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At least 667 records · Page 37Linked to original sources
USGS1973

Microprobe analyses of sericite, chlorite, and epidote from Jerome, Arizona

Volcanic rocks in the vicinity of the massive sulfide deposits at the United Verde mine, Jerome, Ariz., have been modified in several periods of hydrothermal alteration and greenschist metamorphism. Chlorite, 2M, mica (sericite), and epidote are characteristic alteration products. Microprobe analyses for sericite, chlorite, and epidote are recalculated to structural formulas by the method employing oxygen anion equivalents. The sericite has the general composition of muscovite, but is moderately phengitic, and two samples have 6-12 percent paragonite in solid solution. Most of the chlorite is ripidolite with approximately one-third of the tetrahedral sites filled by aluminum; octahedral aluminum slightly exceeds tetrahedral. Fe:Fe+Mg+Mn ratios range from 0.34 to 0.66; low values are associated with sulfide minerals; higher values occur in a sample peripheral to the massive sulfide deposit. The epidote is a solid solution of 70 percent epidote, 30 percent clinozoisite.

Arizona↗
USGS1993

Thermal stability of hydrocarbons in nature: Limits, evidence, characteristics, and possible controls

Numerous petroleum-geochemical analyses of deeply buried, high-rank, fine-grained rocks from ultra-deep wellbores by different investigators demonstrate that C 15 + hydrocarbons (HCs) persist in moderate to high concentrations at vitrinite reflectance ( R 0 ) values of 2.0–5.0% and persist in measurable concentrations up to R 0 = 7.0–8.0%, at which point the thermal deadline for C 15 + HC's is finally approached. Qualitative analyses have been carried out on 1. (1) high-rank gas condensates which have been exposed to the HC-thermal-destructive phase, 2. (2) bitumens from high-temperature aqueous-pyrolysis experiments in the HC-thermal-destructive phase, and 3. (3) bitumens from high-rank, fine-grained rocks near the HC-thermal-destructive phase. These analyses clearly demonstrate that well-defined compositional suites are established in the saturated, aromatic, and sulfur-bearing aromatic HCs in and near the HC-thermal-destructive phase. On the other hand, accepted petroleum-geochemical paradigms place rigid limits on HC thermal stability: C 15 + HCs begin thermal cracking at R 0 values of 0.9% and are completely thermally destroyed by R 0 = 1.35%; C 2 -C 4 HC gases are thermally destroyed by R 0 = 2.0% and methane is thermally destroyed by R 0 = 4.0%. Furthermore, published data and observations in many HC basins worldwide support these models; for example, 1. (1) sharp basinal zonations of gas and oil deposits vs. maturation rank in HC basins and 2. (2) decreasing C 15 + HC concentrations in some fine-grained rocks at ranks of R 0 ≥ 0.9%. The fact that observed data (C 15 + HCs thermally stable to R 0 = 7.0–8.0%) is so far removed from predicted behavior (C 15 + ) HCs expected to be thermally destroyed by R 0 = 1.35%) may be due to 1. (1) a lack of recognition of some important possible controlling parameters of organic matter (OM) metamorphism and too much importance given to other assumed controlling parameters; and 2. (2) assigning HC distribution patterns in petroleum basins to HC thermal cracking when such patterns may be due to other causes. In the first case, laboratory experiments strongly suggest that the presence of water, increasing fluid pressures, and closed systems (product retention) all suppress OM metamorphic reactions. Conversely, the absence of water, low fluid pressures, and open systems (product escape) all promote OM metamorphic reactions. These experiments also demonstrate that OM metamorphic reactions proceed by reaction kinetics greater than first order. Thus, the effect of geologic time appears to have been over-estimated in OM metamorphism. In the second case, the strong decreases in C 15 + HC concentrations in fine-grained rocks with Type III OM over R 0 = 0.9−1.35% are most probably due to intense primary migration and loss of HCs to drilling muds during the trip uphole in drilling operations. Data from coals demonstrate that these decreases in HC concentrations cannot be due to C 15 + HC thermal destruction. Oil deposits are generally found at shallow depths in basins, and “dry gas” (methane ≤ 98% of all HC gases) deposits are found at the greatest depths. This HC distribution pattern would be caused by methane, generated during the late stages of C 15 + HC generation, flushing oil (including C 2 –C 4 HC gases condensed into the liquid phase) out of deep basinal traps by Gussow's (1954) principle of differential entrapment. Hence, only “dry gas” deposits are left in the basin deeps. Oil emplacement processes in traps during expulsion and secondary migration could also contribute to the HC distribution pattern observed in petroleum basins.

Geochimica et Cosmochimica Acta↗
USGS1964

Ground water in folded Cretaceous sandstone of the Bhachau area, Kutch, India, with reference to the Kandla Port water supply

This report is based on an investigation of the availability of ground-water supplies in the Bhachau area for the nearby Kandla Port and township development undertaken by the Government of India. This seaport lies on an estuary of the Gulf of Kutch in western India and in the eastern part of the State of Kutch. The fieldwork on the investigation was carried on from November 1952 through April 1953 with continuing hydrologic observations through 1954-55. The fieldwork included: geologic mapping and delimitation of the principal aquifers of the region; preparation of water-table maps; a detailed inventory of existing wells and springs; observations of significant water table fluctuations; preparation of isobicarb, isochlor and isosulf maps to show the areal distribution of ground-water salinity. The Bhachau area includes about 116 square miles in eastern Kutch and lies in a belt of semiarid low-latitude steppes. The mean annual rainfall is about 15 inches, most of which falls from late June to late September during the southwest monsoon. The area includes a central sandy upland ranging from about 100 to 250 feet above sea level ; a northern lowland of between about 50 to 125 feet altitude that slopes north to the Great Rann of Kutch; a belt of low buttes and discontinuous ridges ranging from about 200 to 275 feet above sea level; and southern lowland which slopes in a southerly to southeasterly direction from an altitude of about 125 feet to 25 feet or less near the Gulf of Kutch. The principal streams are Kageshwar Vokra and Kara Vokra which drain north to the Great Rann and Kotwala Vokra and Dalwala Vokra which drain south toward the Gulf of Kutch. The rocks of the Bhachau area include nonmarine and marine sediments of Mesozoic, Tertiary, and Quaternary age and volcanic rocks of late Mesozoic to early Tertiary age. The oldest rocks in the area are medium- to coarse-grained white to buff current-bedded friable sandstone with occasional partings of white silty shale of the Upper Bhuj series that has been assigned to the Early Cretaceous. The soft friable sandstone of the Upper Bhuj series constitutes the most productive ground-water reservoir in the Bhachau area. At present (1955) there are nine irrigated tracts for which water is obtained from dug wells less than 90 feet deep in the Upper Bhuj. These wells are worked by bullocks and 'motes' (leather bags) at withdrawal rates ranging from about 6,000 to 24,000imperial gallons per day; however, many existing individual wells if equipped with mechanical pumps are capable of yielding 100,000 gallons per day. The Deccan trap of Late Cretaceous to Eocene age occurs in a sequence of basaltic lava flows in the Bhachau area, but trap dikes, sills and plugs that are common in other parts of Kutch have not been observed in the area. Laterite of probable Eocene age is extensive at the top of the Deccan trap, and in places where the lava flows are thin the parent rock has been almost completely lateritized. The Deccan lava flows or the laterite, where the trap is absent, rest disconformably on the Upper Bhuj. No wells have been observed in the Deccan trap of the Bhachau area, but it is possible that locally small supplies of good water may be obtained from these rocks. The Tertiary sediments, which are assigned to the Manchhar series of Pliocene age, generally rest on the laterite or the Deccan trap ; but where both are absent, the Manchhar rests directly on the Upper Bhuj. The Manchhar series includes massive reddish-brown gypseous clay shales, laminated gray siltstones, some limestone, mottled sandstone, and laterite trap gravel. Only meager supplies of brackish water are obtained from wells in these sediments. Along the channels of Kotwala, Dalwala, Kageshwar, and Kara Vokras are narrow bands of unconsolidated coarse sand with fine gravel of Quaternary age. No wells were observed in these deposits, but it is possible that locally they may contain small supplies of bracki

Water Supply Paper↗
USGS1975

A brief history of the U.S. Geological Survey

Established by an Act of Congress in 1879 and charged with responsibility for "classification of the public lands, and examination of the geological structure, mineral resources, and products of the national domain," the U. S. Department of the Interior's Geological Survey has been the Nation's principal source of information about its physical resources the configuration and character of the land surface, the composition and structure of the underlying rocks, and the quality, extent, and distribution of water and mineral resources. Although primarily a research and fact-finding agency, it has responsibility also for the classification of Federal mineral lands and waterpower sites, and since 1926 it has been responsible for the supervision of oil and mining operations authorized under leases on Federal land. From the outset, the Survey has been concerned with critical land and resource problems. Often referred to as the Mother of Bureaus, many of its activities led to the formation of new organizations where a management or developmental function evolved. These included the Reclamation Service (1902), the Bureau of Mines (1910), the Federal Power Commission (1920), and the Grazing Service (1934, since combined with other functions as the Bureau of Land Management). Mrs. Rabbitt's summary of the Survey's history in the following pages brings out well the development of these diverse activities and the Survey's past contributions to national needs related to land and resources.

General Information Product↗
USGS2007

Chapter 7 Magmatic-hydrothermal fluid interaction and mineralization in alkali-syenite nodules from the Breccia Museo pyroclastic deposit, Naples, Italy

The Breccia Museo, a pyroclastic flow that crops out in the Campi Flegrei volcanic complex (Naples, Italy), contains alkali-syenite (trachyte) nodules with enrichment in Cl and incompatible elements (e.g., U, Zr, Th, and rare-earth elements). Zircon was dated at ≈52 ka, by U-Th isotope systematics using a SHRIMP. Scanning electron microscope and electron microprobe analysis of the constituent phases have documented the mineralogical and textural evolution of the nodules of feldspar and mafic accumulations on the magma chamber margins. Detailed electron microprobe data are given for alkali and plagioclase feldspar, salite to ferrosalite clinopyroxene, pargasite, ferrogargasite, magnesio-hastingsite hornblende amphibole, biotite mica, Cl-rich scapolite, and a member (probable davyne-type) of the cancrinite group. Detailed whole rock, major and minor element data are also presented for selected nodules. A wide variety of common and uncommon accessory minerals were identified such as zircon, baddeleyite, zirconolite, pollucite, sodalite, titanite, monazite, cheralite, apatite, titanomagnetite and its alteration products, scheelite, ferberite, uraninite/thorianite, uranpyrochlore, thorite, pyrite, chalcopyrite, and galena. Scanning electron microscope analysis of opened fluid inclusions identified halite, sylvite, anhydrite, tungstates, carbonates, silicates, sulfides, and phosphates; most are probably daughter minerals. Microthermometric determinations on secondary fluid inclusions hosted by alkali feldspar define a temperature regime dominated by hypersaline aqueous fluids. Fluid-inclusion temperature data and mineral-pair geothermometers for coexisting feldspars and hornblende and plagioclase were used to construct a pressure-temperature scenario for the development and evolution of the nodules. We have compared the environment of porphyry copper formation and the petrogenetic environment constructed for the studied nodules. The suite of ore minerals observed in the nodules supports a potential for mineralization, which is similar to that observed in the alkaline volcanic systems of southern Italy (Pantelleria, Pontine Archipelago, Mt. Somma-Vesuvius).

Campi Flegrei↗
USGS1967

The porphyry copper deposit exposed in the Liberty open-pit mine near Ely, Nevada; Part 2, The formation of hydrothermal alteration zones

In the southwest part of the Liberty pit a large porphyry body exhibits a zonal alteration pattern related to fissures and pyrite-bearing veins. The outermost zone contains unaltered K-feldspar, kaolinite after plagioclase, and black biotite after hornblende. An intermediate zone contains reconstituted K-feldspar, phlogopitic biotite, and muscovite or muscovite plus K-feldspar replacing only plagioclase. In the innermost zone the only silicates are quartz and muscovite. In some places an alteration band of K-feldspar after plagioclase separates kaolinite and muscovite.The widespread association of kaolinite and K-feldspar in hydrothermal alteration zones suggests that these two minerals were stable together at the time of formation. Experimental data show that, where quartz controls the activity of silica in solution, kaolinite and K-feldspar should react to form muscovite. However, calculations predict that, at 15,000 psi, solutions with silica activities compatible with amorphous or gelatinous silica could stabilize K-feldspar and kaolinite relative to muscovite at temperatures below about 250 degrees C. The rapid decomposition either of plagioclase feldspar or montmorillonite is considered a prime cause for the attainment of such high activities of silica in pore solutions of rock. The supersaturation of pore solutions with silica is a transient condition; quartz precipitates where kaolinite and K-feldspar react to give muscovite. Thus, the zonally distributed alteration at Ely is considered to have taken place after the rock had cooled to below 250 degrees C. In contrast, the diffusely distributed muscovite and montmorillonite found in another portion of the pit probably commenced at 600 degrees to 700 degrees C with only minor formation of alteration products below 250 degrees C.

Nevada↗
USGS2002

Petroleum geology and total petroleum systems of the Widyan Basin and Interior Platform of Saudi Arabia and Iraq

Two total petroleum systems are associated with the Widyan Basin - Interior Platform Province in northern Saudi Arabia and western Iraq. In the Paleozoic Qusaiba/Akkas/Abba/ Mudawwara Total Petroleum System, which consists of one assessment unit - the Horst/Graben-Related Oil and Gas Assessment Unit - high-gravity, low-sulfur crude oil, as well as natural gas, occurs in horst/graben-related traps that formed prior to, during, and after Hercynian deformation (Carboniferous). The source of oil and gas is from organic-rich marine shale at the base of the Silurian sedimentary sequence (Qusaiba, Akkas, Mudawwara, and Abba Formations) that was deposited under dysoxic to anoxic conditions in an intra-shelf basin located north of the Central Arabian Arch. Onset of oil generation in Iraq began about 250 million years ago (Ma) and in eastern Saudi Arabia about 160 Ma, reaching peak generation, expulsion, migration, and entrapment during the Jurassic Period. In Saudi Arabia, petroleum migrated into fluvial and eolian quartzose sandstones of the Carboniferous-Early Permian Unayzah Formation that overlies the Hercynian unconformity, filling in rifts and half-grabens to thicknesses ranging to more than 400 meters. Combined stratigraphic-structural traps exist where the Unayzah Formation is the reservoir, as is the case in central Saudi Arabia. Oil and gas are sealed in those reservoirs by overlying tight carbonate- evaporite strata, and by subunconformity pinchouts of Pre-Unayzah clastic reservoir units against impermeable facies. In Iraq, reservoirs are sandstones of the Ordovician Upper Khabour and Silurian Akkas Formations. Over most of the Southwestern Desert of Iraq, Lower Silurian shale is a seal for hydrocarbons in the underlying Ordovician Khabour Formation. The Jurassic Gotnia/Barsarin/Sargelu/Najmah Total Petroleum System has two assessment units: the Platform Horst/Graben- Related Oil Assessment Unit and the Basinal Oil and Gas Assessment Unit. All reservoirs are in the Upper Jurassic Najmah Limestone and Gotnia Formation in Iraq, and the correlative Arab Formation in Saudi Arabia, occurring as lenses of marine bar or shelf-margin calcarenites, calcarenitic limestone, and dolomite. These strata grade eastward into organic-rich source rocks that were deposited under anoxic and dysoxic conditions in three restricted intra-shelf basins - from north to south, the Gotnia, Arabian, and Southern Arabian Gulf Basins. Maturation of the Upper Jurassic source-rock formations (Sargelu and Naokelekan Formations in Iraq) began around 90 Ma; peak generation took place from 85 to 13 Ma. With time, the oil migrated updip and was trapped in calcarenite lenses. Later, oil remigrated and was trapped in anticlines that began to form in Early Cretaceous time. Younger Jurassic shale and anhydrite seal rocks are distributed throughout the total petroleum system. The Widyan Basin-Interior Platform Province (2023) ranks 17th in the world, exclusive of the United States, with 62.5 billion barrels of oil equivalent of total petroleum endowment (cumulative production plus remaining petroleum plus estimated mean undiscovered volumes). Mean estimates of undiscovered petroleum for the province, which includes both Paleozoic and Jurassic petroleum systems as well as portions of three additional total petroleum systems from adjacent provinces, are 21.22 billion barrels of oil, 94.75 trillion cubic feet of gas (15.8 billion barrels of oil equivalent), and 6.85 billion barrels of natural gas liquids. The Paleozoic total petroleum system is dominantly gas prone, whereas the volumetrically larger Jurassic total petroleum system is oil prone - resulting in the characterization of the province as an oil province. The discovery maturity for the province is a relatively low 31 percent, meaning that much of the province petroleum potential lies in the future.

Arabian Peninsula↗
USGS1968

Tertiary gold-bearing channel gravel in northern Nevada County, California

The remains of a huge Tertiary gravel-filled channel lie in the area between the South and Middle Yuba Rivers in northern Nevada County, Calif. The deposits in this channel were the site of some of the most productive hydraulic gold mines in California between the 1850's and 1884. The gravel occupies a major channel and parts of several tributaries that in Tertiary time cut into a surface of Paleozoic and Mesozoic igneous and metamorphic rocks. The gravel is partly covered by the remains of an extensive sheet of volcanic rocks, but it crops out along the broad crest of the ridge between the canyons of the South and Middle Yuba Rivers. The lower parts of the gravel deposits generally carry the highest values of placer gold. Traditionally, the richest deposits of all are found in the so-called blue gravel, which, when present, lies just above the bedrock and consists of a very coarse, poorly sorted mixture of cobbles, pebbles, sand, and clay. It is unoxidized, and, at least locally, contains appreciable quantities of secondary sulfide minerals, chiefly pyrite. Information in drill logs from private sources indicates that a 2-mile stretch of the channel near North Columbia contains over half a million ounces of gold dispersed through about 22 million cubic yards of gravel at a grade .averaging about 81 cents per cubic yard. The deposit is buried at depths ranging from 100 to 400 feet. Several geophysical methods have been tested for their feasibility in determining the configuration of the buried bedrock surface, in delineating channel gravel buried under volcanic rocks, and in identifying concentrations of heavy minerals within the gravel. Although the data have not yet been completely processed, preliminary conclusions indicate that some methods may be quite useful. A combination of seismic-refraction and gravity methods was used to determine the depth and configuration of the bottom of the channel to an accuracy within 10 percent as checked by the drill holes. Seismic-refraction methods have identified depressions which are in the bedrock surface, below volcanic rocks, and which may be occupied by gravels. Seismic methods, however, cannot actually recognize the presence of low-velocity gravels beneath the higher velocity volcanic rocks. Electromagnetic methods, supplemented in part by induced-polarization methods, show promise of being able to recognize and trace blue gravel buried less than 200 feet deep. A broad vague magnetic anomaly across the channel suggests that more precise magnetic studies might delineate concentrations of magnetic material. The usefulness of resistivity methods appears from this study to be quite restricted because of irregular topography and the variable conductivity of layers within the gravel.

Circular↗
USGS1999

Age, double porosity, and simple reaction modifications for the MOC3D ground-water transport model

This report documents modifications for the MOC3D ground-water transport model to simulate (a) ground-water age transport; (b) double-porosity exchange; and (c) simple but flexible retardation, decay, and zero-order growth reactions. These modifications are incorporated in MOC3D version 3.0. MOC3D simulates the transport of a single solute using the method-of-characteristics numerical procedure. The age of ground water, that is the time since recharge to the saturated zone, can be simulated using the transport model with an additional source term of unit strength, corresponding to the rate of aging. The output concentrations of the model are in this case the ages at all locations in the model. Double porosity generally refers to a separate immobile-water phase within the aquifer that does not contribute to ground-water flow but can affect solute transport through diffusive exchange. The solute mass exchange rate between the flowing water in the aquifer and the immobile-water phase is the product of the concentration difference between the two phases and a linear exchange coefficient. Conceptually, double porosity can approximate the effects of dead-end pores in a granular porous media, or matrix diffusion in a fractured-rock aquifer. Options are provided for decay and zero-order growth reactions within the immobile-water phase. The simple reaction terms here extend the original model, which included decay and retardation. With these extensions, (a) the retardation factor can vary spatially within each model layer, (b) the decay rate coefficient can vary spatially within each model layer and can be different for the dissolved and sorbed phases, and (c) a zero-order growth reaction is added that can vary spatially and can be different in the dissolved and sorbed phases. The decay and growth reaction terms also can change in time to account for changing geochemical conditions during transport. The report includes a description of the theoretical basis of the model, a detailed description of input requirements and output options, and the results of model testing and evaluation. The model tests illustrate use of these modifications and demonstrate that accurate solutions can be obtained for these simple cases. Two test cases have no dispersion, illustrating the suitability of this method-of-characteristics model for simulation of advection-dominated transport in ground water.

Water-Resources Investigations Report↗
USGS1982

Hydrogeology and results of injection tests at waste-injection test sites in Pinellas County, Florida

Potential benefits or hazards to freshwater resources could result from subsurface injection of treated wastewater. Recognizing this, the U.S. Geological Survey, in cooperation with Pinellas County and the city of St. Petersburg, undertook an evaluation of the hydrogeology and injection of wastewater at proposed test sites on the Pinellas peninsula. The injection sites are underlain by sedimentary rocks ranging in age from Cretaceous to Pleistocene. Lower Eocene carbonate rocks were penetrated to a maximum depth of 3,504 feet and were found to have relatively low water yields. The most permeable part of the investigated section was in rocks of middle Eocene age within the Floridan aquifer. At the injection sites, the Floridan aquifer was subdivided into four permeable zones and three semiconfining beds. The test injection zone is within the Avon Park Limestone, the most productive of the identified permeable zones, with a transmissivity of about 1,000,000 feet squared per day. Two semiconfining beds are above the injection zone in the Suwannee Limestone and Ocala Limestone and have vertical hydraulic conductivities estimated to range from about 0.1 to 1 foot per day where these beds do not contain clay. Limited fresh ground-water supplies exist in the Floridan aquifer within the Pinellas peninsula. At all test sites, chloride concentration in the injection zone ranged from 19,000 to 20,000 milligrams per liter. Injection tests ranging in duration from 3 to 91.1 days were run at three different sites. Pressure buildup occurred in permeable zones above and below the injection zone during these tests. Calculated pressure buildup in observation wells close to and at some distance from the test wells was typically less than 1 pound per square inch. Injection and formation water will probably move slowly through the semiconfining bed overlying the injection zone, and long-term injection tests will be needed to determine the effectiveness of these beds to retard flow. The injected water was well mixed with the native formation water, which, in part, is a direct consequence of the fractures in the injection zone.

Water Supply Paper↗
USGS2017

Selenium

Selenium (Se) was discovered in 1817 in pyrite from copper mines in Sweden. It is a trace element in Earth’s crust, with an abundance of three to seven orders of magnitude less than the major rock-forming elements. Commercial use of selenium began in the United States in 1910, when it was used as a pigment for paints, ceramic glazes, and red glass. Since that time, it has had many other economic uses—notably, in the 1930s and 1940s, when it was used in rectifiers (which change alternating current to direct current), and in the 1960s, when it began to be used in the liner of photocopier drums. In the 21st century, other compounds have replaced selenium in these older products; modern uses for selenium include energy-efficient windows that limit heat transfer and thin-film photovoltaic cells that convert solar energy into electricity. In Earth’s crust, selenium is found as selenide minerals, selenate and selenite salts, and as substitution for sulfur in sulfide minerals. It is the sulfide minerals, most commonly those in porphyry copper deposits, that provide the bulk of the selenium produced for the international commodity market. Selenium is obtained as a byproduct of copper refining and recovered from the anode slimes generated in electrolytic production of copper. Because of this, the countries that have the largest resources and (or) reserves of copper also have the largest resources and (or) reserves of selenium. Because selenium occurs naturally in Earth’s crust, its presence in air, water, and soil results from both geologic reactions and human activity. Selenium is found concentrated naturally in soils that overlie bedrock with high selenium concentrations. Selenium mining, processing, use in industrial and agricultural applications, and disposal may all contribute selenium to the environment. A well-known case of selenium contamination from agricultural practices was discovered in 1983 in the Kesterson National Wildlife Refuge in California. There, waters draining from agricultural fields created wetlands with high concentrations of dissolved selenium in the water. The selenium was taken up by aquatic wildlife and caused massive numbers of embryonic deformities and deaths. Regulatory agencies have since worked to safeguard ecological and human health by creating environmental exposure guidelines based upon selenium concentrations in water and in fish tissue. Any attempt to regulate selenium concentrations requires a delicate balance because selenium occurs naturally and is also a vital nutrient for the health of wildlife, domestic stock, and humans. Selenium is commonly added as a vitamin to animal feed, and in some regions of the United States and the world, it is added as an amendment to soils for uptake by agricultural crops. The important role of selenium in economic products, energy supply, agriculture, and health will continue for well into the future. The challenge to society is to balance the benefits of selenium use with the environmental consequences of its extraction. Increased understanding of the elemental cycle of selenium in the earth may lead to new (or unconventional) sources of selenium, the discovery of new methods of extraction, and new technologies for minimizing the transfer of selenium from rock to biota, so to protect environmental and human health.

Professional Paper↗
USGS1998

Petrofacies Analysis - A Petrophysical Tool for Geologic/Engineering Reservoir Characterization

Petrofacies analysis is defined as the characterization and classification of pore types and fluid saturations as revealed by petrophysical measurements of a reservoir. The word "petrofacies" makes an explicit link between petroleum engineers' concerns with pore characteristics as arbiters of production performance and the facies paradigm of geologists as a methodology for genetic understanding and prediction. In petrofacies analysis, the porosity and resistivity axes of the classical Pickett plot are used to map water saturation, bulk volume water, and estimated permeability, as well as capillary pressure information where it is available. When data points are connected in order of depth within a reservoir, the characteristic patterns reflect reservoir rock character and its interplay with the hydrocarbon column. A third variable can be presented at each point on the crossplot by assigning a color scale that is based on other well logs, often gamma ray or photoelectric effect, or other derived variables. Contrasts between reservoir pore types and fluid saturations are reflected in changing patterns on the crossplot and can help discriminate and characterize reservoir heterogeneity. Many hundreds of analyses of well logs facilitated by spreadsheet and object-oriented programming have provided the means to distinguish patterns typical of certain complex pore types (size and connectedness) for sandstones and carbonate reservoirs, occurrences of irreducible water saturation, and presence of transition zones. The result has been an improved means to evaluate potential production, such as bypassed pay behind pipe and in old exploration wells, or to assess zonation and continuity of the reservoir. Petrofacies analysis in this study was applied to distinguishing flow units and including discriminating pore type as an assessment of reservoir conformance and continuity. The analysis is facilitated through the use of colorimage cross sections depicting depositional sequences, natural gamma ray, porosity, and permeability. Also, cluster analysis was applied to discriminate petrophysically similar reservoir rock.

AAPG Memoir↗
USGS2014

Compositional controls on early diagenetic pathways in fine-grained sedimentary rocks: Implications for predicting unconventional reservoir attributes of mudstones

Diagenesis significantly impacts mudstone lithofacies. Processes operating to control diagenetic pathways in mudstones are poorly known compared to analogous processes occurring in other sedimentary rocks. Selected organic-carbon-rich mudstones, from the Kimmeridge Clay and Monterey Formations, have been investigated to determine how varying starting compositions influence diagenesis. The sampled Kimmeridge Clay Formation mudstones are organized into thin homogenous beds, composed mainly of siliciclastic detritus, with some constituents derived from water-column production (e.g., coccoliths, S-depleted type-II kerogen, as much as 52.6% total organic carbon [TOC]) and others from diagenesis (e.g., pyrite, carbonate, and kaolinite). The sampled Monterey Formation mudstones are organized into thin beds that exhibit pelleted wavy lamination, and are predominantly composed of production-derived components including diatoms, coccoliths, and foraminifera, in addition to type-IIS kerogen (as much as 16.5% TOC), and apatite and silica cements. During early burial of the studied Kimmeridge Clay Formation mudstones, the availability of detrital Fe(III) and reactive clay minerals caused carbonate- and silicate-buffering reactions to operate effectively and the pore waters to be Fe(II) rich. These conditions led to pyrite, iron-poor carbonates, and kaolinite cements precipitating, preserved organic carbon being S-depleted, and sweet hydrocarbons being generated. In contrast, during the diagenesis of the sampled Monterey Formation mudstones, sulfide oxidation, coupled with opal dissolution and the reduced availability of both Fe(III) and reactive siliciclastic detritus, meant that the pore waters were poorly buffered and locally acidic. These conditions resulted in local carbonate dissolution, apatite and silica cements precipitation, natural kerogen sulfurization, and sour hydrocarbons generation. Differences in mud composition at deposition significantly influence subsequent diagenesis. These differences impact their source rock attributes and mechanical properties.

AAPG Bulletin↗
USGS2009

Comparison of natural gases accumulated in Oligocene strata with hydrous pyrolysis gases from Menilite Shales of the Polish Outer Carpathians

This study examined the molecular and isotopic compositions of gases generated from different kerogen types (i.e., Types I/II, II, IIS and III) in Menilite Shales by sequential hydrous pyrolysis experiments. The experiments were designed to simulate gas generation from source rocks at pre-oil-cracking thermal maturities. Initially, rock samples were heated in the presence of liquid water at 330 ??C for 72 h to simulate early gas generation dominated by the overall reaction of kerogen decomposition to bitumen. Generated gas and oil were quantitatively collected at the completion of the experiments and the reactor with its rock and water was resealed and heated at 355 ??C for 72 h. This condition simulates late petroleum generation in which the dominant overall reaction is bitumen decomposition to oil. This final heating equates to a cumulative thermal maturity of 1.6% R r , which represents pre-oil-cracking conditions. In addition to the generated gases from these two experiments being characterized individually, they are also summed to characterize a cumulative gas product. These results are compared with natural gases produced from sandstone reservoirs within or directly overlying the Menilite Shales. The experimentally generated gases show no molecular compositions that are distinct for the different kerogen types, but on a total organic carbon (TOC) basis, oil prone kerogens (i.e., Types I/II, II and IIS) generate more hydrocarbon gas than gas prone Type III kerogen. Although the proportionality of methane to ethane in the experimental gases is lower than that observed in the natural gases, the proportionality of ethane to propane and i-butane to n-butane are similar to those observed for the natural gases. ?? 13 C values of the experimentally generated methane, ethane and propane show distinctions among the kerogen types. This distinction is related to the ?? 13 C of the original kerogen, with 13 C enriched kerogen generating more 13 C enriched hydrocarbon gases than kerogen less enriched in 13 C. The typically assumed linear trend for ?? 13 C of methane, ethane and propane versus their reciprocal carbon number for a single sourced natural gas is not observed in the experimental gases. Instead, the so-called "dogleg" trend, exemplified by relatively 13 C depleted methane and enriched propane as compared to ethane, is observed for all the kerogen types and at both experimental conditions. Three of the natural gases from the same thrust unit had similar "dogleg" trends indicative of Menilite source rocks with Type III kerogen. These natural gases also contained varying amounts of a microbial gas component that was approximated using the ???? 13 C for methane and propane determined from the experiments. These approximations gave microbial methane components that ranged from 13-84%. The high input of microbial gas was reflected in the higher gas:oil ratios for Outer Carpathian production (115-1568 Nm 3 /t) compared with those determined from the experiments (65-302 Nm 3 /t). Two natural gas samples in the far western part of the study area had more linear trends that suggest a different organic facies of the Menilite Shales or a completely different source. This situation emphasizes the importance of conducting hydrous pyrolysis on samples representing the complete stratigraphic and lateral extent of potential source rocks in determining specific genetic gas correlations. ?? 2009 Elsevier Ltd.

Organic Geochemistry↗
USGS2016

Chemical and isotopic changes in Williston Basin brines during long-term oil production: An example from the Poplar dome, Montana

Brine samples were collected from 30 conventional oil wells producing mostly from the Charles Formation of the Madison Group in the East and Northwest Poplar oil fields on the Fort Peck Indian Reservation, Montana. Dissolved concentrations of major ions, trace metals, Sr isotopes, and stable isotopes (oxygen and hydrogen) were analyzed to compare with a brine contaminant that affected groundwater northeast of the town of Poplar. Two groups of brine compositions, designated group I and group II, are identified on the basis of chemistry and 87 Sr/ 86 Sr ratios. The solute chemistry and Sr isotopic composition of group I brines are consistent with long-term residency in Mississippian carbonate rocks, and brines similar to these contaminated the groundwater. Group II brines probably resided in clastic rocks younger than the Mississippian limestones before moving into the Poplar dome to replenish the long-term fluid extraction from the Charles Formation. Collapse of strata at the crest of the Poplar dome resulting from dissolution of Charles salt in the early Paleogene probably developed pathways for the ingress of group II brines from overlying clastic aquifers into the Charles reservoir. Such changes in brine chemistry associated with long-term oil production may be a widespread phenomenon in the Williston Basin.

Montana↗
USGS2012

Estimated trichloroethene transformation rates due to naturally occurring biodegradation in a fractured-rock aquifer

Rates of trichloroethene (TCE) mass transformed by naturally occurring biodegradation processes in a fractured rock aquifer underlying a former Naval Air Warfare Center (NAWC) site in West Trenton, New Jersey, were estimated. The methodology included (1) dividing the site into eight elements of equal size and vertically integrating observed concentrations of two daughter products of TCE biodegradation– cis -dichloroethene ( cis -DCE) and chloride–using water chemistry data from a network of 88 observation wells; (2) summing the molar mass of cis -DCE, the first biodegradation product of TCE, to provide a probable underestimate of reductive biodegradation of TCE, (3) summing the molar mass of chloride, the final product of chlorinated ethene degradation, to provide a probable overestimate of overall biodegradation. Finally, lower and higher estimates of aquifer porosities and groundwater residence times were used to estimate a range of overall transformation rates. The highest TCE transformation rates estimated using this procedure for the combined overburden and bedrock aquifers was 945 kg/yr, and the lowest was 37 kg/yr. However, hydrologic considerations suggest that approximately 100 to 500 kg/yr is the probable range for overall TCE transformation rates in this system. Estimated rates of TCE transformation were much higher in shallow overburden sediments (approximately 100 to 500 kg/yr) than in the deeper bedrock aquifer (approximately 20 to 0.15 kg/yr), which reflects the higher porosity and higher contaminant mass present in the overburden. By way of comparison, pump-and-treat operations at the NAWC site are estimated to have removed between 1,073 and 1,565 kg/yr of TCE between 1996 and 2009.

New Jersey↗
USGS1992

A mid-Permian chert event: Widespread deposition of biogenic siliceous sediments in coastal, island arc and oceanic basins

Radiolarian and conodont of Permian siliceous rocks from twenty-three areas in teh the circum-Pacific and Mediterranean regions reveal a widespread Permian Chert Event during the middle Leonardian to Wordian. Radiolarian- and (or) sponge spicule-rich siliceous sediments accumulated beneath high productivity zones in coastal, island arc and oceanic basins. Most of these deposits now crop out in fault-bounded accreted terranes. Biogenic siliceous sediments did not accumulate in terranes lying beneath infertile waters including the marine sequences in terranes of northern and central Alaska. The Permian Chert Event is coeval with major phosphorite deposition along the western margin of Pangea (Phosphoria Formation and related deposits). A well-known analogue for this event is middle Miocene deposition of biogenic siliceous sediments beneath high productivity zones in many parts of the Pacific and concurrent deposition of phosphatic as well as siliceous sediments in basins along the coast of California. Interrelated factors associated with both the Miocene and Permian depositional events include plate reorientations, small sea-level rises and cool polar waters.

western North America↗
USGS2020

Petrologic insights into rift zone magmatic interactions from the 2011 eruption of Kīlauea Volcano, Hawaiʻi

The high frequency of historical eruptions at Kīlauea Volcano presents an exceptional opportunity to address fundamental questions related to the transport, storage, and interaction of magmas within rift zones. The Nāpau Crater area on Kīlauea’s East Rift Zone (ERZ) experienced nine fissure eruptions within 50 years (1961–2011). Most of the magma intruded during these frequent eruptions remained stored within the rift zone, creating a potential magma mixing depot within the ERZ. The superbly monitored and sampled 2011 eruption (Puʻu ʻŌʻō episode 59) presents an extraordinary opportunity to evaluate magma mixing processes within the ERZ. Whole-rock, glass, and olivine compositions were determined, not only for lava from the 2011 eruption, but also for a new suite of Nāpau Crater area samples from the 1963, 1965, 1968, 1983, and 1997 eruptions, as well as the previously undocumented 1922 eruption. Whole-rock XRF data revealed two geochemically distinct magma batches for episode 59: one less evolved (∼6·6 wt % MgO, 0·46 wt % K2O) than the other (∼6·2 wt % MgO, 0·58 wt % K2O). Episode 59 lava is remarkably aphyric (∼0·1 vol. % phenocrysts), making use of mineralogy to identify parent magma affinities problematic. Linear compositional trends of whole-rock major and trace elements, and reversely zoned olivine crystals indicate episode 59 lavas underwent magma mixing. Least squares regression calculations and plots of major and trace element data, were used to evaluate whether the episode 59 samples are products of mixing summit-derived magma with residual magma from previous Nāpau Crater area eruptions. The regression results and trace element ratios are inconsistent with previously proposed mixing scenarios, but they do support mixing between summit-derived magma and residual magma from the 1983 and 1997 Nāpau Crater area eruptions. These magmas were stored in physically and chemically distinct pods at depths of 1·6–3·0 km prior to mixing with new magma intruded from the summit to produce the episode 59 lava. One pod contained a fractionated equivalent of 1983 lava, and the other a hybrid of compositions similar to 1983 and 1997 lavas. The petrology of episode 59 lava demonstrates that magmas from two previous eruptions (1983 and 1997) were available to mix with magma intruded from the summit region. This study clarifies the pre-eruptive history of the mixed episode 59 lava, and elucidates the evolution of the volcano's magmatic system in a region of frequent eruptions.

Hawaii↗