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Adaptation to climate change is, at its roots, a relational process. Increased awareness of and connection to native species help to drive ʻaina-based (nature-based) restoration practices. As we invest in such local human and more-than-human relationships, we become both more adaptive and more resilient.
A new ion chromatography electrospray tandem mass spectrometry (IC-ESI/MS/MS) method has been developed for quantification and confirmation of chlorate (ClO 3 − ) in environmental samples. The method involves the electro-chemical generation of isotopically labeled chlorate internal standard (Cl 18 O 3 − ) using 18 O water (H 2 18 O). The standard was added to all samples prior to analysis thereby minimizing the matrix effects that are associated with common ions without the need for expensive sample pretreatments. The method detection limit (MDL) for ClO 3 − was 2 ng L −1 for a 1 mL volume sample injection. The proposed method was successfully applied to analyze ClO 3 − in difficult environmental samples including soil and plant leachates. The IC-ESI/MS/MS method described here was also compared to established EPA method 317.0 for ClO 3 − analysis. Samples collected from a variety of environments previously shown to contain natural perchlorate (ClO 4 − ) occurrence were analyzed using the proposed method and ClO 3 − was found to co-occur with ClO 4 − at concentrations ranging from <2 ng L −1 in precipitation from Texas and Puerto Rico to >500 mg kg −1 in caliche salt deposits from the Atacama Desert in Chile. Relatively low concentrations of ClO 3 − in some natural groundwater samples (<0.1 μg L −1 ) analyzed in this work may indicate lower stability when compared to ClO 4 − in the subsurface. The high concentrations of ClO 3 − in caliches and soils (3−6 orders of magnitude greater) as compared to precipitation samples indicate that ClO 3 − , like ClO 4 − , may be atmospherically produced and deposited, then concentrated in dry soils, and is possibly a minor component in the biogeochemical cycle of chlorine.
The effects of water-level regulation on aquatic macrophyte communities, individual plant species, and potential faunal habitat were investigated in a study of two regulated lakes and an unregulated lake in northern Minnesota. Water levels in Rainy Lake and Namakan Reservoir in Voyageurs National Park are regulated by dams. Natural annual fluctuations of 1.8 m are replaced with fluctuations of 1.1 m in Rainy Lake and 2.7 m in the five lakes that comprise Namakan Reservoir. In addition, springtime peaking of water levels in Namakan Reservoir is delayed by one month. After reaching the peak, water levels in the regulated lakes are held at that level through the summer and allowed to gradually decline through autumn and winter. This study was conducted by estimating the cover of each plant species in randomly placed quadrats along transects that followed depth contours in the lakes. These contours were selected to represent different plant habitats, as defined by the timing and duration of flooding and dewatering in unregulated Lac La Croix. Detrended correspondence analysis showed that the macrophyte communities at all depths of the regulated lakes differed from those in the unregulated lake. The differences were more profound in deeper parts of the littoral zone. Lac La Croix contained taxonomically and structurally diverse plant communities at all depths, maximizing faunal habitat. The greatest effect of the regulation on Rainy Lake was along transects at the depth that is never dewatered. There were only four taxa present; they were all erect aquatics that extended through the entire water column and offered little structurally diverse faunal habitat. The greatest effect of regulation on Namakan Lake was along transects at the depth where drawdown occurs in early winter and disturbance results from ice formation in the sediments. Rosette and mat-forming species were dominant, providing minimal faunal habitat. The hydrologic regime at Lac La Croix results in intermediate disturbance that maintains high diversity. There is too little disturbance from water-level fluctuations in Rainy Lake and too much disturbance in Namakan Reservoir, resulting in reduced diversity in both cases. The macrophyte communities of the regulated lake systems would benefit from a return to more natural hydrologic regimes. Namakan Reservoir should be regulated to reach its peak water level at the beginning of June, summer drawdowns should occur at both Rainy Lake and Namakan Reservoir, and the amplitude of annual drawdowns should vary between years but approximate 1.8 m. These hydrologic conditions should, over time, result in more diverse macrophyte communities and more diverse faunal habitat throughout the littoral zone of the regulated lakes.
Adverse ecological and water-quality effects associated with industrial land-use changes are common for littoral wetlands connected to river mouth ecosystems in the Grand Calumet River-Indiana Harbor Canal Area of Concern. These effects can be exacerbated by recent high Lake Michigan water levels that are problematic for wetland restoration. Wetlands in the adjacent Clark and Pine Nature Preserve and Pine Station Nature Preserve are intended to mitigate wetland destruction in the area of concern by restoring residual dune-and-swale wetlands and preserving habitat for endangered and threatened plant species. Physical hydrology and water-quality monitoring of restored wetland cells at the preserves were initiated during 2019 to evaluate changes after wetland restoration efforts in 2015 and near record-low water levels in early 2013. Lake Michigan water levels rose steadily between late 2013 and 2018 to record-high water levels in 2019 and 2020. In this report, precipitation, evapotranspiration, and groundwater and surface-water levels are analyzed to better understand wetland inundation controls and flow directions in restored northern dune-and-swale wetland settings relative to the Grand Calumet River. Continuous specific conductance data and discrete water-quality samples were collected and analyzed to provide a synoptic view of water quality for the restored wetlands. High Lake Michigan water levels affected Grand Calumet River stage and shallow groundwater elevations in the study area after the onset of peak lake levels in June 2019, that persisted through summer 2020, before finally receding in September 2020. Grand Calumet River stage peaked soon after lake levels in July 2019, whereas groundwater elevations in the study area peaked in October 2019. Specific conductance values in closed-basin wetland cells in the western and central parts of the nature preserves indicated a dilution trend and contrasted those of interconnected wetland cells along an eastern corridor, where alterations to wetland cells were more pronounced. Monitoring results indicate that varying seasonal wetland inundation trends with low stands in autumn have returned after high water table conditions owing to high water levels on Lake Michigan. Wetland water balance results during the study period indicated that the wetland ecosystem partially moderated flooding during high lake levels through summer evapotranspiration.
The monitoring program for elk effects on Tomales Point vegetation is designed to provide information on how tule elk grazing affects plant communities and rare species. The basic objective of the program is to show whether the elk are driving the vegetation into an unacceptable state by their grazing. The expectation is that as elk numbers increase, grazing pressure will increase too, resulting in unacceptable levels of any or all of the following: low vegetation ground cover, poor nutritional quality for the elk, undesirable increases in weedy species, unacceptable loss of native plant biodiversity, population declines in rare plants, population declines in plants used for food and nectar by the endangered silverspot butterfly, and increased erosion. The monitoring program has 3 basic components designed to provide complementary information on different aspects of the elk-vegetation system. Long-term plant community monitoring along permanent transects will show how plant species composition and cover are changing since cattle removal in 1979, and it will show whether any of he undesirable traits listed above are developing in the vegetation. However, monitoring these transects alone will not tell us what the effects of continued grazing by elk are apart from changes the vegetation would be undergoing anyway. In order to tease apart the elk effects from change that is happening because of cattle removal, elk exclosures are needed. By sampling inside and outside exclosures, we will be able to see how elk are modifying the rates and directions of change in the vegetation that would be happening in their absence. In a sense, the exclosures serve as a “check” on elk effects. They will allow us to interpret how much of the change is due to elk and how much can be attributed to other processes such as natural succession or weather patterns. This information will allow us to analyze whether changing elk management will have a desirable effect on the vegetation. Finally, periodic mapping and counting of plants in rare plant populations will show whether plant population ranges are expanding and populations are stable or growing. If not, then management actions can be taken to improve habitat conditions for the plants. A general summary of the rationale and sample design for each of the 3 components of the elk-effects monitoring program follows. Field sampling for the entire program should require about 15 weeks for a 2 to 3- person team, and data processing, analysis, and report writing should require about 9 weeks. Time and labor estimates for this program are given in Table A-1. In addition to elk-effects monitoring, Point Reyes staff periodically monitor fire transects and residual dry matter plots on Tomales Point. They are not included as part of the elk-effects monitoring program and they are described elsewhere. Protocols for fire and residual dry matter sampling are not included in the time estimate for the elk- effects monitoring program.
Wildfires are often viewed as destructive disturbances. We propose that when including both evolutionary and socioecological scales, most ecosystem fires can be understood as natural processes that provide a variety of benefits to humankind. Wildfires provide open habitats that enable the evolution of a diversity of shade-intolerant plants and animals that have long been used by humans. There are many provisioning, regulating, and cultural services that we obtain from wildfires; prescribed fires and wildfire management are tools for mimicking the ancestral role of wildfires in a highly populated world.
Knowledge about vegetation and fire history of the mountains of Northern Sicily is scanty. We analysed five sites to fill this gap and used terrestrial plant macrofossils to establish robust radiocarbon chronologies. Palynological records from Gorgo Tondo, Gorgo Lungo, Marcato Cixé, Urgo Pietra Giordano and Gorgo Pollicino show that under natural or near natural conditions, deciduous forests ( Quercus pubescens , Q. cerris , Fraxinus ornus , Ulmus ), that included a substantial portion of evergreen broadleaved species ( Q. suber , Q. ilex , Hedera helix ), prevailed in the upper meso-mediterranean belt. Mesophilous deciduous and evergreen broadleaved trees ( Fagus sylvatica , Ilex aquifolium ) dominated in the natural or quasi-natural forests of the oro-mediterranean belt. Forests were repeatedly opened for agricultural purposes. Fire activity was closely associated with farming, providing evidence that burning was a primary land use tool since Neolithic times. Land use and fire activity intensified during the Early Neolithic at 5000 bc , at the onset of the Bronze Age at 2500 bc and at the onset of the Iron Age at 800 bc . Our data and previous studies suggest that the large majority of open land communities in Sicily, from the coastal lowlands to the mountain areas below the thorny-cushion Astragalus belt (ca. 1,800 m a.s.l.), would rapidly develop into forests if land use ceased. Mesophilous Fagus - Ilex forests developed under warm mid Holocene conditions and were resilient to the combined impacts of humans and climate. The past ecology suggests a resilience of these summer-drought adapted communities to climate warming of about 2 °C. Hence, they may be particularly suited to provide heat and drought-adapted Fagus sylvatica ecotypes for maintaining drought-sensitive Central European beech forests under global warming conditions.
Soils are naturally occurring bodies that form in the interface between the geosphere, biosphere, hydrosphere , and atmosphere. They are the medium for much of the Earth's plant and animal growth. Soil morphology and how it evolves are functions of the soil-forming factors of climate, organisms, relief, parent material, and time. The expression of soil morphology takes the form of layers, called horizons, that differ in their color, particle size distribution, structure, chemistry, and organic matter content from the parent material. A fundamental soil mapping unit in the USA is the soil order and 12 soil orders have been defined on the basis of soil morphology, physical and chemical properties, and climate. Soil geography in the USA is explained by an examination of how these 12 soil orders are found in particular climates, under specific vegetation communities, how they develop from compositionally distinct parent materials, or how they are a result of the age of soil parent material. Paleosols are ancient soils, those that formed in the past. Three types of paleosols are recognized, buried soils (those covered by a younger sediment or rock), exhumed paleosols (formerly buried soils that are now exposed at the surface due to erosion of overlying materials), and relict paleosols (soils that occur at the land surface, but which formed in an environment, such as a climate or biome, very different from that at the present time). Paleosols can help define geologic contacts and can aid in elucidating past climates or vegetation regimes. Although there are rich geologic records of paleosols in the Quaternary, there is an increasing recognition of the importance of all these features in the longer, pre-Quaternary geologic record.
Health of humans, animals, plants, and ecosystems are intertwined. Disturbance tips the balance in favor of weedy species, vectors, and disease agents. Biodiversity is important to prevent imbalance in nature. However, more scholarship is needed, and there is still much more to study, understand, and manage than we currently know.
Soil samples were collected at 420 locations in a 5-km grid pattern in the Istria and Gorski Kotar areas of Croatia, and on the Croatian islands of Cres, Rab and Krk, in order to relate geochemical variation in the soils to underlying differences in geology, bedrock lithology, soil type, environment and natural versus anthropogenic influences. Specific objectives included assessment of possible agricultural and industrial sources of contamination, especially from airborne effluent emitted by a local power plant. The study also tested the adequacy of a fixed-depth soil sampling procedure developed for meager karstic soils. Although 40 geochemical variables were analyzed, only 15 elements and 5 radionuclides are common to all the sample locations. These elements can be divided into three groups: (1) those of mostly anthropogenic origin — Pb, V, Cu and Cr; (2) those of mixed origin — radionuclides and Zn; and (3) those of mostly geogene origin — Ba, Sr, Ti, Al, Na, Ca, Mg, Fe, Mn, Ni and Co. Variation in Pb shows a strong correlation with the pattern of road traffic in Istria. The distributions of Ca, Na and Mg in the flysch basins of southern Istria and Slovenia are clearly distinguishable from the distributions of these elements in the surrounding carbonate terrains, a consequence of differences in bedrock permeability, type of drainage and pH. The spatial pattern of 137 Cs from the Chernobyl nuclear power plant accident reflects almost exclusively the precipitation in Istria during the days immediately after the explosion.
This paper describes a method that uses published data to calculate locally robust CO 2 emission factors for U.S. coal. The method is demonstrated by calculating CO 2 emission factors by coal origin (223 counties, in 1999) and destination (479 power plants, in 2005). Locally robust CO 2 emission factors should improve the accuracy and verification of greenhouse gas emission measurements from individual coal-fired power plants. Based largely on the county origin, average emission factors for U.S. lignite, subbituminous, bituminous, and anthracite coal produced during 1999 were 92.97,91.97,88.20, and 98.91 kg CO 2 /GJ gross , respectively. However, greater variation is observed within these rank classes than between them, which limits the reliability of CO 2 emission factors specified by coal rank. Emission factors calculated by destination (power plant) showed greater variation than those listed in the Emissions & Generation Resource Integrated Database (eGRID), which exhibit an unlikely uniformity that is inconsistent with the natural variation of CO 2 emission factors for U.S. coal. ?? 2010 American Chemical Society.
Weather and climate are strong drivers of population dynamics, plant and animal spatial distributions, community interactions, and ecosystem states. Information on local weather and climate is crucial in interpreting trends and patterns in the natural environment for resource management, research, and visitor enjoyment. This document describes the weather and climate monitoring program at the Channel Islands National Park (fig. 1), initiated in the 1990s. Manual and automated stations, which continue to evolve as technology changes, are being used for this program. The document reviews the history of weather data collection on each of the five Channel Islands National Park islands, presents program administrative structure, and provides an overview of procedures for data collection, archival, retrieval, and reporting. This program overview is accompanied by the 'Channel Islands National Park Remote Automated Weather Station Field Handbook' and the 'Channel Islands National Park Ranger Weather Station Field Handbook'. These Handbooks are maintained separately at the Channel Island National Park as 'live documents' that are updated as needed to provide a current working manual of weather and climate monitoring procedures. They are available on request from the Weather Program Manager (Channel Islands National Park, 1901 Spinnaker Dr., Ventura, CA 93001; 805.658.5700). The two Field Handbooks describe in detail protocols for managing the four remote automated weather stations (RAWS) and the seven manual Ranger Weather Stations on the islands, including standard operating procedures for equipment maintenance and calibration; manufacturer operating manuals; data retrieval and archiving; metada collection and archival; and local, agency, and vendor contracts.
The chemical reactions that lead to the formation of dissolved organic matter (DOM) in natural waters are poorly understood. Studies on the formation of DOM generally are complicated because almost all DOM isolates have been derived from mixtures of plant species composed of a wide variety of different types of precursor compounds for DOM formation. This report describes a study of DOM derived mainly from bales of wheat straw that had been left in a field for several years. During this period of time, black water from the decomposing wheat straw accumulated in pools in the field. The nuclear magnetic resonance and infrared spectra of the black water DOM indicate that it is composed almost entirely of lignin and carbohydrate polymeric units. Analysis by high-performance size-exclusion chromatography with multi-angle laser-light scattering detection indicates that the number average molecular weight of the DOM is 124,000 daltons. The results presented in this report indicate that the black water DOM is composed of hemicellulose chains cross-linked to lignin oligomers. These types of structures have been shown to exist in the hemicellulose matrix of plant cell walls. The cross-linked lignin-hemicellulose complexes apparently were released from partially degraded wheat-straw cell walls with little alteration. In solution in the black water, these lignin-hemicellulose polymers fold into compact globular particles in which the nonpolar parts of the polymer form the interiors of the particles and the polar groups are on the exterior surfaces of the particles. The tightly folded, compact conformation of these particles probably renders them relatively resistant to microbial degradation. This should be especially the case for the aromatic lignin structures that will be buried in the interiors of the particles.
The Rio Grande Valley study unit of the U.S. Geological Survey National Water-Quality Assessment Program collected monthly water- quality samples at a network of surface-water sites from April 1993 through September 1995. This basic-fixed-site network consisted of nine main-stem sites on the Rio Grande, five sites on tributaries of the Rio Grande, two sites on streams in the Rio Grande Valley study unit that are not directly tributary to the Rio Grande, and one site on a conveyance channel. During each monthly sampling, field properties were measured and samples were collected for the analysis of dissolved solids, major constituents, nutrients, selected trace elements, and suspended-sediment concentrations. During selected samplings, supplemental samples were collected for the analysis of additional trace elements, organic carbon, and/or pesticides. Spatial variations of dissolved-solids, major-constituent, and nutrient data were analyzed. The report presents summary statistics for the monthly water-quality data by sampling site and background information on the drainage basin upstream from each site. Regression equations are presented that relate dissolved-solids, major-constituent, and nutrient concentrations to streamflow, selected field properties, and time. Median instantaneous streamflow at each basic-fixed site ranged from 1.4 to 1,380 cubic feet per second. Median specific conductance at each basic-fixed site ranged from 84 to 1,680 microsiemens per centimeter at 25 degrees Celsius, and median pH values ranged from 7.8 to 8.5. The water sampled at the basic-fixed sites generally was well oxygenated and had a median dissolved-oxygen percent of saturation range from 89 to 108. With the exception of Rio Grande above mouth of Trinchera Creek, near Lasauses, Colorado, dissolved-solids concentrations in the main stem of the Rio Grande generally increased in a downstream direction. This increase is from natural sources such as ground-water inflow and evapotranspiration and from anthropogenic sources such as irrigation- return flows, urban runoff, and wastewater-treatment plant discharges. The smallest median dissolved-solids concentration detected at a basic- fixed site was 58 milligrams per liter and the largest was 1,240 milligrams per liter. The spatial distribution of calcium, magnesium, sodium, sulfate, chloride, and fluoride was similar to the spatial distribution of dissolved solids. The spatial distribution of potassium and bicarbonate varied slightly from that of dissolved solids. Median silica concentrations generally decreased in a downstream direction. Of all cations, calcium and sodium had the largest concentrations at most basic-fixed sites. Bicarbonate and sulfate were the anions having the largest concentrations at most sites. The largest median silica concentration was at Rito de los Frijoles in Bandelier National Monument, New Mexico, where silica composed approximately 50 percent of the dissolved solids. The largest concentrations and largest median concentrations of dissolved-nutrient analytes were detected at Santa Fe River above Cochiti Lake, New Mexico, and Rio Grande at Isleta, New Mexico. The relatively large dissolved-nutrient concentrations at these sites probably were due to discharges from wastewater-treatment plants and urban runoff. The largest concentrations and largest median concentrations of total ammonia plus organic nitrogen and total phosphorus were detected at Rio Puerco near Bernardo, New Mexico. The largest concentrations of these nutrients at this site were associated with runoff from summer thunderstorms. Dissolved-iron concentrations ranged from censored concentrations to 914 micrograms per liter. Median dissolved-iron concentrations ranged from 3 to 160 micrograms per liter.
Natural-resource managers and other conservation practitioners are under unprecedented pressure to categorize and quantify the vulnerability of natural systems based on assessment of the exposure, sensitivity, and adaptive capacity of species to climate change. Despite the urgent need for these assessments, neither the theoretical basis of adaptive capacity nor the practical issues underlying its quantification has been articulated in a manner that is directly applicable to natural-resource management. Both are critical for researchers, managers, and other conservation practitioners to develop reliable strategies for assessing adaptive capacity. Drawing from principles of classical and contemporary research and examples from terrestrial, marine, plant, and animal systems, we examined broadly the theory behind the concept of adaptive capacity. We then considered how interdisciplinary, trait- and triage-based approaches encompassing the oft-overlooked interactions among components of adaptive capacity can be used to identify species and populations likely to have higher (or lower) adaptive capacity. We identified the challenges and value of such endeavors and argue for a concerted interdisciplinary research approach that combines ecology, ecological genetics, and eco-physiology to reflect the interacting components of adaptive capacity. We aimed to provide a basis for constructive discussion between natural-resource managers and researchers, discussions urgently needed to identify research directions that will deliver answers to real-world questions facing resource managers, other conservation practitioners, and policy makers. Directing research to both seek general patterns and identify ways to facilitate adaptive capacity of key species and populations within species, will enable conservation ecologists and resource managers to maximize returns on research and management investment and arrive at novel and dynamic management and policy decisions.
Records obtained by the Geological Survey, United States Department of the Interior, and the Geological Division, Kentucky Department of Mines and Minerals, indicate that industries at Louisville pumped about 62 million gallons of water per day from wells in 1943. This was over 20 million gallons a day more than the natural recharge to the glacial outwash sand and gravel from which the wells draw the water. The ground water is especially in demand because of its uniformly low temperature throughout the year. In order to stop the resulting serious decline of water levels and decrease in yields of wells, the pumpage is now gradually being reduced. Also, the recharge has been increased about 2 million gallons a day by introducing water into the aquifer through wells. During the spring of 1944 the Seagram and National distilleries helped solve a local shortage of ground water by recharging the underground reservoir with 1.7 million gallons a day of cold water from the municipal river-water supply. While this water was being added to the aquifer through several supply wells the plants were operated with additional city water, and the rest of the supply wells were kept idle. In this way, the large cone of depression in the water table that had been created by heavy pumping from the wells was practically filled with cold water from a combination of natural and artificial recharge. As a result, during the summer when the city water became too warm to be used in the plants, an increased and ample supply of cold water was available from the wells. It has been suggested that other industries at Louisville might adopt similar procedures for insuring adequate supplies of cold water during the summers.
Early detection and eradication of invasive plants are more cost-effective than managing well-established invasive plant populations and their impacts. However, there is high uncertainty around which taxa are likely to become invasive in a given area. Horizon scanning that combines a data-driven approach with rapid risk assessment and consensus building among experts can help identify invasion threats. We performed a horizon scan of potential invasive plant threats to Florida, USA—a state with a high influx of introduced species, conditions that are generally favorable for plant establishment, and a history of negative impacts from invasive plants. We began with an initial list of 2128 non-native plant taxa that are known invaders or crop pests. We built on previous invasive species horizon scans by developing data-based criteria to prioritize 100 taxa for rapid risk assessment. The semi-automated prioritization process included selecting taxa “on the horizon” (i.e., not yet in the target location and not on a noxious weed list) with climate matching, naturalization history, “weediness” record, and global commonness. We derived overall invasion risk scores with rapid risk assessment by evaluating the likelihood of each of the taxa arriving, establishing, and having an impact in Florida. Then, following a consensus-building discussion, we identified six plant taxa as high risk, with overall risk scores ranging from 75 to 100 out of a possible 125. The six taxa are globally distributed, easily transported to new areas, found in regions with climates similar to Florida’s, and can impact native plant communities, human health, or agriculture. Finally, we evaluated our initial and final lists for potential biases. Assessors tended to assign higher risk scores to taxa that had more available information. In addition, we identified biases towards four plant families and certain geographical regions of origin. Our horizon scan approach identified taxa conforming to metrics of high invasion risk and used a methodology refined for plants that can be applied to other locations.
The South District Wastewater Treatment Plant in southeastern Miami-Dade County, Florida, includes a Class I treated wastewater injection well system. The detection of ammonia in monitoring zones above the injection zone in the Lower Floridan aquifer has elicited a need to understand the nature of confinement within the Lower Floridan aquifer as it pertains to the vertical migration of injectate out of the injection zone upward into the Underground Source of Drinking Water in the upper part of the Floridan aquifer system. Geologic and geophysical data, borehole video imagery, and aquifer performance data were used to refine and clarify the geologic and hydrogeologic frameworks of part of the Lower Floridan aquifer at the treatment plant. The data provide evidence for zones of enhanced dissolution permeability, extensive secondary porosity, fractures, karst collapse structures, and faults that could provide vertical cross-formational fluid pathways that transect the Lower Floridan aquifer.