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At least 685 records · Page 38Linked to original sources
USGS1999

Correlation of soil and sediment organic matter polarity to aqueous sorption of nonionic compounds

Polarities of the soiL/sediment organic matter (SOM) in 19 soil and 9 freshwater sediment sam pies were determined from solid-state 13C-CP/MAS NMR spectra and compared with published partition coefficients (K(oc)) of carbon tetrachloride (CT) from aqueous solution. Nondestructive analysis of whole samples by solid-state NMR permits a direct assessment of the polarity of SOM that is not possible by elemental analysis. The percent of organic carbon associated with polar functional groups was estimated from the combined fraction of carbohydrate and carboxylamide-ester carbons. A plot of the measured partition coefficients (K(oc)) of carbon tetrachloride (CT) vs. percent polar organic carbon (POC) shows distinctly different populations of soils and sediments as well as a roughly inverse trend among the soil/sediment populations. Plots of K(oc) values for CT against other structural group carbon fractions did not yield distinct populations. The results indicate that the polarity of SOM is a significant factor in accounting for differences in K(oc) between the organic matter in soils and sediments. The alternate direct correlation of the sum of aliphatic and aromatic structural carbons with K(oc) illustrates the influence of nonpolar hydrocarbon on solute partition interaction. Additional elemental analysis data of selected samples further substantiate the effect of the organic matter polarity on the partition efficiency of nonpolar solutes. The separation between soil and sediment samples based on percent POC reflects definite differences of the properties of soil and sediment organic matters that are attributable to diagenesis.Polarities of the soil/sediment organic matter (SOM) in 19 soil and 9 freshwater sediment samples were determined from solid-state 13C-CP/MAS NMR spectra and compared with published partition coefficients (Koc) of carbon tetrachloride (CT) from aqueous solution. Nondestructive analysis of whole samples by solid-state NMR permits a direct assessment of the polarity of SOM that is not possible by elemental analysis. The percent of organic carbon associated with polar functional groups was estimated from the combined fraction of carbohydrate and carboxyl-amide-ester carbons. A plot of the measured partition coefficients (Koc) of carbon tetrachloride (CT) vs. percent polar organic carbon (POC) shows distinctly different populations of soils and sediments as well as a roughly inverse trend among the soil/sediment populations. Plots of Koc values for CT against other structural group carbon fractions did not yield distinct populations. The results indicate that the polarity of SOM is a significant factor in accounting for differences in Koc between the organic matter in soils and sediments. The alternate direct correlation of the sum of aliphatic and aromatic structural carbons with Koc illustrates the influence of nonpolar hydrocarbon on solute partition interaction. Additional elemental analysis data of selected samples further substantiate the effect of the organic matter polarity on the partition efficiency of nonpolar solutes. The separation between soil and sediment samples based on percent POC reflects definite differences of the properties of soil and sediment organic matters that are attributable to diagenesis.

Environmental Science & Technology↗
USGS2010

The onset of metamorphism in ordinary and carbonaceous chondrites

Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by X-ray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO-rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr-rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr-rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr 3+ . Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re-enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to subdivide types 3.0 and 3.1 into types 3.00 through 3.15. On this basis, the most primitive ordinary chondrite known is Semarkona, although even this meteorite has experienced a small amount of metamorphism. Allan Hills (ALH) A77307 is the least metamorphosed CO chondrite and shares many properties with the ungrouped carbonaceous chondrite Acfer 094. Analytical problems are significant for glasses in type II chondrules, as Na is easily lost during microprobe analysis. As a result, existing schemes for chondrule classification that are based on the alkali content of glasses need to be revised.

Meteoritics and Planetary Science↗
USGS1976

An experiment in earthquake control at Rangely, Colorado

An experiment in an oil field at Rangely, Colorado, has demonstrated the feasibility of earthquake control. Variations in seismicity were produced by controlled variations in the fluid pressure in a seismically active zone. Precise earthquake locations revealed that the earthquakes clustered about a fault trending through a zone of high pore pressure produced by secondary recovery operations. Laboratory measurements of the frictional properties of the reservoir rocks and an in situ stress measurement made near the earthquake zone were used to predict the fluid pressure required to trigger earthquakes on preexisting fractures. Fluid pressure was controlled by alternately injecting and recovering water from wells that penetrated the seismic zone. Fluid pressure was monitored in observation wells, and a computer model of the reservoir was used to infer the fluid pressure distributions in the vicinity of the injection wells. The results of this experiment confirm the predicted effect of fluid pressure on earthquake activity and indicate that earthquakes can be controlled wherever we can control the fluid pressure in a fault zone.

Colorado↗
USGS2009

Ecology and the ratchet of events: climate variability, niche dimensions, and species distributions

Climate change in the coming centuries will be characterized by interannual, decadal, and multidecadal fluctuations superimposed on anthropogenic trends. Predicting ecological and biogeographic responses to these changes constitutes an immense challenge for ecologists. Perspectives from climatic and ecological history indicate that responses will be laden with contingencies, resulting from episodic climatic events interacting with demographic and colonization events. This effect is compounded by the dependency of environmental sensitivity upon life-stage for many species. Climate variables often used in empirical niche models may become decoupled from the proximal variables that directly influence individuals and populations. Greater predictive capacity, and more-fundamental ecological and biogeographic understanding, will come from integration of correlational niche modeling with mechanistic niche modeling, dynamic ecological modeling, targeted experiments, and systematic observations of past and present patterns and dynamics.

Proceedings of the National Academy of Sciences↗
USGS2014

Occurrence and origin of Escherichia coli in water and sediments at two public swimming beaches at Lake of the Ozarks State Park, Camden County, Missouri, 2011-13

In the past several years, the Missouri Department of Natural Resources has closed two popular public beaches, Grand Glaize Beach and Public Beach 1, at Lake of the Ozarks State Park in Osage Beach, Missouri when monitoring results exceeded the established Escherichia coli (E. coli) standard. As a result of the beach closures, the U.S. Geological Survey and Missouri University of Science and Technology, in cooperation with the Missouri Department of Natural Resources, led an investigation into the occurrence and origins of E. coli at Grand Glaize Beach and Public Beach 1. The study included the collection of more than 1,300 water, sediment, and fecal source samples between August 2011 and February 2013 from the two beaches and vicinity. Spatial and temporal patterns of E. coli concentrations in water and sediments combined with measurements of environmental variables, beach-use patterns, and Missouri Department of Natural Resources water-tracing results were used to identify possible sources of E. coli contamination at the two beaches and to corroborate microbial source tracking (MST) sampling efforts. Results from a 2011 reconnaissance sampling indicate that water samples from Grand Glaize Beach cove contained significantly larger E. coli concentrations than adjacent coves and were largest at sites at the upper end of Grand Glaize Beach cove, indicating a probable local source of E. coli contamination within the upper end of the cove. Results from an intensive sampling effort during 2012 indicated that E. coli concentrations in water samples at Grand Glaize Beach cove were significantly larger in ankle-deep water than waist-deep water, trended downward during the recreational season, significantly increased with an increase in the total number of bathers at the beach, and were largest during the middle of the day. Concentrations of E. coli in nearshore sediment (sediment near the shoreline) at Grand Glaize Beach were significantly larger in foreshore samples (samples collected above the shoreline) than in samples collected in ankle-deep water below the shoreline, significantly larger in the left and middle areas of the beach than the right area, and substantially larger than similar studies at E. coli- contaminated beaches on Lake Erie in Ohio. Concentrations of E. coli in the water column also were significantly larger after resuspension of sediments. Results of MST indicate a predominance of waterfowl-associated markers in nearshore sediments at Grand Glaize Beach consistent with frequent observations of goose and vulture fecal matter in sediment, especially on the left and middle areas of the beach. The combination of spatial and temporal sampling and MST indicate that an important source of E. coli contamination at Grand Glaize Beach during 2012 was E. coli released into the water column by bathers resuspending E. coli-contaminated sediments, especially during high-use days early in the recreational season.

Missouri↗
USGS2023

The geometry and kinematics of the latest paleozoic Allatoona Fault, one of the youngest thrusts in the southernmost Appalachian Hinterland, Alabama and Georgia, U.S.A.

The Allatoona thrust fault in the southernmost hinterland of the Appalachian Blue Ridge-Piedmont megathrust sheet is among the latest structures in the kinematic sequence of events along the west flank of the orogen. It is an out-of-sequence, craton-directed thrust fault that cuts metamorphic isograds and earlier thrusts, and it has a nearly linear trace of ≥280 km, making it one of the major thrust faults in the orogen. On the northwest, the fault cuts Pennsylvanian or younger(?) regional cross antiforms that cause significant orogenic curvature of older underlying thrust sheets and is likely Permian in age. To the southeast, however, units within the fault hanging wall maintain a nearly constant width resulting in a significant change in the regional structural architecture of the orogen. In the central segment of the fault, where it marks the western/eastern Blue Ridge domain boundary, a ~20 km-long eyelid window (Mulberry Rock window) framed by three amphibolite facies thrust sheets overlying the greenschist facies Talladega belt allochthon, allows a 3-D view into the structural architecture, kinematics, and trajectories of the regional thrusts. Two earlier thrusts within the window (Mulberry Rock and Burnt Hickory Ridge thrusts, with a combined minimum horizontal net slip component of 27 km) are cut by the Allatoona fault, which is a ~15 m-wide high strain zone with top-to-the-northwest displacement, and a >17.2 km horizontal net slip vector. Structural branch points between the Allatoona and Mulberry Rock thrusts indicate that the Mulberry Rock allochthon is a large north-trending horse beneath the Allatoona fault, centered on the Mulberry Rock window, which is likely the result of oblique ramp thrusting over the massive Mulberry Rock Gneiss. The Allatoona fault cuts down obliquely into the tectonostratigraphy progressively deeper both to the northeast and northwest, locally approaching underlying foreland thrust sheets, and cutting older regional structures. To the northeast, the Allatoona fault lies at the base of the Dahlonega gold belt, becoming an internal eastern Blue Ridge thrust at Dawsonville, Georgia. Although that sequence extends another 120 km into North Carolina, continuation of the Allatoona fault that additional distance is in debate. Regardless, the Allatoona is one of the kinematically latest and longest faults in the southern Appalachian orogen.

Alabama, Georgia, South Carolina↗
USGS2016

Establishing links between streamflow and ecological integrity in the Sudbury River (Northeastern U.S.)

With increased pressure from a growing human population, managers are challenged to understand how novel disturbances (e.g., climate change, increased water withdrawals, urbanization) may affect natural resources. The Sudbury River is a National Wild and Scenic River located in suburban Boston, Massachusetts (Northeastern US) with myriad impairments (e.g., mainstem impoundments, withdrawals, and urbanization) that is under increasing pressure from hydrologic alteration. We sampled fish, mussel, and macroinvertebrate assemblages in the Sudbury River and used species traits to investigate potential effects of past and future flow alteration on biota. Analysis of 33 years of stream gage data indicates continued hydrologic alteration of the Sudbury River, likely related to increased urbanization and water withdrawals over that time. These changes include a roughly 200% increase in rise rates of flows, an approximate 65% decrease in 1-day minimum flows, and a trend towards increasing high flow pulse counts. Biotic sampling in summer of 2014 demonstrated that the Sudbury River is now dominated by generalist species. Of five mussel species sampled, all are generalists in their habitat requirements. Though one mussel species of special concern was sampled, the most abundant species collected were the widespread Eastern elliptio (58%) and Eastern lampmussel (40%). We used the target fish community (TFC) model to assess the degree to which the fish assemblage deviated from that expected for a river with similar zoogeographic and physical features. Overall, the current community has a 22.7% similarity to the TFC. Of the four fluvial specialist species present in the TFC, only fallfish was sampled in our study. While the TFC showed that the historical assemblage was likely dominated by fluvial specialist and fluvial dependent species, the current assemblage is overwhelmingly dominated by macrohabitat generalists (90.6% of fishes sampled). These results are consistent with other studies that show shifts in assemblages from fluvial specialists to habitat generalists with hydrologic alteration. If the current trends continue, it is likely that biotic assemblages will experience increasing pressure from hydrologic alteration. While hydrologic alteration is likely impacting biotic assemblages in the Sudbury River, other factors such as high temperatures, low dissolved oxygen, high nutrients, low availability of high-quality habitat, and poor habitat connectivity may also be negatively impacting biotic assemblages. Comparisons to other rivers and a complete longitudinal habitat survey could help to identify availability of unique habitats and representativeness of this study. While this study suggests impacts of flow on biota, future studies with quantitative, habitat-specific sampling during different flow levels could help to directly identify links between hydrologic alteration and biotic impairment in the Sudbury River.

Massachussetts↗
USGS2024

Prioritizing US Geological Survey science on salinization and salinity in candidate and selected priority river basins

The US Geological Survey (USGS) is selecting and prioritizing basins, known as Integrated Water Science basins, for monitoring and intensive study. Previous efforts to aid in this selection process include a scientifically defensible and quantitative assessment of basins facing human-caused water resource challenges (Van Metre et al. in Environmental Monitoring and Assessment , 192(7), 458 2020). In the present work, we explore this ranking process based on water quality considerations, specifically salinity and salinization. We selected top candidate basins to study salinity and salinization issues in 18 hydrologic regions that include 163 candidate basins. Our prioritization is based on quantitative assessment of sources of salinity, drivers of change, and receptors that must respond to those sources and drivers. Source terms represented in the prioritization include geology, depth to brackish groundwater, stream conductivity, chloride in precipitation, urban and agricultural land use, application of road salt as a deicer, and irrigation. Drivers represented in prioritization include changes in chemical weathering as a result of changes in rainwater chemistry. Receptors include measures of water stress, measurements of stream ecological health, and socioeconomic factors. In addition, we present research activities for the USGS on salinity and salinization that can be pursued in these basins including assessment of sources, pathways, and loadings; predicting and understanding changes in sources, peaks, and trends; understanding the components of salinity and mobilization of contaminants; understanding the relationship between salinization and changing ecosystems; and developing knowledge on the causes and distribution of groundwater salinity, brackish water resources, and challenges related to desalination.

Enviornmental Monitoring and Assessment↗
USGS1994

Determination of atrazine in rainfall and surface water by enzyme immunoassay

Rainwater and surface water from four sites in Germany (Bavaria and Lower Saxony) were analyzed for atrazine by enzyme immunoassay from June 1990 until October 1992. The limit of quantification of the immunoassay was 0.02 μg/L with a middle of the test at 0.2 μg/L. About 60 % of the samples contained measurable amounts of atrazine. Seasonal trends were observed, with the highest concentration in the summer months of up to 4 μg/L for rainwater and up to 15 μg/L for surface waters. The highest concentrations were found in agricultural areas, while in the investigated national parks up to 0.56 μg/L could be detected in rain water. This points to long-range atmospheric transport from agricultural areas to pristine national parks. Samples from forest stands usually showed higher atrazine concentrations than samples from open fields. Deposition rates of 10 – 50 μg/m 2 · yr were observed in the national parks and 10–180 μg/m 2 · yr at the agricultural sites. Comparison of results obtained by enzyme immunoassay and GC/MS showed a good correlation of r = 0.95.

Environmental Science and Pollution Research↗
USGS1983

Vapor phase exsolution as a controlling factor in hydrogen isotope variation in granitic rocks: the Notch Peak granitic stock, Utah

The Notch Peak granitic stock, western Utah, is comprised of three concentric sequentially intruded rock types, from granite at the rim, to quartz monzonite I, to quartz monzonite II at the core. The δ 18 O values of whole rocks vary about an average of 9.4 (SMOW), irrespective of the rock type and position relative to contact, suggesting that the three magmas had the same parent. The whole rock δD values in the stock range from −100 to −55. δD values increase toward the cores of both quartz monzonite I and quartz monzonite II, resulting in concentric contours. The δD contours of quartz monzonite II cross-cut those of quartz monzonite I, suggesting little isotopic interaction between these bodies and the absence of a late pervasive fluid phase. There is a positive correlation between δD values and water content of the samples, where samples from each body define a distinct field. The positive correlation is explained by isotopic fractionation attendant on vapor exsolution from the crystallizing magma. An observed increase in δD with the degree of chloritization, a trend opposite to that observed in systems where participation of meteoric water has been demonstrated, is the result of subsolidus interaction with the exsolved fluids. These results show that large variations in the hydrogen isotope ratios of a granitoid can arise by exsolution of a vapor phase from the melt on crystallization. In general, magmas with larger modal amount of primary hydrous phases will tend to have higher δD values than those with small amounts of hydrous phases. Furthermore, the relatively high δD values of chlorites at Notch Peak confirm the applicability of classical concepts of closed-system deuteric alteration to some granitoid bodies. Thus, meteoric water interaction need not be always invoked to explain hydrogen isotope variation and deuteric alteration in granitoids.

Earth and Planetary Science Letters↗
USGS1984

Geochemistry of tholeiitic and alkalic lavas from the Koolau Range, Oahu, Hawaii: Implications for Hawaiian volcanism

Lavas of the post-erosional, alkalic Honolulu Volcanics have significantly lower 87 Sr/ 86 Sr and higher 143 Nd/ 144 Nd than the older and underlying Koolau tholeiites which form the Koolau shield of eastern Oahu, Hawaii. Despite significant compositional variation within lavas forming the Honolulu Volcanics, these lavas are isotopically (Sr, Nd, Pb) very similar which contrasts with the isotopic heterogeneity of the Koolau tholeiites. Among Hawaiian tholeiitic suites, the Koolau lavas are geochemically distinct because of their lower iron contents and Sr and Nd isotopic ratios which range to bulk earth values. These geochemical data preclude simple models such as derivation of the Honolulu Volcanics and Koolau tholeiites from a common source by different degrees of melting or by mixing of two geochemically distinct sources. There may be no genetic relationship between the origin and evolution of these two lava suites; however, the trend shown by Koolau Range lavas of increasing 143 Nd/ 144 Nd and decreasing 87 Sr/ 86 Sr with decreasing eruption age and increasing alkalinity also occurs at Haleakala, East Molokai and Kauai volcanoes. A complex mixing model proposed for Haleakala lavas can account for the variations in Sr and Nd isotopic ratios and incompatible element abundances found in lavas from the Koolau Range. This model may reflect mixing and melting processes occurring during ascent of relatively enriched mantle through relatively depleted MORB-related lithosphere. Although two isotopically distinct components may be sufficient to explain Sr and Nd isotopic variations at individual Hawaiian volcanoes, more than two isotopically distinct materials are required to explain variations of Sr, Nd and Pb isotopic ratios in all Hawaiian lavas.

Hawaii↗
USGS2022

Looking ahead, guided by the past: The role of U.S. national parks in amphibian research and conservation

Protected areas like national parks are essential elements of conservation because they limit human influence on the landscape, which protects biodiversity and ecosystem function. The role of national parks in conservation, however, often goes far beyond limiting human influence. The U.S. National Park Service and its system of land units contribute substantively to conservation by providing protected lands where researchers can document trends in species distributions and abundances, examine characteristics important for generating these trends, and identify and implement conservation strategies to preserve biodiversity. We reviewed the contribution of U.S. national parks to amphibian research and conservation and highlight important challenges and findings in several key areas. First, U.S. national parks were instrumental in providing strong support that amphibian declines were real and unlikely to be simply a consequence of habitat loss. Second, research in U.S. national parks provided evidence against certain hypothesized causes of decline, like UV-B radiation, and evidence for others, such as introduced species and disease. However, describing declines and identifying causes contributes to conservation only if it leads to management; importantly, U.S. national parks have implemented many conservation strategies and evaluated their effectiveness in recovering robust amphibian populations. Among these, removal of invasive species, especially fishes; conservation translocations; and habitat creation and enhancement stand out as examples of successful conservation strategies with broad applicability. Successful management for amphibians is additionally complicated by competing mandates and stakeholder interests; for example, past emphasis on increasing visitor enjoyment by introducing fish to formerly fishless lakes had devastating consequences for many amphibians. Other potential conflicts with amphibian conservation include increasing development, increased risk of introductions of disease and exotic species with increased visitation, and road mortality. Decision science and leveraging partnerships have proven to be key components of effective conservation under conflicting mandates in national parks. As resource managers grapple with large-scale drivers that are outside local control, public-private partnerships and adaptive strategies are increasing in importance. U.S. national parks have played an important role in many aspects of identifying and ameliorating the amphibian decline crisis and will continue to be essential for the conservation of amphibians in the future.

Ecological Indicators↗
USGS2002

Identification of lithofacies using Kohonen self-organizing maps

Lithofacies identification is a primary task in reservoir characterization. Traditional techniques of lithofacies identification from core data are costly, and it is difficult to extrapolate to non-cored wells. We present a low-cost automated technique using Kohonen self-organizing maps (SOMs) to identify systematically and objectively lithofacies from well log data. SOMs are unsupervised artificial neural networks that map the input space into clusters in a topological form whose organization is related to trends in the input data. A case study used five wells located in Appleton Field, Escambia County, Alabama (Smackover Formation, limestone and dolomite, Oxfordian, Jurassic). A five-input, one-dimensional output approach is employed, assuming the lithofacies are in ascending/descending order with respect to paleoenvironmental energy levels. To consider the possible appearance of new logfacies not seen in training mode, which may potentially appear in test wells, the maximum number of outputs is set to 20 instead of four, the designated number of lithosfacies in the study area. This study found eleven major clusters. The clusters were compared to depositional lithofacies identified by manual core examination. The clusters were ordered by the SOM in a pattern consistent with environmental gradients inferred from core examination: bind/boundstone, grainstone, packstone, and wackestone. This new approach predicted lithofacies identity from well log data with 78.8% accuracy which is more accurate than using a backpropagation neural network (57.3%). The clusters produced by the SOM are ordered with respect to paleoenvironmental energy levels. This energy-related clustering provides geologists and petroleum engineers with valuable geologic information about the logfacies and their interrelationships. This advantage is not obtained in backpropagation neural networks and adaptive resonance theory neural networks. ?? 2002 Elsevier Science Ltd. All rights reserved.

Computers & Geosciences↗
USGS2021

Informing future condition scenario planning for habitat specialists of the imperiled pine rockland ecosystem of South Florida

This project evaluated habitat conditions for two species found in the imperiled pine rockland ecosystem—the Rim Rock Crowned Snake ( Tantilla oolitica ) and the Key Ring-Necked Snake ( Diadophis punctatus acricus ). The Rim Rock Crowned Snake historically occurred in eastern Miami-Dade County (hereafter, mainland) as well as throughout the Florida Keys, whereas the Key Ring-Necked Snake occurs only in lower Florida Keys (Enge et al. 2004; Mays and Enge 2016). Both species are very elusive, small (< 20 cm in length) and primarily fossorial. Pine rockland habitat is rapidly disappearing in South Florida, with < 3 percent of its original extent remaining. Saltwater intrusion from hurricanes and sea-level rise (SLR), and human development pose the greatest threats to the longevity of this ecosystem which, in turn, places species that are endemic to this unique habitat at risk of extinction. The Rim Rock Crowned Snake and the Key Ringed-Necked Snake are being considered for listing by the U.S. Fish and Wildlife Service (USFWS). To aid the agency’s decision, it must be able to forecast species’ responses to potential future environmental conditions, as well as to different conservation and management actions. Yet, the information needed to complete these forecasts—such as population trends, life history traits, habitat use, and future land use and climate conditions—is often lacking for most rare species. This is especially problematic for assessments of species resiliency to changes in climate and land use. When these types of data are lacking, information on habitat quality can be used to help determine how a species will respond to change. First, this project gathered current and historical records for both species from various sources such as museum specimens, inventories, and other personal account. Then, we identified potential future changes in habitat that could result from different management actions, such as habitat acquisition or restoration, and environmental conditions, such as changes in the frequency and intensity of tropical storms and rates of SLR. Researchers then explored the potential impacts of these habitat condition changes on the Rim Rock Crowned Snake and Key Ring-Necked Snake. This information can be used by the USFWS to help make decisions about the need to protect these species under the Endangered Species Act and could inform the conservation, management, and recovery of other at-risk species found in the pine rockland ecosystem. This work supports the Secretary of Interior’s priority to create a conservation stewardship legacy by using science to identify best practices to manage land and water resource and adapt to changes in the environment.

Florida↗
USGS2026

Optimizing cryo-focused pyrolysis GC/MS for tracing soil organic matter across diverse ecosystems

The cycling of organic matter in terrestrial soils and sediments is central to a range of biogeochemical processes that regulate nutrient cycling, crop productivity, trace gas emissions, and contaminant transport. Pyrolysis-gas chromatography/mass spectrometry (py-GC/MS) is a powerful tool for characterizing bulk soil organic matter (SOM) at the molecular level. In this study, we used a cryo-focused py-GC/MS system to analyze soil samples from seven diverse ecosystems: vernal pool, prairie pothole, temperate forest, tropical forest, tundra, wildfire-affected boreal forest, and grassland. We addressed a key bottleneck in molecular-level SOM characterization by developing an automated data analysis pipeline to optimize py-GC/MS and complementary evolved gas analysis/mass spectrometry (EGA/MS) methods, incorporating advanced tools for data deconvolution, developing a custom compound class library, and implementing fragmentation spectrum-based molecular networking for the first time. This improved workflow was applied to soil samples from all seven ecosystems, including multiple depths and density fractions. Our findings demonstrate that ecosystem type plays a dominant role in shaping compositional differences in SOM. We also identified trends in the source of SOM compounds (e.g., microbial vs. plant-derived) across soil depth and density fractions, which are critical for understanding persistence and turnover of SOM. Our molecular networking analysis indicated that although many compounds are widespread across ecosystems, others are restricted to specific environments, such as wetlands. This underscores the utility of molecular-level data in elucidating the complexity of SOM composition and the environmental drivers that shape it. Such molecular-level insights can deepen our knowledge of biogeochemical SOM cycles.

Environmental Science and Technology↗
USGS2026

Region-specific understanding of virus transmission to support salmonid health at hatcheries in three regions of the Pacific Northwest, North America

Juvenile salmonid mortality due to infectious haematopoietic necrosis virus (IHNV) can be a major burden on fish hatcheries. We consider possible IHNV transmission routes and specialist–generalist patterns across three regions in the Pacific Northwest of North America: Coastal Washington and Oregon (CWO), Lower Columbia River Basin (LCRB) and Snake River Basin (SRB) to obtain multi-region inference about IHNV transmission and specialization. While individual regions have been studied previously, our consideration of three regions to identify consistent trends or localized patterns is novel. The most consistent patterns we found were that most exposure to IHNV was from migrating adult salmonids and that the IHNV lineage MD specialized in steelhead and rainbow trout. Our results were consistent with LCRB being a source of IHNV and the SRB and CWO being sinks. Results specific to particular regions include the role of local geography on exposure and influence of hatchery complexes on transmission, which highlights the need to understand local hatchery operations before disease ecology can be understood and suitable hatchery management can be planned. Results demonstrate the need for spatially and temporally explicit quantitative approaches to understand disease dynamics and inform management.

Oregon, Washington↗
USGS2020

A newly emerging thermal area in Yellowstone

Yellowstone is a large restless caldera that contains many dynamic thermal areas that are the surface expression of the deeper magmatic system. In 2018, using a Landsat 8 nighttime thermal infrared image, we discovered the emergence of a new thermal area located near Tern Lake on the northeast margin of the Sour Creek dome. A high-spatial-resolution airborne visible image from August 2017 revealed a large (~33,000 m2) area of recently fallen trees, mostly devoid of vegetation, with bright soil, similar to other nearby thermal areas. Field observations in August 2019 confirmed that this was a steam-heated acid-sulfate thermal area, with an arc-shaped zone of hydrothermally altered soil and heated ground, with surface temperatures of 60-80 °C, several steaming fumaroles, and boiling temperatures (93 °C) just beneath the surface. Fallen trees in contact with warm ground were being carbonized, yet there were some cooler areas with new trees growing. Observations of stressed or dying vegetation from archived satellite and airborne remote sensing data going back to 1994 indicated that this thermal area started emerging around 2000. It increased in size slowly until around 2005, when the radiative heat output started measurably increasing. From 2005 to 2012 it grew more rapidly; and from 2012 through 2019 the growth rate slowed and the heat output stabilized. We predict that this stabilizing trend will continue in the coming years. The initial formation of this new thermal area was not clearly linked to any distinct seismic or geodetic events, although the period of rapid growth partly coincided with a period of rapid local uplift, possibly suggesting a causative relationship. The identification of this emerging thermal area illustrates the importance of satellite thermal infrared imaging combined with high-spatial-resolution remote sensing data and field observations for mapping, measuring, and monitoring Yellowstone's thermal areas. It is also an example of the dynamics we expect to observe within large caldera systems like Yellowstone, where changes in the size and distribution of thermal areas are normal and do not indicate an impending eruption nor any significant changes in the broader magmatic system.

Wyoming↗
USGS2020

Spatiotemporal variability of light attenuation and net ecosystem metabolism in a back-barrier estuary

Quantifying system-wide biogeochemical dynamics and ecosystem metabolism in estuaries is often attempted using a long-term continuous record at a single site or short-term records at multiple sites due to sampling limitations that preclude long-term monitoring. However, differences in the dominant primary producer at a given location (e.g., phytoplankton versus benthic producers) control diel variations in dissolved oxygen and associated ecosystem metabolism, and they may confound metabolic estimates that do not account for this variability. We hypothesize that even in shallow, well-mixed estuaries there is strong spatiotemporal variability in ecosystem metabolism due to benthic and water-column properties, as well as ensuing feedbacks to sediment resuspension, light attenuation, and primary production. We tested this hypothesis by measuring hydrodynamic properties, biogeochemical variables (fluorescent dissolved organic matter – fDOM, turbidity, chlorophyll a fluorescence, dissolved oxygen), and photosynthetically active radiation (PAR) over 1 year at 15 min intervals at paired channel (unvegetated) and shoal (vegetated by eelgrass) sites in Chincoteague Bay, Maryland–Virginia, USA, a shallow back-barrier estuary. Light attenuation ( K dPAR ) at all sites was dominated by turbidity from suspended sediment, with lower contributions from fDOM and chlorophyll a . However, there was significant seasonal variability in the resuspension–shear stress relationship on the vegetated shoals, but not in adjacent unvegetated channels. This indicated that K dPAR on the shoals was mediated by submerged aquatic vegetation (SAV) and possibly microphytobenthos presence in the summer, which reduced resuspension and therefore K dPAR . We also found that gross primary production ( P g ) and K dPAR were significantly negatively correlated on the shoals and uncorrelated in the channels, indicating that P g over the vegetated shoals is controlled by a feedback loop between benthic stabilization by SAV and/or microphytobenthos, sediment resuspension, and light availability. Metabolic estimates indicated substantial differences in net ecosystem metabolism between vegetated and unvegetated sites, with the former tending towards net autotrophy in the summer. Ongoing trends of SAV loss in this and other back-barrier estuaries suggest that these systems may also shift towards net heterotrophy, reducing their effectiveness as long-term carbon sinks. With regards to temporal variability, we found that varying sampling frequency between 15 min and 1 d resulted in comparable mean values of biogeochemical variables, but extreme values were missed by daily sampling. In fact, daily resampling minimized the variability between sites and falsely suggested spatial homogeneity in biogeochemistry, emphasizing the need for high-frequency sampling. This study confirms that properly quantifying ecosystem metabolism and associated biogeochemical variability requires characterization of the diverse estuarine environments, even in well-mixed systems, and demonstrates the deficiencies introduced by infrequent sampling to the interpretation of spatial variability.

Maryland, Virginia↗