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At least 631 records · Page 35Linked to original sources
USGS2010

Gas transport in unsaturated porous media: The adequacy of Fick's law

The increasing use of natural unsaturated zones as repositories for landfills and disposal sites for hazardous wastes (chemical and radioactive) requires a greater understanding of transport processes in the unsaturated zone. For volatile constituents an important potential transport mechanism is gaseous diffusion. Diffusion, however, cannot be treated as an independent isolated transport mechanism. A complete understanding of multicomponent gas transport in porous media (unsaturated zones) requires a knowledge of Knudsen transport, the molecular and nonequimolar components of diffusive flux, and viscous (pressure driven) flux. The constitutive equations relating these flux components are available from the “dusty gas” model of Mason et al. (1967). This review presents a brief discussion of the underlying principles and interrelationships among each of the above flux mechanisms. Some aspects of these transport mechanisms are, to our knowledge, generally unrecognized in the Earth science literature. The principles underlying the transport mechanisms are illustrated with binary systems; the constitutive equations are then cast in forms thought to be most useful for the study of natural unsaturated zones. The viscous and diffusive fluxes are coupled in the constitutive equations through the Knudsen diffusivities; a knowledge of Knudsen diffusivities is necessary to calculate the viscous component of flux and pressure gradients. The Knudsen diffusivities can be calculated from measurements of the Klinkenberg effect. Two examples are presented showing that in natural systems, very small pressure gradients (1 Pa/m or less) can produce viscous fluxes greater than or equal to diffusive fluxes and that, conversely, pressure gradients of this magnitude can be generated by diffusive processes. The example calculations show that major concentration gradients can be developed for stagnant (zero flux, nonreactive) gases. A method is presented for approximating the viscous and diffusive flux components of gases in a multicomponent system from a knowledge of the concentration profiles of stagnant gases. In subsoil environments, argon and nitrogen are considered to be stagnant gases. Fick's laws are essentially, by definition, inadequate to deal with stagnant gases. In the examples presented, the error associated with estimating the total fluxes of nonstagnant gases by Fick's law, relative to stationary coordinates, ranges from a few percent to orders of magnitude.

Reviews of Geophysics↗
USGS2010

Intra- and interspecific facilitation in mangroves may increase resilience to climate change threats

Mangroves are intertidal ecosystems that are particularly vulnerable to climate change. At the low tidal limits of their range, they face swamping by rising sea levels; at the high tidal limits, they face increasing stress from desiccation and high salinity. Facilitation theory may help guide mangrove management and restoration in the face of these threats by suggesting how and when positive intra- and interspecific effects may occur: such effects are predicted in stressed environments such as the intertidal, but have yet to be shown among mangroves. Here, we report the results of a series of experiments at low and high tidal sites examining the effects of mangrove density and species mix on seedling survival and recruitment, and on the ability of mangroves to trap sediment and cause surface elevation change. Increasing density significantly increased the survival of seedlings of two different species at both high and low tidal sites, and enhanced sediment accretion and elevation at the low tidal site. Including Avicennia marina in species mixes enhanced total biomass at a degraded high tidal site. Increasing biomass led to changed microenvironments that allowed the recruitment and survival of different mangrove species, particularly Ceriops tagal .

Philosophical Transactions of the Royal Society B:↗
USGS2024

Wildfires influence mercury transport, methylation, and bioaccumulation in headwater streams of the Pacific Northwest

The increasing frequency and severity of wildfires are among the most visible impacts of climate change. However, the effects of wildfires on mercury (Hg) transformations and bioaccumulation in stream ecosystems are poorly understood. We sampled soils, water, sediment, in-stream leaf litter, periphyton, and aquatic invertebrates in 36 burned (one-year post fire) and 21 reference headwater streams across the northwestern U.S. to evaluate the effects of wildfire occurrence and severity on total Hg (THg) and methylmercury (MeHg) transport and bioaccumulation. Suspended particulate THg and MeHg concentrations were 89 and 178% greater in burned watersheds compared to unburned watersheds and increased with burn severity, likely associated with increased soil erosion. Concentrations of filter-passing THg were similar in burned and unburned watersheds, but filter-passing MeHg was 51% greater in burned watersheds, and suspended particles in burned watersheds were enriched in MeHg but not THg, suggesting higher MeHg production in burned watersheds. Among invertebrates, MeHg in grazers, filter-feeders, and collectors was 33, 48, and 251% greater in burned watersheds, respectively, but did not differ in shredders or predators. Thus, increasing wildfire frequency and severity may yield increased MeHg production, mobilization, and bioaccumulation in headwaters and increased transport of particulate THg and MeHg to downstream environments.

Idaho, Oregon, Washington↗
USGS2007

Ecological Investigations of the Federally Endangered Shivwits Milk-Vetch (Astragalus ampullarioides)--2006 Annual Report

Astragalus ampullarioides (Welsh) Welsh, the Shivwits milk-vetch, is an herbaceous perennial legume that was listed as federally endangered in September 2001. Known populations of this edaphic endemic species are restricted to Washington County, Utah, with the majority of occurrences found on gently sloping outcrops of the Triassic Petrified Forest Member of the Chinle Formation at the edge of the Mojave Desert. At the time of listing in 2001, surveys estimated a total of 1000 individuals for the species. In April-May 2006, surveys estimated approximately 4205 individuals distributed among six populations. Of the total number of individuals estimated in spring 2006, over 75 percent were distributed among three subpopulations in Zion National Park and approximately 60 percent occurred at a single 0.3-ha site in the Park. In addition to small population sizes and limited geographic distributions, the species is threatened to varying degrees by urbanization, livestock grazing, off-road vehicle use, and invasive exotic plants. In April 2006, the U.S. Geological Survey (USGS) initiated ecological investigations of the Shivwits milk-vetch to support conservation management and recovery of the species by the National Park Service (NPS; Zion National Park), the U.S. Fish and Wildlife Service (USFWS), the Bureau of Land Management (BLM), the Shivwits Band of the Paiute Tribe, and other cooperators such as The Nature Conservancy of Utah (TNC). To date, funding for this research has been provided by the Southwest Biological Science Center of the USGS Biological Resources Discipline, the USGS-NPS Park-Oriented Biological Support Project, and the Earth Surface Dynamics Program of the USGS Geologic Discipline. Additional logistical support has been provided by the Bureau of Land Management, Grand Staircase-Escalante National Monument. General objectives of this research are (1) to develop a better understanding of species-environment relations to support habitat modelling, future surveys for additional recovery populations, and potential efforts to establish new recovery populations; and (2) to evaluate effects of invasive exotic plants on habitat conditions and measures of milk-vetch performance. Specific objectives are to: Describe the distribution and abundance of milk-vetch populations and associated invasive exotic plant species within and outside of Zion National Park (Zion NP) in relation to geologic / geomorphic setting, soil properties, and plant community composition. In a field setting in Zion NP, conduct experiments to evaluate effects of invasive exotic plants on reproductive output and seedling establishment of A. ampullarioides across a gradient of exotic species biomass. Conduct greenhouse studies and analyze soils to evaluate effects of invasive exotic plants on soil biological properties (including mycorrhizal inocculation potential) that affect cycling and plant uptake of essential mineral nutrients. Based on environmental characteristics of known population locations, use Geographic Information System (GIS) tools to prepare a predictive habitat model that can be used to guide future surveys and efforts to evaluate sites for reintroduction efforts. This report describes 2006 progress and future plans for achieving these four objectives.

Open-File Report↗
USGS2011

Overview of the ARkStorm scenario

The U.S. Geological Survey, Multi Hazards Demonstration Project (MHDP) uses hazards science to improve resiliency of communities to natural disasters including earthquakes, tsunamis, wildfires, landslides, floods and coastal erosion. The project engages emergency planners, businesses, universities, government agencies, and others in preparing for major natural disasters. The project also helps to set research goals and provides decision-making information for loss reduction and improved resiliency. The first public product of the MHDP was the ShakeOut Earthquake Scenario published in May 2008. This detailed depiction of a hypothetical magnitude 7.8 earthquake on the San Andreas Fault in southern California served as the centerpiece of the largest earthquake drill in United States history, involving over 5,000 emergency responders and the participation of over 5.5 million citizens. This document summarizes the next major public project for MHDP, a winter storm scenario called ARkStorm (for Atmospheric River 1,000). Experts have designed a large, scientifically realistic meteorological event followed by an examination of the secondary hazards (for example, landslides and flooding), physical damages to the built environment, and social and economic consequences. The hypothetical storm depicted here would strike the U.S. West Coast and be similar to the intense California winter storms of 1861 and 1862 that left the central valley of California impassible. The storm is estimated to produce precipitation that in many places exceeds levels only experienced on average once every 500 to 1,000 years. Extensive flooding results. In many cases flooding overwhelms the state’s flood-protection system, which is typically designed to resist 100- to 200-year runoffs. The Central Valley experiences hypothetical flooding 300 miles long and 20 or more miles wide. Serious flooding also occurs in Orange County, Los Angeles County, San Diego, the San Francisco Bay area, and other coastal communities. Windspeeds in some places reach 125 miles per hour, hurricane-force winds. Across wider areas of the state, winds reach 60 miles per hour. Hundreds of landslides damage roads, highways, and homes. Property damage exceeds $ 300 billion, most from flooding. Demand surge (an increase in labor rates and other repair costs after major natural disasters) could increase property losses by 20 percent. Agricultural losses and other costs to repair lifelines, dewater (drain) flooded islands, and repair damage from landslides, brings the total direct property loss to nearly $ 400 billion, of which $ 20 to $ 30 billion would be recoverable through public and commercial insurance. Power, water, sewer, and other lifelines experience damage that takes weeks or months to restore. Flooding evacuation could involve 1.5 million residents in the inland region and delta counties. Business interruption costs reach $ 325 billion in addition to the $ 400 billion property repair costs, meaning that an ARkStorm could cost on the order of $ 725 billion, which is nearly 3 times the loss deemed to be realistic by the ShakeOut authors for a severe southern California earthquake, an event with roughly the same annual occurrence probability. The ARkStorm has several public policy implications: (1) An ARkStorm raises serious questions about the ability of existing federal, state, and local disaster planning to handle a disaster of this magnitude. (2) A core policy issue raised is whether to pay now to mitigate, or pay a lot more later for recovery. (3) Innovative financing solutions are likely to be needed to avoid fiscal crisis and adequately fund response and recovery costs from a similar, real, disaster. (4) Responders and government managers at all levels could be encouraged to conduct risk assessments, and devise the full spectrum of exercises, to exercise ability of their plans to address a similar event. (5) ARkStorm can be a reference point for application of Federal Emergency Management Agency (FEMA) and California Emergency Management Agency guidance connecting federal, state and local natural hazards mapping and mitigation planning under the National Flood Insurance Plan and Disaster Mitigation Act of 2000. (6) Common messages to educate the public about the risk of such an extreme disaster as the ARkStorm scenario could be developed and consistently communicated to facilitate policy formulation and transformation. These impacts were estimated by a team of 117 scientists, engineers, public-policy experts, insurance experts, and employees of the affected lifelines. In many aspects the ARkStorm produced new science, such as the model of coastal inundation. The products of the ARkStorm are intended for use by emergency planners, utility operators, policymakers, and others to inform preparedness plans and to enhance resiliency.

California↗
USGS2004

Wilderness experience in Rocky Mountain National Park 2002: Report to RMNP

Approximately 250,000 acres of backcountry in Rocky Mountain National Park (RMNP or the Park) may be designated as wilderness use areas in the coming years. Currently, over 3 million people visit RMNP each year; many drive through the park on Trail Ridge Road, camp in designated campgrounds, or hike in front-country areas. However, visitors also report much use of backcountry areas that are not easily accessible by roads or trails. Use of the backcountry is growing at RMNP and is accompanied by changing visitor expectations and preferences for wilderness management. For these reasons it is of great importance for the Park to periodically assess what types of environments and conditions wilderness users seek, to help them facilitate a quality wilderness experience. To assist in this effort, the Political Analysis and Science Assistance [PASA] program / Fort Collins Science Center / U.S. Geological Survey, in close collaboration with personnel and volunteers from RMNP and in cooperation with the Natural Resource Recreation and Tourism [NRRT] Department at CSU, and launched a research effort in the summer of 2002 to investigate visitor numbers, wilderness experiences, and management preferences in the Park. Specifically, the purposes of the research reported here are: (1) To determine what constitutes a wilderness experience; (2) To identify important places, visual features, and sounds essential to a quality wilderness experience and; (3) To determine what aspects may detract from wilderness experience in RMNP. Thus, answers to these questions should provide insight for Park managers about visitors' expectations for wilderness recreation and the conditions they seek for quality wilderness experiences. Ultimately, this information can be used to support wilderness management decisions within RMNP. The social science technique of Visitor Employed Photography [VEP] was used to obtain information from visitors about wilderness experiences. Visitors were selected at random from Park-designated wilderness trails, in proportion to their use, and asked to participate in the survey. Respondents were given single-use, 10-exposure cameras and photo-log diaries to record experiences. A total of 293 cameras were distributed, with a response rate of 87%. Following the development of the photos, a copy of the photos, two pertinent pages from the photo-log, and a follow-up survey were mailed to respondents. Fifty six percent of the follow-up surveys were returned. Findings from the two surveys were analyzed and compared.

Open-File Report↗
USGS2011

Transfer and transformation of soil iron and implications for hydrogeomorpholocial changes in Naoli River catchment, sanjiang plain, Northeast China

Wetland soils are characterized by alternating redox process due to the fluctuation of waterlogged conditions. Iron is an important redox substance, and its transfer and transformation in the wetland ecosystem could be an effective indicator for the environment changes. In this paper, we selected the Naoli River catchment in the Sanjiang Plain, Northeast China as the study area to analyze the dynamics of transfer and transformation of soil iron, and the relationship between iron content change and environmental factors. The results show that the total and crystalline iron contents reach the peak in the depth of 60 cm in soil profile, while the amorphous iron content is higher in the topsoil. In the upper reaches, from the low to high landscape positions, the total and crystalline iron contents decrease from 62.98 g/kg to 41.61 g/kg, 22.82 g/kg to 10.53 g/kg respectively, while the amorphous iron content increases from 2.42 g/kg to 8.88 g/kg. Amorphous iron content has positive correlation with organic matter and soil water contents, while negative correlation with pH. Moreover, both the crystalline and amorphous iron contents present no correlation with total iron content, indicating that environmental factors play a more important role in the transfer and transformation of iron other than the content of the total iron. Different redoximorphic features were found along the soil profile due to the transfer and transformation of iron. E and B horizons of wetland soil in the study area have a matrix Chroma 2 or less, and all the soil types can meet the criteria of American hydric soil indicators except albic soil. ?? Science Press, Science Press, Northeast Institute of Geography and Agroecology, CAS and Springer-Verlag Berlin Heidelberg 2011.

Chinese Geographical Science↗
USGS2008

Magnetic monitoring of earth and space

For centuries, navigators of the world’s oceans have been familiar with an effect of Earth’s magnetic field: It imparts a directional preference to the needle of a compass. Although in some settings magnetic orientation remains important, the modern science of geomagnetismhas emerged from its romantic nautical origins and developed into a subject of great depth and diversity. The geomagnetic field is used to explore the dynamics of Earth’s interior and its surrounding space environment, and geomagnetic data are used for geophysical mapping, mineral exploration, risk mitigation, and other practical applications. A global distribution of ground-based magnetic observatories supports those pursuits by providing accurate records of the magnetic-field direction and intensity at fixed locations and over long periods of time. Magnetic observatories were first established in the early 19th century in response to the influence of Alexander von Humboldt and Carl Friedrich Gauss. Since then, magnetic measurement has advanced significantly, progressing from simple visual readings of magnetic survey instruments to include automatic photographic measurement and modern electronic acquisition. To satisfy the needs of the scientific community, observatories are being upgraded to collect data that meet ever more stringent standards, to achieve higher acquisition frequencies, and to disseminate data in real time. To appreciate why data from magnetic observatories can be used for so many purposes, one needs only to recall that the geomagnetic field is a continuum, connecting the different parts of Earth to each other and to nearby space. Beneath our feet and above our heads, electric currents generate magnetic fields that contribute to the totality of the geomagnetic field measured at an observatory on Earth’s surface. The many physical processes that operate in each geophysical domain give rise to a complicated field that exhibits a wide variety of time-dependent behavior. In this article I review the status of the global community of magnetic observatories, show how Earth and space can be monitored for purposes of scientific understanding and practical application, and highlight the role played by magnetic observatories in the history of geomagnetism research.

Physics Today↗
USGS2025

The US EPA’s National Nutrient Inventory: Critical shifts in US nutrient pollution sources from 1987 to 2017

Efforts to constrain the negative environmental impacts of excess nitrogen (N) and phosphorus (P) are costly and challenging, due in part to inconsistent reporting of nutrient sources at temporal and spatial scales relevant for local decision making. To meet this challenge, the U.S. Environmental Protection Agency’s National Nutrient Inventory provides estimates of major agricultural, urban, atmospheric, and natural nutrient fluxes for the contiguous United States at county and HUC12 scales annually from 1987 (from 1950 for agriculture) to 2017. Since the late 1980s, total N emissions and atmospheric N deposition have declined 22% and 15%, respectively, despite increased agricultural emissions. Over the same period, municipal wastewater N and P loads remained largely stable, despite population increases, through wastewater treatment upgrades and the phaseout of phosphorus-containing detergents. Improved agricultural efficiency allowed for dramatic increases in agricultural production and crop harvest since 1987 (∼25% for N and P), with little change in surplus nutrients left on fields. Overall, a combination of innovative technologies and management has stemmed or even decreased major sources of nutrient pollution to the environment over the last several decades, representing an important shift that, if continued, may contribute to improved air, land, and water quality and human health.

contiguous United States↗
USGS2003

Use of similar habitat by cutthroat trout and brown trout in a regulated river during winter

Few differences in habitat use were observed between cutthroat trout and brown trout during winter in the Shoshone River, a regulated river in northwestern Wyoming. Radio-tagged fish of 20-30 cm total length were found in pool habitat five to six times more frequently than would be expected if they were using pools in proportion to pool availability. Nevertheless, run habitat was most frequently used by both species. The microhabitat characteristics at locations of each species were similar when in both pools and runs, however, habitat use was variable suggesting that a variety of microhabitats were suitable over-wintering habitat. Brown trout were more frequently associated with boulder cover than were cutthroat trout. Cutthroat trout used large pools that provided refuge from high water velocities more frequently that brown trout. Cutthroat trout and brown trout were found at similar distances from the bank except in late February when cutthroat trout were farther from the bank. Both species moved frequently during the winter, but cutthroat trout showed a greater propensity than brown trout to move long distances. This study suggests that during a mild winter in a stable environment, these species were able to overwinter successfully in a variety of habitats.

Northwest Science↗
USGS2012

Data resources for the Wyoming Landscape Conservation Initiative (WLCI) Integrated Assessment (IA)

The data contained in this report were compiled, modified, and analyzed for the Wyoming Landscape Conservation Initiative (WLCI) Integrated Assessment (IA). The WLCI is a long-term science based effort to assess and enhance aquatic and terrestrial habitats at a landscape scale in southwest Wyoming while facilitating responsible energy development through local collaboration and partnerships. The IA is an integrated synthesis and analysis of WLCI resource values based on best available data and information collected from multiple agencies and organizations. It is a support tool for landscape-scale conservation planning and evaluation, and a data and analysis resource that can be used for addressing specific management questions. The IA analysis was conducted using a Geographic Information System in a raster (that is, a grid) environment using a cell size of 30 meters. To facilitate the interpretation of the data in a regional context, mean values were summarized and displayed at the subwatershed unit (WLCI subwatersheds were subset from the National Hydrography Dataset, Hydrologic Unit Code 12/Level 6). A dynamic mapping platform, accessed via the WLCI webpage at http://www.wlci.gov is used to display the mapped information, and to access underlying resource values that were combined to produce the final mapped results. The raster data used in the IA are provided here for use by interested parties to conduct additional analyses and can be accessed via the WLCI webpage. This series contains 74 spatial data sets: WLCI subwatersheds (vector) and 73 geotiffs (raster) that are segregated into the major categories of Multicriteria Index (including Resource Index and Condition), Change Agents, and Future Change. The Total Multicriteria Index is composed of the Aquatic Multicriteria Index and the Terrestrial Multicriteria Index. The Aquatic Multicriteria Index is composed of the Aquatic Resource Index and the Aquatic Condition. The Aquatic Resource Index is composed of the following components: Groundwater, Special Management Areas, and Priority Areas. The Aquatic Condition is composed of the following components: Focal Species, Species of Concern, Focal Ecosystems, and Proper Functioning Condition. The Terrestrial Multicriteria Index is composed of the Terrestrial Resource Index and the Terrestrial Condition. The Terrestrial Resource Index is composed of the following components: Special Management Areas, Agriculture, and Priority Areas. The Terrestrial Condition is composed of the following components: Focal Species, Big Game, Species of Concern, Rare Plants, and Focal Ecosystems. The Change Agents are composed the following components: Roads, Energy, Mines, and Urban. The Future Change is composed of the following components: Oil-Gas-Coal, Wind, Minerals, Climate-Temperature, Invasive Species, and Urban.

Wyoming↗
USGS2016

Copper speciation in variably toxic sediments at the Ely Copper Mine, Vermont, United States

At the Ely Copper Mine Superfund site, Cu concentrations exceed background values in both streamwater (160–1200 times) and sediments (15–79 times). Previously, these sediment samples were incubated with laboratory test organisms, and they exhibited variable toxicity for different stream sites. In this study we combined bulk- and microscale techniques to determine Cu speciation and distribution in these contaminated sediments on the basis of evidence from previous work that Cu was the most important stressor in this environment and that variable observed toxicity could have resulted from differences in Cu speciation. Copper speciation results were similar at microscopic and bulk scales. The major Cu species in the more toxic samples were sorbed or coprecipitated with secondary Mn (birnessite) and Fe minerals (jarosite and goethite), which together accounted for nearly 80% of the total Cu. The major Cu species in the less toxic samples were Cu sulfides (chalcopyrite and a covellite-like phase), making up about 80–95% of the total Cu, with minor amounts of Cu associated with jarosite or goethite. These Cu speciation results are consistent with the toxicity results, considering that Cu sorbed or coprecipitated with secondary phases at near-neutral pH is relatively less stable than Cu bound to sulfide at lower pH. The more toxic stream sediment sites were those that contained fewer detrital sulfides and were upstream of the major mine waste pile, suggesting that removal and consolidation of sulfide-bearing waste piles on site may not eliminate all sources of bioaccessible Cu.

Vermont↗
USGS2008

Influence of habitat amount, arrangement, and use on population trend estimates of male Kirtland's warblers

Kirtland's warblers (Dendroica kirtlandii) persist in a naturally patchy environment of young, regenerating jack pine forests (i.e., 5-23 years old) created after wildfires and human logging activities. We examined how changing landscape structure from 26 years of forest management and wildfire disturbances influenced population size and spatial dispersion of male Kirtland's warblers within their restricted breeding range in northern Lower Michigan, USA. The male Kirtland's warbler population was six times larger in 2004 (1,322) compared to 1979 (205); the change was nonlinear with 1987 and 1994 identified as significant points of change. In 1987, the population trend began increasing after a slowly declining trend prior to 1987, and the rate of increase appeared to slow after 1994. Total amount of suitable habitat and the relative area of wildfire-regenerated habitat were the most important factors explaining population trend. Suitable habitat increased 149% primarily due to increasing plantations from forest management. The relative amount and location of wildfire-regenerated habitat modified the distribution of males among various habitat types, and the spatial variation in their abundance across the primary breeding range. These findings indicate that the Kirtland's warbler male population shifted its use of habitat types temporally and spatially as the population increased and as the relative availability of habitats changed through time. We demonstrate that researchers and managers need to consider not only habitat quality, but the temporal and the spatial context of habitat availability and population levels when making habitat restoration decisions. ?? 2008 Springer Science+Business Media B.V.

Landscape Ecology↗
USGS2006

An estimation of carrying capacity for sea otters along the California coast

Carrying capacity (K) for the California sea otter ( Enhydra lutris nereis ) was estimated as a product of the density of sea otters at equilibrium within a portion of their existing range and the total area of available habitat. Equilibrium densities were determined using the number of sea otters observed during spring surveys in 1994, 1995, and 1996 in each of three habitat types where sea otters currently exist. Potential sea otter habitat was defined as from the California coastline to the 40-m isobath and classified as rocky, sandy, or mixed habitat according to the amount of kelp and rocky substrate in the area. The amount of habitat available to sea otters in California was estimated using a Geographic Information Systems (GIS) program. The estimated mean number of sea otters that could be supported by the marine environment to a depth of 40 m in California was 15,941 (95% CI 13,538–18,577). The GIS-based approach incorporated detailed bathymetric contours, produced repeatable and accurate estimates, and served as an innovative method of measuring sea otter habitat. We believe the approach described in this paper represents the best available information on how a sea otter population at equilibrium would be distributed along the California coast.

California↗
USGS1999

Temporal variations in dissolved selenium in Lake Kinneret (Israel)

Selenium is an essential micronutrient for the growth of the dinoflagellate Peridinium gatunense that dominates the spring algal bloom in Lake Kinneret (LK). The relationship between the levels of dissolved selenium species and the occurance of algal blooms in this lake was studied. During algal blooms of P. gatunense in spring and of the blue-green Aphanizomenon ovalisporum in fall (in 1994) the concentration of epilimnetic dissolved organic Se (Se(org)) increased whereas that of selenite (SeIV) decreased, to levels below the limit of detection: 5 ng/l. The disappearance of SeIV during these blooms is attributed to algal uptake and it is suggested that the growth of both algae may have depended on Se(org) regeneration. A budget performed for selenate (SeVI) suggests that this species is also consumed by algae but to a lesser extent than SeIV (in 1994 ~40% of the epilimnetic load). During the stratification period the hypolimnion of Lake Kinneret becomes anoxic, with high levels of dissolved sulfide. The affects of this environment on the distribution of Se oxy-anions, selenite (SeIV) and selenate(SeVI), were also studied. At the onset of thermal stratification (March) about 35% of the lake inventory of both Se oxidized species are entrapped in the hypolimnion. During stages of oxygen depletion and H2S accumulation, SeIV is completely and SeVI partially removed from this layer. The removal is attributed to reduction followed by formation of particulate reduced products, such as elemental selenium Se(o). The ratio between SeVI to total dissolved selenium (SE(T)) in water sources to the lake is ~0.84, about twice the corresponding ratio in the lake (~0.44, during holomixis). In the lake about 75% of annual SeVI inflow from external sources undergoes reduction to selenide (Se-II) and Se(o) through epilimnetic algal assimilation and hypolimnetic anoxic reduction, respectively. It is suggested that the latter oxidation of the dissolved organic selenide released from biogenic particles and of Se(o) only to the tetravalent species is the cause for the lower ratio of SeVI/Se(T) in the lake.

Aquatic Sciences↗
USGS2001

Dry deposition of ammonia, nitric acid, ammonium, and nitrate to alpine tundra at Niwot Ridge, Colorado

Micrometeorological measurements and ambient air samples, analyzed for concentrations of NH3, HNO3, NH4+, and NO3-, were collected at an alpine tundra site on Niwot Ridge, Colorado. The measured concentrations were extremely low and ranged between 5 and 70ngNm-3. Dry deposition fluxes of these atmospheric species were calculated using the micrometeorological gradient method. The calculated mean flux for NH3 indicates a net deposition to the surface and indicates that NH3 contributed significantly to the total N deposition to the tundra during the August-September measurement period. Our pre-measurement estimate of the compensation point for NH3 in air above the tundra was 100-200ngNm-3; thus, a net emission of NH3 was expected given the low ambient concentrations of NH3 observed. Based on our results, however, the NH3 compensation point at this alpine tundra site appears to have been at or below about 20ngNm-3. Large deposition velocities (>2cms-1) were determined for nitrate and ammonium and may result from reactions with surface-derived aerosols. Copyright (C) 2001 Elsevier Science B.V.Micrometeorological measurements and ambient air samples, analyzed for concentrations of NH3, HNO3, NH4+, and NO3-, were collected at an alpine tundra site on Niwot Ridge, Colorado. The measured concentrations were extremely low and ranged between 5 and 70 ng N m-3. Dry deposition fluxes of these atmospheric species were calculated using the micrometeorological gradient method. The calculated mean flux for NH3 indicates a net deposition to the surface and indicates that NH3 contributed significantly to the total N deposition to the tundra during the August-September measurement period. Our pre-measurement estimate of the compensation point for NH3 in air above the tundra was 100-200 ng N m-3; thus, a net emission of NH3 was expected given the low ambient concentrations of NH3 observed. Based on our results, however, the NH3 compensation point at this alpine tundra site appears to have been at or below about 20 ng N m-3. Large deposition velocities (>2 cm s-1) were determined for nitrate and ammonium and may result from reactions with surface-derived aerosols.

Atmospheric Environment↗
USGS1999

Occurrence and behavior of the herbicide Prometon in the hydrologic system

Prometon, a triazine herbicide, is used for total vegetation control on industrial sites, on noncrop areas on farms, in and under asphalt, and to a small extent by homeowners. Prometon has often been detected in surface water and groundwater in studies reported in the literature, but its presence is seldom discussed, partly because of its infrequent inclusion on lists of herbicides used in either agricultural or urban areas. In recent large-scale studies by the U.S. Geological Survey, prometon has been the most commonly detected herbicide in surface water and groundwater in urban areas and the third and fourth most commonly detected herbicide in groundwater and surface water, respectively, in agricultural areas. It also has been detected in rain. The frequent detection of prometon in the environment is discussed in relation to its use practices and predicted environmental behavior. Prometon is compared to atrazine, a structurally similar agricultural triazine herbicide that is one of the most studied and most commonly detected herbicides found in the hydrologic environment. The environmental data presented here demonstrate the wide-scale occurrence of prometon in all components of the hydrologic system, particularly in the surface water and groundwater of urban areas.Prometon, a triazine herbicide, is used for total vegetation control on industrial sites, on noncrop areas on farms, in and under asphalt, and to a small extent by homeowners. Prometon has often been detected in surface water and groundwater in studies reported in the literature, but its presence is seldom discussed, partly because of its infrequent inclusion on lists of herbicides used in either agricultural or urban areas. In recent large-scale studies by the U.S. Geological Survey, prometon has been the most commonly detected herbicide in surface water and groundwater in urban areas and the third and fourth most commonly detected herbicide in groundwater and surface water, respectively, in agricultural areas. It also has been detected in rain. The frequent detection of prometon in the environment is discussed in relation to its use practices and predicted environmental behavior. Prometon is compared to atrazine, a structurally similar agricultural triazine herbicide that is one of the most studied and most commonly detected herbicides found in the hydrologic environment. The environmental data presented here demonstrate the wide-scale occurrence of prometon in all components of the hydrologic system, particularly in the surface water and groundwater of urban areas.

Environmental Science & Technology↗
USGS2005

Arsenate adsorption mechanisms at the allophane: Water interface

We investigated arsenate (As(V)) reactivity and surface speciation on amorphous aluminosilicate mineral (synthetic allophane) surfaces using batch adsorption experiments, powder X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS). The adsorption isotherm experiments indicated that As(V) uptake increased with increasing [As(V)] o from 50 to 1000 μM (i.e., Langmuir type adsorption isotherm) and that the total As adsorption slightly decreased with increasing NaCl concentrations from 0.01 to 0.1 M. Arsenate adsorption was initially (0−10 h) rapid followed by a slow continuum uptake, and the adsorption processes reached the steady state after 720 h. X-ray absorption spectroscopic analyses suggest that As(V) predominantly forms bidentate binuclear surface species on aluminum octahedral structures, and these species are stable up to 11 months. Solubility calculations and powder XRD analyses indicate no evidence of crystalline Al−As(V) precipitates in the experimental systems. Overall, macroscopic and spectroscopic evidence suggest that the As(V) adsorption mechanisms at the allophane−water interface are attributable to ligand exchange reactions between As(V) and surface-coordinated water molecules and hydroxyl and silicate ions. The research findings imply that dissolved tetrahedral oxyanions (e.g., H 2 PO 4 2 - and H 2 AsO 4 2 - ) are readily retained on amorphous aluminosilicate minerals in aquifer and soils at near neutral pH. The inner-sphere adsorption mechanisms might be important in controlling dissolved arsenate and phosphate in amorphous aluminosilicate-rich low-temperature geochemical environments.

Environmental Science & Technology↗