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At least 667 records · Page 37Linked to original sources
USGS2008

Simulations of ground-water flow and particle pathline analysis in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California

Shallow ground water in the eastern San Joaquin Valley is affected by high nitrate and uranium concentrations and frequent detections of pesticides and volatile organic compounds (VOC), as a result of ground-water development and intensive agricultural and urban land use. A single public-supply well was selected for intensive study to evaluate the dominant processes affecting the vulnerability of public-supply wells in the Modesto area. A network of 23 monitoring wells was installed, and water and sediment samples were collected within the approximate zone of contribution of the public-supply well, to support a detailed analysis of physical and chemical conditions and processes affecting the water chemistry in the well. A three-dimensional, steady-state local ground-water-flow and transport model was developed to evaluate the age of ground water reaching the well and to evaluate the vulnerability of the well to nonpoint source input of nitrate and uranium. Particle tracking was used to compute pathlines and advective travel times in the ground-water flow model. The simulated ages of particles reaching the public-supply well ranged from 9 to 30,000 years, with a median of 54 years. The age of the ground water contributed to the public-supply well increased with depth below the water table. Measured nitrate concentrations, derived primarily from agricultural fertilizer, were highest (17 milligrams per liter) in shallow ground water and decreased with depth to background concentrations of less than 2 milligrams per liter in the deepest wells. Because the movement of water is predominantly downward as a result of ground-water development, and because geochemical conditions are generally oxic, high nitrate concentrations in shallow ground water are expected to continue moving downward without significant attenuation. Simulated long-term nitrate concentrations indicate that concentrations have peaked and will decrease in the public-supply well during the next 100 years because of the low nitrate concentrations in recharge beneath the urban area and the increasing proportion of urban-derived ground water reaching the well. The apparent lag time between peak input concentrations and peak concentrations in the well is about 20 to 30 years. Measured uranium concentrations were also highest (45 micrograms per liter) in shallow ground water, and decreased with depth to background concentrations of about 0.5 microgram per liter. Naturally-occurring uranium adsorbed to aquifer sediments is mobilized by oxygen-rich, high-alkalinity water. Alkalinity increased in shallow ground water in response to agricultural development. As ground-water pumping increased in the 1940s and 1950s, this alkaline water moved downward through the ground-water flow system, mobilizing the uranium adsorbed to aquifer sediments. Ground water with high alkalinity and high uranium concentrations is expected to continue to move deeper in the system, resulting in increased uranium concentrations with depth in ground water. Because alkalinity (and correspondingly uranium) concentrations were high in shallow ground water beneath both the urban and the agricultural land, long-term uranium concentrations in the public-supply well are expected to increase as the proportion of uranium-affected water contributed to the well increases. Assuming that the alkalinity near the water table remains the same, the simulation of long-term alkalinity in the public-supply well indicates that uranium concentrations in the public-supply well will likely approach the maximum contaminant level; however, the time to reach this level is more than 100 years because of the significant proportion of old, unaffected water at depth that is contributed to the public-supply well.

California↗
USGS2015

Organic waste compounds as contaminants in Milwaukee-area streams

Organic waste compounds (OWCs) are ingredients and by-products of common agricultural, industrial, and household substances that can contaminate our streams through sources like urban runoff, sewage overflows, and leaking septic systems. To better understand how OWCs are affecting Milwaukee-area streams, the U.S. Geological Survey, in cooperation with the Milwaukee Metropolitan Sewerage District, conducted a three-year study to investigate the presence and potential toxicity of 69 OWCs in base flow, stormflow, pore water, and sediment at 14 stream sites and 3 Milwaukee harbor locations. This fact sheet summarizes the major findings of this study, including detection frequencies and concentrations, potential toxicity, the prevalence of polycyclic aromatic hydrocarbons (PAHs), and the influence of urbanization.

Wisconsin↗
USGS2024

Mapping development preferences on the perceived value of ecosystem services and land use conflict and compatibility in Greater Kuala Lumpur

Rapid and unplanned development can diminish the social values for ecosystem services associated with urban landscapes. Tropical Global South cities, such as Greater Kuala Lumpur (GKL), Malaysia, that are highly biodiverse, are particularly vulnerable to the fragmentation and loss of natural ecosystems. This study investigates the social values for ecosystem services in GKL, a rapidly urbanising metropolitan area in Southeast Asia and presents the novel application of the SolVES ( Social Values for Ecosystem Services ) tool to an urban area. A public participatory GIS (PPGIS) survey was conducted to assess residents’ development preferences and perceived distribution of social values. The study revealed two groups of respondents, using cluster analysis, each with unique development preferences - a group favouring both green and grey developments and another favouring green development but strongly opposing grey development. The two groups differed statistically in their sociodemographic characteristics, and also how they mapped different social values. Our spatial analysis of their preferences towards future urban expansion in GKL highlighted locations where there is potential for land-use conflict. For example, the favour-balanced-development group tended to value built areas over green spaces. These findings support the need to consider residents’ preferences and socioecological traits through greater public engagement in urban landscape management.

Greater Kuala Lumpur↗
USGS2008

Reverse Evolution of Armor Plates in the Threespine Stickleback

Faced with sudden environmental changes, animals must either adapt to novel environments or go extinct. Thus, study of the mechanisms underlying rapid adaptation is crucial not??only for the understanding of natural evolutionary processes but also for the understanding of human-induced evolutionary change, which is an increasingly important problem [1-8]. In the present study, we demonstrate that the frequency of completely plated threespine stickleback fish (Gasterosteus aculeatus) has increased in an urban freshwater lake (Lake Washington, Seattle, Washington) within the last 40 years. This is a dramatic example of "reverse evolution," [9] because the general evolutionary trajectory is toward armor-plate reduction in freshwater sticklebacks [10]. On the basis of our genetic studies and simulations, we propose that the most likely cause of reverse evolution is increased selection for the completely plated morph, which we suggest could result from higher levels of trout predation after a sudden increase in water transparency during the early 1970s. Rapid evolution was facilitated by the existence of standing allelic variation in Ectodysplasin (Eda), the gene that underlies the major plate-morph locus [11]. The Lake Washington stickleback thus provides a novel example of reverse evolution, which is probably caused by a change in allele frequency at the major plate locus in response to a changing predation regime. ?? 2008 Elsevier Ltd. All rights reserved.

Current Biology↗
USGS1997

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin– Results of investigations through April 1992

A water-quality assessment of the upper Illinois River Basin (10,949 square miles) was conducted during water years 1987-91. This assessment involved interpretation of available data; 4 years of intensive data collection, including monthly sample collection at eight fixed-monitoring stations in the basin; and synoptic studies of selected water-quality constituents at many sites. The number of exceedances of water-quality criteria for chromium, copper, lead, mercury, silver, and zinc in water was essentially the same at similar stations between 1978-86 and 1987-90. For water and sediment, a large signature for many trace inorganic constituents was observed from the Chicago metropolitan area, mainly from the Des Plaines River Basin and continuing down the Illinois River. Loads of trace inorganic constituents in water were 2-13 times greater from the Chicago metropolitan area than from rural areas in the upper Illinois River Basin. Concentrations of cadmium, mercury, nickel, selenium, and zinc appeared to be relatively enriched in biota in the upper Illinois River Basin compared to other river basins. Biota from some urban sites were enriched with respect to several elements. For example, relatively large concentrations of cadmium, chromium, copper, lead, and nickel were observed in biota from sites in the Chicago River in the metropolitan area and the Calumet River. Results of pesticide sampling in 1988 and 1989 identified the pesticides bromacil, diazinon, malathion, prometon, and simazine as urban related and alachlor, atrazine, cyanazine, metolachlor, and metribuzin as agricultural related. Phenol concentrations never exceeded general-use and secondary-contact water-quality standards of 100 and 300 micrograms per liter, respectively. Pentachlorophenol concentrations observed at the Illinois River at Marseilles, Ill., between 1981 and 1992 decreased beginning in 1987. A breakdown product of the organochlorine pesticide dichloro-diphenyl-trichloroethane (DDT), p,p'-DDE was the most commonly detected organic compound in biota in both 1989 and 1990. In the nine fish-fillet samples collected in 1989, exceedances of U.S. Environmental Protection Agency (USEPA) fish tissue concentrations were noted for p,p'-DDE in all nine fillets and for dieldrin in five of the nine fillets. Nutrient concentrations in water in the study area generally were larger than concentrations typically found in natural waters. The Des Plaines River Basin contributed approximately 41 percent of the total nitrogen load to the upper Illinois River Basin, whereas the Kankakee River and Iroquois River Basins contributed about 34 and 14 percent of the total load, respectively. Dissolved-oxygen concentrations measured during a 1988 synoptic sampling exceeded State water-quality standards at 76 percent of the sampled sites. Bacteria densities greater than water-quality standards were observed at all of the fixed-monitoring stations, but densities greater than water-quality criteria and standards were observed more often at stations in the Des Plaines River Basin. Results from the analysis of changes in water quality following changes in wastewater-treatment practices indicated that current monitoring programs, although sufficient for their intended purposes, are not suitable for this type of retrospective assessment in large-scale water-quality assessments. Changes were not indicated in fish-community structure and population following changes in wastewater-treatment practices. A strong relation between the quality of the fish community and overall water-quality conditions was observed, although USEPA acute criteria for the protection of freshwater aquatic life were rarely exceeded. Analyses of fish-community data clearly showed that water quality in the urbanized parts of the study area were degraded relative to those in agricultural areas. Total chromium in streambed sediments and total recoverable sodium in water were highly correlated

Illinois, Indiana, Wisconsin↗
USGS2015

The Pacific northwest stream quality assessment

In 2015, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) program is assessing stream quality in the Pacific Northwest. The goals of the Pacific Northwest Stream Quality Assessment (Pacific Northwest study) are to assess the quality of streams in the region by characterizing multiple water-quality factors that are stressors to aquatic life and to evaluate the relation between these stressors and biological communities. The effects of urbanization and agriculture on stream quality for the Puget Lowlands and Willamette Valley are the focus of this regional study. Findings will provide the public and policymakers with information regarding which human and environmental factors are the most critical in affecting stream quality and, thus, provide insights about possible approaches to protect or improve the health of streams in the region. The Pacific Northwest study will be the third regional study by the NAWQA program, and it will be of similar design and scope as the first two—the Midwest in 2013 and the Southeast in 2014 (Van Metre and others, 2012, 2014).

Oregon, Washington↗
USGS1983

Magnitude and frequency of flooding on small urban watersheds in the Tampa Bay area, west-central Florida

Hydrologic data collected on nine small urban watersheds in the Tampa Bay area of west-central Florida and a method for estimating peak discharges in the study area are described. The watersheds have mixed land use and range in size from 0.34 to 3.45 square miles. Watershed soils, land use, and storm-drainage system data are described. Urban development ranged from a sparsely populated area with open-ditch storm sewers and 19% impervious area to a completely sewered watershed with 61% impervious cover. The U.S. Geological Survey natural-basin and urban-watershed models were calibrated for the nine watersheds using 5-minute interval rainfall data from the Tampa, Florida, National Weather Service rain gage to simulate annual peak discharge for the period 1906-52. A log-Pearson Type III frequency analysis of the simulated annual maximum discharge was used to determine the 2-, 5-, 10-, 25-, 50-, and 100-year flood discharges for each watershed. Flood discharges were related in a multiple-linear regression to drainage area, channel slope, detention storage area, and an urban-development factor determined by the extent of curb and gutter street drainage and storm-sewer system. The average standard error for the regional relations ranged from + or - 32 to + or - 42%. (USGS)

Florida↗
USGS1987

Magnitude and frequency of floods in rural and urban basins of North Carolina

The applicability of the nationwide urban flood relations in the Piedmont and Coastal Plain provinces is evaluated. Data for 254 gaging stations on rural streams with 10 or more years of record were used in multiple linear regression analyses with basin and climatic variables, to derive regional relations for estimating flood discharges having recurrence intervals of 2- to 100-years. Rural relations are presented for three hydrologic areas: (1) Blue Ridge-Piedmont, (2) Coastal Plain, and (3) Sand Hills. Drainage area is the only basin characteristic in the relations. The average standard error of estimate of the relations for the Blue Ridge-Piedmont, Coastal Plain, and Sand Hills hydrologic areas is 44, 39, and 24%, respectively. Flood discharges for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for the 254 streamflow stations used in the regionalization study are also presented. Flood frequency distributions of simulated annual maximum discharges for four urban basins in the Coastal Plain indicate that the nationwide relations are applicable in the province. The root mean squared error for the 10- and 100-year flood discharges, using the nationwide relations, is 44% and 49%, respectively. Simulated data for six sites in the Piedmont were used to analyze the applicability of the nationwide urban relations in the province. The root mean squared error is 64% for the 10-year flood and 42% for the 100-year flood. No recommendation is made concerning use of the nationwide relations in the Piedmont.

North Carolina↗
USGS2012

Recent and historic sediment dynamics along Difficult Run, a suburban Virginia Piedmont stream

Suspended sediment is one of the major concerns regarding the quality of water entering the Chesapeake Bay. Some of the highest suspended-sediment concentrations occur on Piedmont streams, including Difficult Run, a tributary of the Potomac River draining urban and suburban parts of northern Virginia. Accurate information on catchment level sediment budgets is rare and difficult to determine. Further, the sediment trapping portion of sediment budget represents an important ecosystem service that profoundly affects downstream water quality. Our objectives, with special reference to human alterations to the landscape, include the documentation and estimation of floodplain sediment trapping (present and historic) and bank erosion along an urbanized Piedmont stream, the construction of a preliminary sediment balance, and the estimation of legacy sediment and recent development impacts. We used white feldspar markers to measure floodplain sedimentation rates and steel pins to measure erosion rates on floodplains and banks, respectively. Additional data were collected for/from legacy sediment thickness and characteristics, mill pond impacts, stream gaging station records, topographic surveying, and sediment density, texture, and organic content. Data were analyzed using GIS and various statistical programs. Results are interpreted relative to stream equilibrium affected by both post-colonial bottomland sedimentation (legacy) and modern watershed hardening associated with urbanization. Six floodplain/channel sites, from high to low in the watershed, were selected for intensive study. Bank erosion ranges from 0 to 470 kg/m/y and floodplain sedimentation ranges from 18 to 1369 kg/m/y (m refers to meters of stream reach). Upstream reaches are net erosional, while downstream reaches have a distinctly net depositional flux providing a watershed sediment balance of 2184 kg/m/y trapped within the system. The amounts of both deposition and erosion are large and suggest nonequilibrium channel conditions. Both peak discharge and number of peaks above base have substantially increased since the mid-1960s when urbanization of the watershed began. Deposition patterns are most closely correlated with channel gradient, sinuosity, and channel width/floodplain width for recent and historic periods. The substantial amounts of fine grained sediment deposited on the floodplain over the past two centuries or so do not appear to be closely related to historic mill pond presence or location. The floodplain continues to provide the critical ecosystem service of sediment trapping in the face of multiple human alterations. Trends in sediment deposition/erosion may react rapidly to land use practices within the watershed and offer a valuable barometer of the effects of management actions.

Geomorphology↗
USGS2022

Discovery and potential ramifications of reduced iron-bearing nanoparticles — Magnetite, wüstite, and zero-valent iron — In wildland–urban interface fire ashes

The increase in fires at the wildland–urban interface has raised concerns about the potential environmental impact of ash remaining after burning. Here, we examined the concentrations and speciation of iron-bearing nanoparticles in wildland–urban interface ash. Total iron concentrations in ash varied between 4 and 66 mg g −1 . Synchrotron X-ray absorption near-edge structure (XANES) spectroscopy of bulk ash samples was used to quantify the relative abundance of major Fe phases, which were corroborated by transmission electron microscopy measurements. Maghemite (γ-(Fe 3+ ) 2 O 3 ) and magnetite (γ-Fe 2+ (Fe 3+ ) 2 O 4 ) were detected in most ashes and accounted for 0–90 and 0–81% of the spectral weight, respectively. Ferrihydrite (amorphous Fe( III )–hydroxide, (Fe 3+ ) 5 HO 8 ·4H 2 O), goethite (α-Fe 3+ OOH), and hematite (α-Fe 3+ 2 O 3 ) were identified less frequently in ashes than maghemite and magnetite and accounted for 0–65, 0–54, and 0–50% of spectral weight, respectively. Other iron phases identified in ashes include wüstite (Fe 2+ O), zerovalent iron, FeS, FeCl 2 , FeCl 3 , FeSO 4 , Fe 2 (SO 4 ) 3 , and Fe(NO 3 ) 3 . Our findings demonstrate the impact of fires at the wildland–urban interface on iron speciation; that is, fires can convert iron oxides ( e.g. , maghemite, hematite, and goethite) to reduced iron phases such as magnetite, wüstite, and zerovalent iron. Magnetite concentrations ( e.g. , up to 25 mg g −1 ) decreased from black to gray to white ashes. Based on transmission electron microscopy (TEM) analyses, most of the magnetite nanoparticles were less than 500 nm in size, although larger particles were identified. Magnetite nanoparticles have been linked to neurodegenerative diseases as well as climate change. This study provides important information for understanding the potential environmental impacts of fires at the wildland–urban interface, which are currently poorly understood.

Environmental Science Nano↗
USGS2010

Occurrence of organic wastewater-indicator compounds in urban streams of the Atlanta area, Georgia, 2003-2006

Between March 2003 and January 2006, 863 water samples were collected from streams in seven urban watersheds with varying land uses within or near the City of Atlanta, Georgia. Sixty-four sampling sites representing three site types were established in those watersheds. The first type consisted of sites within three watersheds not affected by combined sewer overflows; these were designated as the control basins. The second and third site types were established in four watersheds and were designated as sites upstream or downstream from combined sewer outfalls. Stream samples collected during the study were analyzed for major ions, nutrients, trace metals, and 60 organic compounds commonly found in wastewater (organic wastewater-indicator compounds, OWICs). Inorganic constituents were analyzed to discern possible relations between OWICs and urban runoff, sewage effluent, or combined sewer overflows (CSOs). The OWICs were grouped into nine compound classes based either on an already accepted class of compounds (such as pesticide) or the manner in which the compounds are used (such as automotive uses). The compounds benzo(a)pyrene, 4-cumylphenol, 3-tert-butyl-4-hydroxyanisole (BHA), isophorone, isoquinoline, metolachlor, metalaxyl, and 4-octylphenol were not detected in any sample collected during the study. As many as 33 OWICs were detected above study reporting levels in water samples collected from streams in the Intrenchment Creek, Peachtree Creek, Proctor Creek, and South River watersheds (basins with CSOs), a number markedly higher than the number detected in water samples from the control basins (watersheds without CSOs). Several compounds known to disrupt the endocrine systems of aquatic biota were among the compounds detected. The median numbers of OWICs detected in base-flow samples from the control basins ranged from 3 to 4 and 7 to 9 in stormflow samples, while the median in base-flow samples from the four CSO-affected watersheds ranged from 4 to 16 and 11 to 19 in stormflow samples. The detection frequencies and concentrations of OWICs in water samples varied depending on flow conditions during sample collection; however, regardless of flow condition, the total OWICs concentrations were strongly related to the numbers of OWICs detected in these samples. In addition, the median number of detectable OWICs and total OWIC concentrations increased linearly with increasing impervious area and stream flashiness (flashiness indicates the rapidity with which streamflow responds to high rainfall amounts). Four compounds-tris(2-butoxyethyl) phosphate (TBEP), tris(2-chloroethyl) phosphate (TCEP), bromacil, and cholesterol-were detected at concentrations greater than study reporting levels in at least 45 percent of all samples collected during the study. On a broad scale, the seasonal distributions of OWICs detected in samples collected during the study period were consistent with use patterns or urban activity, but were markedly different and more variable within individual watersheds. Seven of the nine OWIC classes were detected with greater frequency in base-flow samples from sites downstream from CSOs than from those upstream from CSOs or from control-basin sites; these OWICs also were detected in a greater percentage of base-flow samples from upstream than control-basin sites. Polycyclic aromatic hydrocarbon (PAH) and automotive-use compounds were detected with similar frequency in base-flow samples from all sites. The pesticides and industrial-use compounds were detected with similar frequency in base-flow samples from sites upstream and downstream from CSOs. The compounds 7-acetyl-1,1,3,4,4,6-hexamethyl tetrahydronaphthalene (AHTN), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl cyclopenta-g-2-benzopyran (HHCB), and triclosan were detected with greater frequency in base-flow than in stormflow samples from all sites. The detection frequencies of these three compounds were particularly high in base-flow samples from downstream sites, especially those from the Intrenchment Creek watershed. In stormflow samples, only the industrial-use compounds were detected with similar frequency among samples from control basins, and upstream and downstream sites. Caffeine, camphor, and menthol were detected in a greater percentage of stormflow than base-flow samples from all sites. The disinfectant byproduct bromoform was detected with the highest frequency in base-flow samples from the upstream sites, particularly those from the South River watershed. Typically, compounds in the pesticide class were detected with similar frequency in base-flow and stormflow samples from upstream and downstream sites, although bromacil and carbaryl were the exceptions. Bromacil was detected with greatest frequency in base-flow samples from all sites, but was detected in a larger percentage of base-flow samples from upstream and downstream sites, especially upstream and downstream sites in the Proctor Creek and South River watersheds. Carbaryl, however, was detected in a greater percentage of stormflow samples from all sites. Although collectively the industrial-use compounds were detected in more stormflow than base-flow samples, tetrachloroethene (PCE) was detected in more base-flow than stormflow samples at all sites. More specifically, PCE was detected with the highest frequency in samples from the upstream sites, particularly those from the Proctor Creek watershed. The similarity in the pattern and distribution of OWICs in samples at sites upstream and downstream from known CSO outfalls indicates that CSOs were not the dominant source of OWICs during the study period. Other sources may include non-sewage discharges-both permitted, permitted but out of compliance, and non-permitted, contaminated groundwater from leaking sewer lines or septic systems, sanitary-sewer overflows, or dry-weather runoff from outdoor water use. These OWICs may be better suited for identifying sewage-contaminated groundwater than sewage-contaminated surface water because groundwater is not typically affected by the OWICs that are more common in urban runoff.

Georgia↗
USGS2022

Ephemeral stream network extraction from lidar-derived elevation and topographic attributes in urban and forested landscapes

Under-representations of headwater channels in digital stream networks can result in uncertainty in the magnitude of headwater habitat loss, stream burial, and watershed function. Increased availability of high-resolution (<2 m) elevation data makes the delineation of headwater channels more attainable. In this study, elevation data derived from light detection and ranging was used to predict ephemeral stream networks across a forested and urban watershed in the Maryland Piedmont USA. A method was developed using topographic openness (TO) and wetness index to remotely predict the extent of stream networks. Predicted networks were compared against a comprehensive field survey of the ephemeral network in each watershed to evaluate performance. Comparisons were also made to the U.S. Geological Survey National Hydrography Dataset (NHD) and a flow accumulation approach where a single drainage area threshold defined channel initiation. Although the NHD and flow accumulation methods resulted in low commission errors, omission errors were highest in these networks. The TO-based networks detected a larger number of ephemeral channels, but with higher commission error. Small ephemeral channels with less defined banks or originating at groundwater seeps were difficult to detect in all methods. Comparisons between forested and urban watersheds also highlight the difficulty of identifying headwater channels using topographic attributes in human-modified landscapes.

Maryland↗
USGS2024

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey↗
USGS2018

Designing a protected area to safeguard imperiled species from urbanization

Reserve design is a process that can address ecological, social, and political factors to identify parcels of land needed to sustain wildlife populations and other natural resources. Acquisition of parcels for a large terrestrial reserve is difficult because it typically occurs over a long timeframe and thus invokes consideration of future conditions such as climate and urbanization changes. In central Florida, a new protected area, the Everglades Headwaters National Wildlife Refuge, has been authorized by the United States Government. The new refuge will host important threatened and endangered species and habitats, as well as be located to allow for species adaptation from climate change impacts. For this study we combined habitat objectives defined by the U.S. Fish and Wildlife Service and projections from two urbanization models to provide guidance for Everglades Headwaters National Wildlife Refuge design. We used Marxan with Zones to find near-optimal solutions for protecting explicit amounts of five target habitats. We identified parcels for inclusion into the reserve design that the model allocated among two zones representing different methods of protection: fee-simple purchase (up to 20,234 hectares authorized by the United States government), and conservation easement agreements (up to 40,469 hectares authorized). As expected, for all scenarios we found an increase in costs as the proportion of fee-simple purchases was increased, reflecting the lesser cost of easements, but the number of parcels required for protection differed little among scenarios. The two urbanization models showed considerable agreement over which habitat patches were not forecast to be developed, and showed some agreement over which parcels might be developed. The U.S. Fish and Wildlife Service may benefit from focusing on parcels that are selected frequently by our analyses under both urban scenarios because these parcels are more likely to be in areas where urbanization threats and demand for land is reduced. The reserve designs we generated met U.S. Fish and Wildlife Service habitat goals within fee and easement zone restrictions, and we found reserve configurations that fell well below the mandated size limit.

Florida↗
USGS2003

Hydrology and water quality of an urban stream reach in the Great Basin — Little Cottonwood Creek near Salt Lake City, Utah, water years 1999–2000

The hydrology and water quality of an urbanized reach of Little Cottonwood Creek near Salt Lake City, Utah, were examined as part of the Great Salt Lake Basins study, part of the U.S. Geological Survey National Water-Quality Assessment program. Physical and chemical properties of the stream were referenced to established aquatic-life criteria as available. Two fixed sampling sites were established on Little Cottonwood Creek with the purpose of determining the influence of urbanization on the water quality of the stream. The fixed-site assessment is a component of the National Water-Quality Assessment surface-water study design used to assess the spatial and temporal distribution of selected water-quality constituents. The occurrence and distribution of major ions, nutrients, trace elements, dissolved and suspended organic carbon, pesticides, volatile organic compounds, and suspended sediment were monitored during this study. From October 1998 to September 2000, stream samples were collected at regular intervals at the two fixed sites. Additional samples were collected at these sites during periods of high flow, which included runoff from snowmelt in the headwaters and seasonal thunderstorms in the lower basin.

Utah↗
USGS2019

The importance of natural versus human factors for ecological conditions of streams and rivers

Streams are influenced by watershed-scale factors, such as climate, geology, topography, hydrology, and soils, which mostly vary naturally among sites, as well as human factors, agriculture and urban development. Thus, natural factors could complicate assessment of human disturbance. In the present study, we use structural equation modeling and data from the 2008-2009 United States National Rivers and Streams Assessment to quantify the relative importance of watershed-scale natural and human factors for in-stream conditions. We hypothesized that biological condition, represented using a diatom multimetric index (MMI), is directly affected by in-stream physicochemical environment, which in turn is regulated by natural and human factors. We evaluated this hypothesis at both national and ecoregion scales to understand how influences vary among regions. We found that direct influences of in-stream environment on diatom MMIs were greater than natural and human factors at the national scale and in all but one ecoregion. Meanwhile, in-stream environments were jointly explained by natural variations in precipitation, base flow index, hydrological stability, % volcanic rock, soil water table depth, and soil depth and by human factors measured as % crops, % other agriculture, and % urban land use. The explained variance of in-stream environment by natural and human factors ranged from 0.30 to 0.75, for which natural factors independently accounted for the largest proportion of explained variance at the national scale and in seven ecoregions. Covariation between natural and human factors accounted for a higher proportion of explained variance of in-stream environment than unique effects of human factors in most ecoregions. Ecoregions with relatively weak effects by human factors had relatively high levels of covariance, high levels of human disturbance, or small ranges in human disturbance. We conclude that accounting for effects of natural factors and their covariation with human factors will be important for accurate ecological assessments.

Science of the Total Environment↗
USGS2021

Identifying sources of contaminants in urban stormwater and evaluation of their removal efficacy across a continuum of urban best management practices

Precipitation events in urban areas often result in stormwater runoff containing a diverse array of chemical contaminants. Although many traditional contaminants, such as nutrients, heavy metals, and polycyclic aromatic hydrocarbons have been studied extensively, only recently has evidence emerged showing that trace organic compounds (TrOCs), including pharmaceuticals, personal care products and pesticides are frequently found in stormwater runoff. As there is little existing information about the sources of TrOCs in urban stormwater or their removal efficacy across a range of stormwater treatment options, we conducted a study to address these knowledge gaps and to characterize the potential contribution of TrOCs to groundwater resources from stormwater infiltration practices, based on several synoptic measurements. The current study allowed us to enhance an existing effort to assess TrOC presence and toxicity in stormwater runoff and treatment pond outflow by addressing questions related to TrOC sources to stormwater and TrOC transport to groundwaters. Analysis of eDNA confirms multiple sources of TrOCs to stormwater including human sewage, dog waste, and feces from waterfowl. It is likely that the presence of some TrOCs detected in stormwater are the result of direct, untreated sewage inputs to stormwater from either human (i.e., leaking sewer infrastructure) or pet waste (washed from sidewalks into storm drains). The seasonal detection of avian eDNA is noteworthy as it highlights seasonality and patterns of migration patterns as contributing factors to stormwater contamination. In contrast to human and pet waste, which likely enters stormwater ponds via the stormwater conveyance system, avian feces may enter ponds either through stormwater runoff or through direct inputs by waterfowl stopping-over temporarily at stormwater ponds. Stormwater ponds had little effect in reducing TrOCs as determined by comparative inflow and outflow analysis. Our results also indicate that overall few TrOCs were present in receiving groundwater adjacent to underground infiltration basins, compared to inflow. However, some contaminants were present at relatively high concentrations compared to stormwater flowing into the basins. This is particularly true for pesticides and their degradants. Fewer TrOCs were detected in interstitial water collected near stormwater ponds compared to inflow and outflow. The presence and concentrations of TrOCs in outflow from ponds was generally similar to or higher than what was observed in inflow. The data collected as part of this study can be used to guide future research or monitoring in an effort to better understand TrOC fate and transport in the environment via stormwater BMPs. Specifically, more work is needed to track parcels of water as they flow through BMPs to better quantify transport and degradation of TrOCs, monitor flow into and out of ponds for mass balance calculations, and conduct tracer tests to better quantify the amount of water that monitoring wells are intercepting from underground infiltration basins. These results have been shared in multiple presentations and in meetings with high school teachers to develop age-appropriate curriculum to highlight the role of individuals in reducing and preventing stormwater contamination. The ongoing pandemic hindered some of these efforts (cancelled conferences; suspended MN Water Roundtable meetings; pre-occupation with teachers moving materials online), however, as dissemination activities become more common in the near future, we will continue to educate stakeholders and educators about the root causes and effects of urban stormwater contamination.

Minnesota↗
USGS1999

Relation of Land Use to Streamflow and Water Quality at Selected Sites in the City of Charlotte and Mecklenburg County, North Carolina, 1993-98

Streamflow and water-quality data were collected at nine sites in the city of Charlotte and Mecklenburg County, North Carolina, during 1993–97. Six of the basins drained areas having relatively homogeneous land use and were less than 0.3 square mile in size; the other three basins had mixed land use. Atmospheric wet-deposition data were collected in three of the basins during 1997–98. Streamflow yield varied by a factor of six among the sites, despite the fact that sites were in close proximity to one another. The lowest yield occurred in a residential basin having no curbs and gutters. The variability in mean flow from these small, relatively homogeneous basins is much greater than is found in streams draining basins that are 10 square miles in size or larger. The ratio of runoff to rainfall in the developing basin appears to have increased during the study period. Low-flow suspended-sediment concentrations in the study basins were about the same magnitude as median stormflow concentrations in Piedmont agricultural basins. Sediment concentrations were higher in the mixed land-use basins and in the developing basin. Median suspended-sediment concentrations in these basins generally were an order of magnitude greater than median concentrations in the other five basins, which had stable land use. Some of the highest total nitrogen concentrations occurred in residential basins. Total nitrogen concentrations detected in this study were about twice as high as concentrations in small Piedmont streams affected by agriculture and urbanization. Most of the total nitrogen consisted of organic nitrogen at all of the sites except in two residential land- use basins. The high ammonia content of lawn fertilizer may explain the higher ammonia concentration in stormflow from residential basins. The two basins with the highest median suspended-sediment concentrations also had the highest total phosphorus concentrations. Median total phosphorus concentrations measured in this study were several times greater than median concentrations in small Piedmont streams but almost an order of magnitude less than total phosphorus concentrations in Charlotte streams during the late 1970's. Bacteria concentrations are not correlated to streamflow. The highest bacteria levels were found in 'first-flush' samples. Higher fecal coliform concentrations were associated with residential land use. Chromium, copper, lead, and zinc occurred at all sites in concentrations that exceeded the North Carolina ambient water-quality standards. The median chromium concentration in the developing basin was more than double the median concentration at any other site. As with chromium, the maximum copper concentration in the developing basin was almost an order of magnitude greater than maximum concentrations at other sites. The highest zinc concentration also occurred in the developing basin. Samples were analyzed for 121 organic compounds and 57 volatile organic compounds. Forty-five organic compounds and seven volatile organic compounds were detected. At least five compounds were detected at all sites, and 15 or more compounds were detected at all sites except two mixed land-use basins. Atrazine, carbaryl, and metolachlor were detected at eight sites, and 90 percent of all samples had measurable amounts of atrazine. About 60 percent of the samples had detectable levels of carbaryl and metolachlor. Diazinon and malathion were measured in samples from seven sites, and methyl parathion, chlorpyrifos, alachlor, and 2,4-D were detected at four or more sites. The fewest compounds were detected in the larger, mixed land-use basins. Residential basins and the developing basin had the greatest number of detections of organic compounds. The pH of wet atmospheric deposition in three Charlotte basins was more variable than the pH measured at a National Atmospheric Deposition Program (NADP)site in Rowan County. Summer pH values were significantly lower than pH measured during the remainder of the year, probably as a result of poorer air quality and different weather patterns during the summer. Concentrations of ammonia and nitrate at the Charlotte sites generally were lower than those measured at the NADP site. Summer concentrations of ammonia and nitrate at both the Charlotte and the NADP sites were significantly greater than concentrations measured during the remainder of the year, again probably reflecting poorer summertime air-quality conditions. Sediment yields at the nine sites ranged from 77 tons per square mile per year in a residential basin to 4,700 tons per square mile per year at the developing basin. Residential areas that have been built-out for several years and industrial areas appear, in general, to have the lowest sediment yields for the Charlotte study sites. Average annual yields of total nitrogen loads ranged from about 1.7 tons per square mile to 6.6 tons per square mile. Average annual total phosphorus yields for all sites except the developing basin were less than 1.4 tons per square mile. Phosphorus yield at the developing basin was 13 .4 tons per square mile per year. Biochemical oxygen demand loading in 1993 from all of the permitted wastewater-treatment facilities in Charlotte and Mecklenburg County was about 1.5 tons per day or 548 tons per year. Converting this point-source loading to an annual yield for the 528 square-mile area of Mecklenburg County is equivalent to 1.03 tons per square mile per year, or a yield much lower than any of the yields measured at the nine study sites. In other words, biochemical oxygen demand loading from nonpoint sources in Mecklenburg County probably exceeds loading from all point sources by a large amount. Loads and average annual yields were computed for five metals-chromium, copper, lead, nickel, and zinc. The highest annual average yields for all five of these metals were in the developing basin, which also had the highest annual average suspended-sediment yield of all the sites. Estimated wet-deposition watershed loadings suggest that atmospheric deposition may be an important source of some metals, including chromium, copper, lead, and zinc, in Charlotte storm water. Storm water from residential land-use basins has higher concentrations of total nitrogen, fecal coliform bacteria, and organic compounds than do other land-use types. Reductions in suspended-sediment concentrations should generally result in reduced export of phosphorus and metals. Stable land uses, such as industrial areas and built-out residential basins, have lower sediment concentrations in stormwater than do mixed land use and developing basins. Finally, atmospheric deposition may be an important source of nitrogen and some metals in Charlotte stormwater.

North Carolina↗