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At least 631 records · Page 35Linked to original sources
USGS1978

Isotopic composition of lead in oceanic basalt and its implication to mantle evolution

New data are given in this report for (1) Pb isotopic compositions and U, Th, and Pb concentrations of basalts from the island of Hawaii; (2) redetermined Pb isotopic compositions of some abyssal tholeiites; and (3) U, Th, and Pb concentrations of altered and fresh abyssal basalts, and basalt genesis and mantle evolution are discussed. The Th/U ratios of abyssal and Japanese tholeiites are distinctly lower than those of tholeiites and alkali basalts from other areas. It is thought that these low values reflect a part of the mantle depleted in large ionic lithophile elements. Thus a mantle evolution model is presented, in which Th/U ratios of the depleted zone in the mantle have decreased to ∼2, and U/Pb ratios have increased, showing an apparent ∼1.5-b.y. isochron trend in the 207 Pb/ 204 Pb vs. 206 Pb/ 204 Pb plot. The Pb isotopic compositions of basalts from the island of Hawaii are distinct for each of the five volcanoes, and within each volcano, Pb's of tholeiites and alkali basalts are similar. An interaction between partially melted material (hot plume?) of the asthenosphere and the lithosphere is suggested to explain the trend in the Pb isotopic compositions of Hawaiian basalts.

Earth and Planetary Science Letters↗
USGS1978

Radioactive disequilibrium in altered mid-oceanic basalts

A young (<1 m.y.) tholeiitic basalt dredged from the Mid-Atlantic Ridge displays a 234 U excess and a 230 Th deficiency that have resulted from the addition of seawater uranium during weathering at seafloor temperatures. Two older samples, though they acquired substantial amounts of uranium from seawater, are depleted in 234 U, indicating preferential leaching of this isotope. Hydrothermally altered samples suggest that some uranium loss may have occurred. Possible isotopic effects of preferential 234 U leaching, however, are obscured by secondary addition of seawater uranium at lower temperatures.

Earth and Planetary Science Letters↗
USGS1968

Spectrographic date on cores from the Pacific Ocean and the Gulf of Mexico

Average quantitative spectrographic data are presented for V, Ti, Zr, Ni, Co, Sc, Cr and La in the following Pacific deep-sea cores: siliceous ooze (3), red clay (6), volcanic mud (3), calcareous ooze (3) and one manganese nodule, and in 23 near-shore cores, mostly from the Gulf of Mexico.

Geochimica et Cosmochimica Acta↗
USGS1975

Trace element evaluation of a suite of rocks from Reunion Island, Indian Ocean

Reunion Island consists of an olivine-basalt shield capped by a series of flows and intrusives ranging from hawaiite through trachyte. Eleven rocks representing the total compositional sequence have been analyzed for U, Th and REE. Eight of the rocks (group 1) have positive-slope, parallel, chondrite-normalized REE fractionation patterns. Using a computer model, the major element compositions of group 1 whole rocks and observed phenocrysts were used to predict the crystallization histories of increasingly residual liquids, and allowed semi-quantitative verification of origin by fractional crystallization of the olivine-basalt parent magma. Results were combined with mineral-liquid distribution coefficient data to predict trace element abundances, and existing data on Cr, Ni, Sr and Ba were also successfully incorporated in the model. The remaining three rocks (group 2) have nonuniform positive-slope REE fractionation patterns not parallel to group 1 patterns. Rare earth fractionation in a syenite is explained by partial melting of a source rich in clinopyroxene and/or hornblende. The other two rocks of group 2 are explained as hybrids resulting from mixing of syenite and magmas of group 1.

Geochimica et Cosmochimica Acta↗
USGS1988

The metal oxide fraction of pelagic sediment in the equatorial North Pacific Ocean: A source of metals in ferromanganese nodules

Pelagic sediment recovered at DOMES Site A in the equatorial North Pacific (151°W, 9° 15′N) consists of a surface homogeneous layer, approximately 10 cm thick, overlying a strongly mottled layer that is lighter in color. The radiolarian composition of both units is Quaternary. In areas where this sediment was only a few centimeters thick, the underlying sediment was early Tertiary. Clay mineralogy and major oxide composition of the two Quaternary sediments are uniform. Their similarity to continental shale suggests that the sediment has a terrigenous source. Clay mineralogy and major oxide composition of the Tertiary sediment also are uniform, although they differ markedly from the Quarternary sediment. In contrast to the major oxides, concentrations of Mn, Co, Cu, and Ni soluble in hydroxylamine hydrochlorideacetic acid are strongly different in the surface and subsurface Quaternary sediment. Mn and Ni exhibit pronounced depletions in the subsurface sediment, Ni slightly more than Mn. Cu is also depleted in the subsurface sediment, but less than Mn. It is also depleted in the subsurface Tertiary sediment, whereas the Mn concentration remains high. Concentration of Co relative to Mn increases into the subsurface Quaternary sediment to a constant Co:Mn ratio of 3 × 10 −2 . The trivalent REE (the REE exclusive of Ce) and Fe exhibit little down-core variation. Distribution of elements in these sediments is closely related to their concentration in associated surface ferromanganese nodules. The nodules are of two distinct types: those from the area where the Quaternary sediment is relatively thick have δ-MnO 2 as the dominant manganese mineral. The ratios of Ni:Mn, Cu:Mn, and Fe:Mn in these nodules approximate the corresponding ratios of the soluble fraction of surface sediment. Todorokite is the dominant mineral of nodules recovered from areas where the Quaternary sediment is thin. Relatively high Cu/Mn, Ni/Mn, and low Fe/Mn ratios of these nodules mirror differences between the soluble fraction of surface and subsurface Quaternary sediment. These compositional trends of sediment and nodules at DOMES Site A reflect a diagenetic origin for the todorokite nodules and a predominantly hydrogenous origin for the δ-MnO 2 nodules.

Geochimica et Cosmochimica Acta↗
USGS1981

Patterns of groundwater salinity changes in a deep continental-oceanic transect off the southeastern Atlantic coast of the U.S.A.

Investigations of formation-fluid salinities in a transect from western Georgia to the edge of the Blake Plateau off the coast of Georgia show surprisingly similar hydrochemical features offshore and onshore. A fresh-brackish wedge of groundwater (<25 g/kg total dissolved solids) lies beneath the shelf to a depth of ∼ 900 m. On land, brackish waters extend to a maximum depth of ∼ 1.2 km below sea level in Lowndes County, Georgia. In deeper horizons, hypersaline brines (> 100 g/kg) occur in Lower Cretaceous (?) strata. These strata have a pronounced evaporitic (anhydritic) character in the offshore segment. Strong salinity gradients in interstitial waters signify buried evaporite deposits at drill sites beneath the Blake Plateau.

Florida, Georgia, South Carolina↗
USGS1980

Current-controlled, abyssal microtopography and sedimentation in Mozambique Basin, southwest Indian Ocean

The Antarctic Bottom Water (AABW) activity and the variations in the abundance and grain size of the terrigenous sediments, derived from Africa and Madagascar land masses, are reflected in different types of microtopography in the Mozambique Basin. In southerly areas, where the sediment supply is much less, the bottom-current activity has resulted in the presence of manganese nodules, a thin veneer of sediments, and the absence of sediment waves. Farther north, along the marginal areas of the basin where the fine-grained sediments from the Africa—Madagascar source have been supplied in abundance, wavy bedforms have been generated by AABW. Wavy bedforms do not exist even in the northerly areas if coarse-grained, turbidite sediments are present on the sea floor. The continuation of acoustic reflectors from the zone of turbidites in the central areas of the basin into the zone of sediment waves along the margins, and the lithology and structures in sediment cores from these zones suggest that the turbidity-current-fed, fine-grained sediments were deposited as wavy bedforms by AABW flow. Thus, sediment waves formed readily during Pleistocene times. The enrichment of quartz and displaced Antarctic diatoms, and the relatively low kaolinite/chlorite ratios in the sediments, the north-pointing current lineations on the sea floor, the lack of any perceptible sedimentary fill in the troughs of waves, and the dense nepheloid layer in the westerly areas of the Mozambique Basin, attest to the current-controlled sedimentation and generation of wavy bedforms during Holocene time also. The formation of sediment waves in the Mozambique Basin can be modeled after a fluvial antidune mechanism. This model envisages that internal waves, focused on a benthic boundary layer cap, have been locked in phase with sediment waves in the presence of an 8–10 cm/sec current in the Mozambique Basin. A density contrast of 2·10 −6 g/cm 3 appears to exist at the tops of benthic boundary layers in the Mozambique Basin and is quite sufficient for supporting the internal waves. The densiometric Froude number calculated for a 60–280 m thick boundary layer in the basin is close to unity or greater, and is compatible with the antidune model.

Marine Geology↗
USGS1981

Tertiary carbonate-dissolution cycles on the Sierra Leone Rise, eastern equatorial Atlantic Ocean

Most of the Tertiary section on Sierra Leone Rise off northwest Africa consists of chalk, marl, and limestone that show cyclic alterations of clay-rich and clay-poor beds about 20–60 cm thick. On the basis of biostratigraphic accumulation rates, the cycles in Oligocene and Miocene chalk have periods which average about 44,000 years, and those in Eocene siliceous limestone have periods of 4000–27,000 years. Several sections were sampled in detail to further define the cycles in terms of content of CaCO 3 , clay minerals, and relative abundances of calcareous nannofossils. Extending information gained by analyses of Pleistocene cores from the continental margin of northwest Africa to the Tertiary cycles on Sierra Leone Rise, both dilution by noncarbonate material and dissolution of CaCO 3 could have contributed to the observed relative variations in clay and CaCO 3 . However, dissolution of CaCO 3 as the main cause of the carbonate-clay cycles on the Sierra Leone Rise, rather than dilution by clay, is suggested by the large amount of change (several thousand percent) in terrigenous influx required to produce the observed variations in amount of clay and by the marked increase in abundance of dissolution-resistant discoasters relative to more easily dissolved coccoliths in low-carbonate parts of cycles. The main cause of dissolution of CaCO 3 was shoaling of the carbonate compensation depth (CCD) during the early Neogene and climatically induced fluctuations in the thickness of Antarctic Bottom Water.

Marine Geology↗
USGS1981

Mineralogy and composition of concentric layers within a manganese nodule from the North Pacific Ocean

The minor-element composition of concentric layers within a single ferromanganese nodule from the eastern North Pacific exhibits strong correlations with Fe and Mn contents but appears to be independent of pronounced mineralogic variations. On the basis of these correlations, the elemental composition of individual layers apparently is controlled by the relative contribution of two sources: seawater, and interstitial water of associated sediment. In contrast, the mineralogy of the nodule, consisting of birnessite in the outer few layers and todorokite in the inner layers, is considered to be a function of nodule diagenesis.

Marine Geology↗
USGS1989

Sea-floor drainage features of Cascadia Basin and the adjacent continental slope, northeast Pacific Ocean

Sea-floor drainage features of Cascadia Basin and the adjacent continental slope include canyons, primary fan valleys, deep-sea valleys, and remnant valley segments. Long-range sidescan sonographs and associated seismic-reflection profiles indicate that the canyons may originate along a mid-slope escarpment and grow upslope by mass wasting and downslope by valley erosion or aggradation. Most canyons are partly filled with sediment, and Quillayute Canyon is almost completely filled. Under normal growth conditions, the larger canyons connect with primary fan valleys or deep-sea valleys in Cascadia Basin, but development of accretionary ridges blocks or re-routes most canyons, forcing abandonment of the associated valleys in the basin. Astoria Fan has a primary fan valley that connects with Astoria Canyon at the fan apex. The fan valley is bordered by parallel levees on the upper fan but becomes obscure on the lower fan, where a few valley segments appear on the sonographs. Apparently, Nitinat Fan does not presently have a primary fan valley; none of the numerous valleys on the fan connect with a canyon. The Willapa—Cascadia—Vancouver—Juan de Fuca deep-sea valley system bypasses the submarine fans and includes deeply incised valleys to broad shallow swales, as well as within-valley terraces and hanging-valley confluences.

Marine Geology↗
USGS1987

Multiple sources of alkanes in Quaternary oceanic sediment of Antarctica

Normal alkanes ( n -C 13 n -C 36 ), isoprenoid hydrocarbons ( i -C 15 , i -C 16 , i -C 18 , i -C 19 , and i -C 20 ) triterpanes (C 27 C 32 ), and (C 27 C 29 ) are present in low concentrations offshore Antarctica in near-surface, Quaternary sediment of the Wilkes Land continental margin and of the western Ross Sea. The distributions of these hydrocarbons are interpreted relative to possible sources and processes. The hydrocarbons appear to be mixtures of primary and recycled material from marine and terrigenous sources. The n -alkanes are most abundant and are characterized by two distinct populations, one of probable marine origin and the other likely from terrigenous, vascular plant sources. Because the continent of Antarctica today is devoid of higher plants, the plant-derived hydrocarbons in these offshore sediments probably came from wind-blown material and recycled Antarctic sediment that contains land-plant remains from an earlier period of time. Isoprenoid hydrocarbons are partially recycled and mainly of marine origin; the dominance of pristane over phytane suggests oxic paleoenvironmental conditions. Both modern and ancient triterpanes and steranes are present, and the distribution of these indicates a mixture of primary and recycled bacterial, algal, and possible higher-plant materials. Although the sampled sediments were deposited during the Quaternary, they apparently contain a significant component of hydrocarbons of pre-Quaternary age.

Organic Geochemistry↗
USGS1991

Pliocene shallow water paleoceanography of the North Atlantic ocean based on marine ostracodes

Middle Pliocene marine ostracodes from coastal and shelf deposits of North and Central America and Iceland were studied to reconstruct paleotemperatures of shelf waters bordering portions of the Western Boundary Current System (including the Gulf Loop Current, Florida Current, Gulf Stream and North Atlantic Drift). Factor analytic transfer functions provided Pliocene August and February bottom-water temperatures of eight regions from the tropics to the subfrigid. The results indicate: (1) meridional temperature gradients in the western North Atlantic were less steep during the Pliocene than either today or during Late Pleistocene Isotope Stage 5e; (2) tropical and subtropical shelf waters during the Middle Pliocene were as warm as, or slightly cooler than today; (3) slightly cooler water was on the outer shelf off the southeastern and mid-Atlantic coast of the U.S., possibly due to summer upwelling of Gulf Stream water; (4) the shelf north of Cape Hatteras, North Carolina may have been influenced by warm water incursions from the western edge of the Gulf Stream, especially in summer; (5) the northeast branch of the North Atlantic Drift brought warm water to northern Iceland between 4 and 3 Ma; evidence from the Iceland record indicates that cold East Greenland Current water did not affect coastal Iceland between 4 and 3 Ma; (6) Middle Pliocene North Atlantic circulation may have been intensified, transporting more heat from the tropics to the Arctic than it does today.

Quaternary Science Reviews↗
USGS1991

Neogene biostratigraphy and paleoenvironments of Enewetak Atoll, equatorial Pacific Ocean

Micropaleontologic analyses of Neogene sediments from Enewetak Atoll, Marshall Islands, provide data on the age of lagoonal deposits, stratigraphic disconformities and the paleoenvironmental and subsidence history of the atoll. Benthic foraminifers, planktic foraminifers, calcareous nannofossils and ostracodes were studied from six boreholes, the deepest penetrating 1605 feet below the lagoon floor into upper Oligocene strata. The Oligocene-Miocene boundary occurs at about 1200 ft below the lagoon floor. The early and middle Miocene is characterized by brief periods of deposition and numerous hiatuses. Ostracodes and benthic foraminifers indicate a shallow-marine reefal environment with occasional brackish water conditions. Upper Miocene and lower Pliocene deposits placed in calcareous nannofossil Zones NN9-15 and in planktic foraminifer Zones N16-19 contain species-rich benthic microfaunas which indicate alternating reefal and brackish water mangrove environments. The upper Pliocene contains at least two major depositional hiatuses that coincide with a major faunal turnover in benthic foraminiferal and ostracode assemblages. The Quaternary is characterized by benthic microfaunas similar to those of modern atoll lagoons and is punctuated by at least 11 disconformities which signify periods of low sea level. Atoll subsidence rates during the last 10 Ma averaged 30 to 40 m/m.y. ?? 1991 Elsevier Science Publishers B.V. All rights reserved.

Marine Micropaleontology↗
USGS1992

High resolution late Pliocene sea-surface temperature record from the northeast Atlantic Ocean

Application of quantitative micropaleontologic methods of sea-surface temperature (SST) estimation to the planktic foraminiferal faunas at Hole 548 in the northeast Atlantic between 3.5 and 2.0 Ma provide a detailed record of Pliocene surface temperature changes during the onset of major Northern Hemisphere glaciation. SST estimates indicate a relatively warm interval of “enhanced interglacials (warm peaks)” between 3.2 and 2.8 Ma followed by steady cooling with a significant step-like change toward colder temperatures occurring about 2.4 Ma. This record compares well with faunal and SST records from other North Atlantic sites.

Marine Micropaleontology↗
USGS2002

Gas hydrates in the ocean environment

A GAS HYDRATE, also known as a gas clathrate, is a gas-bearing, icelike material. It occurs in abundance in marine sediments and stores immense amounts of methane, with major implications for future energy resources and global climate change. Furthermore, gas hydrate controls some of the physical properties of sedimentary deposits and thereby influences seafloor stability.

Book chapter↗
USGS2014

Deep-ocean ferromanganese crusts and nodules

Ferromanganese crusts and nodules may provide a future resource for a large variety of metals, including many that are essential for emerging high- and green-technology applications. A brief review of nodules and crusts provides a setting for a discussion on the latest (past 10 years) research related to the geochemistry of sequestration of metals from seawater. Special attention is given to cobalt, nickel, titanium, rare earth elements and yttrium, bismuth, platinum, tungsten, tantalum, hafnium, tellurium, molybdenum, niobium, zirconium, and lithium. Sequestration from seawater by sorption, surface oxidation, substitution, and precipitation of discrete phases is discussed. Mechanisms of metal enrichment reflect modes of formation of the crusts and nodules, such as hydrogenetic (from seawater), diagenetic (from porewaters), and mixed diagenetic–hydrogenetic processes.

Book chapter↗
USGS2016

Invasive species: Ocean ecosystem case studies for earth systems and environmental sciences

Marine species are increasingly transferred from areas where they are native to areas where they are not. Some nonnative species become invasive, causing undesirable impacts to environment, economy and/or human health. Nonnative marine species can be introduced through a variety of vectors, including shipping, trade, inland corridors (such as canals), and others. Effects of invasive marine species can be dramatic and irreversible. Case studies of four nonnative marine species are given (green crab, comb jelly, lionfish and Caulerpa algae).

Earth Systems and Environmental Sciences↗