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At least 685 records · Page 38Linked to original sources
USGS2019

Hydrologic balance, water quality, chemical-mass balance, and geochemical modeling of hyperalkaline ponds at Big Marsh, Chicago, Illinois, 2016–17

Hyperalkaline (pH greater than 12) ponds and groundwater exist at Big Marsh near Lake Calumet, Chicago, Illinois, a site used by the steel industry during the mid-1900s to deposit steel- and iron-making waste, in particular, slag. The hyperalkaline ponds may pose a hazard to human health and the environment. The U.S. Geological Survey (USGS), in cooperation with the Environmental Protection Agency (EPA) and in collaboration with the City of Chicago’s Park District, completed a study to evaluate the hydrologic balance, water quality, and chemical-mass balance of hyperalkaline ponds at Big Marsh and geochemical modeling used to evaluate remediation options for water quality at the site based on data collected in 2016–17. Synoptic measurements of surface-water and groundwater elevations were used to determine flow directions and to enable a preliminary estimate of the hydrologic balance for the ponds. Water-quality samples also were collected and analyzed for selected constituents including major anions and cations, nutrients, metals, and trace elements. The results of the water-quality analyses were used to develop a geochemical model to evaluate concentrations, factors affecting pH, and the state of equilibrium between surface waters and atmospheric carbon dioxide. The geochemical model was used to evaluate remediation scenarios using riprap, spillways, or active aeration. The results indicate that active aeration will decrease the pH to near 7.5 in about 8 hours, the fastest rate of the scenarios. Passive aeration, such as riprap or spillways, also can be effective at decreasing the pH in about 45 hours, but spatial obstacles limit their implementation. Seasonal variations in temperature also affect the rate of equilibration, where colder temperatures may have a lower pH than warmer temperatures and may affect the timing and frequency of remediation.

Illinois↗
USGS2020

Simulation of water-management scenarios for the Mississippi Delta

To compare the effectiveness of proposed alternative water-supply scenarios on future water availability in the Mississippi Delta, the U.S. Geological Survey and the Mississippi Department of Environmental Quality are collaborating on the update and enhancement of an existing regional groundwater-flow model of the area. Through this collaboration, the model has been updated to include boundary conditions through March 2014 with the most recent water-use data, precipitation and recharge data, and streamflow and water-level observation data. The updated model has been used to evaluate selected alternative water-supply scenarios to determine relative effects on the Mississippi River Valley alluvial aquifer. Alternative water-supply options evaluated in this report include: (1) irrigation efficiency, (2) on-farm storage and tailwater recovery, (3) instream weirs to increase surface-water availability, (4) intrabasin transfer of surface water, and (5) groundwater transfer and injection. A relative comparison approach was used to calculate the simulated water-level response caused by each scenario. Water-level response is the difference between water levels simulated by the alternative water-supply scenario and those simulated by a base or “no action” scenario. Water-level response in the alluvial aquifer varied for each scenario based on the location, magnitude, and (or) adoption rates of the simulated alternative water-supply option. The groundwater transfer and injection scenario showed the largest water-level response.

Arkansas, Louisiana, Mississippi, Missouri↗
USGS2022

Understanding sources and distribution of Escherichia coli at Lake St. Clair Metropark Beach, Macomb County, Michigan

Lake St. Clair Metropark Beach (LSCMB) in Michigan is a public beach near the mouth of the Clinton River that has a history of beach closures for public health concerns. The Clinton River is designated as a Great Lakes Area of Concern, and the park has a Beneficial Use Impairment for beach closings because of elevated Escherichia coli ( E. coli ) concentrations. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and in collaboration with the Michigan Department of the Environment, Great Lakes, and Energy, Macomb County Health Department, and Huron-Clinton Metroparks, completed a 2-year study to determine sources of E. coli in LSCMB. Samples were collected during dry and wet weather periods to observe the sampling sites under different conditions. Nearshore surface water samples were collected biweekly July through October in 2018 and May through September in 2019. There were 20 sampling sites along the shoreline of the park and in the channel north of the park. In addition to collecting nearshore surface-water samples, samples were collected from shallow groundwater, lake-bottom material, standing water on the beach and surrounding the recreational beach area, solids (beach sands and detritus), and offshore surface-water sites. In 2019, additional samples for microbial source tracking (MST) were collected on three dates in midsummer and were analyzed for human (HF183) and bird/waterfowl (GFD) MST markers. The concentrations of E. coli at LSCMB (in order of highest to lowest E. coli concentrations) were as follows: shallow groundwater nearest to the water’s edge, surface sands and organic matter (detritus), standing water on the beach, nearshore surface water in and surrounding the recreational beach area, lake-bottom material, and offshore surface water. The combination of low E. coli concentrations offshore and higher concentrations nearshore indicate nearshore sources, possibly from beach sands or groundwater, rather than sources coming from offshore Lake St. Clair waters. The subset of samples for MST analysis did not have enough positive results to illustrate MST trends, but this study demonstrated that both human and waterfowl sources can affect the water quality at LCSMB.

Michigan↗
USGS2021

Continuous monitoring and Bayesian estimation of nutrient and sediment loads from Illinois watersheds, for water years 2016–2020

The State of Illinois is one of the leading contributors of nitrogen, phosphorus, and suspended sediment to the Mississippi River and the Gulf of Mexico. During water years 2016–20, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, operated continuous monitoring stations on eight major rivers in Illinois to better quantify nutrient and sediment loadings from the State of Illinois to the Mississippi River. This report estimates nitrate, phosphorus, and suspended-sediment loadings over that period, which can provide a benchmark against which to assess future changes in loading. In addition, this report develops a new method for incorporating the uncertainty created by gaps in continuous datasets based on Bayesian machine learning. Data gaps are a common problem in continuous monitoring, and gap filling is necessary to quantify loadings and the uncertainty in loadings, which is essential if these results are to provide a benchmark for future studies. The uncertainty estimates may also be useful in an operational context, and this report provides examples of how uncertainty can be used in monitoring-network design and potentially reducing monitoring costs.

Illinois↗
USGS2024

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island↗
USGS2025

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma↗
USGS2000

Effect of Georgetown Lake on the water quality of Clear Creek, Georgetown, Colorado, 1997-98

Georgetown Lake is a recreational reservoir located in the upper Clear Creek Basin, a designated Superfund site because of extensive metal mining in the past. Metals concentrations in Clear Creek increase as the stream receives runoff from mining-affected areas. In 1997, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, began a study to determine the effect of the reservoir on the transport of metals in Clear Creek. A bathymetric survey determined the capacity of the reservoir to be about 440 acre-feet of water, which remained constant during the study. Average water residence time in the reservoir is about 1-3 days during high flow. During low flow (10 cubic feet per second), average residence is about 22 days without ice cover and about 15 days with a 3-foot-thick ice cover. Sediment samples collected from the bottom of Georgetown Lake contained substantial concentrations of iron (average 25,500 milligrams per kilogram), aluminum (average 12,300 milligrams per kilogram), zinc (2,830 milligrams per kilogram), lead (618 milligrams per kilogram), manganese (548 milligrams per kilogram), and sulfide minerals (average 602 milligrams per kilogram as S). Sediment also contained abundant sulfate-reducing bacteria, indicating anoxic conditions. Algae and diatoms common to cold-water lakes were identified in sediment samples; one genus of algae is known to adapt to low-light conditions such as exist beneath ice cover. Vertical profiles of temperature, specific conductance, pH, and dissolved-oxygen concentrations were measured in the reservoir on July 28, 1997, when inflow to the reservoir was about 170 cubic feet per second and average residence time of water was about 1.3 days, and on February 13, 1998, when the reservoir was covered with about 3 feet of ice, inflow was about 15 cubic feet per second, and average residence time was about 12 days. The measurements on July 28, 1997, showed that the reservoir water was well mixed, although pH and dissolved-oxygen concentrations were increased by photosynthesis near the bottom of the reservoir. Measurements on February 13, 1998, indicated thermal and chemical stratification with warmer water (about 4 degrees Celsius) beneath colder water and increases in pH and dissolved-oxygen concentrations generally occurring near the top of the warmer layer. Concentrations of dissolved oxygen were saturated to over-saturated throughout the water column on both dates, although the concentrations were greater on February 13, 1998, because of colder temperature and photosynthesis. Median pH was about 0.5 unit higher on February 13, 1998, than on July 28, 1997, largely because the longer residence time on February 13, 1998, allowed greater cumulative effects of photosynthesis. Samples of inflow and outflow water were collected from August 1997 to August 1998. Dissolved cadmium and dissolved lead in inflow and outflow samples exceeded acute and chronic water-quality standards during some of the sampling period, whereas dissolved zinc exceeded both standards in inflow and outflow samples during the entire sampling period. Chromium, nickel, and silver were detected in a few samples at small concentrations. Arsenic, selenium, and thallium were not reported in any water samples. Georgetown Lake removes some metals from inflow water and releases others to outflow water. From August 1997 to August 1998, Georgetown Lake estimated outflow loads were about 21 percent less than the inflow load of cadmium and about 11 percent less than the inflow load of zinc. Estimated inflow loads were about 18 percent less than the outflow load of copper, about 13 percent less than the outflow load of iron, and about 27 percent less than the outflow load of manganese. Inflow and outflow loads of lead were essentially balanced. The outflow load of nitrite plus nitrate was about 14 percent less than the inflow load, probably because of plant uptake.

Colorado↗
USGS2000

Ground-water quality in the upper Santa Cruz Basin, Arizona, 1998

Fifty-eight ground-water samples were collected and analyzed in 1998 by the U.S. Geological Survey and the Arizona Department of Environmental Quality to assess ground-water quality and to identify factors affecting ground-water quality in the Upper Santa Cruz Basin. In addition, pre-existing groundwater quality data for six wells were analyzed to determine changes in the ground-water quality of the basin over time. Twenty-nine percent of the ground-water samples collected had concentrations of at least one constituent that exceeded a Federal or State water-quality standard. The Maximum Contaminant Levels of the U.S. Environmental Protection Agency and the aquifer water-quality standards of the State of Arizona were exceeded for arsenic, fluoride, and nitrite plus nitrate. The Secondary Maximum Contaminant Levels of the U.S. Environmental Protection Agency were exceeded for fluoride, iron, manganese, pH, sulfate, and dissolved solids. Ground-water quality in the basin is affected by natural factors and human activities. The natural factors that have the most effect on ground-water quality in the basin are depth in the aquifer and distance from major faults. Ground-water temperatures and pH significantly increased with well depth (p≤0.05). Concentrations of dissolved solids, alkalinity, calcium, potassium, chloride, and sulfate were significantly higher in samples collected from wells less than 2 kilometers from major faults than in samples from wells greater than 2 kilometers from major faults (p≤0.05). Previous studies have attributed this relation to the upward migration through faults of ground water from gypsiferous mudstones. Ground-water quality was not significantly different among the various basin-fill units; between parts of the basin fill that differ in thickness, lateral extent, and composition north and south of an inferred fault; or among areas that differ in distance from stream alluvium (p>0.05). Human activities have a substantial effect on ground-water quality in the basin. Ground water that contained recent (post-1953) recharge from urban areas had significantly higher concentrations of nitrite plus nitrate than ground water that did not contain recent recharge from the land surface (p≤0.05). Ground water that contained recent recharge from present agricultural areas had significantly higher concentrations of nitrite plus nitrate, calcium, and potassium than ground water that did not contain recent recharge from the land surface (p≤0.05). Ground water that contained recent recharge from present agricultural areas also had significantly higher concentrations of calcium, potassium, alkalinity, and dissolved solids than ground water that contained recent recharge from urban areas (p≤0.05). Pre-existing ground-water quality data for six wells indicated that from the 1980s to 1998, concentrations of nitrite plus nitrate and dissolved solids significantly increased at a well in an agricultural area, concentrations of nitrite plus nitrate significantly increased at a well where the land use had changed from rangeland to urban, and concentrations of nitrite plus nitrate and dissolved solids significantly decreased at a well in an urban area (p≤0.10). Constituents did not significantly increase or decrease from the 1980s to 1998 at an additional well in an agricultural area, at an additional well where the land use had changed from rangeland to urban, and at a well where the land use had changed from agricultural to urban (p≤0.10).

Arizona↗
USGS2001

Statewide water-quality network for Massachusetts

A water-quality monitoring program is proposed that would provide data to meet multiple information needs of Massachusetts agencies and other users concerned with the condition of the State's water resources. The program was designed by the U.S. Geological Survey and the Massachusetts Department of Environmental Protection, Division of Watershed Management, with input from many organizations involved in water-quality monitoring in the State, and focuses on inland surface waters (streams and lakes). The proposed monitoring program consists of several components, or tiers, which are defined in terms of specific monitoring objectives, and is intended to complement the Massachusetts Watershed Initiative (MWI) basin assessments. Several components were developed using the Neponset River Basin in eastern Massachusetts as a pilot area, or otherwise make use of data from and sampling approaches used in that basin as part of a MWI pilot assessment in 1994. To guide development of the monitoring program, reviews were conducted of general principles of network design, including monitoring objectives and approaches, and of ongoing monitoring activities of Massachusetts State agencies.Network tiers described in this report are primarily (1) a statewide, basin-based assessment of existing surface-water-quality conditions, and (2) a fixed-station network for determining contaminant loads carried by major rivers. Other components, including (3) targeted programs for hot-spot monitoring and other objectives, and (4) compliance monitoring, also are discussed. Monitoring programs for the development of Total Maximum Daily Loads for specific water bodies, which would constitute another tier of the network, are being developed separately and are not described in this report. The basin-based assessment of existing conditions is designed to provide information on the status of surface waters with respect to State water-quality standards and designated uses in accordance with the reporting requirements [Section 305(b)] of the Clean Water Act (CWA). Geographic Information System (GIS)-based procedures were developed to inventory streams and lakes in a basin for these purposes. Several monitoring approaches for this tier and their associated resource requirements were investigated. Analysis of the Neponset Basin for this purpose demonstrated that the large number of sites needed in order for all the small streams in a basin to be sampled (about half of stream miles in the basin were headwater or first-order streams) pose substantial resource-based problems for a comprehensive assessment of existing conditions. The many lakes pose similar problems. Thus, a design is presented in which probabilistic monitoring of small streams is combined with deterministic or targeted monitoring of large streams and lakes to meet CWA requirements and to provide data for other information needs of Massachusetts regulatory agencies and MWI teams.The fixed-station network is designed to permit the determination of contaminant loads carried by the State's major rivers to sensitive inland and coastal receiving waters and across State boundaries. Sampling at 19 proposed sites in 17 of the 27 major basins in Massachusetts would provide information on contaminant loads from 67 percent of the total land area of the State; unsampled areas are primarily coastal areas drained by many small streams that would be impossible to sample within realistic resource limitations. Strategies for hot-spot monitoring, a targeted monitoring program focused on identifying contaminant sources, are described with reference to an analysis of the bacteria sampling program of the 1994 Neponset Basin assessment. Finally, major discharge sites permitted under the National Pollutant Discharge Elimination System (NPDES) were evaluated as a basis for ambient water-quality monitoring. The discharge sites are well distributed geographically among basins, but are primarily on large rivers (two-thirds or more

Water-Resources Investigations Report↗
USGS2002

Dissolved cadmium, zinc, and lead loads from ground-water seepage into the South Fork Coeur d'Alene River system, northern Idaho, 1999

The valley of the South Fork Coeur d’Alene River and some of its tributaries have been heavily impacted by the dispersion of metal-enriched materials from the Coeur d’Alene mining district since 1884. The valley floor, including the unconsolidated valley-fill/flood-plain aquifers, is a major holding area for mine tailings. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, characterized groundwater and surface-water relations for parts of the South Fork Coeur d’Alene River Basin and quantified the loading of dissolved metals into the South Fork Coeur d’Alene River system from groundwater seepage. This information can be used to determine the effects of dissolved metal from ground-water seepage on the river system and to evaluate the necessity and feasibility of remediation along gaining reaches. This study defines a field approach that can be repeated during and after the implementation of remediation solutions to measure the effectiveness of these efforts in reducing loading to streams. The study area includes three reaches along the South Fork Coeur d’Alene River valley in the Coeur d’Alene mining district in central Shoshone County, northern Idaho: a 3.3-mile reach of Canyon Creek at Woodland Park, a 4.8-mile reach of the South Fork Coeur d’Alene River near Osburn, and a 6.5-mile reach of the South Fork Coeur d’Alene River near Kellogg and Smelterville. Seepage studies were conducted during July 27–29; September 17–19; and October 15–17, 1999. Each seepage study was conducted over a 3-day period, during which each station was measured on a daily basis for streamflow, and waterquality samples were collected. The consecutiveday approach allowed for an evaluation of variability in streamflow gains and losses and metal loading that resulted from changing hydrologic conditions. During the July, September, and October seepage studies, ground-water seepage was the predominant source for gains in dissolved cadmium and zinc loads in the three study reaches, whereas tributary inflow loads were a minor source. The overall average net gain in dissolved zinc load from ground-water seepage into the South Fork Coeur d’Alene River near Kellogg and Smelterville was about 730 pounds per day, compared with the net gains in Canyon Creek at Woodland Park and the South Fork Coeur d’Alene River near Osburn, which were roughly similar at 150 and 218 pounds per day, respectively. The net gain in dissolved cadmium load from ground-water seepage into the three river reaches was about two orders of magnitude less than the gain in dissolved zinc. On the South Fork Coeur d’Alene River study reaches near Osburn and near Kellogg and Smelterville, no pattern associated with an increase or decrease in dissolved lead load along gaining or losing subreaches was recognizable. Canyon Creek at Woodland Park was the only study reach where ground-water seepage contributed appreciably to the dissolved lead load; the average net gain was 1.5 pounds per day. The average dissolved lead loads leaving South Fork Coeur d’Alene River study reaches (corrected for tributary inflow along the study reaches) near Osburn and near Kellogg and Smelterville were 1.4 and 0.8 pounds per day less, respectively, than the loads entering the study reaches. The decrease in dissolved lead could be the result of lead adsorbing onto organic and inorganic sediment surfaces and (or) coprecipitating with iron and manganese oxides. These forms of lead likely will be resuspended into the water column at high flows.

Idaho↗
USGS1984

An assessment of cumulative impacts of coal mining on the hydrology in part of the Powder River structural basin, Wyoming: A progress report

The U.S. Geological Survey and the Wyoming Department of Environmental Quality are involved in a cooperative effort to assess the probable cumulative impacts of coal mining on the hydrology of a part of the Powder River Structural Basin in Wyoming. It was assumed that the principal impacts on the ground-water system due to mining will occur in the relatively shallow aquifers which can be grouped into three homogeneous aquifers, namely, the Wyodak coal, the overburden, and the under burden. Emphasis of this report is on the results of analysis of surface-water resources in the Caballo Creek drainage. A surface-water model of the Caballo Creek drainage was developed using the Hydrological Simulation Program-Fortran model to help assess the impacts of mining activities on streamflow. The Caballo Creek drainage was divided into 10 land segments and 6 stream reaches in the modeling process. Three simulation runs show little, if any, change in streamflow between pre- and post-mining conditions and very little change between pre-mining and during-mining conditions. The principal reason for the absence of change is the high infiltration rate used in the model for all three conditions.

Wyoming↗
USGS1989

Hydrogeology and results of aquifer tests in the vicinity of a hazardous-waste disposal site near Byron, Illinois

The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted an investigation of a Superfund Site near Byron, Illinois. The purpose of the investigation was to determine the hydrogeologic properties of the Galena-Platteville and St. Peter aquifers, the primary water-supply aquifers for domestic supply in the area. The Galena and Platteville Groups and older St. Peter Sandstone are separated by the Harmony Hill Shale Member of the Glenwood Formation. The Harmony Hill Shale Member is a semiconfining unit. Groundwater flow in the study area is from the site northwestward to the Rock River. Movement of groundwater in the dolomites is mainly through joints, fractures, and solution openings. Analysis of the Galena-Platteville aquifer-test data indicates that the calculated aquifer transmissivity ranges from 490 to 670 sq ft/day, and the calculated specific yield ranges from 0.017 to 0.140. Aquifer test data also indicate that the Galena-Platteville aquifer is heterogeneous and anisotropic. Analysis of the St. Peter aquifer-test data indicates that the calculated transmissivity of the aquifer ranges from 1,200 to 1 ,305 sq ft/day, storativity ranges from 0.000528 to 0.00128, horizontal hydraulic conductivity ranges from 2.9 to 3.1 ft/day, and leakage through the Harmony Hill Shale Member ranges from .000123 to .000217 ft/day/ft.

Illinois↗
USGS1993

Contribution of return flows to streamflow in selected stream reaches in Illinois, 1988-89

Water returns by sewage-treatment plants and various water users can be a significant part of streamflow. Knowledge of the effect of return flows on stream- flow is needed for purposes of assessing streamwater quality and water supply. The results of a study by the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, are presented to describe the contribution of return flows to streamflow for five stream reaches in Illinois during 1988-89. The reaches studied were South Branch Kishwaukee River upstream from De Kaib, Mackinaw River upstream from Congerville, Addison Creek upstream from Bellwood, Flag Creek upstream from Willow Springs, and Thorn Creek upstream from Glenwood. The annual average contributions of return flows to streamflow in each reach ranged from 1 to 99 percent of the annual average streamflow. Return flows significantly affected streamflows in the Flag Creek and Thorn Creek reaches. Significant return flows probably sustained streamflows in the Addison Creek, Flag Creek, and Thorn Creek reaches. Return flows exceeded streamflow during at least 1 month during the 1988 drought at all of the study reaches, except the Thorn Creek reach. Of the amount of return flows that exceeded streamflow, all reaches lost an estimated 0.01 to 0.34 Mgal/d (million gallons per day) to evaporation and 0.36 to 1.33 Mgal/d to infiltration. An analysis-of-variance test indicated that return flows did not differ among seasons. A second analysis indicated that the proportion of return flows to streamflow did differ seasonally. Return flows during July through September 1988-89 constituted a large proportion (67 percent) of the annual streamflows.

Water-Resources Investigations Report↗
USGS1997

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Effects of nutrient management on quality of surface runoff and ground water at a small carbonate-rock site near Ephrata, Pennsylvania, 1984-90

The U.S. Geological Survey and the Pennsylvania Department of Environmental Protection conducted a study from 1984 to 1990 to determine theeffects of the implementation and practice of nutrient management [an agricultural best-management practice (BMP)] on the quality of surface runoff and ground water at a 55-acre crop and livestock farm in carbonate terrain nearEphrata, Pa. Implementation of nutrient management at Field-Site 2 resulted in application decreases of 33 percent for nitrogen and 29 percent for phosphorus. There wereno significant changes in nitrogen or phosphorusloads for a given amount of runoff from the pre-BMP to the post-BMP periods. However, less than 2 percent of the applied nutrients weredischarged with runoff throughout the study period.After the implementation of nutrient management, statistically significant decreases in concentrations of nitrate in ground-water samples occurred at threeof the four wells monitored throughout the pre- and post-BMP periods. The largest decreases in nitrate concentrations occurred at wells where samples hadthe largest nitrate concentrations prior to nutrient management. Changes in nitrogen applications to the contributing areas of five wells were correlated with nitrate concentrations of the well water. The correlations between the timing and amount of applied nitrogen and changes in ground-water quality met the four conditions that are characteristic of a cause-effect relation: an association, consistency, responsiveness, and a mechanism. Changes in ground-water nitrate concentrations lagged behind changes in loading of nitrogen fertilizers (primarily manure) by approximately 4 to 19 months.

Pennsylvania↗
USGS1997

Characterization of fill deposits in the Calumet region of northwestern Indiana and northeastern Illinois

In October 1993, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, began a study of the fill deposits in the Calumet region of northwestern Indiana and northeastern Illinois. Fill in this area is a mixture of steel-industry wastes, other industrial waste, municipal solid waste, dredging spoil, construction debris, ash, cinders, natural materials, and biological sludge. Fill deposits are concentrated along Lake Michigan; from the Lake Calumet area to the east of the Indiana Harbor Canal; along the Calumet, Little Calumet, and Grand Calumet Rivers; and along the Calumet Sag Channel. Industrial wastes and municipal solid wastes are used as fill near Lake Calumet. Steel-industry wastes, primarily slag, are used as fill along Lake Michigan, Wolf Lake, Lake George, parts of Lake Calumet, and parts of the Calumet and Little Calumet Rivers. Dredging spoil is located along the rivers, and in abandoned river channels, landfills, and tailing ponds. Cinders, ash, construction debris, and natural materials are scattered throughout the area. Currently (1996), fill covers about 60.2 square miles of the study area. A total volume of about 2.1 x 1010 cubic feet of fill was calculated to be present in the Calumet region. Most of this fill is steel-industry waste. Fill deposition in the study area has been essentially continuous from about 1870 to the present (1996). Fill deposited before 1964 was used as foundation for streets and railroad tracks, to create land for industrial expansion, and to dispose of waste material. Much of the fill deposited after 1964 was disposed of in landfills designed to minimize environmental effects. Industrial wastes, municipal solid wastes, steel-industry wastes, and, perhaps, dredging spoil can be associated with increased concentrations of volatile and semivolatile organic compounds, pesticides, cyanide, metals, or major ions in ground water in this area. Construction debris, ash, cinders, and natural fill may be associated with increased concentrations of major ions in ground water.

Illinois, Indiana↗
USGS1997

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH.Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir.During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June.During September, small vertical variations in metalconcentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado↗
USGS1996

Physical and chemical characteristics of Terrace Reservoir, Conejos County, Colorado, May 1994 through May 1995; interim report

Terrace Reservoir receives drainage of low-pH, metal-enriched water from mineralized areas, including the Summitville Mine, within the Alamosa River Basin. Drainage from the Summitville Mine has contributed a substantial part of the metal load to Terrace Reservoir. From May 1994 through May 1995, a study was done by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, to evaluate the physical and chemical characteristics of Terrace Reservoir. Terrace Reservoir was thermally stratified from about mid-May through August 1994. Thermal stratification was absent from September\x111994through March 1995. During periods of stratification, underflow of the Alamosa River was predominant, and residence times of the underflow were shortened by 40 to 75\x11percent of the theoretical residence times for a well-mixed reservoir. Transport and deposition of suspended solids in Terrace Reservoir varied spatially and temporally. Most of the suspended solids were deposited in Terrace Reservoir. The concentration of dissolved oxygen in the reservoir varied little spatially or temporally and generally was within a few tenths of the dissolved-oxygen concentration of the inflow. The pH of water in the reservoir generally ranged from about 4.0 to about 7.0, depending on date, depth, and location. The largest pH values were measured during May. A markeddecrease of about 1.5\x11pH units occurred at site T5 in the reservoir about mid-June. The pH of the reservoir remained at or below 5.5 from mid-June through November. Dissolved-metal concentrations varied spatially and temporally in response to several factors, which included inflow characteristics, reservoir stratification and mixing, inflow-routing and flow-through patterns, residence times, sedimentation, dissolved oxygen, and pH. Inflow chemistry is the dominant controlling factor of metal chemistry within Terrace Reservoir. During periods of stratification, large vertical variations in metal concentrations occurred. The highest metal concentrations in the reservoir generally were measured in the hypolimnion between June and August. During June, epilimnetic water of the reservoir had pH values greater than 6.0, and metal concentrations were lower than hypolimnetic concentrations. In the hypolimnion, pH values were less than 5.5. The difference between the chemistry of the epilimnion and the hypolimnion was due to differences in flow routing and residence times of water in those respective layers. The dissolved-metal concentrations were larger during July and August than during June. During September, small vertical variations in metal concentrations occurred, and the dissolved-metal concentrations were nearly equivalent to the average August metal concentrations, indicatingthat the metal concentrations measured during September resulted largely from reservoir mixing.During March, the largest metal concentrationsoccurred in the epilimnion, where pH was about 5.5; in the hypolimnion, where the pH was about 6.0, dissolved-metal concentrations were substantially lower and reflected inflow concentrations.

Colorado↗
USGS1999

Potentiometric levels and water quality in the aquifers underlying Belvidere, Illinois, 1993–96

In 1992, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency (USEPA), began a study of the hydrogeology and water quality of the aquifers underlying the vicinity of Belvidere, Boone County, Ill. Previously, volatile organic compounds (VOC's) and other constituents of industrial origin were detected in one or more ground-water samples from about 100 of the approximately 700 monitoring and water-supply wells in the area, including the 8 municipal wells in Belvidere. A glacial drift aquifer underlies at least 50 percent of the 80-square-mile study area; bedrock aquifers that underlie virtually all of the study area include the Galena-Platteville, St. Peter Sandstone, Ordovician, and Cambrian-Ordovician aquifers. During 1993, water levels were measured in 152 wells and water-quality samples were collected from 97 wells distributed throughout the study area. During 1994–96, similar data were collected from 31 wells. Potentiometric levels in the glacial drift and Galena-Platteville aquifers are similar and range from about 750 to 900 feet above sea level. The potentiometric surfaces of the aquifers are subdued representations of the land surface. Horizontal ground-water flow in the aquifers primarily is towards the Kishwaukee River, which flows through the central part of the study area, and its principal tributaries. Vertical ground-water flow appears to be downward at most locations in the study area, particularly in the urbanized areas affected by pumping of the Belvidere municipal wells and upland areas remote from the principal surface-water drainages. Flow appears to be upward between the Galena-Platteville and glacial drift aquifers where ground water discharges to the Kishwaukee River and its principal tributaries. All water samples were analyzed for VOC's. Selected samples also were analyzed for trace metals, cyanide, semivolatile organic compounds, or other constituents. VOC's were detected in samples from 50 wells (52 percent of total wells sampled). Twenty-seven specific VOC's were identified in the samples. Samples were collected from six municipal wells in use during the study; two wells were not in use because one or more VOC's exceeded maximum contaminant levels (MCL's). Two VOC's were detected in one of the samples at concentrations below MCL's established by the USEPA for protection of public-water supplies. Samples from 21 wells had at least one VOC detected at a concentration above MCL's. The VOC's detected above MCL's and their maximum concentrations were 1,2-dichloroethene (total), 470 micrograms per liter; trichloroethene (TCE), 360 micrograms per liter; tetrachloroethene (PCE), 82 micrograms per liter; benzene, 53 micrograms per liter; and vinyl chloride, 11 micrograms per liter. TCE and PCE were the most frequently detected VOC's and generally had the highest concentrations. VOC's with concentrations above MCL's were detected in samples from 15 wells open to the glacial drift aquifer and 6 wells open to the Galena-Platteville aquifer. Generally, the concentrations of VOC's were higher, and number and type of VOC's detected were greater in the glacial drift aquifer than in the Galena-Platteville aquifer and the deeper bedrock aquifers. The high concentrations and spatial distribution of VOC's in the glacial drift aquifer usually were related to nearby sources of contamination. Except in the immediate vicinity of a known hazardous-waste site, possible sources of VOC's in the bedrock aquifers were difficult to identify in the study area; VOC concentrations at most locations in the bedrock aquifers were below 5 micrograms per liter. Most locations where VOC's were detected in the glacial and bedrock aquifers were within about 1,000 feet of the Kishwaukee River. Hydrogeologic factors that affect the distribution of VOC's in the aquifers include ground-water flow through (1) the glacial drift aquifer with discharge to the nearby Kishwaukee River; and (2) the weathered-surface deposits, bedding-plane partings, and fractures in the Galena-Platteville aquifer. One bedding-plane parting intersecting wells that represent an area of about 1.5 square miles has a horizontal hydraulic conductivity as high as 220 feet per day. Pumping of high-capacity wells may contribute to the widespread distribution of VOC’s at low concentrations in the bedrock aquifers.

Illinois↗