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Lead isotopes in iron and manganese oxide coatings and their use as an exploration guide for concealed mineralization
Lead isotopes from Fe and Mn oxides that coat stream pebbles from around the Mount Emmons porphyry molybdenum deposit in Colorado were studied to assess the feasibility of using Pb isotopes to detect concealed mineral deposits. The Fe/Mn oxide coatings were analyzed to determine their elemental concentrations using ICP-AES. The Pb isotope compositions of solutions from a selected suite of samples were measured, using both thermal ionization and ICP mass spectrometry, to compare results determined by the two analytical methods. Heavy mineral concentrates from the same sites were also analyzed to compare the Pb isotope compositions of the Fe/Mn coatings with those found in panned concentrates. The Fe/Mn and 206 Pb/ 204 Pb ratios of the oxide coatings are related to the lithology of the host rocks; Fe/Mn oxide coatings on pebbles of black shale have higher Fe/Mn values than do the coatings on either sandstone or igneous rocks. The shale host rocks have a more radiogenic signature (e.g. higher 206 Pb/ 204 Pb) than the sandstone or igneous host rocks. The Pb isotope data from sandstone and igneous hosts can detect concealed mineralized rock on both a regional and local scale, even though there are contributions from: (1) metals from the main-stage molybdenite ore deposit; (2) metals from the phyllic alteration zone which has a more radiogenic Pb isotope signature reflecting hydrothermal leaching of Pb from the Mancos Shale; (3) Pb-rich base metal veins with a highly variable Pb isotope signature; and (4) sedimentary country rocks which have a more radiogenic Pb isotope signature. An investigation of within-stream variation shows that the Pb isotope signature of the molybdenite ore zone is retained in the Fe/Mn oxide coatings and is not camouflaged by contributions from Pb-rich base-metal veins that crop out upstream. In another traverse, the Pb isotope data from Fe/Mn oxide coatings reflect a complex mixing of Pb from the molybdenite ore zone and its hornfels margin, Pb-rich base-metal veins, and sedimentary country rocks. Stream-sediment anomalies detected using oxalic acid leaches can be evaluated using Pb isotope analysesof selected geochemical anomalies. Such an evaluation procedure, given regional target Pb isotope signatures for concealed mineralization, can greatly reduce the cost of exploration for undiscovered ore deposits concealed beneath barren overburden. Lead isotope measurements on aliquots of the same solutions showed that ICP-MS determinations are of low precision and vary non-systematically when compared with the Pb isotope values of the higher precision thermal ionization method. These variations and lower precision of the ICP-MS measurements are attributed to matrix effects.
Complex carbonate ore mineralogy in the Mountain Pass carbonatite rare earth element deposit, USA
Economic concentrations of rare earth element (REE) minerals are uncommon in the Earth’s crust, with most occurring in carbonatites. Unlike most igneous rocks composed of silicate minerals, carbonatites are dominated by carbonate minerals, some of which can incorporate significant light REEs (LREEs; La, Ce, Pr, Nd). Technological applications of REEs are numerous and they have been identified as some of the most critical mineral commodities to the global economy. The Mountain Pass carbonatite stock in the Mojave Desert of California is the most economically significant REE deposit in the USA and contains a few to tens of percent (by volume) of the carbonate REE ore mineral bastnäsite. Despite the economic significance of the Mountain Pass deposit, studies of its ore mineralogy are limited. Here we present new carbonate ore mineralogy data for a compositionally diverse suite of carbonatitic rocks from the Mountain Pass stock and related dikes. Whole-rock geochemical data are integrated with mineral-scale textural and chemical data obtained by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and microRaman spectroscopy. Our results document a complex spectrum of REE-bearing carbonate minerals and intermediate mixed-layer structures. Mineral species include bastnäsite [REE(CO 3 )F], hydroxylbastnäsite [REE(CO 3 )OH], parisite [Ca(REE) 2 (CO 3 ) 3 F 2 ], synchysite [Ca(REE)(CO 3 ) 2 F], röntgenite [Ca 2 (Ce,La) 3 (CO 3 ) 5 F 3 ], and sahamalite [(Mg,Fe 2+ )(REE) 2 (CO 3 ) 4 ]. Carbonate ore mineralogy is heterogeneous within and between samples, including at the intracrystal scale. Complexly zoned crystals exhibit as many as five to six different compositional domains and syntaxial intergrowths, commonly with the more Ca-rich varieties (parisite, synchysite) forming crystal rims that surround relict bastnäsite cores. We attribute the phenocryst variability to changes in the chemistry and temperature of primary carbonatite magmas and evolved/exsolved fluids. Cross-cutting vein textures of calcite, celestine and various REE carbonate minerals, interstitial bastnäsite crystallization, breccia blocks lined by fine-grained bastnäsite, and the presence of hydroxylbastnäsite and partially hydroxylated bastnäsite point to the role of secondary hydrothermal processes in REE mineralization. Fluorcarbonate mineral compositions demonstrate that La and Ce are more structurally abundant in bastnäsite, whereas the more Ca-rich species (parisite, synchysite) contain a greater proportion of REE heavier than Pr (Nd, Sm, Eu, Gd) and Y. Atomic ratios of Pr/(Nd + Pr) are likewise variable, with the highest average value for bastnäsite (0.25) compared to parisite (0.22) and sychysite (0.21). This finding has geometallurgical implications, given that current mining operations are focused on recovery of Nd and Pr for high field strength permanent magnets and the Nd/Pr ratios are a critical factor in ore processing and magnet manufacture.
Magnetic map of the Irish Hills and surrounding areas, San Luis Obispo County, central California
A magnetic map of the Irish Hills and surrounding areas was created as part of a cooperative research and development agreement with the Pacific Gas and Electric Company and is intended to promote further understanding of the areal geology and structure by serving as a basis for geophysical interpretations and by supporting geological mapping, mineral and water resource investigations, and other topical studies. Local spatial variations in the Earth's magnetic field (evident as anomalies on magnetic maps) reflect the distribution of magnetic minerals, primarily magnetite, in the underlying rocks. In many cases the volume content of magnetic minerals can be related to rock type, and abrupt spatial changes in the amount of magnetic minerals can be related to either lithologic or structural boundaries. Magnetic susceptibility measurements from the area indicate that bodies of serpentinite and other mafic and ultramafic rocks tend to produce the most intense magnetic anomalies, but such generalizations must be applied with caution because some sedimentary units also can produce measurable magnetic anomalies. Remanent magnetization does not appear to be a significant source for magnetic anomalies because it is an order of magnitude less than the induced magnetization. The map is a mosaic of three separate surveys collected by (1) fixed-wing aircraft at a nominal height of 305 m, (2) by boat with the sensor at sea level, and (3) by helicopter. The helicopter survey was flown by New-Sense Geophysics in October 2009 along flight lines spaced 150-m apart and at a nominal terrain clearance of 50 to 100 m. Tie lines were flown 1,500-m apart. Data were adjusted for lag error and diurnal field variations. Further processing included microleveling using the tie lines and subtraction of the reference field defined by International Geomagnetic Reference Field (IGRF) 2005 extrapolated to August 1, 2008.
Rock geochemistry in the Mahd adh Dhahab district, Kingdom of Saudi Arabia
Ten sets of geochemical samples from country rock, altered country rock, and quartz veins were collected to determine metal abundances and distributions in the Mahd adh Dhahab district. Gold, silver, copper, lead, and zinc are present throughout the district in veins and altered country rock. Although four generations of quartz veins are defined, there is complete gradation between types. The metals present are the same in all four, only the abundances vary. The concentrations of gold, silver, copper, lead, and zinc in altered country rock are zoned around known or projected mineralized-vein zones. Similarities in metal populations of all quartz veins, altered rock, and mineralized zones, plus the distribution of metals and some major elements, suggest that all formed as part of a single hydrothermal system. Gold in abundances greater than 1 ppm does not correlate with any other element and its distribution is very erratic. The variance in gold values between replicate samples collected in 0.5 m square panels is very high. Radio-element analyses (radium-equivalent uranium, thorium, and potassium) for 40 widely distributed sample localities indicate little variation in these elements throughout the district. If the hydrothermal system had an effect on the distribution of these elements, the system must have extended beyond the limits of the sampled area. Anomalous values of gold, silver, lead, and to a lesser extent copper and zinc in surface rock samples clearly delineated the northern mineralized zone in the upper agglomerate, and an east-vein area and west-vein area of the southern mineralized zone in the lower agglomerate. A third geochemically anomalous area occurs farther to the west in the lower agglomerate, suggesting that mineralization may have extended at least to this area along the lower agglomerate-lower tuff contact, and possibly even further to the west.
The Sukari gold deposit, Egypt: Geochemical and geochronological constraints on the ore genesis and implications for regional exploration
The Sukari gold deposit (>15 Moz Au) in the Eastern Desert of Egypt is hosted by a deformed granitoid stock (Sukari tonalite-trondhjemite intrusion) and mainly occurs as a network of crosscutting sulfide-bearing quartz (± carbonate) veins and intensely sulfidized-silicified-sericitized wall rock. Emplacement of the Sukari intrusion into a tectonized Neoproterozoic accretionary complex was controlled by a system of NE- to NNE-trending oblique faults that are related to a deep-seated positive flower structure. A robust genetic model has been hampered by the poorly understood relationships between gold mineralization and host rocks. In this study, zircon U-Pb ages of three samples from the Sukari intrusion define a crystallization age of ~695 ± 2 Ma. In contrast, hydrothermal sericite from the ore zone yields an 40 Ar/ 39 Ar age of ~625 ± 3 Ma, which coincides with the onset of major sinistral transpression in the region. Features including sigmoidal morphology of gold quartz veins and abundant subhorizontal tension gashes alongside widespread brecciation and recrystallization suggest that quartz veining occurred during renewed shortening and exhumation through the brittle-ductile transition. Petrographic and micro-X-ray fluorescence (µXRF) studies indicate that disseminated gold and sulfides, commonly associated with sericite and carbonate alteration, are mostly confined to stylolitic bands in the quartz veins. Oscillatory and sector zoning patterns, irregular As-rich bands, and truncations between early- and late-genetic pyrites reflect variations in temperature and mechanism of ore deposition, demonstrated by variable As/S and Co/Ni ratios in the different pyrite generations. Laser ablation-inductively coupled plasma-mass spectrometry analysis pinpoints the covariance of gold and arsenic contents in pyrite, but free milling gold inclusions in microfractures consistently have a mercury-bearing electrum composition, depicting different ore formation stages. Ore fluids with δ 34 S H 2 s "> S H 2 s values of –1.9 to –3.0‰, modeled from gold-associated pyrite and arsenopyrite assemblages with nearly identical δ 34 S values, suggest a likely single source of sulfur. Alternatively, multisourced sulfur could have extensively mixed and equilibrated by fluid reaction with carbonaceous wall rock. Gold deposition was triggered by abrupt changes in fluid pH and ƒ f O 2 "> O 2 . As an implication for future exploration, sites of maximized strain gradients adjacent to granitoid bodies along extensive transpression zones in the district could be highly prospective targets, particularly where imprinted by sericite-carbonate ± graphite alteration.
Black monazite from Taiwan
Two forms of detrital monazite are known in offshore bars in southwestern Taiwan: a yellow-green to colorless form and an unusual but abundant pelletlike form, generally black but also colored gray or brown. These black pellets, which are about 160 by 200 microns in size, are composed of fine-grained monazite crystals from 2 to 20 microns in size. The pellets are associated with highly variable amounts of discrete grains of detrital quartz, rutile, amphibole, tourmaline, and other minerals. Intergrown with the monazite are quartz, a cerium oxide mineral, chlorite, sulfides, and other minerals. Opaqueness of the pelletlike monazite is due principally to the cryptocrystalline nature of part of the monazite; only a small part of the opaqueness can be attributed to opaque inclusions. The black pelletlike monazite lacks thorium and has a high content of europium. In this respect, as in color, shape, size, and inclusions, the pelletlike monazite differs from the yellow-green detrital monazite. Despite the fact that they occur together in the littoral placers, they appear to have had different origins. The yellow-green monazite originated as an accessory mineral in plutonic rocks and has accumulated at the coast through erosion and transport. The origin of the pelletlike monazite is as yet unknown, but it is here inferred that it originated in unconsolidated coastal plain sediments through migration of cerium from the detrital monazite during weathering, and of the intermediate weight mobile rare earths from clay minerals during diagenesis. Possibly these pelletlike grains are detrital particles formed through erosion and transport from originally larger aggregates cemented by diagenetic monazite.
Pb-Sr-Nd isotopes in surficial materials at the Pebble Porphyry Cu-Au-Mo Deposit, Southwestern Alaska: can the mineralizing fingerprint be detected through cover?
The Cretaceous Pebble porphyry Cu-Au-Mo deposit is covered by tundra and glacigenic sediments. Pb-Sr-Nd measurements were done on sediments and soils to establish baseline conditions prior to the onset of mining operations and contribute to the development of exploration methods for concealed base metal deposits of this type. Pebble rocks have a moderate range for 206 Pb/ 204 Pb = 18.574 to 18.874, 207 Pb/ 204 Pb = 15.484 to 15.526, and 208, Pb/ 204 Pb = 38.053 to 38.266. Mineralized granodiorite shows a modest spread in 87 Sr/ 86 Sr (0.704354–0.707621) and 143 Nd/ 144 Nd (0.512639–0.512750). Age-corrected (89 Ma) values for the granodiorite yield relatively unradiogenic Pb (e.g., 207 Pb/ 204 Pb <15.52), low values of 87 Sr/ 86 Sr, and positive values of ɛNd (1.00–4.52) that attest to a major contribution of mantle-derived source rocks. Pond sediments and soils have similar Pb isotope signatures and 87 Sr/ 86 Sr and 143 Nd/ 144 Nd values that resemble the mineralized granodiorites. Glacial events have obscured the recognition of isotope signatures of mineralized rocks in the sediments and soils. Baseline radiogenic isotope compositions, prior to the onset of mining operations, reflect natural erosion, transport and deposition of heterogeneous till sheets that included debris from barren rocks, mineralized granodiorite and sulfides from the Pebble deposit, and other country rocks that pre- and postdate the mineralization events. Isotopic variations suggest that natural weathering of the deposit is generally reflected in these surficial materials. The isotope data provide geochemical constraints to glimpse through the extensive cover and together with other geochemical observations provide a vector to concealed mineralized rocks genetically linked with the Pebble deposit.
Uranium-bearing lignite and its relation to the White River and Arikaree formations in northwestern South Dakota and adjacent states
In northwestern South Dakota and adjacent areas uranium-bearing lignite beds occur at many horizons in the Hell Creek formation of late Cretaceous age and the overlying Ludlow, Tongue River, and Sentinel Butte members of the Fort Union formation of Paleocene age. Uranium analyses of 275 surface and auger samples and about 1,000 core samples show that many of the lignite beds contain 0. 005 to 0. 02 percent uranium with concentrations of 0. 05 to 0.10 percent uranium in the lignite ash. Analytical data indicate that the region contains an aggregate of at least 47,500, 000 tons of lignite with an average grade of slightly more than .0. 008 percent containing 3, 900 tons of uranium. Almost a fifth of the estimated reserves are adapted to strip mining and are in beds averaging about 4 feet in thickness. Uranium concentrations of this magnitude in lignite indicate that these deposits upon the development of proper utilization techniques and processes may be an important future source of uranium. Recent discoveries of ore-grade deposits of autunite-bearing lignite and secondary uranium minerals in carbonaceous sandstone at Cave Hills and Slim Buttes indicate that northwestern South Dakota and adjacent areas may containimportant reserves of uranium-ore. The stratigraphic units containing the uraniferous lignite beds have a combined thickness of about 1, 500 feet and are unconformably overlapped by 300 feet or more of tuffaceous sandstone and bentonitic claystone of the White River and Arikaree formations of Oligocene and Miocene age. The stratigraphically highest lignite beds in the local sequence have the greatest concentration of uranium,, and the uranium content is greatest at the top of thick lignite beds, diminishing progressively downward to a vanishing point in their lower parts. Variations in permeability of the rock overlying the mineralized lignite beds seem to be reflected in the intensity of uranium mineralization. Most of the known uranium-bearing lignite deposits in the region are closely overlain by the White River and Arikaree formations. Field evidence indicates that the uranium in the lignite is independent of the age of the formation in which the lignite occurs and that the uranium has been concentrated by downward and laterally moving ground water from the overlying mildly radioactive, tuffaceous rocks. The White River and Arikaree formations have about 1.2 times more uranium than the average sedimentary rock. The uranium content of spring water from these formations is 30 times as great or greater than that of normal ground water. Field relations suggest that the uranium is of secondary origin and has been introduced subsequent to the accumulation and marked regional warping of the lignite beds and associated rocks. During the transportation of the uranium-bearing volcanic materials from their place of origin to the site of deposition in South Dakota, the uranium is believed to have been held as a finely disseminated constituent in volcanic ash. Subsequent release or displacement of the uranium is thought to have resulted from weathering and chemical breakdown, thus freeing and allowing the transportation of the uranium, probably in ionic form, to the lignite by downward and laterally moving groundwaters 0 Gar bonaceous material in the path of these uranium-bearing waters is believed to have acted as a receptor that extracted the uranium as a result of an ion exchange mechanism or by the formation of organo-metallic compounds Geologic factors that seem most significant in controlling the distribution and concentration of uranium in Dakota lignites are as follows: 1) stratlgraphic proximity of the lignite to the base of the White River formation; 2) permeability of the rocks overlying the lignites; 3) adsorptive properties and porosities of the lignitic constituents; 4) present and past position of the groundwater table; and 5) the amount of uranium in the original White River and Arikaree sediments. Individual maps showing the extent, thickness, and variations in mineral content of the important deposits in the Table Mountain, Cave Hills, Slim Buttes, Lodgepole, and Medicine Pole areas are included. Conditions controlling the concentration of uranium are described and their application as guides to finding additional reserves by the presently held concepts are explained and illustrated.
Mineral resource database for deposits related to the Mesoproterozoic Midcontinent Rift System, United States and Canada
The Midcontinent Rift System (MRS) of North America is one of the world’s largest continental rifts and has an age of 1.1 Ga (giga-annum). The MRS hosts a diverse suite of magmatic and hydrothermal mineral deposits in the Lake Superior region where rift rocks are exposed at or near the surface. As part of the construction of a database summarizing information on mineral deposits in the MRS, data from regional mineral deposits were downloaded from the U.S. Geological Survey (USGS) Mineral Resources Data System (MRDS), the USGS Mineral Deposit Database (USMIN), and the Ontario Ministry of Energy, Northern Development and Mines Mineral Deposit Inventory (MDI). Deposits related to MRS rocks or mineralizing events were identified and compiled into a database to develop a space/time classification for MRS-related mineral deposits. Information from MRDS, USMIN, and MDI records and from the extensive literature describing MRS mineral deposits was used to classify each entry by deposit type, host rock age and type, and estimated mineralization age. Most deposits were readily classified because of unique mineralogy, location, or well-constrained host rock. These deposits were then put into a tectonic evolutionary framework for the MRS, which showed that many deposits formed within discrete spatial and temporal stages of rift evolution.
Conceptual models of the formation of acid-rock drainage at road cuts in Tennessee
Pyrite and other minerals containing sulfur and trace metals occur in several rock formations throughout Middle and East Tennessee. Pyrite (FeS2) weathers in the presence of oxygen and water to form iron hydroxides and sulfuric acid. The weathering and interaction of the acid on the rocks and other minerals at road cuts can result in drainage with low pH (< 4) and high concentrations of trace metals. Acid-rock drainage can cause environmental problems and damage transportation infrastructure. The formation and remediation of acid-drainage from roads cuts has not been researched as thoroughly as acid-mine drainage. The U.S Geological Survey, in cooperation with the Tennessee Department of Transportation, is conducting an investigation to better understand the geologic, hydrologic, and biogeochemical factors that control acid formation at road cuts. Road cuts with the potential for acid-rock drainage were identifed and evaluated in Middle and East Tennessee. The pyrite-bearing formations evaluated were the Chattanooga Shale (Devonian black shale), the Fentress Formation (coal-bearing), and the Precambrian Anakeesta Formation and similar Precambrian rocks. Conceptual models of the formation and transport of acid-rock drainage (ARD) from road cuts were developed based on the results of a literature review, site reconnaissance, and the initial rock and water sampling. The formation of ARD requires a combination of hydrologic, geochemical, and microbial interactions which affect drainage from the site, acidity of the water, and trace metal concentrations. The basic modes of ARD formation from road cuts are; 1 - seeps and springs from pyrite-bearing formations and 2 - runoff over the face of a road cut in a pyrite-bearing formation. Depending on site conditions at road cuts, the basic modes of ARD formation can be altered and the additional modes of ARD formation are; 3 - runoff over and through piles of pyrite-bearing material, either from construction or breakdown material weathered from shale, and 4 - the deposition of secondary-sulfate minerals can store trace metals and, during rainfall, result in increased acidity and higher concentrations of trace metals in storm runoff. Understanding the factors that control ARD formation and transport are key to addressing the problems associated with the movement of ARD from the road cuts to the environment. The investigation will provide the Tennessee Department of Transportation with a regional characterization of ARD and provide insights into the geochemical and biochemical attributes for the control and remediation of ARD from road cuts.
Remote sensing characterization of the Animas River watershed, southwestern Colorado, by AVIRIS imaging spectroscopy
Visible-wavelength and near-infrared image cubes of the Animas River watershed in southwestern Colorado have been acquired by the Jet Propulsion Laboratory's Airborne Visible and InfraRed Imaging Spectrometer (AVIRIS) instrument and processed using the U.S. Geological Survey Tetracorder v3.6a2 implementation. The Tetracorder expert system utilizes a spectral reference library containing more than 400 laboratory and field spectra of end-member minerals, mineral mixtures, vegetation, manmade materials, atmospheric gases, and additional substances to generate maps of mineralogy, vegetation, snow, and other material distributions. Major iron-bearing, clay, mica, carbonate, sulfate, and other minerals were identified, among which are several minerals associated with acid rock drainage, including pyrite, jarosite, alunite, and goethite. Distributions of minerals such as calcite and chlorite indicate a relationship between acid-neutralizing assemblages and stream geochemistry within the watershed. Images denoting material distributions throughout the watershed have been orthorectified against digital terrain models to produce georeferenced image files suitable for inclusion in Geographic Information System databases. Results of this study are of use to land managers, stakeholders, and researchers interested in understanding a number of characteristics of the Animas River watershed.
Deposit model for heavy-mineral sands in coastal environments
This report provides a descriptive model of heavy-mineral sands, which are sedimentary deposits of dense minerals that accumulate with sand, silt, and clay in coastal environments, locally forming economic concentrations of the heavy minerals. This deposit type is the main source of titanium feedstock for the titanium dioxide (TiO 2 ) pigments industry, through recovery of the minerals ilmenite (Fe 2+ TiO 3 ), rutile (TiO 2 ), and leucoxene (an alteration product of ilmenite). Heavy-mineral sands are also the principal source of zircon (ZrSiO 4 ) and its zirconium oxide; zircon is often recovered as a coproduct. Other heavy minerals produced as coproducts from some deposits are sillimanite/kyanite, staurolite, monazite, and garnet. Monazite [(Ce,La,Nd,Th)PO 4 ] is a source of rare earth elements as well as thorium, which is used in thorium-based nuclear power under development in India and elsewhere. The processes that form coastal deposits of heavy-mineral sands begin inland. High-grade metamorphic and igneous rocks that contain heavy minerals weather and erode, contributing detritus composed of sand, silt, clay, and heavy minerals to fluvial systems. Streams and rivers carry the detritus to the coast, where they are deposited in a variety of coastal environments, such as deltas, the beach face (foreshore), the nearshore, barrier islands or dunes, and tidal lagoons, as well as the channels and floodplains of streams and rivers in the coastal plain. The sediments are reworked by waves, tides, longshore currents, and wind, which are effective mechanisms for sorting the mineral grains on the basis of differences in their size and density. The finest-grained, most dense heavy minerals are the most effectively sorted. The result is that heavy minerals accumulate together, forming laminated or lens-shaped, heavy-mineral-rich sedimentary packages that can be several meters and even as much as tens of meters thick. Most economic deposits of heavy-mineral sands are Paleogene, Neogene, and Quaternary in age; some are modern coastal deposits. Superimposed on these basic processes of ore formation are a multitude of contributing and modifying factors, such as the following: Strong, sustained wave action moves sand from offshore to the shore, where the sand and heavy minerals are sorted by size and density. Mineral sorting occurs mainly on the upper part of the hightide swash (wave) zone. Fine-grained sands and heavy minerals on the foreshore can be remobilized by winds, forming heavy mineral-rich sand dunes behind the beach. Longshore drift combined with the geomorphology of the coast exert strong influence on the location of the heavy-mineral sands deposits. Sea level changes are a function of climatic changes, such as ice ages. Rises in regional sea level (transgression) and lowering of sea level (regression) strongly influence the deposition and preservation of heavy-mineral sands. The majority of heavy-mineral sands accumulation appears related to seaward progradation of the shore during regression events. Local faulting may affect the geomorphology of the coast, which controls the distribution of heavy mineral deposition in a coastal basin. Heavy mineral grains appear to weather primarily after their deposition in the coastal plain; this weathering is caused by groundwaters, humic acids, and other intrabasinal fluids. This weathering can enhance the TiO 2 content of ilmenite. Iron is leached from ilmenite during weathering, which thereby upgrades the TiO 2 content of the ilmenite, forming leucoxene. The resulting deposits of heavy-mineral sands can be voluminous. Individual bodies of heavy mineral-rich sands are typically about 1 kilometer wide and more than 5 kilometers long. Many heavy-mineral sands districts extend for more than 10 kilometers and contain several individual deposits that are spread along an ancient or modern strandline. Reported thicknesses of economic deposits range from 3 to 45 meters. Individual ore deposits typically comprise at least 10 megatonnes of ore (the total size of the individual sand-silt body), whose overall heavy-mineral content is 2 to greater than 10 percent. Heavy-mineral sands deposits are relatively easy to mine because they are weakly to poorly consolidated, and they are relatively easy to process. From a geoenvironmental standpoint, mining of heavy mineral-sands generates little or no acid or solubilized metals. However, environmental and human health concerns related to such mining include potential effects on indigenous flora and fauna, effects on local hydrology, and issues related to processing and storing thorium-bearing monazite, owing to its radioactivity. Regional exploration for deposits of heavy-mineral sands can utilize the analyses of stream sediment samples for Ti, Hf, the rare earth elements, Th, and U, and geophysical surveys, particularly radiometric (gamma-ray spectrometry for K, U, and Th) and magnetic methods. Geophysical anomalies may be small, and surveys are generally more successful when conducted close to sources of interest.
An evaluation of the zircon method of isotopic dating in the Southern Arabian Craton
A zircon study has been made on eleven samples of igneous rocks from the Saudi Arabian Craton. Ages of sized and magnetic fractions of zircon concentrates show variable degrees of discordance which seem to result from a very young disturbance that produces linear arrays in the Concordia plot. Model age calculations based on a statistically and geologically reasonable lower intercept produce very consistent internal relationships. The Pan African Orogeny, considered to be responsible for loss of radiogenic argon and strontium from minerals of many rocks, does not appear to have affected the zircon data, even though uplift had exposed the rocks of the Arabian Shield at that time. Tonalite, granodiorite, and crosscutting leucoadamellite bodies in the southern part of the An Nimas Bathylith yield ages in the time range 820-760 Ma. A narrow time range of 660 to 665 million years was indicated for ages of widely separated and compositionally different intrusive bodies all to the east of the An Nimas Bathylith. This work suggests that the younger end of the age spectrum established from regional K-Ar and Rb-Sr measurements may be underestimated, and that magmatic activity could be more episodic than previously assumed.
An evaluation of the zircon method of isotopic dating in the southern Arabian Craton, Kingdom of Saudi Arabia
A zircon study has been made on 11 samples of igneous rocks from the Saudi Arabian craton. Ages of sized and magnetic fractions of zircon concentrates show variable degrees of discordance, which seem to result from a very young disturbance that produces linear arrays in the Concordia plot. Model age calculations based on a statistically and geologically reasonable lower intercept produce very consistent internal relationships. The Pan African Orogeny, considered to be responsible for loss of radiogenic argon and strontium from minerals of many rocks, does not appear to have affected the zircon data, even though uplift had exposed the rocks of the Arabian Shield at that time. Tonalite, granodiorite, and crosscutting leuco-adamellite bodies in the southern part of the An Nimas batholith yield ages in the time range 820-760 m.y. A narrow time range of 660 to 665 million years was indicated for ages of widely separated and compositionally different intrusive bodies all to the east of the An Nimas batholith. This work suggests that the younger end of the age spectrum established from regional K-Ar and Rb-Sr measurements may be underestimated, and that magmatic activity could have been more episodic than previously assumed.
Preliminary report on certain metals of potential economic interest in thin vanadium-rich zones in the Meade Park member of the Phosphoria Formation in western Wyoming and eastern Idaho
Electron microprobe, optical and chemical studies of fresh and weathered rocks permit preliminary conclusions concerning the concentration and mineralogical residence of certain elements of potential economic significance in thin, vanadium-rich zones in the Meade Peak Member of the Phosphoria Formation in western Wyoming and eastern Idaho. Elements of particular interest are V, Cr, Zn, Cd, Ag, Se, S, Ti, and Mo. Their principal mineralogical residence in fresh or unweathered rock has been established as follows: V is in, or associated with, organic material and minor amounts of V are in Ti-Fe oxysulfide and an unidentified Fe sulfide; Cr is in a 10 A mica. Zn and Cd are in sphalerite; Se is in pyrite; S is in pyrite, sphalerite and organic material; Ti is in TiO 2 and Ti 2 Fe(SO 3 ) 2 and Mo is in powellite. The principal minerals in fresh rocks are quartz, K-feldspar, albite, illite, calcite, and dolomite. Weathering or leaching by ground water removes pyrite, calcite, and dolomite. The leached rock sequences currently mined for phosphate may be amenable to extraction of the metals associated with the organic material.
Heat and mass transport in a vapor-dominated hydrothermal area in Yellowstone National Park, USA: Inferences from magnetic, electrical, electromagnetic, subsurface temperature and diffuse CO2 flux measurements
Vapor‐dominated hydrothermal systems are characterized by localized and elevated heat and gas flux. In these systems, steam and gas ascend from a boiling water reservoir, steam condenses beneath a low‐permeability cap layer, and liquid water descends, driven by gravity (“heat pipe” model). We combine magnetic, electromagnetic, and geoelectrical methods and CO 2 flux and subsurface temperature measurements in the Solfatara Plateau Thermal Area in the Yellowstone Caldera to address several fundamental questions: (1) What are the structural and/or lithological controls on heat and mass transport in vapor‐dominated areas? (2) What is the geometry and size of convecting multiphase thermal plumes? (3) Are thermal plumes associated with subsurface rock alteration and demagnetization? Magnetic and electromagnetic data inversions suggest an asymmetric 50‐ to 100‐m thick basin of glacial deposits with the thickest part adjacent to the margin of a rhyolite flow. The 3‐D electrical conductivity model in the glacial basin reveals a narrow vertical conductor interpreted as a focused multiphase plume, which coincides at the ground surface with the heat and CO 2 flux maxima. The magnetic data suggest that destruction of magnetic minerals due to rock alteration associated with the hydrothermal plume occurs mainly near the ground surface. We propose a model where the buoyant multiphase plume forms in response to decompression, boiling, and phase separation of pressurized thermal groundwater that discharges from the brecciated base of a rhyolite flow into the basin of glacial deposits. Results from multiphase groundwater flow and heat transport numerical simulations corroborate the first‐order characteristics of this model.