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At least 685 records · Page 38Linked to original sources
USGS2010

Hydrogeology and groundwater quality of Highlands County, Florida

Groundwater is the main source of water supply in Highlands County, Florida. As the demand for water in the county increases, additional information about local groundwater resources is needed to manage and develop the water supply effectively. To address the need for additional data, a study was conducted to evaluate the hydrogeology and groundwater quality of Highlands County. Total groundwater use in Highlands County has increased steadily since 1965. Total groundwater withdrawals increased from about 37 million gallons per day in 1965 to about 107 million gallons per day in 2005. Much of this increase in water use is related to agricultural activities, especially citrus cultivation, which increased more than 300 percent from 1965 to 2005. Highlands County is underlain by three principal hydrogeologic units. The uppermost water-bearing unit is the surficial aquifer, which is underlain by the intermediate aquifer system/intermediate confining unit. The lowermost hydrogeologic unit is the Floridan aquifer system, which consists of the Upper Floridan aquifer, as many as three middle confining units, and the Lower Floridan aquifer. The surficial aquifer consists primarily of fine-to-medium grained quartz sand with varying amounts of clay and silt. The aquifer system is unconfined and underlies the entire county. The thickness of the surficial aquifer is highly variable, ranging from less than 50 to more than 300 feet. Groundwater in the surficial aquifer is recharged primarily by precipitation, but also by septic tanks, irrigation from wells, seepage from lakes and streams, and the lateral groundwater inflow from adjacent areas. The intermediate aquifer system/intermediate confining unit acts as a confining layer (except where breached by sinkholes) that restricts the vertical movement of water between the surficial aquifer and the underlying Upper Floridan aquifer. The sediments have varying degrees of permeability and consist of permeable limestone, dolostone, or sand, or relatively impermeable layers of clay, clayey sand, or clayey carbonates. The thickness of the intermediate aquifer system/ intermediate confining unit ranges from about 200 feet in northwestern Highlands County to more than 600 feet in the southwestern part. Although the intermediate aquifer system is present in the county, it is unclear where the aquifer system grades into a confining unit in the eastern part of the county. Up to two water-bearing units are present in the intermediate aquifer system within the county. The lateral continuity and water-bearing potential of the various aquifers within the intermediate aquifer system are highly variable. The Floridan aquifer system is composed of a thick sequence of limestone and dolostone of Upper Paleocene to Oligocene age. The top of the aquifer system ranges from less than 200 feet below NGVD 29 in extreme northwestern Highlands County to more than 600 feet below NGVD 29 in the southwestern part. The principal source of groundwater supply in the county is the Upper Floridan aquifer. As of 2005, about 89 percent of the groundwater withdrawn from the county was obtained from this aquifer, mostly for agricultural irrigation and public supply. Over most of Highlands County, the Upper Floridan aquifer generally contains freshwater, and the Lower Floridan aquifer contains more mineralized water. The potentiometric surface of the Upper Floridan aquifer is constantly fluctuating, mainly in response to seasonal variations in rainfall and groundwater withdrawals. The potentiometric surface of the Upper Floridan aquifer in May 2007, which represents the hydrologic conditions near the end of the dry season when water levels generally are near their lowest, ranged from about 79 feet above NGVD 29 in northwestern Highlands County to about 40 feet above NGVD 29 in the southeastern part of the county. The potentiometric surface of the Upper Floridan aquifer in September 2007 was about 3 to 10 feet high

Scientific Investigations Report↗
USGS2009

'Natural background' soil water repellency in conifer forests of the north-western USA: Its prediction and relationship to wildfire occurrence

Soils under a wide range of vegetation types exhibit water repellency following the passage of a fire. This is viewed by many as one of the main causes for accelerated post-fire runoff and soil erosion and it has often been assumed that strong soil water repellency present after wildfire is fire-induced. However, high levels of repellency have also been reported under vegetation types not affected by fire, and the question arises to what degree the water repellency observed at burnt sites actually results from fire. This study aimed at determining 'natural background' water repellency in common coniferous forest types in the north-western USA. Mature or semi-mature coniferous forest sites (n = 81), which showed no evidence of recent fires and had at least some needle cast cover, were sampled across six states. After careful removal of litter and duff at each site, soil water repellency was examined in situ at the mineral soil surface using the Water Drop Penetration Time (WDPT) method for three sub-sites, followed by collecting near-surface mineral soil layer samples (0-3 cm depth). Following air-drying, samples were further analyzed for repellency using WDPT and contact angle (?? sl ) measurements. Amongst other variables examined were dominant tree type, ground vegetation, litter and duff layer depth, slope angle and aspect, elevation, geology, and soil texture, organic carbon content and pH. 'Natural background' water repellency (WDPT > 5 s) was detected in situ and on air-dry samples at 75% of all sites examined irrespective of dominant tree species (Pinus ponderosa, Pinus contorta, Picea engelmanii and Pseudotsuga menziesii). These findings demonstrate that the soil water repellency commonly observed in these forest types following burning is not necessarily the result of recent fire but can instead be a natural characteristic. The notion of a low background water repellency being typical for long-unburnt conifer forest soils of the north-western USA is therefore incorrect. It follows that, where pre-fire water repellency levels are not known or highly variable, post-fire soil water repellency conditions are an unreliable indicator in classifying soil burn severity. The terrain and soil variables examined showed, overall, no convincing relationship with the repellency levels observed (R 2 < 0.15) except that repellency was limited in soils (i) developed over meta-sedimentary lithology and (ii) with clay contents >4%. This suggests that water repellency levels cannot be predicted with confidence from common terrain or soil variables. ?? 2009 Elsevier B.V.

Journal of Hydrology↗
USGS2022

Primary deposition and early diagenetic effects on the high saturation accumulation of gas hydrate in a silt dominated reservoir in the Gulf of Mexico

On continental margins, high saturation gas hydrate systems (>60% pore volume) are common in canyon and channel environments within the gas hydrate stability zone, where reservoirs are dominated by coarse-grained, high porosity sand deposits. Recent studies, including the results presented here, suggest that rapidly deposited, silt-dominated channel-levee environments can also host high saturation gas hydrate accumulations. Here we present several sedimentological data sets, including sediment composition, biostratigraphic age from calcareous nannofossils, grain size, total organic carbon (TOC), C/N elemental ratio, δ 13 C-TOC , CaCO 3 , total sulfur (TS), and δ 34 S-TS from sediments collected with pressure cores from a gas hydrate rich, turbidite channel-levee system in the Gulf of Mexico during the 2017 UT-GOM2-1 Hydrate Pressure Coring Expedition. Our results indicate the reservoir is composed of three main lithofacies, which have distinct sediment grain size distributions (type A-silty clay to clayey silt, type B-clayey silt, and type C-sandy silt to silty sand) that are characteristic of variable turbidity current energy regimes within a Pleistocene (< 0.91 Ma) channel-levee environment. We document that the TOC in the sediments of the reservoir is terrestrial in origin and contained within the fine fraction of each lithofacies, while the CaCO 3 fraction is composed of primarily reworked grains, including Cretaceous calcareous nannofossils, and part of the detrital load. The lack of biogenic grains within the finest grained sediment intervals throughout the reservoir suggests interevent hemipelagic sediments are not preserved, resulting in a reservoir sequence of silt dominated, stacked turbidites. We observe two zones of enhanced TS at the top and bottom of the reservoir that correspond with enriched bulk sediment δ 34 S, indicating stalled or slowly advancing paleo-sulfate-methane transition zone (SMTZ) positions likely driven by relative decreases in sedimentation rate. Despite these two diagenetic zones, the low abundance of diagenetic precipitates throughout the reservoir allowed the primary porosity to remain largely intact, thus better preserving primary porosity for subsequent pore-filling gas hydrate. In canyon, channel, and levee environments, early diagenesis may be regulated via sedimentation rates, where high rates result in rapid progression through the SMTZ and minimal diagenetic mineralization and low rates result in the stalling of the SMTZ, enhancing diagenetic mineralization. Here, we observed some enhanced pyritization to implicate potential sedimentation rate changes, but not enough to consume primary porosity, resulting in a high saturation gas hydrate reservoir. These results emphasize the important implications of sedimentary processes, sedimentation rates, and early diagenesis on the distribution of gas hydrate in marine sediments along continental margins.

Alabama, Louisiana, Mississippi↗
USGS2015

Geologic framework and evidence for neotectonism in the epicentral area of the 2011 Mineral, Virginia, earthquake

The epicenters of the main shock and associated aftershocks of the 2011 moment magnitude, M w 5.8 Mineral, Virginia (USA), earthquake, and the updip projection of the possible fault plane that triggered the quakes, are contained in the areas of 2 adjoining 7.5′ quadrangles in the central Virginia Piedmont. These quadrangles have therefore been the focus of concentrated geologic study in the form of bedrock and surficial mapping and near-surface trenching in order to identify potential seismogenic structures. Bedrock mapping has outlined a series of northeast-southwest–trending lithologic belts that include the Ordovician Chopawamsic and Quantico Formations, the narrow neck of the Late Ordovician Ellisville pluton, and mélange zone III of the Mine Run Complex. The region was affected by at least two ductile deformational events, one in the early Paleozoic that was broadly synchronous with the intrusion of the pluton, and one later in the Paleozoic. The earlier deformation produced the Quantico synclinorium and other regional folds, and the later deformation produced faults with associated high-strain zones. Two of these faults have been trenched at their intersection along the east-dipping eastern contact of the Ellisville neck, near where the causative fault for the earthquake projects to the surface. The trenches have exposed abundant evidence of post-Paleozoic fracturing and faulting, including brecciated quartz-tourmaline veins, slickensided thrust and strike-slip faults, and clay-filled fractures. Fluvial and colluvial gravels that overlie these brittle structures have yielded optically stimulated luminescence ages ranging from ca. 27 to 10 ka. These structures are likely representative of surface features associated with Quaternary earthquakes in the Central Virginia seismic zone.

GSA Special Papers↗
USGS1998

Preliminary lithostratigraphy, interpreted geophysical logs and hydrogeologic characteristics of the 98th Street core hole, Albuquerque, New Mexico

Core samples, cuttings, and numerous geophysical logs obtained from the 1560 ft (475.5 m) core hole drilled at 98th Street on the west side of Albuquerque provide key stratigraphic and hydraulicproperty information for the upper clastic sediments of the Santa Fe Group, which form the principal aquifer in the region. The core hole and an adjacent water-level monitoring well were drilled cooperatively by the U.S. Geological Survey (USGS) and the City of Albuquerque and investigated in collaboration with the New Mexico Bureau of Mines and Mineral Resources and the New Mexico Office of the State Engineer to improve understanding of aquifer characteristics and controls on ground-water availability and quality. The 751.5 ft (229 m) of core samples recovered from the core hole are the only undisturbed samples of nonlithified sediments of the upper part of the Santa Fe Group that have been collected in this area. These samples have allowed us, for the first time, to directly observe and characterize the lithic and sedimentologic features of this part of the section, and to correlate the detailed geologic features with geophysical-log characteristics, magnetic susceptibility measurements, hydraulic variables, and trace-element geochemistry. The adjacent well was designed to be an areally representative ground-water level and water-quality monitoring well for the Santa Fe Group aquifer. This report chiefly addresses the lithologic, stratigraphic, and hydrogeologic features determined from the 98th Street core hole; other reports address related characteristics. Previous geologic studies predicted the stratigraphy at the site to be, from the land surface downward: 1) Quaternary alluvial and eolian valley-border sediments; 2) fluvial sand and gravel of the upper unit of the Santa Fe Group (Ceja Member of the Santa Fe Formation of Kelly, 1978; equivalent to the Sierra Ledrones Formation of Machette (1978a); 3) downward-fining basin-floor silty clay deposits and 4) fluvial sandy and silty facies of the middle unit of the Santa Fe Group (the Middle Red Member of Bryan and McCann, 1937, and Lambert, 1968). New geologic interpretations indicate that the drill site is in a fault block bounded by east-dipping normal faults and the oblique Atrisco-Rincon fault zone. Core-hole sampling recovered 760.6 ft (231.8 m) of core, in core segments 2.1-2.375 in. (5.3-6 cm) in diameter, and 0.2-10 ft (6.1 cm-3 m) long. The core hole was cased with centered 3-in. PVC casing, and is available for geophysical logging. The monitoring-well hole contains four piezometers at depths of 1544 ft (470.6 m), 1112 ft (338.9 m), 749 ft (228.3 m), and 458 ft (139.6 m). Sediments in the core are loose to weakly cemented gravel, sand, silt, and clay, and lithified sandstone. Laboratory analyses of particle-size distributions of 28 channel samples show that most silty sand samples are uniformly graded and poorly sorted; medium sand samples are moderately sorted. Six principal sediment types are used to describe the core; these sediment types are repeated in various combinations throughout the core and are used to define 22 lithologic units in the cored interval. The six principal sediment types contain sequences of beds having similar modal grain size and sedimentary structure, and are listed in decreasing abundance: 1) Silty fine sand, poorly sorted, containing a coarse silt matrix. Geophysical logs show highly variable baselines with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.12-2.25 g/cc and porosity values of 30-35 percent are typical. 2) Medium sand, moderately to poorly sorted. Geophysical logs show baselines of low variability with deflections that are related to clay beds and sequences of silt, clay, and sorted fine sand. Density values of 2.05-2.20 g/cc and porosity values of 30-35 percent are typical. 3) Clayey sandy silt, poorly sorted, locally microlaminated clay and silt, generally nonplastic. Geophysical logs show highly variable baselines with deflections that are related to sequences of clay and fine sand. Density values of 2.1-2.2 g/cc and porosity values of 30-40 percent are typical. 4) Silt and clay, characteristically red to reddish brown and medium to high plasticity, massive to indistinctly microlaminated. Geophysical logs show variable baselines with broad, high-amplitude compound spikes that are related to sequences of silt and fine sand. Density values of 2.12-2.25 g/cc and porosity values of >45 percent are typical. 5) Sand and gravel, poorly sorted. Geophysical logs show variable baselines with deflections that are related to sequences of silty and sorted fine sand. 6) Sandstone, fine-to-medium grained, poorly sorted, cemented chiefly by calcite, which fills the original pore space. Geophysical logs show density values >2.25 g/cc and porosity values <30 percent. The 22 lithologic units are correlated with recognized basin-floor fluvial lithofacies (Hawley, 1996), which include sand and gravel (lithofacies I), sand with lenses of pebbly sand, silt, and silty clay (lithofacies II), and interbedded sand, silt, and silty clay (modified lithofacies III, IV, IX). The sediments in the core hole are correlated with three informal lithostratigraphic units. The top unit, 0-19 ft (0-5.8 m) depth, consists of Quaternary eolian sand and valley-border alluvium. Coarsegrained deposits in the 19-97 ft (5.8-29.6 m) interval are correlated with the upper unit of the Santa Fe Group. The fine-grained section in the 97-787 ft (29.6-239.9 m) interval is correlated tentatively with the middle unit of the Santa Fe Group. This section contains thick sequences of laminated red and olivebrown clay and silt overbank deposits (441-787 ft) in the distinctive Atrisco member of Connell and others (1998). The Atrisco is correlated with fine-grained zones in numerous wells throughout the central Albuquerque metropolitan area, and is recognized as a zone that separates the upper Santa Fe aquifer from underlying middle Santa Fe deposits. The lower section of the middle unit of the Santa Fe, 787-1500 ft (239.9-457.2 m) depth, includes an upper sequence of moderately sorted channel-fill medium sand, and a lower sequence of sand, silt, and clay overbank deposits. The age of the cored interval is not known precisely. The upper Santa Fe gravel is related regionally to a through-flowing river system that was established in the Rio Grande rift valleys in Early Pliocene time, >4.5 MA. The middle Santa Fe unit is dated tentatively by correlation with a fossiliferous section, in which sandy beds that directly underlie the upper Santa Fe are Late Miocene (Hemphellian), 4.6- 8.9 MA. Further, the middle Santa Fe unit, with dominantly normal magnetic polarity, may have been deposited during closely spaced normal magnetic chrons 5.9-8.3 Ma. Four hydrostratigraphic units summarize the hydrogeologic framework for the 98th Street site: 1) Quaternary valley-border deposits, 2) upper Santa Fe sand and gravel deposits, 3) middle Santa Fe overbank deposits, and 4) middle Santa Fe channel-sand deposits. Empirical values of horizontal hydraulic conductivity estimated from core samples reveal a previously unknown contrast in hydraulic conductivity in the lowest two hydrostratigraphic units. Correlations among numerous wells show that the distinctively fine-grained Atrisco member, with estimated hydraulic conductivities (K) of <0.02-17 ft/day, is a laterally extensive barrier to vertical ground-water flow. The underlying unit that contains moderately sorted medium sand is a potential aquifer production zone that should be investigated further. Laboratory determination of vertical hydraulic conductivity values for fine-grained core samples range from 10 -2 to 10 -7 ft/day; recompacted sandy samples have K values of 1 to 10 -2 ft/day. Results of tests conducted with increasing effective stress show that K values of all samples decrease with decreasing porosity. Comparison of K values from laboratory, empirical, and calculated geophysical values shows discrepancies of 1-3 orders of magnitude (ft/day), indicating that additional analyses of core samples and geophysical data are necessary for future characterization of the Santa Fe Group aquifer.

New Mexico↗
USGS2020

Exploring methane behavior in Marcellus Shale micropores via contrast matching neutron scattering

Petroleum in shale reservoirs is hosted in organic matter and mineral pores as well as in natural fractures and voids. For thermally mature plays, e.g., the Marcellus Shale, methane and other light alkane gases are thought to be primarily contained in organic matter pores with radii ≦50 nm. Thus, in order to understand natural gas occurrence, transport, storage, and recoverability within unconventional reservoirs at the dry-gas stage of thermal maturity, it is critical to characterize the associated organic matter porosity across length scales from 50 nm down to the angstrom level. We utilized wide Q-range neutron total scattering to characterize deuterated methane (CD 4 ) adsorption at 60ºC up to the zero average contrast (ZAC) pressure (~60 MPa) within two mineralogically different samples collected from the same producing interval from the Middle Devonian Marcellus Shale. The neutron scattering approach used here provides structural information from the inter-atomic regime up to a nominal pore radius of ~12.5 nm and, by reaching the CD 4 ZAC pressure (~60 MPa), it is possible to examine the distribution of open versus closed pores within this pore size range in the samples. Our results indicate that ~10% of the largest pores measured are closed to CD 4 for a quartz-rich sample whereas up to 25% of pores with a nominal radius of ~12.5 nm are inaccessible within a sample with an equivalent proportion of quartz, carbonate, and clay. As pore size decreases, accessibility also decreases; all pores with radii ~0.5 nm are effectively closed to CD 4 in both samples. Additionally, up to ~4.5× more CD 4 is adsorbed within the quartz-rich sample at 60 MPa and we see no evidence for densification of CD 4 within the shale pores. These findings suggest that, for shale samples within the dry-gas window, (i) nanometer-scale porosity is primarily located within organic matter, (ii) the amount of available nano-porosity can vary widely over meter scales, and (iii) mineralogy plays a secondary role in dictating methane behavior within these systems.

West Virginia↗
USGS1975

A survey of the water resources of St. Croix, Virgin Islands

St. Croix consists of two mountainous volcanic rock cores separated by a graben containing clays with minor limestone and conglomerate that is overlain by about 300 feet of marl and limestone. Predominantly fine-grained alluvium mantles much of the limestone and marl area and fills overdeepened south-trending valleys to depths of as much as 100 feet. Rainfall follows an orographic pattern ranging from about 30 inches in eastern St. Croix to 55 inches in the northwestern mountains. Four streams, all heading in the Northside Range, have intermittent reaches. All other streams in St. Croix are ephemeral, flowing only for a few hours or days following major rainstorms. Flow in the intermittent streams ranges from about 1 to 9 percent of the total rainfall and usually half or more of the flow is storm runoff resulting from two or three major storms. Storm runoff from individual storms seldom exceeds 5 percent of the rainfall. Only from 2 storms, one of 5 inches and the other of 7 inches in less than 48 hours, did runoff reach 20 percent, both times on River Gut at Golden Grove. The lack of storm runoff is attributed to the capability of the soil zone to accept large volumes of water and deficient soil moisture most of the year. The dissolved-solids content of the water of St. Croix. reflects the influence of the sea and land. Bulk precipitation is believed to be the source of the initial mineral content of the island water. Additional mineralization, particularly of ground water, results from the solution of soluble salts, mixing with residual sea water, and concentration by evapotranspiration. Water in the volcanic rocks is basically a calcium bicarbonate sodium chloride type with dissolved solids ranging from 500 to 1,000 mg/l (milligrams per liter), and chloride concentration of 100 to 300 mg/1. By contrast, water in the limestone is a sodium bicarbonate sodium chloride type with dissolved-solids content ranging from less than 1,000 to more than 20,000 mg/1 and chloride concentration from less than 100 to more than 10,000 mg/l. The mineral content of water in the limestone invariably increases with depth. Water in the alluvial deposits and in the streams usually reflects the characteristics of water from the adjacent bedrock. The retention of large volumes of rainfall in the soil zone from which it is evaporated and transpired by plants greatly reduces the water available for recharge to the aquifers of the island. Estimates of effective recharge to the aquifers range from less than 0.5 inch in some volcanic and marl rocks to 5 inches annually in more porous limestone and alluvium. Long-term yield from the aquifers is also affected by their storage capacity which may range from less than 1 percent in volcanic rocks and marl to 10 to 15 percent in limestone and alluvium. The ground-water potential (equivalent to the quantity of recharge) of St. Croix is estimated at 3.9 mgd (million gallons per day)--0.9 mgd from the Northside Range (Area 1) ; 0.4 mgd from the East End Range (Area 2), and 2.6 mgd from the central lowlands (Area 3). Most areas where major ground-water supplies are .available, principally in Central St. Croix, have already been developed. The Castle Coakley area, with a potential yield of 400,000 gpd, is the only major ground-water area still undeveloped. The ground-water potential could be increased by reducing the brush and forest cover thus reducing water losses from transpiration; artificial recharge of alluvial aquifer by water spreading; utilizing streamflow (including storm runoff) or treated sewage effluent; or by lowering the ground-water level adjacent to streams to induce infiltration. Advancements in desalination have made the brackish ground water in the Kingshill Marl (estimated at 35 billion recoverable gallons by Robison, 1972) a potential source of water. Recovery of this water would partly de-water the aquifer, which would cause water of better quality in the overlying rocks to

Open-File Report↗
USGS2015

Copper toxicity and organic matter: Resiliency of watersheds in the Duluth Complex, Minnesota, USA

We estimated copper (Cu) toxicity in surface water with high dissolved organic matter (DOM) for unmined mineralized watersheds of the Duluth Complex using the Biotic Ligand Model (BLM), which evaluates the effect of DOM, cation competition for biologic binding sites, and metal speciation. A sediment-based BLM was used to estimate stream-sediment toxicity; this approach factors in the cumulative effects of multiple metals, incorporation of metals into less bioavailable sulfides, and complexation of metals with organic carbon. For surface water, the formation of Cu-DOM complexes significantly reduces the amount of Cu available to aquatic organisms. The protective effects of cations, such as calcium (Ca) and magnesium (Mg), competing with Cu to complex with the biotic ligand is likely not as important as DOM in water with high DOM and low hardness. Standard hardness-based water quality criteria (WQC) are probably inadequate for describing Cu toxicity in such waters and a BLM approach may yield more accurate results. Nevertheless, assumptions about relative proportions of humic acid (HA) and fulvic acid (FA) in DOM significantly influence BLM results; the higher the HA fraction, the higher calculated resiliency of the water to Cu toxicity. Another important factor is seasonal variation in water chemistry, with greater resiliency to Cu toxicity during low flow compared to high flow. Based on generally low total organic carbon and sulfur content, and equivalent metal ratios from total and weak partial extractions, much of the total metal concentration in clastic streambedsediments may be in bioavailable forms, sorbed on clays or hydroxide phases. However, organicrich fine-grained sediment in the numerous wetlands may sequester significant amount of metals, limiting their bioavailability. A high proportion of organic matter in waters and some sediments will play a key role in the resiliency of these watersheds to potential additional metal loads associated with future mining operations.

Minnesota↗
USGS2009

Petrographic observations on the Exmore breccia, ICDP-USGS drilling at Eyreville, Chesapeake Bay impact structure, USA

The International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) Eyreville A and B drill cores sampled crater fill in the region of the crater moat, ??9 km to the NE of the center of the Chesapeake Bay impact structure, Virginia, USA. They provide a 953 m section (444-1397 m depth) of sedimentary clast breccia and intercalated sedimentary and crystalline megablocks knownas Exmore beds, deposited on top of the impactite sequence between 1397 and 1551 m depth. We petrographically investigated the sandy-clayey groundmass-dominated breccia, which resembles a diamictite ("Exmore breccia"), and which, in its lower parts, carries sedimentary and crystalline blocks. The entire breccia interval is characterizedby the presence of glauconite and bioclastic carbonate, which distinguishes the Exmore breccia from other sandy facies above and below in the stratigraphy. The sediment-clast breccia exhibits strong heterogeneity from sample to sample with respect to groundmass nature, e.g., clay versus sand content, as well as clast content, in general, and shocked clast content, in particular. There is a consistently signifi cantly larger macroscopic sedimentary to crystalline clast content. On the microscopic scale, the intersample sediment to crystalline clast ratios are quite variable. A very small component of shocked material, in the form of shock-deformed quartz, and to an even lesser degree feldspar, and somewhat more abundant but still relatively scarce shardshaped,altered melt particles, is present throughout the section. However, between ??458 and 469 m, and between 514 and 527 m depths, the abundance of such melt particlesis notably enhanced. These sections are also chemically distinct and relatively more mafic than the other parts of the Exmore breccia. It appears that from the time of deposition of the 527 m material, calming of the ocean occurred over the crater area as a result of abatement of resurge activity, so that ejecta from the plume abovethe crater could accumulate within the crater area to a larger degree. Deposition ofejecta fallout from the collapsing ejecta plume was terminated by the time of deposition of the 458 m material. This raises questions about the positioning of the exact upper contact of Exmore breccia to post-Exmore sediment (Chickahominy Formation), which is currently placed at 444 m depth and which possibly should be revisedto 458 m depth. Based on a signifi cant record of granite-derived material with shocked minerals, the shocked debris component seems to be largely derived from crystalline target rocks. This provides further evidence that the basement-derived material of the basal section of the Eyreville drill cores, which is essentially unshocked, is likely of an allochthonous nature and that the drilling did not intersect the actual crater floor. 76??W. ?? 2009 Geological Society of America.

Special Paper of the Geological Society of America↗
USGS1951

Ground-water resources of the Paintrock irrigation project, Wyoming, with a section on the quality of the water

The ground-water conditions of the area covered by the Paintrock irrigation project, in north-central Wyoming, were investigated during the summer of 1947. The purpose of the study was to obtain a general evaluation of ground-water recharge, discharge, and storage in the area now irrigated and in the adjacent areas where additional lands are to be irrigated. Much of the area covered by this report consists of flat to gently sloping stream terraces and alluvial-bottoms along Nowood, Paintrock, and Medicine Lodge Creeks. The stream-terrace materials consist of fluviatile sand, clay, and gravel. The alluvium is very fine grained and in general has low permeability. The materials underlying the stream terraces and the bottomlands became progressively finer grained and less permeable downstream. The bedrock formations underlying the area studied range from the Madison limestone of Mississippian age to the Fort Union formation of Paleocene age. Beds have been folded into several prominent structures which trend northwest-southeast across the area. Several of the formations exposed in the area serve as aquifers and yield water to domestic and stock wells. The most important bedrock aquifers are the Fort Union, Lance, Meeteetee, Mesaverde, Frontier, Cloverly and Morrison formations , the Tensleep sandstone, the Amsden formation, and the Madison limestone. More than 7,000 feet of strata are exposed in the area, the older beds being exposed on the western flank of the Big Horn Range near the eastern end of the area. The quality of the water in the project ranges within wide limits. The concentration of dissolved solids in seven samples of ground water ranges from 279 parts per million for a water in the Tensleep sandstone to 4,590 parts per million for a water in the Morrison formation. The hardness as calcium carbonate (CaCO 3 ) ranges from 13 to 1,680 parts per million. Limited data on the quality of water in Nowood and Paintrock Creeks indicate that these waters are suitable for irrigation. The water in Paintrock Creek near Tensleep is higher in mineral content and hardness than the water upstream at Hyattville as a result of return flow of the irrigation water that is applied to farm lands above Tensleep.

Wyoming↗
USGS2006

Petrography, palynology, and paleoecology of the Lower Pennsylvanian Bon Air coal, Franklin County, Cumberland Plateau, southeast Tennessee

Stratigraphy, palynology, petrography, and geochemistry of the Bon Air coal from the Armfield, Dotson, Rutledge, and Shakerag mine sites of Franklin County, Tennessee suggest that Bon Air seams at all sites were small (??? 1.0 mile, 1.6 km), spatially distinct paleomires that evolved from planar to domed within the fluviodeltaic Lower Pennsylvanian Raccoon Mountain Formation. Of observed palynoflora, 88-97% are from lycopsids prevalent in the Westphalian. Densosporites palynomorphs of small lycopsids (e.g., Omphalophloios) dominate at the shale-hosted Armfield site, while Lycospora palynoflora of large arboreous lycopsids (especially Lepidodendron, with lesser Lepidophloios harcourtii and Lepidophloios hallii) dominate where intercalated siltstone/sandstone/shale hosts the coal (all other sites). Palynoflora of other lycopsids (Sigillaria and Paralycopodites), tree ferns, seed ferns, small ferns, calamites, and cordaites are generally minor. Genera of clastic-associated Paralycopodites are most common in Shakerag's coal (??? 10%), yet quite rare in Rutledge or Dotson coals. Overall, the palynomorph assemblages suggest that the Bon Air paleomires were forest swamps, and Early Pennsylvanian in age (Westphalian A, Langsettian). Dominant macerals at all sites are vitrinites, with fine collodetrinite (from strongly decomposed plant debris) more common than coarser collotelinite (from well-preserved plant fragments), and with lesser inertinites (fusinite and semifusinite) and liptinites (dominantly sporinite). Shakerag's coal has greatest abundance (mineral-matter-free) of collotelinite (up to 47%) and total vitrinite (74-79%) of any sites, but lowest liptinite (12-14.5%) and inertinite (7-11%). The Dotson and Rutledge seams contain moderate liptinite (21-23%) and highest inertinite (36-37%), lowest vitrinite (??? 41%), and lowest collotelinite (13-15%). Armfield's seam has relatively high liptinite (26-28%) and vitrinite (56.5-62%), but rather low inertinite (12-15%). Moderately high ash (11.0-20.0%) and low to moderate sulfur (1.24% avg.) are typical, but ash may locally be up to 38% and sulfur up to 2.9%. Volatile matter (32.1-41.3%), calorific value (33.3-34.9 MJ/kg MAF), moisture (2.2-3.4%), and vitrinite reflectance (0.70-0.84% Rmax; 0.64-0.79% Rrandom) place the Bon Air's rank as high-volatile-A bituminous (hvAb). The Armfield coal was probably a channel-distal paleomire, perhaps an oxbow lake or floodplain depression, which domed and then subsided back to planarity prior to burial. Features of its basal and uppermost benches suggest low-lying, often-flooded (but periodically dry) mires marked by fluvial influxes and diverse lycopsid growth. These include variable inertinite, common palynoflora of both small lycopsids (Omphalophloios-like) and large arboreous ones (Lepidophloios and Lepidodendron), minor but significant palynoflora of subaerial levee or levee/mire transition species (especially Paralycopodites), moderate to high ash, variable sulfur, and elevated levels of commonly fluvial trace elements (e.g., Al, Cr, REEs, Rb, Sr, Th, V, Y, and Zr). These benches also contain high total vitrinite, high collotelinite/collodetrinite ratios, and clays with moderate to low kaolinite/quartz ratios, all consistent with the near-neutral pH and limited peat degradation that typify such planar mires. By contrast, middle benches at Armfield reflect mires domed above the land surface, less-often flooded, less-preservational, and of lower pH: coals have lower ash, vitrinite, and collotelinite, less palynoflora of both large arboreous lycopsids and Paralycopodites, and high proportions of kaolinite, liptinite, and Densosporites. Similar data at Shakerag suggest that its mire also grew from planar to domed. However, more abundant Paralycopodites, a kaolinite-poor but quartz-and-illite-rich underclay, benches alternately ash-rich and ash-poor, and an upper bench truncated by channel sandstone, suggest that it was channel-proximal and pron

International Journal of Coal Geology↗
USGS1979

Geology, petrology, and chemistry of the Leadville Dolomite: host for uranium at the Pitch Mine, Saguache County, Colorado

Newly documented uranium ore in the Pitch Mine occurs chiefly in brecciated Mississippian Leadville Dolomite along the Chester reverse fault zone, and to a lesser extent in sandstone, siltstone, and carbonaceous shale of the Pennsylvanian Belden Formation and in Precambrian granitic rocks and schist. Uranium-mineralized zones are generally thicker, more consistent, and of higher grade in dolomite than in other hosts, and roughly 50 percent of the new reserves are in dolomite. Strong physical control by dolomite is evident, as this is the only lithology that is pervasively brecciated within the fault slices that make up the footwall of the reverse fault zone. Other lithologies tend to either remain unbroken or undergo ductile deformation. Chemical controls are subtle and appear to involve chiefly formation of FeS2 as pyrite and marcasite, which accompany uranium. Leadville Dolomite in the area is about 130 m thick and is predominantly nonfossiliferous dolomicrite. In the Pitch Mine, Leadville Dolomite is bound by faults and maximum known thickness is about 17 m. Mud texture, paucity of fossils and other allochems, thin laminations, and probable algal mat structures suggest sedimentation in a tidal-flat (possibly supratidal) environment. Preservation of mud texture and lack of replacement features indicate that dolomitization was an early, prelithification process, as in modern tidal flats, and produced a chemically and texturally uniform rock over tens of meters with relatively few limestone beds surviving. The sedimentary and diagenetic environment of the tidal-flat dolomite, apparently most favorable for uranium deposits, probably obtained over a large area and should consistute an exploration target over a broad area of central Colorado. Carbonate rocks of the Belden Formation, in contrast to those of the Leadville, contain calcite in great excess of dolomite, more than 5 percent silt-size quartz and clay, and abundant fossils and oolites. Belden limestones (sandy micrite and sandy wackestone) probably were deposited in an intertidal or subtidal environment. Very little uranium ore occurs in these rocks. Chemical aspects, such as the iron, sulfur, and organic carbon contents, are very similar to those of Leadville dolomites, and hence seem favorable, but Belden limestones generally are only mildly fractured. The minor-element content of ore-bearing dolomites is generally normal judging from the relatively scarce data yet published for comparable rocks. Elements enriched in ore include iron, sulfur, molybdenum, and lead. One surface expression of ore in dolomite is ocher-colored, leached, porous gossan that is characterized by residual silica and limonite and by high radioactivity but low chemical uranium content.

Open-File Report↗
USGS2016

Soil amplification with a strong impedance contrast: Boston, Massachusetts

In this study, we evaluate the effect of strong sediment/bedrock impedance contrasts on soil amplification in Boston, Massachusetts, for typical sites along the Charles and Mystic Rivers. These sites can be characterized by artificial fill overlying marine sediments overlying glacial till and bedrock, where the depth to bedrock ranges from 20 to 80 m. The marine sediments generally consist of organic silts, sand, and Boston Blue Clay. We chose these sites because they represent typical foundation conditions in the city of Boston, and the soil conditions are similar to other high impedance contrast environments. The sediment/bedrock interface in this region results in an impedance ratio on the order of ten, which in turn results in a significant amplification of the ground motion. Using stratigraphic information derived from numerous boreholes across the region paired with geologic and geomorphologic constraints, we develop a depth-to-bedrock model for the greater Boston region. Using shear-wave velocity profiles from 30 locations, we develop average velocity profiles for sites mapped as artificial fill, glaciofluvial deposits, and bedrock. By pairing the depth-to-bedrock model with the surficial geology and the average shear-wave velocity profiles, we can predict soil amplification in Boston. We compare linear and equivalent-linear site response predictions for a soil layer of varying thickness over bedrock, and assess the effects of varying the bedrock shear-wave velocity (V Sb ) and quality factor (Q). In a moderate seismicity region like Boston, many earthquakes will result in ground motions that can be modeled with linear site response methods. We also assess the effect of bedrock depth on soil amplification for a generic soil profile in artificial fill, using both linear and equivalent-linear site response models. Finally, we assess the accuracy of the model results by comparing the predicted (linear site response) and observed site response at the Northeastern University (NEU) vertical seismometer array during the 2011 M 5.8 Mineral, Virginia, earthquake. Site response at the NEU vertical array results in amplification on the order of 10 times at a period between 0.7-0.8 s. The results from this study provide evidence that the mean short-period and mean intermediate-period amplification used in design codes (i.e., from the F a and F v site coefficients) may underpredict soil amplification in strong impedance contrast environments such as Boston.

Massachusetts↗
USGS1975

Hydrologic evaluation of the Haystack Butte area : with emphasis on possible discharge of class-I wastes, Edwards Air Force Base, California

The discharge of 3 acre-feet (4 x 10 -3 cubic hectometres) per year of Class-I wastes in the Haystack Butte area of Edwards Air Force Base, Calif., has been proposed by the Air Force. Evaporation in this arid basin exceeds the 4 inches (100 millimetres) of annual precipitation. Fifteen test holes, ranging in depth from 40 to 240 feet (12 to 73 metres) below land surface, indicate that ground water occurs mostly in Tertiary volcanic and sedimentary rocks overlying pre-Tertiary quartz monzonite. Depth to water averages about 100 feet (30 metres) below land surface. Hydraulic conductivity of cores of Tertiary rock taken from a test hole at depths of 9 to 88 feet (2.7 to 27 metres) below land surface suggests values of 6.9 x 10-5 to 4.9 x 10 -3 feet per day (2.1 x 10 -5 to 1.5 x 10 -3 metres per day). Petrographic analyses of these cores indicate a material consisting mostly of weathered volcanic rocks with a moderate concentration of montmorillonite clay. The water-level gradient averages about 4 feet per mile (0.76 metre per kilometre). Ground-water discharge through a narrow gap in the southeastern part of the basin is calculated to be 3.8 x 10 -4 acre-feet (4.7 x 10 -7 cubic hectometres) per year. After leaving the basin, the underflow becomes part of a regional flow system discharging into Harper Lake playa. An increase in the underflow from 3.8 x 10 -4 acre-feet (4.7 x 10 -7 cubic hectometres) per year to 3 acre-feet (4 x 10 -3 cubic hectometres) per year may result in an undesirable surface-water flow by increasing the saturated thickness of the aquifer near the narrow gap in the southeastern part of the basin. Also, the very low hydraulic-conductivity values suggest that some difficulties may exist in percolating 3 acre-feet (4 x 10 -3 cubic hectometres) per year of wastes resulting in possible saturation of the ground surface outside the boundaries of the potential Class-I site. Because the rate of evaporation is very high (116 inches or 294.6 millimetres per year) in the study area, many of the problems associated with the percolation of the waste water and the subsequent changes in ground-water movement could be minimized by evaporating the wastes to complete dryness. The quality of the ground water in the basin is generally unsuitable for domestic, industrial, and irrigation purposes. The concentration and type of chemical constituents in the ground water suggest slow circulation in a geologic environment with soluble minerals.

California↗
USGS1975

Interstitial solutions and diagenesis in deeply buried marine sediments: Results from the Deep Sea Drilling Project

Through the Deep Sea Drilling Project samples of interstitial solutions of deeply buried marine sediments throughout the World Ocean have been obtained and analyzed. The studies have shown that in all but the most slowly deposited sediments pore fluids exhibit changes in composition upon burial. These changes can be grouped into a few consistent patterns that facilitate identification of the diagenetic reactions occurring in the sediments. Pelagic clays and slowly deposited (<1 cm/10 3 yr) biogenic sediments are the only types that exhibit little evidence of reaction in the pore waters. In most biogenic sediments sea water undergoes considerable alteration. In sediments deposited at rates up to a few cm/10 3 yr the changes chiefly involve gains of Ca 2+ and Sr 2+ and losses of Mg 2+ which balance the Ca 2+ enrichment. The Ca-Mg substitution may often reach 30 mM/kg while Sr 2+ may be enriched 15-fold over sea water. These changes reflect recrystallization of biogenic calcite and the substitution of Mg 2+ for Ca 2+ during this reaction. The Ca-Mg-carbonate formed is most likely a dolomitic phase. A related but more complex pattern is found in carbonate sediments deposited at somewhat greater rates. Ca 2+ and Sr 2+ enrichment is again characteristic, but Mg 2+ losses exceed Ca 2+ gains with the excess being balanced by SO 4 post staggered2- losses. The data indicate that the reactions are similar to those noted above, except that the Ca 2+ released is not kept in solution but is precipitated by the HCO 3 post staggered- produced in SO 4 post staggered2- reduction. In both these types of pore waters Na + is usually conservative, but K + depletions are frequent. In several partly consolidated sediment sections approaching igneous basement contact, very marked interstitial calcium enrichment has been found (to 5.5 g/kg). These phenomena are marked by pronounced depletion in Na + , Si and CO 2 , and slight enhancement in Cl - . The changes are attributed to exchange of Na + for Ca 2+ in silicate minerals forming from submarine weathering of igneous rocks such as basalts. Water is also consumed in these reactions, accounting for minor increases in total interstitial salinity. Terrigenous, organic-rich sediments deposited rapidly along continental margins also exhibit significant evidences of alteration. Microbial reactions involving organic matter lead to complete removal of SO 4 post staggered2- , strong HCO 3 post staggered- enrichment, formation of NH 4 post staggered+ , and methane synthesis from H 2 and CO 2 once SO 4 post staggered2- is eliminated. K + and often Na + (slightly) are depleted in the interstitial waters. Ca 2+ depletion may occur owing to precipitation of CaCO 3 . In most cases interstitial Cl - remains relatively constant, but increases are noted over evaporitic strata, and decreases in interstitial Cl - are observed in some sediments adjacent to continents.

Geochimica et Cosmochimica Acta↗
USGS2020

Li and Ca enrichment in the Bristol Dry Lake brine compared to brines from Cadiz and Danby Dry Lakes, Barstow-Bristol Trough, California, USA

Relatively few discharging playas in western United States extensional basins have high concentrations of lithium (Li) and calcium (Ca) in the basin-center brines. However, the source of both these ions is not well understood, and it is not clear why basins in close proximity within the same extensional trough have notably different concentrations of Li and Ca. In the Barstow-Bristol Trough, California, USA, three playas in separate topographically closed basins vary in Li and Ca concentrations from northwest to southeast: 71–110 mg/L Li and 17–65 g/L Ca at Bristol Dry Lake, 20–80 mg/L Li and 7.5–40 g/L Ca at Cadiz Dry Lake, and <5 mg/L Li and <0.5 g/L Ca at Danby Dry Lake. Using new and historic data from recently drilled wells (2017–2018), it has been determined that there is minimal variation of temperature, Li, and major ion concentrations with depth (down to 500 m), suggesting that the brines are well mixed and likely to circulate slowly due to density driven flow. Although it has been postulated that geothermal fluids supply the Li and Ca to Bristol and Cadiz closed basins, there is little to no surface evidence for geothermal fluids, except for a young (80,000-year-old) volcanic crater in Bristol Dry Lake. However, major-ion chemistry of fluid inclusions in bedded halite deposits show no change in brine chemistry over the last 3 million years in Bristol Dry Lake indicating that the source of lithium is not related to these recent basaltic eruptions. Mg–Li geothermometry of basin-center brines indicates that Bristol and Cadiz brines have possibly been heated to near 160 °C at some time and Danby brine water has been heated to less than 100 °C, although Cadiz and Danby lakes have no known surface geothermal features. The difference in Li concentrations between the different basins is likely caused by variable sources of both ions and the hydrology of the playas, including differences in how open or closed the basins are, recharge rates, evaporative concentration, permeability of basin-center sediments, and the possible amount of geothermal heating. The differences in Ca concentrations are more difficult to determine. However, historic groundwater data in the basins indicate that less saline groundwater on the north side of the basins has molar Ca:HCO 3 and Ca:SO 4 ratios greater than one, which indicates a non-saline groundwater source for at least some of the Ca. The similar Li and Ca concentrations in Bristol and Cadiz lakes may be because they are separated only by a low topographic divide and may have been connected at times in the past three million years. All three basins are at least Miocene in age, as all three basins have been interpreted to contain Bouse Formation sediments at various depths or in outcrop. The age of the basins indicates that there is ample time for concentration of Li and Ca in the basins even at low evaporation rates or low geothermal inputs. The source of Li for brines in Bristol and Cadiz basins is postulated to be from ancient geothermal fluids that no longer exist in the basin. The source of Li to the sediment may be either geothermal fluids or dissolution and concentration of Li from tephra layers and detrital micas or clays that are present in the sediments, or a combination of both. The source of Ca must at least partially come from groundwater in the alluvial fans, as some wells have Ca:HCO 3 ratios that are greater than one. The source of Ca could be from the dissolution of Ca-bearing igneous rocks in the surrounding catchments with limited HCO 3 contribution, or dilute geothermal water migrating up through faults in the basin margin. The relatively low concentration of Li and Ca in Danby playa is likely caused by a lack of sources in the basin and because the basin was (or is) partially hydrologically open to the south, reducing the effectiveness of evaporative concentration of solutes. Bristol Dry Lake is likely the only hydrologically closed basin of the three because although Cadiz has a similar brine chemistry and salinity, there is almost no halite deposition in the basin. It is only Bristol Dry Lake that contains 40% halite in its basin center.

California↗
USGS2003

Geologic framework and hydrogeologic characteristics of the Edwards aquifer, Uvalde County, Texas

The Edwards aquifer in Uvalde County is composed of Lower Cretaceous carbonate (mostly dolomitic limestone) strata of the Devils River Formation in the Devils River trend and of the West Nueces, McKnight, and Salmon Peak Formations in the Maverick basin. Rocks in the Devils River trend are divided at the bottom of the Devils River Formation into the (informal) basal nodular unit. Maverick basin rocks are divided (informally) into the basal nodular unit of the West Nueces Formation; into lower, middle, and upper units of the McKnight Formation; and into lower and upper units of the Salmon Peak Formation. The Edwards aquifer overlies the (Lower Cretaceous) Glen Rose Limestone, which composes the lower confining unit of the Edwards aquifer. The Edwards aquifer is overlain by the (Upper Cretaceous) Del Rio Clay, the basal formation of the upper confining unit. Upper Cretaceous and (or) Lower Tertiary igneous rocks intrude all stratigraphic units that compose the Edwards aquifer, particularly in the southern part of the study area. The Balcones fault zone and the Uvalde salient are the principal structural features in the study area. The fault zone comprises mostly en echelon, high-angle, and down-to-the-southeast normal faults that trend mostly from southwest to northeast. The Uvalde salient—resulting apparently from a combination of crustal uplift, diverse faulting, and igneous activity—elevates the Edwards aquifer to the surface across the central part of Uvalde County. Downfaulted blocks associated with six primary faults—Cooks, Black Mountain, Blue Mountain, Uvalde, Agape, and Connor—juxtapose the Salmon Peak Formation (Lower Cretaceous) in central parts of the study area against Upper Cretaceous strata in the southeastern part. The carbonate rocks of the Devils River trend and the Maverick basin are products of assorted tectonic and depositional conditions that affected the depth and circulation of the Cretaceous seas. The Devils River Formation formed in a fringing carbonate bank—the Devils River trend— in mostly open shallow marine environments of relatively high wave and current energy. The West Nueces, McKnight, and Salmon Peak Formations resulted mostly from partly restricted to open marine, tidal-flat, and restricted deep-basinal environments in the Maverick basin. The porosity of the Edwards aquifer results from depositional and diagenetic effects along specific lithostratigraphic horizons (fabric selective) and from structural and solutional features that can occur in any lithostratigraphic horizon (non-fabric selective). In addition to porosity depending upon the effects of fracturing and the dissolution of chemically unstable (soluble) minerals and fossils, the resultant permeability depends on the size, shape, and distribution of the porosity as well as the interconnection among the pores. Upper parts of the Devils River Formation and the upper unit of the Salmon Peak Formation compose some of the most porous and permeable rocks in Uvalde County.

Texas↗
USGS2006

Pore-Water Quality in the Clay-Silt Confining Units of the Lower Miocene Kirkwood Formation and Hypothetical Effects on Water Quality in the Atlantic City 800-Foot Sand, Northeastern Cape May County, New Jersey, 2001

Pore water was extracted from clay-silt core samples collected from a borehole at Ocean View, west of Sea Isle City, in northeastern Cape May County, New Jersey. The borehole intersects the lower Miocene Kirkwood Formation, which includes a thick sand and gravel unit between two clay-silt units. The sand and gravel unit forms a major confined aquifer in the region, known as the Atlantic City 800-foot sand, the major source of potable water along the Atlantic Coast of southern New Jersey. The pore water from the core is of interest because the borehole intersects the aquifer in an area where the ground water is sodium-rich and sulfidic. Locally in the aquifer in central and southern Cape May County, sodium concentrations are near the New Jersey secondary drinking-water standard of 50 mg/L (milligrams per liter), and typically are greater than 30 mg/L, but chloride and sulfate do not approach their respective secondary drinking-water standards except in southernmost Cape May County. Pore waters from the confining units are suspected to be a source of sodium, sulfur, and chloride to the aquifer. Constituent concentrations in filtered pore-water samples were determined using the inductively coupled plasma-mass spectrometry analytical technique to facilitate the determination of low-level concentrations of many trace constituents. Calcium-sodium-sulfate-bicarbonate, calcium-chloride-sulfate, calcium-sulfate, and sodium-sulfate-chloride-bicarbonate type waters characterize samples from the deepest part of the confining unit directly overlying the aquifer (termed the 'lower' confining unit). A sodium-chloride-sulfate type water is dominant in the composite confining unit below the aquifer. Sodium, chloride, and sulfate became increasingly dominant with depth. Pore water from the deepest sample recovered (1,390 ft (feet) below land surface) was brackish, with concentrations of sodium, chloride, and sulfate of 5,930, 8,400, and 5,070 mg/L, respectively. Pore-water samples from 900 ft or less below land surface, although mineralized, were fresh, not brackish. Sodium concentrations ranged from 51.3 to 513 mg/L, with the maximum concentration found at 882 ft below land surface in the composite confining unit below the aquifer. Chloride concentrations ranged from 46.4 to 757 mg/L, with the maximum concentration found at 596 ft below land surface in the 'lower' confining unit, and were higher than those in pore water from the same units at Atlantic City, N.J. Concentrations of chloride in the composite confining unit below the aquifer were consistently greater than 250 mg/L, indicating that the confining unit can be a source of chloride at depth. Of the major anions, sulfate was the constituent whose concentration varied most, ranging from 42 to 799 mg/L. The maximum concentration was found at 406 ft below land surface, in the upper part of the confining unit overlying the aquifer and the Rio Grande water-bearing zone (termed the 'upper' confining unit). Sulfide was not detected in any pore-water sample despite the presence of abundant quantities of sulfate and sulfide in the aquifer. The absence of sulfide in the pore waters is consistent with the hypothesis that sulfate is reduced in the aquifer. The presence of arsenic, at concentrations ranging from 0.0062 to 0.0374 mg/L, is consistent with the absence of sulfide and the possible presence of iron in the pore water.

Scientific Investigations Report↗