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Future trends in transport and fate of diffuse contaminants in catchments, with special emphasis on stable isotope applications

A summary is provided of the first of a series of proposed Integrated Science Initiative workshops supported by the UNESCO International Hydrological Programme. The workshop brought together hydrologists, environmental chemists, microbiologists, stable isotope specialists and natural resource managers with the purpose of communicating new ideas on ways to assess microbial degradation processes and reactive transport at catchment scales. The focus was on diffuse contamination at catchment scales and the application of compound-specific isotope analysis (CSIA) in the assessment of biological degradation processes of agrochemicals. Major outcomes were identifying the linkage between water residence time distribution and rates of contaminant degradation, identifying the need for better information on compound specific microbial degradation isotope fractionation factors and the potential of CSIA in identifying key degradative processes. In the natural resource management context, a framework was developed where CSIA techniques were identified as practically unique in their capacity to serve as distributed integrating indicators of process across a range of scales (micro to diffuse) of relevance to the problem of diffuse pollution assessment. Copyright ?? 2006 John Wiley & Sons, Ltd.

Hydrological Processes↗

Interactions among wildland fires in a long-established Sierra Nevada natural fire area

We investigate interactions between successive naturally occurring fires, and assess to what extent the environments in which fires burn influence these interactions. Using mapped fire perimeters and satellite-based estimates of post-fire effects (referred to hereafter as fire severity) for 19 fires burning relatively freely over a 31-year period, we demonstrate that fire as a landscape process can exhibit self-limiting characteristics in an upper elevation Sierra Nevada mixed conifer forest. We use the term 'self-limiting' to refer to recurring fire as a process over time (that is, fire regime) consuming fuel and ultimately constraining the spatial extent and lessening fire-induced effects of subsequent fires. When the amount of time between successive adjacent fires is under 9 years, and when fire weather is not extreme (burning index <34.9), the probability of the latter fire burning into the previous fire area is extremely low. Analysis of fire severity data by 10-year periods revealed a fair degree of stability in the proportion of area burned among fire severity classes (unchanged, low, moderate, high). This is in contrast to a recent study demonstrating increasing high-severity burning throughout the Sierra Nevada from 1984 to 2006, which suggests freely burning fires over time in upper elevation Sierra Nevada mixed conifer forests can regulate fire-induced effects across the landscape. This information can help managers better anticipate short- and long-term effects of allowing naturally ignited fires to burn, and ultimately, improve their ability to implement Wildland Fire Use programs in similar forest types. ?? 2008 Springer Science+Business Media, LLC.

Ecosystems↗

Education and training of future wetland scientists and managers

Wetland science emerged as a distinct discipline in the 1980s. In response, courses addressing various aspects of wetland science and management were developed by universities, government agencies, and private firms. Professional certification of wetland scientists began in the mid-1990s to provide confirmation of the quality of education and experience of persons involved in regulatory, management, restoration/construction, and research involving wetland resources. The education requirements for certification and the need for persons with specific wetland training to fill an increasing number of wetland-related positions identified a critical need to develop curriculum guidelines for an undergraduate wetland science and management major for potential accreditation by the Society of Wetland Scientists. That proposed major contains options directed toward either wetland science or management. Both options include required basic courses to meet the general education requirements of many universities, required upper-level specialized courses that address critical aspects of physical and biological sciences applicable to wetlands, and a minimum of four additional upper-level specialized courses that can be used to tailor a degree to students' interests. The program would be administered by an independent review board that would develop guidelines and evaluate university applications for accreditation. Students that complete the required coursework will fulfill the education requirements for professional wetland scientist certification and possess qualifications that make them attractive candidates for graduate school or entry-level positions in wetland science or management. Universities that offer this degree program could gain an advantage in recruiting highly qualified students with an interest in natural resources. Alternative means of educating established wetland scientists are likewise important, especially to provide specialized knowledge and experience or updates related to new management discoveries, policies, and regulations. ?? 2008 The Society of Wetland Scientists.

Wetlands↗

Catalog of US GeoData

The development of geographic information systems (GIS) is a rapidly growing industry that supports natural resources, studies, land management, environmental analysis, and urban and transporation planning. The increasing use of computers for storing and analyzing earth science information has greatly expanded the demand for digital cartographic and geographic data. Digital cartography involves the collection, storage, processing, analysis, and display of map data with the aid of computers. The U.S. Geological Survey (USGS), the Nation's largest earth science research agency, through its National Mapping Program, has expanded digital cartography operations to include the collection of elevation, planimetric, land use and land cover, and geographic names information in digital form. This digital information is available on 9-track magnetic tapes and, in the case of 1:2,000,000-scale planimetric digital line graph data, in Compact Disc Read Only Memory (CD-ROM) format. Digital information can be used with all types of geographic and land information systems.

General Information Product↗

Water-Quality Data for Selected National Park Units within the Southern Colorado Plateau Network, Arizona, Utah, Colorado, and New Mexico, Water Years 2005 and 2006

The National Park Service initiated a Level 1 Water-Quality Inventory program to provide water-quality data to park managers so informed natural resource management decisions could be made. Level 1 water-quality data were collected by the U.S. Geological Survey Arizona Water Science Center at 57 sites in 13 National Park units located in the Southern Colorado Plateau Inventory and Monitoring network in water years 2005 and 2006. These data describe the current water-quality at selected sites within the park units and provide information for monitoring future trends. Water samples were collected three times at each type of site including wells, springs, seeps, tinajas, rivers, a lake, and an irrigation ditch. Field measurements were taken at each site and they included pH, specific conductance, temperature, barometric pressure, dissolved oxygen, alkalinity, turbidity, and discharge rates where applicable. Water samples collected were sent to the U.S. Geological Survey National Water Quality Laboratory and analyzed for major ions, trace elements, and nutrients. The National Water Quality Laboratory also analyzed selected samples for mercury and petroleum hydrocarbons. Additional samples at selected sites were collected and analyzed for cyanide, radiochemistry, and suspended sediment by U.S. Geological Survey contract labs. Fecal-indicator bacteria (Escherichia coli) were sampled for at selected sites as another indicator of water quality. Quality control for this study was achieved through proper training of field personnel, use of standard U.S. Geological Survey field and laboratory protocols, collection of sample blanks and replicates, and a thorough review of the water-quality analyses. Measured field pH ranged from 6.0 to 8.8, within normal range for springs and rivers, at most sites. Concentrations of dissolved solids ranged from 48 to 8,680 mg/L and the majority of samples had concentrations of dissolved solids below 900 mg/L. Trace-element concentrations at most sites were at or near the laboratory reporting levels. The highest overall trace-element concentrations were found at U.S. Highway 160 Spring near Park Entrance to Mesa Verde National Park. Concentrations of uranium in samples at all sites ranged from below the detection limit to 55.7 ?g/L. Water samples from selected sites were analyzed for total petroleum hydrocarbons and concentrations of total petroleum hydrocarbons were at or above the laboratory detection limit in samples at six National Park units. Ten sites were sampled for Escherichia coli and positive counts were found at 9 out of the ten sites, the highest colony counts were found at Chinle Creek at Chinle, AZ in Canyon de Chelly National Monument. Measured concentrations of dissolved ammonia, nitrite, and nitrate were at or near laboratory reporting levels at most sites; nitrate concentrations ranged from below the reporting limit (0.047 mg/L) to 9.77 mg/L. Samples that were analyzed for mercury had concentrations below or at the laboratory reporting level. Concentrations of cyanide were less than the laboratory reporting level for all samples except two, Spruce Tree House Spring in Mesa Verde National Park and Pine Tree Canyon Tinaja in Canyon de Chelly National Monument, which had average concentrations of .042 and .011 ?g/L respectively. Gross alpha/beta radioactivity counts were below the U.S. Environmental Protection Agency maximum contaminant level except for samples from Casa Chiquita Well  Middle at Chaco Culture National Historical Park which averaged 35 pCi/L. Suspended-sediment concentrations were variable and ranged from 10 to 150,000 mg/L.

Open-File Report↗

Importance of return flow as a component of water use

Understanding the relation between the hydrologjc cycle and water use is important for effective water-resources management. The hydrologic cycle is the natural pathway of water from evaporation to precipitation to infiltration or runoff and to storage from which evaporation can again occur. The science of water use is the study of human influences on the hydrologic cycle. Human activities affect the hydrologic cycle by changing the quantity, distribution, and quality of available water. Quantifying return flow is useful to water managers in evaluating such changes. Return flow is often thought of as what runs down the drain, or what is leftover after the water's purpose has been served. As innocuous as that may sound, return flow plays a significant part in the overall water-use picture.

Minnesota↗

Bibliography of geology and hydrology, eastern New Mexico

The High Plains of the eastern New Mexico region are recognized as an abundant and varied source of natural resources. The bibliography of over 1,900 references concerned with geology, hydrology, chemistry, and geography has been compiled to assist physical science researchers in their study of this region. (Kosco-USGS)

Water-Resources Investigations Report↗

Bibliography of geology and hydrology, southwestern New Mexico

The southwestern part of New Mexico is recognized as a source of abundant and varied natural resources. This bibliography of over 2,700 references concerned with geology, hydrology, chemistry, and geography has been compiled to assist physical science researchers in their study and development of this region.

New Mexico↗

Predictive mapping of seabirds, pinnipeds and cetaceans off the Pacific Coast of Washington

About this report This report supports Washington-led marine spatial planning and responsible stewardship of natural and cultural resources by the Olympic Coast National Marine Sanctuary. Washington state agencies and the sanctuary continually seek the best available science to improve management of marine uses and stewardship of resources (Etheridge et al., 2010; Washington Department of Fish and Wildlife, 2015a). This report and associated data provide new, state- and sanctuary-requested information on seabird, pinniped, and cetacean distributions. Through spatial planning, information on species distributions can help to identify high-value conservation areas, minimize adverse effects of ocean uses and mitigate impacts of coastal hazards. Correspondingly, the Washington Department of Fish and Wildlife has already begun to use the maps of predicted relative density presented in this report to identify ecologically important areas off the Pacific Coast of Washington and apply this information to plan for offshore renewable energy development. This is the culmination of three years of work to compile information on seabirds, pinnipeds, and cetaceans, and advance a modeling framework that can integrate data sets and develop accurate predictions of relative density for important species off the Pacific Coast of Washington. Previous reports, which evaluated existing datasets of at-sea observations (Menza et al., 2014; Kracker and Menza, 2015) and presented superseded versions of seabird models (Menza et al., 2015), provided base information for this report. In addition to the maps in this published report, all new seabird, pinniped and cetacean predictions will be made publicly available as digital geospatial data through the National Centers for Environmental Information. This research supports the National Oceanic and Atmospheric Administration (NOAA) Coastal Zone Management Program, a voluntary partnership between the federal government and U.S. coastal and Great Lakes states and territories authorized by the Coastal Zone Management Act (CZMA) of 1972 to address national coastal issues. The act provides the basis for protecting, restoring, and responsibly developing our nation&rsquo;s diverse coastal communities and resources. To meet the goals of the CZMA, the national program takes a comprehensive approach to coastal resource management &ndash; balancing the often competing and occasionally conflicting demands of coastal resource use, economic development, and conservation. A wide range of issues are addressed through the program, including coastal development, water quality, public access, habitat protection, energy facility siting, ocean governance and planning, coastal hazards, and climate change. Accurate maps of seabird and marine mammal distributions are an important tool for making informed management decisions that affect all of these issues.

Washington↗

Extreme coastal water level in Washington state: Guidance to support sea level rise planning

This document provides guidelines for assessing exposure to future coastal flooding during extreme coastal water level events – whether these are due to tides, surge, wave run-up, or, more likely, a combination of the three. These guidelines provide information about the current and future magnitude of extreme coastal water levels across Washington State and the underlying processes that influence them. This information is intended to be combined with sea level projections to assess future exposure to coastal flooding along Washington’s coastline. Although the results of our analyses can be combined with any available sea level projections, this report is intended as a companion to the localized sea level rise projections (Miller et al., 2018) developed as part of the Washington Coastal Resilience Project. The Washington Coastal Resilience Project was a three-year effort to rapidly increase the state’s capacity to prepare for sea level rise. The project aimed to improve risk projections, provide better guidelines for land use planners and strengthen capital investment programs for coastal restoration and infrastructure. Partners in the Washington Coastal Resilience Project included Washington Sea Grant, Washington Department of Ecology, Island County, King County, NOAA Office for Coastal Management, Pacific Northwest National Laboratory, Padilla Bay National Estuary Research Reserve, The City of Tacoma, The Nature Conservancy, U.S. Geological Survey, University of Oregon, University of Washington Climate Impacts Group, University of Washington Department of Earth and Space Sciences, Washington Department of Fish and Wildlife and Western Washington University. The 2018 sea level projections are described in an accompanying technical report, along with a review of the science related to sea level rise (Miller et al., 2018). The report and all associated supporting information are available on the Washington Coastal Hazards Resilience Network website (http://www.wacoastalnetwork.com/).

Washington↗

Science, Society, Solutions: An Introduction to the USGS

The USGS serves the Nation by providing relevant, impartial scientific information to * Describe and understand the Earth; * Minimize loss of life and property from natural disasters; * Manage water, biological, energy, and mineral resources; and * Enhance and protect our quality of life.

Fact Sheet↗

Gulf of Mexico integrated science - Tampa Bay study, the impact of groundwater and contaminants on Tampa Bay

Despite the recreational and economic value of coastal bays and estuaries, these ecosystems are often among our most 'troubled' natural environments. Urbanization, agriculture, mining, and shipping are just a few activities that can have a profound and lasting impact on the coastal zone. In order to maintain a healthy coastal ecosystem, it is crucial to develop reasonable management practices around expert scientific information. We still have much to learn about the quantity and quality of groundwater being discharged into Tampa Bay, Florida. We also need to improve our knowledge of a wide range of contaminants entering the bay and must be able to determine where they accumulate in seafloor sediments. Such buried contaminants can potentially be harmful to biota if they are released to the water column. U.S. Geological Survey (USGS) scientists and research partners from the University of South Florida (USF), the University of Florida (UF), and the Florida Marine Research Institute (FMRI) are mapping sources of groundwater, measuring groundwater flow into Tampa Bay, and assessing the impact of contaminants and sediments on bay water quality and ecosystem health.

Open-File Report↗

Joint analysis of geodetic and earthquake fault-plane solution data to constrain magmatic sources: A case study from Kīlauea Volcano

A joint analysis of geodetic and seismic datasets from Kīlauea Volcano during a period of magmatic unrest in 2006 demonstrates the effectiveness of this combination for testing and constraining models of magma dynamics for a complex, multi-source system. At the end of 2003, Kīlauea's summit began a four-year-long period of inflation due to a surge in magma supply to the volcano. In 2006, for the first time since 1982, Kīlauea's Southwest Rift Zone (SWRZ) also experienced inflation. To investigate the characteristics of active magma sources and the nature of their interactions with faults in the SWRZ during 2006, we integrate, through Coulomb stress modeling, contemporary geodetic data from InSAR and GPS with a new catalogue of double-couple fault-plane solutions for volcano-tectonic earthquakes. We define two periods of inflation during 2006 based on the rate of deformation measured in daily GPS data, spanning February to 15 March 2006 (Period 1) and 16 March to 30 September 2006 (Period 2). InSAR data for these two periods are inverted to determine the position, change in size, and shape of inflation sources in each period. Our new models are consistent with microseismic activity from each period. They suggest that, during Period 1, deformation in the SWRZ can be explained by pressurization of magma in a spherical reservoir beneath the south caldera, and that, during Period 2, magma was also aseismically intruded farther to the southwest into the SWRZ along a sub-horizontal plane. Our Coulomb stress analysis shows that the microseismicity recorded in the SWRZ is induced by overpressurization of the south caldera reservoir, and not by magma intrusion into the SWRZ. This study highlights the importance of a joint analysis of independent geophysical datasets to fully constrain the nature of magma accumulation.

Hawaii↗

Evaluating the impact of irrigation on surface water – groundwater interaction and stream temperature in an agricultural watershed

Changes in groundwater discharge to streams caused by irrigation practices can influence stream temperature. Observations along two currently flood-irrigated reaches in the 640-square-kilometer upper Smith River watershed, an important agricultural and recreational fishing area in west-central Montana, showed a downstream temperature decrease resulting from groundwater discharge to the stream. A watershed-scale coupled surface water and groundwater flow model was used to examine changes in streamflow, groundwater discharge to the stream and stream temperature resulting from irrigation practices. The upper Smith River watershed was used to develop the model framework including watershed climate, topography, hydrography, vegetation, soil properties and current irrigation practices. Model results were used to compare watershed streamflow, groundwater recharge, and groundwater discharge to the stream for three scenarios: natural, pre-irrigation conditions (PreIrr); current irrigation practices involving mainly stream diversion for flood and sprinkler irrigation (IrrCurrent); and a hypothetical scenario with only groundwater supplying sprinkler irrigation (IrrGW). Irrigation increased groundwater recharge relative to natural PreIrr conditions because not all applied water was removed by crop evapotranspiration. Groundwater storage and groundwater discharge to the stream increased relative to natural PreIrr conditions when the source of irrigation water was mainly stream diversion as in the IrrCurrent scenario. The hypothetical IrrGW scenario, in which groundwater withdrawals were the sole source of irrigation water, resulted in widespread lowering of the water table and associated decreases in groundwater storage and groundwater discharge to the stream. A mixing analysis using model predicted groundwater discharge along the reaches suggests that stream diversion and flood irrigation, represented in the IrrCurrent scenario, has led to cooling of stream temperatures relative to natural PreIrr conditions improving fish thermal habitat. However, the decrease in groundwater discharge in the IrrGW scenario resulting from large-scale groundwater withdrawal for irrigation led to warmer than natural stream temperatures and possible degradation of fish habitat.

Montana↗

Rates of As and trace-element mobilization caused by Fe reduction in mixed BTEX–ethanol experimental plumes

Biodegradation of organic matter, including petroleum-based fuels and biofuels, can create undesired secondary water-quality effects. Trace elements, especially arsenic (As), have strong adsorption affinities for Fe(III) (oxyhydr)-oxides and can be released to groundwater during Fe-reducing biodegradation. We investigated the mobilization of naturally occurring As, cobalt (Co), chromium (Cr), and nickel (Ni) from wetland sediments caused by the introduction of benzene, toluene, ethylbenzene, and xylenes (BTEX) and ethanol mixtures under iron- and nitrate-reducing conditions, using in situ push–pull tests. When BTEX alone was added, results showed simultaneous onset and similar rates of Fe reduction and As mobilization. In the presence of ethanol, the maximum rates of As release and Fe reduction were higher, the time to onset of reaction was decreased, and the rates occurred in multiple stages that reflected additional processes. The concentration of As increased from <1 μg/L to a maximum of 99 μg/L, exceeding the 10 μg/L limit for drinking water. Mobilization of Co, Cr, and Ni was observed in association with ethanol biodegradation but not with BTEX. These results demonstrate the potential for trace-element contamination of drinking water during biodegradation and highlight the importance of monitoring trace elements at natural and enhanced attenuation sites.

Environmental Science & Technology↗

Novel and non-traditional use of stable isotope tracers to study metal bioavailability from natural particles

We devised a novel tracing approach that involves enriching test organisms with a stable metal isotope of low natural abundance prior to characterizing metal bioavailability from natural inorganic particles. In addition to circumventing uncertainties associated with labeling natural particles and distinguishing background metals, the proposed "reverse labeling" technique overcomes many drawbacks inherent to using radioisotope tracers. Specifically, we chronically exposed freshwater snails (Lymnaea stagnalis) to synthetic water spiked with Cu that was 99.4% 65 Cu to increase the relative abundance of 65 Cu in the snail’s tissues from 32% to >80%. The isotopically enriched snails were then exposed to benthic algae mixed with Cu-bearing Fe–Al particles collected from the Animas River (Colorado), an acid mine drainage impacted river. We used 63 Cu to trace Cu uptake from the natural particles and inferred their bioavailability from calculation of Cu assimilation into tissues. Cu assimilation from these particles was 44%, indicating that 44% of the particulate Cu was absorbed by the invertebrate. This demonstrates that inorganic particulate Cu can be bioavailable. The reverse labeling approach shows great potential in various scientific areas such as environmental contamination and nutrition for addressing questions involving uptake of an element that naturally has multiple isotopes.

Environmental Science & Technology↗

Size-dependent reactivity of magnetite nanoparticles: a field-laboratory comparison

Logistic challenges make direct comparisons between laboratory- and field-based investigations into the size-dependent reactivity of nanomaterials difficult. This investigation sought to compare the size-dependent reactivity of nanoparticles in a field setting to a laboratory analog using the specific example of magnetite dissolution. Synthetic magnetite nanoparticles of three size intervals, ∼6 nm, ∼44 nm, and ∼90 nm were emplaced in the subsurface of the USGS research site at the Norman Landfill for up to 30 days using custom-made subsurface nanoparticle holders. Laboratory analog dissolution experiments were conducted using synthetic groundwater. Reaction products were analyzed via TEM and SEM and compared to initial particle characterizations. Field results indicated that an organic coating developed on the particle surfaces largely inhibiting reactivity. Limited dissolution occurred, with the amount of dissolution decreasing as particle size decreased. Conversely, the laboratory analogs without organics revealed greater dissolution of the smaller particles. These results showed that the presence of dissolved organics led to a nearly complete reversal in the size-dependent reactivity trends displayed between the field and laboratory experiments indicating that size-dependent trends observed in laboratory investigations may not be relevant in organic-rich natural systems.

Environmental Science & Technology↗

Recruitment phenology and pelagic larval duration in Caribbean amphidromous fishes

Amphidromous fishes are major components of oceanic tropical island stream ecosystems, such as those of the Caribbean island, Puerto Rico. Fishes with this life history face threats related to the requirement for connectivity between freshwater and marine environments during early life stages. Pelagic larval duration and recruitment phenology are 2 early life-history processes that are crucial for the biology, ecology, conservation, and management of amphidromous fishes. However, these processes are understudied in the Caribbean in general and have never been quantified in Puerto Rico. We quantified recruit abundance, recruitment phenology, and pelagic larval duration of several Caribbean amphidromous fish species in multiple rivers in Puerto Rico and explored the effects of environmental variables on recruit abundances. Two fish taxa—sirajo goby ( Sicydium spp.) and River Goby ( Awaous banana )—were exceptionally abundant as postlarvae and recruited to Caribbean rivers in pulsed migration episodes that were periodic at annual and lunar scales. Sirajo goby and River Goby recruit abundances varied among rivers, were greater at sunrise than at sunset, and were positively related to river discharge. The pelagic larval duration of 4 fish taxa ranged from a minimum of 28 d to a maximum of 103 d with means between 43 ± 7 d (SD) and 65 ± 11 d. We identified the last-quarter moon phase during the months of June through January as periods of maximum amphidromous fish recruitment to freshwater streams. The results and conclusions of our study can be applied to identify critical times to maintain river–ocean connectivity and stream flow for the benefit of the amphidromous fish population dynamics, stream ecology, and natural resources of the Caribbean.

Puerto Rico↗