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Volcanology and mineral deposits

Traditionally, volcanologists have focused on forecasting, observing, and interpreting events, processes, and products of eruptions at active volcanoes. Such work involves drama, beauty, fascination scientific problems, and the socially important aim of reducing risks to life and property. In contrast, old volcanic regions, which host many of the world's major hydrothermal-vein, porphyry, and massive-sulfide ore deposits, have been studied mainly by economic geologists, regional stratigraphers, and structural geologists who have limited familiarity with the complexities of volcanic processes. Such "dead" volcanoes, ranging in age from a few million million years (tertiary) to a few billion years (Precambrian), are commonly incompletely and discontinuously preserved due to rapid erosion of originally high-standing volcanic edifices. They can be difficult to date reliably, especially in terms of the time scales of individual volcanic events, and are variably hydrothermally altered-impeding high-resolution petrologic and geochemical studies. Many volcanologists, geochemists, and geophysicists who work on active volcanoes accordingly have been reluctant to become involved in studies of such less tractable rocks.

Earthquakes & Volcanoes (USGS)↗

A review of lignite resources of western Tennessee and the Jackson Purchase area, western Kentucky

This review of the lignite deposits of western Tennessee and the Jackson Purchase area in western Kentucky (Figure 1) is an updated report on part of the U.S. Geological Survey's National Coal Resource Assessment of the Gulf Coastal Plain Coal Province (see Ruppert et al., 2002; Hackley et al., 2006; Dennen, 2009; and other chapters of this publication). Lignite deposits of western Kentucky and Tennessee are an extension of the Gulf Coastal Plain Coal Province (Cushing et al., 1964), and currently are not economic to mine. These deposits have not been extensively investigated or developed as an energy resource. This review includes a description of the geology of the lignite-bearing units, a discussion of the available coal quality data, and information on organic petrology. Palynological data for lignite samples collected in Kentucky and Tennessee as part of this work are presented in Table 1. Lignite trace element data originally presented in Hackley et al. (2006) are not included in this report due to potential laboratory quality control issues during the time the samples were analyzed (U.S. Geological Survey Energy Resources Program, 2010).

Kentucky, Tennessee↗

Geology and mining industry of the Tintic district, Utah: Section in Nineteenth Annual Report of the United States Geological Survey to the Secretary of the Interior 1897 - 1898: Part III - Economic Geology

The field work upon which this report is based was begun in July, 1897, and continued without interruption until December of the same year. The area studied is approximately 15 miles square and contains 234 square miles. The topographic maps, which are two in number, were prepared under the direction of Mr. R. U. Goode, Mr. S. S. Gannett doing the triangulation and Messrs. Marshall and Griswold the topography in the fall of 1896 and summer of 1897. The mapping is done on two scales; the larger area, approximately 15 miles square, is mapped on a scale of 1: 62,500. This map is designed to form a part of the Geologic Atlas of the United States. The other map represents the portion of the larger area in which the majority of the mines are located. It is on a scale of 1: 9,600, and covers an area of 12 square miles. The work has been greatly facilitated through the assistance rendered by the mining men of the district, among whom special thanks are due to Messrs. G. H. Robinson, W. J. Craig, W. M. Nesbit, and C. H. Blanchard. The chemical work on the ores and country rocks from the district has been done in the laboratory of the Survey by Messrs. H. N. Stokes and George Steiger, and the determination of the fossils collected is to be credited to Mr. G. H. Girty, also of the Geological Survey. In the field work the authors have cooperated constantly on every phase of the varied problems. The same is true for the office work, except that the stratigraphic and economic problems have been the especial studies of Mr. Tower, while the petrologic and remaining problems have been the special studies of Mr. Smith. In pursuance of this system of work the introduction has been written conjointly, Chapter II of Part I and all of Part II have been written by Mr. Tower, and Chapters I and III to VII of Part I by Mr. Smith.

Utah↗

Northward displacements of forearc slivers in the Coast Ranges of California and Southwest Oregon during the late Mesozoic and early Cenozoic

North American-Farallon-Kula plate motion data, combined with estimated strikeslip displacements obtained from the obliquity of convergence along active circumPacific subduction zones, can be used to estimate the amount of strike-slip displacement along the forearc region of western North America. This evidence suggests a minumum of 500 km and maximum of 1600 km displacement with respect to the Farallon plate, and a minumum of 1600 km and a maximum of 4900 km with respect to the Kula plate (or some equivalent) from Late Jurassic to middle Eocene (145 Ma to 43 Ma). These displacements are consistent with pre-middle Eocene displacements of paleoforearc strata (Franciscan Complex, Great Valley sequence and related units), inferred from pa 1eomagnetic, petrologic, stratigraphic, and conglomerate pebble data. Tentative restorations suggest that the Elk outlier and Snow Camp terrane of southwest Oregon have affinities with the southern Klamath Mountains of northern California; that the Gold Beach terrane of southwest Oregon has affinities with central or southern California; that the Healdsburg terrane of the San Francisco area has affinities with southern California; that other Franciscan rocks of the San Francisco area have affinities with central or southern California; and that the Nacimiento block has affinities with the Peninsular Ranges or Vizcaino area of Baja California. These tentative correlations suggest about 600-1000 km of right-lateral displacement between Early Cretaceous and middle Eocene time which can be entirely accommodated by Farallon plate motions and (or) represent minimal displacement with respect to Kula plate motions (or some equivalent).

Book chapter↗

Contrasting cratonal provenances for upper Cretaceous Valle Group quartzite clasts, Baja California

Late Cretaceous Valle Group forearcbasin deposits on the Vizcaino Peninsula of Baja California Sur are dominated by firstcycle arc-derived volcanic-plutonic detritus derived from the adjacent Peninsular Ranges batholith. Craton-derived quartzite clasts are a minor but ubiquitous component in Valle Group conglomerates. The source of these clasts has implications for tectonic reconstructions and sediment-dispersal paths along the paleo-North American margin. Three strongly contrasting types of quartzite are recognized based on petrology and detrital zircon U-Pb geochronology. The first type is ultramature quartz arenite with well-rounded, highly spherical zircon grains. Detrital zircon ages from this type are nearly all >1.8 Ga with age distributions that closely match the distinctive Middle-Late Ordovician Peace River arch detrital signature of the Cordilleran margin. This type has been previously recognized from prebatholithic rocks in northeast Baja California (San Felipe quartzite). A second quartzite type is subarkosic sandstone with strong affinity to southwestern North America; important features of the age spectra are ~1.0-1.2 Ga, 1.42 and 1.66 Ga peaks representing cratonal basement, 500-300 Ma grains interpreted as recycled Appalachian-derived grains, and 284- 232 Ma zircon potentially derived from the Early Permian-Middle Triassic east Mexico arc. This quartzite type could have been carried to the continental margin during Jurassic time as outboard equivalents of Colorado Plateau eolianites. The third quartzite type is quartz pebble conglomerate with significant ~900- 1400 Ma and ~450-650 Ma zircon components, as well as mid- and late Paleozoic grains. The source of this type of quartzite is more problematic but could match either upper Paleozoic strata in the Oaxaca terrane of southern Mexico or a southwestern North America source. The similarity of detrital 98 zircon spectra in all three Valle Group quartzite types to rocks of the adjacent Cordilleran margin support previous interpretations that Valle Group forearc basin sediments were deposited in proximity to rocks on the mainland of northwest Mexico and southwestern United States.

Book chapter↗

The USGS National crustal model for seismic hazard studies: 2019 update

The United States Geological Survey (USGS) National Crustal Model (NCM) is being developed to assist in the modeling of seismic hazards across the conterminous United States, specifically by improving estimates of site response. The NCM is composed of geophysical profiles, extending from the Earth’s surface into the upper mantle, constructed from 5 primary elements: 1) depth to bedrock and basement; 2) 3D geologic framework; 3) petrologic and mineral physics database; 4) 3D temperature model; and 5) calibration of a porosity and attenuation model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters (VS30) and the depths to 1.0 and 2.5 km/s shear-wave velocity (Z1.0 and Z2.5), can be extracted from the NCM. As GMMs develop, other metrics could also be extracted or derived from the NCM such as fundamental frequency, a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis including better accounting for path-dependent attenuation and geometric spreading and more accurate estimation of earthquake source properties such as hypocentral location and stress drop.

Conference Paper↗

The significance of observations at active volcanoes; A review and annotated bibliography of studies at Kilauea and Mount St. Helens

Study of active volcanoes yields information of much broader significance than to only the discipline of volcanology. Some applications are 1) interpretation of lava-flow structures, stratigraphic complexities, and petrologic relations in older volcanic units; 2) interpretation of bulk properties of the mantle and constraints on partial melting and deep magma transport; 3) interpretation of geophysical characteristics of potentially active volcanic systems; 4) direct determination of physical properties of molten and solidified basalt, and of intensive variables (e.g., oxygen fugacity and temperature) accompanying cooling and crystallization; 5) quantitative assessment of crystal fractionation and magma mixing, 6) tests of theoretical and experimental geochemical, geophysical, and rheologic models of volcanic behavior; and 7) confirmation in nature of laboratory experiments related to crystallization in igneous systems. The critical factors that make real-time study of volcanic activity valuable are that the location and timing of events are known, and that molten rock and gases are available for direct observation and sampling for subsequent study. Observations made over a period of time make it possible to calculate rates of magma transport, storage, and crystallization, as well as to quantitatively determine elastic and inelastic deformation and the build up and decay of stress within the active volcanic system. Discussion of these topics is keyed to an annotated bibliography from which quantitative information on properties and processes may be obtained. Emphasis is on Hawaii's active basaltic volcanoes for which the most information is available. Additional references are made to research at Mount St. Helens, one of the first real-time studies of an active volcano of dacitic composition.

Hawaii, Washington↗

Tertiary igneous rocks and Laramide structure and stratigraphy of the Spanish Peaks Region, South-Central Colorado: Road log and descriptions from Walsenburg to La Veta

The Spanish Peaks are located in the western part of the Raton basin in south-central Colorado, southwest of Walsenburg. The two peaks, West Spanish Peak (WSP, 13,626 feet) and East Spanish Peak (ESP, 12,683 feet), are located on the upland part of the far western edge of the Great Plains physiographic region. East of Spanish Peaks, a deeply dissected plateau extends into the Great Plains. The Raton basin, an asymmetric structure of Laramide age, underlies and surrounds the Spanish Peaks. The basin extends north from Ute Park, New Mexico, to Huerfano Park, Colorado. The juncture of steeply dipping western and gently dipping eastern limbs of the Raton basin forms the basin axis, known locally as the La Veta syncline. The La Veta syncline extends north-northwest into Huerfano Park, between the Sangre de Cristo and Wet Mountains. These features and others such as the Laramide orogeny, igneous rocks, and an overview of petrology are discussed.

Colorado↗

Finalization of the Confocal Laser Scanning Microscopy (CLSM) working group

A working group in Commission II to investigate applications of confocal laser scanning microscopy (CLSM) for organic petrology investigations has finalized with publication of the manuscript “Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy” in the International Journal of Coal Geology. The manuscript is available via Open Access from https://doi.org/10.1016/j.coal.2022.103927 and also from the Commission II working group (WG) webpage https://www.iccop.org/workinggroup/confocal-laser-scanning-microscopy-clsm/. A report detailing the full history and results from the WG also is available from the Commission II WG webpage. The working group investigated the application of CLSM to an organic-rich (44 wt.% TOC), thermally immature sample (VRo 0.42%) of the Kimmeridge Clay Formation. CLSM imaging and spectroscopy and atomic force microscopy (AFM) were used to characterize bituminite.

ICCP News↗

The Confocal Laser Scanning Microscopy Working Group of the ICCP: Final report 2021

This report summarizes the activities and results of the Confocal Laser Scanning Microscopy (CLSM) working group (WG) of the International Committee for Coal and Organic Petrology (ICCP), from its inception in September, 2015, to the present day (September, 2021). The purpose of this report is to document the history of the working group and to compile and evaluate its results. The CLSM WG examined an immature, organic-rich sample of Kimmeridge Clay, which was characterized via CLSM imaging and spectroscopy. In addition, mechanically polished and broad ion beam (BIB) milled sample preparations were characterized via atomic force microscopy. Highlights of findings from the CLSM WG include: the interpreted presence of Botryococcus; incomplete blocking of laser light from highly reflective materials; surface roughening and surface flattening induced by differential BIB milling dependent on location and scale of measurement; substitution of uranium for iron in sulfides; red-shift of reflectance and auto-fluorescence from below the sample surface; positive alteration from laser-induced photo-oxidation of the sample surface including fluorescence blue-shift; blueshift associated to higher fluorescence intensity regions in amorphous organic matter; need for fluorescence spectroscopy standardization as applied via CLSM; and the suitability of CLSM to predict solid bitumen reflectance via calibration to an extant data set. Due to the inability of WG members to continue participating in a WG format, the CLSM WG is hereby finalized. This report represents the final product of WG activity, with the aim to summarize the information included herein for a future peer-reviewed manuscript.

Final Report↗

Andesite sills in the Red Mountain area, Scapegoat Wilderness, Lewis and Clark County, Montana

Sills 2-200 ft (0.6-60 in) thick in the Red Mountain area of the Scapegoat Wilderness in northwest Montana consist of altered andesite, basaltic andesite, and dacite and occur over a stratigraphic range of 8,000 ft (2,400 m) in the Helena and Snowslip Formations. The approximate compositional range of the sills is 50-80 percent plagioclase, 0-25 percent orthoclase, and 5-30 percent amphibole, pyroxene, and biotite; the uppermost sill contains about 15 percent quartz in the groundmass. Accessory minerals include quartz, magnetite, ilmenite, apatite, and pyrite. The petrology and alteration of the sills distinguish them from other sills in the region. Field observations and laboratory studies consisting of chemical, isotopic and X-ray analyses, and petrographic and mineralogic investigations suggest that the sills may have been emplaced in Precambrian Y time at about the same time as the extrusion of the Purcell Lava in the vicinity of Glacier National Park. Alternatively, the sills may represent a Precambrian igneous event not previously recognized in the Belt basin.

Montana↗

Fifth special report of the Hawaiian Volcano Observatory of the Hawaiian Volcano Research Association and the U.S. Geological Survey: Abrasion hardness

After reviewing the work of sclerometry, this paper shows that yielding and relative softness are the mechanical basis of what should be called malacometry. The experiments have been made with diamond drills, ring cuts, end millers and grinding wheels. Auerbach's "limited scope of the Mohs list" is quantitatively confirmed. The wear of diamonds is examined. A program is carried out, for rotary or annular abrasion by diamond under three applications of energy, each progressively slower. A selected commercial talc is the control substance of softness value 100. The instruments used are synchronous motors, drill presses, wheel grinders, and watchmaker lathes. Some 200 minerals, woods, metals, glasses and plastics were originally measured. Hardness tables and curves are shown for comparison with volumetric abradability. For a Mohs succession the softer substances abrade relatively more under higher energy of contact friction, and any one substance shows higher relative values under lower energy of attrition; in other words, under slower scratching. An artificially cut diamond octahedron gives more consistent results than a natural crystal, under light pressures. Standard successions of relative abradability measurements do not hold good under different energies of attack. Functions of plasticity, brittleness, cleavage, powder lubricity, ductility and the like introduce various anomalies, and constancy of pressure varies with variable yielding. The supposition that rhythmic instrumental abrading will hold its mechanical constants, while the substance attacked yields in accord with its own surface molecular mobility relative to a control substance, is only approximately true. At low energies the approximation is better than at high, but at high speeds the wear of tool is less. Hence the advantage of using with slow speed a replaceable tool. Substances of different categories such as steels and woods, differ in behavior from minerals. The Mohs System has the great advantage of extending the controls from mineral to mineral up through the whole scale, and is purely qualitative. It is not numerically quantitative at all in terms of equal units. A principal result of this investigation is that 80 per cent of the Mohs Scale, Numbers 3 to 10, are by common consent within 1 per cent of a malacometric scale numbered 1 to 100. The scientists who determined this relation were the sclerometry investigators of the nineteenth century, who mistakenly thought that the wide intervals of sclerometry are between the hard minerals. They used the reciprocals of the measures of yielding. The simple scratch tester finally arrived at is quite different from the instruments of Parts II and III. It eliminates diamond drilling, retains the Mohs controls and utilizes a dental grinding wheel and a modern low speed motor. The object of this research has been to design a simple instrument for many uses, especially for the mechanic's shop. It is planned for manufacture at an early date. The author is indebted to Dr. Earl Ingerson, Chief, Geochemistry and Petrology Branch, for critical correction and approval of this paper, by authority of the Director, U. S. Geological Survey.

Report of the Hawaiian Volcano Observatory↗

Chemical variability in the Lakeview Mountains pluton, southern California batholith: A comparison of the methods of correspondence analysis and extended Q-mode factor analysis

An extended method of Q -mode factor analysis that has been described previously offers a number of important advantages over conventional Q -mode factor analysis and correspondence analysis when applied to compositional data. Among these are the ability to compute the compositions, in the original units of the data, represented by the reference axes. The only special requirement of the data is that the values for each observation sum to a constant. Mathematically derived reference axes, such as the principal-components and varimax axes, commonly represent compositions that are partly negative. Even where no negative values are present, these compositions are comparatively difficult to interpret in petrologic terms and impossible or inappropriate to include in petrogenetic models. A model has been developed for the Lakeview Mountains pluton which employs vectors representing the compositions of melanocratic schlieren, leucocratic schlieren, and inclusions as the reference axes. When the effect of the inclusions is removed, the compositional zoning in the pluton is like that found in otherwise similar plutons in the Sierra Nevada batholith. The genetic implication of the model is that the inclusions were separated from the magma at least in its marginal parts. In the central part of the pluton, the inclusions were either separated to a lesser extent than in the marginal parts, or were reincorporated into the magma.

California↗

Updates to and applications of the USGS National Crustal Model for seismic hazard studies

The U.S. Geological Survey (USGS) National Crustal Model (NCM) is being developed to assist in the modeling of seismic hazards across the conterminous United States. The NCM is composed of a grid of geophysical profiles, extending from the Earth’s surface into the upper mantle. It is constructed from a 3D geologic framework and geophysical rules defined by: (1) a petrologic and mineral physics database; (2) a 3D temperature model; and (3) a calibrated rock type- and age-dependent porosity model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters ( V S 30 ) and the depths to 1.0 and 2.5 km/s shear-wave velocity ( Z 1.0 and Z 2.5 ), can be extracted from the NCM. As GMMs develop, other metrics could also be extracted or derived from the NCM such as sediment thickness and travel times, fundamental frequency, a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis including better accounting for path-dependent attenuation and geometric spreading, more accurate estimation of earthquake source properties such as hypocentral location and stress drop, and calculation of crustal strength profiles that inform estimates of the base of seismicity.

Conference Paper↗

Volcanoes of the Mojave: The 2022 Desert Symposium field trip road log

Basalt lava fields, some decorated with scoria ‘cinder’ cones, are scattered around the Mojave Desert. Most basalt fields are short-lived, but the Cima volcanic field is unique in having eruptions that span ~7.5 m.y., including the youngest eruption in the Mojave Desert at ~12 ka. Xenolith-bearing basalts that include both mantle and deep crustal rocks are known in several fields. All basalt fields except Cima are restricted to the active eastern California shear zone, and many lie directly on active faults, indicating a direct relation between faults and volcanism. The field trip will visit the Pisgah, Dish Hill, Amboy, Cima, and Bicycle Lake volcanic fields, and it will enable examination of the physical volcanology in the basalt fields, including the types of eruptions (effusive and explosive) and the resulting deposits (lava flows, scoria cones, and tuff cones). It will also review the petrology, paleomagnetism, remote sensing, and planetary geology studies conducted at each volcanic field, and how these studies influenced the development of each of these study areas.

California↗

Recent applications of the USGS National Crustal Model for Seismic Hazard Studies

The U.S. Geological Survey is developing the National Crustal Model (NCM) for seismic hazard studies to facilitate modeling site, path, and source components of seismic hazard across the conterminous United States. The NCM is composed of a 1km grid of geophysical profiles, extending from the Earth’s surface into the upper mantle. It is constructed from a threedimensional (3D) geologic framework and geophysical rules that use (1) a petrologic and mineral physics database; (2) a 3D temperature model; and (3) a calibrated rock type- and age-dependent porosity model. Parameters needed to estimate site response for existing ground motion models (GMMs), including the time-averaged velocity in the upper 30 meters (VS30), the depths to 1.0 and 2.5 km/s shear-wave velocity (Z1.0 and Z2.5), and sediment thickness, can be computed from the NCM. As GMMs continue to improve in the future, other metrics could also be extracted or derived from the NCM, such as fundamental period, site attenuation (ko), a fully frequency-dependent site response function, or 3D geophysical volumes for wavefield simulations. Application of the NCM may also benefit other aspects of seismic hazard analysis, including better accounting for path-dependent attenuation and geometric spreading, more accurate estimation of earthquake source properties such as hypocentral location and stress drop, and calculation of crustal strength profiles that inform estimates of the base of seismicity.

conterminous United States↗

Exposure of a late cretaceous layered mafic-felsic magma system in the central Sierra Nevada batholith, California

New U-Pb zircon ages for the Lamarck Granodiorite, associated synplutonic gabbro and diorite plutons, and two large mafic intrusive complexes that underlie them in the Sierra Nevada batholith are 92??1 Ma. These ages establish the Late Cretaceous as a period of extensive mafic-felsic magmatism in the central part of the batholith, and confirm the significance of mafic magmatism in the evolution of the voluminous silicic plutions in the Sierran arc. The lack of significant zircon inheritance in any of the units analyzed supports isotopic evidence that the Lamarck and other Late Cretaceous Sierran plutons were derived predominantly from young crust. Recognition of an extensive mafic-felsic magma system in the Sierra Nevada batholith emphasizes the importance of basaltic liquids in the evolution of continental crust in arc settings. ?? 1995 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Deep drilling at the Siljan Ring impact structure: oxygen-isotope geochemistry of granite

The Siljan Ring is a 362-Ma-old impact structure formed in 1700-Ma-old I-type granites. A 6.8-km-deep borehole provides a vertical profile through granites and isolated horizontal diabase sills. Fluid-inclusion thermometry, and oxygen-isotope compositions of vein quartz, granite, diabase, impact melt, and pseudotachylite, reveal a complex history of fluid activity in the Siljan Ring, much of which can be related to the meteorite impact. In granites from the deep borehole, ??18O values of matrix quartz increase with depth from near 8.0 at the surface to 9.5??? at 5760 m depth. In contrast, feldspar ??18O values decrease with depth from near 10 at the surface to 7.1??? at 5760 m, forming a pattern opposite to the one defined by quartz isotopic compositions. Values of ??18O for surface granites outside the impact structure are distinct from those in near-surface samples from the deep borehole. In the deep borehole, feldspar coloration varies from brick-red at the surface to white at 5760 m, and the abundances of crack-healing calcite and other secondary minerals decrease over the same interval. Superimposed on the overall decrease in alteration intensity with depth are localized fracture zones at 4662, 5415, and 6044 m depth that contain altered granites, and which provided pathways for deep penetration of surface water. The antithetic variation of quartz and feldspar ??18O values, which can be correlated with mineralogical evidence of alteration, provides evidence for interaction between rocks and impact-heated fluids (100-300?? C) in the upper 2 km of the pluton. Penetration of water to depths below 2 km was restricted by a general decrease in impact-fracturing with depth, and by a 60-m-thick diabase sill at 1500 m depth that may have been an aquitard. At depths below 4 km in the pluton, where water/rock ratios were low, oxygen isotopic compositions preserve evidence for limited high-temperature (>500?? C) exchange between alkali feldspar and fluids. The high-temperature exchange may have been a post-impact event involving impact-heated fluids, or a post-magmatic event. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗