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Water-quality data for selected stations in the East Everglades, Florida

The results of water-quality samples collected from April 1978 through April 1980 from three canal stations, four marsh stations, and two ground-water stations within the East Everglades, Dade County, Florida, are tabulated in 37 tables. The major categories of parameters analyzed are field measurements, physical characteristics, macronutrients (carbon, nitrogen, and phosphorus), major ions, trace elements, and algae. Chemical data for bulk-precipitation stations within and adjacent to the East Everglades are also given. The parameters analyzed include macronutrients, major ions, and trace elements. The period of record for these stations is October 1977 through April 1980. Bottom material at the canal and marsh stations was collected twice during the investigation. These data include analyses for macronutrients, trace elements, and chlorinated-hydrocarbon insecticides.

Florida↗

Data supplement to: Quality of coal mine drainage to Washington, 1975-77

From December 1975 to September 1977 the U.S. Geological Survey studied coal mine drainage in western Washington to 1) characterize the water quality of drainage from abandoned mines in the 11 coal-bearing areas of the State; 2) examine the water quality effects on a stream receiving drainage from an abandoned coal mine; 3) determine the baseline water-quality conditions at two prospective underground coal mine areas; and 4) recommend procedures for monitoring stream quality in the baseline areas in the event that mining occurs. This report presents physical, chemical, and biological data collected during the study period from Gallop Creek (Whatcom County), Loretta Creek (Skagit County), and Wilkeson Creek (Pierce County) and from 100 abandoned coal mines in western Washington, and from a borehole hydraulic-mining test site. Biological information included taxonomic identifications and counts of benthic invertebrates and periphytic algae. (USGS)

Open-File Report↗

Chemical and biological quality of selected lakes in Ohio, 1978 and 1979

Twenty-eight Ohio lakes were sampled by the U.S. Geological Survey and the Ohio Environmental Protection Agency for water-quality characteristics during the spring and summer of 1978 and 1979. This report is the third in a series covering a lake-sampling program that began in 1975. Data include water-column profiles of temperature, dissolved oxygen, pH, and specific conductance. Chemical, physical, and biological properties were measured at specific points in the water column, and selected physical and chemical properties also were measured in the principal inflows. The lakes were predominatly hard (120 180 milligrams per liter) to very hard water, although several soft-water lakes were found in southeastern Ohio. Calcium, bicarbonate, and sulfate were the principal dissolved constituents. Specific conductance ranged from 103 micromhos per centimeter (at 25 degrees Celsius) at Tycoon Lake, 1978, to 2,550 micromhos per centimeter at West Fork Mill Creek Lake, 1978. Thirteen lakes had trace-element concentrations that were above the limits for exceptional warm-water habitat recammended by the Ohio Environmental Protection Agency. Seasonal thermal gradients developed in most lakes deeper than 17 feet. Oxygen concentrations were zero or near zero during the summer sampling of the bottom water of all lakes having definite thermal gradients. Most anaerobic zones contained hydrogen sulfide and high concentrations of ammonia. All lakes were evaluated and classified by Carlson's trophic state index. Most of the lakes were classified as eutrophic. Blue-green algae (CyanophytaJ) dominated the summer algal communities. Fecal colifrom counts were within Ohio standards, although high (more than 1,000 colonies per 100 milliliters) fecal colifrom and fecal streptococcus counts were observed in West Fork Mill Creek Lake after significant runoff.

Open-File Report↗

Index to limnological data for southcentral Alaska Lakes

South-central Alaska lakes are a valuable natural resource and provide a variety of recreational opportunities to the public. Lakeside development has increased significantly in the past 10 years and several south-central Alaskan lakes have documented pollution problems. Cultural eutrophication, the process by which man-induced nutrient loading to a lake results in large increases in biological productivity, can also produce noxious algae blooms, dissolved oxygen depletion at depth, reduced water transparency, and fish kills. The potential for cultural eutrophication of south-central Alaska lakes prompted the U.S. Geological Survey (USGS) Water Resources Division and the Alaska Department of Natural Resources-Division of Geological and Geophysical Surveys (ADGGS) to provide lake researchers, managers, and the public with this index of published historical and current limnological references. The purpose of the index is to provide reference to the data which can be used to identify and monitor cultural eutrophication of south-central Alaska lakes. (Lantz-PTT)

Open-File Report↗

Text to accompany slides/photographs of Lower Cretaceous pollen and spores in sediments from the Muirkirk clay pit (Prince Georges County, MD)

The pollen and spores found in clay beds at the Muirkirk clay pit are those of ferns and lycopods, seed ferns, shrubby conifers, bald cypress-type conifers, and tree-sized conifers. Some of the ferns and conifers have modern representatives which help interpret the vegetation of this site that bears Early Cretaceous dinosaur fossils. The plants, as well as the presence of algae, fungi, and mineral remains of bacteria, show that the site was once a wetland that developed on the clay floor of a waning oxbow lake.

Maryl↗

Methods for collecting algal samples as part of the National Water-Quality Assessment Program

Benthic algae (periphyton) and phytoplankton communities are characterized in the U.S. Geological Survey's National Water-Quality Assessment Program as part of an integrated physical, chemical, and biological assessment of the Nation's water quality. This multidisciplinary approach provides multiple lines of evidence for evaluating water-quality status and trends, and for refining an understanding of the factors that affect water-quality conditions locally, regionally, and nationally. Water quality can be characterized by evaluating the results of qualitative and quantitative measurements of the algal community. Qualitative periphyton samples are collected to develop of list of taxa present in the sampling reach. Quantitative periphyton samples are collected to measure algal community structure within selected habitats. These samples of benthic algal communities are collected from natural substrates, using the sampling methods that are most appropriate for the habitat conditions. Phytoplankton samples may be collected in large nonwadeable streams and rivers to meet specific program objectives. Estimates of algal biomass (chlorophyll content and ash-free dry mass) also are optional measures that may be useful for interpreting water-quality conditions. A nationally consistent approach provides guidance on site, reach, and habitat selection, as well as information on methods and equipment for qualitative and quantitative sampling. Appropriate quality-assurance and quality-control guidelines are used to maximize the ability to analyze data locally, regionally, and nationally.

Open-File Report↗

Report of the Interagency biological methods workshop

The U.S. Geological Survey hosted the Interagency Biological Methods Workshop in Reston, Virginia, during June 22-23, 1993. The purposes of the workshop were to (1) promote better communication among Federal agencies that are using or developing biological methods in water-quality assessment programs for streams and rivers, and (2) facilitate the sharing of data and interagency collaboration. The workshop was attended by 45 biologists representing numerous Federal agencies and programs, and a few regional and State programs that were selected to provide additional perspectives. The focus of the workshop was community assessment methods for fish, invertebrates, and algae; physical habitat characterization; and chemical analyses of biological tissues. Charts comparing program objectives, design features, and sampling methods were compiled from materials that were provided by participating agencies prior to the workshop and formed the basis for small workgroup discussions. Participants noted that differences in methods among programs were often necessitated by differences in program objectives. However, participants agreed that where programs have identified similar data needs, the use of common methods is beneficial. Opportunities discussed for improving data compatibility and information sharing included (1) modifying existing methods, (2) adding parameters, (3) improving access to data through shared databases (potentially with common database structures), and (4) future collaborative efforts that range from research on selected protocol questions to followup meetings and continued discussions.

Open-File Report↗

Effectiveness of a stormwater collection and detention system for reducing constituent loads from bridge runoff in Pinellas County, Florida

The quantity and quality of stormwater runoff from the Bayside Bridge were evaluated to determine the effectiveness of the stormwater collection and detention pond system of the bridge in reducing constituent loads to Old Tampa Bay. Water-quality samples of stormwater runoff from the bridge and outflow from the detention pond were collected during and after selected storms. These samples were used to compute loads for selected constituents. Stormwater on the Bayside Bridge drained rapidly during rain events. The volume of stormwater runoff from 24 storms measured during the study ranged from 4,086 to 103,705 cubic feet. Storms were most frequent during July through September and were least frequent from February through May. Concentrations of most constituents in stormwater runoff before the bridge opened to traffic were less than or equal to concentrations measured after the bridge was opened to traffic. However, concentrations of arsenic in the outflow from the detention pond generally were greater before the bridge opened than concentrations after, and concentrations of orthophosphorus in the stormwater runoff and outflow from the pond were greater before the bridge opened than during over half the sampled storms after the bridge opened. Concentrations of most constituents measured in stormwater runoff from the bridge were greatest at the beginning of the storm and decreased as the storm continued. Variations in suspended solids, nutrients, and trace element concentrations were not always concurrent with each other. The source of the measured constituent (rainfall or road debris) and the phase of the constituent (suspended or dissolved) probably affected the timing of concentration changes. The quality of stormwater runoff from the Bayside Bridge varied with total runoff volume, with the length of the dry period before the storm, and with season. Average concentrations of suspended solids, ammonia plus organic nitrogen, nitrite plus nitrate nitrogen, orthophosphorus, phosphorus, total organic carbon, aluminum, arsenic, copper, and zinc in stormwater runoff generally were inversely related to runoff volume. The quality of outflow from the detention pond also varied during a storm event and with season. Maximum concentrations generally occurred near the beginning of a storm, and decreased as the storm continued. Maximum concentrations of many constituents occurred in June and July 1995. During the summer months, pH exceeded 9.0 while inorganic nitrogen concentrations were very low. These high pH values and low inorganic nitrogen concentrations are most likely associated with photosynthesis by algae or aquatic plants in the pond. Concentrations of nitrogen, phosphorus, and nickel in stormwater runoff were correlated with total organic carbon concentrations. Concentrations of chromium, copper, iron, nickel, lead, and zinc in stormwater runoff were correlated with aluminum concentrations. The source of these metals is probably the bridge materials and metallic debris from vehicles. The northern detention pond system of the Bayside Bridge effectively reduced concentrations of suspended solids, ammonia nitrogen, nitrite plus nitrate nitrogen, phosphorus, aluminum, cadmium, chromium, copper, iron, lead, nickel, and zinc in stormwater runoff before water discharged from the pond. However, concentrations of ammonia plus organic nitrogen, organic carbon, arsenic, and values for alkalinity, pH, and specific conductance generally were greater in outflow from the pond than in stormwater runoff from the bridge. Stormwater runoff and pond outflow for three storm events were evaluated to determine the effectiveness of the detention pond system in removing selected constituents from the stormwater runoff. Most constituents and constituent loads were reduced in the outflow from the pond. Suspended solids loads were reduced about 30 to 45 percent, inorganic nitrogen loads were reduced by about 60 to 90 percent, and loads of most trace elements

Open-File Report↗

Preliminary paleontologic report on cores 19A and 19B, from Russell Bank, Everglades National Park, Florida Bay

The fauna and flora preserved in two cores, 19A and 19B, from the south side of Russell Bank (N 25 03.831', W 80 37.486') in north-central Florida Bay, Everglades National Park, Florida, record a history of environmental change over the last century. The benthic foraminifera and molluscs indicate fluctuating salinities with increasing average salinity upcore in core 19B. Shifts from low salinity (12-15 ppt) to higher average salinity (30 ppt) occurred at 70-66 cm and 24-18 cm in core 19B (approximately 1937-1940 and 1975-1980). The inverse, shifts from periods of higher average salinity to periods of lower salinity, occurred at 140 cm, 90 cm, and 42 cm (approximately 1880, 1921, and 1960). Significant changes in the molluscan fauna indicative of specific substrate types occur at 88 cm, 68 cm, and 22 cm. The lower portion of the core is dominated by a mixture of sediment and grass dwellers, the middle portion by sediment dwellers, and the upper portion of the core by grass and finally grass and algae dwellers. Changes occur in the floral assemblages in core 19A, but the significance of these changes is unclear. Three subtle shifts occur in the pollen assemblages indicating the onshore vegetation was responding to some environmental factor. Two peaks in dinocyst abundance occur in core 19A, but the composition of dinocyst assemblages remains relatively stable throughout the core. Correspondence between changes in salinity and onshore vegetation changes is consistent with results from previous cores. The pattern of increased salinity upcore is consistent with patterns seen in core T24 from the mouth of Taylor Creek and in core 6A from Bob Allen mudbank.

Florida↗

Water-quality characteristics of the Slate and East rivers, Colorado, during the winter recreational season, December 1996

Periods of population influxes during winter recreation occur simultaneously with periods of extreme low flow in many Rocky Mountain areas. The ability of streams to assimilate additional nutrient loading is reduced by the low-flow conditions. Low-flow water-quality characteristics of the Slate and East Rivers, which drain the Crested Butte area, were investigated in December 1996. Six sites were chosen for evaluation-four on the Slate River and two on the East River-to assess water-quality conditions, including nutrient (nitrogen and phosphorus) concentrations and algal biomass, during a 24-hour period. Discharge in the Slate River ranged from about 18 to 30 cubic feet per second, and discharge in the East River downstream from the mouth of the Slate River was about 80 cubic feet per second. Chemical concentrations in water in the Slate and East Rivers generally were dilute with specific-conductance values of 175 to 300 microsiemens per centimeter and alkalinity values of 40 to 110 milligrams per liter during low-flow conditions. Dissolved oxygen was at or near saturation at all measurements sites. Ammonia nitrogen concentrations increased downstream from Crested Butte and Mount Crested Butte in the Slate River and then returned to background concentrations in the East River. Concentrations of nitrite plus nitrate nitrogen increased downstream from the Crested Butte area, probably associated with the nitrification of the ammonia to nitrate, and concentrations then were diluted in the East River downstream from the confluence of the Slate River. Phosphorus concentrations also increased slightly in the reach downstream from Crested Butte and Mount Crested Butte. Algal biomass values increased downstream from the Crested Butte area, decreased to low values in a subsequent reach, and then returned to higher values downstream. Biomass values were similar to those found in unenriched to moderately enriched streams. The lower biomass and higher phosphorus values occurred in a reach that was covered completely with ice and snow. Algal biomass in this reach was extremely low, probably due to the absence of light. The biomass values upstream and downstream from this reach were moderately high and probably resulted in the lower phosphorus and possibly somewhat lower nitrogen, which suggests that benthic algae may be partially controlling the nutrient levels through assimilation and uptake. When light conditions restrict algal growth and subsequent loading occurs, the concentrations of phosphorus increase slightly. Once the physical limitation (absence of light) is removed, the biomass responds with a corresponding decrease in phosphorus. The nutrient concentrations were low and well below stream standards. Nutrient increases were measured downstream from Crested Butte and Mount Crested Butte, and these increases resulted in an increase of algal biomass. Overall results indicate that, at the present time, the Slate and East Rivers can assimilate winter low-flow nutrient loads.

Colorado↗

Irrigation-induced contamination of water, sediment, and biota in the western United States-synthesis of data from the National Irrigation Water Quality Program

In October 1985 the U.S. Department of the Interior (DOI), through the National Irrigation Water Quality Program (NIWQP), began a series of field investigations at 26 areas in the Western United States to determine whether irrigation drainage has had harmful effects on fish, wildlife, and humans or has reduced beneficial uses of water. In 1992 NIWQP initiated the Data Synthesis Project to evaluate data collected during the field investigations. Geologic, climatologic, and hydrologic data were evaluated and water, sediment, and biota from the 26 areas were analyzed to identify commonalities and dominant factors that result in irrigation-induced contamination of water and biota. Data collected for the 26 area investigations have been compiled and merged into a common data base. The structure of the data base is designed to enable assessment of relations between contaminant concentrations in water, sediment, and biota. The data base is available to the scientific community through the World Wide Web at URL http://www.usbr.gov/niwqp. Analysis of the data base for the Data Synthesis included use of summary statistics, factor analysis, and logistic regression. A Geographic Information System was used to store and analyze spatially oriented digital data such as land use, geology and evaporation rates. In the U.S. Department of the Interior (DOI) study areas, samples of water, bottom sediment, and biota were collected for trace-element and pesticide analysis. Contaminants most commonly associated with irrigation drainage were identified by comparing concentrations in water with established criteria. For surface water, the criteria used were typically chronic criteria for the protection of freshwater aquatic life. Because ground water can discharge to the surface where wildlife can be exposed to it, the criteria used for ground water were both the maximum contaminant levels (MCL's) for drinking water and the chronic criteria for the protection of freshwater aquatic life. Data collected by the NIWQP studies indicated that, in surface water, filtered and unfiltered samples had nearly the same concentrations of arsenic, boron, molybdenum, and selenium for concentrations greater than about 10 micrograms per liter. Therefore, in this concentration range, filtered concentrations can be directly compared to biological-effect levels developed for unfiltered samples. In the range of 1 to 10 micrograms per liter there may be a tendency for unfiltered arsenic concentrations to be greater than filtered concentrations. For selenium, however, the data suggest differences from equality in that range result from analytical imprecision and not a general tendency for unfiltered concentrations to be greater than filtered concentrations. This relation may not be true in lentic, nutrient-rich waters because in such settings algae can bioaccumulate large amounts of selenium and other trace elements. Selenium was the trace element in surface water that most commonly exceeded chronic criteria for the protection of freshwater aquatic life; more than 40 percent of the selenium concentrations in surface-water samples exceeded the U.S. Environmental Protection Agency (USEPA) aquatic-life chronic criterion (5 micrograms per liter). In 12 of the 26 areas at least 25 percent of the surface water-samples had selenium concentrations that either equaled or exceeded the chronic criterion (5 micrograms per liter). More than 28 percent of boron concentrations and almost 17 percent of the molybdenum concentrations exceeded the aquatic life criteria established by the State of California (550 and 19 micrograms per liter, respectively). In ground water, more than 22 percent of the arsenic concentrations and more than 35 percent of the selenium concentrations exceeded the MCL (10 and 50 micrograms per liter, respectively). Few samples of uranium in surface water exceeded a criterion for the protection of aquatic life (300 micrograms per liter), but 44 percent

Professional Paper↗

Evidence for Cambrian petroleum source rocks in the Rome trough of West Virginia and Kentucky, Appalachian basin

A 130-foot-thick Cambrian black shale sampled from a core between 11,150 and 11,195 feet in the Exxon No. 1 Smith well in Wayne County, W. Va., has been identified as a good to very good source rock. The black shale is located in the Middle Cambrian Rogersville Shale of the Conasauga Group. Total organic carbon (TOC) values of four samples that range from 1.2 to 4.4 weight percent (average 2.6 weight percent) are the highest reported to date in the pre-Knox section of the Rome trough. Although the samples are probably in the zone of gas generation based on their low hydrogen index values (55 to 63) and temperature maximum of second hydrocarbon peak (S 2 ) values of about 465°C, first hydrocarbon peak (S 1 ) values of 0.81 to 2.71 indicate that they contain free extractable hydrocarbons. A bitumen sample extracted from the Rogersville Shale is characterized by (1) a broad spectrum of n -alkanes from n -C 11 through n -C 30 , (2) strong odd-carbon predominance in the n -C 13 to n -C 19 range, and (3) small but detectable amounts of isoprenoids pristane and phytane. The strong odd-carbon predominance of the n -C 15 to n -C1 9 n-alkanes is commonly attributed to the Ordovician alga Gloeocapsomorpha prisca . This occurrence of G. prisca is among the first to be reported in Cambrian rocks. Thin black shale beds collected from the Lower to Middle Cambrian Rome Formation in the Texaco No. 1 Kirby well in Garrard County, Ky., have TOC values as high as 3.2 percent, hydrogen index values as high as 417, and bitumen extract characteristics similar to the Rogersville Shale. The bitumen extract from the Rogersville Shale compares very closely with oils or condensates from Cambrian reservoirs in the Carson Associates No. 1 Kazee well, Homer gas field, Elliott County, Ky.; the Inland No. 529 White well, Boyd County, Ky.; and the Miller No. 1 well, Wolfe County, Ky. These favorable oil-source rock correlations suggest a new petroleum system in the Appalachian basin that is characterized by a Conasauga Group source rock and Rome Formation and Conasauga Group reservoirs. This petroleum system probably extends along the Rome trough from eastern Kentucky to at least central West Virginia.

Kentucky, West Virginia↗

The Yellowstone hotspot, Greater Yellowstone ecosystem, and human geography

Active geologic processes associated with the Yellowstone hotspot are fundamental in shaping the landscapes of the greater Yellowstone ecosystem (GYE), a high volcanic plateau flanked by a crescent of still higher mountainous terrain. The processes associated with the Yellowstone hotspot are volcanism, faulting, and uplift and are observed in the geology at the surface. We attribute the driving forces responsible for the northeastward progression of these processes to a thermal plume rising through the Earth’s mantle into the base of the southwest-moving North American plate. This progression began 16 million years ago (Ma) near the Nevada-Oregon border and arrived at Yellowstone about 2 Ma. Before arrival of the hotspot, an older landscape existed, particularly mountains created during the Laramide orogeny about 70–50 Ma and volcanic terrain formed by Absaroka andesitic volcanism mostly between 50–45 Ma. These landscapes were more muted than the present, hotspot-modified landscape because the Laramide-age mountains had worn down and an erosion surface of low relief had developed on the Absaroka volcanic terrain. The Yellowstone Plateau was built by hotspot volcanism of rhyolitic lavas and caldera-forming rhyolite tuffs (ignimbrites). Streams eroding back into the edges of this plateau have created scenic waterfalls and canyons such as the Grand Canyon of the Yellowstone and Lewis Canyon. Rhyolite is poor in plant nutrients and forms sandy, well-drained soils that support the monotonous, fire-adapted lodgepole pine forests of the Yellowstone Plateau. Non-rhyolitic rocks surround this plateau and sustain more varied vegetation, including spruce, fir, and whitebark pine forests broken by grassy meadows. Heat from the hotspot rises upward and drives Yellowstone’s famed geysers, hot springs, and mudpots. These thermal waters are home to specialized, primitive ecosystems, rich in algae and bacteria. The rock alteration associated with hydrothermal systems creates the bright colors of Yellowstone’s Grand Canyon. Basin-and-range-style faulting has accompanied migration of the hotspot to Yellowstone and formed the linear mountains and valleys that occur north and south of the hotspot track, which is the present-day eastern Snake River Plain. High rates of basin-and-range faulting occurred adjacent to the migrating Yellowstone hotspot, creating distinctive landscapes within the GYE such as the Teton Range/Jackson Hole, with characteristic rugged, forested ranges and adjacent flat-floored grassy valleys. The difference in altitude between the mountains and valleys provides a topographic gradient in which vegetation maturation advances with altitude; animal-migration patterns also follow this trend. The valleys provide natural meadows, agricultural land, town sites, and corridors for roads. Uplift of the GYE by as much as 1 km (3,000 ft) during the last 5 million years has resulted in ongoing erosion of deep, steep-walled valleys. Many prominent ecological characteristics of Yellowstone derive from this hotspot-induced uplift, including the moderate- to high- altitude terrain and associated cool temperatures and deep snowfall. Modern and Pleistocene climate and associated vegetation patterns strongly relate to the topography created by the hotspot and its track along the eastern Snake River Plain. Winter air masses from the moist northern Pacific Ocean traverse the topographic low of the Snake River Plain to where orographic rise onto the Yellowstone Plateau and adjacent mountains produces deep snow. A winter precipitation shadow forms on the lee (eastern) sides of the GYE. During Pleistocene glacial times, this moisture conduit provided by the hotspot-track-produced ice-age glaciers that covered the core of the present GYE. These glaciers sculpted bedrock and produced glacial moraines that are both forested and unforested, sand and gravel of ice-marginal streams and outwash gravels that are commonly covered with sagebrush-grassland, and silty lake sediments that are commonly covered by lush grassland such as Hayden Valley. The effects of the Yellowstone hotspot also profoundly shaped the human history in the GYE. Uplift associated with the hotspot elevates the GYE to form the Continental Divide, and streams drain radially outward like spokes from a hub. Inhabitants of the GYE 12,000–10,000 years ago, as well as more recent inhabitants, followed the seasonal green-up of plants and migrating animals up into the mountain areas. During European immigration, people settled around Yellowstone in the lower parts of the drainages and established roads, irrigation systems, and cultural associations. The core Yellowstone highland is too harsh for agriculture and inhospitable to people in the winter. Beyond this core, urban and rural communities exist in valleys and are separated by upland areas. The partitioning inhibits any physical connection of communities, which in turn complicates pursuit of common interests across the whole GYE. Settlements thus geographically isolated evolved as diverse, independent communities

Idaho, Montana, Utah, Wyoming↗

The rocks and fossils of Glacier National Park: The story of their origin and history

The story of Glacier National Park begins about 500 million years ago, at a time when there were no mountains in the region - only a vast, exceedingly shallow sea, bordered by desolate plains. The sand, clay, and mud, in part very limy, that were laid down in this sea eventually hardened into the rocks that are now known as the Belt series. These are the principal rocks in the park. Scattered through these rocks are crinkled, limy masses of many forms, the remains of deposits made by colonies of algae. After the Belt series was laid down, successive seas slowly advanced and retreated through long ages across what is now Glacier National Park, burying the Belt rocks under younger ones. After another very long time, a gentle uplift, the forerunner of later events, brought this part of the continent above the reach of sea water for the last time. Much later, some 50 million years ago, the disturbance became far more intense. To climax this upheaval, a mass of rock thousands of feet thick and hundreds of miles long was shoved eastward for 35 miles or more. This tremendous dislocation, well exposed along the eastern boundary of the park, is known as the Lewis overthrust. When the rocks of the region emerged from the sea they began to be attacked by erosion. As successive periods of crustal movement and erosion continued, the younger rocks were slowly stripped off the Belt series and sculpture of the latter by weather and water shaped the early Rocky Mountains. The final episode in the park's geologic past was the ice age, beginning about a million years ago. Repeated advances and retreats of the great glaciers in the high valleys accentuated the mountain terrain and developed the scenic grandeur that is now Glacier National Park. One may say that the park is still in the ice age, for some glaciers still exist. The present report, companion to two more technical reports on the region, informally presents the story of the park's development through past eras for readers without geologic training. Many places worth visiting are cited in the text, and a shaded relief map is provided to help find them.

Professional Paper↗

Geology of Glacier National Park and the Flathead Region, Northwestern Montana

This report summarizes available data on two adjacent and partly overlapping regions in northwestern Montana. The first of these is Glacier National Park plus small areas east and west of the park. The second is here called, for convenience, the Flathead region; it embraces the mountains from the southern tip of Glacier Park to latitude 48 deg north and between the Great Plains on the east and Flathead Valley on the west. The fieldwork under the direction of the writer was done in 1948, 1949, 1950, and 1951, with some work in 1952 and 1953. The two regions together include parts of the Swan, Flathead, Livingstone, and Lewis Ranges. They are drained largely by branches of the Flathead River. On the east and north, however, they are penetrated by tributaries of the Missouri River and in addition by streams that flow into Canada. Roads and highways reach the borders of the regions; but there are few roads in the regions and only two highways cross them. The principal economic value of the assemblage of mountains described in the present report is as a collecting ground for snow to furnish the water used in the surrounding lowlands and as a scenic and wildlife recreation area. A few metallic deposits and lignitic coal beds are known, but these have not proved to be important and cannot, as far as can now be judged, be expected to become so. No oil except minor seeps has yet been found, and most parts of the two regions covered do not appear geologically favorable to the presence of oil in commercial quantities. The high, Hungry Horse Dam on which construction was in progress during the fieldwork now floods part of the Flathead region and will greatly influence the future of that region. The rocks range in age from Precambrian to Recent. The thickest units belong to the Belt series of Precambrian age, and special attention was paid to them. As a result, it is clear that at least the upper part of the series shows marked lateral changes within short distances. This fact introduces complexities into stratigraphic correlation and should be remembered wherever the series is studied. The stromatolites, or fossil algae, in the Belt series, although still imperfectly understood, give clues with respect to problems of ecology and stratigraphy. The subdivisions of the Belt series within the areas covered by the present report are, in ascending order, Altyn limestone, Appekunny argillite, Grinnell argillite, Siyeh limestone, and Missoula group. Local subdivisions of the Missoula group are possible in certain areas, and all the units just named are expected to be subdivided when detailed studies are undertaken. In the Glacier National Park and Flathead regions together, it is probable that between 25,000 and 30,000 feet of beds belonging to the Belt series, possibly more, are present. These consist largely of quartzitic argillite, quartzite, and carbonate rocks, mostly dolomitic. Small gabbroic and diabasic intrusive bodies and, at one horizon, basaltic lava are associated with the Belt series. Above the Belt series is a thick sequence of Cambrian, Devonian, and Carboniferous strata, in which limestone is dominant, followed by strata of Jurassic and Cretaceous age, largely limestone and shale and partly of terrestrial origin. Slightly consolidated gravel, sand, and silt of Tertiary age are preserved in some valleys and as erosional remnants on the plains close to the mountain border. Pleistocene and Recent glacial and fluviatile deposits are plentiful in mountain valleys and on the plains east of the mountains. Sufficient crustal movements took place during the latter part of Belt time to produce tension cracks that permitted some intrusion and related extrusion to occur. Broad crustal warping probably took place at intervals during the Paleozoic era, but these successive movements left little record other than the absence of sedimentary rock units that might otherwise have been deposited. The same can be said of much of the Me

Professional Paper↗

Geochemical Exploration Techniques Applicable in the Search for Copper Deposits

Geochemical exploration is an important part of copper-resource evaluation. A large number of geochemical exploration techniques, both proved and untried, are available to the geochemist to use in the search for new copper deposits. Analyses of whole-rock samples have been used in both regional and local geochemical exploration surveys in the search for copper. Analyses of mineral separates, such as biotite, magnetite, and sulfides, have also been used. Analyses of soil samples are widely used in geochemical exploration, especially for localized surveys. It is important to distinguish between residual and transported soil types. Orientation studies should always be conducted prior to a geochemical investigation in a given area in order to determine the best soil horizon and the best size of soil material for sampling in that area. Silty frost boils, caliche, and desert varnish are specialized types of soil samples that might be useful sampling media. Soil gas is a new and potentially valuable geochemical sampling medium, especially in exploring for buried mineral deposits in arid regions. Gaseous products in samples of soil may be related to base-metal deposits and include mercury vapor, sulfur dioxide, hydrogen sulfide, carbon oxysulfide, carbon dioxide, hydrogen, oxygen, nitrogen, the noble gases, the halogens, and many hydrocarbon compounds. Transported materials that have been used in geochemical sampling programs include glacial float boulders, glacial till, esker gravels, stream sediments, stream-sediment concentrates, and lake sediments. Stream-sediment sampling is probably the most widely used and most successful geochemical exploration technique. Hydrogeochemical exploration programs have utilized hot- and cold-spring waters and their precipitates as well as waters from lakes, streams, and wells. Organic gel found in lakes and at stream mouths is an unproved sampling medium. Suspended material and dissolved gases in any type of water may also be useful media. Samples of ice and snow have been used for limited geochemical surveys. Both geobotanical and biogeochemical surveys have been successful in locating copper deposits in many parts of the world. Micro-organisms, including bacteria and algae, are other unproved media that should be studied. Animals can be used in geochemical-prospecting programs. Dogs have been used quite successfully to sniff out hidden and exposed sulfide minerals. Tennite mounds are commonly composed of subsurface material, but have not as yet proved to be useful in locating buried mineral deposits. Animal tissue and waste products are essentially unproved but potentially valuable sampling media. Knowledge of the location of areas where trace-element-associated diseases in animals and man are endemic as well as a better understanding of these diseases, may aid in identifying regions that are enriched in or depleted of various elements, including copper. Results of analyses of gases in the atmosphere are proving valuable in mineral-exploration surveys. Studies involving metallic compounds exhaled by plants into the atmosphere, and of particulate matter suspended in the atmosphere are reviewed these methods may become important in the future. Remote-sensing techniques are useful for making indirect measurements of geochemical responses. Two techniques applicable to geochemical exploration are neutron-activation analysis and gamma-ray spectrometry. Aerial photography is especially useful in vegetation surveys. Radar imagery is an unproved but potentially valuable method for use in studies of vegetation in perpetually clouded regions. With the advent of modern computers, many new techniques, such as correlation analysis, regression analysis, discriminant analysis, factor analysis, cluster analysis, trend-surface analysis, and moving-average analysis can be applied to geochemical data sets. Selective use of these techniques can provide new insights into the interpretatio

Professional Paper↗

Chloroform in the hydrologic system--sources, transport, fate, occurrence, and effects on human health and aquatic organisms

Chloroform is one of the volatile organic compounds (VOCs) detected most frequently in both ground and surface water. Because it is also one of the four trihalomethanes (THMs) produced in the highest concentrations during the chlorination of drinking water and wastewater, the frequent detection of this compound in ground and surface water of the United States is presumed to be caused primarily by the input of chlorinated water to the hydrologic system. Although anthropogenic sources of the compound are substantial, they are currently estimated to constitute only 10 percent of the total global input to the hydrologic system. Natural sources of the compound include volcanic gases, biomass burning, marine algae, and soil microorganisms. Under most conditions (except in the presence of unusually high bromide concentrations), chloroform is the THM produced in the highest concentrations during chlorination. Furthermore, in most cases where more than one THM is produced from chlorination, the relative concentrations among the different compounds usually decrease with increasing bromination (chloroform > dichlorobromomethane > chlorodibromomethane > bromoform). This phenomenon is presumed to be responsible for the common observation that when more than one THM is detected during investigations of the occurrence of these compounds in the hydrologic system, this same trend is typically observed among their relative concentrations or, for a uniform reporting limit, their relative frequencies of detection. This pattern could provide a valuable means for distinguishing between chlorinated water and other potential sources of chloroform in the environment. Chloroform has been widely detected in national, regional, and local studies of VOCs in ground, surface, source, and drinking waters. Total THM (TTHM) concentrations of the compound, however, were typically less than the Maximum Contaminant Level (MCL) of 80 ?g/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA) for TTHMs. In the studies that compared land-use settings, frequencies of detection of chloroform were higher beneath urban and residential areas than beneath agricultural or undeveloped areas. Because chloroform is a suspected human carcinogen, its presence in drinking water is a potential human health concern. Liver damage, however, is known to occur at chloroform exposures lower than those required to cause cancer, an observation that has been considered by the USEPA as the basis for setting a new, non-zero Maximum Contaminant Level Goal of 70 ?g/L for the compound. As part of its National Water-Quality Assessment Program, the U.S. Geological Survey has been assembling and analyzing data on the occurrence of VOCs (including chloroform) in ground and surface water on a national scale from studies conducted between 1991 and the present. This report presents a summary of current (2004) information on the uses, sources, formation, transport, fate, and occurrence of chloroform, as well as its effects on human health and aquatic organisms.

Scientific Investigations Report↗

Hydrology and cycling of nitrogen and phosphorus in Little Bean Marsh: A remnant riparian wetland along the Missouri River in Platte County, Missouri, 1996–97

The lack of concurrent water-quality and hydrologic data on riparian wetlands in the Midwestern United States has resulted in a lack of knowledge about the water-quality functions that these wetlands provide. Therefore, Little Bean Marsh, a remnant riparian wetland along the Missouri River, was investigated in 1996 and 1997 primarily to determine the magnitude and character of selected water-quality benefits that can be produced in such a wetland and to identify critical processes that can be managed in remnant or restored riparian wetlands for amelioration of water quality. Little Bean Marsh averages 69 hectares in size, has a maximum depth of about 1 meter, and the majority of the marsh is covered by macrophytes. In 1997, 41 percent of the water received by Little Bean Marsh was from direct precipitation, 14 percent was from ground-water seepage, 30 percent from watershed runoff, and 15 percent was backflow from Bean Lake. Although, Little Bean Marsh was both a ground-water recharge and discharge area, discharge to the marsh was three times the recharge to ground water. Ground-water levels closely tracked marsh water levels indicating a strong hydraulic connection between ground water and the marsh. Reduced surface runoff and ground-water availability are stabilizing influences on marsh hydrology and probably contribute to the persistence of emergent vegetation. The rapid hydraulic connection between Little Bean Marsh and ground water indicates that the hydrologic regime of most wetlands along the lower Missouri River is largely a function of the altitude of the marsh bottom relative to the altitude of the water table. More water was lost from the marsh through evapotranspiration (59 percent) than all other pathways combined. This is partially because the transpiration process of abundant macrophytes can greatly contribute to the evapotranspiration above that lost from open water surfaces. Surface outflow accounted for 36 percent and ground-water seepage accounted for only 5 percent of the losses. Large residence times allows the marsh to greatly affect water quality before water escapes as ground-water recharge or surface outflow. The shallowness of Little Bean Marsh and ion exclusion during ice formation caused the highest specific conductances of 1,100 to 1,300 microsiemens per centimeter at 25 degrees Celsius to occur during the winter. This concentration of dissolved solutes under ice can make wetlands more vulnerable to toxic contaminants than deeper surface-water bodies. Dissolved oxygen was less than 5 mg/L (milligrams per liter) for 3 to 4 months and near 0 mg/L for about 1 month in summer. Despite depths of less than 1 meter, temperature stratification persisted more than 3 months during the summers of 1996 and 1997, preventing mixing and contributing to periods of anoxia. Shallow depths and extended periods of anoxia in the marsh limit the ability of some organisms to escape high-temperature stress. Turbidity in Little Bean Marsh usually was low for several reasons: sediment loadings from the largely flood-plain drainage were low, emergent vegetation shade out algae and shield the water from wind, and high concentrations of bivalent cations increase flocculation rates of inorganic suspended material. The high concentrations of bivalent cations was largely because of a substantial amount of ground-water seepage into the marsh. Dissolved organic nitrogen was the dominant nitrogen species in Little Bean Marsh. Denitrification and biotic uptake kept more than 62 percent of nitrate (NO3) and 43 percent of ammonium (NH4) concentrations in marsh samples less than a detection limit of 0.005 mg/L. This contrasts with the Missouri River where inorganic NO3 dominates. Consequently, artificial flood-plain drainage that bypasses riparian wetlands likely deliver substantially more biotically available inorganic nitrogen to receiving waters than surface water that has been routed through a remnant wetland. Average total nitrogen concentrations in Little Bean Marsh were substantially less than those at other Missouri River wetlands, roughly one-half the mean concentrations in the Missouri River, but roughly twice the average nitrogen values in reservoirs of the glaciated plains of Missouri. The largest concentrations of nearly all species of nitrogen and phosphorus and the most intense period of hypereutrophy coincided with a phytoplankton bloom and senescence of River Bulrush (Scirpus fluviatilis) and common cattail (Typha latifolia) in September 1997. The rapid leaching of nitrogen that occurs soon after macrophyte senescence combined with a recent destratification of the marsh probably provided nitrogen to the nitrogen-limited open-water areas and triggered a phytoplankton bloom. Despite the rarity of runoff events, surface runoff from the watershed, combined with atmospheric deposition, contributed more than seven times the 530 kg (kilograms) of nitrogen that escaped Little Bean Marsh in surface outflow during 1997. Atmospheric deposition alone was more than 530 kg. Seepage to ground water contained less than 1.5 percent of the nitrogen leaving the marsh in surface outflow. The slow decay rate of Scirpus fluviatilis and reducing conditions in bottom sediments make burial of organic nitrogen a substantial sink of nitrogen. Denitrification experiments indicate that denitrification rates were limited by NO3 in the water column. Consequently, decomposition and nitrification of NH4 and organic nitrogen are the rate limiting steps of nitrogen removal in Little Bean Marsh. The NO3-limited rates of denitrification also indicate that Little Bean Marsh has a large unused capacity for nitrogen removal. These data indicate that the vast extent of riparian marshes along the Missouri and Mississippi Rivers may have had a substantial role in limiting NO3 loads to the Gulf of Mexico before agricultural development of flood plains. Drainage and removal of riparian marshes may be a major cause of the increased NO3 loads to the Gulf of Mexico. Periods of anoxia had much larger effects on phosphorus release than the other variables. The largest concentrations of phosphorus occurred in late summer and corresponded with senescing macrophytes, periods of anoxia, and a large algal bloom in Little Bean Marsh. Low water levels prevented the escape of phosphorus in surface outflow during these periods of highest phosphorus concentrations. Dry weather in late summer is typical and probably makes the correspondence of low water levels, anoxia, and consequent low phosphorus release a common occurrence in marshes along the Missouri River. Little Bean Marsh retained more than 95 percent of the phosphorus it received. The amount of phosphorus in surface inflows to the marsh were more than one order of magnitude greater than that escaping in surface outflows. The long hydraulic residence time of the marsh and large contributions of iron from ground water (that provide many sorption sites for phosphorus) make the marsh an effective sediment and phosphorus trap.

Missouri↗