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A Regional Approach to Wildlife Monitoring Related to Energy Exploration and Development in Colorado

The U.S. Bureau of Land Management (BLM) is currently developing a National Monitoring Strategy that will guide efforts to create an efficient and effective process for monitoring land health by BLM. To inform the ongoing development of the national strategy, BLM selected two States (Colorado, Alaska) to serve as focal areas on which to base a flexible framework for developing monitoring programs that evaluate wildlife responses to energy development. We developed a three-phase monitoring plan to serve as a template and applied it to the design of a monitoring program for the Colorado focal area (White River and Glenwood Springs Field Offices of the BLM). Phase I is a synthesis and assessment of current conditions that capitalizes on existing but under used data sources. A key component is the use of existing habitat and landscape models to evaluate the cumulative effects of surface disturbance. Phase II is the data collection process that uses information provided in Phase I to refine management objectives and provide a linkage to management decisions. The linkage is established through targeted monitoring, adaptive management, and research. Phase III establishes priorities and strategies for regional and national monitoring, and facilitates coordination among other land management agencies and organizations. The three phases are designed to be flexible and complementary. The monitoring plan guides an iterative process that is performed incrementally, beginning with the highest-priority species and management issues, while building on lessons learned and coordination among administrative levels. The activities associated with each phase can be repeated or updated as new information, data, or tools become available. This allows the development of a monitoring program that expands gradually and allows for rapid implementation. A demonstration application of the three-phase monitoring plan was conducted for a study area encompassing five BLM field offices in Colorado: White River, Glenwood Springs, Kremmling, Grand Junction, and Little Snake. The overall study area was selected to encompass the primary distribution of sagebrush and greater sage-grouse (Centrocercus urophasianus) in Colorado and to provide a larger context for evaluating priority management issues of the White River and Glenwood Springs Field Offices. Within the study area, we selected an additional scale of analysis: the Roan Plateau, an area of increased energy development. We focused our demonstration project on the primary objectives identified by the BLM and other stakeholders: (1) How do we evaluate the cumulative effects of energy development and mitigation activities on species of management interest or concern? (2) How can cumulative effects, including direct and indirect effects, be quantified relative to natural variation? (3) How can we implement compliance and effectiveness monitoring to determine whether lease stipulations are met and restoration/mitigation goals are achieved? We targeted greater sage-grouse because this species was identified as a monitoring priority for the White River Field Office. We also evaluated landscape-level indices to address fragmentation resulting from surface disturbance. The primary purpose of this exercise was to highlight the types of analyses and approaches that could be used to evaluate energy development in an application of the three-phase framework. We provide examples of Phase I products that can be used to guide the refinement of management objectives, development of adaptive management and research frameworks, and planning activities in Phase II. Finally, we report on the BLM's National Sage-Grouse Habitat Conservation Strategy as an example of Phase III activities. The development of an effective monitoring program is a daunting task, and will be difficult to implement by the BLM independently due to the current work load of staff. However, the scientific expertise and experience for developing cr

Open-File Report

The organic geochemistry of black sedimentary barite: Significance and implications of trapped fatty acids

Fatty acids isolated in sedimentary black barite (BaSO 4 ) from Arkansas and Nevada were identified by gas chromatography-mass spectroscopy. The dominant or major fatty acids found in these beds of barite are C 16:0 , C 18:0 , and C 18:1 . The occurrence and distribution of these acids in this type of rock may serve as “molecular fingerprints” of microbial biogeochemical processes. The organic matter and associated microorganisms are shown to be trapped within the finely crystalline barite, thus forming a closed system for microbial diagenesis. Important differences that occur in the distribution of the lesser or minor fatty acids probably result from: (1) the nature of the progenitor organic detritus in the environment of barite deposition: and (2) the subsequent degree of microbiological alteration of the parent organic debris swept into and trapped in the depositional environment. Three general models of sedimentary environments are proposed in which anoxic conditions may prevail and where barium sulfate (BaSO 4 ) may precipitate: (1) in a silled basin with semi-restricted circulation; (2) on an outer continental shelf where the slope is encroached upon by water of the oxygen minimum layer; (3) on a low-energy, inner shelf or semi-restricted embayment impinged by a wedge of anoxic water. The major geochemical and geological parameters which are believed to be the significant factors controlling the formation and high grade of these organic-rich, black bedded barites are: (1) a unique source of barium-rich fluid that only contains trace amounts of other elements; (2) the presence of an anoxic bottom environment within the depositional basin; (3) a reflux source of sulfate ion; (4) an adequate source of organic matter. The results of this study may serve as guidelines for future exploration in similar, untested sedimentary basins, especially those with rocks of middle Paleozoic age.

Arkansas, Nevada

An episode of reinflation of the Long Valley Caldera, eastern California: 1989-1991

Following the episodes of inflation of the resurgent dome associated with the May 1980 earthquake sequence (four M 6 earthquakes) and the January 1983 earthquake swarm (two M 5.2 events), 7 years of frequently repeated two-color geodimeter measurements spanning the Long Valley caldera document gradually decreasing extensional strain rates from 5 ppm/yr in mid-1983, when the measurements began, to near zero in mid-1989. The corresponding seismic activity within the caldera persisted at a low rate of fewer than 10 M ≥ 1.2 earthquakes per week from 1985 through November 1989 with no events exceeding M 3.0. Early October 1989 marked a change in activity when measurements of the two-color geodimeter network showed a significant increase in extensional strain rate (9 ppm/yr) across the caldera. The seismic activity began exceeding 10 M ≥ 1.2 per week in early December 1989 and rapidly increased to a sustained level of tens of M ≥ 1.2 per week with bursts having hundreds of events per day. Many events exceeded M 3.0 and the largest event was M ≈ 4. The 1989–1991 inflation episode is the first time that we have sufficient geodetic measurements in Long Valley to define the temporal relation between onset of an inflation episode and onset of brittle failure (earthquake swarm within the caldera). Here, the onset of deformation preceded the onset of increased earthquake activity by more than 2 months. The seismicity rate began to decrease in mid-July 1990, consistent with a gradually slowing of extension across the caldera as measured by the two-color geodimeter. The recent episode of inflation can be modeled by a single Mogi point source located about 7 km beneath the center of the resurgent dome. In contrast, the deformation pattern observed between mid-1983 and mid-1989 is best reproduced by fault slip in the south moat, inflation at 6.5 km depth near Casa Diablo Hot Springs and inflation beneath the resurgent dome. It appears that the 7-km source beneath the resurgent dome that was active for the earlier episodes is the primary source for the more recent episode. The model used to satisfy the line length observations predicts 7.5 cm of uplift along leveling route along highway 395 from mid-1983 to mid-1989 and an additional 11 cm through the end of 1991. To comp are with the energy release from seismicity, the modeled inflation from late 1989 through the end of 1991 has a moment that is a factor of 40 more than the cumulative seismic moment from earthquakes located within the caldera from the same period. Thus the recent inflation episode represents a significant portion of the observed geodetic deformation with only little seismic energy release.

Journal of Geophysical Research

Synchrotron radiation and its application to digital subtraction angiography

The intense synchrotron radiation produced at electron storage rings provides a new source of X-rays highly suited to iodine K-edge digital subtraction angiography. The high intensity and small angular divergence permit the radiation to be monochromatized by Bragg diffraction and made available in beams of small vertical size, of arbitrary horizontal width, and of tunable energy. The use of such beams provides maximum sensitivity to intra-arterial iodine and virtually eliminates image contrast due to non-vascular body structures. The sensitivity of this method to iodine offers the prospect of visualizing arteries by peripheral venous injection.

Conference Paper

Geologic assessment of undiscovered gas resources of the Eastern Oregon and Washington Province

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered oil and gas potential of the Eastern Oregon and Washington Province of Oregon and Washington (USGS Province 5005). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Eastern Oregon and Washington Province, the USGS used this geologic framework to define one total petroleum system and two assessment units within the total petroleum system, and quantitatively estimated the undiscovered gas resources within each assessment unit.

Oregon, Washington

Geologic assessment of undiscovered, technically recoverable coalbed-gas resources in Cretaceous and Tertiary rocks, North Slope, and adjacent state waters, Alaska

The purpose of the U.S. Geological Survey's (USGS) National Oil and Gas Assessment is to develop geology-based hypotheses regarding the potential for additions to oil and gas reserves in priority areas of the United States, focusing on the distribution, quantity, and availability of oil and natural gas resources. The USGS has completed an assessment of the undiscovered, technically recoverable coalbed-gas resources in Cretaceous and Tertiary rocks underlying the North Slope and adjacent State waters of Alaska (USGS Northern Alaska Province 5001). The province is a priority Energy Policy and Conservation Act (EPCA) province for the National Assessment because of its potential for oil and gas resources. The assessment of this province is based on geologic principles and uses the total petroleum system concept. The geologic elements of a total petroleum system include hydrocarbon source rocks (source rock maturation, hydrocarbon generation and migration), reservoir rocks (stratigraphy, sedimentology, petrophysical properties), and hydrocarbon traps (trap formation and timing). In the Northern Alaska Province, the USGS used this geologic framework to define one composite coalbed gas total petroleum system and three coalbed gas assessment units within the petroleum system, and quantitatively estimated the undiscovered coalbed-gas resources within each assessment unit.

Alaska

Germanium redistribution during weathering of Zn mine wastes: Implications for environmental mobility and recovery of a critical mineral

Germanium (Ge) is a metal used in emerging energy technologies, communications, and defense, and has been deemed critical by the United States due to its essential applications and scarce supply. Germanium is recovered as a byproduct of zinc (Zn) sulfides, and mining and processing of these materials lead to waste that could act both as a source of extractable Ge and a source for exposure to humans and ecosystems. Yet the distribution, speciation, and mineral hosts of Ge in mining-impacted areas are poorly understood. The Tar Creek Superfund Site, a former Zn mining area and Ge producer, is a natural laboratory to understand the environmental behavior and economic implications of Ge in mine wastes. We studied the distribution and behavior of Ge in solid wastes at the Tar Creek Superfund Site using bulk and microanalytical techniques. In wastes at this site we find that Ge has been redistributed from its original host, sphalerite (ZnS), to the fine-grained weathering product hemimorphite (Zn4Si2O7(OH)2·H2O), which impacts germanium's mobility, bioaccessibility, and potential for recovery. We provide chemical and mineralogical evidence of this redistribution, along with an evaluation of the oxidation state and molecular-scale substitution of Ge into sphalerite, hemimorphite, and quartz. Geochemical modeling shows that hemimorphite is more stable than sphalerite in waste piles and provides a stable secondary repository for Ge. However, hemimorphite is fine-grained, and if ingested or inhaled is readily soluble, with the potential to release Ge. Lastly, we discuss other sites internationally where similar behavior may be important. This study shows that weathering can have a significant impact on the distribution, speciation, and mineral hosts of Ge in mine wastes; directly influence mobilization from waste piles and subsequent availability to humans and ecosystems; and dictate metallurgical strategies to target Ge for recovery.

Oklahoma

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska

Selenium

Selenium (Se) was discovered in 1817 in pyrite from copper mines in Sweden. It is a trace element in Earth’s crust, with an abundance of three to seven orders of magnitude less than the major rock-forming elements. Commercial use of selenium began in the United States in 1910, when it was used as a pigment for paints, ceramic glazes, and red glass. Since that time, it has had many other economic uses—notably, in the 1930s and 1940s, when it was used in rectifiers (which change alternating current to direct current), and in the 1960s, when it began to be used in the liner of photocopier drums. In the 21st century, other compounds have replaced selenium in these older products; modern uses for selenium include energy-efficient windows that limit heat transfer and thin-film photovoltaic cells that convert solar energy into electricity. In Earth’s crust, selenium is found as selenide minerals, selenate and selenite salts, and as substitution for sulfur in sulfide minerals. It is the sulfide minerals, most commonly those in porphyry copper deposits, that provide the bulk of the selenium produced for the international commodity market. Selenium is obtained as a byproduct of copper refining and recovered from the anode slimes generated in electrolytic production of copper. Because of this, the countries that have the largest resources and (or) reserves of copper also have the largest resources and (or) reserves of selenium. Because selenium occurs naturally in Earth’s crust, its presence in air, water, and soil results from both geologic reactions and human activity. Selenium is found concentrated naturally in soils that overlie bedrock with high selenium concentrations. Selenium mining, processing, use in industrial and agricultural applications, and disposal may all contribute selenium to the environment. A well-known case of selenium contamination from agricultural practices was discovered in 1983 in the Kesterson National Wildlife Refuge in California. There, waters draining from agricultural fields created wetlands with high concentrations of dissolved selenium in the water. The selenium was taken up by aquatic wildlife and caused massive numbers of embryonic deformities and deaths. Regulatory agencies have since worked to safeguard ecological and human health by creating environmental exposure guidelines based upon selenium concentrations in water and in fish tissue. Any attempt to regulate selenium concentrations requires a delicate balance because selenium occurs naturally and is also a vital nutrient for the health of wildlife, domestic stock, and humans. Selenium is commonly added as a vitamin to animal feed, and in some regions of the United States and the world, it is added as an amendment to soils for uptake by agricultural crops. The important role of selenium in economic products, energy supply, agriculture, and health will continue for well into the future. The challenge to society is to balance the benefits of selenium use with the environmental consequences of its extraction. Increased understanding of the elemental cycle of selenium in the earth may lead to new (or unconventional) sources of selenium, the discovery of new methods of extraction, and new technologies for minimizing the transfer of selenium from rock to biota, so to protect environmental and human health.

Professional Paper

Size and growth patterns of the Yellowstone grizzly bear

Weights and/or measurements of 151 grizzly bears ( Ursus arctos ) captured 261 times were recorded from 1975 to 1985. Males were consistently heavier than females within all age classes beginning at age 2. Mean weight for 65 captive males (5+ years old) was 192 kg and 135 kg for 63 adult females (5+ years old). Mean monthly weights by sex and age class indicated adults lost weight from den emergence through July, generally regaining emergence weight by August. Weaned yearlings lost weight July-Septmber, whereas unweaned yearlings gained weight during the same period. Sexual dimorphism in body measurements within age classes was apparent in cubs and became significant in all body measurements by age 3. Girth was the measurement most closely correlated with weight for both males and females. Adults feeding at garbage dumps weighted more than bears relying on natural food sources. Bears were smaller and weighed less in this study than during the period 1959-70, when major dumps were available as a food source. Mean annual weights of nondump females were highly correlated with annual habitat productivity indices for Yellowstone Park. Correlations between mean adult female weight an cub litter size ( r ) = 0.92) and mean age at 1st cub production ( r = -0.52) were apparent. In general, females with reliable high-energy foods tended to attain larger body sizes, mature at an earlier age, and have larger cub litters than females using relatively low-energy foods.

Book

Reducing energy-related CO 2 emissions using accelerated weathering of limestone

The use and impacts of accelerated weathering of limestone (AWL; reaction: CO 2 +H 2 O+CaCO 3 →Ca 2+ +2(HCO 3 - ) is explored as a CO 2 capture and sequestration method. It is shown that significant limestone resources are relatively close to a majority of CO 2 -emitting power plants along the coastal US, a favored siting location for AWL. Waste fines, representing more than 20% of current US crushed limestone production (>10 9 tonnes/yr), could provide an inexpensive or free source of AWL carbonate. With limestone transportation then as the dominant cost variable, CO 2 mitigation costs of $3-$4/tonne appear to be possible in certain locations. Perhaps 10–20% of US point–source CO 2 emissions could be mitigated in this fashion. It is experimentally shown that CO 2 sequestration rates of 10 -6 to 10 -5 moles/sec per m 2 of limestone surface area are achievable, with reaction densities on the order of 10 -2 tonnes CO 2 m -3 day -1 , highly dependent on limestone particle size, solution turbulence and flow, and CO 2 concentration. Modeling shows that AWL would allow carbon storage in the ocean with significantly reduced impacts to seawater pH relative to direct CO 2 disposal into the atmosphere or sea. The addition of AWL-derived alkalinity to the ocean may itself be beneficial for marine biota.

Energy

Improving understanding of near-term barrier island evolution through multi-decadal assessment of morphologic change

Observed morphodynamic changes over multiple decades were coupled with storm-driven run-up characteristics at Fire Island, New York, to explore the influence of wave processes relative to the impacts of other coastal change drivers on the near-term evolution of the barrier island. Historical topography was generated from digital stereo-photogrammetry and compared with more recent lidar surveys to quantify near-term (decadal) morphodynamic changes to the beach and primary dune system between the years 1969, 1999, and 2009. Notably increased profile volumes were observed along the entirety of the island in 1999, and likely provide the eolian source for the steady dune crest progradation observed over the relatively quiescent decade that followed. Persistent patterns of erosion and accretion over 10-, 30-, and 40-year intervals are attributable to variations in island morphology, human activity, and variations in offshore bathymetry and island orientation that influence the wave energy reaching the coast. Areas of documented long-term historical inlet formation and extensive bayside marsh development show substantial landward translation of the dune–beach profile over the near-term period of this study. Correlations among areas predicted to overwash, observed elevation changes of the dune crestline, and observed instances of overwash in undeveloped segments of the barrier island verify that overwash locations can be accurately predicted in undeveloped segments of coast. In fact, an assessment of 2012 aerial imagery collected after Hurricane Sandy confirms that overwash occurred at the majority of near-term locations persistently predicted to overwash. In addition to the storm wave climate, factors related to variations within the geologic framework which in turn influence island orientation, offshore slope, and sediment supply impact island behavior on near-term timescales.

New York

Simulation of groundwater and surface-water flow in the upper Deschutes Basin, Oregon

This report describes a hydrologic model for the upper Deschutes Basin in central Oregon developed using the U.S. Geological Survey (USGS) integrated Groundwater and Surface-Water Flow model (GSFLOW). The upper Deschutes Basin, which drains much of the eastern side of the Cascade Range in Oregon, is underlain by large areas of permeable volcanic rock. That permeability, in combination with the large annual precipitation at high elevations, results in a substantial regional aquifer system and a stream system that is heavily groundwater dominated. The upper Deschutes Basin is also an area of expanding population and increasing water demand for public supply and agriculture. Surface water was largely developed for agricultural use by the mid-20th century, and is closed to additional appropriations. Consequently, water users look to groundwater to satisfy the growing demand. The well‑documented connection between groundwater and the stream system, and the institutional and legal restrictions on streamflow depletion by wells, resulted in the Oregon Water Resources Department (OWRD) instituting a process whereby additional groundwater pumping can be permitted only if the effects to streams are mitigated, for example, by reducing permitted surface-water diversions. Implementing such a program requires understanding of the spatial and temporal distribution of effects to streams from groundwater pumping. A groundwater model developed in the early 2000s by the USGS and OWRD has been used to provide insights into the distribution of streamflow depletion by wells, but lacks spatial resolution in sensitive headwaters and spring areas. The integrated model developed for this project, based largely on the earlier model, has a much finer grid spacing allowing resolution of sensitive headwater streams and important spring areas, and simulates a more complete set of surface processes as well as runoff and groundwater flow. In addition, the integrated model includes improved representation of subsurface geology and explicitly simulates the effects of hydrologically important fault zones not included in the previous model. The upper Deschutes Basin GSFLOW model was calibrated using an iterative trial and error approach using measured water-level elevations (water levels) from 800 wells, 144 of which have time series of 10 or more measurements. Streamflow was calibrated using data from 21 gage locations. At 14 locations where measured flows are heavily influenced by reservoir operations and irrigation diversions, so called “ naturalized ” flows, with the effects of reservoirs and diversion removed, developed by the Bureau of Reclamation, were used for calibration. Surface energy and moisture processes such as solar radiation, snow accumulation and melting, and evapotranspiration were calibrated using national datasets as well as data from long-term measurement sites in the basin. The calibrated Deschutes GSFLOW model requires daily precipitation, minimum and maximum air temperature data, and monthly data describing groundwater pumping and artificial recharge from leaking irrigation canals (which are a significant source of groundwater recharge). The calibrated model simulates the geographic distribution of hydraulic head over the 5,000 ft range measured in the basin, with a median absolute residual of about 53 ft. Temporal variations in head resulting from climate cycles, pumping, and canal leakage are well simulated over the model area. Simulated daily streamflow matches gaged flows or calculated naturalized flows for streams including the Crooked and Metolius Rivers, and lower parts of the mainstem Deschutes River. Seasonal patterns of runoff are less well fit in some upper basin streams. Annual water balances of streamflow are good over most of the model domain. Model fit and overall capabilities are appropriate for the objectives of the project. The integrated model results confirm findings from other studies and models indicating that most streamflow in the upper Deschutes Basin comes directly from groundwater discharge. The integrated model provides additional insights about the components of streamflow including direct groundwater discharge to streams, interflow, groundwater discharge to the land surface (Dunnian flow), and direct runoff (Hortonian flow). The new model provides improved capability for exploring the timing and distribution of streamflow capture by wells, and the hydrologic response to changes in other external stresses such as canal operation, irrigation, and drought. Because the model uses basic meteorological data as the primary input; and simulates surface energy and moisture balances, groundwater recharge and flow, and all components of streamflow; it is well suited for exploring the hydrologic response to climate change, although no such simulations are included in this report. The model was developed as a tool for future application; however, example simulations are provided in this report. In the example simulations, the model is used to explore the influence of well location and geologic structure on stream capture by pumping wells. Wells were simulated at three locations within a 12-mi area close to known groundwater discharge areas and crossed by a regional fault zone. Simulations indicate that the magnitude and timing of stream capture from pumping is largely controlled by the geographic location of the wells, but that faults can have a large influence on the propagation of pumping stresses.

Oregon

Efficacy of non-lead ammunition distribution programs to offset fatalities of golden eagles in southeast Wyoming

Golden eagles ( Aquila chrysaetos ) face many anthropogenic risks including illegal shooting, electrocution, collision with wind turbines and vehicles, and lead poisoning. Minimizing or offsetting eagle deaths resulting from human-caused sources is often viewed as an important management objective. Despite understanding the leading anthropogenic sources of eagle fatalities, existing scientific research supports few practical solutions to mitigate these causes of death. We implemented a non-lead ammunition distribution program in southeast Wyoming, USA, and evaluated its effectiveness as a compensatory mitigation action to offset incidental take (i.e., fatalities) of golden eagles at wind energy facilities. In 2020 and 2022, we distributed non-lead ammunition to 699 hunters with big-game tags specific to our >400,000-ha study area. These hunters harvested 296 pronghorn ( Antilocapra americana ), 14 deer ( Odocoileus spp.), and 33 elk ( Cervus canadensis ) in the study area, which accounted for 6.9% and 6.5% of the harvest in these hunt units in 2020 and 2022, respectively. We used road surveys in 2020 to estimate a density of 0.036 (95% CI = 0.018–0.058) golden eagles/km 2 during the big game hunting season in our study area. Model output suggests that our non-lead ammunition distribution program offset the fatality of 3.84 (95% CI = 1.06–23.72) eagles over the course of these 2 hunting seasons. Our work illustrates the potential usefulness of non-lead ammunition distribution programs as an action to mitigate eagle fatalities caused by wind facilities or other anthropogenic causes of death.

Wyoming

Acceleration spectra for subduction zone earthquakes

We estimate the source spectra of shallow earthquakes from digital recordings of teleseismic P wave groups, that is, P + p P + s P , by making frequency dependent corrections for the attenuation and for the interference of the free surface. The correction for the interference of the free surface assumes that the earthquake radiates energy from a range of depths. We apply this spectral analysis to a set of 12 subduction zone earthquakes which range in size from M S = 6.2 to 8.1, obtaining corrected P wave acceleration spectra on the frequency band from 0.01 to 2.0 Hz. Seismic moment estimates from surface waves and normal modes are used to extend these P wave spectra to the frequency band from 0.001 to 0.01 Hz. The acceleration spectra of moderate subduction zone earthquakes, that is, earthquakes whose seismic moments are less than 10 27 dyn cm, exhibit ω-square or Brune-type spectra, while the acceleration spectra of large subduction zone earthquakes, that is, earthquakes whose seismic moments are greater than 10 27 dyn cm, exhibit intermediate slopes where ü(ω) ∝ ω 5/4 for frequencies from 0.005 to 0.05 Hz. For this set of earthquakes, spectral shape appears to be a discontinuous function of seismic moment. Using reasonable assumptions for the phase characteristics, we transform the spectral shape observed for large earthquakes into the time domain to fit Ekström's (1987) moment rate functions for the M S = 8.1 Michoacan earthquake of September 19, 1985, and the M S = 7.6 Michoacan aftershock of September 21, 1985.

Journal of Geophysical Research Solid Earth

Variability of isotope and major ion chemistry in the Allequash Basin, Wisconsin

As part of ongoing research conducted at one of the U.S. Geological Survey's Water, Energy, and Biogeochem-ical Budgets sites, work was undertaken to describe the spatial and temporal variability of stream and ground water isotopic composition and cation chemistry in the Trout Lake watershed, to relate the variability to the watershed flow system, and to identify the linkages of geochemical evolution and source of water in the watershed. The results are based on periodic sampling of sites at two scales along Allequash Creek, a small headwater stream in northern Wisconsin. Based on this sampling, there are distinct water isotopic and geochemical differences observed at a smaller hillslope scale and the larger Allequash Creek scale. The variability was larger than expected for this simple watershed, and is likely to be seen in more complex basins. Based on evidence from multiple isotopes and stream chemistry, the flow system arises from three main source waters (terrestrial-, lake-, or wetland-derived recharge) that can be identified along any flowpath using water isotopes together with geochemical characteristics such as iron concentrations. The ground water chemistry demonstrates considerable spatial variability that depends mainly on the flow-path length and water mobility through the aquifer. Calcium concentrations increase with increasing flowpath length, whereas strontium isotope ratios increase with increasing extent of stagnation in either the unsaturated or saturated zones as waters move from source to sink. The flowpath distribution we identify provides important constraints on the calibration of ground water flow models such as that undertaken by Pint et al. (this issue).

Wisconsin

Assessment of the undiscovered oil and gas of the Senegal province, Mauritania, Senegal, the Gambia, and Guinea-Bissau, northwest Africa

Undiscovered, conventional oil and gas resources were assessed in the Senegal Province as part of the U.S. Geological Survey World Petroleum Assessment 2000 (U.S. Geological Survey World Energy Assessment Team, 2000). Although several total petroleum systems may exist in the province, only one composite total petroleum system, the Cretaceous-Tertiary Composite Total Petroleum System, was defined with one assessment unit, the Coastal Plain and Offshore Assessment Unit, having sufficient data to allow quantitative assessment. The primary source rocks for the Cretaceous-Tertiary Composite Total Petroleum System are the Cenomanian-Turonian marine shales. The Turonian shales can be as much as 150 meters thick and contain Type II organic carbon ranging from 3 to 10 weight percent. In the Senegal Province, source rocks are mature even when situated at depths relatively shallow for continental passive margin basins. Reservoir rocks consist of Upper Cretaceous sandstones and lower Tertiary clastic and carbonate rocks. The Lower Cretaceous platform carbonate rocks (sealed by Cenomanian shales) have porosities ranging from 10 to 23 percent. Oligocene carbonate rock reservoirs exist, such as the Dome Flore field, which contains as much as 1 billion barrels of heavy oil (10? API, 1.6 percent sulfur) in place. The traps are a combination of structural closures and stratigraphic pinch-outs. Hydrocarbon production in the Senegal Province to date has been limited to several small oil and gas fields around Cape Verde (also known as the Dakar Peninsula) from Upper Cretaceous sandstone reservoirs bounded by normal faults, of which three fields (two gas and one oil) exceed the minimum size assessed in this study (1 MMBO; 6 BCFG). Discovered known oil resources in the Senegal Province are 10 MMBO, with known gas resources of 49 BCFG (Petroconsultants, 1996). This study estimates that 10 percent of the total number of potential oil and gas fields (both discovered and undiscovered) of at least the minimum size have been discovered. The estimated mean size and number of assessed, undiscovered oil fields are 13 MMBO and 13 fields, respectively, whereas the mean size and number of undiscovered gas fields are estimated to be 50 BCFG and 11 fields. The mean estimates for undiscovered conventional petroleum resources are 157 MMBO, 856 BCFG, and 43 MMBNGL (table 2). The mean sizes of the largest anticipated undiscovered oil and gas fields are 66 MMBO and 208 BCFG, respectively. The Senegal Province is underexplored considering its large size. The province has hydrocarbon potential in both the offshore and onshore, and undiscovered gas resources may be significant and accessible in areas where the zone of oil generation is relatively shallow.

Bulletin

Mineral resource of the month: molybdenum

The article offers information about the mineral molybdenum. Sources includes byproduct or coproduct copper-molybdenum deposits in the Western Cordillera of North and South America. Among the uses of molybdenum are stainless steel applications, as an alloy material for manufacturing vessels and as lubricants, pigments or chemicals. Also noted is the role played by molybdenum in renewable energy technology.

Earth