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At least 667 records · Page 37Linked to original sources

Groundwater model of the Blue River basin, Nebraska-Twenty years later

Groundwater flow models have become almost a routine tool of the practicing hydrologist. Yet, surprisingly little attention has been given to true verification analysis of studies using these models. This paper examines predictions for 1982 of water-level declines and streamflow depletions that were made in 1965 using an electric analog groundwater model of the Blue River basin in southeastern Nebraska. Analysis of the model's predictions suggests that the analog model used too low an estimate of net groundwater withdrawals, yet overestimated water-level declines. The model predicted that almost all of the net groundwater pumpage would come from storage in the Pleistocene aquifer within the Blue River basin. It appears likely that the model underestimated the contributions of other sources of water to the pumpage, and that the aquifer storage coefficients used in the model were too low. There is some evidence that groundwater pumpage has had a greater than predicted effect on streamflow. Considerable uncertainty about the basic conceptualization of the hydrology of the Blue River basin greatly limits the reliability of groundwater models developed for the basin. The paper concludes with general perspectives on groundwater modeling gained from this post-audit analysis.

Nebraska↗

Recent data and information system initiatives for remotely sensed measurements of the land surface

As part of the International Satellite Land Satellite Climatology Program (ISLSCP) Workshop on Remote Sensing of the Land Surface for Studies of Global Change, five invited presentations were given on recent data initiatives relevant to the ISLSCP community. The presentations are summarized in this paper along with some observations by the authors on data systems for the land sciences community. The invited presentations are by no means all inclusive but were selected as examples of current data activities, representing a range of topics associated with data for land sciences including: the generation of global and local scale data sets, the reworking of historical data sets, new data initiatives and some programmatic aspects of land data base development. This paper serves to provide information on these data initiatives and to air some of the issues concerning land science data systems that were raised at the meeting.

Remote Sensing of Environment↗

Rock mechanics observations pertinent to the rheology of the continental lithosphere and the localization of strain along shear zones

Emphasized in this paper are the deformation processes and rheologies of rocks at high temperatures and high effective pressures, conditions that are presumably appropriate to the lower crust and upper mantle in continental collision zones. Much recent progress has been made in understanding the flexure of the oceanic lithosphere using rock-mechanics-based yield criteria for the inelastic deformations at the top and base. At mid-plate depths, stresses are likely to be supported elastically because bending strains and elastic stresses are low. The collisional tectonic regime, however, is far more complex because very large permanent strains are sustained at mid-plate depths and this requires us to include the broad transition between brittle and ductile flow. Moreover, important changes in the ductile flow mechanisms occur at the intermediate temperatures found at mid-plate depths. Two specific contributions of laboratory rock rheology research are considered in this paper. First, the high-temperature steady-state flow mechanisms and rheology of mafic and ultramafic rocks are reviewed with special emphasis on olivine and crystalline rocks. Rock strength decreases very markedly with increases in temperature and it is the onset of flow by high temperature ductile mechanisms that defines the base of the lithosphere. The thickness of the continental lithosphere can therefore be defined by the depth to a particular isotherm Tc above which (at geologic strain rates) the high-temperature ductile strength falls below some arbitrary strength isobar (e.g., 100 MPa). For olivine Tc is about 700??-800??C but for other crustal silicates, Tc may be as low as 400??-600??C, suggesting that substantial decoupling may take place within thick continental crust and that strength may increase with depth at the Moho, as suggested by a number of workers on independent grounds. Put another way, the Moho is a rheological discontinuity. A second class of laboratory observations pertains to the general phenomenon of ductile faulting in which ductile strains are localized into shear zones. Ductile faults have been produced in experiments of five different rock types and is generally expressed as strain softening in constant-strain-rate tests or as an accelerating-creep-rate stage at constant differential stress. A number of physical mechanisms have been identified that may be responsible for ductile faulting, including the onset of dynamic recrystallization, phase changes, hydrothermal alteration and hydrolytic weakening. Microscopic evidence for these processes as well as larger-scale geological and geophysical observations suggest that ductile faulting in the middle to lower crust and upper mantle may greatly influence the distribution and magnitudes of differential stresses and the style of deformation in the overlying upper continental lithosphere.

Tectonophysics↗

Losses from effluent taxes and quotas under uncertainty

Recent theoretical papers by Adar and Griffin ( J. Environ. Econ. Manag. 3 , 178–188 (1976)), Fishelson ( J. Environ. Econ. Manag. 3 , 189–197 (1976)), and Weitzman ( Rev. Econ. Studies 41 , 477–491 (1974)) show that, different expected social losses arise from using effluent taxes and quotas as alternative control instruments when marginal control costs are uncertain. Key assumptions in these analyses are linear marginal cost and benefit functions and an additive error for the marginal cost function (to reflect uncertainty). In this paper, empirically derived nonlinear functions and more realistic multiplicative error terms are used to estimate expected control and damage costs and to identify (empirically) the mix of control instruments that minimizes expected losses.

Journal of Environmental Economics and Management↗

Statistical relationship between pyrite grain size distribution and pyritic sulfur reduction in Ohio coal

This paper presents a statistical relationship between the pyrite particle size distribution and the potential amount of pyritic sulfur reduction achieved by specific-gravity-based separation. This relationship is obtained from data on 26 Ohio coal samples crushed to 14 × 28 mesh. In this paper a prediction equation is developed that considers the complete statistical distribution of all the pyrite particle sizes in the coal sample. Assuming that pyrite particles occurring in coal have a lognormal distribution, the information about the particle size distribution can be encapsulated in terms of two parameters only, the mean and the standard deviation of the logarithms of the grain diameters. When the pyritic sulfur reductions of the 26 coal samples are related to these two parameters, a very satisfactory regression equation ( R 2 = 0.91) results. This equation shows that information on both these parameters is needed for an accurate prediction of potential sulfur reduction, and that the mean and the standard deviation interact negatively insofar as their influence on pyritic sulfur reduction is concerned.

International Journal of Coal Geology↗

Collection and analysis of colloidal particles transported in the Mississippi River, U.S.A.

Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (>63 ??m), silt-sized (<63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.Sediment transport has long been recognized as an important mechanism for the transport of contaminants in surface waters. Suspended sediment has traditionally been divided into three size classes: sand-sized (> 63 ??m), silt-sized (< 63 ??m but settleable) and clay-sized (non-settleable). The first two classes are easily collected and characterized using screens (sand) and settling (silt). The clay-sized particles, more properly called colloids, are more difficult to collect and characterize, and until recently received little attention. From the hydrologic perspective, a colloid is a particle, droplet, or gas bubble with at least one dimension between 0.001 and 1 ??m. Because of their small size, colloids have large specific surface areas and high surface free energies which may facilitate sorption of hydrophobic materials. Understanding what types of colloids are present in a system, how contaminants of interest interact with these colloids, and what parameters control the transport of colloids in natural systems is critical if the relative importance of colloid-mediated transport is to be understood. This paper describes the collection, concentration and characterization of colloidal materials in the Mississippi River. Colloid concentrations, particle-size distributions, mineral composition and electrophoretic mobilities were determined. Techniques used are illustrated with samples collected at St. Louis, Missouri, U.S.A.

Journal of Contaminant Hydrology↗

An analytical model for in situ extraction of organic vapors

This paper introduces a simple convective-flow model that can be used as a screening tool and for conducting sensitivity analyses for in situ vapor extraction of organic compounds from porous media. An assumption basic to this model was that the total mass of volatile organic chemicals (VOC) exists in three forms: as vapors, in the soil solution, and adsorbed to soil particles. The equilibrium partitioning between the vapor-liquid phase was described by Henry's law constants (K(H)) and between the liquid-soil phase by soil adsorption constants (K(d)) derived from soil organic carbon-water partition coefficients (K(oc)). The model was used to assess the extractability of 36 VOCs from a hypothetical site. Most of the VOCs appeared to be removable from soil by this technology, although modeling results suggested that rates for the alcohols and ketones may be very slow. In general, rates for weakly adsorbed compounds (K(oc) < 100 mL/g) were significantly higher when K(H) was greater than 10-4 atm??m3??mol-1. When K(oc) was greater than about 100 mL/g, the rates of extraction were sensitive to the amount of organic carbon present in the soil. The air permeability of the soil material (k) was a critical factor. In situ extraction needs careful evaluation when k is less than 10 millidarcies to determine its applicability. An increase in the vacuum applied to an extraction well accelerated removal rates but the diameter of the well had little effect. However, an increase in the length of the well screen open to the contaminated zone significantly affected removal rates, especially in low-permeability materials.This paper introduces a simple convective-flow model that can be used as a screening tool and for conducting sensitivity analyses for in situ vapor extraction of organic compounds from porous media. An assumption basic to this model was that the total mass of volatile organic chemicals (VOC) exists in three forms: as vapors, in the soil solution, and adsorbed to soil particles. The equilibrium partitioning between the vapor-liquid phase was described by Henry's law constants (KH) and between the liquid-soil phase by soil adsorption constants (Kd) derived from soil organic carbon-water partition coefficients (Koc). The model was used to assess the extractability of 36 VOCs from a hypothetical site. Most of the VOCs appeared to be removable from soil by this technology, although modeling results suggested that rates for the alcohols and ketones may be very slow. In general, rates for weakly adsorbed compounds (Koc < 100 mL/g) were significantly higher when KH was greater than 10-4atm-m3-mol-1. When Koc was greater than about 100 mL/g, the rates of extraction were sensitive to the amount of organic carbon present in the soil. The air permeability of the soil material (k) was a critical factor. In situ extraction needs careful evaluation when k is less than 10 millidarcies to determine its applicability. An increase in the vacuum applied to an extraction well accelerated removal rates but the diameter of the well had little effect. However, an increase in the length of the well screen open to the contaminated zone significantly affected removal rates, especially in low-permeability materials.

Journal of Hazardous Materials↗

Thermal history of the unsaturated zone at Yucca Mountain, Nevada, USA

Secondary calcite, silica and minor amounts of fluorite deposited in fractures and cavities record the chemistry, temperatures, and timing of past fluid movement in the unsaturated zone at Yucca Mountain, Nevada, the proposed site of a high-level radioactive waste repository. The distribution and geochemistry of these deposits are consistent with low-temperature precipitation from meteoric waters that infiltrated at the surface and percolated down through the unsaturated zone. However, the discovery of fluid inclusions in calcite with homogenization temperatures (Th) up to ???80 ??C was construed by some scientists as strong evidence for hydrothermal deposition. This paper reports the results of investigations to test the hypothesis of hydrothermal deposition and to determine the temperature and timing of secondary mineral deposition. Mineral precipitation temperatures in the unsaturated zone are estimated from calcite- and fluorite-hosted fluid inclusions and calcite ??18O values, and depositional timing is constrained by the 207Pb/235U ages of chalcedony or opal in the deposits. Fluid inclusion Th from 50 samples of calcite and four samples of fluorite range from ???35 to ???90 ??C. Calcite ??18O values range from ???0 to ???22??? (SMOW) but most fall between 12 and 20???. The highest Th and the lowest ??18O values are found in the older calcite. Calcite Th and ??18O values indicate that most calcite precipitated from water with ??18O values between -13 and -7???, similar to modern meteoric waters. Twenty-two 207Pb/235U ages of chalcedony or opal that generally postdate elevated depositional temperatures range from ???9.5 to 1.9 Ma. New and published 207Pb/235U and 230Th/Uages coupled with the Th values and estimates of temperature from calcite ??18O values indicate that maximum unsaturated zone temperatures probably predate ???10 Ma and that the unsaturated zone had cooled to near-present-day temperatures (24-26 ??C at a depth of 250 m) by 2-4 Ma. The evidence of elevated temperatures persisting in ash flow tuffs adjacent to parent calderas for as much as ???8 Ma is a new finding, but consistent with thermal modeling. Simulations using the HEAT code demonstrate that prolonged cooling of the unsaturated zone is consistent with magmatic heat inputs and deep-seated (sub-water table) hydrothermal activity generated by the large magma body ???8 km to the north that produced the 15-11 Ma ash flows and ash falls that make up Yucca Mountain. The evidence discussed in this and preceding papers strongly supports unsaturated zone deposition of the secondary minerals from descending meteoric waters. Although depositional temperatures reflect conductive (and possibly vapor-phase convective) heating of the unsaturated zone related to regional magmatic sources until perhaps 6 Ma, depositional conditions similar to the present-day unsaturated zone have prevailed for at least the past 2-4 Ma.

Applied Geochemistry↗

Modeling and management of pit lake water chemistry 1: Theory

Pit lakes are permanent hydrologic/landscape features that can result from open pit mining for metals, coal, uranium, diamonds, oil sands, and aggregates. Risks associated with pit lakes include local and regional impacts to water quality and related impacts to aquatic and terrestrial ecosystems. Stakeholders rely on predictive models of water chemistry to prepare for and manage these risks. This paper is the first of a two part series on the modeling and management of pit lakes. Herein, we review approaches that have been used to quantify wall-rock runoff geochemistry, wall-rock leachate geochemistry, pit lake water balance, pit lake limnology (i.e. extent of vertical mixing), and pit lake water quality, and conclude with guidance on the application of models within the mine life cycle. The purpose of this paper is to better prepare stakeholders, including future modelers, mine managers, consultants, permitting agencies, land management agencies, regulators, research scientists, academics, and other interested parties, for the challenges of predicting and managing future pit lakes in un-mined areas.

Applied Geochemistry↗

Acceptability of residential development in a regional landscape: Potential effects on wildlife occupancy patterns

The conversion of natural lands to developed uses may pose the single greatest human threat to global terrestrial biodiversity. Continued human growth and development over the next century will further exacerbate these effects of habitat loss and fragmentation. Natural resource managers are tasked with managing wildlife as a public trust, yet often have little say in land use decisions. Generally speaking, decision makers could benefit from an understanding of what different regulations mean in terms of wildlife distribution. In a previous paper ( Bettigole et al., 2013 ), we surveyed town residents throughout Vermont to measure how respondents feel about a range of development levels within their town boundaries. We estimated the &ldquo;social carrying capacity for development&rdquo; &ndash; or SK d &ndash; for 251 towns in Vermont. SK d provides an estimate of the level of developed land cover classes that town residents deem &ldquo;acceptable&rdquo; within their town boundaries. In this paper, we design a framework for linking the town-specific SK d estimates with the wildlife distribution patterns for three wide-ranging mammalian species: American black bear ( Ursus americanus ), fisher ( Martes pennanti ), and bobcat ( Lynx rufus ). We simulated landscape conditions at SK d for each town in Vermont, and then used existing occupancy models for the three target species to spatially map and compare occupancy rates in the baseline year 2000 with occupancy rates at SK d . With nearly 90% of Vermont towns willing to increase developed landcover classes within town boundaries compared to baseline levels, significant state-wide changes in occupancy rates were predicted for all three focal species. Average occupancy rates declined by &minus;15.9% and &minus;3.1% for black bear and bobcats, respectively. Average occupancy rates for fisher increased by 9.0%. This study provides a method for linking development standards within a town with wildlife occurrence. Across towns, the methodology spatially identifies areas that may be at risk of future development, as well as identifying areas where wildlife distribution patterns may face future change as a result of increased human population growth and development.

Biological Conservation↗

Amphibian conservation in the Anthropocene

Research is necessary to identify patterns in nature, to understand how a system functions, and to make predictions about the future state of an ecosystem. Applied research in conservation biology can identify effective strategies to maintain biodiversity, though many papers end with the conclusion that more research is needed. However, more research does not necessarily lead to solutions. We use the ongoing global decline of amphibians as a salient example to highlight limitations in current conservation research, and to focus on finding solutions which are directly relevant for conservation. While research has been conducted since declines were first detected in the 1990s, outside a few specific examples, little progress in conservation has been achieved. We suggest that the case of amphibian declines is relevant to conservation science in general, as the current paradigm for conservation is that management is planned after research is completed; research and management are not effectively (and not directly) connected. This disconnect illustrates the knowledge-action divide which has been identified as a serious deficiency in conservation. Accordingly, we use this introductory paper to the Special Issue (Amphibian conservation in the Anthropocene: Progress and challenges) to describe amphibians as a conservation dilemma, and to make the case for a different, more pragmatic, and more solutions-focused view of conservation research.

Kansas, Oklahoma↗

Geochemistry of sulfate minerals in high- and low-temperature environments: A tribute to Robert O. Rye

This special issue is a tribute to Robert O. Rye, known as "Bob" to most, in light of his highly productive and ongoing career. Almost all of the papers in this issue are derived from topical sessions on sulfate minerals in hydrothermal and low-temperature environments. The sessions, held at the 2000 Geological Society of America meeting in Reno, NV, and sponsored jointly by the Mineralogical Society of America, the Society of Economic Geologists and the Geochemical Society, included 29 oral and 9 poster presentations. The sessions complemented a short course on the crystallography, geochemistry and environmental significance of sulfate minerals, sponsored by the Mineralogical Society of America and the Geochemical Society, which immediately preceded the meeting (Alpers et al., 2000). The 23 papers in this special issue typify the breadth of Bob Rye’s research in this important area of geochemistry.

Chemical Geology↗

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology↗

Review and update of the applications of organic petrology: Part 2, geological and multidisciplinary applications

The present paper is focused on organic petrology applied to unconventional and multidisciplinary investigations and is the second part of a two part review that describes the geological applications and uses of this branch of earth sciences. Therefore, this paper reviews the use of organic petrology in investigations of: (i) ore genesis when organic matter occurs associated with mineralization; (ii) the behavior of organic matter in coal fires (self-heating and self-combustion); (iii) environmental and anthropogenic impacts associated with the management and industrial utilization of coal; (iv) archeology and the nature and geographical provenance of objects of organic nature such as jet, amber, other artifacts and coal from archeological sites; and (v) forensic science connected with criminal behavior or disasters. This second part of the review outlines the most recent research and applications of organic petrology in those fields.

International Journal of Coal Geology↗

The geochemistry of deep-sea coral skeletons: a review of vital effects and applications for palaeoceanography

Deep-sea corals were discovered over a century ago, but it is only over recent years that focused efforts have been made to explore the history of the oceans using the geochemistry of their skeletal remains. They offer a promising archive of past oceanic environments given their global distribution, layered growth patterns, longevity and preservation as well as our ability to date them using radiometric techniques. This paper provides an overview of the current state-of-the-art in terms of geochemical approaches to using deep-sea coral skeletons to explore the history of the ocean. Deep-sea coral skeletons have a wide array of morphologies (e.g. solitary cup corals, branching colonial corals) and materials (calcite, aragonite and proteins). As such their biomineralization strategies are diverse, leading to complex geochemistry within coral skeletons. Notwithstanding these complications, progress has been made on developing methods for reconstructing the oceanographic environment in the past using trace elements and isotopic methods. Promising approaches within certain coral groups include clumped isotopes and Mg/Li for temperature reconstructions, boron isotopes and radiocarbon for carbon cycling, εNd, and radiocarbon for circulation studies and δ 15 N, P/Ca and Ba/Ca for nutrient tracer studies. Likewise there is now a range of techniques for dating deep-sea corals skeletons (e.g. U-series, radiocarbon), and determining their growth rates (e.g. radiocarbon and 210 Pb). Dating studies on historic coral populations in the Atlantic, Southern Ocean and Pacific point to climate and environmental changes being dominant controls on coral populations over millennial and orbital timescales. This paper provides a review of a range of successes and promising approaches. It also highlights areas in which further research would likely provide new insights into biomineralization, palaeoceanography and distribution of past coral populations.

Deep-Sea Research Part II: Topical Studies in Ocea↗

Understanding gaps in early detection of and rapid response to invasive species in the United States: A literature review and bibliometric analysis

While concepts regarding invasive species establishment patterns and eradication possibilities have long been a topic of invasion biology, the specific terminology referring to early detection of and rapid response to (EDRR) invasive species emerged in scientific literature during the early 2000s. Since then, the EDRR approach has expanded to include a suite of detection, planning, and management tools. By conducting a systematic literature review, we attempt to characterize the field of EDRR in the United States and its territories as reflected by publication records. Specifically, we assessed publication data such as the number of publications per year, the most common journals where papers were published, and the relationship between author’s keywords for studies focusing on aquatic and terrestrial habitats. For publications that used invasive species occurrence or abundance data (whether collected for the purposes of the respective publication or acquired from another data source), we manually vetted additional information such as focal taxa, data collection years and locations, sources of other data used, and whether data or code were deposited in open access formats. We also conducted network analyses for the author institutions that coauthored papers together most frequently and for the references most cited by EDRR publications. Overall, we found that silos existed in terms of which author institutions worked together, which existing literature was cited, and which topics were frequently explored. We also found evidence of substantial gaps in data access and use. For example, although a wide variety of data sources for invasive species occurrences are available, these sources were seldom cited by published literature, and newly collected data was not often deposited into invasive species databases or other open-source data repositories. Considering the continued advocation for a centralized national EDRR information system, our study suggests that facilitating access to data, decision support tools, and other informational resources represents a key opportunity for improving EDRR capabilities.

Ecological Informatics↗

Markov decision processes in natural resources management: observability and uncertainty

The breadth and complexity of stochastic decision processes in natural resources presents a challenge to analysts who need to understand and use these approaches. The objective of this paper is to describe a class of decision processes that are germane to natural resources conservation and management, namely Markov decision processes, and to discuss applications and computing algorithms under different conditions of observability and uncertainty. A number of important similarities are developed in the framing and evaluation of different decision processes, which can be useful in their applications in natural resources management. The challenges attendant to partial observability are highlighted, and possible approaches for dealing with it are discussed.

Ecological Modelling↗