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Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Apatite (U-Th)/He thermochronology from Marsh Creek anticline reconciles Cenozoic and Holocene strain patterns and elucidates the Cenozoic canning displacement zone of Arctic Alaska

The northeastern Brooks Range is a vast fold-thrust belt that records the northernmost expression of Cenozoic deformation in Alaska, likely with complex dynamic linkages to distant tectonic elements. The principal focus of this manuscript is the Marsh Creek anticline (MCA), which is a large and recently active structure within the broader northeastern Brooks Range. The MCA is a complex, polyphase structure mostly buried beneath the Arctic coastal plain. We present apatite (U-Th)/He (AHe) dates from six outcrop samples, all near the structural crest of the anticline, as well as supporting detrital zircon U/Pb (ZUPb) age spectra from five outcrop samples. The AHe sample transect spans ~3 km of structural relief. The four shallowest AHe samples are not reset. However, the two deepest samples exhibit low intrasample variability among replicates and strong date versus grain radius correlations, suggesting post-depositional burial heating to within the AHe partial retention zone. Inverse thermal history modeling of these data resolves a protracted phase of exhumational cooling that began around 33–28 Ma. Detrital ZUPb age spectra from Paleogene strata support an interpretation of diverse inherited thermal histories recorded by the AHe data, and they are also consistent with extant reconstructions of Paleogene sediment dispersal. Placed into regional context, the results constrain a phase of increasing structural relief in the northeastern Brooks Range fold-thrust belt that began by the Eocene. The relief developed in a zone characterized by diminishing structural relief to the west called the Canning displacement zone. Although this zone was active since the Eocene, several structures including the studied part of the MCA were rapidly exhumed in the Oligocene. Lastly, we argue for kinematic compatibility between Cenozoic contraction and active strike-slip in the northeastern Brooks Range, with the temporal change in strain style likely reflecting the increase in structural relief and topography.

Alaska

Methodology for quantitative spatial sensitivity analysis of volcanic geodetic networks

Introduction This report introduces a methodology for assessing the state of the U.S. Geological Survey Volcano Observatories’ geodetic monitoring networks that measure how volcanoes deform or change shape. This new method uses a model-based approach that considers the uniqueness of the instrument environments at each volcano. This report focuses on simplified volcanic sources, is independent of the shape or size of the volcano, or the network geometry, and thus highlights the strengths and potential vulnerabilities of each volcano’s geodetic network in an actionable visual format. This analysis can help observatories to make informed decisions about whether volcanoes have an adequate level of geodetic monitoring and indicate where improvements are needed.

Lassen Peak, Mount Shasta

Prioritizing resource protection and understanding potential susceptibility of springs to surficial changes in a low-temperature geothermal system

Geothermal systems are vulnerable to changes in water budget and composition, requiring science-based management. This study uses a dataset of spring water temperatures, time series of groundwater residence time tracers (tritium and carbon-14), and stable isotopes of water to understand geothermal flow in a low-temperature geothermal system in north west Colorado, United States (Steamboat Springs). The geothermal system is bisected by the Yampa River, necessitating a stream mass balance approach to quantify total discharge. Time series analysis of water temperature data provides a ranked list of features more susceptible to surficial changes, which is corroborated using time series of tritium which indicate spatially distinct patterns of mixing between modern and pre-modern groundwater. All springs contain a portion of pre-modern groundwater that is thousands to tens of thousands of years old, a period coinciding with melting of extensive Pleistocene glaciers that was likely one of the recharge sources to the geothermal system. Stream mass balance indicates that greater than 80% of the total geothermal discharge is derived from diffuse or small springs, highlighting the extensive nature of the geothermal outflow zone and the association with local geologic structures. This study provides baseline data to support management of the Steamboat Springs geothermal system and indicates the utility of these approaches in developing science-based geothermal management.

Colorado

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California

Generalized potentiometric maps of the Fort Union, Hell Creek, and Fox Hills aquifers within the Standing Rock Reservation

Generalized potentiometric surfaces of the Fort Union, Hell Creek, and Fox Hills aquifers were constructed to assess the groundwater resources of the Standing Rock Reservation. Additionally, this information can provide water managers with tools and data to effectively manage water resources in the future. Previous studies that mapped the geology and hydrogeology of the area at differing scales were used to confirm in which aquifer the study wells were completed. Water-level data from wells are provided by the U.S. Geological Survey Groundwater System Inventory database, the South Dakota Department of Agriculture and Natural Resources, and the North Dakota Department of Water Resources. Hydrographs were constructed for five selected observation wells to evaluate historical water-level fluctuations and trends. Hydrographs for the Hell Creek aquifer showed a flat trend with a rise in 2020. Hydrographs for the deeper Fox Hills aquifer showed that water levels fluctuated in response to climatic conditions and demonstrated an increasing trend in water-level elevations starting in 2010. Hydrographs were not constructed for any wells completed in the Fort Union Formation because none of the wells had continuous long-term measurements. Generalized potentiometric surfaces, constructed from interpolating water-level elevations, gave insight into groundwater flow directions. Groundwater in the Fort Union aquifer likely flows radially outward from the northwest part of the study area to the northeast and south-southeast parts. Groundwater in the Hell Creek aquifer generally flows from higher elevations in the northwest towards lower areas, where surface-water tributaries have incised into the aquifer. Groundwater in the Fox Hills aquifer likely flows from higher elevations in the west, southwest, and central parts of the study area towards the valleys of the Grand River and Missouri River. Most wells used for constructing potentiometric maps had only one recorded water-level measurement from drillers at the time of well construction. These measurements are often subject to error because the well is still recovering and because of spatial limitations of data availability. Also, because single water-level measurements were recorded at different points in time, additional uncertainty is introduced by fluctuating climatic conditions effect on water levels. Potentiometric map interpretation limitations are a result of areas with sparse data. Limitations also arise from potentiometric surfaces generalizing a complex and dynamic hydrogeologic system; however, the generalized potentiometric surface maps can be used to assist water managers and can help prioritize locations for future monitoring in areas with high uncertainty from sparse existing data.

North Dakota, South Dakota

Relating systematic molecular and textural properties of graptolite pyrolyzed via gold tube hydrous pyrolysis: Implications for thermal proxies in lower Paleozoic marine shales

A series of gold tube pyrolysis experiments (72 h, 300–550 °C, 50 MPa) conducted on a graptolite-rich lower Paleozoic marine shale generated pyrolysis residues for a comprehensive evaluation of the molecular and structural variability of three types of graptolite periderm. Organic petrology, Raman spectroscopy, and field emission scanning electron microscopy (FE-SEM) with energy dispersive spectroscopy (EDS) were combined to evaluate the thermal evolution process. The three types of graptolite periderm, namely granular, non-granular, and nodular graptolite, were analyzed by Raman spectroscopy wherein point measurements were obtained after the maceral was identified and the location verified by organic petrology. Distinct thermal evolution pathways among non-granular, granular, and nodular graptolite periderms were recorded. The evolution patterns of the Raman parameters, particularly D1 and G bands, highlight the differences in geochemical composition of the graptolite periderm types and the alteration of molecular structure with increasing thermal maturity. Raman parameters D1 (position of the D1 peak), G-FWHM (full width at half maximum of the G peak), and ratios D1-FWHM/G-FWHM (full width at half maximum of the D1 peak ratioed to G-FWHM) and A D1 /A G (ratio of D1 and G peak intensities) showed effectiveness in assessing thermal maturity. Bireflectance with increasing gold tube pyrolysis temperature followed a hierarchy: non-granular > granular > nodular, reflecting different molecular alignment intensities. Qualitative FE-SEM evaluation showed that fine-grained mineral inclusions (primarily Fe-sulfide as determined via EDS) were associated with the graptolite populations, with granular graptolite containing greater amounts of coarser-grained (e.g., ∼300–1400 nm) mineral inclusions relative to non-granular and nodular graptolite, which contain finer-grained (e.g., ∼100–200 nm) inclusions difficult to resolve with optical microscopy. These findings are investigated to highlight the mechanisms that drive organic matter evolution within graptolite during thermal maturation, as well as to explore some of the limitations of using spectroscopic parameters as thermal maturity proxies.

International Journal of Coal Geology

From critical minerals to food security, the benefits of data collaboration

The volume of data in the public geoscience sphere is rapidly and continually expanding. At Geoscience Australia (GA) we saw an over 500% increase in data points within our relational databases between 2018 and 2024, over the life of the Exploring for the Future (EFTF) program. With the Resourcing Australia’s Prosperity initiative, a continued increase in data quantity will be seen for the next 10 to 35 years. At the same time, a broadening audience for geoscience data is increasing the desire to enhance the diversity of delivery streams. This ranges from data-dense highly technical outputs for geoscience specialists to curated interpretive products for people who are non-geoscientists. Development of these curated outputs has contributed to our awareness of the need for data to be collected and compiled in a way that ensures its reuse, with a focus on quality metadata and data provenance.

Conference Paper

Map of topographic lineaments interpreted as recent surface ruptures along the Bennett Valley and Southern Maacama Fault Zones, Sonoma County, California

This study documents lidar-illuminated topographic lineaments interpreted as evidence of recent surface fault ruptures and surface ruptures related to distributed deformation along the Bennett Valley Fault Zone and the southernmost Maacama Fault Zone in the northern San Francisco Bay area (fig. 1, on map sheet). Together, these fault zones form a structural connection across a right stepover between the main Maacama Fault Zone and the Rodgers Creek Fault, overlapping principal strands of the San Andreas plate boundary system north of San Francisco Bay (figs. 1, 2, on map sheet) that accommodate about a quarter of the ~40 millimeters per year of regional dextral tectonic slip (Parsons and others, 2013). Although much of the Bennett Valley Fault Zone is seismically active (McLaughlin and others, 2012; Sowers and others, 2010), only the north end of the fault zone (the “Spring Valley strand,” indicated on southern map panel of map sheet and labeled “D” in figure 2, on map sheet) was previously known to have youthful geomorphic expression and to displace Holocene deposits (McLaughlin and others, 2008; Sowers and others, 2010; Sowers and others, 2016). Holocene activity along the length of the Bennett Valley Fault Zone and southernmost Maacama Fault Zone, with possible implications for rupture propagation, continuity, and slip transfer, had not been identified. However, fault splays that project eastward from the Rodgers Creek Fault have been mapped and hypothesized to accommodate slip transfer to the Bennett Valley Fault Zone (Hecker and Randolph Loar, 2018). The generally subtle and distributed nature of surface-rupture evidence along the Bennett Valley and southernmost Maacama Fault Zones, and extensive vegetation cover, had left recent faulting previously unmapped along most of the zone. The map presented here represents a new compilation of inferred surface-rupture features detected using high-resolution topographic lidar data from an airborne lidar survey of Sonoma County, California (OpenTopography, 2014). These data, which enable subtle topographic features to be discerned, indicate that recent (likely Holocene) surface ruptures extend throughout the Bennett Valley and southernmost Maacama Fault Zones. The rupture-lineament map was created using a GIS (geographic information system) framework and is included herein as an image map at a scale of 1:36,000 and as digital datasets (included as supplemental information to this report). The mapping is intended to lay the groundwork for future studies designed to better characterize how plate-boundary slip is accommodated on this important and complex system of faults.

California

A 700-year rupture sequence of great eastern Aleutian earthquakes from tsunami modeling of stratigraphic records

Great Aleutian underthrusting earthquakes produced destructive tsunamis impacting Hawaiʻi in 1946 and 1957. Prior modeling of the 1957 tsunami deposit and runup records on eastern Aleutian and Hawaiian Islands jointly with tide-gauge observations across the Pacific Ocean constrained a rupture model with shallow slip up to 26 m along 600 km of the plate boundary. Here we implement this modeling approach to older deposits and show alternating deep and shallow megathrust slip up to 26, 32, and 22 m for great earthquakes along the same segment in the 18 th , 15 th , and 14 th centuries. All three modeled prehistoric Aleutian earthquakes produce tsunami inundation in Hawaiʻi with the most severe, 14 th century event having impacts exceeding the 1957 event. The along-dip variability of these four ruptures spanning seven centuries provides insights on earthquake cycles for engineering design and hazard assessment. The 15 th century and 1957 rupture models provide evidence for recurrence of tsunami earthquakes, which can produce disproportionately large tsunamis for a given moment magnitude due to reduced rigidity in the shallow megathrust. The 14 th and 18 th century events likely ruptured deeper regions that did not slip in 1957, suggesting potential for corresponding deeper failure in the next great eastern Aleutian earthquake.

Alaska, Hawaii

Sensitivity of benthic biota and toxicity of cadmium, cobalt, copper, nickel, lead, and zinc mixtures in Washington, United States, and British Columbia, Canada

Relative sensitivities and responses of juvenile white sturgeon ( Acipenser transmontanus ), Hyalella azteca , two families of mayfly (Ephemerellidae, Heptageniidae), one family of caddisfly (Brachycentridae), and a natural community of benthic macroinvertebrates (BMI) to multiple metals are predicted using previously collected laboratory and field samples and a metal mixture model. Biological responses in single metal exposures are used to parameterize toxicity functions, which include accumulations of hydrogen and selected metals on biological receptors, intrinsic potencies of hydrogen and metals, sensitivities of organisms, and times of exposure. The model then is used to predict responses in multiple metal laboratory exposures and field-collected porewater. The following sensitivity sequence in porewater was determined based on endpoints of survival or total abundance: juvenile white sturgeon greater than (>) Ephemerellidae family > Hyalella azteca > Heptageniidae family about equal to (~) benthic macroinvertebrate community > Brachycentridae family. The fraction of porewater samples that are predicted to have adverse impacts on benthic biota (20-percent or greater negative response) depends on organism sensitivities and metal toxicities, and ranges from 44 to 48 percent for juvenile white sturgeon, 23 to 26 percent for the Ephemerellidae family, 16 to 22 percent for Hyalella azteca , 5 to 8 percent for the Heptageniidae family and BMI community, and 0 percent for the caddisfly family. The most toxic porewater in the upper Columbia River Basin (UCR) is at the backwater bar site at Deadmans Eddy and China Bend. The model also indicates that the element responsible for the most toxic conditions in UCR porewater is copper for all organisms, except Hyalella azteca and the metal-insensitive Brachycentridae family. Copper and lead result in the most toxic conditions for Hyalella azteca . This approach and results can aid in assessing metal toxicity and its potential risk to aquatic biota in ecosystems impacted by historical mining activities.

British Columbia, Washington

Quantitative mineral resource assessment of lithium pegmatite deposits in the northern Appalachian orogen, USA

Lithium demand is projected to increase more than 48 times by 2040 due to electric vehicle production and other energy storage needs. Most lithium production is outside of the USA, thereby increasing supply chain vulnerability. The combined end use importance and heightened supply risk of lithium make this lightest metallic element a critical commodity to the USA. To mitigate this supply risk, the US Geological Survey is actively assessing lithium deposits in the USA. Herein, we detail an assessment for lithium-mineralized pegmatites in the US northern Appalachian Mountains. Permissive tracts were generated by cross-referencing tectonic and geologic maps and mineral occurrence data with mappable criteria derived from generalized and region-specific lithium pegmatite ore deposit models; tracts were then ranked as having high, medium, or low permissibility. Available geophysical and geochemical data were found to be of minimal utility for this deposit type at the scale of the assessment. The number of undiscovered deposits were estimated and integrated into probabilistic simulations, which included an expanded and updated global grade and tonnage model of pegmatite-hosted lithium ore. The estimated total amount of undiscovered resources for the northern Appalachian Orogen has a median value of 1,410,000 metric tons of Li 2 O when considering moderate correlation across sub-regions. At a confidence level of 90%, a resource of at least 90,000 metric tons of Li 2 O remains undiscovered, and at a 10% confidence level, a resource of as much as 7,380,000 metric tons Li 2 O remains undiscovered. After applying an up-to-date economic filter to convert median contained lithium to recoverable material, a correlated total of 900,000 metric tons of Li 2 O may be economically extractable, equating to enough Li 2 O to provide the current annual US lithium supply deficit (presently obtained through net imports) for 127 years at 2025 rates of apparent consumption. This period of provision will inevitably shorten with projected increasing consumption rates, emphasizing that further research could be completed to better delineate regions of high lithium resource potential and support exploration and domestic production.

Connecticut, Delaware, Maine, Massachusetts, New H

California State Waters Map Series—Benthic habitat characterization in the region offshore Humboldt Bay, California

Coastal and Marine Ecological Classification Standard (CMECS) geoform, substrate, and biotic component geographic information system (GIS) products were developed for the California State Waters of northern California in the region offshore of Humboldt Bay. The study was motivated by interest in development of offshore wind-energy capacity and infrastructure in Federal waters offshore. This project, carried out by the U.S. Geological Survey (USGS), resulted in four data releases for individual map blocks that are part of the “California State Waters Map Series”: (1) Offshore of Arcata, (2) Offshore of Eureka, (3) Offshore of the Eel River, and (4) Offshore of Cape Mendocino. The study area consists of 436 square kilometers of multibeam echo sounder (MBES) data acquired by Fugro Pelagos, Inc., in 2007. Towed camera-sled video was acquired in 2009 and 2010 to supervise the classification of the MBES data into habitats, and single channel sparker data were collected to calculate sediment thickness above the transgressive unconformity. Using video observations of habitat as ground truth, derivatives of the MBES data were classified into 3 seafloor character types (hard-rugose, hard-flat, and soft-flat), 26 induration-slope-depth groups, and 15 geoforms. The study area substrate is predominantly soft-flat sediment (mud and fine sand) covering 73.6 percent of the area. Hard-flat substrate areas, predominantly coarse sediment in scour depressions, cover 5.4 percent of the study area. The hard-rugose substrate areas are primarily outcrops of layered sedimentary bedrock and constitute 20.9 percent of the study area. Fifteen geoforms were identified in the analysis. The predominant geoforms mirror the seafloor character results, shelf geoforms, rock outcrop geoforms, and scour depression geoforms. Rock and scour areas are restricted to the southern portion of the study area off Cape Mendocino where uplift has exposed bedrock. On the flat shelf area post-transgressive sediment varies in thickness from 1.7 meters (m) nearshore to 28.1 m offshore.

California

Deaf, deafblind, and hard of hearing university student experiences with earthquake early warning in the United States: Evaluating language planning and technology access

The growing literature on deaf and hard of hearing (DHH+) populations and disasters demonstrates that emergency communication (including alerts) is not reaching global DHH + individuals with dangerous impacts for morbidity and mortality. This is the first research study in the U.S. to qualitatively explore the experiences of DHH + persons with earthquake early warning (EEW) through group-based dialogue sessions. The study investigates eight DHH + university students'past earthquake experiences, access to EEW alerts, and perceptions of ShakeAlert Ⓡ , an EEW system for detecting earthquakes and alerting residents of California, Oregon, and Washington. Findings highlight key gaps in disaster alert usability within four thematic areas: lack of messaging in participants' language(s), unclear alert messaging, deficient message delivery mechanisms for deafblind persons, and insufficient access to earthquake information and training that leads to dependence on informal information networks. Weaknesses identified in these four themes reduce DHH + trust in EEW systems and compromise the capacity of alert recipients to take swift protective action or to mentally prepare before shaking starts. The study also underscores structural factors such as insufficient linguistic representation in disaster language planning and technology design, which ignores the linguistic and sensory access needs of DHH + individuals. Building on disaster language planning frameworks, we recommend involving DHH + populations to co-develop EEW alerts. By centering DHH + perspectives, this research contributes to ongoing efforts to ensure that EEW systems reach everyone.

California

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews

High-resolution landscape-scale maps of nutrients, phytoplankton, and related water-quality constituents in Suisun Bay and the Sacramento–San Joaquin Delta, California, during 2018—Results from high-resolution underway surveys

We examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun, Grizzly, and Honker Bays in California by completing three spatial surveys that used continuous underway high frequency (1 hertz) measurements and sampling onboard a high-speed boat. Surveys were conducted in May, July, and October 2018. Water was sampled continuously during surveys to simultaneously collect information about the concentration and spatial distribution of all major nutrient forms together with information about the major classes of phytoplankton and associated standard field measurements of water quality, such as dissolved oxygen, dissolved organic matter, pH, salinity, specific conductance, turbidity, and water temperature. The results show a greater than 50-fold variation in nutrient and phytoplankton concentrations across space and time, providing evidence of the dynamic environmental processes that shape the ways nutrients interact with and affect Delta aquatic habitats.

Data Report

Generating geochemical and mineralogy distributions of soil in the conterminous United States using Bayesian hierarchical spatial models

Characterizing geochemical and mineralogical soil distributions across large spatial extents is essential for understanding mineral resources, ecosystem processes, and environmental risks. Rasters of soil geochemical distributions for the conterminous United States, however, are limited. We present a Bayesian modeling workflow and tool for generating predictive geochemical and mineralogy distribution maps for the conterminous United States using integrated nested Laplace approximation (INLA) with the stochastic partial differential equation approach. By modeling soil geostatistical data with environmental covariates (soil properties, topography, climate, and land cover), we generate predictive distributions of soil geochemistry that can be mapped or extracted for further analyses. As an example, we model the spatial distribution of trace elements in soil relevant to vertebrate health (cobalt, copper, iron, manganese, selenium, and zinc) and provide a workflow that can be used to generate and visualize predictive distributions of 39 other major and trace elements and 21 minerals of the soil survey, supporting a variety of ecological, environmental, and agricultural applications.

MethodsX

Evidence for offset of Cretaceous plutons by the Tintina fault in eastern Alaska: Implications for regional metallogeny

Cretaceous magmatism in eastern interior Alaska is voluminous, but temporally and spatially diverse – suggestive of varying sources and drivers. More than 150 new U-Pb zircon and more than 500 geochemical analyses of Cretaceous plutonic units allow for the grouping of distinct plutonic suites. Magmatism was continuous from 120-66 Ma but can be grouped into temporally distinct pulses from ca. 115-100 Ma, 100-90 Ma, and 75-66 Ma. Geochemical diversity occurs during each pulse, further distinguishing multiple suites. Diverse metallogenic epochs are strongly correlated to pluton chemistry. Mineralization is largely absent prior to 108 Ma. From 108-100 Ma, plutonism is coeval with sparse, but notable Au-quartz veins with variable Bi, As, W, and Mo. From 100-90 Ma, intrusion-related mineralization zones from Au-Cu(-Bi) and U-Th in the northwest to central Au- Bi-As-Te(-W), and Mo-W to the southeast. Porphyry style Cu-Mo(-Au) occurrences occur with the latest Cretaceous plutons emplaced from 75-66 Ma . Restoration of ~450 km of dextral movement on the Tintina fault and comparison of metallogenic and geochemical characteristics of Alaska plutons suggest 100-90 Ma plutons may be the continuation of the metallogenically significant Tombstone, Mayo, and Tungsten suites from the Yukon.

Alaska