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USGS2023

Dissolved organic carbon dynamics and fluxes in Mississippi-Atchafalaya deltaic system impacted by an extreme flood event and hurricanes: A multi-satellite approach using Sentinel-2/3 and Landsat-8/9 data

Transport of riverine and wetland-derived dissolved organic carbon (DOC) spanning tidal wetlands, estuaries, and continental shelf waters functionally connects terrestrial and aquatic carbon reservoirs, yet the magnitude and ecological significance of this variable and its spatiotemporal linkage remains uncertain for coastal deltaic regions, such as Mississippi River Delta Plain, which includes Mississippi (MR) and Atchafalaya (AR) rivers and estuaries with vast expanses of wetlands and coastal forests. We examined DOC dynamics and fluxes in this large river-dominated wetland-estuarine system for the period between 2019 and 2021 that included an extreme river flood event in 2019, two major hurricanes (Barry in 2019 and Ida in 2021), and cold front passage using an improved adaptive quasi-analytical algorithm (QAA-AD) applied to multi-satellite sensors (Sentinel 3A/B OLCI, Landsat-8/OLI and Sentinel-2A/B MSI) with varying spectral and spatial (10/30/300 m) resolutions. The DOC estimates from multi-satellite sensors in combination with water fluxes were used to assess DOC fluxes from two large rivers (MR and AR) and small channels across the delta plain. Overall, this system delivered a total of 6.7 Tg C yr -1 (1 Tg = 10 12 g) into the estuarine zone and the northern Gulf of Mexico (nGoM) during 2019. High DOC fluxes from the AR (1.3 Tg C yr -1 ) and MR (4.5 Tg C yr -1 ) were associated with the extreme flood event in 2019. Hurricanes that occurred in the study period also contributed to the wetland and estuarine DOC fluxes into continental shelf waters; for example, the passage of Hurricane Barry in July 2019, delivered over a 3-day period ~1.33 ×10 9 g DOC from Barataria Basin into the nGoM. Sentinel 2-MSI land and water classification revealed that Hurricane Ida eroded a total of 1.34×10 8 m 2 of marshes in middle Barataria Basin, converting those habitats into open water with 3.0 m inundation depth and high DOC concentrations (16.4 mg L -1 ), a potentially large DOC source to the coastal waters. Overall, storms and flood events are major sources of DOC flux that facilitate transport of upstream carbon as well as transformation of carbon in the wetlands, through the conversion of vegetated wetland to open water.

Louisiana↗

USGS2014

Spatio-temporal patterns and climate variables controlling of biomass carbon stock of global grassland ecosystems from 1982 to 2006

Grassland ecosystems play an important role in subsistence agriculture and the global carbon cycle. However, the global spatio-temporal patterns and environmental controls of grassland biomass are not well quantified and understood. The goal of this study was to estimate the spatial and temporal patterns of the global grassland biomass and analyze their driving forces using field measurements, Normalized Difference Vegetation Index (NDVI) time series from satellite data, climate reanalysis data, and a satellite-based statistical model. Results showed that the NDVI-based biomass carbon model developed from this study explained 60% of the variance across 38 sites globally. The global carbon stock in grassland aboveground live biomass was 1.05 Pg·C, averaged from 1982 to 2006, and increased at a rate of 2.43 Tg·C·y −1 during this period. Temporal change of the global biomass was significantly and positively correlated with temperature and precipitation. The distribution of biomass carbon density followed the precipitation gradient. The dynamics of regional grassland biomass showed various trends largely determined by regional climate variability, disturbances, and management practices (such as grazing for meat production). The methods and results from this study can be used to monitor the dynamics of grassland aboveground biomass and evaluate grassland susceptibility to climate variability and change, disturbances, and management.

Remote Sensing↗

USGS2018

A molecular investigation of soil organic carbon composition across a subalpine catchment

The dynamics of soil organic carbon (SOC) storage and turnover are a critical component of the global carbon cycle. Mechanistic models seeking to represent these complex dynamics require detailed SOC compositions, which are currently difficult to characterize quantitatively. Here, we address this challenge by using a novel approach that combines Fourier transform infrared spectroscopy (FT-IR) and bulk carbon X-ray absorption spectroscopy (XAS) to determine the abundance of SOC functional groups, using elemental analysis (EA) to constrain the total amount of SOC. We used this SOC functional group abundance (SOC-fga) method to compare variability in SOC compositions as a function of depth across a subalpine watershed (East River, Colorado, USA) and found a large degree of variability in SOC functional group abundances between sites at different elevations. Soils at a lower elevation are predominantly composed of polysaccharides, while soils at a higher elevation have more substantial portions of carbonyl, phenolic, or aromatic carbon. We discuss the potential drivers of differences in SOC composition between these sites, including vegetation inputs, internal processing and losses, and elevation-driven environmental factors. Although numerical models would facilitate the understanding and evaluation of the observed SOC distributions, quantitative and meaningful measurements of SOC molecular compositions are required to guide such models. Comparison among commonly used characterization techniques on shared reference materials is a critical next step for advancing our understanding of the complex processes controlling SOC compositions.

Soil Systems↗

USGS2014

The implications of microbial and substrate limitation for the fates of carbon in different organic soil horizon types of boreal forest ecosystems: a mechanistically based model analysis

The large amount of soil carbon in boreal forest ecosystems has the potential to influence the climate system if released in large quantities in response to warming. Thus, there is a need to better understand and represent the environmental sensitivity of soil carbon decomposition. Most soil carbon decomposition models rely on empirical relationships omitting key biogeochemical mechanisms and their response to climate change is highly uncertain. In this study, we developed a multi-layer microbial explicit soil decomposition model framework for boreal forest ecosystems. A thorough sensitivity analysis was conducted to identify dominating biogeochemical processes and to highlight structural limitations. Our results indicate that substrate availability (limited by soil water diffusion and substrate quality) is likely to be a major constraint on soil decomposition in the fibrous horizon (40–60% of soil organic carbon (SOC) pool size variation), while energy limited microbial activity in the amorphous horizon exerts a predominant control on soil decomposition (>70% of SOC pool size variation). Elevated temperature alleviated the energy constraint of microbial activity most notably in amorphous soils, whereas moisture only exhibited a marginal effect on dissolved substrate supply and microbial activity. Our study highlights the different decomposition properties and underlying mechanisms of soil dynamics between fibrous and amorphous soil horizons. Soil decomposition models should consider explicitly representing different boreal soil horizons and soil–microbial interactions to better characterize biogeochemical processes in boreal forest ecosystems. A more comprehensive representation of critical biogeochemical mechanisms of soil moisture effects may be required to improve the performance of the soil model we analyzed in this study.

Biogeosciences↗

USGS2016

Colored dissolved organic matter in shallow estuaries: relationships between carbon sources and light attenuation

Light availability is of primary importance to the ecological function of shallow estuaries. For example, benthic primary production by submerged aquatic vegetation is contingent upon light penetration to the seabed. A major component that attenuates light in estuaries is colored dissolved organic matter (CDOM). CDOM is often measured via a proxy, fluorescing dissolved organic matter (fDOM), due to the ease of in situ fDOM sensor measurements. Fluorescence must be converted to CDOM absorbance for use in light attenuation calculations. However, this CDOM–fDOM relationship varies among and within estuaries. We quantified the variability in this relationship within three estuaries along the mid-Atlantic margin of the eastern United States: West Falmouth Harbor (MA), Barnegat Bay (NJ), and Chincoteague Bay (MD/VA). Land use surrounding these estuaries ranges from urban to developed, with varying sources of nutrients and organic matter. Measurements of fDOM (excitation and emission wavelengths of 365 nm (±5 nm) and 460 nm (±40 nm), respectively) and CDOM absorbance were taken along a terrestrial-to-marine gradient in all three estuaries. The ratio of the absorption coefficient at 340 nm (m −1 ) to fDOM (QSU) was higher in West Falmouth Harbor (1.22) than in Barnegat Bay (0.22) and Chincoteague Bay (0.17). The CDOM : fDOM absorption ratio was variable between sites within West Falmouth Harbor and Barnegat Bay, but consistent between sites within Chincoteague Bay. Stable carbon isotope analysis for constraining the source of dissolved organic matter (DOM) in West Falmouth Harbor and Barnegat Bay yielded δ 13 C values ranging from −19.7 to −26.1 ‰ and −20.8 to −26.7 ‰, respectively. Concentration and stable carbon isotope mixing models of DOC (dissolved organic carbon) indicate a contribution of 13 C-enriched DOC in the estuaries. The most likely source of 13 C-enriched DOC for the systems we investigated is Spartina cordgrass. Comparison of DOC source to CDOM : fDOM absorption ratios at each site demonstrates the relationship between source and optical properties. Samples with 13 C-enriched carbon isotope values, indicating a greater contribution from marsh organic material, had higher CDOM : fDOM absorption ratios than samples with greater contribution from terrestrial organic material. Applying a uniform CDOM : fDOM absorption ratio and spectral slope within a given estuary yields errors in modeled light attenuation ranging from 11 to 33 % depending on estuary. The application of a uniform absorption ratio across all estuaries doubles this error. This study demonstrates that light attenuation coefficients for CDOM based on continuous fDOM records are highly dependent on the source of DOM present in the estuary. Thus, light attenuation models for estuaries would be improved by quantification of CDOM absorption and DOM source identification.

Biogeosciences↗

USGS2012

Carbon export by rivers draining the conterminous United States

Material exports by rivers, particularly carbon exports, provide insight to basin geology, weathering, and ecological processes within the basin. Accurate accounting of those exports is valuable to understanding present, past, and projected basin-wide changes in those processes. We calculated lateral export of inorganic and organic carbon (IC and OC) from rivers draining the conterminous United States using stream gaging and water quality data from more than 100 rivers. Approximately 90% of land area and 80% of water export were included, which enabled a continental-scale estimate using minor extrapolation. Total carbon export was 41–49 Tg C yr −1 . IC was >75% of export and exceeded OC export in every region except the southeastern Atlantic seaboard. The 10 largest rivers, by discharge, accounted for 66% of water export and carried 74 and 62% of IC and OC export, respectively. Watershed carbon yield for the conterminous United States was 4.2 and 1.3 g C m −2 yr −1 for IC and OC, respectively. The dominance of IC export was unexpected but is consistent with geologic models suggesting high weathering rates in the continental United States due to the prevalence of easily weathered sedimentary rock.

Inland Waters↗

USGS1991

Areal extent, hydrogeologic characteristics, and possible origins of the carbonate rock Newburg Zone (Middle-Upper Silurian) in Ohio

The zone occurs in carbonate rocks of Middle to Late Silurian age across much of Ohio. Known also to well drillers as the "Second Water' in the "Big Lime' carbonate sequence, the Newburg zone is a source of hydrocarbons in northeast Ohio, brines in southeast Ohio, and a widespread source of water over much of west-central Ohio. Close to recharge areas, the quality of the water is comparable to that of the overlying carbonate rocks; thus, the Newburg zone warrants further investigation as a source of water for domestic use. Theories for the porosity and permeabilty of the Newburg zone include: 1) deposition of carbonate or quartz sand along an erosional surface and later lithified to porous and permeable sandstone; 2) dissolution of fossils within Silurian reef complexes; 3) fracture-induced porosity along thrust faults developed during the Alleghenian orogeny; and 4) a combination of these processes. -from Authors

Ohio Journal of Science↗

USGS1996

Ichnology of transgressive-regressive surfaces in mixed carbonate-siliciclastic sequences, early Permian Chase Group, Oklahoma

Early Permian rocks of the Chase Group in north-central Oklahoma consist of repeated couplets of carbonates and clastics. The carbonates and clastics correlate to major transgressive and regressive events, respectively. The sole of the lowest (first) transgressive carbonate bed of each depositional couplet is covered with ubiquitous horizontal boxworks of the trace fossil Thalassinoides isp. Horizontal forms of the trace fossil Rhizocorallium isp. characterize the top bedding-plane surface of the highest (last) carbonate unit of each couplet, and mark the discontinuity surface at the culmination of a major transgression and the initial onset of a major regression. These trace-fossil associations are assigned to the substrate-controlled Glossifungites ichnofacies.

Paleozoic sequence stratigraphy: views from the No↗

USGS1999

Quantitative models for aggregate: some types and examples from Oklahoma carbonate rocks

Evaluation of data for three engineering variable--absorption, bulk specific gravity, and freeze-thaw durability (350 cycles)--was made for quarries in carbonate rocks in Oklahoma that supply aggregate. It was found that lower Palrozoic carbonate rocks (Cambrian through Devonian) are likely to make a better quality aggregate than upper Paleozoic (Mississippian to Permian) carbonate rocks. In addition, freeze-thaw durability can be forecast from absorption and is exemplary for lower Paleozoic carbonate rocks.

Oklahoma↗

USGS2015

Architecture and evolution of an Early Permian carbonate complex on a tectonically active island in east-central California

The newly named Upland Valley Limestone represents a carbonate complex that developed on and adjacent to a tectonically active island in east-central California during a brief interval of Early Permian (late Artinskian) time. This lithologically unique, relatively thin limestone unit lies within a thick sequence of predominantly siliciclastic rocks and is characterized by its high concentration of crinoidal debris, pronounced lateral changes in thickness and lithofacies, and a largely endemic fusulinid fauna. Most outcrops represent a carbonate platform and debris derived from it and shed downslope, but another group of outcrops represents one or possibly more isolated carbonate buildups that developed offshore from the platform. Tectonic activity in the area occurred before, probably during, and after deposition of this short-lived carbonate complex.

California↗

USGS2009

Improving conceptual models of water and carbon transfer through peat

Northern peatlands store 500 × 10 15 g of organic carbon and are very sensitive to climate change. There is a strong conceptual model of sources, sinks, and pathways of carbon within peatlands, but challenges remain both in understanding the hydrogeology and the linkages between carbon cycling and peat pore water flow. In this chapter, research findings from the glacial Lake Agassiz peatlands are used to develop a conceptual framework for peatland hydrogeology and identify four challenges related to northern peatlands yet to be addressed: (1) develop a better understanding of the extent and net impact of climate-driven groundwater flushing in peatlands; (2) quantify the complexities of heterogeneity on pore water flow and, in particular, reconcile contradictions between peatland hydrogeologic interpretations and isotopic data; (3) understand the hydrogeologic implications of free-phase methane production, entrapment, and release in peatlands; and (4) quantify the impact of arctic and subarctic warming on peatland hydrogeology and its linkage to carbon cycling.

Book chapter↗

USGS2018

Increasing soil organic carbon to mitigate greenhouse gases and increase climate resiliency for California

Rising air temperatures are projected to continue to drive up urban, agricultural, and rangeland water use, straining both surface and groundwater resources. Scientific studies have shown that managing farms, ranches, and public lands to increase soil carbon can increase soil waterholding capacity and increase hydrologic benefits such as increased baseflows and aquifer recharge, reduced flooding and erosion, and reduced climate-related water deficits. Coincident improvements in forage and crop yields are also indicated, while simultaneously sequestering carbon, reducing atmospheric greenhouse gases and mitigating climate change. This study was developed to consider the multiple benefits of increasing the organic matter content of soils across California’s working lands. Study results indicate that a one-time ¼” application of compost to rangelands can lead to carbon sequestration rates in soils that are maximized after approximately 15 years, and more than offset greenhouse gas emissions stimulated by the compost addition for at least five decades longer. Modeled increases in total soil organic matter of 3% enhanced hydrologic benefits across 97% of working lands, and reduced climate change impacts. Economic valuation indicated all benefits increasing over time, demonstrating a large potential for the California carbon market to support incentives in regionalizing the impacts in the coming decades. Socioeconomic and related land use pressures pose barriers to implementing management practices to increase soil organic matter by driving conversion of rangeland to urban or to more greenhouse-gas emission intensive agriculture. Results can be effectively used with land use change scenarios to identify where on California’s working lands hydrologic benefits of soil organic matter enhancement coincide with development risk, highlighting counties in California in which there may be resilience to climate change when strategic soil management and land conservation are combined.

California↗

USGS2021

Preserving soil organic carbon in prairie wetlands of central North America

Wetlands of the Prairie Pothole Region (PPR) in the Great Plains of central North America are numerous, densely distributed, and have highly productive plant and animal communities (Photo 49). When in a natural, unaltered condition, these wetlands store relatively large amounts of organic carbon in their soils (Photo 50). Human alterations, such as extensive drainage and land-use conversion for agriculture (Figure 7), have been linked with the loss of soil organic carbon (SOC) and associated emission of carbon dioxide (CO 2 ), as well as impacts to other ecosystem services provided by these wetlands, such as wildlife and waterfowl habitat, plant biodiversity, flood mitigation, groundwater recharge, nutrient removal and retention, and recreation (Gleason et al., 2011). It has been estimated that more than half of the wetlands of the PPR have been lost due to drainage and other disturbances, with losses approaching 90 percent in some areas (Dahl, 2014; Serran et al., 2018). The goal of this case study was to identify land-management strategies that are consistent with maintaining and increasing SOC stocks of PPR wetlands. Two overarching strategies generally are promoted to preserve and enhance SOC stocks of PPR wetlands: avoided drainage and rewetting or restoration. Avoided drainage involves protecting natural, unaltered wetlands from impacts of human actives with the purpose of retaining wetland functions and services such as carbon storage. Rewetting or restoration involves reestablishing natural hydrology and land use with the purpose of enhancing wetland functions and services that were previously lost due to human activities. Avoided drainage provides immediate and long-lasting benefits, while replenishing SOC through rewetting and restoration requires many decades. Both strategies are associated with higher methane (CH 4 ) emissions but lower CO 2 and nitrous oxide (N 2 O) emissions.

Alberta, Iowa, Manitoba, Minnesota, Montana, North↗

USGS2024

Thermal and hydrological limitations on modeling carbon dynamics at wetland sites of discontinuous and continuous permafrost extent

Accurate representation of cryohydrological processes is fundamental for biosphere models, particularly at high-latitudes, given their influence on carbon and permafrost dynamics in carbon-rich peatlands and wetlands. This study analyzes site-level simulations in moist and wet drainage conditions in continuous or discontinuous permafrost regions, using a terrestrial ecosystem model DVM-DOS-TEM. Functional benchmarking was conducted against eddy covariance flux alongside soil temperature, moisture, and thaw depth observations. Thermal and hydrological analysis reveals parameter sensitivity and uncertainty concerning carbon cycling and permafrost dynamics. Flux representation is markedly consistent at sites characterized by continuous permafrost with less seasonal variation, owing to longer soil freezing duration. Sites in discontinuous permafrost, exhibiting active permafrost degradation and talik formation, pose considerable challenges in accurately depicting thaw depth. Underprediction of soil moisture across all sites has more pronounced effects on boreal wetlands characterized by thick organic layers up to 1 m. These results illustrate the limitations of terrestrial ecosystem models to represent environmental and ecological dynamics in wetlands. Attempts to adjust model hydrology have yielded marginal improvements in thaw depth prediction, but revealed large effects of abrupt phase changes for poorly drained sites on discontinuous permafrost. Our analysis suggests the importance of gradual phase change representation, particularly in ice-rich wetlands with thick organic layers, which will be crucial when evaluating the permafrost carbon-climate feedback in model projections.

Alaska↗

USGS2006

Model-data fusion in the studies of terrestrial carbon sink

Current uncertainty in quantifying the global carbon budget remains a major contributing source of uncertainty in reliably projecting future climate change. Furthermore, quantifying the global carbon budget and characterizing uncertainties have emerged as critical to a successful implementation of United National Framework Convention on Climate Change and its Kyoto Protocol. Beyond fundamental quantification, attribution of the processes responsible for the so-called ‘residual terrestrial uptake’ is important to the carbon cycle communities’ ability to simulated the future response of the terrestrial biosphere to climate change and intentional sequestration activities. This paper’s objective is to describe the efforts of the workshop participants and their approaches to model-data fusion enabling continued advances in the solution of quantifying carbon cycling and the terrestrial mechanisms at work.

Conference Paper↗

USGS2013

National assessment of geologic carbon dioxide storage resources: Data

In 2012, the U.S. Geological Survey (USGS) completed the national assessment of geologic carbon dioxide storage resources. Its data and results are reported in three publications: the assessment data publication (this report), the assessment results publication (U.S. Geological Survey Geologic Carbon Dioxide Storage Resources Assessment Team, 2013a, USGS Circular 1386), and the assessment summary publication (U.S. Geological Survey Geologic Carbon Dioxide Storage Resources Assessment Team, 2013b, USGS Fact Sheet 2013–3020). This data publication supports the results publication and contains (1) individual storage assessment unit (SAU) input data forms with all input parameters and details on the allocation of the SAU surface land area by State and general land-ownership category; (2) figures representing the distribution of all storage classes for each SAU; (3) a table containing most input data and assessment result values for each SAU; and (4) a pairwise correlation matrix specifying geological and methodological dependencies between SAUs that are needed for aggregation of results.

Data Series↗

USGS2001

Effects of dissolved carbon dioxide on the physiology and behavior of fish artificial streams

A new technology for treating waters contaminated with acid mine drainage involves the dissolution of limestone particles using carbon dioxide at pressures above ambient. Because of the fish health risks associated with episodes of high carbon dioxide levels in treated waters, we subjected three species of fish, brook trout ( Salvelinus fontinalis ), slimy sculpin ( Cottus cognatus ), and blacknose dace ( Rhinichthys atratulus ), to 24 h exposures of elevated dissolved carbon dioxide (CO 2 ) at three levels, ranging from 1.0 (low) to 6.3 (high)%, under laboratory conditions. We measured blood physiological variables as well as behavior, including feeding responses, before, during, and after exposure. Physiological responses differed by species, but all species had elevated hematocrits after 1 h of exposure. Brook trout hematocrits were higher at medium and high levels of CO 2 than in a control group (0.0% CO 2 ) after 24 h of exposure. Slimy sculpin hematocrits were higher in medium- and high-level exposure groups than in controls after 1 h, but not after 24 h, of exposure. Blacknose dace hematocrits were higher in all three exposure groups than in controls after 1 h but only in medium-level exposure groups after 24 h. Brook trout plasma glucose was significantly higher in medium- and high-level exposure groups after 1 h, and in the high-level group after 24 h, than in controls. Slimy sculpin plasma glucose was not significantly different in elevated CO 2 exposure groups from that of controls throughout exposure. Branchial ventilation was significantly greater in all species at elevated CO 2 during exposure, indicating stress; however, no difference was observed between treatment and control groups of blacknose dace after 24 h, indicating acclimation. Pectoral fin beats and cough rates were not consistently related to CO 2 exposure throughout the study. Brook trout had the longest lasting reaction to stress at lower levels of CO 2 among the three species tested. Many of the 11 observed behavioral variables, related to swimming, feeding, social, and illness factors, were affected by elevations of dissolved CO 2 . Two to seven behavioral variables (18–64% of those measured) were affected by treatment level of dissolved CO 2 with a trend by species for the number of variables affected: brook trout>blacknose dace>slimy sculpin. However, behavioral sensitivity to treatment level was greatest in blacknose dace. Recovery to pre-treatment activity rates for most behavior patterns (including feeding) was observed 24 h after cessation of exposure in all three species. Recovery was independent of treatment level, was most rapid in blacknose dace, and was slowest in brook trout. Overall, slimy sculpin was least affected behaviorally by elevated CO 2 . Although all three species showed stress response and changes in behavior at moderate levels of CO 2 (≥2%), brook trout and blacknose dace showed evidence of ability to avoid harmful CO 2 levels by swimming out of affected waters, whereas the slimy sculpin showed minimal behavioral changes despite remaining in place during exposure. Thus, predation risk and other sources of mortality seem minimal in the event of technological malfunction at a stream treatment site involving the use of CO 2 under pressure.

Environmental Toxicology↗

USGS2015

Switching predominance of organic versus inorganic carbon exports from an intermediate-size subarctic watershed

Hydrologic exports of dissolved inorganic and organic carbon (DIC, DOC) reflect permafrost conditions in arctic and subarctic river basins. DIC yields in particular, increase with decreased permafrost extent. We investigated the influence of permafrost extent on DIC and DOC yield in a tributary of the Yukon River, where the upper watershed has continuous permafrost and the lower watershed has discontinuous permafrost. Our results indicate that DIC versus DOC predominance switches with interannual changes in water availability and flow routing in intermediate-size watersheds having mixed permafrost coverage. Large water yield and small concentrations from mountainous headwaters and small water yield and high concentrations from lowlands produced similar upstream and downstream carbon yields. However, DOC export exceeded DIC export during high-flow 2011 while DIC predominated during low-flow 2010. The majority of exported carbon derived from near-surface organic sources when landscapes were wet or frozen and from mineralized subsurface sources when infiltration increased.

Alaska↗