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Origin of epigenetic calcite in coal from Antarctica and Ohio based on isotope compositions of oxygen, carbon and strontium

Isotopic compositions of oxygen, carbon and strontium of calcite cleats in coal seams of southern Victoria Land, Antarctica, and Tuscarawas County, Ohio, contain a record of the conditions a the time of their formation. The Antarctic calcites (?? 18O(SMOW) = +9.14 to +11.82%0) were deposited from waters enriched in 16O whose isotopic composition was consistent with that of meteoric precipitation at low temperature and high latitude. The carbon of the calcite cleats (?? 13C(PDB) = -15.6 to -16.9%0) was derived in part from the coal (?? 13C(PDB) = -23.5 to -26.7%0) as carbon dioxide and by oxidation of methane or other hydrocarbon gases. The strontium ( 87Sr 86Sr = 0.71318-0.72392) originated primarily from altered feldspar grains in the sandstones of the Beacon Supergroup. Calcite cleats in the Kittaning No. 6 coal seam of Ohio (?? 18O(SMOW) = +26.04 to +27.79%0) were deposited from waters that had previously exchanged oxygen, possibly with marine carbonate at depth. The carbon (?? 13C(PDB) = 0.9 to +2.4%0) is enriched in 13C even though that cleats were deposited in coal that is highly enriched in 12C and apparently originated from marine carbonates. Strontium in the cleats ( Sr 87 0.71182-0.71260) is not of marine origin but contains varying amounts of radiogenic 87Sr presumably derived from detrital Rb-bearing minerals in the adjacent sedimentary rocks. The results of this study suggest that calcite cleats in coal of southern Victoria Land, Antarctica, were deposited after the start of glaciation in Cenozoic time and that those in Ohio precipitated from formation waters derived from the underlying marine carbonate rocks, probably in the recent geologic past. ?? 1984.

Chemical Geology↗

Implications of volcanism in coastal California for the Neogene deformation history of western North America

The geologic record of coastal California includes evidence of numerous volcanic centers younger than 30 Ma that do not appear to have erupted in an arc setting. By correlating these volcanic centers with specific slab windows predicted from analysis of magnetic anomalies on the Pacific plate, we add new constraints to tectonic reconstructions since 30 Ma. Our correlations, such as erupting the Morro Rock–Islay Hill complex south of the Pioneer fracture zone and the Iversen Basalt south of the Mendocino fracture zone, require larger displacements within western North America than advocated by most previous authors. Specifically, we infer at least 315 km of motion between the Sierra Nevada and rigid North America at an azimuth of about N60°W and at least 515 km between Baja California and rigid North America in a similar direction. A consequence of inferring a large displacement of Baja California is that the Pacific–North American plate boundary must have developed most of its current form prior to 10 Ma. We interpret a slab window developing between Cocos and Monterey plates after 19 Ma that reconstructs under nearly all of the southern California volcanic centers dated at 18–14 Ma. Most of the sedimentary basins associated with volcanic rocks show brief periods of rapid subsidence synchronous with volcanism, followed by slow subsidence of variable but often extended duration, consistent with rapid extension of cold lithosphere over recently introduced hot asthenosphere.

California↗

Sedimentary response to orogenic exhumation in the northern Rocky Mountain Basin and Range province, Flint Creek basin, west-central Montana

Middle Eocene through Upper Miocene sedimentary and volcanic rocks of the Flint Creek basin in western Montana accumulated during a period of significant paleoclimatic change and extension across the northern Rocky Mountain Basin and Range province. Gravity modelling, borehole data, and geologic mapping from the Flint Creek basin indicate that subsidence was focused along an extensionally reactivated Sevier thrust fault, which accommodated up to 800 m of basin fill while relaying stress between the dextral transtensional Lewis and Clark lineament to the north and the Anaconda core complex to the south. Northwesterly paleocurrent indicators, foliated metamorphic lithics, 64 Ma (40Ar/39Ar) muscovite grains, and 76 Ma (U-Pb) zircons in a ca. 27 Ma arkosic sandstone are consistent with Oligocene exhumation and erosion of the Anaconda core complex. The core complex and volcanic and magmatic rocks in its hangingwall created an important drainage divide during the Paleogene shedding detritus to the NNW and ESE. Following a major period of Early Miocene tectonism and erosion, regional drainage networks were reorganized such that paleoflow in the Flint Creek basin flowed east into an internally drained saline lake system. Renewed tectonism during Middle to Late Miocene time reestablished a west-directed drainage that is recorded by fluvial strata within a Late Miocene paleovalley. These tectonic reorganizations and associated drainage divide explain observed discrepancies in provenance studies across the province. Regional correlation of unconformities and lithofacies mapping in the Flint Creek basin suggest that localized tectonism and relative base level fluctuations controlled lithostratigraphic architecture.

Canadian Journal of Earth Sciences↗

Beach-ridge development and lake-level variation in southern Lake Michigan

The most accurate source of information on lake-level fluctuations in the Great Lakes is the historical record from lake-level gauges. Although it can be semiquantitatively extended back into the late 1700's, the historical record is too short to recognize long-term patterns of lake-level behavior. To extend the historical record, information must be obtained from the Great Lakes geologic record. Such information includes the elevation and age of geomorphic features and stratigraphic sequences. One of the longest geologic records of late Holocene lake-level variation is preserved in a beach-ridge complex along the southern shore of Lake Michigan called the Toleston Beach. This strandplain contains over 150 beach ridges that arc across northwestern Indiana and fan out into northeastern Illinois. Each ridge was formed during the fall from a high lake level, and the elevation of the foreshore deposits in each ridge provides information on the upper physical limit of lake level over the past 4000 years. Three scales of quasi-periodic lake-level variation were determined by radiocarbon-dating basal peats of wetlands between the ridges and by measuring the elevation of foreshore (swash) deposits within ridges. These three scales are: (1) a short-term and small-scale fluctuation of 25 to 35 years with a range of about 0.5 to 0.6 m; (2) an intermediate-term and meso-scale fluctuation of 140 to 160 years and a range of about 0.8 to 0.9 m; and (3) a long-term and large-scale fluctuation of 500 to 600 years and a range of 1.8 to 3.7 m. The short-term and intermediate-term fluctuations are reflected in the historical record. An increase in the rate of shoreline progradation from east to west across Indiana's shoreline causes differential preservation of the lake-level fluctuations. That is, groups of four to six ridges in the western part of the strandplain that formed in response to the small-scale fluctuations combine eastward into single ridges and groups of ridges representing the meso-scale fluctuations. The large-scale fluctuations produced the most dramatic response in the western part of the Toleston Beach. Here, following each high stand, individual spits prograded southward off of a bedrock headland. The successive spit extensions created several small lakes landward of the spits and started the 20 km eastward stream-mouth deflection of the Grand Calumet River across Indiana's western lakeshore.

Illinois, Indiana↗

Shoreface translation and the Holocene stratigraphic record: Examples from Nova Scotia, the Mississippi Delta and eastern Australia

Classic descriptive models of barrier sedimentation have been developed with data from the Atlantic and Gulf coasts of the United States. These models are dominated by low to moderate rates of relative sea level (RSL) rise and wave energy. Barriers respond by landward recycling of sediment through the mechanism of shoreface retreat. Sedimentation processes on the central coast of New South Wales (N.S.W.), Australia, consist of rapid RSL rise in early Holocene times followed by a stillstand since 6500 B.P. Wave energy is relatively high year-round and sand sources for barrier formation are only found on the inner shelf. Barrier sedimentation on the central coast of N.S.W. exhibits a thick, composite sequence composed of a basal marine transgressive sand overlain by regressive beach and dune facies. The Louisiana coast surrounding the Mississippi delta is underlain by compacting deltaic muds which generate very rapid rates of RSL rise. The Louisiana coast experiences low wave energy punctuated by high-energy tropical and extra-tropical storm events. Barrier sediments accumulate from the erosion of deltaic headlands and undergo a transformation from subaerial barrier island systems to subaqueous shoals located on the inner shelf. Drumlins experience coastal erosion on the Eastern Shore of Nova Scotia and provide a sediment source for compartmented estuary mouth barriers. An ongoing, moderate rise of RSL results from the passage of a glacial forebulge. Wave energy is intermediate between Louisiana and N.S.W. and displays a seasonal pattern dominated by frequent winter storms. Coastal barrier sedimentation is episodic, consisting of a period of beach ridge progradation followed by barrier destruction and re-establishment further landward. The three contrasting sedimentary sequences found in examples from Louisiana, N.S.W. and Nova Scotia indicate that presently available sedimentation models from locations such as the middle Atlantic or Texas coasts of the United States may only represent well-documented regional case studies. A true generalised coastal sedimentation model is required which can identify the parameters controlling vertical and horizontal translation of the depositional surface and provide relationships between these parameters which quantitatively predict the genesis, distribution and geometry of coastal sedimentary facies.

Marine Geology↗

Pocomoke Sound Sedimentary and Ecosystem History

Summary of Results: Pocomoke Sound Sediment and Sediment Processes Transport of sediment from coastal marshes. Analyses of pollen and foraminifera from surface sediments in Pocomoke Sound suggest that neither the upstream forested wetlands nor coastal marshes bordering the sound have contributed appreciably to particulate matter in the 10- to 1000-micron size range that is currently being deposited in the sound. Sediment processes derived from short-lived isotope. Analyses of beryllium-7, cesium-137 and lead-210 and redox sensitive elements from Pocomoke sediments showed that there has been a significant increase in anthropogenic elements since the late 1940's when the Delmarva Peninsula became more accessible from the Baltimore-Washington region. Cesium-137 was found to be a useful tool to determine changes in sedimentation within the system. Three major stages of sedimentation occurred. Before 1950, the system was equilibrium with the agriculture activity in the watershed, whereas urbanization and agricultural activity changes during and immediately preceding World War II resulted in increased sediment flux. Around 1970, the sediment flux diminished and there was an apparent increase in bank erosion sediment to the deeper parts of the system. Rates of sediment deposition. Radiocarbon, lead-210, and pollen dating of sediment cores from Pocomoke Sound indicate relatively continuous deposition of fine-grained sediments in the main Pocomoke channel at > ~7 m water depths. Mean sediment accumulation rates during the past few centuries were relatively high (>1 cm yr -1 ). The ages of coarser-grained sediments (sands) blanketing the shallow (< ~ 7 m water depth) flanks of Pocomoke Sound are not well constrained but were probably deposited discontinuously. Impacts of land-use on benthic biota. The Pocomoke Sound paleoecological record shows that in the 1940-50s and again in the 1970-80s, the sound experienced unprecedented changes in the benthic assemblages of both ostracodes and foraminifera that can be attributed to degradation in water quality. These changes represent perturbations to the natural variability in faunal assemblages, which are normally driven by climatically influenced changes in salinity regimes. Changes in 20th century benthic communities were characterized by the rise to dominance of facultative anaerobic taxa tolerant of hypoxia and detrital-feeding species, reflecting increased influx of organic matter, and perhaps greater turbidity. Results support the hypothesis of Orth et al. (2002) and Orth and Moore (1983) that unprecedented changes to the bay ecosystem affected submerged aquatic vegetation in the Tangiers-Pocomoke region prior to large-scale monitoring began in the 1970s and 80s. Comparison of Pocomoke paleoecological record with those from the mainstem bay indicate that environmental degradation during the 20th century was nearly synchronous bay-wide within the limits of sediment core chronology (10-20 years). Stable isotopic evidence for decadal water quality changes. Stable isotopic records from benthic foraminifera in Pocomoke Sound sediment cores, especially oxygen isotopes, document regional decadal and centennial climate processes which influence salinity and water quality over the past few centuries. These results provide indirect evidence for discharge-driven changes in freshwater and presumably river-borne sediment from the watershed to the sound. They are consistent with studies in the mainstem indicating the important influence of climatic and hydrological processes on water quality. Pollen evidence for high sedimentation and vegetation change during colonial land clearance. Pollen assemblages from sediment cores in Pocomoke Sound document high sedimentation rates (0.7->4.0 cm yr -1 ) at most sites throughout the Sound in post-Colonial time. These results confirm those from other regions of the bay that land-clearance increased the flux of river-borne sediment to certain r

Open-File Report↗

A regime shift in sediment export from a coastal watershed during a record wet winter, California: Implications for landscape response to hydroclimatic extremes

Small, steep watersheds are prolific sediment sources from which sediment flux is highly sensitive to climatic changes. Storm intensity and frequency are widely expected to increase during the 21st century, and so assessing the response of small, steep watersheds to extreme rainfall is essential to understanding landscape response to climate change. During record winter rainfall in 2016–2017, the San Lorenzo River, coastal California, had nine flow peaks representing 2–10‐year flood magnitudes. By the third flood, fluvial suspended sediment showed a regime shift to greater and coarser sediment supply, coincident with numerous landslides in the watershed. Even with no singular catastrophic flood, these flows exported more than half as much sediment as had a 100‐year flood 35 years earlier, substantially enlarging the nearshore delta. Annual sediment load in 2017 was an order of magnitude greater than during an average‐rainfall year, and 500‐fold greater than in a recent drought. These anomalous sediment inputs are critical to the coastal littoral system, delivering enough sediment, sometimes over only a few days, to maintain beaches for several years. Future projections of megadroughts punctuated by major atmospheric‐river storm activity suggest that interannual sediment‐yield variations will become more extreme than today in the western USA, with potential consequences for coastal management, ecosystems, and water‐storage capacity. The occurrence of two years with major sediment export over the past 35 years that were not associated with extremes of the El Niño Southern Oscillation or Pacific Decadal Oscillation suggests caution in interpreting climatic signals from marine sedimentary deposits derived from small, steep, coastal watersheds, to avoid misinterpreting the frequencies of those cycles.

California↗

The construction of Chasma Boreale on Mars

The polar layered deposits of Mars contain the planet’s largest known reservoir of water ice 1,2 and the prospect of revealing a detailed Martian palaeoclimate record 3,4 , but the mechanisms responsible for the formation of the dominant features of the north polar layered deposits (NPLD) are unclear, despite decades of debate. Stratigraphic analyses of the exposed portions of Chasma Boreale—a large canyon 500 km long, up to 100 km wide, and nearly 2 km deep—have led most researchers to favour an erosional process for its formation following initial NPLD accumulation. Candidate mechanisms include the catastrophic outburst of water 5 , protracted basal melting 6 , erosional undercutting 7 , aeolian downcutting 7,8,9 and a combination of these processes 10 . Here we use new data from the Mars Reconnaissance Orbiter to show that Chasma Boreale is instead a long-lived, complex feature resulting primarily from non-uniform accumulation of the NPLD. The initial valley that later became Chasma Boreale was matched by a second, equally large valley that was completely filled in by subsequent deposition, leaving no evidence on the surface to indicate its former presence. We further demonstrate that topography existing before the NPLD began accumulating influenced successive episodes of deposition and erosion, resulting in most of the present-day topography. Long-term and large-scale patterns of mass balance achieved through sedimentary processes, rather than catastrophic events, ice flow or highly focused erosion, have produced the largest geomorphic anomaly in the north polar ice of Mars.

Nature↗

Earthquake site response in Santa Cruz, California

Aftershocks of the 1989 Loma Prieta, California, earthquake are used to estimate site response in a 12-km 2 area centered on downtown Santa Cruz. A total of 258 S -wave records from 36 aftershocks recorded at 33 sites are used in a linear inversion for site-response spectra. The inversion scheme takes advantage of the redundancy of the large data set for which several aftershocks are recorded at each site. The scheme decomposes the observed spectra into source, path, and site terms. The path term is specified before the inversion. The undetermined degree of freedom in the decomposition into source and site spectra is removed by specifying the site-response factor to be approximately 1.0 at two sites on crystalline bedrock. The S -wave site responses correlate well with the surficial geology and observed damage pattern of the mainshock. The site-response spectra of the floodplain sites, which include the heavily damaged downtown area, exhibit significant peaks. The largest peaks are between 1 and 4 Hz. Five floodplain sites have amplification factors of 10 or greater. Most of the floodplain site-response spectra also have a smaller secondary peak between 6 and 8 Hz. Residential areas built on marine terraces above the floodplain experienced much less severe damage. Site-response spectra for these areas also have their largest peaks between 1 and 4 Hz, but the amplification is generally below 6. Several of these sites also have a secondary peak between 6 and 8 Hz. The response peaks seen at nearly all sites between 1 and 4 Hz are probably caused by the natural resonance of the sedimentary rock column. The higher amplifications at floodplain sites may be caused by surface waves generated at the basin margins. The secondary peak between 6 and 8 Hz at many sites may be a harmonic of the 1- to 4-Hz peaks.

California↗

Description of landscape features, summary of existing hydrologic data, and identification of data gaps for the Osage Nation, northeastern Oklahoma, 1890-2012

The Osage Nation of northeastern Oklahoma, conterminous with Osage County, is characterized by gently rolling uplands and incised stream valleys that have downcut into underlying sedimentary rock units of Pennsylvanian through Permian age. Cattle ranching and petroleum and natural-gas extraction are the principal land uses in this rural area. Freshwater resources in the Osage Nation include water flowing in the Arkansas River and several smaller streams, water stored in several lakes, and groundwater contained in unconsolidated alluvial aquifers and bedrock aquifers. The Vamoosa-Ada aquifer is the primary source of fresh groundwater in this area. Fresh groundwater is underlain by saline groundwater in aquifers underlying the Osage Nation. Because of the potential for future population increases, demands for water from neighboring areas such as the Tulsa metropolitan area, and expansion of petroleum and natural-gas extraction on water resources of this area, the U.S. Geological Survey, in cooperation with the Osage Nation, summarized existing hydrologic data and identified data gaps to provide information for planning of future development of water resources in the Osage Nation. Streamflows in the Osage Nation are substantially affected by precipitation. During the relatively wet periods from the 1970s to 2000, the annual streamflows in the Osage Nation increased by as much as a factor of 2 relative to preceding decades, with subsequent decreases in streamflow of as much as 50 percent being recorded during intermittent drier years of the early 2000s. This report summarizes hydrologic data from 3 surface-water sites and 91 wells distributed across the Osage Nation. Data collected at those sites indicate that surface water in the Osage Nation generally has sufficient dissolved oxygen for survival of both coldwater and warmwater aquatic biota. Total dissolved solids concentration exceeded the secondary drinking-water standard of 500 milligrams per liter (mg/L) in up to 75 percent of the surface-water samples, indicating limited availability of potable water at some sites. Some surface-water samples collected in the Osage Nation contained dissolved chloride concentrations exceeding the secondary drinking-water standard of 250 mg/L, with greater chloride concentrations in selected basins appearing to be associated with greater densities of petroleum well locations. Several lakes sampled in the Osage Nation from 2011–12 contained sufficient chlorophyll-a concentrations to be ranked as mesotrophic to eutrophic, indicating impairment by nutrients. Relatively large dissolved phosphorus concentrations in many surface-water samples, compared to water-quality standards, indicate that eutrophication can occur in local streams and lakes. The amount of fresh groundwater stored in alluvial aquifers and the Vamoosa-Ada bedrock aquifer is adequate for domestic and other purposes in the Osage Nation at the current rate of usage. In areas where these aquifers are absent, groundwater must be pumped from minor bedrock aquifers that produce smaller volumes of water. About 30 and 60 percent of 32 and 54 water samples collected from the alluvial and Vamoosa-Ada aquifers, respectively, contained total dissolved solids concentrations larger than the secondary drinking-water standard of 500 mg/L. Local factors, such as natural seepage of brines or leakage from petroleum and natural-gas extraction activities, may cause substantial variations in dissolved chloride concentration in groundwater in the Osage Nation. Total phosphorus concentrations measured in groundwater samples were similar to dissolved phosphorus concentrations measured in the base flow of several streams. Total fresh surface-water withdrawals (use) and fresh groundwater withdrawals in the Osage Nation were estimated to have increased from 0.75 to 16.19 million gallons per day and from 0.13 to 2.39 million gallons per day, respectively, over the period from 1890 through 2010. Estimated saline-groundwater reinjection volumes at the heavily developed Burbank Oil Field in the Osage Nation from 1950 through 2012 were many times larger than the total amounts of freshwater withdrawn in this area, with estimated increases in saline-groundwater reinjection in the 2000s probably being related to increased petroleum extraction. Estimates of freshwater resources in local streams, lakes, and freshwater aquifers and of net annual precipitation indicate that less than 1 percent of freshwater resources and net annual precipitation currently is being withdrawn annually in the Osage Nation. In addition to freshwater resources, the Osage Nation may be underlain by 45,000,000 million gallons of brines, a small portion of which are withdrawn and reinjected during petroleum and natural-gas extraction. Ongoing development of desalinization technology may lead to the ability to expand use of these saline waters in the future. Several additional studies could improve understanding of the hydrologic resources of the Osage Nation. Development of computer models (simulations) of groundwater and surface-water flow for this area could enable testing of scenarios of localized and widespread effects of future climate variations and water-use changes on streamflows, lake-water levels, and groundwater levels in the Osage Nation. Installation of additional long-term streamflow and water-quality sampling stations, some with continuous water-quality monitors, could expand and improve understanding of surface-water quality. Periodic measurement of groundwater levels and sampling of water from a network of wells could provide better information about trends of groundwater quantity and quality with time. Measurement of water withdrawals at selected sites could enable more accurate estimates of water use. Lastly, better understanding of aquifer properties and spatial distribution of saline groundwater provided by geophysical surveys could improve understanding of fresh and saline groundwater resources underlying the Osage Nation.

Oklahoma↗

Petrographic observations on the Exmore breccia, ICDP-USGS drilling at Eyreville, Chesapeake Bay impact structure, USA

The International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) Eyreville A and B drill cores sampled crater fill in the region of the crater moat, ??9 km to the NE of the center of the Chesapeake Bay impact structure, Virginia, USA. They provide a 953 m section (444-1397 m depth) of sedimentary clast breccia and intercalated sedimentary and crystalline megablocks knownas Exmore beds, deposited on top of the impactite sequence between 1397 and 1551 m depth. We petrographically investigated the sandy-clayey groundmass-dominated breccia, which resembles a diamictite ("Exmore breccia"), and which, in its lower parts, carries sedimentary and crystalline blocks. The entire breccia interval is characterizedby the presence of glauconite and bioclastic carbonate, which distinguishes the Exmore breccia from other sandy facies above and below in the stratigraphy. The sediment-clast breccia exhibits strong heterogeneity from sample to sample with respect to groundmass nature, e.g., clay versus sand content, as well as clast content, in general, and shocked clast content, in particular. There is a consistently signifi cantly larger macroscopic sedimentary to crystalline clast content. On the microscopic scale, the intersample sediment to crystalline clast ratios are quite variable. A very small component of shocked material, in the form of shock-deformed quartz, and to an even lesser degree feldspar, and somewhat more abundant but still relatively scarce shardshaped,altered melt particles, is present throughout the section. However, between ??458 and 469 m, and between 514 and 527 m depths, the abundance of such melt particlesis notably enhanced. These sections are also chemically distinct and relatively more mafic than the other parts of the Exmore breccia. It appears that from the time of deposition of the 527 m material, calming of the ocean occurred over the crater area as a result of abatement of resurge activity, so that ejecta from the plume abovethe crater could accumulate within the crater area to a larger degree. Deposition ofejecta fallout from the collapsing ejecta plume was terminated by the time of deposition of the 458 m material. This raises questions about the positioning of the exact upper contact of Exmore breccia to post-Exmore sediment (Chickahominy Formation), which is currently placed at 444 m depth and which possibly should be revisedto 458 m depth. Based on a signifi cant record of granite-derived material with shocked minerals, the shocked debris component seems to be largely derived from crystalline target rocks. This provides further evidence that the basement-derived material of the basal section of the Eyreville drill cores, which is essentially unshocked, is likely of an allochthonous nature and that the drilling did not intersect the actual crater floor. 76??W. ?? 2009 Geological Society of America.

Special Paper of the Geological Society of America↗

Geology and Mineral Resources of the East Mojave National Scenic Area, San Bernardino County, California

The rocks of the East Mojave National Scenic Area (EMNSA) record a history of dynamic geologic events that span more than 1,800 million years (m.y.). These geologic events contributed significantly to development of the spectacular vistas and panoramas present in the area today. The oldest rocks underlie much of the northern part of the EMNSA. These rocks were subjected to extreme pressures and temperatures deep in the Earth's crust about 1,700 million years ago (Ma). They were subsequently intruded by granitic magmas from about 1,695 to 1,650 Ma, by additional granitic magmas at about 1,400 Ma and, later, at about 1,100 Ma, by iron-rich magmas that crystallized to form dark igneous rocks termed diabase. Unusual potassium- and magnesium-rich rocks, emplaced at about 1,400 Ma, crop out in a few places within and near the EMNSA. Their distinctive composition results from very small degrees of partial melting of mantle peridotite that was highly enriched in incompatible trace elements. At Mountain Pass, just outside the northeast boundary of the EMNSA, the potassium- and magnesium-rich rocks are accompanied by a rare type of carbonatite, an igneous rock composed of carbonate minerals, that contains high-grade rare earth element mineralization. Subsequent to these igneous-dominated events, sedimentary strata began to be deposited at about 1,000 Ma; mostly sandstone and shale were deposited initially in marine and, less commonly, in continental environments along the west edge of the core of the North American continent. Sedimentation eventually culminated in the widespread deposition of thick marine limestones from about 400 to about 245 Ma. These limestones represent a continental-shelf environment where shallow-water limestone formed to the east and deeper water limestone formed to the west. The end of the formation of these sedimentary deposits probably was caused by uplift of the shelf, which marked the beginning of a long period of tectonic upheaval. At about 170 Ma, widespread emplacement of coarse-grained granitic magmas began again in the region; some of these magmas also erupted as volcanic rocks. Additional episodes of magmatism took place at about 100 Ma and at 75 Ma. Most of the metallic-mineral occurrences in the EMNSA are associated with the igneous rocks that range in age from 170 to 75 Ma. During each of these magmatic events, the previously deposited sedimentary strata were buckled and broken as the entire region, part of a continental-scale fold and thrust belt, underwent crustal shortening and compression. A period of tectonic quiescence characterized the region from about 65 Ma to about 20 Ma. The quiet period ended abruptly with widespread volcanism along the southern and eastern parts of the EMNSA. The major gold deposits in the Castle Mountains are associated with this episode of volcanism. During this volcanic outburst, the crust extended laterally in several areas that border the EMNSA: along the lower Colorado River 65 km to the east, in the Kingston Range 20 km to the north, and in the central Mojave Desert 75 km to the southwest. This extensional deformation is characterized by the superposition of upper-crustal rocks over midcrustal rocks along large flat-lying faults, several of which project beneath rocks now exposed at the surface in the EMNSA. The near-surface rocks of the EMNSA, however, apparently escaped much of this intense extensional deformation. High-angle faults, which cut several of the mountain ranges, possibly have undergone several periods of movement, which date back to approximately 70 to 100 Ma. Some faults are of local importance to the physiographic development of the mountain ranges and intervening basins, and, in places, the faults seem to have localized various kinds of ore bodies and mineral occurrences. Volcanism and extensional deformation waned from 14 to 11 Ma. By approximately 10 Ma, widespread erosion had produced broad erosional dome-shaped mountains in the n

Bulletin↗

Geochemical and climatic effects of increased marine organic carbon burial at the Cenomanian/Turonian boundary

Perhaps the most significant event in the Cretaceous record of the carbon isotope composition of carbonate 1,2 , other than the 1–2.5 ‰ negative shift in the carbon isotope composition of calcareous plankton at the Cretaceous/Tertiary boundary 3 , is the rapid global positive excursion of ∼ 2 ‰ ( 13 C enrichment) which took place between ∼ 91.5 Myr and 90.3 Myr (late Cenomanian to earliest Turonian (C/T boundary event)) 1,4,5 . This excursion has been attributed to a change in the isotope composition of the marine total dissolved carbon (TDC) reservoir resulting from an increase in rate of burial of 13 C-depleted organic carbon, which coincided with a major global rise in sea level 5 during the so-called C/T oceanic anoxic event (OAE) 6 . Here we present new data, from nine localities, which demonstrate that a positive excursion in the carbon isotope composition of organic carbon at or near the C/T boundary 7,8 is nearly synchronous with that for carbonate and is widespread throughout the Tethys and Atlantic basins (Fig. 1), as well as in more high-latitude epicontinental seas. The postulated increase in the rate of burial of organic carbon may have had a significant effect on CO 2 and O 2 concentrations in the oceans and atmosphere, and consequent effects on global climate and sedimentary facies.

Nature↗

Tectonic influence on axial-transverse sediment routing in the Denver Basin

Detrital zircon U-Pb and (U-Th)/He ages from latest Cretaceous–Eocene strata of the Denver Basin provide novel insights into evolving sediment sourcing, recycling, and dispersal patterns during deposition in an intracontinental foreland basin. In total, 2464 U-Pb and 78 (U-Th)/He analyses of detrital zircons from 21 sandstone samples are presented from outcrop and drill core in the proximal and distal portions of the Denver Basin. Upper Cretaceous samples that predate uplift of the southern Front Range during the Laramide orogeny (Pierre Shale, Fox Hills Sandstone, and Laramie Formation) contain prominent Late Cretaceous (84–77 Ma), Jurassic (169–163 Ma), and Proterozoic (1.69–1.68 Ga) U-Pb ages, along with less abundant Paleozoic through Archean zircon grain ages. These grain ages are consistent with sources in the western U.S. Cordillera, including the Mesozoic Cordilleran magmatic arc and Yavapai-Mazatzal basement, with lesser contributions of Grenville and Appalachian zircon recycled from older sedimentary sequences. Mesozoic zircon (U-Th)/He ages confirm Cordilleran sources and/or recycling from the Sevier orogenic hinterland. Five of the 11 samples from syn-Laramide basin fill (latest Cretaceous–Paleocene D1 Sequence) and all five samples from the overlying Eocene D2 Sequence are dominated by 1.1–1.05 Ga zircon ages that are interpreted to reflect local derivation from the ca. 1.1 Ga Pikes Peak batholith. Corresponding late Mesoproterozoic to early Neoproterozoic zircon (U-Th)/He ages are consistent with local sourcing from the southern Front Range that underwent limited Mesozoic–Cenozoic unroofing. The other six samples from the D1 Sequence yielded detrital zircon U-Pb ages similar to pre-Laramide units, with major U-Pb age peaks at ca. 1.7 and 1.4 Ga but lacking the 1.1 Ga age peak found in the other syn-Laramide samples. One of these samples yielded abundant Mesozoic and Paleozoic (U-Th)/He ages, including prominent Early and Late Cretaceous peaks. We propose that fill of the Denver Basin represents the interplay between locally derived sediment delivered by transverse drainages that emanated from the southern Front Range and a previously unrecognized, possibly extraregional, axial-fluvial system. Transverse alluvial-fluvial fans, preserved in proximal basin fill, record progressive unroofing of southern Front Range basement during D1 and D2 Sequence deposition. Deposits of the upper and lower D1 Sequence across the basin were derived from these fans that emanated from the southern Front Range. However, the finer-grained, middle portion of the D1 Sequence that spans the Cretaceous-Paleogene boundary was deposited by both transverse (proximal basin fill) and axial (distal basin fill) fluvial systems that exhibit contrasting provenance signatures. Although both tectonic and climatic controls likely influenced the stratigraphic development of the Denver Basin, the migration of locally derived fans toward and then away from the thrust front suggests that uplift of the southern Front Range may have peaked at approximately the Cretaceous-Paleogene boundary.

Colorado↗

Late Early Permian continental ichnofauna from Lake Kemp, north-central Texas, USA

Continental trace fossils of Early Permian age are well known in the western United States from Wolfcampian (~ Asselian to Artinskian) strata, but few examples are known from Leonardian (~ Kungurian) deposits. A substantial ichnofauna from strata of the lower part of the Clear Fork Formation at Lake Kemp, Baylor County, Texas, augments the meager North American record of Leonardian continental trace fossil assemblages. Ichnofossils at Lake Kemp occur in the informally-named Craddock dolomite member of the Clear Fork Formation, which is 12–15 m above the local base of the Clear Fork. The trace-bearing stratum is an up-to-0.3 m thick, laminated to flaser-bedded, dolomitic siltstone that also contains mud cracks, raindrop impressions, microbially induced mat structures, and some land-plant impressions. We interpret the Craddock dolomite member as the feather-edge of a marine transgressive carbonate deposit of an irregular coastline marked by shallow bays or estuaries on the eastern shelf of the Midland basin, and the trace-fossil-bearing stratum at Lake Kemp is an unchannelized flow deposit on a muddy coastal plain. The fossil site at Lake Kemp yields a low to moderately diverse fauna of invertebrate and vertebrate traces. A sparse invertebrate ichnofauna consists of arthropod feeding and locomotion traces assigned to Walpia cf. W. hermitensis White, 1929 and Diplichnites gouldi Gevers in Gevers et al., 1971. Tetrapod footprints are most common and assigned to Batrachichnus salamandroides (Geinitz, 1861), cf. Amphisauropus kablikae (Geinitz and Deichmüller, 1882), and Dromopus lacertoides (Geinitz, 1861), which represent small temnospondyl, seymouriamorph, and basal sauropsid trackmakers. Both the traces and sedimentary features of the fossil horizon indicate a freshwater setting at the time of track formation, and the trace assemblage represents the Scoyenia ichnofacies and the Batrachichnus ichnofacies in an overbank environment with sheet flooding and shallow ephemeral pools on an extensive coastal plain. The Lake Kemp tetrapod track assemblage is characteristic of the global Early Permian tetrapod ichnofauna found in red beds, which is dominated by a handful of ichnogenera that include Batrachichnus, Limnopus, Amphisauropus, Dromopus, Varanopus, Hyloidichnus, Ichniotherium and Dimetropus, which are the tracks of temnospondyls, seymouriamorphs, diadectomorphs, “pelycosaurs”, “captorhinomorphs”, and araeoscelids. The Lake Kemp tracks also further document the continuity of the ichnogenera Batrachichnus, Amphisauropus and Dromopus from Wolfcampian into Leonardian time and thus support the concept that Wolfcampian and Leonardian red-bed tetrapod footprints represent a single biostratigraphic assemblage.

Texas↗

Hydrogeology of, and simulation of ground-water flow in, a mantled carbonate-rock system, Cumberland Valley, Pennsylvania

The U.S. Geological Survey conducted a study in a highly productive and complex regolith-mantled carbonate valley in the northeastern part of the Cumberland Valley, Pa., as part of its Appalachian Valleys and Piedmont Regional Aquifer-system Analysis program. The study was designed to quantify the hydrogeologic characteristics and understand the ground-water flow system of a highly productive and complex thickly mantled carbonate valley. The Cumberland Valley is characterized by complexly folded and faulted carbonate bedrock in the valley bottom, by shale and graywacke to the north, and by red-sedimentary and diabase rocks in the east-southeast. Near the southern valley hillslope, the carbonate rock is overlain by wedge-shaped deposit of regolith, up to 450 feet thick, that is composed of residual material, alluvium, and colluvium. Locally, saturated regolith is greater than 200 feet thick. Seepage-run data indicate that stream reaches, near valley walls, are losing water from the stream, through the regolith, to the ground-water system. Results of hydrograph-separation analyses indicate that base flow in stream basins dominated by regolith-mantled carbonate rock, carbonate rock, and carbonate rock and shale are 81.6, 93.0, and 67.7 percent of total streamflow, respectively. The relative high percentage for the regolith-mantled carbonate-rock basin indicates that the regolith stores precipitation and slowly, steadily releases this water to the carbonate-rock aquifer and to streams as base flow. Anomalies in water-table gradients and configuration are a result of topography and differences in the character and distribution of overburden material, permeability, rock type, and geologic structure. Most ground-water flow is local, and ground water discharges to nearby springs and streams. Regional flow is northeastward to the Susquehanna River. Average-annual water budgets were calculated for the period of record from two continuous streamflow-gaging stations. Average-annual precipitation range from 39.0 to 40.5 inches, and averages about 40 inches for the model area. Average-annual recharge, which was assumed equal to the average-annual base flow, ranged from 12 inches for the Conodoguinet Creek, and 15 inches for the Yellow Breeches Creek. The thickly-mantled carbonate system was modeled as a three- dimensional water-table aquifer. Recharge to, ground-water flow through, and discharge from the Cumberland Valley were simulated. The model was calibrated for steady-state conditions using average recharge and discharge data. Aquifer horizontal hydraulic conductivity was calculated from specific-capacity data for each geologic unit in the area. Particle-tracking analyses indicate that interbasin and intrabasin flows of groundwater occur within the Yellow Breeches Creek Basin and between the Yellow Breeches and Conodoguinet Creek Basins.

Pennsylvania↗

Local earthquake Vp and Vs tomography in the Mount St. Helens region with the iMUSH broadband array

We present new 3-D P wave and S wave velocity models of the upper 20 km of the Mount St. Helens (MSH) region. These were obtained using local-source arrival time tomography from earthquakes and explosions recorded at 70 broadband stations deployed as part of the imaging Magma Under St. Helens (iMUSH) project and augmented by several data sets. Principal features of our models include (1) low P wave and S wave velocities along the St. Helens seismic zone to depths of at least 20 km corresponding to high conductivity imaged by iMUSH magnetotelluric studies. This delineates a zone of weakness that magma can exploit at the location of MSH; (2) a 5- to 7-km diameter, 6–15 km deep, 3–6% negative P wave and S wave velocity anomaly beneath MSH, consistent with previous estimates of the source region for recent eruptions. We interpret this as a magma storage region containing up to 15–20 km 3 of partial melt, which is about 5 times more than the largest documented eruption at MSH; (3) a broad region of low P wave velocity below 10-km depth extending between Mount Adams and Mount Rainier along and to the east of the main Cascade arc, which is likely due to high-temperature arc crust and possible presence of fluids or melt; (4) several anomalies associated with surface-mapped features, including high-velocity igneous units such as the Spud Mountain and Spirit Lake plutons and low velocities in the Chehalis sedimentary basin and the Indian Heaven volcanic field. Our results place further constraints on the geometry of these features at depth.

Washington↗

Coarse-clast ridge complexes of the Caribbean: A preliminary basis for distinguishing tsunami and storm-wave origins

Coastal gravel-ridge complexes deposited on islands in the Caribbean Sea are recorders of past extreme-wave events that could be associated with either tsunamis or hurricanes. The ridge complexes of Bonaire, Jamaica, Puerto Rico (Isla de Mona), and Guadeloupe consist of polymodal clasts ranging in size from sand to coarse boulders that are derived from the adjacent coral reefs or subjacent rock platforms. Ridge-complex morphologies and crest elevations are largely controlled by availability of sediments, clast sizes, and heights of wave runup. The ridge complexes are internally organized, display textural sorting and a broad range of ages including historical events. Some display seaward-dipping beds and ridge-and-swale topography, and some terminate in fans or steep avalanche slopes. Together, the morphologic, sedimentologic, lithostratigraphic, and chronostratigraphic evidence indicates that shore-parallet ridge complexes composed of gravel and sand that are tens of meters wide and several meters thick are primarily storm-constructed features that have accumulated for a few centuries or millennia as a result of multiple high-frequency intense-wave events. They are not entirely the result of one or a few tsunamis as recently reported. Tsunami deposition may account for some of the lateral ridge-complex accretion or boulder fields and isolated blocks that are associated with the ridge complexes. Copyright ?? 2008, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗