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Mountain goat declines in a protected, interior, native population

A shifting climate poses threats to alpine-adapted species including mountain goats. We used long-term (12 years) citizen science monitoring data and Bayesian N-mixture modeling to estimate population trends and drivers of population metrics among mountain goats in Glacier National Park (GNP). Median goats per site ( n = 37 sites) declined by 45% (95% credible interval [CRI] = 32%, 57%) from 77.8 (95% CRI = 64.4, 95.1) in 2008 to 42.3 (95% CRI = 34.3, 52.2) in 2019, with consistent declines from 2008 until 2015, when the number of estimated goats stabilized. The decline exceeds IUCN criteria for classifying a population as vulnerable, >30% declines over only two generations. Across years, relatively few goats occupied northwestern GNP. Goat numbers declined the most at northeastern sites, trended toward decline in most southern sites, and increased at only two west-central sites. The proportion of permanent snow and glaciers, the presence of natural mineral licks, and habituation strongly increased the initial abundance of goats in the area. Weather variables had the greatest influence on population growth rates, particularly precipitation between May 15 and June 15 of the previous summer, the neonatal period. Lower growth occurred with less snow water equivalent and lower mean winter temperature, early summer temperature, and early summer precipitation. Projected reductions of permanent snow, increasing spring and summer temperatures, and insufficient and variable spring precipitation raise concerns for the future of native goats in this region. Our analyses reveal ways to improve detection rates of goats during surveys, which is important for optimizing the precision of estimates and the power to detect future trends. Detection increased with goat habituation, retention of observers with experience, use of binoculars, and conducting surveys at lower temperatures and earlier dates. Improving detection will be particularly important given the lower number of goats currently observed in the park. Research to estimate park-wide population size, evaluate genetic structure and diversity, assess changing habitat, human recreation levels and forage, and forward-project climate effects on persistence will be crucial to understanding the context of these results and conserving this iconic, metapopulation at the southern edge of the distribution of native mountain goats.

Montana

Assessment of long-term changes in surface-water extent within Klamath Marsh, south-central Oregon, 1985–2021

The annual maximum extent of surface water in Klamath Marsh has naturally fluctuated in response to periods of wet and dry conditions in the surrounding basin. Field observations during the 2010s indicate that the annual maximum extent of surface water has been declining and the marsh is not responding to hydrologic inputs as it had historically. This report describes the results of a hydrologic evaluation of Klamath Marsh to characterize and understand multi-year declines in the surface-water extent and increased intermittency of streamflow exiting the marsh. Landsat imagery collected during 1985–2021 was processed to create a time series of annual maximum surface-water extent to assess changes in surface-water inundation within the marsh. A 50-percent decrease in the mean surface area of annual total open-water extent (TOWE) during the latter half of the study period (2003–21) compared to the first half (1985–2003) was observed in this 37-year time-series dataset. The change in open-water extent was offset by a corresponding increase in dry land in the marsh. Time series of streamflow, groundwater level, total annual precipitation, annual mean temperature, and anthropogenic water use and water management were compiled and evaluated to improve understanding of the factors affecting TOWE. Statistically significant downward trends in the regional groundwater table and streamflow into and out of the marsh were identified as well as statistically significant upward trends in annual mean temperature. Statistically significant correlations among TOWE, streamflow, and groundwater level also were identified. The decreasing trends could not be attributed to changes in total annual precipitation or changing anthropogenic groundwater use within the study area. Declines in the open-water extent of Klamath Marsh since 2000 principally are due to a decoupling of the groundwater and surface-water system beneath the marsh because of regional declines in groundwater level. Regional increases in air temperature and the reestablishment of more than 55,000 acres of forested land within the study area have likely contributed to increasing evapotranspiration, leaving less water available for groundwater recharge and stream base flow and resulting in basin-wide declines in streamflow and groundwater levels.

Oregon

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Geophysical constraints on continental rejuvenation in central China: Implications for outward growth of the Tibetan Plateau

Continental rejuvenation results from the tectonic reactivation of crustal structures and lithospheric reworking by mantle flow. Geochemical observations and field mapping have traditionally provided the primary evidence for the secular evolution of crustal composition and tectonic processes during continental rejuvenation. Nonetheless, the impact of continental rejuvenation on the observed present-day strain rate and orogenic-scale lithospheric structure has not been well constrained. The pre-existing E-W–trending Central China Orogenic Belt has been overprinted by the N-S–trending Central Longitudinal Seismic Belt and constitutes the intracontinental West Qinling Syntaxis in central China, where the tectonic setting changes eastward from contraction to extension. Combining updated global positioning system data and high-resolution crustal seismic tomography, we reveal a modern continental rejuvenation process within the West Qinling Syntaxis in central China. The northward extrusion of the Tibetan Plateau's weak lithospheric layer (middle-lower crust and lithospheric mantle) of southwestern China relative to the rigid Sichuan Basin/Ordos Block of the eastern West Qinling Syntaxis results in regional dextral shearing that shapes the Central Longitudinal Seismic Belt and defines the eastern Tibetan Plateau margin. The pre-existing E-W–trending Central China Orogenic Belt has been preserved above the brittle-ductile transition zone, and the northward movement of the deep lithospheric layer drives the deformation of the upper crust in the West Qinling Syntaxis. Our results, along with previous studies, suggest the presence of an intracontinental lithospheric interchange structure in central China. The continental rejuvenation of the West Qinling Syntaxis results from a combination of fault reactivation in the upper crust (Stage I, Eocene–Oligocene) and reworking of the deep lithosphere (Stage II, middle–late Miocene) related to the plateau-wide shift in stress accommodation ultimately driven by the redistribution of mass outward from the central Tibetan Plateau. At present, the transition zone between the high- and low-velocity anomalies along the Central Longitudinal Seismic Belt not only shapes the landscape boundary but controls the size and recurrence interval of earthquakes within the West Qinling Syntaxis in central China.

GSA Bulletin

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Estimating groundwater level records using MOVE.1 and computing monthly percentiles from estimated groundwater records in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed record extensions on groundwater levels at select wells using the Maintenance of Variance Extension type 1 (MOVE.1) method. The groundwater levels estimated from these record extensions were used to compute monthly percentiles to improve future determinations of a groundwater index. In Massachusetts, 27 of 29 short-record study wells with continuous groundwater levels between 0.8 and 8.1 years were suitable for record extensions; 37 long-record index wells were used to extend the groundwater level records at the study wells. The index well selected to pair with a study well was chosen based on Pearson correlation coefficient values; cross-correlation between the two wells; geologic and topographic similarity; and smallest distance spanning the wells. Each study well and its corresponding index well have 1 or more years of concurrent, overlapping data; a Pearson correlation coefficient that exceeded a threshold value of 0.8; and a similar aquifer type and hydrologic characteristics. Of the 29 study wells, 2 showed poor correlations with all index wells and were not considered for record extensions. Performance metrics used to assess the accuracy of the MOVE.1 models indicated that most models provided reasonable estimates of groundwater levels. Root mean square error values ranged from 0.097 to 2.292 feet, with a median of 0.536 foot. Nash-Sutcliffe efficiency coefficient values ranged from 0.623 to 0.996, with a median value of 0.759. Generally, study wells in close geographical proximity to their index well resulted in stronger model performance. The average length of groundwater level records was extended by 14.1 years to a new average of 18.1 years. The estimated groundwater level records from the MOVE.1 models resulted in an increase in the range of highest and lowest groundwater levels at 23 of 27 wells. The increase in range of groundwater levels was between 0.08 to 7.95 feet. Monthly percentiles for State drought indices were computed from the estimated MOVE.1 records and observed records through December 31, 2021. Percentiles computed from estimated records show an average groundwater level about 1.0 foot lower than observed data at the 2d percentile and 0.1 foot lower at the 30th percentile.

Massachusetts

Geoelectric evidence for a wide spatial footprint of active extension in central Colorado

Three-dimensional magnetotelluric (MT) imaging in central Colorado reveals a set of north-striking high-conductivity tracks at lower-crustal (50–20 km) depths, with conductive finger-like structures rising off these tracks into the middle crust (20–5 km depth). We interpret these features to represent saline aqueous fluids and partial melt that are products of active extensional tectonomagmatism. These conductors are distributed over a wider region than the narrow corridor along which Rio Grande rift structures are traditionally mapped at the surface, and they consequently demarcate regions of the lower crust where accommodation of bulk extensional strain has concentrated conductive phases. Our observations reveal limitations in existing models of Rio Grande rift activity and may reflect unrecognized spatiotemporal variations in rift system evolution globally.

Colorado

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Thermo-hydrologic processes governing supra-permafrost talik dynamics in discontinuous permafrost near Umiujaq (Québec, Canada)

Widespread supra-permafrost talik formation is currently recognized as a critical mechanism that could accelerate permafrost thaw in the Arctic (e.g., Connon et al. 2018; Farquharson et al. 2022). However, the trajectory of permafrost dynamics following talik formation may prove difficult to predict. Physically-based cryohydrogeologic models provide a powerful tool for understanding processes and factors controlling talik dynamics and, ultimately, how permafrost will respond to climate change. Such models are typically used to represent multiple non-linear processes relevant for groundwater systems in cold regions, such as coupled heat and groundwater movement, including freeze-thaw dynamics and the effects on the surface energy balance and the subsurface thermal and hydraulic properties (Lamontagne-Hallé et al. 2020). Though cryohydrogeologic modeling advances have been made in simulating talik dynamics, few applications have been tested against robust long-term hydrometeorological and subsurface observations.

Quebec

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

Decadal shifts in groundwater age detected by environmental tracers across California, USA

Groundwater age offers important insight into recharge, storage, and contamination risk. Although models predict age changes can be driven by pumping and climate variability, direct observational evidence remains limited. Here, we analyzed paired environmental tracer suites (tritium, carbon-14, and tritiogenic helium-3) collected a decade apart from 268 wells across California to assess the prevalence of groundwater age transience. Travel-time distribution models and statistical tests indicated age transience at 29% of sites, occurring most often in agricultural regions, such as the San Joaquin Valley and Southern Coast Ranges, where large carbon-14 changes coincided with substantial nitrate and chloride shifts. Sites with tritiogenic helium-3 data showed more frequent age transience, underscoring the value of multi-tracer data sets. These results provide the first regional evidence of widespread groundwater age change and a method for detecting changing water balances with implications for groundwater sustainability and water quality.

California

Anomalous shear stress variation in wet granular medium: Implications for landslide lateral faults

Landslide assessments typically focus on the mechanical properties of the basal shear zone, but lateral faults are frequently overlooked, possibly due to their lower normal stresses and variably saturated conditions. Using double-cylinder shear experiments on wet granular systems as analogs for landslide lateral faults, we observe anomalous shear stress variations with fluid volume fractions, defying an expected unimodal relationship associated with capillary cohesion. At low fluid volume fractions, shear strength weakens as the wet grain assembly experiences reduced lateral pressure and increased boundary slip. This boundary slip subsequently vanishes, with an abrupt strengthening due to the dilation of the grain assembly against fluid surface tension as saturation approaches. Strike-slip motion and confinement in this system explain the strength anomaly, highlighting a critical role of lateral faults in landslide stability, particularly in cases where dynamics cannot be adequately explained by monitored pore-water pressure or basal friction.

Geophysical Research Letters

Time varying crustal anisotropy at Whakaari/White Island volcano

Whakaari/White Island has been the most active New Zealand volcano in the 21st century, producing small phreatic and phreatomagmatic eruptions, which are hard to predict. The most recent eruption occurred in 2019, tragically claiming the lives of 22 individuals and causing numerous injuries. We employed shear-wave splitting analyses to investigate variations in anisotropy during quiescence, unrest, and an eruption between 2018 and 2020. We examined spatial and temporal variations in 7972 shear-wave splitting measurements and derived 1402 V p /IV s ratio measurements. Comparing shear-wave splitting parameters from similar earthquake paths across different times indicates that the observed temporal changes are unlikely to result from variations in earthquake paths through media with spatial variability. Instead, these changes may stem from variations in anisotropy over time, likely caused by changes in crack alignment due to stress or varying fluid content.

Whakaari/White Island volcano

Estimating the probability of export restrictions to inform mineral criticality

To assess risks associated with advanced technologies’ supply chain disruptions, governmental agencies and others have developed mineral “criticality” assessments, with criticality described using the economic impact and probability of supply chain disruptions. Previous work developed subjective supply risk indicators to approximate this probability, typically combining several factors such as supply diversity and trading partners’ political stability, where indicator weightings can substantially impact results. This work explicitly quantifies export barrier probability using an ensemble of machine learning classifiers, with probability estimates informed by exogenous variables, including prior barrier implementation and global export dominance. Major differences in high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. The Supplementary Data File provides export barrier probability estimates for each analyzed country-commodity pair, enabling a direct, quantitative, objective contribution to assessing mineral criticality, enhancing risk identification and prioritization for policymakers.

Resources, Conservation, and Recycling

Water-withdrawal and groundwater-level fluctuations, physical and infiltration characteristics of Ohio River sediment, and isotope-based estimates of water sources relative to a riverbank filtration system in an alluvial aquifer, Louisville, Kentucky, 2000–20

The U.S. Geological Survey and the Louisville Water Company, from 2000 to 2020, cooperatively investigated physical and hydrologic conditions in the Ohio River alluvial aquifer and adjacent riverbed sediments in the northeast part of Louisville, Kentucky, to increase knowledge of processes affecting water sources to collector wells during operation of a riverbank filtration system (RBF). The RBF, in 2020, included an initial collector well (CW1) completed in 1999 and a tunnel and collector well system (TCWS) composed of four collector wells (CW2–CW5) completed in late 2010 that were connected by a tunnel that routed water to a pumping station and a treatment plant. Daily mean water-withdrawal rates typically ranged from about 10.4 to 20.7 million gallons per day (Mgal/d) from 2005 to 2007, then were cyclic from 2008 to 2010 and ranged from as low as about 9 to 13 Mgal/d in winter-spring months up to about 19 to 20 Mgal/d in summer-autumn months. From 2011 through 2017, peak daily mean water-withdrawal rates from CW2–CW5 fluctuated between winter-spring lows of about 20–30 Mgal/d to summer-autumn peak rates of about 41.6 Mgal/d in 2013 to about 48.2 Mgal/d in 2012. From 2017 to 2020, TCWS peak daily mean water-withdrawal rates decreased from about 45.7 Mgal/d in 2017 to about 37.5 Mgal/d in 2020 and peak daily mean rates from CW1 ranged from about 20.7 Mgal/d in 2020 to about 21.6 Mgal/d in 2018. Periods in 2019–20 with tunnel pumping station daily mean water-withdrawal rates smaller than about 30 Mgal/d had generally stable water levels in CW2 and indicated the sustainable yield of the TCWS collector wells under the prevailing hydrologic conditions. Drawdown during July–August of 2008 and 2009 was associated with CW1, the sole operating collector well. Groundwater-flow directions outside the CW1 cone of depression during July–August of 2008 and 2009 were from areas near the alluvial valley margin toward the Ohio River and in 2009 toward Harrods Creek. Collector wells CW2 through CW5 derived water during 2011–19 surveys from surface-water infiltration, as indicated by drawdown that extended beneath the Ohio River and Harrods Creek. Increases in drawdown toward the alluvial valley margins in July–August of 2013 and 2015, compared with July 2011, indicated less available recharge from those flow directions and decreased yield of groundwater from the aquifer after progressively longer TCWS water withdrawals. Drawdown at CW2–CW5 and at observation wells between them lessened in October 2019 and indicated that onshore groundwater levels can recover when collector well withdrawals decrease. Overlapping cones of depression in 2011–15 potentiometric surfaces centered around CW2, CW3, CW4, and CW5, and drawdown along divides between those wells indicated well interference between collector wells. Well-interference effects increased during 2013 and 2015 survey periods, despite decreased water-withdrawal rates compared with July 2011, and expanded to include CW1 when its use resumed. Groundwater-level fluctuations in observation wells near the Ohio River were consistent with gradual depletion of groundwater yield during tunnel pumping station operation at river elevations of about 420 feet above the National Geodetic Vertical Datum of 1929 (NGVD 29) and enhanced recharge of the aquifer when river elevations were above flood stage of about 430 feet above NGVD 29. Groundwater-level declines in observation wells near the Ohio River were most apparent in summer and some autumn months between 2012 and 2017 during periods when tunnel pumping station mean daily water-withdrawal rates were about 35 Mgal/d or more. Periods of relatively stable groundwater levels during 2019–20 in observation wells between CW2–CW5, when tunnel pumping station water-withdrawal rates were about 30–33 Mgal/d or less, also indicated that the prevailing sustainable yield was about 30 Mgal/d or less. Wells associated with CW3 and CW4 had the largest increases in slopes of best-fit lines relating water-level difference to water-withdrawal rate between 2012 and 2020, an indication of decreased efficiencies of those wells to supply water or of changes in groundwater yield around the well. Increased slopes of best-fit lines relating water-level difference to water-withdrawal rate from 2019 to 2020, when groundwater levels were otherwise relatively stable, also indicated that the specific capacity of one or more TCWS collector wells may have declined during that period. Riverbed surface elevation, roughness, and hardness changes between hydroacoustic surveys indicated active accretion and erosion of bed sediment offshore from the riverbank filtration system in 2002–4. Riverbed hydraulic conductivity computed from 2013 to 2015 in tests at 11 sites ranged from 0.2 to 230 feet per day. Ten temporary piezometer sites with adjacent operating collector wells had drawdowns that ranged from about 4 to 11.7 feet and hammer blows greater than or equal to 49 counts, which indicated a relatively great density of alluvial sediments and the potential for diminished riverbed infiltration rates. Contributions of Ohio River infiltration to collector wells estimated from deuterium and oxygen-18 isotopic ratios in representative Ohio River and groundwater samples were considerably larger in warmer months than cooler months and ranged from 80–90 percent in CW1–CW5 in May 2020 to 100 percent in May 2019 at CW2, CW4, and CW5. Groundwater contributions to water withdrawals by collector wells increased in cooler autumn months and ranged from 40 percent at CW3 and CW5 in November 2020 to 70 percent at CW2, CW4, and CW5 in November–December 2019. November 2019 and November 2020 isotopic compositions of water from the collector wells had enriched deuterium and oxygen-18 isotopic ratios consistent with mixtures of evaporation-modified water from the Ohio River and meteoric-origin groundwater.

Indiana, Kentucky

Estimating the probability of export restrictions to inform mineral criticality

As demand for advanced technologies rises, mineral commodities will increase in geopolitical importance. To assess risks associated with mineral commodity supply chain disruptions, governmental agencies and others have developed "criticality" assessments, with criticality described using the economic impact and probability of supply chain disruptions. In previous work, subjective supply risk indicators were developed to approximate this probability, typically combining several factors such as supply diversity and political stability of trading partners, where indicator weightings can substantially impact results. This work explicitly quantifies trade barrier probability using an ensemble of several machine learning classifiers, with probability estimates informed by exogenous variables such as prior trade barrier implementation and global export dominance. Major differences in the high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. This approach enables a direct, quantitative, objective approach to assessing trade barrier probability, enhancing risk identification and prioritization for policymakers.

SSRN

A cross-site comparison of ecosystem- and plot-scale methane fluxes across multiple sites

Wetland and upland ecosystems play significant but opposing roles in the global methane (CH 4 ) budget, acting as natural sources and sinks, respectively. Two of the most common approaches for measuring CH 4 fluxes (FCH 4 ) are chambers, which measure fluxes at fine spatial scales (ca. 1 m 2 ), and eddy covariance (EC) towers, which integrate fluxes across larger footprints (ca. 100–10 000 m 2 ). Although chamber and EC observations have been combined in various syntheses and databases to estimate CH 4 budgets, a unified cross-site evaluation of FCH 4 estimates at plot and ecosystem scales is lacking. As a first step toward a systematic spatiotemporal scaling of EC tower and chamber footprints, we quantified differences in site-level aggregate FCH 4 between EC and chamber measurements ( Δ FCH 4 ) across ten wetland and upland sites at half-hourly, hourly, daily, weekly, monthly, and annual timescales. We found that ecosystem-scale median FCH 4 was consistently higher than plot-scale FCH 4 at all temporal scales, with the smallest difference at the daily timescale (multi-site median Δ FCH 4 : 1.36 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 1.56 nmol m −2 s −1 , median plot-scale FCH 4 = 0.06 nmol m −2 s −1 ) and the largest at annual scales (2.58 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 25.91 nmol m −2 s −1 , median plot-scale FCH 4 = 6.55 nmol m −2 s −1 ). In general, the agreement between ecosystem- and plot-scale FCH 4 decreased with finer temporal resolution (from Spearman ρ = 0.95 at the annual scale to ρ = 0.65 at the half-hourly scale), while Δ FCH 4 variation was greatest at daily-to-annual scales. Key environmental predictors of Δ FCH 4 across the ten sites included plot-scale spatial heterogeneity, dominant vegetation type, vapor pressure deficit, atmospheric pressure, and friction velocity at the daily and monthly scales. Wind direction was a significant predictor only at the monthly scale, suggesting EC footprint effects at these sites. These findings suggest that accounting for variability in EC footprint extent, chamber measurement placement, and measurement artifacts is key to reconciling multi-scale FCH 4 observations across diverse ecosystems and refining CH 4 budgets.

Biogeosciences