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USGS2014

A review of environmental impacts of salts from produced waters on aquatic resources

Salts are frequently a major constituent of waste waters produced during oil and gas production. These produced waters or brines must be treated and/or disposed and provide a daily challenge for operators and resource managers. Some elements of salts are regulated with water quality criteria established for the protection of aquatic wildlife, e.g. chloride (Cl − ), which has an acute standard of 860 mg/L and a chronic standard of 230 mg/L. However, data for establishing such standards has only recently been studied for other components of produced water, such as bicarbonate (HCO 3 − ), which has acute median lethal concentrations (LC50s) ranging from 699 to > 8000 mg/L and effects on chronic toxicity from 430 to 657 mg/L. While Cl− is an ion of considerable importance in multiple geographical regions, knowledge about the effects of hardness (calcium and magnesium) on its toxicity and about mechanisms of toxicity is not well understood. A multiple-approach design that combines studies of both individuals and populations, conducted both in the laboratory and the field, was used to study toxic effects of bicarbonate (as NaHCO 3 ). This approach allowed interpretations about mechanisms related to growth effects at the individual level that could affect populations in the wild. However, additional mechanistic data for HCO 3 − , related to the interactions of calcium (Ca 2 + ) precipitation at the microenvironment of the gill would dramatically increase the scientific knowledge base about how NaHCO 3 might affect aquatic life. Studies of the effects of mixtures of multiple salts present in produced waters and more chronic effect studies would give a better picture of the overall potential toxicity of these ions. Organic constituents in hydraulic fracturing fluids, flowback waters, etc. are a concern because of their carcinogenic properties and this paper is not meant to minimize the importance of maintaining vigilance with respect to potential organic contamination.

International Journal of Coal Geology↗

USGS2025

Comparative toxicity of aircraft deicers, runway deicers, and road salt in winter airport runoff

Aircraft deicer and anti-icer formulations and airfield pavement deicer formulations are commonly used at airports that experience freezing precipitation. In addition, road salt is often applied in urban areas surrounding airports. This mixture of deicers in receiving streams can be toxic to aquatic organisms. A 17-year study of deicers and toxicity in runoff samples from sites in and near Milwaukee Mitchell International Airport included bioassay testing of Ceriodaphnia dubia , Pimephales promelas , Raphidocelis subcapitata , and Aliivibrio fischeri concurrently with quantification of freezing-point depressants that represent presence of the various deicers. Propylene glycol was monitored to represent aircraft deicers and anti-icers, acetate and formate were monitored to represent airfield pavement deicers, and chloride was monitored to represent road salt. Toxicity endpoints (e.g., lethal concentrations and inhibitive concentrations) were compiled for 19 airport deicer products and sodium chloride. Comparison of freezing-point depressant concentrations with toxicity endpoints indicated that propylene glycol, acetate, and chloride exceeded endpoint concentrations in multiple samples: more than 70% of 492 runoff samples exceeded at least one endpoint concentration with exceedances of propylene glycol and acetate-based deicer endpoints as well as road salt endpoints. Validation of these results were observed with measured toxic effects on C. dubia , P. promelas , and R. subcapitata in bioassays conducted on undiluted samples: samples with multiple deicers exceeding endpoint thresholds had greater toxicity than samples with individual deicer endpoint exceedances, and samples with no endpoint exceedances typically exhibited less toxicity than samples with only one endpoint exceedance. A comparison of additivity of toxicity quotients with bioassay results fit a log-logistic regression curve, indicating that the condition of tested organisms degraded with increasing deicer presence. These findings suggest that concurrent reduction of runoff from aircraft, airfield pavement, and road salt deicers will be needed to eliminate aquatic toxicity in adjacent watersheds.

Wisconsin↗

USGS2016

Users and uses of Landsat 8 satellite imagery—2014 survey results

Executive Summary In 2013, Landsat 8 began adding high quality, global, moderate-resolution imagery to the more than 40-year archive of Landsat imagery. To assess the potential effects of the availability of Landsat 8 imagery on users and their work, the U.S. Geological Survey (USGS) Land Remote Sensing Program (LRS) initiated a survey of Landsat users. The objectives of the survey were to 1. Characterize various Landsat user groups, such as United States (U.S.) and international users and Landsat 8 and non-Landsat 8 users; 2. Identify any differences among user groups in uses and preferences; 3. Measure the importance of and satisfaction with Landsat 8 attributes; 4. Assess the importance to users of the frequency of usable imagery; and 5. Determine any challenges in using Landsat 8. The online survey was sent to 51,617 Landsat users registered with USGS in May 2014. Almost 13,000 people responded to the survey for a response rate of 25 percent (n = 12,966). Current Landsat users (users who had used Landsat in their work in the year prior to the survey) composed 89 percent of the sample (n = 11,549) and past Landsat users composed 11 percent (n = 1,417). The results reported here apply to current Landsat users registered with the USGS Earth Resources Observation and Science (EROS) Center. Users from 161 countries responded to the survey. Of those, 19 percent were citizens or permanent residents of the United States and 81 percent resided in other countries. More than 70 percent of current users had used Landsat 8 in the year prior to the survey. The majority of Landsat 8 users (65 percent) were established users who used Landsat imagery regularly both before and after Landsat 8 imagery became available. The average current Landsat user was male, 36 years old, and highly educated, with 9 years of experience using satellite imagery or geographic information system (GIS) software. Landsat 8 users had, on average, two more years of experience than non-Landsat 8 users. Users were employed predominantly by academic institutions (65 percent), followed by private businesses (13 percent), Federal governments (10 percent), State and local governments (6 percent), and nonprofit organizations (6 percent). Of the Landsat imagery obtained in the past year by current users, on average 31 percent came from a Landsat 8 sensor. An equivalent amount came from the Landsat 7 ETM+ sensor (33 percent); slightly less came from Landsats 4 and 5 TM sensors (27 percent). Much less came from Landsats 1 through 5 MSS sensors (5 percent). Overall, more than a third of users’ work used Landsat imagery (38 percent). Of this work, on average, 37 percent of the work was operational. Landsat 8 users considered a greater proportion of their work operational than non-Landsat 8 users (39 percent compared with 29 percent). Environmental sciences and management were the most commonly selected primary applications (selected by 42 percent of users). Land use/land cover (23 percent) was the second most commonly selected primary application, followed by education (12 percent), agriculture (9 percent), and planning and development (6 percent). Landsat 8 users were asked to rank the importance of certain attributes in determining whether to use Landsat 8 imagery in their work. The archive was ranked most important, followed by cost, spatial resolution, extent of coverage, data quality, and frequency of revisit. Users were asked how satisfied they were with these same attributes as they currently apply to Landsat 8 imagery. On average, users were most satisfied with lack of cost, extent of coverage, data quality, and the archive, but they were satisfied with all attributes. Users were asked how often they needed Landsat imagery to meet various requirements for their primary application. The survey question specifically asked how often users needed usable imagery, which differs from how often they would like the Landsat satellites to acquire an image. Users were asked to identify their needed frequency of usable imagery for the following levels: 1. Threshold level—the minimum frequency of usable imagery needed to be of any value to their primary application. 2. Breakthrough level—the frequency of usable imagery that would result in a significant improvement for their primary application of the imagery. 3. Target level—the frequency of usable imagery that would only provide a limited additional increase in the expected performance for their primary application. To meet the threshold level, three-quarters of users needed usable imagery every 17 days or less frequently. At the breakthrough level, two-thirds of users (64 percent) needed a usable image every 5–16 days. The current constellation of two satellites (Landsat 7 and 8) is capable of meeting the threshold and breakthrough needs of most users at least some of the time, but a single satellite would be highly unlikely to do so. Two-fifths of users (40 percent) felt that usable imagery provided every 4 days or more frequently would meet their target level which the current Landsat constellation cannot provide. Landsat 8 users were significantly more likely than non-Landsat 8 users to need usable imagery more frequently to meet their target levels. Additionally, U.S. Landsat 8 users were significantly more likely than other Landsat users to need usable imagery more frequently in order meet both their breakthrough and target levels. To explore the effect of the availability of Landsat 8 imagery on Landsat imagery use in general, established users (those who had consistently used Landsat imagery both before and after Landsat 8 imagery became available) using Landsat 8 imagery were asked about changes in the amount of Landsat imagery they used. The majority of established users using Landsat 8 imagery (60 percent) reported an average increase of 51 percent in the number of scenes obtained after Landsat 8 imagery became available. Landsat 8 users were asked if they had encountered challenges in using Landsat 8 whereas non-Landsat 8 users were asked if such challenges had played a role in why they were not using Landsat 8 imagery. Although many users did not encounter challenges when using or trying to use Landsat 8 data, slightly less than 30 percent did encounter issues with processing the data to a usable point. The most common issue reported was not being able to create or have access to a surface reflectance corrected product. Other challenges were related to the file sizes of images being too large to download, store, or analyze. There were no statistically significant differences between Landsat 8 and non-Landsat 8 users in terms of challenges encountered when using or trying to use the imagery, which indicates that users were not unduly discouraged by the challenges they may have encountered. When asked about potential consequences of not using Landsat 8, more than half of the non-Landsat 8 users did not report detrimental effects on their work from not using the imagery. Of those who did report detrimental effects, decreased quality of work, decreased scope of work, and increased time spent on work were the most common.

Open-File Report↗

USGS2013

Implications of multi-scale sea level and climate variability for coastal resources

While secular changes in regional sea levels and their implications for coastal zone management have been studied extensively, less attention is being paid to natural fluctuations in sea levels, whose interaction with a higher mean level could have significant impacts on low-lying areas, such as wetlands. Here, the long record of sea level at Key West, FL is studied in terms of both the secular trend and the multi-scale sea level variations. This analysis is then used to explore implications for the Everglades National Park (ENP), which is recognized internationally for its ecological significance, and is the site of the largest wetland restoration project in the world. Very shallow topographic gradients (3–6 cm per km) make the region susceptible to small changes in sea level. Observations of surface water levels from a monitoring network within ENP exhibit both the long-term trends and the interannual-to-(multi)decadal variability that are observed in the Key West record. Water levels recorded at four long-term monitoring stations within ENP exhibit increasing trends approximately equal to or larger than the long-term trend at Key West. Time- and frequency-domain analyses highlight the potential influence of climate mechanisms, such as the El Niño/Southern Oscillation and the North Atlantic Oscillation (NAO), on Key West sea levels and marsh water levels, and the potential modulation of their influence by the background state of the North Atlantic Sea Surface Temperatures. In particular, the Key West sea levels are found to be positively correlated with the NAO index, while the two series exhibit high spectral power during the transition to a cold Atlantic Multidecadal Oscillation (AMO). The correlation between the Key West sea levels and the NINO3 Index reverses its sign in coincidence with a reversal of the AMO phase. Water levels in ENP are also influenced by precipitation and freshwater releases from the northern boundary of the Park. The analysis of both climate variability and climate change in such wetlands is needed to inform management practices in coastal wetland zones around the world.

Regional Environmental Change↗

USGS2020

Endocrine and physiological responses of hatchling American kestrels (Falco sparverius) following embryonic exposure to technical short-chain chlorinated paraffins (C10-13)

Short chain chlorinated paraffins (SCCPs) are complex mixtures of polychlorinated n -alkanes, shown to bioaccumulate but with unknown effects in wild birds. The present study examined development-related effects of SCCPs on captive American kestrels ( Falco sparverius ) treated in ovo on embryonic day (ED) 5 by injection with technical Chloroparaffin® (C 10-13 , 55.5% Cl) at environmentally relevant nominal (measured) concentrations of 10 (10), 50 (29) or 100 (97) ng ΣSCCP/g egg ww, and artificially incubated until hatching (ED27–ED29). The SCCP concentrations measured in the yolk sacs of the hatchling kestrels bracketed concentrations reported in the eggs of wild birds. Uptake and deposition of these SCCPs differed between male and female hatchlings, with only males showing differences in SCCP concentrations, being highest in the high-dose males than each of the other male groups. Embryonic exposure to SCCPs suppressed glandular total thyroxine (TT4) (20–33%) and reduced circulating triiodothyronine (TT3) (37–40%) in male hatchlings only when compared to control males, but had no effect on glandular TT3 or circulating TT4 in male or female kestrels. Histological assessments of thyroid glands showed that both sexes experienced significant structural changes indicative of gland activation. These thyroid glandular changes and the variations in SCCP concentrations were related to circulating TT3 in female hatchlings. Hepatic deiodinase enzyme (D1, D2) activities were stable and no SCCP-related changes were observed in hatching success, hatchling size, or immune organ size. However, several of the thyroid function indicators were correlated with hatchling size and smaller bursas and spleens, possibly indirectly through SCCP-induced changes in thyroid function. Because changes in thyroid function were evident at concentrations measured in wild bird eggs, similar changes may occur in wild nestlings. The potential impact of these changes on thyroid-mediated growth and survival in wild birds requires further investigation.

Environment International↗

USGS2022

A hydrologic perspective of major U.S. droughts

Drought is a recurring natural hazard that has substantial human and environmental impacts. Given continued global warming and associated climate change, there is concern that droughts could become more severe and longer lasting. To better monitor and understand drought development and persistence, it is helpful to understand the development and climatic drivers of past droughts. In this study we use monthly runoff percentiles to identify five major drought events in the conterminous United States (CONUS) from 1901 through 2020. For each drought event we examined spatial patterns of departures of mean monthly precipitation, temperature, soil moisture storage, and runoff for 2,107 hydrologic units (HUs) across the CONUS. Results indicated that precipitation deficits have been the primary driver of past major-drought events and temperature a secondary driver, even of the most recent drought event (September 1999 through September 2015) when positive temperature anomalies occurred over most of the CONUS. Additionally, negative soil moisture storage departures were more negative than runoff departures during the five drought events we examined, which emphasizes the importance of measuring both runoff and soil moisture to monitor drought conditions. We also examined the use of statistical persistence to develop short-term (i.e., 1 month) forecasts of runoff drought conditions in the CONUS by developing autoregressive integrated moving average (ARIMA) models for each HU. Results indicated that persistence can be used to predict short-term changes in the spatial pattern of drought and the areal extent of drought, but that predictions of runoff magnitude for any particular site are often poor.

International Journal of Climatology↗

USGS2018

Relations between total phosphorus and orthophosphorus concentrations and rainfall, surface-water discharge, and groundwater levels in Big Cypress Seminole Indian Reservation, Florida, 2014–16

The Seminole Tribe of Florida (the Tribe) is partnering with the U.S. Environmental Protection Agency to develop a numeric phosphorus criterion for the 52,000-acre Big Cypress Seminole Indian Reservation (BCSIR), which is located downgradient of the Everglades Agricultural Area, and of other public and private lands, in southeastern Hendry County and northwestern Broward County in southern Florida. The U.S. Geological Survey (USGS), in cooperation with the Tribe, used water-quality data collected between October 2014 and September 2016 by the Tribe and the South Florida Water Management District (SFWMD), along with data from rainfall gages, surface-water stage and discharge gages, and groundwater monitoring wells, to (1) examine the relations between local hydrology and measured total phosphorus (TP) and orthophosphorus (OP) concentrations and (2) identify explanatory variables for TP concentrations. Of particular concern were conditions when TP exceeded 10 parts per billion (ppb) (0.01 milligram per liter [mg/L]) given that the State of Florida and the Miccosukee Tribe of Indians Alligator Alley Reservation (located downstream of the BCSIR) have adopted a 10-ppb maximum TP criterion for surface waters. From October 2014 to September 2016, the Tribe collected 47–52 samples at each of nine water-quality sites for analysis of TP and OP, except at one site where 28 samples were collected. For all sites sampled, concentrations of TP (as phosphorus [P]) ranged from less than 0.002 mg/L (2 ppb) to a maximum of nearly 0.50 mg/L (500 ppb), whereas concentrations of OP (as P), the reactive form of inorganic phosphorus readily absorbed by plants and (or) abiotically absorbed, ranged from less than 0.003 mg/L (3 ppb) to a maximum of 0.24 mg/L (240 ppb). The median and interquartile ranges of concentrations of TP and OP in the samples collected in 2014–16 by the Tribe were similar to the median and interquartile ranges of concentrations in samples collected by the SFWMD at nearby sites during the same period. Differences in concentrations can likely be explained by differences in sample collection methods, sampling locations, sample collection time, and the hydrology during sampling or by the number of samples collected. A major limitation of this study was the short duration of sample collection, which covers a limited range of hydrologic conditions within the BCSIR. The effect of surface-water and groundwater hydrologic conditions on TP and OP concentrations was assessed by using rainfall data and surface-water stage and discharge records. The highest TP and OP concentrations occurred during peak surface-water flows in the canals following long dry periods. Concentrations of TP and OP increased internal to the BCSIR in the western half of the BCSIR during wet periods, but increased concentrations tended to lag behind rainfall events, likely because control structures upstream of sampling sites do not release flows until the water levels in the canals reach predetermined levels. This pattern may indicate that bed sediments in the canals contain high concentrations of phosphorus that becomes resuspended during high flows or that phosphorus salts that had accumulated on dry land during dry periods are carried into the canals by runoff. The largest TP spikes usually occurred at the beginning of high-flow events, but then quickly tapered off even when flows remained high. Groundwater flows were assessed in the BCSIR by using groundwater level observations from two preexisting USGS monitoring well clusters, each characterized by a shallow well installed in the surficial aquifer system and a deeper well installed in the intermediate aquifer system. Groundwater levels were evaluated with respect to surface-water levels and discharge in the BCSIR during the period of surface-water sampling. During dry conditions water levels in canals were often higher than groundwater levels in the surficial aquifer, indicating the potential for surface water to recharge the surficial aquifer. During wetter conditions, this trend reversed, and there was potential for shallow groundwater discharge into the canals. From October 2014 to September 2016, concentrations of TP tended to decrease as surface-water inflows moved across the BCSIR from north to south. In both the western and eastern halves of the reservation, the mean concentration of TP was lower in the surface-water outflows from the BCSIR than in the inflows. The mean concentration of TP in the inflows to the western reservation was 0.04 mg/L (40 ppb), whereas the mean concentration of TP in the outflows was 0.03 mg/L (30 ppb). In the eastern reservation, the mean concentration of TP in the inflows was 0.07 mg/L (70 ppb), whereas the mean concentration of TP in the outflows was 0.04 mg/L (40 ppb). TP and OP concentrations were evaluated relative to other water-quality parameters, including turbidity, suspended solids, nitrate plus nitrite, dissolved oxygen, pH, and specific conductance, to determine if any relations existed between TP and other variables. Weak relations were indicated for turbidity and suspended solids at two sites, which indicates that there may be a relation of increased TP to mobilization of sediment.

Florida↗

USGS1998

North American landscape characterization project: The production of a continental scale three-decade Landsat data set

The North American Landscape Characterization (NALC) project is a component of the National Aeronautics and Space Administration (NASA) Landsat Pathfinder program. Pathfinder projects are focused on the investigation of global change utilizing current remote sensing technologies. The NALC project is a cooperative effort between the U. S. Environmental Protection Agency (EPA), the U.S. Geological Survey (USGS), and NASA to make Landsat data available to the widest possible user community for scientific research and general public interest. The NALC project is principally funded by the EPA Office of Research and Development and the USGS's Earth Resources Observation Systems (EROS) Data Center (EDC). The objectives of the NALC project are to produce standardized remote sensing data sets, develop standardized analysis methods, and derive standardized land cover change products for a large portion of the North American continent (the conterminous United States and Mexico) (Lunetta and Sturdevant, 1993). The standard product is the NALC “triplicate”;, consisting of co‐registered Landsat multispectral scanner data for the years 1973, 1986, and 1991 (plus or minus one year), plus co‐registered 3 arcsecond digital terrain elevation data. Processing began with the 1986 scene, which was precision corrected (with full terrain correction) to a 60 meter Universal Transverse Mercator base. Automated cross‐correlation procedures were used to co‐register the 1970's and 1990's data to the 1980's base, and independent verifications of registration quality were performed on all triplicate components. The pertinent metadata were compiled in a relational database, which includes WRS2 path/rows, scene ID's, image dates, solar azimuth and elevation, verification RMSE's, and the number of verification control points. NALC triplicate data sets are being used for a number of applications, including the analysis of urbanization patterns, dynamics of climatic fluctuations, deforestation studies, and vegetation classification and mapping. These data are being distributed through the Earth Observing System Data and Information System (EOSDIS) Information Management System (IMS) at a cost of $15(U.S.) for each triplicate.

Geocarto International↗

USGS2005

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology↗

USGS2024

Annotated bibliography of scientific research relevant to oil and gas reclamation best management practices in the western United States, published from 1969 through 2020

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey has created a series of annotated bibliographies on topics of management concern for lands in the western United States (U.S.). Oil and gas development on public lands is a long-standing and substantial component of local and regional economies and has expanded in recent decades, particularly on public lands in the western U.S. This development is associated with extensive networks of pipelines, roads, and processing facilities, across which reclamation is Federally mandated following initial well pad development (“interim” reclamation) and once resource extraction is complete (“final” reclamation). Reclamation is critical for recovering ecological services to energy-affected lands, including vegetation productivity, wildlife habitat, water and air quality, and soil stability (for example, resistance to wind and water erosion). However, reclamation of oil and gas affected lands in the western U.S. has proved challenging due to an array of regulatory and environmental factors, such as minimally developed soils, short growing seasons, herbivory, high winds, invasive species, rugged terrain, and in particular, arid climates associated with low total precipitation, high evapotranspiration rates, and highly variable precipitation patterns. We compiled and summarized journal articles, government reports, technical reports, proceedings, and theses and dissertations relevant to oil and gas reclamation. We constrained our search to products published on or before December 31, 2020 but did not limit our search by a starting date; the earliest product resulting from this effort was published in March 1969. Second, we manually scanned the last 15 years (2005-2020) of tables of contents in journals, bibliographies, and proceedings of which we were aware would contain articles highly relevant to this bibliography. We carried out the search for these products through multiple means: (1) performing a structured search of two reference databases, (2) examining articles published since 2005 in highly relevant scientific journals and conference proceedings, and (3) reviewing additional material suggested by authors of products identified in steps 1 and 2. Our search was intentionally broad in order to identify as much relevant work as possible, much of which is professionally applied and tested within the industry of oil and gas reclamation, but which remains unpublished in scientific journals. We refined the initial list of products by removing: (1) duplicates, (2) products not written in English, (3) products that were not relevant to the arid ecosystems of western North America, (4) products that were not released as research, data products, or review articles in journals or as formal scientific reports, and (5) products with data which were not relevant to reclamation of oil and gas-affected lands, or for which the study did not present new data, findings, or syntheses relevant to reclamation of oil and gas-affected lands. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and assigned standardized management topics to each. Management topics are intended to aid online searching within the bibliography and are described in more detail in the Methods Section of this report; they include what type of disturbance the product addresses (well pads, mining, pipelines), what aspect of oil and gas reclamation they pertain to (practices, standards, monitoring), what type of data are present in the product (for instance soil or vegetation recovery data), and an indication if the product were from a source other than a published, peer-reviewed outlet (such as dissertations or unpublished professional reports – these are identified as grey literature). The review process for this annotated bibliography included an initial internal colleague review of each summary, requesting input on each summary from an author of the original product, and a formal peer-review. Our initial searches resulted in 3,197 total products, of which 290 met our criteria for inclusion. “Reclamation Practices” is by far the management topic most addressed, followed by “Reclamation Monitoring,” for example, products assessing what and how monitoring methods are used to track and measure reclamation outcome. This document may be accessed at https://doi.org/10.3133/ofr20231068 or from the U.S. Geological Survey Publication Warehouse ( https://pubs.usgs.gov/ ). The 1-page product summaries herein will also be used to create a bibliography at https://apps.usgs.gov/science-for-resource-managers that includes links to each original product, where available, and in which subject matter will be searchable by topic, location, and year. The studies compiled and summarized here may inform planning and management actions that seek to reclaim landscapes across the western U.S. which have been affected by oil and gas development.

Open-File Report↗

USGS2017

Assessment of the potential respiratory hazard of volcanic ash from future Icelandic eruptions: A study of archived basaltic to rhyolitic ash samples

Background The eruptions of Eyjafjallajökull (2010) and Grímsvötn (2011), Iceland, triggered immediate, international consideration of the respiratory health hazard of inhaling volcanic ash, and prompted the need to estimate the potential hazard posed by future eruptions of Iceland’s volcanoes to Icelandic and Northern European populations. Methods A physicochemical characterization and toxicological assessment was conducted on a suite of archived ash samples spanning the spectrum of past eruptions (basaltic to rhyolitic magmatic composition) of Icelandic volcanoes following a protocol specifically designed by the International Volcanic Health Hazard Network. Results Icelandic ash can be of a respirable size (up to 11.3 vol.% < 4 μm), but the samples did not display physicochemical characteristics of pathogenic particulate in terms of composition or morphology. Ash particles were generally angular, being composed of fragmented glass and crystals. Few fiber-like particles were observed, but those present comprised glass or sodium oxides, and are not related to pathogenic natural fibers, like asbestos or fibrous zeolites, thereby limiting concern of associated respiratory diseases. None of the samples contained cristobalite or tridymite, and only one sample contained quartz, minerals of interest due to the potential to cause silicosis. Sample surface areas are low, ranging from 0.4 to 1.6 m2 g−1, which aligns with analyses on ash from other eruptions worldwide. All samples generated a low level of hydroxyl radicals (HO•), a measure of surface reactivity, through the iron-catalyzed Fenton reaction compared to concurrently analyzed comparative samples. However, radical generation increased after ‘refreshing’ sample surfaces, indicating that newly erupted samples may display higher reactivity. A composition-dependent range of available surface iron was measured after a 7-day incubation, from 22.5 to 315.7 μmol m−2, with mafic samples releasing more iron than silicic samples. All samples were non-reactive in a test of red blood cell-membrane damage. Conclusions The primary particle-specific concern is the potential for future eruptions of Iceland’s volcanoes to generate fine, respirable material and, thus, to increase ambient PM concentrations. This particularly applies to highly explosive silicic eruptions, but can also hold true for explosive basaltic eruptions or discrete events associated with basaltic fissure eruptions.

Environmental Health↗

USGS1995

Paleoecology of the Springfield Coal Member (Desmoinesian, Illinois Basin) near the Leslie Cemetery paleochannel, southwestern Indiana

The Springfield Coal Member (Carbondale Group, Petersburg Formation of Indiana) is split locally in Warrick and Gibson Counties, Indiana, by clastic rocks of the Folsomville Member (Carbondale Group, Petersburg Formation) that represent the Leslie Cemetery paleochannel, part of a large, interconnected paleochannel system in the Springfield coal bed. This study incorporated analysis of miospore and megaspore assemblages, coal petrography, plant compression fossils and conodonts from the coal and clastic split to document changes in the swamp and its vegetation in response to the activity of the Leslie Cemetery paleochannel. Palynological and petrographic data indicate that environmental conditions and vegetation in the lower bench of coal near the Leslie Cemetery paleochannel were similar to those found in profiles through the coal bed at sites near the larger, more extensive Galatia paleochannel. Miospore floras of the high-vitrinite, lower bench of coal were dominated by tree-fern miospores, with those of lycopsids ranking second in abundance; megaspore assemblages were dominated by lycopsid megaspores. Near the contacy between the lower bench of coal and clastic split, medullosan prepollen increases in abundance and fusain bands are more common, which may indicate the occurrence of fire, either within or outside the swamp. Vegetation in the Folsomville Member and upper bench of coal differ markedly from that of the lower bench of coal. Plant megafossils from the Folsomville Member indicate dominance by pteridosperms and/or lycopsids and Folsomville Member miospore assemblages are dominated by lycopsid miospores most typically found in mudstones, including Lycospora torquifer and higher than normal abundances of Granasporites medius . In the transition from clastic rocks of the Folsomville Member to the upper bench of coal, miospores of ‘ecotonal’ lycopsids ( Paralycopodites ) reach their peak abundance, pteridosperms dominate megafossil assemblages and inertinite levels are relatively high. At higher levels of the upper bench of coal, vitrinite levels are higher and miospore assemblages are dominated by lycopsid miospores typical of coal swamps ( Lycospora granulata, L. pusilla ). The presence of conodonts in coalballs in the upper bench of coal and spirorbid worms in the split indicate that the paleoswamp may have received some marine or brackish water influence. Higher than normal salinity levels may explain the vegetational changes observed in the upper bench of coal near the Leslie Cemetery paleochannel.

Indiana↗

USGS2023

Predicting methane emissions and developing reduction strategies for a Central Appalachian Basin, USA, longwall mine through analysis and modeling of geology and degasification system performance

Coal mine methane is a safety concern in active mines due to explosion risk and an environmental concern due to the greenhouse gas (GHG) properties of methane emissions to the atmosphere. Depending on the mine design and operation, structural and stratigraphic characteristics of the geology, and the properties of coal beds affected by mining, a significant amount of methane can be released during coal extraction. These emissions may be low and uniform, but they also can be high and abrupt, if not captured by using pre- and post-mining methods of degasification or not controlled by ventilation during mining. Therefore, emissions should be monitored and predicted accurately for underground safety and GHG reduction. Ventilation and degasification systems should be designed accordingly by taking into account the mine geological properties and the degasification system's performance. This paper presents a comprehensive study to predict emissions and proposes alternatives to reduce emissions in a longwall mine extracting metallurgical coal from the Pocahontas No. 3 coal bed in Virginia (Central Appalachian Basin), USA. The work focused on mining activity in four adjacent panels through analysis and modeling of geology and evaluation of the performance of the methane control system. Results showed that the mine geology contained a significant amount of gas within and around the panel areas, which was controlled by utilizing different degasification methods besides ventilation during mining. The study showed that after pre-mining degasification using fractured vertical wells and in-seam horizontal wells, each panel potentially contained ∼19 MMscf and ∼ 2 MMscf of gas remaining to be handled by the gob gas ventholes (GGVs) and the ventilation, respectively, per acre of mining. It was shown that extending the pre-mining degasification duration of vertical wells by as much as 4 years or drilling more horizontal wells with closer spacing could significantly reduce ventilation and gob emissions during the mining of coal.

Kentucky, Virginia, West Virginia↗

USGS2026

The impacts of cover crop biomass on satellite-based detectability of cover crops in Maryland

Cover crop adoption in the U.S. has increased over the past decades, increasing the need to quantify their performance and environmental benefits. While remote sensing (RS)-based approaches for detecting cover crop presence have been developed, there has been limited research on how cover crops with varied biomass and management practices influence detectability. Using unique field-level cover crop presence and biomass datasets in Maryland, U.S., we investigated how RS-based detectability changes for cover crops with varied aboveground biomass, planting, and termination dates. Specifically, we proposed a time-integrated satellite-based greenness feature from Harmonized Landsat-8 and Sentinel-2 (HLS) time series from 2017 to 2021 to estimate biomass of cover crops and evaluated their detectability using a phenology-based cover crop detection framework. The impacts of cover crop planting and termination dates on cover crop biomass were also analyzed. Our results demonstrated that Normalized Difference Vegetation Index (NDVI) estimated biomass with higher accuracy compared to other vegetation indices, and the time-integrated model estimated biomass with higher accuracy than the single-date “snapshot” linear model (R2 from 0.53 to 0.66 and RMSE from 922 kg/ha to 747 kg/ha). While the snapshot models were species sensitive, the time-integrated models showed strong robustness across different species. Detectability increased with cover crop biomass, as detected cover crops averaged 963.3 ±719.5 kg/ha compared to 297.2 ± 209.0 kg/ha for non-detected cover crops. Detection accuracy reached 96.1% for fields exceeding 500 kg/ha, compared with an overall accuracy of 62.7%. Earlier planting and later termination increased biomass and detectability, with biomass rising by 4.14 kg/ha/day (p < 0.01). This study demonstrates how management practices affect cover crop biomass and detectability via satellite time series and provides insights that can inform management of cover crops and monitoring of their effects on agroecosystems.

Maryland↗

USGS2012

Hybrid analysis of multiaxis electromagnetic data for discrimination of munitions and explosives of concern

The remediation of land containing munitions and explosives of concern, otherwise known as unexploded ordnance, is an ongoing problem facing the U.S. Department of Defense and similar agencies worldwide that have used or are transferring training ranges or munitions disposal areas to civilian control. The expense associated with cleanup of land previously used for military training and war provides impetus for research towards enhanced discrimination of buried unexploded ordnance. Towards reducing that expense, a multiaxis electromagnetic induction data collection and software system, called ALLTEM, was designed and tested with support from the U.S. Department of Defense Environmental Security Technology Certification Program. ALLTEM is an on-time time-domain system that uses a continuous triangle-wave excitation to measure the target-step response rather than traditional impulse response. The system cycles through three orthogonal transmitting loops and records a total of 19 different transmitting and receiving loop combinations with a nominal spatial data sampling interval of 20 cm. Recorded data are pre-processed and then used in a hybrid discrimination scheme involving both data-driven and numerical classification techniques. The data-driven classification scheme is accomplished in three steps. First, field observations are used to train a type of unsupervised artificial neural network, a self-organizing map (SOM). Second, the SOM is used to simultaneously estimate target parameters (depth, azimuth, inclination, item type and weight) by iterative minimization of the topographic error vectors. Third, the target classification is accomplished by evaluating histograms of the estimated parameters. The numerical classification scheme is also accomplished in three steps. First, the Biot–Savart law is used to model the primary magnetic fields from the transmitter coils and the secondary magnetic fields generated by currents induced in the target materials in the ground. Second, the target response is modelled by three orthogonal dipoles from prolate, oblate and triaxial ellipsoids with one long axis and two shorter axes. Each target consists of all three dipoles. Third, unknown target parameters are determined by comparing modelled to measured target responses. By comparing the rms error among the self-organizing map and numerical classification results, we achieved greater than 95 per cent detection and correct classification of the munitions and explosives of concern at the direct fire and indirect fire test areas at the UXO Standardized Test Site at the Aberdeen Proving Ground, Maryland in 2010.

Geophysical Journal International↗

USGS1999

A possible link between Balkan endemic nephropathy and the leaching of toxic organic compounds from Pliocene lignite by groundwater: Preliminary investigation

Balkan endemic nephropathy (BEN) is a fatal kidney disease that is known to occur only in clusters of villages in alluvial valleys of tributaries of the Danube River in Bulgaria, Romania, Yugoslavia, Bosnia, and Croatia. The confinement of this disease to a specific geographic area has led to speculation that an environmental factor may be involved in the etiology of BEN. Numerous environmental factors have been suggested as causative agents for producing BEN, including toxic metals in drinking water, metal deficiency in soils of BEN areas, and environmental mycotoxins to name a few. These hypotheses have either been disproved or have failed to conclusively demonstrate a connection to the etiology of BEN, or the clustering of BEN villages. In previous work, we observed a distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and BEN villages. We hypothesized that the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites by groundwater was a primary factor in the etiology of BEN. In our current work, chemical analysis using 13C nuclear magnetic resonance (13CNMR) spectroscopy indicated a high degree of organic functionality in Pliocene lignite from the Balkans, and suggested that groundwater can readily leach organic matter from these coal beds. Semi-quantitative gas chromatography/mass spectroscopy analysis of solvent extracts of groundwater from shallow wells in BEN villages indicated the presence of potentially toxic aromatic compounds, such as napthalene, fluorene, phenanthrene, and pyrene at concentrations in the ppb range. Laboratory leaching of Balkan Pliocene lignites with distilled water yielded soluble organic matter (> 500 MW) containing large amounts of aromatic structures similar to the simple/discrete aromatic compounds detected in well water from BEN villages. These preliminary results are permissive of our hypothesis and suggest that further work on the possible relationship between the etiology of BEN and toxic aromatic substances leached from Pliocene lignites in well water is warranted.A distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and villages where Balkan endemic nephropathy (BEN) occurs has been observed, indicating a possible link between BEN and the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites. Preliminary investigations by NMR spectroscopy, gas chromatography/mass spectroscopy and leaching experiments show a high degree of organic functionality in the Pliocene lignites, high-leachability by groundwater of organic matter from these beds, and the presence of toxic aromatic compounds.

International Journal of Coal Geology↗

USGS2020

Simulation of discharge, water-surface elevations, and water temperatures for the St. Louis River estuary, Minnesota-Wisconsin, 2016–17

The St. Louis River estuary is a large freshwater estuary, next to Duluth, Minnesota, that encompasses the headwaters of Lake Superior. The St. Louis River estuary is one of the most complex and compromised near-shore systems in the upper Great Lakes with a long history of environmental contamination caused by logging, mining, paper mills, and other heavy industrial activities. Presently (2020), a widely available, science-based assessment tool capable of evaluating ecosystem-level responses to remediation and restoration projects has not existed for the estuary. To address this need, the U.S. Geological Survey (USGS) built a predictive, mechanistic, three-dimensional hydrodynamic model for the estuary using the Environmental Fluid Dynamics Code framework. In the current version, the model can simulate continuous discharge, water-surface elevations, water temperature, and flow velocity, although the modular framework allows for future additions of water-quality modeling. The model was calibrated using data collected from April 2016 through November 2016 and validated with data collected from April 2017 through November 2017. The four types of data used to evaluate model performance were water-surface elevations, discharge, water temperature, and flow velocities. Streamflow and temperature boundary condition data included a mixture of USGS streamgage data, Minnesota Department of Natural Resources gage data, and estimates derived from the gage data. The model was able to simulate the water-surface elevations with generally good agreement between the simulated and measured values for both years at the daily time step. Specifically, the model was able to demonstrate excellent agreement with the measured data with Nash-Sutcliffe efficiency coefficients greater than 0.8 for all three locations; however, the model was unable to produce hourly water-surface elevations with such accuracy for 2016–17. Discharge was more dynamic than the water-surface elevations, both for the measured and simulated data. Generally, most of the discharge ranged from −650 to 1,200 cubic meters per second, but the constantly changing flux exiting the estuary into Lake Superior (positive flows) and entering the estuary from Lake Superior (negative flows) occurred throughout the year. Even upstream at the St. Louis River at Oliver, Wisconsin, gage (USGS station 0402403250), the effect of flows into the estuary from Lake Superior did occur, demonstrating the strong effect of the Lake Superior seiche on flows for the estuary. From a performance standpoint, the model was able to simulate discharge with generally good agreement in both years, although the 2017 validation was better than the 2016 calibration period. For the daily Nash-Sutcliffe efficiency coefficients, the simulated values were 0.98, 0.62, 0.49, and 0.71 for the Oliver gage; the Superior Bay entry channel at Superior, Wisc., (USGS station 464226092005600); the Superior Bay Duluth Ship Canal at Duluth, Minn., (USGS station 464646092052900); and total entries (combination of the Superior entry and Duluth entry), respectively. For the hourly evaluation criteria, the model performed poorly, with Nash-Sutcliffe efficiency coefficients less than 0 for the two entries into Lake Superior; therefore, as a predictor of discharge at the hourly scale, the model performed worse than using the measured data average. Similar to discharge, the model was a good predictor of flow velocity at the daily time scale but had difficulty matching the measured data at the hourly scale. For discharge and flow velocity, matching at subdaily time steps for a system as complicated as the St. Louis River estuary is considered difficult because the match is highly sensitive to coordinating the exact measurement location to the simulated value. The final calibration target was water temperature, calibrated for the Oliver gage and the Duluth entry. For calibration purposes, the Duluth entry was the more important water temperature target because the Oliver gage was more of an internal check on the model. The Nash-Sutcliffe efficiency coefficients for the Duluth entry were high; hourly Nash-Sutcliffe efficiency coefficients at the Duluth entry were either at or greater than 0.7 for both years, and daily values were 0.84 and 0.82 for 2016 and 2017, respectively.

Minnesota, Wisconsin↗

USGS2025

Component identification of solid biomass fuels using reflected light microscopy: Interlaboratory study 2

As nations transition toward sustainable energy systems , biomass has become a vital component of global energy portfolios. Derived from organic materials such as wood, agricultural residues, forestry byproducts, and organic waste, biomass is a renewable energy source with significant environmental and economic benefits. Responsible biomass energy production can improve waste management, reduce emissions of greenhouse gases, and mitigate environmental pollution. However, as the diversity of biomass-derived fuels increases, robust quality assessment methods are essential to ensure their efficiency, safety, and minimal environmental impact. Reflected light microscopy (RLM) is one such technique with the potential to complement conventional physico-chemical analyses by enabling a rapid identification of material constituents and impurities. To refine this methodology and evaluate the reproducibility of solid biomass component identification using RLM, an interlaboratory study (ILS) was conducted. The study involved the recognition of 58 components across 45 photomicrographs, with the participation of 65 scientists and students from 25 countries. The participants faced high difficulty identifying some of the marked components, and as a result, the percentage of correct answers ranged from 19.0 % to 98.3 %, with an average correct identification rate of 62.7 %. The most challenging aspects of the identification process included distinguishing between woody and non-woody (agro) biomass, accurately identifying petroleum-derived materials, and differentiating agro biomass from inorganic matter. The results suggest that while RLM is an important tool for characterizing solid biomass, further development of methodology guidelines and training are necessary to enhance its effectiveness. Future research should prioritize preparing detailed, image-rich, microscopic morphological descriptions of biomass fuel components, which could improve the accuracy and reliability of using RLM in biomass fuel characterization.

International Journal of Coal Geology↗