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At least 631 records · Page 35Linked to original sources
USGS1976

Chemical analyses of 183 rocks from the Modoc mine area, Lander County, Nevada

This report presents analytical data for 183 rock samples from the Modoc mine area and a statistical treatment of the data. The Modoc mine area is located in the southwestern part of the Antler Peak quadrangle, between Willow Creek and Rocky Canyon, Lander County, Nev. (fig. 1). The area we studied is centered on a small middle Tertiary pluton, cropping out across an area of less than 0.1 km 2 , which intrudes sandstone, quartzite, shale, limestone, and chert of the Pennsylvanian and Lower Permian Havallah Formation (fig. 2). Detailed descriptions of the geology and geochemistry of the porphyry-copper environment of the general area are given by Roberts (1964), Roberts and Arnold (1965), Nash and Theodore (1971), Theodore, Silberman, and Blake (1973), and Theodore and Blake (1975). Theodore, Silverman, and Blake (1973) determined ages of 41 and 39 m.y. by the K-Ar method on mineral separates of magmatic hornblende and biotite, respectively, from the pluton of the Modoc mine area. Gold mineralization in the immediate area was apparently first discovered in 1925, and the property has been worked intermittently since that time; mineral rights are presently held by Charles L. Caldwell of Battle Mountain, Nev. The major underground workings explore two steeply dipping and parallel shear zones that strike approx-imately N. 25° W. These zones are up to 1 m wide and contain steeply plunging shoots of high concentrations of precious metals. Little is known about the production from the area, but it appears that only a few thousand dollars in gold and small amounts of silver may have been produced. Gold was found in narrow quartz veinlets near the surface of the pluton, and sulfides were encountered at a depth of about 10 m. Assays indicate that the sulfide-rich rock contains gold and silver. Trace amounts of secondary copper minerals occur in both the underground workings and on the surface. Samples collected away from the two major veins also yielded anomalous gold concentrations.

Nevada↗
USGS1977

Geologic interpretation of a radioactivity anomaly near the west fork of the Buckland River, western Alaska

A large part of western Alaska has been included in a uranium- thorium metallogenic province (Clark and others, 1974; Miller and Bunker, 1976; Miller, 1976) chiefly because of the occurrence of uraniferous plutonic rocks with local concentrations of uranium minerals. Recently, however, anomalous amounts of uranium and thorium have been found by the Geological Survey in volcanic and volcaniclastic rocks near the headwaters of the West Fork of the Buckland River in the central Candle quadrangle (fig. 1). This occurrence is apparently in a different geologic environment than previously noted uranium occurrences in western Alaska. An increase in radioactivity was noted in this general area and three airborne gamma-ray survey traverses, done as part of an ERDA-sponsored reconnaissance survey of western Alaska, cross the area (figs. 1, 2) and confirm the existence of a radioactivity anomaly (U.S. Energy Research and Development Administration, 1975, report GJO-1653).

Alaska↗
USGS1987

Macrofauna and environment of the Nanpil-Kiepw River, Ponape, Eastern Caroline Islands

The first comprehensive evaluation of stream fauna in the Eastern Caroline Islands resulted from collections on Ponape, a 334-km- island having more than 40 streams, many of which arise along 700-m-high interior ridges. Field surveys centered on the Nanpil-Kiepw River below 170 m elevation, a bouldery reach with water of low mineral content and frequent surging flows. Faunal specimens were collected by electrofishing, rotenone treatment, netting, and hand picking. Discharge character of the Nanpil-Kiepw River is similar to but more extreme than that of other streams of Oceania with which it was compared. Drastic flow surges appeared to be a major factor affecting community structure. At least 44 faunal species were present, 36 of them representing taxons primarily of marine origin that are characteristic of oceanic islands: 15 fishes (5 families), 10 decapod crustaceans (3 families), and 11 snails (2 families). Larvae of aquatic moths were the only insects of significance. Four sicydiine gobies are new species possibly endemic to Ponape or the Eastern Caroline Islands. Based on numbers of species within prominent taxons and diadromous groups, Ponape’s faunal diversity exceeds that of Samoa, Guam, and Hawaii, but is lower than that of Palau. Similarities of Ponape's identified fish species to those of Palau suggest that Ponape was colonized from the west along the “Caroline conduit.”

Pohnpei↗
USGS2004

Mineralogical and geochemical controls on the release of trace elements from slag produced by base- and precious-metal smelting at abandoned mine sites

Slag collected from smelter sites associated with historic base-metal mines contains elevated concentrations of trace elements such as Cu, Zn and Pb. Weathering of slag piles, many of which were deposited along stream banks, potentially may release these trace elements into the environment. Slags were sampled from the Ely and Elizabeth mines in the Vermont copper belt, from the copper Basin mining district at Ducktown, Tennessee and from the Clayton silver mine in the Bayhorse mining district, Idaho, in the USA. Primary phases in the slags include: olivine-group minerals, glass, spinels, sulfide minerals and native metals for Vermont samples; glass, sulfide minerals and native metals for the Ducktown sample; and olivine-group minerals, clinopyroxenes, spinels, sulfide minerals, native metals and other unidentified metallic compounds for Clayton slag. Olivine-group minerals and pyroxenes are dominantly fayalitic and hedenbergitic in composition, respectively and contain up to 1.25 wt.% ZnO. Spinel minerals range between magnetite and hercynite in composition and contain Zn (up to 2.07 wt.% ZnO), Ti (up to 4.25 wt.% TiO2) and Cr (up to 1.39 wt.% Cr2O3). Cobalt, Ni, Cu, As, Ag, Sb and Pb occur in the glass phase, sulfides, metallic phases and unidentified metallic compounds. Bulk slag trace-element chemistry shows that the metals of the Vermont and Tennessee slags are dominated by Cu (1900-13,500 mg/kg) and Zn (2310-10,200 mg/kg), whereas the Clayton slag is dominated by Pb (63,000 mg/kg), Zn (19,700 mg/kg), Cu (7550 mg/kg), As (555 mg/kg), Sn (363 mg/kg) and Ag (200 mg/kg). Laboratory-based leach tests indicate metals can be released under simulated natural conditions. Leachates from most slags were found to contain elevated concentrations of Cu and Zn (up to 1800 and 470 ??g/l, respectively), well in excess of the acute toxicity guidelines for aquatic life. For the Idaho slag, the concentration of Pb in the leachate (11,000 ??g/l) is also in excess of the acute toxicity guideline. Geochemical modeling of the leachate chemistry suggests that leachates from the Vermont, Tennessee and Clayton slags are saturated with amorphous silica and Al hydroxide. Therefore, the dissolution of silicate and oxide phases, the oxidation of sulfide phases, as well as the precipitation of secondary phases may control the composition of leachate from slags. The presence of secondary minerals on slag deposits in the field is evidence that these materials are reactive. The petrographic data and results of leaching tests from this study indicate slag may be a source of potentially toxic metals at abandoned mine sites.

Conference Paper↗
USGS2010

Organic petrology of subbituminous carbonaceous shale samples from Chalāw, Kabul Province, Afghanistan: Considerations for paleoenvironment and energy resource potential

Neogene (?) subbituminous carbonaceous shale deposits from Chalāw, Afghanistan, were investigated through organic petrology techniques and standard coal analyses to determine paleoenvironment and potential for resource utilization. The Chalāw deposit, approximately 30 km southeast of Kabul, currently is exploited for brick making and domestic heating and cooking. Three multiple-bench channel samples of the mined bed at Chalāw were collected and evaluated. The presence of significant huminite (ranging from 0.2 to 59.0 vol.%, mineral-inclusive basis) is suggestive of a terrestrial lignin-rich precursor plant material. Measured reflectance values of 0.38–0.55% indicate subbituminous rank. This rank suggests burial depths of approximately 1500 m and maximum temperatures of approximately 50 °C. Structured liptinite macerals generally are absent except for some fluorescing morphologies interpreted to be poorly-preserved root cork suberinite. Sponge spicule bioliths including gemmoscleres and megascleres are common. These petrographic observations, in addition to high mineral matter content (33 to > 95 vol.%), medium to high sulfur content (2.1–11.5 wt.%, dry basis; db), and the presence of common gastropod? shell fragments and an aragonite-needle chalk bed are consistent with, but not directly indicative of, a marginal marine or estuarine mangrove depositional environment. However, additional data are necessary to confirm this hypothesis and deposition in a freshwater environment cannot be ruled out at this time. Commercial-scale development and utilization of the Chalāw deposit as a thermal fuel resource may be possible using a fluidized bed combustion system which could accept the low-quality mine product currently produced. Samples examined herein contain high-ash yield (45–90 wt.%, db), high total moisture content (17–39 wt.%), low calorific value (980–6860 Btu/lb, m,mmf), and have poor agglomerating properties (FSI = 0), consistent with fuels utilized in fluidized bed combustors. However, delineation of the extent of the deposit through field investigation will be necessary to make a quantified resource estimate for mine planning.

Kabul Province↗
USGS2011

Porphyry Cu indicator minerals in till as an exploration tool: Example from the giant Pebble porphyry Cu-Au-Mo deposit, Alaska, USA

Porphyry Cu indicator minerals are mineral species in clastic sediments that indicate the presence of mineralization and hydrothermal alteration associated with porphyry Cu and associated skarn deposits. Porphyry Cu indicator minerals recovered from shallow till samples near the giant Pebble Cu-Au-Mo porphyry deposit in SW Alaska, USA, include apatite, andradite garnet, Mn-epidote, visible gold, jarosite, pyrite, and cinnabar. Sulphide minerals other than pyrite are absent from till, most likely due to the oxidation of the till. The distribution of till samples with abundant apatite and cinnabar suggest sources other than the Pebble deposit. With three exceptions, all till samples up-ice of the Pebble deposit contain <10 grains/10kg of garnet (0.25-0.5 mm). Samples in the immediate vicinity of the Pebble deposit contain 10-20 grains, whereas samples with the most grains (>40grains/10kg) are in close proximity to smaller porphyry and skarn occurrences in the region. The distribution of Mn-epidote closely mimics the distribution of garnet in the till samples and further supports the interpretation that these minerals most likely reflect skarns associated with the porphyry deposits. All but two till samples, including those up-ice from the deposit, contain some gold grains. However, tills immediately west and down-ice of Pebble contain more abundant gold grains, and the overall number of grains decreases in the down-ice direction. Furthermore, all samples in the immediate vicinity of Pebble contain more than 65% pristine and modified grains compared to mostly re-shaped grains in distal samples. The pristine gold in till reflects short transport distances and/or liberation of gold during in-situ weathering of transported chalcopyrite grains. Jarosite is also abundant (1-2 500 grains/10kg) in samples adjacent to and up to 7 km down-ice from the deposit. Most jarosite grains are rounded and preliminary Ar/Ar dates suggest the jarosite formed prior to glaciation and it implies that a supergene cap existed over Pebble West. Assuming this interpretation is accurate, it suggests a shallow level of erosion of the Pebble deposit by glacial processes. Overall the results of this study indicate that porphyry Cu indicator minerals in till samples may be useful in the exploration for porphyry deposits in SW Alaska.

Alaska↗
USGS2008

The metallogeny of Late Triassic rifting of the Alexander terrane in southeastern Alaska and northwestern British Columbia

A belt of unusual volcanogenic massive sulfide (VMS) occurrences is located along the eastern margin of the Alexander terrane throughout southeastern Alaska and northwestern British Columbia and exhibits a range of characteristics consistent with a variety of syngenetic to epigenetic deposit types. Deposits within this belt include Greens Creek and Windy Craggy, the economically most significant VMS deposit in Alaska and the largest in North America, respectively. The occurrences are hosted by a discontinuously exposed, 800-km-long belt of rocks that consist of a 200- to 800-m-thick sequence of conglomerate, limestone, marine elastic sedimentary rocks, and tuff intercalated with and overlain by a distinctive unit of mafic pyroclastic rocks and pillowed flows. Faunal data bracket the age of the host rocks between Anisian (Middle Triassic) and late Norian (late Late Triassic). This metallogenic belt is herein referred to as the Alexander Triassic metallogenic belt. The VMS occurrences show systematic differences in degree of structural control, chemistry, and stratigraphic setting along the Alexander Triassic metallogenic belt that suggest important spatial or temporal changes in the tectonic environment of formation. At the southern end of the belt, felsic volcanic rocks overlain by shallow-water limestones characterize the lower part of the sequence. In the southern and middle portion of the belt, a distinctive pebble conglomerate marks the base of the section and is indicative of high-energy deposition in a near slope or basin margin setting. At the northern end of the belt the conglomerates, limestones, and felsic volcanic rocks are absent and the belt is composed of deep-water sedimentary and mafic volcanic rocks. This northward change in depositional environment and lithofacies is accompanied by a northward transition from epithermal-like structurally controlled, discontinuous, vein- and pod-shaped, Pb-Zn-Ag-Ba-(Cu) occurrences with relatively simple mineralogy, to sulfosalt-enriched VMS occurrences exhibiting characteristics of vein, diagenetic replacement, and exhalative styles of mineralization, and finally to Cu-Zn-(Co-Au) occurrences with larger and more clearly stratiform orebody morphologies. Occurrences in the middle of the belt are transitional in nature between structurally controlled types of mineralization that formed in a shallow-water, near-arc setting, to those having a more stratiform appearance, formed in a deeper water, rift-basin setting. The geologic setting in the south is consistent with shallow subaqueous emplacement on the flanks of the Alexander terrane. Northward, the setting changes to an increasingly deeper back- or intra-arc rift basin. Igneous activity in the Alexander Triassic metallogenic belt is characterized by a bimodal suite of volcanic rocks and a previously unrecognized association with mafic-ultramafic hypabyssal intrusions. Immobile trace and rare earth element (BEE) geochemical data indicate that felsic rocks in the southern portion of the belt are typical calc-alkaline rhyolites, which give way in the middle of the belt to peralkaline rhyolites. Rhyolites are largely absent in the northern part of the belt. Throughout the belt, the capping basaltic rocks have transitional geochemical signatures. Radiogenic isotope data for these rocks are also transitional (basalts and gabbros: ??-Nd = 4-9 and 87Sr/86Sr initial at 215 Ma = 0.7037-0.7074). Together these data are interpreted to reflect variable assimilation of mature island-arc crust by more primitive melts having the characteristics of either mid-ocean ridge (MORB) or intraplate (within-plate) basalts (WPB). The ore and host-rock geochemistry and the sulfosalt-rich mineralogy of the deposits are strikingly similar to recent descriptions of active sea-floor hydrothermal (white smoker) systems in back arcs of the southwest Pacific Ocean. These data, in concert with existing faunal ages, record the formation of a belt of VMS deposits

Conference Paper↗
USGS1988

The ecology of the soft-bottom benthos of San Francisco Bay: a community profile

This profile, part of a series of profiles concerning coastal habitats of the United States, is a detailed examination of the soft-bottom benthos of San Francisco Bay. A U.S. Fish and Wildlife Service and California Department of Fish and Game report (1979) entitled "Protection and Restoration of San Francisco Bay Fish and Wildlife Habitat" provides clear recognition of the importance of intertidal and subtidal soft-bottom habitats and their associated organisms to the bay's birds and fishes and to the overall functioning of the estuary. The purpose of this profile is to provide a description of the structure and functioning of the benthic community in San Francisco Bay (exclusive of its tidal marshes, which are discussed by M. Josselyn [1983] in another profile). The habitats covered in this volume include all nonvegetated soft-bottom intertidal and subtidal areas of the bay between the Golden Gate and the mouths of the Sacramento and San Joaquin Rivers to the northeast, and to the southern extremity of the bay. The profile provides a reference to the scientific information concerning the animals and plants of the bay's benthic communities, their importance to the bay ecosystem, and their value as a resource measured in human terms. Because there have been few process-oriented studies of the benthos of San Francisco Bay (e.g., field and laboratory rate-measurement experiments), the material presented herein is largely descriptive. Nonetheless, we have described the processes that interconnect the various physical, chemical, and biological components of the benthic environment, and the important couplings between this environment and the water column above, with reference to research results from other estuaries where necessary. We consider the role of the benthic community as a food source for fish, aquatic birds, and humans; as a consumer or degrader of organic materials including wastes; as a recycler of minerals and nutrients; and as an accumulator of pollutants.

California↗
USGS2015

Conceptual models of the formation of acid-rock drainage at road cuts in Tennessee

Pyrite and other minerals containing sulfur and trace metals occur in several rock formations throughout Middle and East Tennessee. Pyrite (FeS2) weathers in the presence of oxygen and water to form iron hydroxides and sulfuric acid. The weathering and interaction of the acid on the rocks and other minerals at road cuts can result in drainage with low pH (< 4) and high concentrations of trace metals. Acid-rock drainage can cause environmental problems and damage transportation infrastructure. The formation and remediation of acid-drainage from roads cuts has not been researched as thoroughly as acid-mine drainage. The U.S Geological Survey, in cooperation with the Tennessee Department of Transportation, is conducting an investigation to better understand the geologic, hydrologic, and biogeochemical factors that control acid formation at road cuts. Road cuts with the potential for acid-rock drainage were identifed and evaluated in Middle and East Tennessee. The pyrite-bearing formations evaluated were the Chattanooga Shale (Devonian black shale), the Fentress Formation (coal-bearing), and the Precambrian Anakeesta Formation and similar Precambrian rocks. Conceptual models of the formation and transport of acid-rock drainage (ARD) from road cuts were developed based on the results of a literature review, site reconnaissance, and the initial rock and water sampling. The formation of ARD requires a combination of hydrologic, geochemical, and microbial interactions which affect drainage from the site, acidity of the water, and trace metal concentrations. The basic modes of ARD formation from road cuts are; 1 - seeps and springs from pyrite-bearing formations and 2 - runoff over the face of a road cut in a pyrite-bearing formation. Depending on site conditions at road cuts, the basic modes of ARD formation can be altered and the additional modes of ARD formation are; 3 - runoff over and through piles of pyrite-bearing material, either from construction or breakdown material weathered from shale, and 4 - the deposition of secondary-sulfate minerals can store trace metals and, during rainfall, result in increased acidity and higher concentrations of trace metals in storm runoff. Understanding the factors that control ARD formation and transport are key to addressing the problems associated with the movement of ARD from the road cuts to the environment. The investigation will provide the Tennessee Department of Transportation with a regional characterization of ARD and provide insights into the geochemical and biochemical attributes for the control and remediation of ARD from road cuts.

Tennessee↗
USGS2012

Lineament analysis of mineral areas of interest in Afghanistan

During a preliminary mineral resource assessment of Afghanistan (Peters and others, 2007), 24 mineralized areas of interest (AOIs) were highlighted as the focus for future economic development throughout various parts of the country. In addition to located mineral resources of value, development of a viable mining industry in Afghanistan will require the location of suitable groundwater resources for drinking, processing of mineral ores for use or for export, and for agriculture and food production in areas surrounding and supporting future mining enterprises. This report and accompanying GIS datasets describe the results of both automated and manual mapping of lineaments throughout the 24 mineral occurrence AOIs described in detail by Peters and others (2007; 2011). For this study, we define lineaments as "mappable linear or curvilinear features of a surface whose parts align in a straight or slightly curving relationship that may be the expression of a fault or other linear zones of weakness" as derived from remote sensing sources such as optical imagery, radar imagery or digital elevation models (DEMs) (Sabins, 2007). Water wells in bedrock aquifers are generally more productive where boreholes intersect fractures or fracture zones. Lineament identification and analysis have long been used as a reconnaissance tool to identify such favorable conditions for groundwater resources in carbonate bedrock environments (Lattman and Parizek, 1964; Siddiqui and Parizek, 1971). More recently, lineament analysis has been used to identify areas of greater well yields in other bedrock settings, such as crystalline bedrock (Mabee and other, 1994; Moore and others, 2002). Lineaments provide an indication of bedrock areas that warrant further investigation for optimal water well placement. They may also indicate areas of preferential flow and storage of groundwater, and, thus, areas with a greater density of lineaments may indicate greater secondary porosity. Lineaments may indicate structurally trending mineralized areas (for example, Mars and Rowan, 2007), or locations of near-surface water resources, especially when surface vegetation growth coincides with lineaments. The purpose of this report and accompanying GIS data is to provide lineament maps that give one indication of areas that warrant further investigation for optimal bedrock water-well placement within 24 target areas for mineral resources (Peters and others, 2011). These data may also support the identification of faults related to modern seismic hazards (for example, Wheeler and others, 2005; Ruleman and others, 2007), as well as support studies attempting to understand the relationship between tectonic and structural controls on hydrothermal fluid flow, subsequent mineralization, and water-quality issues near mined and unmined mineral deposits (for example, Eppinger and others, 2007).

Open-File Report↗
USGS2023

Insights into the metamorphic history and origin of flake graphite mineralization at the Graphite Creek graphite deposit, Seward Peninsula, Alaska, USA

Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ 13 C VPDB values of − 30 to − 12‰ and pyrrhotite δ 34 S VCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.

Alaska↗
USGS2017

Use of raw materials in the United States from 1900 through 2014

The economic growth of an industrialized nation such as the United States requires raw materials for construction (buildings, bridges, highways, and so forth), defense, and processing and manufacture of goods and services. Since the beginning of the 20th century, the types and quantities of raw materials used have increased and changed significantly. This fact sheet quantifies the amounts of raw materials (other than food and fuel) that have been used in the U.S. economy annually for a period of 115 years, from 1900 through 2014. It provides a broad overview of the quantity (weight) of nonfood and nonfuel materials used in the economy and illustrates the use and significance of raw nonfuel minerals in particular as building blocks of society. These data have been compiled to help the public and policymakers understand the changing annual flow of raw materials put into use in the United States. Such information can be helpful in assessing the potential effects of materials use on the environment, assessing materials’ intensity of use, and examining the role that these materials play in the economy. The data presented indicate the substitution and shift in materials usage from renewable to nonrenewable materials during the 20th century. The disaggregated quantities by commodity (not shown in this fact sheet) may be tested against supply adequacy and end of life issues.

Fact Sheet↗
USGS1986

Applications of UThPb isotope systematics to the problems of radioactive waste disposal

Concentrations of U, Th and Pb, and the isotopic composition of Pb for whole-rock samples of granitoids show: (1) that open-system behavior is nearly universal in the surface and near-surface environment; and (2) that elemental mobility is possible to depths of several hundred meters. Several identified or at least postulated factors that control U and/or Pb mobility include: (1) the mineralogical sites for U and its daughter products; (2) access of groundwater to these sites; (3) the volume of circulating water; and (4) the chemistry of the groundwater. Studies of granitic samples from peralkaline complexes in the Arabian Shield have shown that most samples lost less than 20% of their U during recent exposure to the near-surface environment. Most of the U in these samples appears to be firmly bound in zircons. In contrast, most surface and shallow drill-core samples of the granite of Lankin Dome (Granite Mountains, Wyoming) have lost ??? 70% of their U. Most of the U in these samples is weakly bound in biotite and epidote-family minerals. The granite recovered during the Illinois Deep Drill Hole Project (Stephenson County, Illinois) is mineralogically similar to the granite of Lankin Dome, but this granite lost radiogenic Pb rather than U, probably as a result of exposure to groundwater that had a markedly different chemistry from that in the Granite Mountains. Studies of the Sherman Granite (Wyoming) and the Go??temar Granite (southeastern Sweden) have shown that U and/or Pb mobility is greatest in and near fractured rock. The greater mobility is interpreted to be the result of both a larger water/rock ratio in the fractured rock and exposure to water over an increased surface area (and consequently a greater number of uranium sites). Several types of geochemical and mineralogic data can be used to identify rock-water interaction in granites; however, if rock samples have favorable radiogenic to common Pb ratios, both the amount and approximate timing of U or Pb mobility can be obtained through the use of isotopic studies. Such information can be extremely important in the search for favorable hosts for containment of radioactive waste. Rocks such as the Go??temar Granite have undergone considerable rock-water interaction, most of which occurred ??? 400 Myr. ago and little in recent times. Thus a search for zones that have experienced only a little interaction with water may provide a misleading prediction as to the ability of such zones to shield radioactive wastes from the modern biosphere. From an isotopic point of view, an ideal candidate for evaluation as a host rock for radioactive wastes would have the following characteristics: (1) a high ratio (> 2) of radiogenic to common Pb in order to optimize precision of the results; (2) a simple two-stage geologic history so that results could be interpreted without multiple working hypotheses; and (3) an originally high percentage (> 50%) of labile U so that the results would be highly sensitive to even small amount of rock-water interaction. These characteristics should produce rocks with marked radioactive disequilibrium in surface samples. The disequilibrium should grade to radioactive equilibrium with increasing depth until zones in which water has not circulated are found. Extensive regions of such zones must exist because UThPb systematics of most analyzed granitoids demonstrate closed-system behavior for almost all of their history except for their recent history in the near-surface environment. ?? 1986.

Chemical Geology↗
USGS1992

Reduction of uranium by Desulfovibrio desulfuricans

The possibility that sulfate-reducing microorganisms contribute to U(VI) reduction in sedimentary environments was investigated. U(VI) was reduced to U(IV) when washed cells of sulfate-grown Desulfovibrio desulfuricans were suspended in a bicarbonate buffer with lactate or H2 as the electron donor. There was no U(VI) reduction in the absence of an electron donor or when the cells were killed by heat prior to the incubation. The rates of U(VI) reduction were comparable to those in respiratory Fe(III)-reducing microorganisms. Azide or prior exposure of the cells to air did not affect the ability of D. desulfuricans to reduce U(VI). Attempts to grow D. desulfuricans with U(VI) as the electron acceptor were unsuccessful. U(VI) reduction resulted in the extracellular precipitation of the U(IV) mineral uraninite. The presence of sulfate had no effect on the rate of U(VI) reduction. Sulfate and U(VI) were reduced simultaneously. Enzymatic reduction of U(VI) by D. desulfuricans was much faster than nonenzymatic reduction of U(VI) by sulfide, even when cells of D. desulfuricans were added to provide a potential catalytic surface for the nonenzymatic reaction. The results indicate that enzymatic U(VI) reduction by sulfate-reducing microorganisms may be responsible for the accumulation of U(IV) in sulfidogenic environments. Furthermore, since the reduction of U(VI) to U(IV) precipitates uranium from solution, D. desulfuricans might be a useful organisms for recovering uranium from contaminated waters and waste streams.

Applied and Environmental Microbiology↗
USGS2002

Physical and stable-isotope evidence for formation of secondary calcite and silica in the unsaturated zone, Yucca Mountain, Nevada

Calcite and silica form coatings on fracture footwalls and cavity floors in the welded tuffs at Yucca Mountain, the potential site of a high-level radioactive waste repository. These secondary mineral deposits are heterogeneously distributed in the unsaturated zone (UZ) with fewer than 10% of possible depositional sites mineralized. The paragenetic sequence, compiled from deposits throughout the UZ, consists of an early-stage assemblage of calcite??fluorite??zeolites that is frequently capped by chalcedony??quartz. Intermediate- and late-stage deposits consist largely of calcite, commonly with opal on buried growth layers or outermost crystal faces of the calcite. Coatings on steep-dipping fractures usually are thin (??? 3 mm) with low-relief outer surfaces whereas shallow-dipping fractures and lithophysal cavities typically contain thicker, more coarsely crystalline deposits characterized by unusual thin, tabular calcite blades up to several cms in length. These blades may be capped with knobby or corniced overgrowths of late-stage calcite intergrown with opal. The observed textures in the fracture and cavity deposits are consistent with deposition from films of water fingering down fracture footwalls or drawn up faces of growing crystals by surface tension and evaporated at the crystal tips. Fluid inclusion studies have shown that most early-stage and some intermediate-stage calcite formed at temperatures of 35 to 85??C. Calcite deposition during the past several million years appears to have been at temperatures < 30??C. The elevated temperatures indicated by the fluid inclusions are consistent with temperatures estimated from calcite ??18O values. Although others have interpreted the elevated temperatures as evidence of hydrothermal activity and flooding of the tuffs of the potential repository, the authors conclude that the temperatures and fluid-inclusion assemblages are consistent with deposition in a UZ environment that experienced prolonged heat input from gradual cooling of nearby plutons. The physical restriction of the deposits (and, therefore, fluid flow) to fracture footwalls and cavity floors and the heterogeneous and limited distribution of the deposits provides compelling evidence that they do not reflect flooding of the thick UZ at Yucca Mountain. The textures and isotopic and chemical compositions of these mineral deposits are consistent with deposition in a UZ setting from meteoric waters percolating downward along fracture flow paths.

Applied Geochemistry↗
USGS1990

Monitoring long-term effects of offshore oil and gas development along the Southern California outer continental shelf and slope: Background environmental conditions in the Santa Maria Basin

Potential environmental impacts of materials discharged from oil and gas development and production platforms off the coast of southern California (Santa Maria Basin) are being monitored during an ongoing, long-term (fiveyear) field program. The study combines hypothesis testing of platform effects with basic research on the structure and dynamics of the regional ecosystem over a time series encompassing both seasonal and repeated annual scales. Oceanographic features and processes that are being measured focus on the benthos and include biological community indices and species abundances for hard-bottom and soft-bottom (macroinfauna and meiofauna) assemblages; levels and distributions of trace metals and hydrocarbons in bottom sediments, suspended particulates, animal tissues, and pore waters; water currents and otherphysical-oceanographicfeatures; various sedimentological properties (sediment grain size, total organic carbon, shear strength, distribution of mineral types, radioisotope profiles, and degrees of sediment mixing as a result of bioturbation); sediment and pollutant-transport processes; and animal-sediment-pollutant interactions. Synoptic measurement of these different environmental variables over the extended sampling period provides an opportunity to examine long-term variability in the benthic environment with respect to both natural and anthropogenic causes. Efforts to distinguish between natural variability and low-level cumulative impacts of drilling are given special attention. Results obtained during the first two years of sampling provide a basis for beginning to understand environmental processes and relations important in detecting and interpreting any subsequent impacts caused by drilling activities in this complex and productive region of the California outer continental shelf and slope. Background chemical, physical, and biological data generated during this period demonstrate that impacts of discharges from oil and gas operations should be detectable, if they occur, and should be distinguishable from natural environmental variability. Small inputs of barium and petroleum hydrocarbons have been detected and appear to be associated with the minor drilling activities that have occurred in the area thus far, however, these initial inputs have not led to any noticeable biological impacts. These initial results are hopefully of value for two reasons: (1) in providing a summary of basic chemical, physical, and biological features of the benthic environment within the Santa Maria Basin; and (2) in presenting information on research strategies that should be considered in designing studies dealing with similar resource-management problems in other parts of the world.

California↗
USGS2024

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis↗
USGS2008

View_SPECPR: Software for plotting spectra (installation manual and user's guide, version 1.2)

This document describes procedures for installing and using the 'View_SPECPR' software system to plot spectra stored in SPECPR (SPECtrum Processing Routines) files. The View_SPECPR software is comprised of programs written in IDL (Interactive Data Language) that run within the ENVI (ENvironment for Visualizing Images) image processing system. SPECPR files are used by earth-remote-sensing scientists and planetary scientists for storing spectra collected by laboratory, field, and remote sensing instruments. A widely distributed SPECPR file is the U.S. Geological Survey (USGS) spectral library that contains thousands of spectra of minerals, vegetation, and man-made materials (Clark and others, 2007). SPECPR files contain reflectance data and associated wavelength and spectral resolution data, as well as meta-data on the time and date of collection and spectrometer settings. Furthermore, the SPECPR file automatically tracks changes to data records through its 'history' fields. For more details on the format and content of SPECPR files, see Clark (1993). For more details on ENVI, see ITT (2008). This program has been updated using an ENVI 4.5/IDL7.0 full license operating on a Windows XP operating system and requires the installation of the iTools components of IDL7.0; however, this program should work with full licenses on UNIX/LINUX systems. This software has not been tested with ENVI licenses on Windows Vista or Apple Operating Systems.

Open-File Report↗