bycatch reveals disproportionate mortality among Alaska Northern Fulmar breeding colonies

Global fisheries kill millions of seabirds annually through bycatch, but little is known about population-level impacts, particularly in species that form metapopulations. U.S. North Pacific groundfish fisheries catch thousands of Northern Fulmars ( Fulmarus glacialis rodgersii ) each year, making fulmars the most frequently caught seabird in federally managed U.S. fisheries. Here, we used genetic stock identification to assign 1,536 fulmars sampled as bycatch to one of four Alaska breeding colonies and quantified the similarity of bycatch locations at sea among colonies. We found disproportionately high bycatch from the Pribilof Islands (6% of metapopulation, 23% of bycatch), and disproportionately low bycatch from Chagulak Island (34% of metapopulation, 14% of bycatch). Overlap between fisheries and colony-specific foraging areas diverge more during the summer breeding season, leading to greater differences in bycatch susceptibility. Contemporary and historical gene flow likely contributes to low genetic differentiation among colonies (F ST = 0.003–0.01), yet these values may not represent present connectivity. Our findings illustrate how genetic stock identification can link at-sea threats to colonies and inform management to reduce bycatch from impacted colonies.

Alaska↗

Timing and location of mortality of fledgling, subadult, and adult California Gulls

We investigated patterns of mortality during post-breeding migrations of California Gulls (Larus californicus) nesting near Laramie, Wyoming, USA. We used 151 recoveries and 647 sightings of banded and patagially-marked gulls to compare ratios of mortalities to observations of live birds (1) during four time periods (early and late fall migration, winter, and spring migration), (2) at two locations (Pacific coast and inland), and (3) among three age-classes of gulls (fledglings, 1- and 2-year-olds, and breeding-age adults). Mortality rates were higher in inland areas (35%) than in coastal areas (15%) and were dependent on season within inland areas, but not in coastal areas. Mortality in inland areas during early fall (21%) was comparable with that in coastal areas (13%) but was higher during late fall (68 vs. 13%) and spring migration (46 vs. 17%). Both fledgling (71%) and adult (64%) gulls experienced high mortality rates during late fall migration, possibly because some gulls were too weak to make their way to the Pacific coast and became trapped by poor weather conditions. Adult gulls also experienced high mortality inland during spring migration; few subadults made the costly migration to and from the breeding area. Some adults also skipped breeding and remained in coastal areas during the breeding season.

Wilson Journal of Ornithology↗

Characterization of and temporal changes in groundwater quality of the Upper Black Squirrel Creek Basin, El Paso County, Colorado, 2018–20

In 2018–20, the U.S. Geological Survey, in cooperation with Upper Black Squirrel Creek Ground Water Management District, sampled 48 wells for Phase III of a multiphase plan investigating groundwater quality in the alluvial aquifer of the Upper Black Squirrel Creek Basin (UBSB), El Paso County, Colorado. Results for samples collected from October to December each year were used to assess spatial and temporal changes in groundwater quality and to differentiate sources of nitrate. Groundwater was predominantly classified as mixed-cation and mixed-anion water type in the aquifer, with variable chemistry along the periphery. Concentrations of constituents in groundwater were generally less than regulatory standards, except for nitrate in four wells. Isotopes of nitrogen and oxygen in nitrate identified four different potential sources or processes affecting nitrate in the alluvial aquifer: naturally occurring nitrate from soils, nitrate from animal and (or) human waste, and an unknown source, along with evidence of denitrification. Pharmaceutical compounds and personal-care products were detected in seven wells, with three wells having multiple detections. Stable isotopes of water indicated variability in seasonality of recharge throughout the UBSB alluvial aquifer. Nitrate concentrations from the 1984 study and the 1996 study were compared to the more recent concentrations in the 2013 study and the 2018–20 study. The northern one-third of the UBSB alluvial aquifer had a statistically significant increase in nitrate concentration from the 2013 study to the 2018–20 study, but no change was shown from the 1984 study to the 1996 study. The opposite was found true for the southern two-thirds of the UBSB alluvial aquifer with no statistically significant difference in nitrate concentration from the 2013 study to the 2018–20 study. Analysis of temporal changes indicated an increase in median and maximum nitrate concentrations from the 2013 study to the 2018–20 study throughout the UBSB alluvial aquifer. Continued sampling of wells in the UBSB would be beneficial to better determine temporal changes in groundwater quality, characterize human effects on water quality, and understand characteristics of the alluvial aquifer pertaining to sustainability of the resource.

Colorado↗

Environmental geochemistry of an epigenetic Pb-Zn-Ag deposit at the abandoned Cecilia mine, Puno region, Peru

The abandoned Cecilia Pb-Zn-Ag mine is located at the headwaters of the Lake Titicaca watershed in the Altiplano of Peru. The site is characterized by three months of high precipitation and nine months of limited precipitation. The environmental geochemical characterization of the abandoned mine was done to evaluate environmental risks at the site from mine wastes and mine drainage, and their potential for downstream impacts on water quality in Lake Titicaca. The approach included sampling of mine waste, water, and sediment. Composite mine waste samples were collected from six main piles (four tailings, two waste rock). The surface water was collected from (1) drainage from mine portals; (2) the Cecilia and Crucero rivers upstream of mine influences; (3) the impacted reach of the Cecilia River down to its confluence with the Crucero River; and (4) the Crucero River, which receives drainage from the Cecilia River. Sampling in the dry season did not identify seeps from the waste rock or tailings piles. This study documents the capacity of the site to generate acid mine drainage from the mine waste and underground workings. Mine waste has elevated concentrations of As (up to 883 mg/kg), Cu (up to 20,106 mg/kg), Pb (up to 16,716 mg/kg), and Zn (up to 11,937 mg/kg). Results for dissolved concentrations from leaching experiments on mine waste samples showed high leachability for As (0.001 to 0.95 mg/L), Cu (0.01 to 57.34 mg/L), Cd (0.001 to 1.13 mg/L), Fe (0.42 to 785 mg/L), Zn (0.01 to 91 mg/L), and Mn (0.05 to 279 mg/L) with an acidic pH (2.5 to 6.0). Water chemistry at the site varied on the basis of water type. The Cecilia and Crucero rivers had neutral pH and low concentrations of metals upstream of mine influences. In contrast, samples collected at the mine portal were highly acidic (pH 1.4 to 3.7) with high dissolved concentrations of Fe (up to 4,720 mg/L), Al (up to 400 mg/L), sulfate (up to 19,428 mg/L), As (up to 5.92 mg/L), Cd (up to 9.84 mg/L), Cu (up to 1.56 mg/L), Pb (up to 1.95 mg/L), and Zn (up to 4,065 mg/L), causing an increase in metal concentrations in the river downstream after mixing. Carbonate rocks in the watershed produce alkaline waters that neutralize acid drainage prior to its confluence with the Crucero River. Proposed remediation methods include capping mine waste to limit contact with rainwater and passive treatment of mine portal drainage.

Cecilia mine↗

Stochastic analyses to identify wellfield withdrawal effects on surface-water and groundwater in Miami-Dade County, Florida

Several stochastic analyses were conducted in Miami-Dade County, Florida, to evaluate the effects of wellfield withdrawal on aquifer water levels, canal stage, and canal flow. Multiyear data for withdrawals at four water-supply wellfields, water levels at the S-121 canal control structure and groundwater head at a nearby monitoring well were used to determine the interrelation between wellfield withdrawals and water levels in the canal and aquifer. A spectral analysis was performed first on the wellfield withdrawals, showing similar patterns of fluctuations, but no well-defined seasonality. In order to compare water-level response with withdrawals at each wellfield, the intercorrelation effects between wellfields was removed through a ‘causal chain’ approach where the inter-wellfield correlation is used to isolate the wellfield/water-level correlation. Most computed correlations have magnitudes less than 5 percent, but with statistical significance above 90 percent. Results indicate that withdrawals from the wellfields most distant from the canal had no significant correlation to the canal levels. However the highest correlation was not at the wellfield closest to the canal, but at the two wellfields at the intermediate distance that have higher withdrawal rates. The hydraulic interconnectivity of the canal with the rest of the canal network, covering the study area, allows the canal equalizes with all connected canals. This explains why proximity to a particular canal location does not appear to be as important a factor as the withdrawal rate. Groundwater levels are more highly correlated to a wellfield on the same side of the canal, and to pumping wells in the same wellfield on the same side of the canal. This indicates that canals are an effective barrier and source/sink for the groundwater. Further nonlinear correlation analysis indicates that high withdrawal rates disproportionally affect water levels and are the predominant effect on the canal.

Florida↗

Wet antecedent soil moisture increases atmospheric river streamflow magnitudes non-linearly

Atmospheric rivers (ARs) drive most riverine floods on the United States (U.S.) West Coast. However, estimating flood risk based solely on AR intensity and duration is challenging because precipitation phase, antecedent conditions, and physical watershed characteristics (e.g., slope and soil depth) can influence the magnitude of floods. Here, we analyze how antecedent soil moisture (ASM) conditions contribute to variability in streamflow during AR events and how that changes across climatic regimes and physiography in 122 U.S. West Coast watersheds. We identify a robust non-linear relationship between streamflow and ASM during ARs in 89% of watersheds. The inflection point in this relationship represents a watershed-specific critical ASM threshold, above which event maximum streamflow is, on average, two to four and a half times larger. Wet ASM conditions amplify the hydrologic impacts of more frequent but weaker, lower moisture transport AR events, while dry ASM conditions attenuate the hydrologic impacts that stronger, higher moisture transport AR events could otherwise cause. Our research shows that watersheds prone to ASM-amplified streamflows have higher evaporation ratios, lower cold-season precipitation, lower snow-to-rain ratios, and shallower, clay-rich soils. Higher evaporation and lower precipitation lead to greater ASM variability during the cold season, increasing streamflow during wet periods and buffering streamflow during dry periods. Lower snow fraction and shallower soils limit the antecedent water storage capacity of a watershed, contributing to greater sensitivity of streamflow peaks to ASM variability. Incorporating ASM thresholds into hydrologic models in these regions prone to AR-amplified streamflow could improve forecasts and decrease uncertainty.

California, Nevada, Oregon, Washington↗

The importance of subarctic intertidal habitats to shorebirds: A study of the central Yukon-Kuskokwim Delta, Alaska

A 6-year study of shorebird use of intertidal habitats of the Yukon-Kuskokwim Delta revealed this area to be one of the premiere sites for shorebirds throughout the Holarctic and worthy of designation as a Hemispheric Shorebird Reserve in the Western Hemisphere Shorebird Reserve Network. The study area, which covered 10% (300 km 2 ) of the delta's intertidal flats, regularly hosted 17 species of shorebirds between late April and mid-October. The greatest use was during the postbreeding period (late June-October), when Dunlins ( Calidris alpina ), Western Sandpipers ( C. mauri ), and Rock Sandpipers ( C. ptilocnemis ), each with large local nesting populations, accounted for 95% of the shorebirds recorded. Peak counts during autumn approached 300,000 birds. Considering the seasonal occurrence and turnover of populations, we estimate 1-2 million shorebirds use the central delta each year. The delta supports large fractions of the Pacific Rim or world populations of Bar-tailed Godwits ( Limosa lapponica ), Black Turnstones ( Arenaria melanocephala ), Red Knots ( C. canutus ), Western Sandpipers, Dunlins, and Rock Sandpipers. Densities of shorebirds using the central delta's four major bays and connecting coastal areas peaked at 950 shorebirds/km 2 in early September. Hazen Bay frequently hosted more than 1,200 shorebirds/km 2 . Postbreeding shorebirds used intertidal habitats in three distinct patterns according to age class. For most species (n = 7), there was a period when adults appeared first, followed by a brief interval when adults and juveniles mixed, then by a prolonged period when only juveniles remained. In the second pattern (n = 3 species), adults moved onto the intertidal flats first, were later joined by juveniles for a prolonged staging period, then migrated with them. In the third pattern (n = 3 species), only juveniles used the delta's intertidal habitat. Temporal segregation among species and age groups may minimize competition for food and thereby allow the delta to support high diversity and numbers of shorebirds.

Alaska↗

Occurrence, distribution, loads, and yields of selected pesticides in the Little River basin, Kentucky, 2003-04

Water resources in the Little River Basin are potentially vulnerable to applications of pesticides associated with both agricultural and nonagricultural activities, because much of the basin is characterized by karst topography. Concerns about water quality resulting from pesticide use in karst areas and lack of data on concentrations of pesticides in surface water led to further investigation of water quality in the Little River Basin, which includes about 600 square miles in Christian and Trigg Counties and a portion of Caldwell County in western Kentucky. Water samples were collected in streams in the Little River Basin, Kentucky during 2003-04 as part of a study conducted in cooperation with the Kentucky Department of Agriculture. The objectives of the study were to assess the occurrence and distribution of pesticides, to evaluate the spatial and seasonal variability of pesticides, and to evaluate loads and yields of selected pesticides in the basin. A total of 91 water samples was collected at 4 fixed-network sites from March through November 2003 and from February through November 2004. An additional 20 samples were collected at 5 synoptic-network sites within the same period. Twenty-four pesticides were detected of the 127 pesticides analyzed in the stream samples. Of the 24 detected pesticides, 15 were herbicides, 7 were insecticides, and 2 were fungicides. The most commonly detected pesticides-atrazine, simazine, metolachlor, and acetochlor-were those most heavily used on crops during the study. Atrazine and simazine were detected in 100 percent of all surface-water samples, and metolachlor and acetochlor were detected in more than 45 percent. The pesticide degradate, deethylatrazine, was detected in 100 percent of the samples. Only one nonagricultural herbicide, prometon, was detected in more than 50 percent of the samples. Diazinon, the most commonly detected insecticide, was found in 25 percent of all samples and was found at all sites except Casey Creek. Metalaxyl was the most commonly detected fungicide (14 percent); most detections were in samples from the Sinking Fork subbasin. Concentrations of herbicides were highest following application in the spring (March-May). In contrast, insecticides typically were present during the summer (June-August). The most commonly detected pesticides in the Little River Basin were found at low concentrations in streams year-round. Atrazine and simazine (row-crop herbicides) had the highest measured concentrations (22 and 6.1 micrograms per liter (?g/L), respectively) and were the most heavily applied herbicides in the basin. Metolachlor also was heavily applied in the basin, but measured concentrations did not exceed 0.32 ?g/L. The insecticide, Malathion, was only detected in 4 percent of the samples, although it was heavily applied in the basin during 2003-04. Most detections of pesticides were at low concentrations in relation to drinking-water standards and guidelines established for the protection of aquatic life. Only two pesticide compounds--atrazine and simazine--exceeded the U.S. Environmental Protection Agency (USEPA) standards for drinking water. Atrazine exceeded the USEPA's maximum contaminant level (MCL) 19 times in 111 detections; simazine exceeded the established MCL 2 times in 111 detections. These exceedences occurred in the spring. Concentrations of atrazine also exceeded the established aquatic-life criterion (1.8 ?g/L) in 32 samples collected from all sites. Concentrations of deethylatrazine, an herbicide-transformation compound, tended to follow the same monthly concentration pattern as its parent compound (atrazine), but concentrations of deethylatrazine were lower than those of atrazine. Atrazine may have been present in the soil much longer at these sites, which might have allowed microbial populations to transform atrazine into deethylatrazine. A statistical comparison of concentrations of selected pesticides among four fixed-network sites

Scientific Investigations Report↗

Relation of water quality to land use in the drainage basins of four tributaries to the Toms River, New Jersey, 1994-95

The influence of land use on the water quality of four tributaries to the Toms River, which drains nearly one-half of the Barnegat Bay wateshed, was studied during the initial phase of a multiyear investigation. Water samples were collected from and streamflows were measured in Long Swamp Creek, Wrangel Brook, Davenport Branch, and Jakes Creek during periods of base flow and stormflow in the growing and nongrowing seasons during May 1994 to October 1995. The drainage areas upstream from the seven measurement sites were characterized as highly developed, moderately developed, slightly developed, or undeveloped. Concentrations were determined and area-normalized instantaneous loads (yields) were estimated for total nitrogen, ammonia, nitrate, organic nitrogen, hydrolyzable phosphorus plus orthosphosphorus, orthophosphorus, total suspended solids, and fecal-coliform bacteria in the water samples. Specific conductance, pH, temperature, and dissolved oxygen were measured. Yields of total nitrogen, nitrate, and organic nitrogen at sites on Wrangel Brook, which drains moderately developed areas, were either larger than or similar to yields at the site on Long Swamp Creek, which drains a highly developed area. The magnitude of these yields probably was not related directly to the intensity of land development, but more likely was influenced by the type of development, the amount of base flow, and historical land use in the basin. The large concentrations of total nitrogen and nitrate in base flow in Wrangel Brook could have resulted from fertilizers that were applied to high-maintenance lawns and from agricultural runoff that has remained in the ground water since the 1950's and eventually was discharged to streams. Yields of ammonia appear to be partly related to the intensity of land development and storm runoff. Yields of ammonia at the site on Long Swamp Creek (a highly developed area) were either larger than or similar to yields at sites on Wrangel Brook (moderately developed areas). Yields were smallest at the site on Davenport Branch, which drains a slightly developed area. Yields of hydrolyzable phosphorus plus orthophosphorus and yields of orthophosphorus appear to be related to the intensity of development. Concentrations of hydrolyzable phosphorus plus orthophosphorus were greater in Long Swamp Creek (highly developed areas) than in Wrangel Brook (moderately developed areas). Concentrations of orthophosphorus were largest in Wrangel Brook (moderately developed) and Long Swamp Creek (highly developed). Total suspended solids and bacteria were somewhat related to intensity of development. Yields of total suspended solids were greater at sites downstream from highly and moderately developed areas than from slightly developed areas. Yields of bacteria were strongly related to streamflow and season. Specific conductance appears to be related to streamflow. pH probably was related to intensity of land development; pH was greater (more basic) in streams draining highly developed areas than in those draining other areas. Concentrations of dissolved oxygen were affected more by water temperature than by intensity of development or streamflow.

New Jersey↗

Perfluoroalkyl substances in plasma of smallmouth bass from the Chesapeake Bay Watershed

Smallmouth bass Micropterus dolomieu is an economically important sportfish and within the Chesapeake Bay watershed has experienced a high prevalence of external lesions, infectious disease, mortality events, reproductive endocrine disruption and population declines. To date, no clear or consistent associations with contaminants measured in fish tissue or surface water have been found. Therefore, plasma samples from two sites in the Potomac River and two in the Susquehanna River drainage basins, differing in land-use characteristics, were utilized to determine if perfluoroalkyl substances were present. Four compounds, perfluorooctane sulphonic acid (PFOS), perfluoroundecanoic acid (PFUnA), perfluorodecanoic acid (PFDA) and perfluorododecanoic acid (PFDoA), were detected in every fish. Two additional compounds, perfluorooctane sulphonamide (PFOSA) and perfluorononanoic acid (PFNA), were less commonly detected at lower concentrations, depending on the site. Concentrations of PFOS (up to 574 ng/mL) were the highest detected and varied significantly among sites. No seasonal differences (spring versus fall) in plasma concentrations were observed. Concentrations of PFOS were not significantly different between the sexes. However, PFUnA and PFDoA concentrations were higher in males than females. Both agricultural and developed land-use appeared to be associated with exposure. Further research is needed to determine if these compounds could be affecting the health of smallmouth bass and identify sources.

New York, Pennsylvania, Maryland, Virginia↗

Persistent organic pollutants in the blood of free-ranging sea otters (Enhydra lutris ssp.) in Alaska and California

As part of tagging and ecologic research efforts in 1997 and 1998, apparently healthy sea otters of four age-sex classes in six locations in Alaska and three in California were sampled for persistent organic pollutants (POPs) and other chemicals of ecologic or environmental concern (COECs). Published techniques for the detection of POPs (specifically Σpolychlorinated biphenyls [PCBs], ΣDDTs, Σhexachlorocyclohexanes [HCHs], Σpolycyclic aromatic hydrocarbons [PAHs], Σchlordanes [CHLs], hexachlorobenzene [HCB], dieldrin, and mirex) in the tissue of dead otters were modified for use with serum from live sea otters. Toxic equivalencies (TEQs) were calculated for POPs with proven bioactivity. Strong location effects were seen for most POPs and COECs; sea otters in California generally showed higher mean concentrations than those in Alaska. Differences in contaminant concentrations were detected among age and sex classes, with high levels frequently observed in subadults. Very high levels of ΣDDT were detected in male sea otters in Elkhorn Slough, California, where strong freshwater outflow from agricultural areas occurs seasonally. All contaminants except mirex differed among Alaskan locations; only ΣDDT, HCB, and chlorpyrifos differed within California. High levels of ΣPCB (particularly larger, more persistent congeners) were detected at two locations in Alaska where associations between elevated PCBs and military activity have been established, while higher PCB levels were found at all three locations in California where no point source of PCBs has been identified. Although POP and COEC concentrations in blood may be less likely to reflect total body burden, concentrations in blood of healthy animals may be more biologically relevant and less influenced by state of nutrition or perimortem factors than other tissues routinely sampled.

Alaska, California↗

Variation in biotic assemblages and stream-habitat data with sampling strategy and method in tidal segments of Highland and Marchand Bayous, Galveston County, Texas, 2007

The U.S. Geological Survey, in cooperation with the Houston-Galveston Area Council and the Galveston Bay Estuary Program under the authority of the Texas Commission on Environmental Quality, did a study in 2007 to assess the variation in biotic assemblages (benthic macroinvertebrate and fish communities) and stream-habitat data with sampling strategy and method in tidal segments of Highland Bayou and Marchand Bayou in Galveston County. Data were collected once in spring and once in summer 2007 from four stream sites (reaches) (short names Hitchcock, Fairwood, Bayou Dr, and Texas City) of Highland Bayou and from one reach (short name Marchand) in Marchand Bayou. Only stream-habitat data from summer 2007 samples were used for this report. Additional samples were collected at the Hitchcock, Fairwood, and Bayou Dr reaches (multisample reaches) during summer 2007 to evaluate variation resulting from sampling intensity and location. Graphical analysis of benthic macroinvertebrate community data using a multidimensional scaling technique indicates there are taxonomic differences between the spring and summer samples. Seasonal differences in communities primarily were related to decreases in the abundance of chironomids and polychaetes in summer samples. Multivariate Analysis of Similarities tests of additional summer 2007 benthic macroinvertebrate samples from Hitchcock, Fairwood, and Bayou Dr indicated significant taxonomic differences between the sampling locations at all three reaches. In general, the deepwater samples had the smallest numbers for benthic macroinvertebrate taxa richness and abundance. Graphical analysis of species-level fish data indicates no consistent seasonal difference in fish taxa across reaches. Increased seining intensity at the multisample reaches did not result in a statistically significant difference in fish communities. Increased seining resulted in some changes in taxa richness and community diversity metrics. Diversity increases associated with increased electrofishing intensity were relatively consistent across the two multisample electrofishing reaches (Hitchcock and Fairwood). Differences in the physical characteristics of the Highland and Marchand Bayou reaches are largely the result of the differences in channel gradient and position in the drainage network or watershed of each reach. No trees were observed on the bank adjacent to the five transects at either the Bayou Dr or Texas City reaches. Riparian vegetation at the more downstream Fairwood, Bayou Dr, and Texas City reaches was dominated by less-woody and more-herbaceous shrubs, and grasses and forbs, than at the more upstream Hitchcock and Marchand reaches. The width of the vegetation buffer was variable among all reaches and appeared to be more related to the extent of anthropogenic development in the riparian zone rather than to natural changes in the riparian buffer. Four additional transects per reach were sampled for habitat variables at Hitchcock, Fairwood, and Bayou Dr. Medians of most stream-habitat variables changed with increased sampling intensity (addition of two and four transects to the standard five transects), although none of the differences in medians were statistically significant. All habitat quality index values for the five reaches scored in the intermediate category. Increasing sampling intensity did not change the habitat quality index score for any of the reaches.

Scientific Investigations Report↗

The importance of phenology and thermal exposure to early life history success of nonnative Smallmouth Bass in the Yellowstone River

Knowledge of potential spread by introduced species is critical to effective management and conservation. The Smallmouth Bass Micropterus dolomieu is an example of a fish that has been introduced globally, often spreads after introduction, and has substantial predatory impacts on fish assemblages. Nonnative Smallmouth Bass in the free-flowing Yellowstone River, Montana, have expanded from warmer, downstream sections of river into colder, upstream sections containing socio-economically valuable trout fisheries. We sought insight into mechanisms controlling upstream spread by evaluating whether progressively colder upstream climates physiologically constrained successful recruitment by limiting age-0 growth and preventing overwinter survival (i.e., population establishment). We documented the phenology, growth, and overwinter survival of age-0 Smallmouth Bass across a temperature gradient leading to their upstream extent in the Yellowstone River. The upstream extent of population establishment did not appear limited by water temperature alone. Age-0 body size at the onset of winter did not differ significantly between colder, upstream reaches and warmer, downstream reaches. Instead, the earlier hatch timing exhibited by some age-0 individuals in upstream sections allowed them to experience longer growing seasons than many individuals in downstream sections. This counter-intuitive hatching phenology mediated much of the expected decreases in growth in colder, upstream climates. Furthermore, evidence of successful overwinter survival and simulations of age-0 starvation mortality indicated that age-0 individuals at the upstream extent of their distribution successfully recruited to the age-1 year-class during four consecutive years. However, age-0 individuals were rare or absent throughout the uppermost upstream distribution of adults, suggesting that something other than temperature limits or discourages reproduction farther upstream. Taken together, our results suggest that Smallmouth Bass have not yet reached the thermal limit of their upstream distribution in the Yellowstone River and that future spread may challenge fisheries managers tasked with management of coldwater trout fisheries in this river.

Montana, Wyoming↗