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At least 667 records · Page 37Linked to original sources
USGS1967

Water Resources Data for California, 1966; Part 2: Water Quality Records

Water-resources investigations of the U.S. Geological Survey include the collection of water-quality data on the chemical and physical characteristics of surface- and ground-water supplies of the Nation. These data for the 1966 water year for the quality of surface waters in California are presented in this report. Data for a few water-quality stations in bordering States are also included. The data were collected by the Water Resources Division of the U.S. Geological Survey under the direction of Walter Hofmann and R. Stanley Lord, successive district chiefs, Menlo Park, Calif. Water-quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics such as hardness, sodium-adsorption ratio, specific conductance, and pH. Fluvial-sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water-temperature data represent once-daily observations except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained.

California↗
USGS1973

Water resources data for West Virginia, water year 1972

Water resources data for the 1972 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water, are given in this report. In Part 1, records are included for 126 gaging stations of which 119 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 7 low-flow partial record stations, 42 crest-stage partial-record stations, and 12 miscellaneous sites. Locations of gaging stations are shown in Figure 1. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 30 sampling stations of which 18 are continuous record stations, and 12 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water. Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on pages 15 and 20.

West Virginia↗
USGS2005

Use of dissolved and vapor‐phase gases to investigate methanogenic degradation of petroleum hydrocarbon contamination in the subsurface

At many sites contaminated with petroleum hydrocarbons, methanogenesis is a significant degradation pathway. Techniques to estimate CH 4 production, consumption, and transport processes are needed to understand the geochemical system, provide a complete carbon mass balance, and quantify the hydrocarbon degradation rate. Dissolved and vapor‐phase gas data collected at a petroleum hydrocarbon contaminated site near Bemidji, Minnesota, demonstrate that naturally occurring nonreactive or relatively inert gases such as Ar and N 2 can be effectively used to better understand and quantify physical and chemical processes related to methanogenic activity in the subsurface. In the vadose zone, regions of Ar and N 2 depletion and enrichment are indicative of methanogenic and methanotrophic zones, and concentration gradients between the regions suggest that reaction‐induced advection can be an important gas transport process. In the saturated zone, dissolved Ar and N 2 concentrations are used to quantify degassing driven by methanogenesis and also suggest that attenuation of methane along the flow path, into the downgradient aquifer, is largely controlled by physical processes. Slight but discernable preferential depletion of N 2 over Ar, in both the saturated and unsaturated zones near the free‐phase oil, suggests reactivity of N 2 and is consistent with other evidence indicating that nitrogen fixation by microbial activity is taking place at this site.

Water Resources Research↗
USGS1972

Water resources data for West Virginia, water year 1971; Part 1. Surface water records; Part 2. Water quality records

Water resources data for the 1971 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water, are given in this report. In Part 1, records are included for 111 gaging stations of which 105 are streamflow discharge stations, 1 is stage only streamflow station, and 5 are reservoir or lake stations; also included are records for 5 low-flow partial-record stations, 44 crest-stage partial-record stations, and 6 miscellaneous sites. Locations of gaging stations are shown in Figure 1. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals such as once daily, weekly, monthly, or less frequently, and at some sites data were recorder on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 23 sampling stations of which 10 are continuous record stations, 11 are partial-record stations, and 2 are miscellaneous sites. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia.

West Virginia↗
USGS2010

Groundwater quality of the Gulf Coast aquifer system, Houston, Texas, 2007-08

In the summers of 2007 and 2008, the U.S. Geological Survey (USGS), in cooperation with the City of Houston, Texas, completed an initial reconnaissance-level survey of naturally occurring contaminants (arsenic, other selected trace elements, and radionuclides) in water from municipal supply wells in the Houston area. The purpose of this reconnaissance-level survey was to characterize source-water quality prior to drinking water treatment. Water-quality samples were collected from 28 municipal supply wells in the Houston area completed in the Evangeline aquifer, Chicot aquifer, or both. This initial survey is part of ongoing research to determine concentrations, spatial extent, and associated geochemical conditions that might be conducive for mobility and transport of these constituents in the Gulf Coast aquifer system in the Houston area. Samples were analyzed for major ions (calcium, magnesium, potassium, sodium, bromide, chloride, fluoride, silica, and sulfate), selected chemically related properties (residue on evaporation [dissolved solids] and chemical oxygen demand), dissolved organic carbon, arsenic species (arsenate [As(V)], arsenite [As(III)], dimethylarsinate [DMA], and monomethylarsonate [MMA]), other trace elements (aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, chromium, cobalt, copper, iron, lead, lithium, manganese, molybdenum, nickel, selenium, silver, strontium, thallium, vanadium, and zinc), and selected radionuclides (gross alpha- and beta-particle activity [at 72 hours and 30 days], carbon-14, radium isotopes [radium-226 and radium-228], radon-222, tritium, and uranium). Field measurements were made of selected physicochemical (relating to both physical and chemical) properties (oxidation-reduction potential, turbidity, dissolved oxygen concentration, pH, specific conductance, water temperature, and alkalinity) and unfiltered sulfides. Dissolved organic carbon and chemical oxygen demand are presented but not discussed in the report. Physicochemical properties, major ions, and trace elements varied considerably. The pH ranged from 7.2 to 8.1 (median 7.6); specific conductance ranged from 314 to 856 microsiemens per centimeter at 25 degrees Celsius, with a median of 517 microsiemens per centimeter; and alkalinity ranged from 126 to 324 milligrams per liter as calcium carbonate (median 167 milligrams per liter). The range in oxidation-reduction potential was large, from -212 to 244 millivolts, with a median of -84.6 millivolts. The largest ranges in concentration for filtered major ion constituents were obtained for cations sodium and calcium and for anions chloride and bicarbonate (bicarbonate was calculated from the measured alkalinity). Filtered arsenic was detected in all 28 samples, ranging from 0.58 to 15.3 micrograms per liter (median 2.5 micrograms per liter), and exceeded the maximum contaminant level established by the U.S. Environmental Protection Agency of 10 micrograms per liter in 2 of the 28 samples. As(III) was the most frequently detected arsenic specie. As(III) concentrations ranged from less than 0.6 to 14.9 micrograms arsenic per liter. The range in concentrations for the arsenic species As(V) was from less than 0.8 to 3.3 micrograms arsenic per liter. Barium, boron, lithium, and strontium were detected in quantifiable (equal to or greater than the laboratory reporting level) concentrations in all samples and molybdenum in all but one sample. Filtered iron, manganese, nickel, and vanadium were each detected in at least 18 of the 28 samples. All other selected trace elements were each detected in 16 or fewer samples. Radionuclides were detected in most samples. The gross alpha-particle activities at 30 days and 72 hours ranged from R-0.94 to 15.5 and R-1.1 to 17.2 picocuries per liter, respectively ('R' indicates nondetected result less than the sample-specific critical level). The combined radium (radium-226 plus radium-228) concentrations ranged from an estimat

Texas↗
USGS1996

Evaluation of selected information on splitting devices for water samples

Four devices for splitting water samples into representative aliquots are used by the U.S. Geological Survey's Water Resources Division. A thorough evaluation of these devices (14-liter churn, 8-liter churn, plastic cone, and Teflon cone) encompasses a wide variety of concerns, based on both chemical and physical considerations. This report surveys the existing data (as of April 1994) on cleaning efficiency and splitting capability of these devices and presents the data in a systematic framework for evaluation. From the existing data, some of these concerns are adequately or partially addressed, but the majority of concerns could not be addressed because of the lack of data. In general, the existing cleaning and transport protocols are adequate at the milligram per liter level, but the adequacy is largely unknown for trace elements and organic chemicals at lower concen- trations. The existing data indicate that better results are obtained when the splitters are cleaned in the laboratory rather than in the field. Two conclusions that can be reached on the splitting capability of solids are that more work must be done with all four devices to characterize and quantify their limitations and range of usefulness, and that the 14-liter churn (and by association, the 8-liter churn) is not useful in obtaining representative splits of sand-sized particles.

Water-Resources Investigations Report↗
USGS1994

Remote sensing and airborne geophysics in the assessment of natural aggregate resources

Natural aggregate made from crushed stone and deposits of sand and gravel is a vital element of the construction industry in the United States. Although natural aggregate is a high volume/low value commodity that is relatively abundant, new sources of aggregate are becoming increasingly difficult to find and develop because of rigid industry specifications, political considerations, development and transporation costs, and environmental concerns, especially in urban growth centers where much of the aggregate is used. As the demand for natural aggregate increases in response to urban growth and the repair and expansion of the national infrastructure, new sources of natural aggregate will be required. The USGS has recognized the necessity of developing the capability to assess the potential for natural aggregate sources on Federal lands; at present, no methodology exists for systematically describing and evaluating potential sources of natural aggregate. Because remote sensing and airborne geophysics can detect surface and nearsurface phenomena, these tools may useful for detecting and mapping potential sources of natural aggregate; however, before a methodology for applying these tools can be developed, it is necessary to understand the type, distribution, physical properties, and characteristics of natural aggregate deposits, as well as the problems that will be encountered in assessing their potential value. There are two primary sources of natural aggregate: (1) exposed or near-surface igneous, metamorphic, and sedimentary bedrock that can be crushed, and (2) deposits of sand and gravel that may be used directly or crushed and sized to meet specifications. In any particular area, the availability of bedrock suitable for crushing is a function of the geologic history of the area - the processes that formed, deformed, eroded and exposed the bedrock. Deposits of sand and gravel are primarily surficial deposits formed by the erosion, transportation by water and ice, and deposition of bedrock fragments. Consequently, most sand and gravel deposits are Tertiary or Quaternary in age and are most common in glaciated areas, alluvial basins, and along rivers and streams. The distribution of potential sources of natural aggregate in the United States is closely tied to physiography and the type of bedrock that occurs in an area. Using these criteria, the United States can be divided into 12 regions: western mountain ranges, alluvial basins, Columbia Plateau, Colorado Plateau and Wyoming basin, High Plains, nonglaciated central region, glaciated central region, Piedmont Blue Ridge region, glaciated northeastern and Superior uplands, Atlantic and Gulf coastal plain, Hawaiian Islands, and Alaska. Each region has similar types of natural aggregate sources within its boundary, although there may be wide variations in specific physical and chemical characteristics of the aggregates within a region. Conventional exploration for natural aggregate deposits has been largely a ground-based operation (field mapping, sampling, trenching and augering, resistivity), although aerial photos and topographic maps have been extensively used to target possible deposits for sampling and testing. Today, the exploration process also considers other factors such as the availability of the land, space and water supply for processing purposes, political and environmental factors, and distance from the market; exploration and planning cannot be separated. There are many physical properties and characteristics by which aggregate material is judged to be acceptable or unacceptable for specific applications; most of these properties and characteristics pertain only to individual aggregate particles and not to the bulk deposit. For example, properties of crushed stone aggregate particles such as thermal volume change, solubility, oxidation and hydration reactivity, and particle strength, among many others, are important consi

Open-File Report↗
USGS1985

Water quality and chemical evolution of ground water within the north coast limestone aquifers of Puerto Rico

Waters within the north coastal limestone aquifers are suitable for public supply, industrial and agricultural uses. For the artesian aquifer and the updip parts of the water table aquifer, calcium and bicarbonate are the dominant ionic species with total dissolved solids and chloride concentrations below 500 and 250 mg/L, respectively. In coastal areas of the water table aquifer, where a freshwater-saltwater mixing zone occurs, the calcium bicarbonate facie grade to a sodium-chloride facie. Within this zone, concentrations of total dissolved solids and chloride are greater than 250 and 500 mg/L respectively, affecting the suitability of the water for some uses. Geochemical models were constructed to determine the physical and chemical reasons for the prevailing water quality patterns of the north coast limestone aquifers . Models indicate that calcite and carbon dioxide dissolution, precipitation or degassing are the primary processes. The mixing of recharge water or saltwater with aquifer waters is an important feature within the water table aquifer. The models provide further evidence that support the circulation of groundwater within the north coast limestone.

Conference Paper↗
USGS2017

Ice duration drives winter nitrate accumulation in north temperate lakes

The duration of winter ice cover on lakes varies substantially with climate variability, and has decreased over the last several decades in many temperate lakes. However, little is known of how changes in seasonal ice cover may affect biogeochemical processes under ice. We examined winter nitrogen (N) dynamics under ice using a 30+ yr dataset from five oligotrophic/mesotrophic north temperate lakes to determine how changes in inorganic N species varied with ice duration. Nitrate accumulated during winter and was strongly related to the number of days since ice-on. Exogenous inputs accounted for less than 3% of nitrate accumulation in four of the five lakes, suggesting a paramount role of nitrification in regulating N transformation and the timing of chemical conditions under ice. Winter nitrate accumulation rates ranged from 0.15 μ g N L −1 d −1 to 2.7 μ g N L −1 d −1 (0.011–0.19 μ M d −1 ), and the mean for intermediate depths was 0.94 μ g N L −1 d −1 (0.067 μ M d −1 ). Given that winters with shorter ice duration (< 120 d) have become more frequent in these lakes since the late 1990s, peak winter nitrate concentrations and cumulative nitrate production under ice may be declining. As ice extent and duration change, the physical and chemical conditions supporting life will shift. This research suggests we may expect changes in the form and amount of inorganic N, and altered dissolved nitrogen : phosphorus ratios, in lakes during winters with shorter ice duration.

Limnology and Oceanography Letters↗
USGS1998

Natural attenuation of chlorinated-hydrocarbon contamination at Fort Wainwright, Alaska: A hydrogeochemical and microbiological investigation workplan

Natural attenuation processes include biological degradation, by which microorganisms break down contaminants into simpler product compounds; adsorption of contaminants to soil particles, which decreases the mass of contaminants dissolved in ground water; and dispersion, which decreases dissolved contaminant concentrations through dilution. The primary objectives of this study are to (1) assess the degree to which such natural processes are attenuating chlorinated-hydrocarbon contamination in ground water, and (2) evaluate the effects of ground-water/surface-water interactions on natural-attenuation processes in the area of the former East and West Quartermasters Fueling Systems for Fort Wainwright, Alaska. The study will include investigations of the hydrologic, geochemical, and microbiological processes occurring at this site that influence the transport and fate of chlorinated hydrocarbons in ground water. To accomplish these objectives, a data-collection program has been initiated that includes measurements of water-table elevations and the stage of the Chena River; measurements of vertical temperature profiles within the subsurface; characterization of moisture distribution and movement in the unsaturated zone; collection of ground-water samples for determination of both organic and inorganic chemical constituents; and collection of ground-water samples for enumeration of microorganisms and determination of their potential to mineralize contaminants. We will use results from the data-collection program described above to refine our conceptual model of hydrology and contaminant attenuation at this site. Measurements of water-table elevations and river stage will help us to understand the magnitude and direction of ground-water flow and how changes in the stage of the Chena River affect ground-water flow. Because ambient ground water and surface water typically have different temperature characteristics, temperature monitoring will likely provide further insight into ground-water/surface-water interactions in the subsurface. Characterization of the unsaturated zone will improve our understanding of interactions among ground water, the unsaturated zone, and the atmosphere. The interactions likely of importance to this study include the migration of water, dissolved contaminants, nutrients, and gases (oxygen, carbon dioxide, and methane) between the saturated and unsaturated zones. We will use the results of ground-water chemical analyses to determine the spatial and temporal distribution of (1) chlorinated-hydrocarbon contaminants and their degradation products, (2) oxidation-reduction indicators, (3) nutrients, and (4) major ground-water ions. These water-quality data will provide insight into ground-water flow directions, interactions between ground water and surface water, attenuation of contaminant concentrations caused by dispersion, and intrinsic microbiological processes. Microbiological analyses will indicate whether microorganisms at the site are capable of degrading the contaminants of interest, and will allow us to estimate their potential to attenuate existing contamination. Physical and chemical data interpreted as part of the analysis of ground water and surface water mixing will improve our understanding of the relationship between water quality and contaminant source mixing.

Alaska↗
USGS2010

Water quality.

Significant contributions in the broad area of water quality over the quadrennium 1975-78 are highlighted. This summare is concerned primarily with physical and chemical aspects of water quality. The diversity of subject areas within the topic heading and the large volume of published research results necessitated the selection of representative contributions. Over 400 references are cited which are believed to be indicative of general trends in research and of the more important developments during this period.- from Authors

Reviews of Geophysics and Space Physics↗
USGS2025

Science needs for determining the effects of climate change on harmful algal blooms in the southeastern United States

The Southeastern United States has many lakes, streams, and reservoirs that serve as important drinking water sources with recreational, agricultural, and ecological uses. However, harmful algal blooms (HABs) are becoming more common in these waters, causing health issues for humans and animals. HABs have been listed as a contaminant of emerging concern, and the magnitude, frequency, and duration of HABs appear to be increasing at the global scale. While it is well known that nutrients stimulate algae growth, it is not clear how climate change and other parameters stimulate the development of toxin production by HABs. The scientific literature describes parameters, such as storm occurrence, temperature, dissolved metals, erosion of soils, increasing length of growing season, discharge, and hydroperiod, that may affect algae growth and toxin production. Climate and hydrologic models address many of the physical and environmental parameters that influence HABs, but no climate models directly address HABs. This report compiles information from the existing literature pertaining to HABs and the modeling and forecasting of HABS. This compilation is done through the incorporation of climate change models. HAB research that involves climate change will require multiple disciplines that bring together ecologists, hydrologists, climatologists, engineers, economists, and new technology. Resource managers could use geographic data about the occurrence and distribution of HABs to develop models that identify waterbodies more vulnerable to HAB events. Development of such models will require teams capable of integrating biological, chemical, and physical factors. Model development will require additional research that can resolve anthropogenic and climate-related environmental factors to identify trends in freshwater HABs. The complexity and interconnectedness of the parameters that influence HAB occurrences will make model development challenging and require rigorous regional calibration.

Open-File Report↗
USGS1989

Natural ground-water quality in Michigan, 1974-87

Wide variations occur in the chemical and physical characteristics of natural groundwaters in Michigan. Dissolved-solids concentrations range from 20 to 76,000 mg/L. Waters having low dissolved-solids concentrations are calcium bicarbonate-type waters. Sodium, sulfate, and chloride increase as mineralization increases. Iron, aluminum, and titanium concentrations are higher at some locations than is common in most natural waters. Lead concentrations exceed U.S. Environmental Protection Agency 's primary drinking-water regulations at some locations in the northern part of the lower Peninsula. Generalized areal patterns of water-quality variability indicate that geology is a primary cause of differences across the State. Examples of chemical associations in water indicate that chemical analyses may be valuable in tracing and identifying mineral deposits.

Michigan↗
USGS2007

The role of fault zone drilling

The objective of fault-zone drilling projects is to directly study the physical and chemical processes that control deformation and earthquake generation within active fault zones. An enormous amount of field, laboratory, and theoretical work has been directed toward the mechanical and hydrological behavior of faults over the past several decades. Nonetheless, it is currently impossible to differentiate between – or even adequately constrain – the numerous conceptual models of active faults proposed over the years. For this reason, the Earth science community is left in the untenable position of having no generally accepted paradigm for the mechanical behavior of faults at depth. One of the primary causes for this dilemma is the difficulty of either directly observing or inferring physical properties and deformation mechanisms along faults at depth, as well as the need to observe directly key parameters such as the state of stress acting on faults at depth, pore fluid pressure (and its possible variation in space and time), and processes associated with earthquake nucleation and rupture. Today, we know very little about the composition of active faults at depth, their constitutive properties, the state of in situ stress or pore pressure within fault zones, the origin of fault-zone pore fluids, or the nature and significance of time-dependent fault-zone processes.

Book chapter↗
USGS1975

Water resources data for West Virginia, water year 1974

Water resources data for the 1974 water year for West Virginia including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, records of water-quality data on the chemical and physical characteristics of surface water, and records of ground-water levels at index wells are given in this report. In Part 1, records are included for 131 gaging stations of which 124 are streamflow discharge stations, 1 is stage only streamflow station, and 6 are reservoir or lake stations; also included are records for 12 low-flow partial-record stations, 38 crest-stage partial-record stations and 13 miscellaneous sites. Locations of gaging stations are shown in Figure 1, and location of partial-record stations are shown in Figure 2. In Part 2, data on the quality of surface water (chemical, temperature, and sediment) were collected from designated sampling sites at predetermined intervals, such as once daily, weekly, monthly, or less frequently, and at some sites data were recorded on punched paper tape at 15-, 30-, or 60-minute intervals. Records are given for 42 sampling stations of which 30 are continuous record stations, and 12 are partial-record stations. Locations of water-quality stations are shown in Figure 1. A few pertinent stations (not included above) in bordering States are also included in this report. In Part 3, records are included for 37 observation wells of which 8 are equipped with water-level recorders that give a continuous graph of the fluctuations, 3 are equipped with digital recorders that punch the water level on a tape at hourly intervals, at 26 manual reading are made with a steel tape by observers on the days indicated. Locations of index wells are shown in Figure 2. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Edwin E. Harris, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in West Virginia. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Water-quality records beginning with the 1964 water year have been similarly released either in separate reports or in conjunction with streamflow records. These reports are for limited distribution and are designed primarily for rapid release of data shortly after the end of the water year. Records of discharge and stage of streams, and contents and stage of lakes and reservoirs are published in a series of U.S. Geological Survey water-supply papers entitled, "Surface Water Supply of the United States." Through September 30, 1960, these water-supply papers were in an annual series and since then are in a 5-year series. Records of chemical quality, water temperatures, and suspended sediment have been published since 1941 in an annual series of water-supply papers entitled, "Quality of Surface Waters of the United States." More information is given under the headings "Publications" on page 24. Records of ground water levels are published in a series of water supply papers entitled, "Ground-water Levels in the United States". Through 1955 these were in an annual series but are now in a 5-year series. More information is given under the heading "Publications" on page 25.

West Virginia↗
USGS2003

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗
USGS1977

Late diagenetic indicators of buried oil and gas

At least three hydrocarbon seepage mechanisms are interpreted to operate over oil and gas fields. These are: (1) effusion ofh ydrocarbons through inadequate caprocks and along faults and fractures, (2) low-molecular-weight hydrocarbons dissolved in water moving vertically through capping shales as a result of a hydrodynamic or chemical potential drive, and (3) diffusion of gases dissolved in water. Combinations of these mechanisms may also occur. Seeping hydrocarbons are oxidized near the earth's surface, and the resulting carbon dioxide reacts with water producing bicarbonate ions, which combine with calcium and magnesium dissolved in ground waters to yield isotopically distinctive pore-filling carbonate cements and surface rocks. The passage of hydrocarbons and associated compounds such as hydrogen sulfide through surface rocks causes a reducing environment and consequent reduction, mobilization, and loss of iron from iron-bearing minerals commonly resulting in a discoloration. Other metals such as manganese are also mobilized and redistributed. These changes in the physical and chemical properties of surface rocks correlate with the subsurface distribution of petroleum, and potentially can be detected from both airborne and spaceborne platforms.

Open-File Report↗
USGS1991

A comparison of Sr-Nd-Pb isotopes in young and old continental lithospheric mantle: Patagonia and eastern China

It is commonly accepted that beneath the continental crust lies a keel of lithospheric mantle, which extends 50–200 kilometres downward to a transition zone into the asthenosphere. The chemical and physical properties of this reservoir are best known through studies of the basalts and xenoliths that provide samples of the subcrustal mantle. Although sharing many characteristics with oceanic island basalts, some continental basalts become increasingly distinct isotopically as crustal age increases, strongly supporting a permanent association between crust and mantle. Consequently, the distinctive trace element and isotope composition of the lithospheric mantle is able to give important clues to its origin and evolution. The mantle under newly‐created crust is typified by a radiogenic isotope variability that emphasizes the materials from which the continental lithosphere is assembled. Old lithospheric mantle, on the other hand, exhibits more evolved isotopic patterns that attest to the existence of long‐lived, chemically complex systems. A comparison of the Pb, Sr and Nd isotopes in alkalic to sub‐alkalic basalt derived from Phanerozoic (Patagonia) and Middle Archaean to Early Proterozoic (eastern China) subcrustal mantle is useful for identifying ‘end‐member’ components of the lithosphere. One component, having an isotopic composition close to PREMA, either continues to evolve virtually unchanged after incorporation into the lithosphere or is, itself, a relatively new addition even to old lithosphere. Another component, beginning with the isotopic composition of BSE, undergoes significant reduction in U/Pb and Sm/Nd (but not Rb/Sr) upon incorporation into the lithosphere and, with time, shows an increasingly retarded evolution of 206 Pb/ 204 Pb and negative ε Nd‐values approaching the isotopic composition of EMI. Five models are discussed that relate the isotopic composition of the continental lithospheric mantle to that of other parts of the terrestrial system, which may be involved in its origin and evolution. The potential locations of the contributing components and the mechanisms and timing of their assembly into lithosphere are considered. Current knowledge, however, does not allow us to distinguish unequivocally among the various scenarios for the creation and evolution of this reservoir.

Australian Journal of Earth Sciences↗