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Stable isotope deltas: Tiny, yet robust signatures in nature

Although most of them are relatively small, stable isotope deltas of naturally occurring substances are robust and enable workers in anthropology, atmospheric sciences, biology, chemistry, environmental sciences, food and drug authentication, forensic science, geochemistry, geology, oceanography, and paleoclimatology to study a variety of topics. Two fundamental processes explain the stable isotope deltas measured in most terrestrial systems: isotopic fractionation and isotope mixing. Isotopic fractionation is the result of equilibrium or kinetic physicochemical processes that fractionate isotopes because of small differences in physical or chemical properties of molecular species having different isotopes. It is shown that the mixing of radioactive and stable isotope end members can be modelled to provide information on many natural processes, including 14C abundances in the modern atmosphere and the stable hydrogen and oxygen isotopic compositions of the oceans during glacial and interglacial times. The calculation of mixing fractions using isotope balance equations with isotope deltas can be substantially in error when substances with high concentrations of heavy isotopes (e.g. 13C, 2H, and 18O ) are mixed. In such cases, calculations using mole fractions are preferred as they produce accurate mixing fractions. Isotope deltas are dimensionless quantities. In the International System of Units (SI), these quantities have the unit 1 and the usual list of prefixes is not applicable. To overcome traditional limitations with expressing orders of magnitude differences in isotope deltas, we propose the term urey (symbol Ur), after Harold C. Urey, for the unit 1. In such a manner, an isotope delta value expressed traditionally as−25 per mil can be written as−25 mUr (or−2.5 cUr or−0.25 dUr; the use of any SI prefix is possible). Likewise, very small isotopic differences often expressed in per meg ‘units’ are easily included (e.g. either+0.015 ‰ or+15 per meg can be written as+15 μUr.

Isotopes in Environmental and Health Studies↗

Two-hundred years of hydrogeology in the United States

The Hydrogeology Division of the Geological Society of America (GSA) sponsored a symposium entitled ' Hydrogeology in the United States, 1776- 1976 ' at the annual meeting of the GSA on November 9, 1976. The symposium was organized to provide a forum for discussion of major eras in the history of American hydrogeology and to contribute to the bicentennial celebration of the founding of the United States. Presentations were broken down into 3 sections: The Early Era (with a tribute to Oscar E. Meinzer), 1776-1920; Meinzer Era, 1910-1940; and the Modern Era (including scientific advantages; the quantification of hydrogeology; geochemistry; surface and borehole geophysics; and hydrogeology, policy, and politics) 1940-1976. (Lantz-PTT)

Open-File Report↗

Cenozoic deposits of southeastern New Mexico and an outline of the history of evaporite dissolution

Sedimentary records of Cenozoic history in southeastern New Mexico begin with the Ogallala Formation of Miocene and Pliocene age. Later records include the Gatuna Formation of early or middle Pleistocene age, Mescalero caliche, an informal term, of middle Pleistocene age, and fluvial deposits of late Pleistocene age but there are many gaps in the record. The modern landscape is the result of erosion and deposition in climates that have ranged from semihumid to semiarid as well as dissolution of soluble rocks in Permian formations in the subsurface. This dissolution may have begun as early as Jurassic time and has continued intermittently to the present.

New Mexico↗

Subaerially carved Arctic seavalley under a modern epicontinental sea

A shallow seavalley , averaging 6 feet in relief, extends from the mouth of Ogotoruk Creek, northwest Alaska, for 15 miles across the floor of the Chukchi Sea to a depth of 135 feet. The seavalley is considered to be a drowned subaerial valley of Pleistocene age, which was excavated on an eustatically emerged epicontinental shelf during periods of glacially depressed sea level.

Bulletin of the Geological Society of America↗

APPLICATION OF SPATIAL INFORMATION TECHNOLOGY TO PETROLEUM RESOURCE ASSESSMENT ANALYSIS.

Petroleum resource assessment procedures require the analysis of a large volume of spatial data. The US Geological Survey (USGS) has developed and applied spatial information handling procedures and digital cartographic techniques to a recent study involving the assessment of oil and gas resource potential for 74 million acres of designated and proposed wilderness lands in the western United States. The part of the study which dealt with the application of spatial information technology to petroleum resource assessment procedures is reviewed. A method was designed to expedite the gathering, integrating, managing, manipulating and plotting of spatial data from multiple data sources that are essential in modern resource assessment procedures.

Conference Paper↗

Interglacial theme and variations: 500 k.y. of orbital forcing and associated responses from the terrestrial and marine biosphere, U.S. Pacific Northwest

Sediments collected off northern California by Ocean Drilling Program Leg 167 contain time series that show strong, orbitally driven insolation forcing of surface oceanographic conditions. Orbital forcing caused a strong response in the distribution of major terrestrial vegetation but a less predictable response for primary productivity offshore. Terrestrial vegetation responded primarily to regional sea surface temperature (SST). Coastal ocean productivity appears highest when SST is moderately high, not during peak interglacial conditions nor during insolation maxima. When individual interglacial intervals are examined closely, each has a different signature. Two of six interglacials (MIS [marine isotope stage] 5 and MIS 11) have higher SST than modern conditions, but each elicits a different response from the terrestrial and marine communities. The type of vegetation and the strength of upwelling vary between interglacials, depending on the relative strength of factors that drive the warming, including insolation, ice-cap size, and level of greenhouse gases.

California↗

Bottom-up and top-down control on hydrothermal resources in the Great Basin: An example from Gabbs Valley, Nevada

The Great Basin in the western United States hosts various hydrothermal systems, including both active geothermal systems and ancient systems preserved as mineral deposits. New magnetotelluric and structural geologic data were collected in the Gabbs Valley area of western Nevada to demonstrate the advantage of imaging the full crustal column below known hydrothermal systems. Three-dimensional models are developed and jointly interpreted where the key findings are bottom-up and top-down controls on hydrothermal systems. Bottom-up control is dictated by weaknesses in the brittle-ductile transition that allow hydrothermal fluids to propagate into the crust; these are often collocated with Miocene volcanic structures. Top-down control is dominated by modern Walker Lane and Basin and Range tectonics that control fluid transport through the middle and upper crust. This study demonstrates that the characterization of regional mineral and geothermal resources is better informed by imaging lower crustal structures and preferential pathways to the surface.

Geophysical Research Letters↗

Digitized data from ground geophysical surveys in Afghanistan: A website for distribution of data

This document describes the process of digitization of a 1974 report on geophysical work undertaken by Soviet geophysicists in southern and eastern Afghanistan. These data, uncovered in Afghanistan, represent magnetic and electrical ground surveys for which locations are not well defined. Due to lack of location information, these surveys were georeferenced using the cities, rivers, and surrounding geology found on the maps used to plot survey locations. A geologic map found in the Soviet report contains profile lines that correspond to the geophysical maps, allowing these data to be georeferenced. The profiles correspond to sets of resistivity, chargeabiliy, and magnetic data. Some datasets were presented as graphs and needed to be gridded into a useable image. Only the vertical component of the magnetic field was collected, so conversion to total field anomaly was necessary. The magnetic data were collected in either gammas or milliorstead, both of which required conversion to standard SI units. To be useful to modern studies, the datasets and images contained in this report have been digitized, georeferenced, and in some cases converted into computer-ready formats.

Open-File Report↗

Future of the US National Strong-Motion Program

These reports are presented in response to a charge of the Earthquake Hazards Reduction Program (EHRP) Program Council of the U.S. Geological Survey to 'define the future of the USGS National Strong-Motion Program (NSMP)' (Appendix A). The council requested that a 'Vision Paper' and an 'Options Document' be prepared. Each of these reports is a separate document. The 'Executive Summary' of both reports is presented here under separate cover. The content of the reports and the executive summary is organized to the extent possible according to the main charges of the EHRP Program Council. Detailed evaluation of charges and questions posed by the Council with the benefit of modern GIS tools and the recent deliberations of three national workshops have yielded substantial new insight regarding the status of strong-motion measurement in the US. These reports are intended as an objective evaluation of the nation's need and capability to record the next major earthquake at locations of most significance for public safety.

Open-File Report↗

Executive summary of vision and options for the future of the US National Strong-Motion Program

These reports are presented in response to a charge of the Earthquake Hazards Reduction Program (EHRP) Program Council of the U.S. Geological Survey to 'define the future of the USGS National Strong-Motion Program (NSMP)' (Appendix A). The council requested that a 'Vision Paper' and an 'Options Document' be prepared. Each of these reports is a separate document. The 'Executive Summary' of both reports is presented here under separate cover. The content of the reports and the executive summary is organized to the extent possible according to the main charges of the EHRP Program Council. Detailed evaluation of charges and questions posed by the Council with the benefit of modern GIS tools and the recent deliberations of three national workshops have yielded substantial new insight regarding the status of strong-motion measurement in the US. These reports are intended as an objective evaluation of the nation's need and capability to record the next major earthquake at locations of most significance for public safety.

Open-File Report↗

Relation of Chlorofluorocarbon Ground-Water Age Dates to Water Quality in Aquifers of West Virginia

The average apparent age of ground water in fractured-bedrock aquifers in West Virginia was determined using chlorofluorocarbon (CFC) dating methods. Since the introduction of CFC gases as refrigerants in the late 1930s, atmospheric concentrations have increased until production ceased in the mid-1990s. CFC dating methods are based on production records that date to the early 1940s, and the preservation of atmospheric CFC concentrations in ground water at the time of recharge. As part of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) and Ambient Ground-Water Monitoring Network (AGN) programs in West Virginia from 1997 to 2005, 80 samples from the Appalachian Plateaus Physiographic Province, 27 samples from the Valley and Ridge Physiographic Province, and 5 samples from the Ohio River alluvial aquifers were collected to estimate ground-water ages in aquifers of West Virginia. Apparent CFC ages of water samples from West Virginia aquifers ranged from 5.8 to 56 years. In the Appalachian Plateaus, topographically driven ground-water flow is evident from apparent ages of water samples from hilltop, hillside, and valley settings (median apparent ages of 12, 14, and 25 years, respectively). Topographic setting was the only factor that was found to be related to apparent ground-water age in the Plateaus at the scale of this study. Similar relations were not found in Valley and Ridge aquifers, indicating that other factors such as bedding or geologic structure may serve larger roles in controlling ground-water flow in that physiographic province. Degradation of CFCs was common in samples collected from methanogenic/anoxic aquifers in the Appalachian Plateaus and suboxic to anoxic aquifers in the Valley and Ridge. CFC contamination was most common in Ohio River alluvial aquifers and carbonate units of the Valley and Ridge, indicating that these highly transmissive surficial aquifers are the most vulnerable to water-quality degradation and may contain wastewater from domestic or industrial sources with CFC concentrations greater than modern atmospheric levels. However, based on a lack of detections of the volatile organic compounds analyzed for in most of the water samples collected for this and similar USGS investigations, ground-water resources of West Virginia used for public and private consumption do not appear to be routinely affected by anthropogenic activities despite their young apparent age.

Scientific Investigations Report↗

High-resolution topography and geomorphology of select archeological sites in Glen Canyon National Recreation Area, Arizona

Along the Colorado River corridor between Glen Canyon Dam and Lees Ferry, Arizona, located some 25 km downstream from the dam, archaeological sites dating from 8,000 years before present through the modern era are located within and on top of fluvial and alluvial terraces of the prehistorically undammed river. These terraces are known to have undergone significant erosion and retreat since emplacement of Glen Canyon Dam in 1963. Land managers and policy makers associated with managing the flow of the Colorado River are interested in understanding how the operations of Glen Canyon Dam have affected the archeological sites associated with these terraces and how dam-controlled flows currently interact with other landscape-shaping processes. In 2012, the U.S. Geological Survey initiated a research project in Glen Canyon to study the types and causes of erosion of the terraces. This report provides the first step towards this understanding by presenting comparative analyses on several types of high-resolution topographic data (airborne lidar, terrestrial lidar, and airborne photogrammetry) that can be used in the future to document and analyze changes to terrace-based archaeological sites. Herein, we present topographic and geomorphologic data of four archaeological sites within a 14 km segment of Glen Canyon using each of the three data sources. In addition to comparing each method’s suitability for adequately representing the topography of the sites, we also analyze the data within each site’s context and describe the geomorphological processes responsible for erosion. Our results show that each method has its own strengths and weaknesses, and that terrestrial and airborne lidar are essentially interchangeable for many important topographic characterization and monitoring purposes. However, whereas terrestrial lidar provides enhanced capacity for feature recognition and gully morphology delineation, airborne methods (whether by way of laser or optical sensors) are better suited for reach- and regional-scale mapping. Our site-specific geomorphic analyses of the four archeological sites indicate that their current topographical conditions are a result of different and sometimes competing erosional agents, including bedrock- and terrace-based overland flow, fluvial-induced terrace bank collapse, and alluvial-fan-generated debris flows. Although the influences of anthropogenic-induced erosion from dam operations are not specifically analyzed in this report, we do identify geomorphic settings where dam operations are either more or less likely to affect archeological site stability. This information can be used to assist with future monitoring efforts of these sites and identification of similar conditions for other archeological sites along the Colorado River corridor in Glen Canyon.

Arizona↗

Groundwater quality near the Montebello Oil Field, Los Angeles County, California

Groundwater quality and potential sources and migration pathways of chemical constituents associated with hydrocarbon-bearing formations were assessed by the U.S. Geological Survey for the California State Water Resources Control Board Oil and Gas Regional Monitoring Program (RMP). Groundwater samples were collected as part of the RMP from 21 preexisting wells used for public supply, monitoring, or irrigation in and near the Montebello Oil Field and analyzed for constituents associated with hydrocarbon-bearing formations and constituents used to identify recently recharged groundwater and older groundwater. The newly collected RMP data were supplemented with historical sample data from 849 groundwater wells and analyzed with respect to explanatory factors that have the potential to influence water quality. Potential sources and migration pathways of fluids (water, gas, or oil) from hydrocarbon-bearing formations that could affect groundwater quality in the Montebello Oil Field include large volumes of recycled produced water (water withdrawn from an oil well and brought to the surface that may include oil, water, and gas from the geologic formation and water or gas injected for enhanced recovery) that have been reinjected since the 1960s to enhance oil production, oil and gas wells with well-integrity issues, and oil and gas wells with an uncemented annulus that intersects groundwater resource zones. Trace amounts of dissolved petroleum hydrocarbons, thermogenic gas (propane through pentane range), or both, were detected in seven groundwater samples collected in 2014 and 2018 as part of the RMP. Five of those samples also contained manufactured volatile organic compounds and at least some modern-age groundwater (recharged during or after 1953), indicating that the hydrocarbons could have originated from surficial, or shallow, sources unrelated to oil and gas development. Two samples contained low concentrations of petroleum hydrocarbons (less than 0.1 microgram per liter) and did not contain detections of manufactured volatile organic compounds in pre-modern groundwater. These samples were collected from relatively deep wells (greater than 140 meters below land surface) with perforations completed in marine sediments that may contain water with similar compositions to produced water. The RMP sample results and available historical data in and near the Montebello Oil Field did not provide conclusive evidence that oil and gas development has adversely affected groundwater resources. All samples with detectable petroleum hydrocarbons, thermogenic gases, or both, were collected from sites that also are within 500 meters of anthropogenic hydrocarbon sources not associated with oil and gas development or sources. In addition, naturally occurring sources of hydrocarbons that exist at intervals shallower than, or are in areas outside of, economically productive oil- and gas-producing zones could affect groundwater quality. A definitive analysis of relations of groundwater quality to potential anthropogenic and natural explanatory factors was not possible because of the low density of new and historical sampling data, particularly in parts of the Montebello Oil Field where the largest relative risks to groundwater from hydrocarbon-bearing formations exist. Areas to consider for more detailed monitoring and analysis in the future that may present the largest relative potential risks to groundwater quality include (1) areas downgradient from historical surface ponds and sumps and (2) areas with co-located high net injection (oil reservoir injection exceeds production), old oil and gas wells that may be more likely to develop well-integrity issues than newer wells, and oil and gas wells with uncemented boreholes intersecting groundwater zones. To help fill gaps resulting from sparse groundwater wells, temperature and resistivity borehole log data could be analyzed to locate anomalies that identify potential areas where relatively warm or saline water from deeper hydrocarbon-bearing formations is present in groundwater.

California↗

The role of preexisting upper plate strike-slip faults during long-lived (ca. 30 Myr) oblique flat slab subduction, southern Alaska

Upper plates of subduction zones commonly respond to flat slab subduction by structural reactivation, magmatic arc disruption, and foreland basin inversion. However, the role of active strike-slip faults in focusing convergent deformation and magmatism in response to oblique flat slab subduction remains less clear. Here, we present new detrital apatite fission-track (dAFT) ages from 12 modern catchments in the eastern Alaska Range, Alaska, USA, to reveal how the dextral Denali fault system has facilitated bedrock exhumation and topographic growth during ca. 30 Ma-to-present oblique flat slab subduction of the Yakutat oceanic plateau. Additionally, a 940 ka ( 40 Ar/ 39 Ar whole rock) basalt flow is spatially associated with Cenozoic structures, locally reset AFT ages and provides the first evidence for Quaternary volcanism along the southern flank of the eastern Alaska Range. We integrate our new data with other thermochronologic, geochronologic, and regional geologic datasets to show that (1) most high topography regions in southern Alaska have undergone rapid bedrock cooling and exhumation since ca. 30 Ma; (2) elevated terrain and young cooling are spatially associated with long-lived active strike-slip fault systems; (3) topographic growth associated with strike-slip fault deformation led to local inversion of basin systems and drainage reorganization; (4) the onset of oblique oceanic plateau subduction is coeval with a southward shift in arc magmatism from one region of active strike-slip faulting to another above the northeastern edge of the flat slab; and (5) Quaternary volcanism marks the revival of magmatism in the eastern Alaska Range above the geophysically imaged northeastern edge of the flat slab. Our analysis of the post-30 Ma geologic evolution of southern Alaska demonstrates that strike-slip fault systems that were active at the time of slab flattening evolved into transpression zones that focused bedrock cooling, rock exhumation, and topographic growth.

Alaska↗

Correcting the historical record for Kīlauea Volcano's 1832, 1868, and 1877 summit eruptions

Three fissure eruptions are known to have occurred along the northeastern edge of Kīlauea's summit caldera in the 19th century—in the years 1832, 1868, and 1877. Modern portrayal of these eruptions on maps and in written sources indicates that the 1832 eruption was from a fissure on the side of the Poliokeawe scarp south of Byron Ledge, the 1868 eruption was from a fissure on the southern wall of Kīlauea Iki Crater and fed a lava flow that covered the bottom of that crater, and the eruption in 1877 occurred on the floor of Keanakākoʻi Crater, as well as from a fissure of uncertain location on the east wall of the caldera below Byron Ledge. New geologic mapping and a review of historical documents and maps contradict these views. We find, instead, that: (1) the 1832 eruption discharged from a fissure on Byron Ledge (not Poliokeawe scarp), from another fissure on the southwestern wall of Kīlauea Iki Crater, and from at least one fissure along the east side of Kīlauea caldera below Byron Ledge; (2) the 1868 lava erupted through the floor of Kīlauea Iki Crater, not from a fissure in its southwestern wall; and (3) the 1877 lava erupted from Kīlauea Iki Crater's mid-wall fissure (until now believed to have opened in 1868), from the fissure previously assigned an 1832 date on Poliokeawe escarpment, and from a precisely relocated vent on the northeastern wall of the caldera. Finally, no conclusive first-hand accounts of the late 19th century eruption in Keanakākoʻi Crater were identified, leaving in doubt the often-inferred 1877 date for this event. Possible alternative dates include 1868, 1879, and 1881.

Hawaii↗

Relict colluvial boulder deposits as paleoclimatic indicators in the Yucca Mountain region, southern Nevada

Early to middle Pleistocene boulder deposits are common features on southern Nevada hillslopes. These darkly varnished, ancient colluvial deposits stand but in stark contrast to the underlying light-colored bedrock of volcanic tuffs, and they serve as minor divides between drainage channels on modern hillslopes. To demonstrate the antiquity of these stable hillslope features, six colluvial boulder deposits from Yucca Mountain, Nye County, Nevada, were dated by cation- ratio dating of rock varnish accreted on boulder surfaces. Estimated minimum ages of these boulder deposits range from 760 to 170 ka. Five additional older deposits on nearby Skull and Little Skull Mountains and Buckboard Mesa yielded cation-ratio minimum-age estimates of 1.38 Ma to 800 ka. An independent cosmogenic chlorine-36 surface exposure date was obtained on one deposit, which confirms an estimated early to middle Quaternary age. These deposits have provided the oldest age estimates for unconsolidated hillslope deposits in the southwestern United States. We suggest that the colluvial boulder deposits were produced during early and middle Pleistocene glacial/pluvial episodes and were stabilized during the transition to drier interglacial climates. By comparison to modern periglacial environments, winter minimum monthly temperatures of -3 to -5 °C were necessary to initiate freeze-thaw conditions of such vigor to physically weather relatively large volumes of large boulders from the upper hillslopes of the Yucca Mountain area. These conditions imply that early and middle Pleistocene glacial winter temperatures were at least 1 to 3 °C colder than existed during the last Pleistocene glacial episode and 7 to 9 °C colder than present. We conclude that at least several early and middle Pleistocene glacial episodes were colder, and perhaps wetter, than glacial episodes of the late Pleistocene in the southern Great Basin. Geomorphic processes necessary to form these colluvial boulder deposits are not active on modern hillslopes in the southern Great Basin. In addition, the lack of young, relatively unvarnished colluvial boulder deposits on these hillslopes suggests that boulder-forming conditions did not exist during the late Pleistocene in this region. Modern semiarid hillslope processes primarily erode colluvium during infrequent high-intensity storms. The preservation of old, thin hillslope deposits and the less-than-2-m incision by hillslope runoff adjacent to these deposits, however, indicate that extremely low denudation rates have occurred on resistant volcanic hillslopes in the southern Great Basin during Quaternary time.

Nevada↗

Water priorities for the nation—The U.S. Geological Survey next generation water observing system

The challenges of providing safe and sustainable water supplies for human and ecological uses and protecting lives and property during water emergencies are well recognized. The U.S. Geological Survey (USGS) plays an essential role in meeting these challenges through its observational networks and renowned water science and research activities (National Academies of Science, Engineering, and Medicine, 2018). Substantial advances in water science, together with emerging breakthroughs in technical and computational capabilities, have led the USGS to develop a Next Generation Water Observing System (NGWOS) . The NGWOS will provide real-time data on water quantity and quality in more affordable and rapid ways than previously possible, and in more locations. The data will be served through a modernized USGS National Water Information System that will be coupled to advanced modeling tools to inform daily water operations, decision-making during water emergencies (like floods, droughts, and contaminant spills), assessments of past trends in water quantity and quality, and forecasts of future water availability.

Fact Sheet↗

Geology, geochemistry, and geophysics of the Fry Canyon uranium/copper project site, southeastern Utah: Indications of contaminant migration

The Fry Canyon uranium/copper project site in San Juan County, southeastern Utah, was affected by the historical (1957–68) processing of uranium and copper-uranium ores. Relict uranium tailings and related ponds, and a large copper heap-leach pile at the site represent point sources of uranium and copper to local soils, surface water, and groundwater. This study was designed to establish the nature, extent, and pathways of contaminant dispersion. The methods used in this study are applicable at other sites of uranium mining, milling, or processing. The uranium tailings and associated ponds sit on a bench that is as much as 4.25 meters above the level of the adjacent modern channel of Fry Creek. The copper heap leach pile sits on bedrock just south of this bench. Contaminated groundwater from the ponds and other nearby sites moves downvalley and enters the modern alluvium of adjacent Fry Creek, its surface water, and also a broader, deeper paleochannel that underlies the modern creek channel and adjacent benches and stream terraces. The northern extent of contaminated groundwater is uncertain from geochemical data beyond an area of monitoring wells about 300 meters north of the site. Contaminated surface water extends to the State highway bridge. Some uranium-contaminated groundwater may also enter underlying bedrock of the Permian Cedar Mesa Sandstone along fracture zones. Four dc-resistivity surveys perpendicular to the valley trend were run across the channel and its adjacent stream terraces north of the heap-leach pile and ponds. Two surveys were done in a small field of monitoring wells and two in areas untested by borings to the north of the well field. Bedrock intercepts, salt distribution, and lithologic information from the wells and surface observations in the well field aided interpretation of the geophysical profiles there and allowed interpretation of the two profiles not tested by wells. The geophysical data for the two profiles to the north of the well field suggest that the paleochannel persists at least 900 m to the north of the heap leach and pond sites. Contamination of groundwater beneath the stream terraces may extend at least that far. Fry Creek surface water (six samples), seeps and springs (six samples), and wells (eight samples) were collected during a dry period of April 16–19, 2007. The most uranium-rich (18.7 milligrams per liter) well water on the site displays distinctive Ca-Mg-SO 4 -dominant chemistry indicating the legacy of heap leaching copper-uranium ores with sulfuric acid. This same water has strongly negative δ 34 S of sulfate (–13.3 per mil) compared to most local waters of –2.4 to –5.4 per mil. Dissolved uranium species in all sampled waters are dominantly U(VI)-carbonate complexes. All waters are undersaturated with respect to U(VI) minerals. The average 234 U/ 238 U activity ratio (AR) in four well waters from the site (0.939±0.011) is different from that of seven upstream waters (1.235±0.069). This isotopic contrast permits quantitative estimates of mixing of site-derived uranium with natural uranium in waters collected downstream. At the time of sampling, uranium in downstream surface water was mostly (about 67 percent) site-derived and subject to further concentration by evaporation. Three monitoring wells located approximately 0.4 kilometer downstream contained dominantly (78–87 percent) site-derived uranium. Distinctive particles of chalcopyrite (CuFeS) and variably weathered pyrite (FeS 2 ) are present in tailings at the stream edge on the site and are identified in stream sediments 1.3 kilometers downstream, based on inspection of polished grain mounts of magnetic mineral separates.

Utah↗