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Anthropogenic pollutants and biomarkers for the identification of 2011 Tohoku-oki tsunami deposits (Japan)

Organic geochemistry is commonly used in environmental studies. In tsunami research, however, its applications are in their infancy and it is still rarely used. We present results for two types of organic geochemical markers, biomarkers and anthropogenic markers, present in deposits left by 2011 Tohoku-oki tsunami on the Sendai Plain, Japan. As the tsunami inundated the coastal lowland up to 4.85 km inland, sediments from various sources were eroded, transported and deposited. This led to the distribution of biomarkers from different sources across the Sendai Plain creating a unique geochemical signature in the tsunami deposits. The tsunami also caused destruction along the Sendai coastline, leading to the release of large quantities of environmental pollutants (e.g., fossil fuels, tarmac, pesticides, plastics, etc.) that were distributed across the inundated area. These anthropogenic markers, represented by three main compound groups (polycyclic aromatic hydrocarbons, pesticides, and halogenated compounds), were preserved in tsunami deposits (at least until 2013, prior to land clearing). Their concentrations differed significantly from the pre- and post-tsunami background contamination levels. Organic proxy concentrations can differ for sand and mud deposits due to various factors (e.g., preservation, dilution, microbial alteration). However, it can be concluded that anthropogenic markers and biomarkers have the potential to be a valuable proxy for future studies of recent tsunami deposits because of their high source specificity and relatively good preservation potential providing information about sediment sources and transport pathways (e.g., marine source, evidence of backwash).

Sendai↗

Peralkaline and peraluminous granites and related mineral deposits of the Arabian Shield, Kingdom of Saudi Arabia

In the Precambrian Arabian Shield, granitoid plutonic rocks are widespread and range in age from 800 to 550 Ma old; but the mineral-resource potential associated with these plutonic rocks is restricted mainly to the younger, postorogenic granites. Two granite types of current economic interest are zirconium- niobium-enriched per alkaline granites and tin-tungsten-enriched peraluminous granites. Both types are highly evolved, are enriched in lithium, rubidium, and fluorine, and have distinctive mineralogy, textures, and chemistry. The zirconium-niobium-enriched granites are related to medium- to large-sized plutons and complexes of peralkaline granite, and the tin-tungsten-enriched granites are related to medium-sized plutons of biotite or biotite-muscovite granite. Existing geochemical and geologic data for many parts of the Arabian Shield were compiled as a basis for evaluating the resource potential of the granites of the Shield. Commodities associated with granites that have potential for economic mineral deposits include tin, tungsten, molybdenum, beryllium, niobium, tantalum, zirconium, uranium, thorium, rare-earth elements, and fluorite. Prospecting methods useful in discriminating those granites having significant economic potential include reconnaissance geologic mapping, petrographic and mineralogic studies, geochemical sampling of rock and wadi sediment, and radiometric surveying.

Open-File Report↗

Reconnaissance geologic map of the Hyampom 15' quadrangle, Trinity County, California

The Hyampom 15' quadrangle lies west of the Hayfork 15' quadrangle in the southern part of the Klamath Mountains geologic province of northern California. It spans parts of four generally northwest-trending tectono- stratigraphic terranes of the Klamath Mountains, the Eastern Hayfork, Western Hayfork, Rattlesnake Creek, and Western Jurassic terranes, as well as, in the southwest corner of the quadrangle, a small part of the Pickett Peak terrane of the Coast Range province. Remnants of the Cretaceous Great Valley overlap sequence that once covered much of the pre-Cretaceous bedrock of the quadrangle are now found only as a few small patches in the northeast corner of the quadrangle. Fluvial and lacustrine deposits of the mid-Tertiary Weaverville Formation crop out in the vicinity of the village of Hyampom. The Eastern Hayfork terrane is a broken formation and m-lange of volcanic and sedimentary rocks that include blocks of chert and limestone. The chert has not been sampled; however, chert from the same terrane in the Hayfork quadrangle contains radiolarians of Permian and Triassic ages, but none clearly of Jurassic age. Limestone at two localities contains late Paleozoic foraminifers. Some of the limestone from the Eastern Klamath terrane in the Hayfork quadrangle contains faunas of Tethyan affinity. The Western Hayfork terrane is part of an andesitic volcanic arc that was accreted to the western edge of the Eastern Hayfork terrane. It consists mainly of metavolcaniclastic andesitic agglomerate and tuff, as well as argillite and chert, and it includes the dioritic Ironside Mountain batholith that intruded during Middle Jurassic time (about 170 Ma). This intrusive body provides the principal constraint on the age of the terrane. The Rattlesnake Creek terrane is a melange consisting mostly of highly dismembered ophiolite. It includes slabs of serpentinized ultramafic rock, basaltic volcanic rocks, radiolarian chert of Triassic and Jurassic ages, limestone containing Late Triassic conodonts and Permian or Triassic foraminifers, and small exotic(?) plutons. The plutons probably are similar to ones to the southeast beyond the quadrangle boundary that yielded isotopic ages ranging from 193 Ma to 207 Ma. The Rattlesnake Creek terrane contains several areas of well- bedded sedimentary rocks (rcs) that somewhat resemble the Galice(?) Formation and may be inliers of the Western Jurassic terrane. The Western Jurassic terrane in the Hyampom quadrangle appears to consist only of a narrow tectonic sliver of slaty to semischistose detrital sedimentary rocks of the Late Jurassic Galice(?) Formation. The isotopic age of metamorphism of the rocks is about 150 Ma, which probably indicates when the terrane was accreted to the Rattlesnake Creek terrane. The Pickett Peak terrane, which is the most westerly of the succession of terranes in the Hyampom quadrangle, is the accreted eastern margin of the Coast Ranges province. It mainly consists of semischistose and schistose metagraywacke of the South Fork Mountain Schist and locally contains the blueschist-facies mineral lawsonite. Isotopic analysis indicates a metamorphic age of 120 to 115 Ma. During the Cretaceous period, much of the southern fringe of the Klamath Mountains was onlapped by sedimentary strata of the Great Valley sequence. However, much of the onlapping Cretaceous strata has since been eroded away, and in the Hyampom quadrangle only a few small remnants are found in the northeast corner near Big Bar. Near the west edge of the quadrangle, in the vicinity of the village of Hyampom, weakly consolidated fluvial and lacustrine rocks and coaly deposits of Oligocene and (or) Miocene age are present. These rocks are similar to the Weaverville Formation that occurs in separate sedimentary basins to the east in the Weaverville and Hayfork 15? quadrangles. This map of the Hyampom 15' quadrangle is a digital version of U.S. Geological Survey Miscellaneous Field Study.

California↗

Analysis of nonvolcanic tremor on the San Andreas Fault near Parkfield, CA using U.S. Geological Survey Parkfield Seismic Array

Reports by Nadeau and Dolenc (2005) that tremor had been detected near Cholame Valley spawned an effort to use UPSAR (U. S. Geological Survey Parkfield Seismic Array) to study characteristics of tremor. UPSAR was modified to record three channels of velocity at 40–50 sps continuously in January 2005 and ran for about 1 month, during which time we recorded numerous episodes of tremor. One tremor, on 21 January at 0728, was recorded with particularly high signal levels as well as another episode 3 days later. Both events were very emergent, had a frequency content between 2 and 8 Hz, and had numerous high-amplitude, short-duration arrivals within the tremor signal. Here using the first episode as an example, we discuss an analysis procedure, which yields azimuth and apparent velocity of the tremor at UPSAR. We then provide locations for both tremor episodes. The emphasis here is how the tremor episode evolves. Twelve stations were operating at the time of recording. Slowness of arrivals was determined using cross correlation of pairs of stations; the same method used in analyzing the main shock data from 28 September 2004. A feature of this analysis is that 20 s of the time series were used at a time to calculate correlation; the longer windows resulted in more consistent estimates of slowness, but lower peak correlations. These values of correlation (peaks of about 0.25), however, are similar to that obtained for the S wave of a microearthquake. Observed peaks in slowness were traced back to source locations assumed to lie on the San Andreas fault. Our inferred locations for the two tremor events cluster near the locations of previously observed tremor, south of the Cholame Valley. Tremor source depths are in the 14–24 km range, which is below the seismogenic brittle zone, but above the Moho. Estimates of error do not preclude locations below the Moho, however. The tremor signal is very emergent but contains packets that are several times larger than the background tremor signal and lasts about 5 s. These impulsive wavelets are similar to low-frequency earthquakes signals seen in Japan but appear to be broader band rather than just higher in low-frequency energy. They may be more appropriately called high-energy tremor (HET). HET signals at UPSAR correlate well with the record of this event from station GHIB of the HRSN borehole array at Parkfield and HETs typically have a higher cross-correlation coefficient than the rest of the tremor event. The amplitudes of a large HET are consistent with a magnitude of 0.1 when compared with a M2.3 event that had about the same epicenter. Polarizations of the tremor episode at UPSAR are mostly just north of east. Both linearity and azimuth evolve over time suggesting a change in tremor source location over time and linearity is typically higher at the HETs.

California↗

Hydrologic, Hydraulic, and Flood Analyses of the Blackberry Creek Watershed, Kendall County, Illinois

Results of the hydrologic model, flood-frequency, hydraulic model, and flood-hazard analysis of the Blackberry Creek watershed in Kendall County, Illinois, indicate that the 100-year and 500-year flood plains cover approximately 3,699 and 3,762 acres of land, respectively. On the basis of land-cover data for 2003, most of the land in the flood plains was cropland and residential land. Although many acres of residential land were included in the flood plain, this land was mostly lawns, with 25 homes within the 100-year flood plain, and 41 homes within the 500-year flood plain in the 2003 aerial photograph. This report describes the data collection activities to refine the hydrologic and hydraulic models used in an earlier study of the Kane County part of the Blackberry Creek watershed and to extend the flood-frequency analysis through water year 2003. The results of the flood-hazard analysis are presented in graphical and tabular form. The hydrologic model, Hydrological Simulation Program - FORTRAN (HSPF), was used to simulate continuous water movement through various land-use patterns in the watershed. Flood-frequency analysis was applied to an annual maximum series to determine flood quantiles in subbasins for flood-hazard analysis. The Hydrologic Engineering Center- River Analysis System (HEC-RAS) hydraulic model was used to determine the 100-year and 500-year flood elevations, and the 100-year floodway. The hydraulic model was calibrated and verified using observations during three storms at two crest-stage gages and the U.S. Geological Survey streamflowgaging station near Yorkville. Digital maps of the 100-year and 500-year flood plains and the 100-year floodway for each tributary and the main stem of Blackberry Creek were compiled.

Scientific Investigations Report↗

Water resources data-Maine, water year 2001

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, Federal, and other local governmental agencies, obtains a large amount of data pertaining to the water resources of Maine each year. These data, accumulated during the many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. Water-resources data for the 2001 water year for Maine consists of records of stage, discharge, ground water levels, water quality of streams and ground-water wells, precipitation quantity, and snow quantity,. This report contains discharge records for: 5 gage-height stations, 58 discharge gaging stations, stream water-quality data for 3 stations, water levels for 17 ground-water wells, water-quality data for 1 ground-water well, precipitation quantity data for 12 stations, and snow quantity data for 82 stations. Additional water data were collected at other sites, not part of the systematic data-collection program, and are published as special study and miscellaneous record sections.

Water Data Report↗

Water resources data-Maine, water year 2002

The Water Resources Division of the U.S. Geological Survey, in cooperation with State, Federal, and other local governmental agencies, obtains a large amount of data pertaining to the water resources of Maine each year. These data, accumulated during the many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. Water-resources data for the 2002 water year for Maine consists of records of stage, discharge, ground water levels,water quality of streams and ground-water wells, precipitation quantity, and snow quantity,. This report contains discharge records for: 5 gage-height stations, 61 discharge gaging stations, stream water-quality data for 2 stations, water levels for 19 ground-water wells, water-quality data for 2 ground-water well, precipitation quantity data for 12 stations, and snow quantity data for 82 stations. Additional water data were collected at other sites, not part of the systematic data-collection program, and are published as special study and miscellaneous record.

Water Data Report↗

Water resources data-Maine water year 2004

The Water Resources Dicipline of the U.S. Geological Survey, in cooperation with State, Federal,and other local governmental agencies, obtains a large amount of data pertaining to the water resources of Maine each year. These data, accumulated during the many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. Water-resources data for the 2004 water year for Maine consists of records of stage, discharge, ground water levels, water quality of streams and ground-water wells, precipitation quantity, and snow quantity. This report contains discharge records for: 6 gage-height stations, 62 discharge gaging stations, stream water-quality data for 6 stations, water level for 23 ground-water wells, water-quality data for 24 ground-water wells, precipitation quantity data for 15 stations, and snow quantity data for 80 stations, Additional water data were collected at other sites, not part of the systematic data-collection program, and are published as special study and miscellaneous record sections.

Water Data Report↗

Water-quality assessment of the Kentucky River basin, Kentucky: Nutrients, sediments, and pesticides in streams, 1987-90

The U.S. Geological Survey investigated the water quality of the Kentucky River Basin in Kentucky as part of the National Water Quality Assessment program. Data collected during 1987-90 were used to describe the spatial and temporal variability of nutrients, suspended sediment, and pesticides in streams. Concentrations of phosphorus were signifi- cantly correlated with urban and agricultural land use. The high phosphorus content of Bluegrass Region soils was an important source of phosphorus in streams. At many sites in urban areas, all of the stream nitrogen load was attributable to wastewater- treatment-plant effluent. Tributary streams affected by agricultural sources of nutrients contained higher densities of phytoplankton than streams that drained forested areas. Data indicate that a consid- erable percentage of total nitrogen was transported as algal biomass during periods of low discharge. Average suspended-sediment concentrations for the study period were positively correlated with dis- charge. There was a downward trend in suspended- sediment concentrations downstream in the Kentucky River main stem during the study. Although a large amount of suspended sediment originates in the Eastern Coal Field Region, contributions of suspended sediment from the Red River and other tributary streams of the Knobs Region also are important. The most frequently detected herbicides in water samples were atrazine, 2,4-D, alachlor, metolachlor, and dicamba. Diazinon, malathion, and parathion were the most frequently detected organo- phosphate insecticides in water samples. Detectable concentrations of aldrin, chlordane, DDT, DDE, dieldrin, endrin, endosulfan, heptachlor, heptachlor epoxide, and lindane were found in streambed- sediment samples.

Kentucky↗

Hydrologic characteristics and water quality of headwater streams and wetlands at the Allegheny Portage Railroad National Historic Site, Summit area, Blair and Cambria Counties, Pennsylvania, 2014–16

The Allegheny Portage Railroad National Historic Site (ALPO) in Blair and Cambria Counties, Pennsylvania, protects historic features of the first railroad portage over the Allegheny Front and the first railroad tunnel in the United States. This report, which was completed by the U.S. Geological Survey in cooperation with the National Park Service, summarizes water resources in the headwaters of the Blair Gap Run and Bradley Run watersheds at the ALPO Summit area during 2014–16. These new baseline data fill an existing gap in knowledge and may be helpful to evaluate potential changes in the hydrologic characteristics of streams and associated wetlands at the Summit area. Results of synoptic water-quality surveys and continuous stage records at two streamgages near the headwaters of Blair Gap Run and Bradley Run indicate that the headwater streams of the ALPO Summit area are perennial but have different water-quality characteristics. The water sampled in the headwaters of Blair Gap Run had pH that ranged from acidic to near neutral, combined with elevated concentrations of dissolved solids, mainly sulfate, chloride, and sodium. These characteristics can be attributed to drainage from legacy coal mines and runoff from nearby roads treated with deicing salt. More than once during the study, the chloride and associated contaminant concentrations in tributaries of Blair Gap Run exceeded chronic thresholds for protection of freshwater aquatic organisms. In contrast, the water quality at tributaries of Bradley Run in the Summit area was characterized by near-neutral pH and relatively low concentrations of dissolved constituents, which met criteria for protection of freshwater aquatic life. By comparison, the deep groundwater discharged as abandoned mine drainage to Sugar Run from the Argyle Stone Bridge Mine, which underlies the Summit area, had acidic pH and elevated concentrations of sulfate and metals, which exceeded chronic and acute thresholds for aquatic life. Data on shallow groundwater levels in piezometers at two wetlands in the Summit area, which were monitored during spring through fall of 2016, indicate downward hydraulic gradients (higher water level in shallow piezometer than in deeper piezometer) and potential for local groundwater recharge during rainfall events, particularly in the summer and fall seasons. The wetlands in the upland area (wetland 3, at altitude 2,370 feet NAVD 88) near the divide between Blair Gap Run and Bradley Run between the Lemon House and Picnic Area, exhibited a consistent downward gradient from spring through fall of 2016. The associated surface seepage at wetland 3 dried up in the summer of 2016. In contrast, the wetlands in the adjoining valley (wetland 6, at altitude 2,198 feet NAVD 88) in the northwestern Summit area exhibited upward hydraulic gradients in the spring and produced continuous seepage. Despite downward gradients during summer and fall, the seepage associated with wetland 6 sustained perennial conditions in the Bradley Run drainage through the summer of 2016. Differences in groundwater altitudes and associated water quality among the surface water, shallow groundwater, and deep groundwater in the Summit area imply that the surface water and shallow groundwater in the Summit area could recharge the groundwater of the underlying coal mines. Seasonally upward and downward vertical gradients in the near-surface soil and bedrock at wetland 6, and unimpaired water quality in the Bradley Run headwaters, are consistent with a perched water table and local hydrology that is influenced by local recharge. Persistent downward gradients and impaired water quality at wetland 3 and the adjacent headwaters seeps and tributaries of Blair Gap Run could be attributed to subsidence and drainage from shallow coalbeds (Upper Freeport, seam E) and associated mine workings in that area; however, the underlying deep coal mine pool (Lower Kittanning, seam B), which is hundreds of feet below the surface, does not appear to affect the hydrologic characteristics of the headwater streams and wetlands in the Summit area.

Pennsylvania↗

Environmental processes that affect mineral deposits in the eastern United States

A thorough understanding of the environmental processes that affect mineral deposits and mine wastes has become increasingly important as the Nation wrestles with how to meet our current demand for metals without compromising the environment and how to mitigate the damage caused by the mining practices of previous generations. Regulatory requirements are dominated by empirical approaches to environmental problems associated with mining, but mitigation and reclamation can be enhanced greatly by a theoretical and conceptual understanding of the processes that affect the availability, transport, and fixation of metals and the generation of acidic waters. U.S. Geological Survey (USGS) research efforts in the Eastern United States are concentrating on environmental processes that affect a class of mineral deposits known as massive sulfide deposits. These occurrences were valued historically for their sulfur content and recently for their metals. This deposit type is a research priority because of its economic significance and high potential for adverse environmental impact due to its high sulfide content and the low acid-buffering capacity of host rocks. Numerous examples of these deposits are found in the East, including reclaimed mine sites, abandoned mines, active mines, and sites currently in the permitting process for future production. Published studies of mine drainage chemistry from the Iron Mountain massive sulfide deposit in California have documented extreme conditions of very low pH and high heavy-metal concentrations. These extreme conditions are attributed to the unique hydrologic and climatic settings of the deposit and probably are independent of the mineral deposit type. Areas currently under study include Bald Mountain, Maine, the Great Smoky Mountains National Park, the Vermont copper belt, Contrary Creek, Virginia, and Prince William Forest Park, Virginia (fig.1). Goals of the research are (1) to give land-use planners and the mining industry a better empirical framework from which to assess potential environmental impacts of mining, particularly under eastern climatic conditions, and (2) to provide a better theoretical and conceptual framework from which to design more effective and cost efficient mitigation and reclamation programs.

Information Handout↗

Methodology for Estimation of Flood Magnitude and Frequency for New Jersey Streams

Methodologies were developed for estimating flood magnitudes at the 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence intervals for unregulated or slightly regulated streams in New Jersey. Regression equations that incorporate basin characteristics were developed to estimate flood magnitude and frequency for streams throughout the State by use of a generalized least squares regression analysis. Relations between flood-frequency estimates based on streamflow-gaging-station discharge and basin characteristics were determined by multiple regression analysis, and weighted by effective years of record. The State was divided into five hydrologically similar regions to refine the regression equations. The regression analysis indicated that flood discharge, as determined by the streamflow-gaging-station annual peak flows, is related to the drainage area, main channel slope, percentage of lake and wetland areas in the basin, population density, and the flood-frequency region, at the 95-percent confidence level. The standard errors of estimate for the various recurrence-interval floods ranged from 48.1 to 62.7 percent. Annual-maximum peak flows observed at streamflow-gaging stations through water year 2007 and basin characteristics determined using geographic information system techniques for 254 streamflow-gaging stations were used for the regression analysis. Drainage areas of the streamflow-gaging stations range from 0.18 to 779 mi2. Peak-flow data and basin characteristics for 191 streamflow-gaging stations located in New Jersey were used, along with peak-flow data for stations located in adjoining States, including 25 stations in Pennsylvania, 17 stations in New York, 16 stations in Delaware, and 5 stations in Maryland. Streamflow records for selected stations outside of New Jersey were included in the present study because hydrologic, physiographic, and geologic boundaries commonly extend beyond political boundaries. The StreamStats web application was developed cooperatively by the U.S. Geological Survey and the Environmental Systems Research Institute, Inc., and was designed for national implementation. This web application has been recently implemented for use in New Jersey. This program used in conjunction with a geographic information system provides the computation of values for selected basin characteristics, estimates of flood magnitudes and frequencies, and statistics for stream locations in New Jersey chosen by the user, whether the site is gaged or ungaged.

Scientific Investigations Report↗

Assessment of selected inorganic constituents in streams in the Central Arizona Basins study area, Arizona and northern Mexico, through 1998

Stream properties and water-chemistry constituent concentrations from data collected by the National Water-Quality Assessment and other U.S. Geological Survey water-quality programs were analyzed to (1) assess water quality, (2) determine natural and human factors affecting water quality, and (3) compute stream loads for the surface-water resources in the Central Arizona Basins study area. Stream temperature, pH, dissolved-oxygen concentration and percent saturation, and dissolved-solids, suspended-sediment, and nutrient concentration data collected at 41 stream-water quality monitoring stations through water year 1998 were used in this assessment. Water-quality standards applicable to the stream properties and water-chemistry constituent concentration data for the stations investigated in this study generally were met, although there were some exceedences. In a few samples from the White River, the Black River, and the Salt River below Stewart Mountain Dam, the pH in reaches designated as a domestic drinking water source was higher than the State of Arizona standard. More than half of the samples from the Salt River below Stewart Mountain Dam and almost all of the samples from the stations on the Central Arizona Project Canal—two of the three most important surface-water sources used for drinking water in the Central Arizona Basins study area—exceeded the U.S. Environmental Protection Agency drinking water Secondary Maximum Contaminant Level for dissolved solids. Two reach-specific standards for nutrients established by the State of Arizona were exceeded many times: (1) the annual mean concentration of total phosphorus was exceeded during several years at stations on the main stems of the Salt and Verde Rivers, and (2) the annual mean concentration of total nitrogen was exceeded during several years at the Salt River near Roosevelt and at the Salt River below Stewart Mountain Dam. Stream properties and water-chemistry constituent concentrations were related to streamflow, season, water management, stream permanence, and land and water use. Dissolved-oxygen percent saturation, pH, and nutrient concentrations were dependent on stream regulation, stream permanence, and upstream disposal of wastewater. Seasonality and correlation with streamflow were dependant on stream regulation, stream permanence, and upstream disposal of wastewater. Temporal trends in streamflow, stream properties, and water-chemistry constituent concentrations were common in streams in the Central Arizona Basins study area. Temporal trends in the streamflow of unregulated perennial reaches in the Central Highlands tended to be higher from 1900 through the 1930s, lower from the 1940s through the 1970s, and high again after the 1970s. This is similar to the pattern observed for the mean annual precipitation for the Southwestern United States and indicates long-term trends in flow of streams draining the Central Highlands were driven by long-term trends in climate. Streamflow increased over the period of record at stations on effluent-dependent reaches as a result of the increase in the urban population and associated wastewater returns to the Salt and Gila Rivers in the Phoenix metropolitan area and the Santa Cruz River in the Tucson metropolitan area. Concentrations of dissolved solids decreased in the Salt River below Stewart Mountain Dam and in the Verde River below Bartlett Dam. This decrease represents an improvement in the water quality and resulted from a concurrent increase in the amount of runoff entering the reservoirs. Stream loads of water-chemistry constituents were compared at different locations along the streams with one another, and stream loads were compared to upstream inputs of the constituent from natural and anthropogenic sources to determine the relative importance of different sources and to determine the fate of the water-chemistry constituent. Of the dissolved solids transported into the Basin and Range Lowlands each year from the Central Arizona Project Canal and from streams draining the Central Highlands, about 1.2 billion kilograms accumulated in the soil, unsaturated zone, and aquifers in agricultural and urban areas as a result of irrigating crops and urban vegetation. Stream loads of phosphorus decreased from the 91st Avenue Wastewater-Treatment Plant downstream to the Gila River at Gillespie Dam, probably as a result of adsorption of phosphorus to the streambed sediments. In this same reach, stream loads of nitrogen increased, most likely because of inputs from fertilizers. The annual mass of nitrogen and phosphorus input to developed basins from quantifiable sources was much larger than the mass input to basins that had little or no municipal or agricul-tural development. These computed inputs exclude the mass of nitrogen and phosphorus from sources such as geologic formations and soils that could not be quantified. The quantifiable annual inputs of nitrogen and phosphorus for the upper Salt River Basin and the upper Verde River Basin were similar to those for the West Clear Creek Basin. This similarity suggests that the small amount of municipal and agricultural development in the upper Salt River and the upper Verde River Basins did not greatly change the basin input flux. For basins with minimal urban and agricultural development, the largest quantifiable source of nitrogen was precipitation, and the largest source of phosphorus was human bodily waste treated by sewer and septic systems. This was in contrast to developed basins, for which fertilizer was the largest quantifiable source of both nutrients. For most basins examined, quantifiable inputs of nitrogen and phosphorus from nonpoint sources were greater than inputs from point sources. This relation emphasizes the importance of land- and water-management policies that protect surface-water resources from nonpoint sources of nutrients as well as from point sources. The amount of nitrogen and phosphorus transpor-ted out of basins was a small fraction of the total for the quantifiable inputs. This result indicated that most of the nutrients input to basins were not transported out of the basins in surface water, but rather were transported to the subsurface (the soil, unsaturated zone, or aquifer), released to the atmosphere (such as volatilized ammonia), or incorporated into the biomass.

Central Arizona Basins study area↗

Estimating basin lagtime and hydrograph-timing indexes used to characterize stormflows for runoff-quality analysis

A nationwide study to better define triangular-hydrograph statistics for use with runoff-quality and flood-flow studies was done by the U.S. Geological Survey (USGS) in cooperation with the Federal Highway Administration. Although the triangular hydrograph is a simple linear approximation, the cumulative distribution of stormflow with a triangular hydrograph is a curvilinear S-curve that closely approximates the cumulative distribution of stormflows from measured data. The temporal distribution of flow within a runoff event can be estimated using the basin lagtime, (which is the time from the centroid of rainfall excess to the centroid of the corresponding runoff hydrograph) and the hydrograph recession ratio (which is the ratio of the duration of the falling limb to the rising limb of the hydrograph). This report documents results of the study, methods used to estimate the variables, and electronic files that facilitate calculation of variables. Ten viable multiple-linear regression equations were developed to estimate basin lagtimes from readily determined drainage basin properties using data published in 37 stormflow studies. Regression equations using the basin lag factor (BLF, which is a variable calculated as the main-channel length, in miles, divided by the square root of the main-channel slope in feet per mile) and two variables describing development in the drainage basin were selected as the best candidates, because each equation explains about 70 percent of the variability in the data. The variables describing development are the USGS basin development factor (BDF, which is a function of the amount of channel modifications, storm sewers, and curb-and-gutter streets in a basin) and the total impervious area variable (IMPERV) in the basin. Two datasets were used to develop regression equations. The primary dataset included data from 493 sites that have values for the BLF, BDF, and IMPERV variables. This dataset was used to develop the best-fit regression equation using the BLF and BDF variables. The secondary dataset included data from 896 sites that have values for the BLF and IMPERV variables. This dataset was used to develop the best-fit regression equation using the BLF and IMPERV variables. Analysis of hydrograph recession ratios and basin characteristics for 41 sites indicated that recession ratios are random variables. Thus, recession ratios cannot be estimated quantitatively using multiple linear regression equations developed using the data available for these sites. The minimums of recession ratios for different streamgages are well characterized by a value of one. The most probable values and maximum values of recession ratios for different streamgages are, however, more variable than the minimums. The most probable values of recession ratios for the 41 streamgages analyzed ranged from 1.0 to 3.52 and had a median of 1.85. The maximum values ranged from 2.66 to 11.3 and had a median of 4.36.

Scientific Investigations Report↗

Hydrogeologic and Hydraulic Characterization of the Surficial Aquifer System, and Origin of High Salinity Groundwater, Palm Beach County, Florida

Previous studies of the hydrogeology of the surficial aquifer system in Palm Beach County, Florida, have focused mostly on the eastern one-half to one-third of the county in the more densely populated coastal areas. These studies have not placed the hydrogeology in a framework in which stratigraphic units in this complex aquifer system are defined and correlated between wells. Interest in the surficial aquifer system has increased because of population growth, westward expansion of urbanized areas, and increased utilization of surface-water resources in the central and western areas of the county. In 2004, the U.S. Geological Survey, in cooperation with the South Florida Water Management District, initiated an investigation to delineate the hydrogeologic framework of the surficial aquifer system in Palm Beach County, based on a lithostratigraphic framework, and to evaluate hydraulic properties and characteristics of units and permeable zones within this framework. A lithostratigraphic framework was delineated by correlating markers between all wells with data available based primarily on borehole natural gamma-ray geophysical log signatures and secondarily, lithologic characteristics. These correlation markers approximately correspond to important lithostratigraphic unit boundaries. Using the markers as guides to their boundaries, the surficial aquifer system was divided into three main permeable zones or subaquifers, which are designated, from shallowest to deepest, zones 1, 2, and 3. Zone 1 is above the Tamiami Formation in the Anastasia and Fort Thompson Formations. Zone 2 primarily is in the upper part or Pinecrest Sand Member of the Tamiami Formation, and zone 3 is in the Ochopee Limestone Member of the Tamiami Formation or its correlative equivalent. Differences in the lithologic character exist between these three zones, and these differences commonly include differences in the nature of the pore space. Zone 1 attains its greatest thickness (50 feet or more) and highest transmissivity in coastal areas. Zone 2, the most transmissive and extensive zone, is thickest (80 feet or more) and most transmissive in the inland eastern areas near Florida's Turnpike. In this area, zone 1 is absent, and the semiconfining unit above zone 2 extends to the land surface with a thickness commonly ranging from 50 to 100 feet. The thickness of zone 2 decreases to zero in most wells near the coast. Zone 3 attains its greatest thickness (100 feet or more) in the southwestern and south-central areas; zone 3 is equivalent to the gray limestone aquifer. The distribution of transmissivity was mapped by zone; however, zones 2 and 3 were commonly combined in aquifer tests. Maximum transmissivities for zone 1, zones 2 and 3, and zone 3 were 90,000, 180,000, and 70,000 ft2/d (feet-squared per day), respectively. The northern extent of the area with transmissivity greater than 50,000 ft2/d for zones 2 and 3 in the inland northeastern area along Florida's Turnpike has not been defined based on available data and could extend 5 to 10 miles farther north than mapped. Based on the thickness of zone 2 and a limited number of aquifer tests, a large area of zone 2 with transmissivity greater than 10,000 ft2/d, and possibly as much as 30,000 ft2/d, extends to the west across Water Conservation Area 1 from the inland southeastern area into the south-central area and some of the southwestern area. In contrast to the Biscayne aquifer present to the south of Palm Beach County, zones 2 and 3 are interpreted to be present principally in the Tamiami Formation and are commonly overlain by a thick semiconfining unit of moderate permeability. These zones have been referred to as the 'Turnpike' aquifer in the inland eastern areas of Palm Beach County, and the extent of greatest thickness and transmissivity follows, or is adjacent to, Florida's Turnpike. Where it is thick and transmissive, zone 1 may be considered equivalent to the Biscayne aquifer. Areas

Scientific Investigations Report↗

Sediment transport, terrace incision, and sediment chemistry in subbasins of differing land use, Stinking Water Creek Basin near Rangely, Colorado

In many areas of western Colorado, Late Cretaceous Mancos Shale is a source of sediment, salinity, and selenium to surface water. Natural weathering processes and human activity can expose and move sediments from the Mancos Shale, leading to increased salinity and selenium concentrations in surface water. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, studied four subbasins of Stinking Water Creek near Rangely, Colorado, to provide information regarding landscapes on Mancos Shale that have undergone land-use change. Rangeland grazing is present in all four subbasins. Subbasins A1 and A2 have land use related to energy development and subbasins B1 and B2 do not. Aerial photographs, sediment chemistry, optically stimulated luminescence (OSL) ages, cross-section surveys, and Watershed Erosion Prediction Project (WEPP) modeling were used to characterize the history of land-use change by estimating stream channel incision rates and sediment, salinity, and selenium loads. All subbasins had upper and lower terraces and a modern streambed channel, and these surfaces were dated using OSL. In subbasins A1, A2, and B1, the streambed age was older than the terraces, indicating the channels are incising and widening into the older alluvium. In subbasin B2, however, the streambed age was much younger than the terraces, indicating aggradation is the main process. Differences in channel morphology were not always related to land use but to the subbasin position (upstream compared to downstream). Channels in subbasins A1 and A2 were generally wider and shallower than channels in subbasins B1 and B2. Landscape disturbances related to energy development in subbasins A1 and A2 could have caused channel evolution to progress from incision to widening processes.

Colorado↗

Baseline water quality of an area undergoing shale-gas development in the Muskingum River watershed, Ohio, 2015–16

In 2015–16, the U.S. Geological Survey, in cooperation with the Muskingum Watershed Conservancy District, led a study to assess baseline (2015–16) surface-water quality in six lake drainage basins within the Muskingum River watershed that are in the early years of shale-gas development. In 2015, 9 of the 10 most active counties in Ohio for oil and gas development were wholly or partially within the Muskingum River watershed. In addition to shale gas development, the area has a history of conventional oil and gas development and coal mining. In all, 30 surface-water sites were sampled: 20 in tributaries flowing to the lakes, 4 in lakes themselves, and 6 downstream of the lakes. At each of the 30 sites, 6 samples were collected to characterize surface-water chemistry throughout a range of hydrologic conditions. The sampling generally occurred during low flows (periods of greater groundwater contribution) rather than during runoff events (periods of high stream stage). Trilinear diagrams of major ion chemistry revealed three main types of water in the study area―sulfate-dominated waters, bicarbonate-dominated waters, and waters with mixed bicarbonate and chloride anions. Most sites produced samples of bicarbonate-dominated water, and 11 sites produced samples with sulfate-type waters. Mixed bicarbonate and chloride waters were found in samples from two of the six lake drainage basins studied. The baseline (2015–16) assessment of surface-water quality in the study area indicated that few water-chemistry constituents and properties occurred at concentrations or levels that would adversely affect aquatic organisms. Chemical-specific, aquatic life use criteria were not met in only three instances: two were for total dissolved solids at sites likely impacted by coal mining in their drainage basins (hereafter referred to as “mine-impacted sites”), and one was for dissolved oxygen. Mine drainage from historical coal mining in the region likely affected the quality of about one-third of the streams sampled. To simplify interpretation of water-chemistry results, 11 sites with sulfate-type water were identified as mine-impacted sites based on water-quality criteria established by Ohio Department of Natural Resources, Division of Mineral Resources Management, and separated out for subsequent statistical analysis. Concentrations or levels of bicarbonate, boron, calcium, carbonate, total dissolved solids, fluoride, magnesium, lithium, pH, potassium, sodium, specific conductance, strontium, sulfate, and suspended sediment in water were higher (significance level of 0.05) at mine-impacted stream sites than at non-mine-impacted stream sites. An accidental release of oil- and gas-related brines could increase salinity (sodium and chloride), the concentration of total dissolved solids in shallow groundwater and streams, and specific conductance. For this study, chloride concentrations in the study area ranged from 2.12 to 76.1 milligrams per liter. Sources of chloride in water samples were evaluated using binary mixing curves and ratios of chloride to bromide. These ratios indicated that 13 samples from 3 sites in the drainage basin that contained the highest density of conventional oil and gas wells in the study, as well as 4 samples collected from other drainage basins, likely contained a component of brine. Concentrations or levels of barium, bromide, chloride, iron, lithium, manganese, and sodium were significantly higher (alpha = 0.05) in samples with a component of brine than in samples without a component of brine. Benzene, toluene, ethylbenzene and xylene (BTEX), compounds that occur naturally in crude oil, made up 24 of the 45 detections (53 percent) of volatile organic compounds in the study area. The BTEX detections were not associated with sites containing a component of brine. The only volatile organic compound detected in any of the 17 samples that contained a component of brine was acetone, detected in 3 (18 percent) of these samples and in 11 percent of samples not containing a component of brine. Considering that BTEX are gasoline hydrocarbons and that most of the detections occurred during warmer months in and around the lakes, the BTEX detections likely are associated with increases in outdoor activities such as automobile and boating traffic. Radium-226 and radium-228 were included in the list of analytes for this study because production water from shale-gas drilling can contain these naturally occurring radioactive materials. Concentrations of radium-226 exceeded background levels in only two surface-water samples. Concentrations of radium-228 exceeded background levels in one surface-water sample. A brine signature potentially indicative of oil and gas contamination was detected in samples collected at two sites that contained active or plugged waste injection wells, or both. Results from the study indicated significant differences in the median concentrations of bromide, chloride, lithium, manganese, sodium, and total dissolved nitrogen between sites with and without injection wells in their drainage areas. Median concentrations of bromide, chloride, lithium, and sodium, which are common oil- and gas-related contaminants, were higher at sites with injection wells in their drainage areas compared to sites without injection wells. Historical (1960s, 1970s, and 1980s) chloride concentrations and streamflow data at or near five of the six sampling sites downstream from each lake dam were compared to current (2015–16) values. An analysis of covariance was done to test the effects of streamflow, time (decade), and the combined effects (cross product) of streamflow and time on chloride concentrations. Those analyses indicated that streamflow was not significant in explaining the variation in chloride concentration, likely because streamflow in those locations is controlled by dam operations; therefore, association between runoff-generating events and streamflow is less direct than in unregulated streams. From the 1980s to the study period (2015–16), data for three of the five lakes indicated an increase in chloride concentrations. The comparison of historical and current (2015–16) study data from samples collected at another lake indicated that chloride concentrations increased from the 1960s to the 1970s, but concentrations in the 1970s and 2015–16 were similar even though 13 samples from this lake drainage basin were classified as having a component of brine. Median chloride concentrations for the fifth lake, however, seemed to decrease from the 1980s to 2015–16.

Ohio↗

Exploring the persistence of sorted bedforms on the inner-shelf of Wrightsville Beach, North Carolina

Geological studies offshore of Wrightsville Beach, North Carolina reveal subtle large-scale regions of coarse sand with gravel and shell hash (widths between 100 and 200 m and negative relief of ∼1 m) that trend obliquely to the coast. It was previously suggested that these regions serve as conduits for sand exchange between the shoreface and inner shelf during storm-associated downwelling. Consequently they were classified as rippled scour depressions. More recently, the role of alongshore flows and self-organization as a result of inhibited settling of fine sand has been discussed. In this study, 45 days of near-bed current measurements were analyzed using benthic boundary layer and sediment transport models to examine the role of along- and cross-shore flows in driving sediment transport at this site. The wind climate was found to be a dominant influence on near-bed flows. Six distinct sediment transport events were recognized. During these events, sediment transport models show that bedload transport is directed mainly in the cross-shore direction, while suspended sediments are directed alongshore to the southwest. Current observations during these sediment transport events provide no evidence of cross-shore sediment transport caused by steady downwelling currents. Instead, benthic boundary layer model results are used to show that differences in bed roughness between the coarse areas of the seabed within the “rippled scour depressions” and the finer areas of the inner shelf are more pronounced during increasingly energetic wave and current conditions. The enhanced difference in roughness results in increased turbulence intensities over coarse regions inhibiting the deposition of the fine sand that is resuspended over the shelf during these events relative to finer areas over the shelf. Findings from this study contribute to explaining the observed long-term persistence of these features.

North Carolina↗