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Historical changes to Lake Washington and route of the Lake Washington Ship Canal, King County, Washington

Lake Washington, in the midst of the greater Seattle metropolitan area of the Puget Sound region (fig. 1), is an exceptional commercial, recreational, and esthetic resource for the region . In the past 130 years, Lake Washington has been changed from a " wild " lake in a wilderness setting to a regulated lake surrounded by a growing metropolis--a transformation that provides an unusual opportunity to study changes to a lake's shoreline and hydrologic characteristics -resulting from urbanization.

Washington↗

Assessing the susceptibility to contamination of two aquifer systems used for public water supply in the Modesto and Fresno metropolitan areas, California, 2001 and 2002

Ground-water samples were collected from 90 active public supply wells in the Fresno and Modesto metropolitan areas as part of the California Aquifer Susceptibility (CAS) program. The CAS program was formed to examine the susceptibility to contamination of aquifers that are tapped by public supply wells to serve the citizens of California. The objectives of the program are twofold: (1) to evaluate the quality of ground water used for public supply using volatile organic compound (VOC) concentrations in ground-water samples and (2) to determine if the occurrence and distribution of low level VOCs in ground water and characteristics, such as land use, can be used to predict aquifer susceptibility to contamination from anthropogenic activities occurring at, or near, land surface. An evaluation was made of the relation between VOC occurrence and the explanatory variables: depth to the top of the uppermost well perforation, land use, relative ground-water age, high nitrate concentrations, density of leaking underground fuel tanks (LUFT), and source of recharge water. VOCs were detected in 92 percent of the wells sampled in Modesto and in 72 percent of the wells sampled in Fresno. Trihalomethanes (THM) and solvents were frequently detected in both study areas. Conversely, the gasoline components?benzene, toluene ethylbenzene, and xylenes (BTEX)?were rarely, if at all, detected, even though LUFTs were scattered throughout both study areas. The rare occurrence of BTEX compounds may be the result of their low solubility and labile nature in the subsurface environment. Samples were analyzed for 85 VOCs; 25 were detected in at least one sample. The concentrations of nearly all VOCs detected were at least an order of magnitude below action levels set by drinking water standards. Concentrations of four VOCs exceeded federal and state maximum contaminant levels (MCL): the solvent trichloroethylene (TCE) and the fumigant 1, 2-dibromo-3-chloropropane (DBCP) in Fresno, and the solvents TCE and tetrachloroethylene (PCE) in Modesto. Chloroform, which is a by product of water disinfection and a constituent used in industrial processes since the 1920s, was the most frequently detected compound, whereas the gasoline oxygenate methyl tert-butyl ether (MTBE), which has been in widespread production and use only since the 1990s, was detected in only 2 percent of the samples. Downward migration of contaminants appears to be a viable pathway of contamination in the unconfined and semi-confined aquifers underlying the Fresno and Modesto study areas. Within the individual study areas, VOCs were detected more frequently and in greater numbers in shallower wells than in deeper wells. Additionally, VOCs were detected more frequently and in greater numbers in Modesto than in Fresno. Wells sampled in Modesto were significantly shallower than the wells sampled in Fresno; the other explanatory variables examined in this report were not significantly different between the two study areas. VOCs occurred more frequently in younger ground water (water recharged after 1952) than in older ground water (water recharged prior to 1952). Additionally, wells withdrawing younger ground water had a higher number of VOCs detected per well than did wells withdrawing older ground water. Younger ground water was at or near the land surface during a period when VOCs came into widespread production and use. Therefore, wells from which younger ground water is withdrawn may be more susceptible to contamination. Of the explanatory variables examined in this study, land use was the best predictor of aquifer susceptibility in the Fresno and Modesto study areas. VOCs were detected more frequently in wells located in heavily urbanized areas. The number of VOCs detected in ground water was positively correlated to the degree of urbanization. VOCs are produced and used primarily in urban land use settings; therefore, aquifers underlying urban areas may be more susceptible to

Scientific Investigations Report↗

Hydrogeology and ground-water availability in the carbonate aquifer system of Frederick County, Virginia

The carbonate aquifer system of the northern Shenandoah Valley provides an important water supply to local communities, including Frederick County, Va., which depends on ground water as a source of water supply. The county and surrounding area are undergoing increased urbanization, and increased demands on the carbonate aquifer system are expected. A study was conducted between October 2000 and March 2004 by the U.S. Geological Survey (USGS), in cooperation with the County of Frederick, Va., to describe the hydrogeology and ground-water availability in the carbonate aquifer system underlying the county. The study area encompasses about 25 percent (105 square miles) of the county that is underlain by carbonate bedrock. The carbonate aquifer system of Frederick County is in the Shenandoah Valley region of the Valley and Ridge Physiographic Province. Approximately 10,000 feet of folded and fractured Middle Cambrian to Upper Ordovician sedimentary rocks are exposed and are overlain by Pleistocene (?) and Holocene surficial deposits. All geologic units in the study area are considered to be aquifers. The geologic units are generally unconfined, fractured-rock aquifers that are recharged by precipitation and discharge locally to streams and springs, and by evapotranspiration. Stream density in the carbonate study area is less than in the remainder of the county, which is underlain by siliciclastic rock units. Most streams flow normal to strike (from the northwest towards the southeast) across the study area. These streams are characterized by shallow incisement and are usually limited to a single stream channel. In the southern third of the study area, streams flow parallel to strike (from the northeast towards the southwest) towards the deeply intrenched Cedar Creek. Springs are commonly located at the start of flows for all streams in the carbonate study area, and spring discharges are often a large portion of the streamflow (especially during drought conditions). The general direction of ground-water flow is from the hills in the west of the study area into and across the carbonate valley. A ground-water divide may occur north of Round Hill in the vicinity of the Apple Pie Ridge fault where the North Mountain fault zone cuts out the resistant Silurian and Devonian sandstone units and results in surface drainage from the carbonate rocks toward the west and out of the carbonate valley. Estimates of effective ground-water recharge for 2001-02 range from 5.8 to 6.2 inches in the Cedar Creek Basin, with base flow accounting for between 60 and 64 percent of streamflow, and from 3.2 to 3.8 inches in the Opequon Creek Basin, with base flow accounting for between 86 and 92 percent of streamflow. Water budgets calculated for 2001, a year of below-normal precipitation (33.1 inches), and 2002, a year of above-normal precipitation (41.2 inches), include a streamflow of 9.0 inches in 2001 and 9.2 inches in 2002 in Cedar Creek. Evapotranspiration ranged from 25.9 to 30.7 inches, and ground-water storage decreased 1.8 inches in 2001 and increased 1.3 inches in 2002. Streamflow was 3.7 inches in 2001 and 2002 in Opequon Creek. Evapotranspiration ranged from 29.8 to 37.5 inches, and ground-water storage decreased 0.4 inch in 2001 and did not change in 2002.

Scientific Investigations Report↗

Antibiotic-resistant fecal bacteria, antibiotics, and mercury in surface waters of Oakland County, Michigan, 2005-2006

Water samples collected from 20 stream sites in Oakland and Macomb Counties, Mich., were analyzed to learn more about the occurrence of cephalosporin-resistant Escherichia coli ( E. coli ) and vancomycin-resistant enterococci (VRE) and the co-occurrence of antibiotics and mercury in area streams. Fecal indicator bacteria concentrations exceeded the Michigan recreational water-quality standard of 300 E. coli colony forming units (CFU) per 100 milliliters of water in 19 of 35 stream-water samples collected in Oakland County. A gene commonly associated with enterococci from humans was detected in samples from Paint Creek at Rochester and Evans Ditch at Southfield, indicating that human fecal waste is a possible source of fecal contamination at these sites. E. coli resistant to the cephalosporin antibiotics (cefoxitin and/ or ceftriaxone) were found at all sites on at least one occasion. The highest percentages of E. coli isolates resistant to cefoxitin and ceftriaxone were 71 percent (Clinton River at Auburn Hills) and 19 percent (Sashabaw Creek near Drayton Plains), respectively. Cephalosporin-resistant E. coli was detected more frequently in samples from intensively urbanized or industrialized areas than in samples from less urbanized areas. VRE were not detected in any sample collected in this study. Multiple antibiotics (azithromycin, erythromycin, ofloxacin, sulfamethoxazole, and trimethoprim) were detected in water samples from the Clinton River at Auburn Hills, and tylosin (an antibiotic used in veterinary medicine and livestock production that belongs to the macrolide group, along with erythromycin) was detected in one water sample from Paint Creek at Rochester. Concentrations of total mercury were as high as 19.8 nanograms per liter (Evans Ditch at Southfield). There was no relation among percentage of antibiotic-resistant bacteria and measured concentrations of antibiotics or mercury in the water. Genetic elements capable of exchanging multiple antibiotic-resistance genes (class I integrons) were detected in several samples, indicating that the resistance carried by these organisms may be transferable to other bacteria, including disease-causing bacteria.

Michigan↗

Historical changes to Lake Washington and route of the Lake Washington Ship Canal, King County, Washington

Lake Washington, in the midst of the greater Seattle metropolitan area of the Puget Sound region (fig. 1), is an exceptional commercial, recreational, and esthetic resource for the region . In the past 130 years, Lake Washington has been changed from a " wild " lake in a wilderness setting to a regulated lake surrounded by a growing metropolis--a transformation that provides an unusual opportunity to study changes to a lake's shoreline and hydrologic characteristics -resulting from urbanization.

Washington↗

Hazard potential of compound flooding from rainfall, storm surge, and groundwater in coastal New York and Connecticut

Compound flood events, the co-occurrence of multiple flood drivers, can result in flood hazard potential exceeding that of any single driver alone. To evaluate compound flooding in a semi-urbanized coastal area, historical records dating back to 1970 are used to study the co-occurrences of high precipitation, storm surge, and shallow groundwater conditions along the coastlines of New York and Connecticut. Joint return periods for coincident precipitation-surge events were computed using statistical dependence models and compared to the assumption of independence as a ratio, referred to here as a return period adjustment. Results indicate distinct seasonality where compound events in the area disproportionately occur in the cold season between October and April. Return period adjustments range from a factor of 1 to almost 9, demonstrating the range in precipitation-storm surge dependence across the study area. Across all 24 station triad locations, groundwater levels were elevated during times of precipitation- surge co-occurrence, reflecting the tendency for coastal storms and shallow groundwater conditions to co-occur seasonally. The result is a pseudo-trivariate compound flood hazard score and corresponding hazard map that integrates dependence between daily precipitation-surge events and overall monthly groundwater levels (as a precondition) into a relative compound hazard score. The location with the highest compound flood hazard score is on the south shore of Long Island, as well as locations across coastal Connecticut where groundwater levels compound the co-occurrence of heavy precipitation and storm surge.

Connecticut, New York↗

Assessment of general health of fishes collected at selected sites in the Great Lakes Basin In 2012

During the past decade, there has been a substantive increase in the detection of “emerging contaminants”, defined as a new substance, chemical, or metabolite in the environment; or a legacy substance with a newly expanded distribution, altered release, or a newly recognized effect (such as endocrine disruption). Emerging contaminants include substances such as biogenic hormones (human and animal), brominated flame retardants, pharmaceuticals, personal care products, plasticizers, current use pesticides, detergents, and nanoparticles. These contaminants are frequently not regulated or inadequately regulated by state or Federal water quality programs. Information about the toxicity of these substances to fish and wildlife resources is generally limited, compared to more highly regulated contaminants, and some classes have been shown to cause affects (for example feminization of male fish, immunomodulation) that are not evaluated via traditional toxicity testing protocols. As a result, these compounds may pose a substantial, but currently poorly documented threat to aquatic ecosystems. Failure to identify and understand the impacts of these emerging contaminants on fish and wildlife resources may result in deleterious impacts to Great Lakes resources that can result in adverse ecological, economic and recreational consequences. The U. S. Fish and Wildlife Service received funding through the Great Lakes Restoration Initiative (GLRI) for an Early Warning Program to detect and identify emerging contaminants and to evaluate the effects of these contaminants on fish and wildlife. The U.S. Geological Survey (WV Cooperative Fish and Wildlife Research Unit and National Fish Health Research Laboratory, Leetown Science Center) developed and implemented a biological effects monitoring protocol to assist in this program. Fish collections and measurements of biomarkers of exposure in Fall 2010 and Spring 2011 occurred at individual sites within select Areas of Concern (AOCs). They provided an assessment of the utility of the suite of biomarkers and also identified sites for more in-depth analyses. Selected areas are characterized as areas with known emerging contaminants, sensitive or listed species, areas downstream from municipal wastewater discharges or receiving waters for industrial facilities, and/or areas susceptible to agricultural or urban contamination, or harbors or ports. The results of the 2010- 2011 studies were summarized in Blazer et al. 2014 a, b, c; Braham et al. in review and Blazer et al. in review.

Great Lakes↗

Program design for San Francisco Bay Region environment and resources planning study

The "Program Design" for the San Francisco Bay Region Environment and Resources Planning Study represents a refinement, elaboration, and extension of the plans which formed the basis for the cooperative program between the Department of the Interior, Geological Survey, and the Department of Housing and Urban Development, Office of Research and Technology, formally recognized in the Letter of Agreement of October 24, 1969, and begun January 1, 1970. From the first, the study was recognized as an experimental pilot study, and new developments in the state-of-the-art in the earth sciences and in urban and regional planning were recognized as necessary. Indeed, the development of a suitable structure for such a program was considered one of the important parts of the experiment. Consequently, one of the stated goals of the Letter of Agreement was to produce a Program Design.

California↗

Water-quality assessment of the Connecticut, Housatonic, and Thames River Basins study unit: Analysis of available data on nutrients, suspended sediments, and pesticides, 1972-92

This retrospective report examines available nutrient, suspended sediment, and pesticide data in surface and ground water in the Connecticut, Housatonic and Thames Rivers Study Unit of the National Water-Quality Assessment Program. The purpose of this study is to improve the understanding of natural and anthropogenic factors affecting water quality in the study unit. Waterquality data were acquired from various sources, primarily, the U.S. Geological Survey and the U.S. Environmental Protection Agency. The report examines data for water years 1972-92, focusing on 1980-92, although it also includes additional data from as early as 1905. The study unit lies within the New England Physiographic Province and altitudes range from sea level in coastal Connecticut to 6,288 feet above sea level at Mount Washington, New Hampshire. Two major aquifer types underlie the study unit unconsolidated glacial deposits and fractured bedrock. The climate generally is temperate and humid, with four distinct seasons. Average annual precipitation ranges from 34 to 65 inches. The study unit has a population of about 4.5 million, which is most highly concentrated in southwestern Connecticut and along the south-central region of the Connecticut River Valley. Surface-water-quality data were screened to provide information about sites with adequate numbers of analyses (50) over sufficiently long periods (1980-90) to enable valid statistical analyses. In order to compare effects of different types of land use on surface-water quality, examination of data required application of several statistical and graphical techniques, including mapping, histograms, boxplots, concentration-discharge plots, trend analysis, and load estimation. Spatial and temporal analysis of surface-water-quality data indicated that, with a single exception, only stations in the Connecticut water-quality network had sufficient data collected over adequately long time periods to use in detailed analyses. Ground-water nutrient and pesticide data were compiled from several Federal and State agencies, primarily the U.S. Geological Survey, U.S. Environmental Protection Agency, and Connecticut Department of Health Services. Nutrient data were available for several thousand wells; nitrite plus nitrate as nitrogen was the most commonly reported constituent. Most wells with nutrient data are in Massachusetts and Connecticut. Relative to nutrient data in ground and surface water, pesticide data are less common. Pesticide data were available for slightly more than 200 surface-water sites and less than 500 wells; about 95 percent of the wells are completed in stratified-drift or till aquifers. Data for 81 pesticide compounds were available in various data bases. 2,4-D and silvex were the most commonly detected herbicides in surface water and dieldrin and diazinon were the most commonly detected insecticides. Most surface-water pesticide samples and detections are from bed sediment, but much of the data are not recent. Ethylene dibromide (EDB), a soil fumigant used in tobacco farming was detected in 268 wells in a 50 square-mile area of north-central Connecticut; EDB contamination also was detected in wells in Massachusetts. Atrazine, an herbicide commonly used in corn farming, commonly was detected in wells installed in tilled agricultural fields. Corn herbicides were commonly detected in the northern part of the study unit, although the sampling has been less frequent than in the southern part of the study unit. Pesticides were seldom detected in public-supply wells in Connecticut. Urban sites with relatively high population densities and high concentrations of dischargers were characterized by having the highest nutrient concentrations and loads when adjusted for differences in drainage area or population. Particularly, the Pequabuck, Naugatuck, and Quinnipiac River Basins were characterized by high nutrient concentrations median total nitrogen concentrations ranged from 3.3 to 4.2 mg/L (milligrams per liter) and median total phosphorus concentrations ranged from 0.42 to 0.8 mg/L. In contrast, the predominantly forested and low density residential land-use sites, such as Saugatuck and Salmon River Basins, were characterized by low nutrient concentrations median total nitrogen ranged from 0.50 to 0.60 mg/L and median total phosphorus concentrations ranged from 0.01 to 0.02 mg/L. Estimated total nitrogen loadings in median discharge years ranged from 940 kilograms per square mile at the Salmon River near East Hampton, Conn., to 5,800 kilograms per square mile at the Naugatuck River at Beacon Falls, Conn. Water quality, in terms of nutrient concentrations and areally adjusted loadings, for sites with large drainage basins integrating a wide variety of land-use categories fell between the extremes of the urban and forested sites total nitrogen was 1,400 kilograms per square mile per year at the Connecticut River at Thompsonville, Conn. Nitrate concentrations in ground water occasionally exceeded the safe drinking-water standard of 10 mg/L as nitrogen. The greatest number of detections exceeding the standard, however, were not in public-water supplies but in shallow observation wells in agricultural settings (the most frequently sampled type of well). None of the public-supply wells in Massachusetts exceeded the standard. Although nitrate concentrations for Vermont and New Hampshire generally were low, few data were available and those were seldom reported on the basis of drainage basin, making analysis difficult. Trend analysis indicated that flow-adjusted concentrations of total and dissolved phosphorus generally decreased during the period of analysis, however, total nitrogen did not change substantially. Decreases in ammonia concentrations with time were usually accompanied by increases in nitrate, suggesting improvements in sewage treatment. The lack of adequate data from more or less exclusively agricultural areas points to the need for further study of the effects of fanning on surface-water quality in the study unit. Furthermore, additional information is needed on the rates, transformations, and movements of nutrients and other materials through and between the aquatic and terrestrial components of the study unit.

Connecticut, Massachusetts, New Hampshire, Quebec,↗

Rainfall-runoff characteristics and effects of increased urban density on streamflow and infiltration in the eastern part of the San Jacinto River basin, Riverside County, California

To better understand the rainfall-runoff characteristics of the eastern part of the San Jacinto River Basin and to estimate the effects of increased urbanization on streamflow, channel infiltration, and land-surface infiltration, a long-term (1950?98) time series of monthly flows in and out of the channels and land surfaces were simulated using the Hydrologic Simulation Program- FORTRAN (HSPF) rainfall-runoff model. Channel and land-surface infiltration includes rainfall or runoff that infiltrates past the zone of evapotranspiration and may become ground-water recharge. The study area encompasses about 256 square miles of the San Jacinto River drainage basin in Riverside County, California. Daily streamflow (for periods with available data between 1950 and 1998), and daily rainfall and evaporation (1950?98) data; monthly reservoir storage data (1961?98); and estimated mean annual reservoir inflow data (for 1974 conditions) were used to calibrate the rainfall-runoff model. Measured and simulated mean annual streamflows for the San Jacinto River near San Jacinto streamflow-gaging station (North-South Fork subbasin) for 1950?91 and 1997?98 were 14,000 and 14,200 acre-feet, respectively, a difference of 1.4 percent. The standard error of the mean for measured and simulated annual streamflow in the North-South Fork subbasin was 3,520 and 3,160 acre-feet, respectively. Measured and simulated mean annual streamflows for the Bautista Creek streamflow-gaging station (Bautista Creek subbasin) for 1950?98 were 980 acre-feet and 991 acre-feet, respectively, a difference of 1.1 percent. The standard error of the mean for measured and simulated annual streamflow in the Bautista Creek subbasin was 299 and 217 acre-feet, respectively. Measured and simulated annual streamflows for the San Jacinto River above State Street near San Jacinto streamflow-gaging station (Poppet subbasin) for 1998 were 23,400 and 23,500 acre-feet, respectively, a difference of 0.4 percent. The simulated mean annual streamflow for the State Street gaging station at the outlet of the study basin and the simulated mean annual basin infiltration (combined infiltration from all the channels and land surfaces) were 8,720 and 41,600 acre-feet, respectively, for water years 1950-98. Simulated annual streamflow at the State Street gaging station ranged from 16.8 acre-feet in water year 1961 to 70,400 acre-feet in water year 1993, and simulated basin infiltration ranged from 2,770 acre-feet in water year 1961 to 149,000 acre-feet in water year 1983.The effects of increased urbanization on the hydrology of the study basin were evaluated by increasing the size of the effective impervious and non-effective impervious urban areas simulated in the calibrated rainfall-runoff model by 50 and 100 percent, respectively. The rainfall-runoff model simulated a long-term time series of monthly flows in and out of the channels and land surfaces using daily rainfall and potential evaporation data for water years 1950?98. Increasing the effective impervious and non-effective impervious urban areas by 100 percent resulted in a 5-percent increase in simulated mean annual streamflow at the State Street gaging station, and a 2.2-percent increase in simulated basin infiltration. Results of a frequency analysis of the simulated annual streamflow at the State Street gaging station showed that when effective impervious and non-effective impervious areas were increased 100 percent, simulated annual streamflow increased about 100 percent for low-flow conditions and was unchanged for high-flow conditions. The simulated increase in streamflow at the State Street gaging station potentially could infiltrate along the stream channel further downstream, outside of the model area.

Water-Resources Investigations Report↗

Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows . This study explored a mass-balance field-based computation of consumptive use in a residential setting at the scale of a sanitary sewer service area (sewershed). In addition, the feasibility (cost and difficulty) and relative uncertainties (accuracies) associated with applying the approach at this scale were evaluated. The study was conducted during 2011–13 within a 3.5-square mile (mi 2 ) sewershed confined to a predominantly residential area of Elk Grove Village, Illinois. Following background evaluation of the geohydrologic setting, sewershed infrastructure, and possible components of supplied and returned water, the identified primary components were 1. public water deliveries by the Elk Grove Village Department of Public Works, 2. self-served groundwater withdrawals in an included unincorporated neighborhood with public sanitary sewer service, 3. return flows to the sanitary sewer system, and 4. direct return of water discharged from swimming pools to Salt Creek. Water volumes principally were reported for deliveries, measured for sanitary sewer returns by using an acoustic Doppler current-velocity meter, and estimated for domestic withdrawals and swimming pool discharges to storm sewers. All water volumes required some degree of estimation. Observation wells were installed adjacent to sewer pipelines (lines) to determine the depth of the water table relative to that of the sewer lines and to collect water samples for detection of optical brighteners, as they are routinely discharged as clotheswashing waste to sanitary sewers. These data provided qualitative information on gains (inflow and infiltration) and losses (exfiltration) of sewer flow by pipe leakage, which might otherwise not be considered in the sewer flow return measurements. Hydrographs of sewer flow also were evaluated to identify and estimate storm-associated inputs to sewer flow. The volume of sanitary sewer return flow (778 million gallons per year [Mgal/yr]) was determined to substantially exceed the volume of supplied water (566 Mgal/yr), thus, for this study setting, voiding the utility of the applied mass-balance approach for estimating consumptive water use. Mass-balance components, including sanitary sewer flow and supplied-water use, were estimated within reasonable limits of uncertainty. Evidence of a water table that is typically shallower than the area’s sewer lines, yet is sometimes depressed near more deeply buried sewer lines, suggests groundwater infiltration into the sewers contributes to the excess volume of return flow. Technical obstacles and project resources precluded accurate quantification of infiltration volumes and other gains and losses to sanitary sewer flow. As estimated from various simplified methods, a minimum of 26 percent of return flow measured in the sanitary sewer represented groundwater infiltration and stormwater inflow; separately, about 2 percent of return flow was estimated as inflow. On the basis of the alternative winter base-rate method, consumptive use in the sewershed was estimated as 13 percent, which compares favorably with that used by the State of Illinois for Lake Michigan allocation accounting (10 percent) and other States and Canadian Provinces in the Great Lakes region (generally 10-15 percent). The study also provided other findings considered useful to studies of water use and to performance evaluation of sanitary sewer infrastructure. In urban residential settings, the comparatively small volumes of nonpublic sources of water (self-supplied) and direct (nonsanitary) return flow potentially can be ignored in the estimation of consumptive use. An acoustic Doppler current-velocity meter can be used in sanitary sewers to accurately measure discharge and reasonably estimate storm-associated inflows. Hourly to daily patterns of water use can be readily identified and quantified in the return flow record for the sanitary sewers. Relative volumes of infiltration gains (and exfiltration losses) can be substantial, even in sewer systems of communities making significant investments in system upgrades to limit sewer line leakage. Monitoring of optical brighteners in groundwater (and potentially in sanitary sewer flow) can provide a useful means of identifying probable leakage from (and to) sewer lines. Accurate quantification of gains and losses to sanitary sewer flow at the sewershed scale will require additional research effort and technical advances. Under ideal conditions, accurate quantification of consumptive use at the sewershed scale by the described mass-balance approach might be possible. Under most prevailing conditions, quantification likely would be more costly and time consuming than that of the present study, given the freely contributed technical support of the host community and relatively appropriate conditions of the study area. Essentials to quantification of consumptive use are a fully cooperative community, storm and sanitary sewers that are separate, and newer sewer infrastructure and (or) a robust program for limiting infiltration, exfiltration, and inflow.

Illinois↗

Methods, quality assurance, and data for assessing atmospheric deposition of pesticides in the Central Valley of California

The U.S. Geological Survey monitored atmospheric deposition of pesticides in the Central Valley of California during two studies in 2001 and 2002–04. The 2001 study sampled wet deposition (rain) and storm-drain runoff in the Modesto, California, area during the orchard dormant-spray season to examine the contribution of pesticide concentrations to storm runoff from rainfall. In the 2002–04 study, the number and extent of collection sites in the Central Valley were increased to determine the areal distribution of organophosphate insecticides and other pesticides, and also five more sample types were collected. These were dry deposition, bulk deposition, and three sample types collected from a soil box: aqueous phase in runoff, suspended sediment in runoff, and surficial-soil samples. This report provides concentration data and describes methods and quality assurance of sample collection and laboratory analysis for pesticide compounds in all samples collected from 16 sites. Each sample was analyzed for 41 currently used pesticides and 23 pesticide degradates, including oxygen analogs (oxons) of 9 organophosphate insecticides. Analytical results are presented by sample type and study period. The median concentrations of both chloryprifos and diazinon sampled at four urban (0.067 micrograms per liter [μg/L] and 0.515 μg/L, respectively) and four agricultural sites (0.079 μg/L and 0.583 μg/L, respectively) during a January 2001 storm event in and around Modesto, Calif., were nearly identical, indicating that the overall atmospheric burden in the region appeared to be fairly similar during the sampling event. Comparisons of median concentrations in the rainfall to those in the McHenry storm-drain runoff showed that, for some compounds, rainfall contributed a substantial percentage of the concentration in the runoff; for other compounds, the concentrations in rainfall were much greater than in the runoff. For example, diazinon concentrations in rainfall were about 70 percent of the diazinon concentration in the runoff, whereas the chlorpyrifos concentration in the rain was 1.8 times greater than in the runoff. The more water-soluble pesticides—carbaryl, metolachlor, napropamide, and simazine—followed the same pattern as diazinon and had lower concentrations in rain compared to runoff. Similar to chlorpyrifos,compounds with low water solubilities and higher soil-organic carbon partition coefficients, including dacthal, pendimethalin, and trifluralin, were found to have higher concentrations in rain than in runoff water and were presumed to partition to the suspended sediments and organic matter on the ground. During the 2002–04 study period, the herbicide dacthal had the highest detection frequencies for all sample types collected from the Central Valley sites (67–100 percent). The most frequently detected compounds in the wet-deposition samples were dacthal, diazinon, chlorpyrifos, and simazine (greater than 90 percent). The median wet-deposition amounts for these compounds were 0.044 micrograms per square meter per day (μg/m 2 /day), 0.209 μg/m 2 /day, 0.079 μg/m 2 /day, and 0.172 μg/m 2 /day, respectively. For the dry-deposition samples, detection frequencies were greater than 73 percent for the compounds dacthal, metolachor, and chlorpyrifos, and median deposition amounts were an order of magnitude less than for wet deposition. The differences between wet deposition and dry deposition appeared to be closely related to the Henry’s Law (H) constant of each compound, although the mass deposited by dry deposition takes place over a much longer time frame. Pesticides detected in rainfall usually were detected in the aqueous phase of the soil-box runoff water, and the runoff concentrations were generally similar to those in the rainfall. For compounds detected in the aqueous phase and suspended-sediment samples of soil-box runoff, concentrations of pesticides in the aqueous phase generally were detected in low concentrations and had few corresponding detections in the suspended- sediment samples. Dacthal, diazinon, chlorpyrifos, and simazine were the most frequently detected pesticides (greater than 83 percent) in the aqueous-phase samples, with median concentrations of 0.010 μg/L, 0.045 μg/L, 0.016 μg/L, and 0.077 μg/L, respectively. Simazine was the most frequently detected compound in the suspended-sediment samples (69 percent), with a median concentration of 0.232 μg/L. Results for compounds detected in the surficial-soil samples collected throughout the study period showed that there was an increase in concentration for some compounds, indicating atmospheric deposition of these compounds onto the soil-box surface. In the San Joaquin Valley, the compounds chlorpyrifos, dacthal, and iprodione were detected at higher concentrations (between 1.4 and 2 times greater) than were found in the background samples collected from the San Joaquin Valley soil-box sites. In the Sacramento Valley, the compounds chlorpyrifos, dacthal, iprodione, parathionmethyl, and its oxygen analog, paraoxon-methyl, were detected in samples collected during the study period in low concentrations, but were not detected in the background concentration of the Sacramento Valley soil mix.

California↗

Water-quality assessment of the Central Arizona Basins, Arizona and northern Mexico – Environmental setting and overview of water quality

The Central Arizona Basins study area in central and southern Arizona and northern Mexico is one of 60 study units that are part of the U.S. Geological Survey's National Water-Quality Assessment program. The purpose of this report is to describe the physical, chemical, and environmental characteristics that may affect water quality in the Central Arizona Basins study area and present an overview of water quality. Covering 34,700 square miles, the study area is characterized by generally north to northwestward-trending mountain ranges separated by broad, gently sloping alluvial valleys. Most of the perennial rivers and streams are in the northern part of the study area. Rivers and streams in the south are predominantly intermittent or ephemeral and flow in response to precipitation such as summer thunderstorms. Effluent-dependent streams do provide perennial flow in some reaches. The major aquifers in the study area are in the basin-fill deposits that may be as much as 12,000 feet thick. The 1990 population in the study area was about 3.45 million, and about 61 percent of the total was in Maricopa County (Phoenix and surrounding cities). Extensive population growth over the past decade has resulted in a twofold increase in urban land areas and increased municipal water use; however, agriculture remains the major water use. Seventy-three percent of all water with drawn in the study area during 1990 was used for agricultural purposes. The largest rivers in the study area-the Gila, Salt, and Verde-are perennial near their headwaters but become intermittent downstream because of impoundments and artificial diversions. As a result, the Central Arizona Basins study area is unique compared to less arid basins because the mean surface-water outflow is only 528 cubic feet per second from a total drainage area of 49,650 square miles. Peak flows in the northern part of the study area are the result of snowmelt runoff; whereas, summer thunderstorms account for the peak flows in the southern part. Ground water is the primary water supply in most of Arizona and the only source of drinking water used by communities in the southern half of the study area. Years of overpumping have caused water tables in basin fill to drop below once-perennial streams leaving streambeds dry, water too deep to pump economically, pumping of poorer quality water with depth, and earth fissures resulting from subsidence after dewatering of sediments. Natural processes-such as leaching of trace elements and major ions from geologic formations-and human activities-such as mining, agriculture, and urban development-have major effects on the quality of surface-water and ground-water resources in the Central Arizona Basins study area. Surface-water quality standards in Arizona are based on the designated use of the water such as full or partial body contact, fish consumption, aquatic and wildlife uses, and agriculture. Maintaining the biological integrity (health) of surface waters in Arizona is an important part of ensuring that these waters are suitable for designated uses. Important water-quality issues for surface water that are somewhat unique to Arizona include: (1) streamflows and riparian environments sustained by effluent from municipal wastewater-treatment plants that contains high concentrations of nutrients, potentially toxic trace elements and organic compounds, and fecal bacteria; (2) industrial, mining, agricultural, and municipal sources of contamination from Mexico; and (3) unpredictable high flows from major summer thunder storms causing stream-channel changes; high suspended-sediment concentrations and loads; sewage overflows; and breaching, erosion, and washout of landfills and mining operations. The quality of water in aquifers that are protected for drinking- water use is subject to standards that are in most cases equal to or more stringent than the primary drinking-water regulations of the U.S. Environmental Protection Agency. The general che

Arizona↗

Magnitude of flood flows for selected annual exceedance probabilities in Rhode Island through 2010

Heavy persistent rains from late February through March 2010 caused severe widespread flooding in Rhode Island that set or nearly set record flows and water levels at many long-term streamgages in the State. In response, the U.S. Geological Survey, in partnership with the Federal Emergency Management Agency, conducted a study to update estimates of flood magnitudes at streamgages and regional equations for estimating flood flows at ungaged locations. This report provides information needed for flood plain management, transportation infrastructure design, flood insurance studies, and other purposes that can help minimize future flood damages and risks. The magnitudes of floods were determined from the annual peak flows at 43 streamgages in Rhode Island (20 sites), Connecticut (14 sites), and Massachusetts (9 sites) using the standard Bulletin 17B log-Pearson type III method and a modification of this method called the expected moments algorithm (EMA) for 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probability (AEP) floods. Annual-peak flows were analyzed for the period of record through the 2010 water year; however, records were extended at 23 streamgages using the maintenance of variance extension (MOVE) procedure to best represent the longest period possible for determining the generalized skew and flood magnitudes. Generalized least square regression equations were developed from the flood quantiles computed at 41 streamgages (2 streamgages in Rhode Island with reported flood quantiles were not used in the regional regression because of regulation or redundancy) and their respective basin characteristics to estimate magnitude of floods at ungaged sites. Of 55 basin characteristics evaluated as potential explanatory variables, 3 were statistically significant—drainage area, stream density, and basin storage. The pseudo-coefficient of determination (pseudo- R2 ) indicates these three explanatory variables explain 95 to 96 percent of the variance in the flood magnitudes from 20- to 0.2-percent AEPs. Estimates of uncertainty of the at-site and regression flood magnitudes are provided and were combined with their respective estimated flood quantiles to improve estimates of flood flows at streamgages. This region has a long history of urban development, which is considered to have an important effect on flood flows. This study includes basins that have an impervious area ranging from 0.5 to 37 percent. Although imperviousness provided some explanatory power in the regression, it was not statistically significant at the 95-percent confidence level for any of the AEPs examined. Influence of urbanization on flood flows indicates a complex interaction with other characteristics that confounds a statistical explanation of its effects. Standard methods for calculating magnitude of floods for given AEP are based on the assumption of stationarity, that is, the annual peak flows exhibit no significant trend over time. A subset of 16 streamgages with 70 or more years of unregulated systematic record indicates all but 4 streamgages have a statistically significant positive trend at the 95-percent confidence level; three of these are statistically significant at about the 90-percent confidence level or above. If the trend continues linearly in time, the estimated magnitude of floods for any AEP, on average, will increase by 6, 13, and 21 percent in 10, 20, and 30 years' time, respectively. In 2010, new peaks of record were set at 18 of the 21 active streamgages in Rhode Island. The updated flood frequency analysis indicates the peaks at these streamgages ranged from 2- to 0.2-percent AEP. Many streamgages in the State peaked at a 0.5- and 0.2-percent AEP, except for streamgages in the Blackstone River Basin, which peaked from a 4- to 2-percent AEP.

Rhode Island↗

The quality of our Nation's waters: factors affecting public-supply-well vulnerability to contamination: understanding observed water quality and anticipating future water quality

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the vulnerability of water from public-supply wells to contamination (referred to hereafter as “public-supply-well vulnerability”). The study was designed as a follow-up to earlier NAWQA studies that found mixtures of contaminants at low concentrations in groundwater near the water table in urban areas across the Nation and, less frequently, in deeper groundwater typically used for public supply. Beside the factors affecting public-supply-well vulnerability to contamination, this circular describes measures that can be used to determine which factor (or factors) plays a dominant role at an individual public-supply well. Case-study examples are used throughout to show how such information can be used to improve water quality. In general, the vulnerability of the water from public-supply wells to contamination is a function of contaminant input within the area that contributes water to a well, the mobility and persistence of a contaminant once released to the groundwater, and the ease of groundwater and contaminant movement from the point of recharge to the open interval of a well. The following measures described in this circular are particularly useful for indicating which contaminants in an aquifer might reach an individual public-supply well and when, how, and at what concentration they might arrive: * Sources of recharge—Information on the sources of recharge for a well provides insight into contaminants that might enter the aquifer with the recharge water and potentially reach the well. * Geochemical conditions—Information on the geochemical conditions encountered by groundwater traveling to a well provides insight into contaminants that might persist in the water all the way to the well. * Groundwater-age mixtures—Information on the ages of the different waters that mix in a well provides insight into the time lag between contaminant input at the water table and contaminant arrival at the well. It also provides insight into the potential for in-well dilution of contaminated water by unaffected groundwater of a different age that simultaneously enters the well. Preferential flow pathways—pathways that provide little resistance to flow—can influence how all other factors affect public-supply-well vulnerability to contamination. For example, preferential flow pathways can influence whether a contaminant source is physically linked to a well, whether contaminant concentrations are substantially altered before contaminated groundwater reaches a well, and whether contaminated groundwater can arrive at a well within a timeframe of concern to the well owner. Methods for recognizing the influence of preferential flow pathways on the quality of water from a public-supply well are presented in this circular and can provide opportunities to prevent or mitigate the deterioration of a water supply. Knowing what water-quality variables to measure, what spatial and temporal scales on which to measure them, and how to interpret the resulting data makes it possible for samples from public-supply wells to provide a broad window into a well’s past and present water quality—and possibly future water quality. Such insight can enable resource managers to prioritize actions for sustaining a high-quality groundwater source of drinking water.

Circular↗

Hydrology, Water Quality, and Aquatic Communities of Selected Springs in the St. Johns River Water Management District, Florida

Hydrologic, physicochemical, and aquatic community data were collected and compiled by the U.S. Geological Survey for selected springs within the St. Johns River Water Management District from January 2004 to October 2007. Nine springs were included in this study: Alexander, Apopka, Bugg, De Leon, Gemini, Green, Rock, Silver Glen, and Wekiwa. Urban lands increased in Alexander, Apopka, De Leon, Gemini, Green, and Wekiwa springsheds between 1973 and 2004, accompanied by a loss of forested and/or agricultural lands in most springsheds. Forested cover increased and open surface waters and wetlands decreased in the Bugg and Rock springsheds. Although rainfall did not change significantly over time in each springshed, spring discharge decreased significantly in De Leon, Fern Hammock, Rock, Silver, and Wekiwa Springs. Nitrate concentrations increased significantly with time in Apopka, Fern Hammock, Gemini Springs run, and Juniper Springs, and decreased significantly in Alexander Spring, Bugg Spring run, Rock Springs, and Wekiwa Springs. Phosphorus increased significantly with time in Juniper Springs and decreased significantly in Apopka, De Leon, Rock, Silver Glen, and Wekiwa Springs. Benthic macroinvertebrate communities ranged from relatively low diversity assemblages (Green Spring) to assemblages with high taxonomic richness, diversity, and dominance (Rock and De Leon Springs). Shannon-Wiener diversity index averages among samples pooled by spring were lowest for Apopka Spring and greatest for Rock, Bugg, and Silver Glen Springs. Mean Stream Condition Index for pooled samples per spring was lowest for De Leon and Gemini Springs and highest for Rock and Wekiwa Springs. Mean percentages of very tolerant taxa were lowest for Alexander Spring and highest for Bugg and Green Springs. Fish community richness was lowest for Green Spring, and greatest for Alexander Spring run and Silver Glen Springs. Forty five fish species representing 35 genera and 23 families were collected or observed from all springs in this study. Samples were dominated by centrarchids, cyprinids, fundulids, atherinopsids, and poeciliids.

Scientific Investigations Report↗

Water quality in the Anacostia River, Maryland and Rock Creek, Washington, D.C.: Continuous and discrete monitoring with simulations to estimate concentrations and yields of nutrients, suspended sediment, and bacteria

Concentrations and loading estimates for nutrients, suspended sediment, and E. coli bacteria were summarized for three water-quality monitoring stations on the Anacostia River in Maryland and one station on Rock Creek in Washington, D.C. Both streams are tributaries to the Potomac River in the Washington, D.C. metropolitan area and contribute to the Chesapeake Bay estuary. Two stations on the Anacostia River, Northeast Branch at Riverdale, Maryland and Northwest Branch near Hyattsville, Maryland, have been monitored for water quality during the study period from 2003 to 2011 and are located near the shift from nontidal to tidal conditions near Bladensburg, Maryland. A station on Paint Branch is nested above the station on the Northeast Branch Anacostia River, and has slightly less developed land cover than the Northeast and Northwest Branch stations. The Rock Creek station is located in Rock Creek Park, but the land cover in the watershed surrounding the park is urbanized. Stepwise log-linear regression models were developed to estimate the concentrations of suspended sediment, total nitrogen, total phosphorus, and E. coli bacteria from continuous field monitors. Turbidity was the strongest predictor variable for all water-quality parameters. For bacteria, water temperature improved the models enough to be included as a second predictor variable due to the strong dependence of stream metabolism on temperature. Coefficients of determination (R 2 ) for the models were highest for log concentrations of suspended sediment (0.9) and total phosphorus (0.8 to 0.9), followed by E. coli bacteria (0.75 to 0.8), and total nitrogen (0.6). Water-quality data provided baselines for conditions prior to accelerated implementation of multiple stormwater controls in the watersheds. Counties are currently in the process of enhancing stormwater controls in both watersheds. Annual yields were estimated for suspended sediment, total nitrogen, total phosphorus, and E. coli bacteria using the U.S. Geological Survey model LOADEST with hourly time steps of turbidity, flow, and time. Yields of all four parameters were within ranges found in other urbanized watersheds in Chesapeake Bay. Annual yields for all four watersheds over the period of study were estimated for suspended sediment (65,500 – 166,000 kilograms per year per square kilometer; kg/yr/km 2 ), total nitrogen (465 - 911 kg/yr/km 2 ), total phosphorus (36 - 113 kg/yr/km 2 ), and E. coli bacteria (6.0 – 38 x 10 12 colony forming units/yr/km 2 ). The length of record was not sufficient to determine trends for any of the water-quality parameters; within confidence intervals of the models, results were similar to loads determined by previous studies for the Northeast and Northwest Branch stations of the Anacostia River.

Maryl↗

Temporal and spatial variability of water quality in the San Antonio segment of the Edwards aquifer recharge zone, Texas, with an emphasis on periods of groundwater recharge, September 2017–July 2019

Ongoing urbanization on the Edwards aquifer recharge zone in the greater San Antonio area raises concern about the potential adverse effects on the public water supply from development. To address this concern, the U.S. Geological Survey, in cooperation with the City of San Antonio, studied patterns of temporal and spatial changes in water quality at selected surface-water and groundwater sites in the Edwards aquifer recharge zone, with an emphasis on changes during periods of groundwater recharge. Water-quality characteristics were continuously monitored and discrete water samples were collected at two sets of paired surface-water (stream) and groundwater (well) sites during a 2-year period (2017–19) that included relatively dry conditions and a large recharge event in September 2018 when as much as 16 inches of rain fell in parts of the study area. Continuous monitoring of water-level altitude, specific conductance, and concentrations of nitrate in two wells completed in the Edwards aquifer provided high-resolution data showing detailed changes in water quality across a broad range of hydrologic conditions. Water levels in the wells responded rapidly (within hours to days) to recharge from both small and large rainfall and runoff events; changes in groundwater quality as a consequence of the influx of surface-derived recharge were indicated by changes in values of the monitored characteristics. A broad range in measured values of the stable isotopes of water expressed as delta deuterium and delta oxygen-18 in the water samples collected from two streams (Salado and West Elm Creeks), in comparison to the tight clustering of the values of these isotopes in groundwater samples, indicates that source waters (surface waters) of widely varying chemical characteristics become homogenized within the aquifer system. Concentrations of major ions, trace ions, and nutrient concentrations in stormwater runoff indicate a combination of land-derived and rainfall-derived constituents. The distribution of concentrations of nitrogen species (nitrite, nitrate, and nitrogen in ammonia) among sampling sites transitions from a more variable distribution in stormwater runoff to a more uniform distribution in groundwater in which the dominant form is nitrate. Differences in nitrate isotopic composition and concentration in groundwater across the study area are likely controlled by the relative contributions of natural and anthropogenic nitrogen (with the anthropogenic nitrogen component including a wastewater source) and by the process of nitrification. Among all measured constituents, pesticides detected in discrete stormwater-runoff samples provided the clearest indication that urbanization was adversely affecting water quality; specifically, the more urbanized surface-water site had a greater number of detections and greater variety of detected pesticides. Though temporal variability in the numbers and types of pesticides was evident, the overall proportion of pesticides was dominated by triazine herbicides including atrazine, atrazine degradates, and simazine. The observed hydrologic responses to rainfall and corresponding changes in water quality in wells are thought to result from the direct hydrologic connectivity of surface water and unconfined groundwater; however, patterns of groundwater-quality change indicate mixing from multiple sources such as ambient groundwater, recent surface-derived recharge, and possibly inflow from other aquifers. Therefore, understanding the connection between urbanization and groundwater quality cannot be inferred from the input of stormwater runoff alone as changes related to local and regional hydrologic conditions also need to be considered. It should be noted that a single study comparing the results from two site pairs is not able to support definitive conclusions about the full effect of urbanization on surface water/groundwater quality; however, this study does provide useful insights about the spatial and temporal variability of both stormwater runoff and unconfined groundwater that are consistent with expectations based on the current conceptual model that depicts the Edwards aquifer surface-water/groundwater system as a single water resource.

Texas↗