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The evolution of the southern California uplift, 1955 through 1976

The southern California uplift culminated in 1974 as a 150- km-wide crustal swell that extended about 600 km eastward and east-southeastward from Point Arguello to the Colorado River and Salton Sea, respectively; it was characterized by remarkably uniform height changes between 1959 and 1974 of 0.30-0.35 m over at least half of its 60,000-70,000 km 2 area. At its zenith, the uplift included virtually the entire Transverse Ranges geologic province and parts of the Coast Ranges, San Joaquin Valley, Sierra Nevada, Basin and Range, Mojave Desert, Peninsular Ranges, and Salton Trough provinces. The alinement of the western part of the uplift closely paralleled the east-trending Transverse Ranges, whereas the southern flank of the eastern lobe roughly coincided with the west-northwest-trending San Andreas fault. The position and configuration of the uplift associate it with a singularly complex section of the boundary between the North American and Pacific plates that has certainly sustained major modification during the past 5 million years and probably during the past 1 million years. Surface deformation can be categorized as tectonic or nontectonic. Nontectonic vertical displacements associated with the activities of man have overwhelmed natural compaction and areally significant soil expansion in the southern California area. Because tectonic displacements are implicitly defined as those that cannot be otherwise explained, those vertical movements that can be reasonably attributed to artificial processes have been subtracted from our reconstructed configurations of the uplift. Hence this reconstruction has necessarily included the assembly and evaluation of an enormous volume of data on oil-field operations, changes in ground-water levels, and measured subsidence (or rebound) associated with changes in the underground fluid regimen. Measured changes in height at various stages in the evolution of the uplift have been based chiefly on first-order levelings carried out between 1953 and 1976. Exceptions to this generalization consist largely of the results of pre-1953 surveys through the western Transverse Ranges and the eastern Mojave Desert. Errors in measured height differences derive from blunders, systematic survey errors, random survey errors, improperly formulated orthometric corrections, and intrasurvey movement; the last of these has created the most serious problems encountered in our reconstruction of the basic data. A variety of independent tests indicate that survey error associated with the utilized levelings was generally small and fell largely within the predicted random-error range. Moreover, the redundancy and coherence displayed by the entire data set provide convincing evidence of survey accuracy and the virtual absence of height- and slope-dependent error in particular. Our reconstructions of the changing configuration of the uplift derive chiefly from comparisons among sequentially developed observed elevations along the same route. Most of the observed elevations from which the vertical displacements were computed have been reconstructed with respect to bench mark Tidal 8, San Pedro, as invariant in height. Because the San Pedro tide station has been characterized by a history of modest relative uplift, vertical displacements referred to this station are biased slightly toward the appearance of subsidence. Where the observed elevations cannot be conveniently tied to Tidal 8, they have been referred to secondary control points whose history with respect to Tidal 8 can be independently established. Each of the lines of observed elevation changes provides, accordingly, a section athwart or along the axis of the uplift from which the changes in the configuration of the uplift can be roughly generalized. Because relatively few surveys were run in 1955, which we choose as a representative temporal datum, we have commonly incorporated the results of earlier or of somewhat later levelings as the equivalents of 1955 surveys. Although this procedure introduces a certain subjectivity, the probable equivalence between the results of these earlier or later surveys with those that would have been obtained had this leveling been carried out in 1955, usually can be independently tested. Wherever the calculated vertical displacements are based on comparisons between the results of levelings over different routes, the observed elevations have been orthometrically corrected to agree with those that would have been produced had each of these surveys been along the same route. The growth of the southern California uplift consisted of two well-defined spasms of positive movement, the second of which was closely followed by partial collapse. Our reconstruction, although it clearly errs in detail, indicates that the uplift, together with marginal and apparently ephemeral tectonic subsidence, nucleated in the west-central Transverse Ranges near Ozena, sometime between the spring of 1959 and the spring of 1960. The uplift expanded rapidly eastward (and probably westward as well), and by the fall of 1961 much of the Transverse Ranges and the Mojave Desert at least as far east as Twentynine Palms had risen by as much as 0.25 m. Between 1962 and 1972 the area included by the initially developed (1959-61) uplift sustained additional but clearly decelerating uplift accompanied locally by oscillatory displacements. Between 1972/ 73 and 1974 a second crustal spasm extended the uplift eastward to the Colorado River and elevated much of the eastern Mojave Desert by values that equaled or exceeded those developed within the western lobe. Between 1974 and 1976, at least the central part of the uplift sustained partial collapse that nowhere amounted to less than 50 percent of the cumulative uplift since 1959. Whether this collapse affected the entire uplift is conjectural, but we now recognize well-defined evidence of major down-to-the-north tilting that must have occurred within the eastern part of the uplift at some time between 1974 and 1976. Accumulating evidence indicates that nearly all the area included with the southern California uplift underwent similar uplift and partial collapse during the early part of the 20th century. Thus we infer that the recent uplift represents but a single event in an ongoing, more or less cyclic deformational process characterized by a period of about 50 years. Even though less than two full cycles are expressed in the geodetic record, the cumulative rate of uplift near the center of the recent uplift probably has averaged about 5 mm/yr, a value that is roughly consistent with the uplift rates that have been deduced for the late Quaternary emergent marine terraces along the south flank of the Transverse Ranges. Although the evolution of the recent uplift is relatively well defined, its correlation with the regional seismicity is poorly defined. A comparison between the occurrence of southern California earthquakes of magnitude ≥4 during the period 1932 to 1976 with the 1974 configuration of the uplift demonstrates the existence of (1) relatively aseismic areas within the western lobe of the uplift (in the western Transverse Ranges), in the central part of the uplift (in the western Mojave Desert), and along an east-trending zone that extends into the eastern Mojave athwart the south flank of the uplift (north of the Salton Sea) and (2) localized concentrations of seismic activity along the flanks of the uplift. Moreover, 9 of the 10 largest earthquakes recorded within or around the area of the southern California uplift during the period 1932 to 1976 (the 1933 Long Beach, the 1941 Santa Barbara, the 1946 Walker Pass, the 1947 Manix, the 1948 Desert Hot Springs, and the four major 1952 Kern County shocks) occurred before the inception of the uplift in 1959 or 1960. The area embraced by the southern California uplift has been identified with geodetically defined horizontal strain, part of which may have accumulated as a major north-south contractional event that roughly coincided with the first spasm of uplift. Nonetheless, continuing contractional strain associated with regionally developed partial collapse argues that the uplift cannot be fully explained simply as the vertical expression of continuing north-south compression. Consideration of the two well-defined historical episodes of uplift and partial collapse indicate that the southern California uplift may be the product of decoupling and viscous flow beneath the seismogenic zone, presumably driven by continuing motion between the irregularly margined plates south of the great bend of the San Andreas fault. Because the magnitude of the maximum uplift associated with each episode was approximately the same, there may be some threshold value above which collapse (viscous flow) may ensue; the absence of total collapse may be a function of precollapse strain hardening within the postulated subseismogenic viscoelastic layer.

California↗

The Evolution of the Lower Missouri River: National Mapping Discipline Research at Lisbon Bottom

Before 1800, the Missouri River was one of North America's most diverse and dynamic ecosystems. During the past 200 years, civil engineering has transformed it into a navigation system regulated by reservoirs and confined by bank stabilization and flood control structures. These modifications have reduced seasonal flow variability and sediment load and have disconnected the river from backwater, off-channel, and floodplain habitats. Flooding along the Lower Missouri River in 1993 and again in 1996 created a side-channel chute across Lisbon Bottom, a well-formed loop bottom near Glasgow, Mo. The formation and subsequent development of the chute have provided USGS scientists with a glimpse of a preregulated Missouri River. Knowledge of geologic characteristics and processes in an alluvial setting like Lisbon Bottom provides a scientific basis for floodplain management. This knowledge is also vital to a complete understanding of riverine habitat disturbance, recovery, and rehabilitation. A critical component of this knowledge is an understanding of the spatial and temporal relationships between riverine habitats and geomorphic processes.

Fact Sheet↗

Petrologic evolution of divergent peralkaline magmas from the Silent Canyon caldera complex, southwestern Nevada volcanic field

The Silent Canyon volcanic center consists of a buried Miocene peralkaline caldera complex and outlying peralkaline lava domes. Its location has been corroborated by geophysical data and more than 50 drill holes. Two widespread ash flow sheets, the Tub Spring and overlying Grouse Canyon members of the Miocene Belted Range Tuff, were erupted from the caldera complex and have volumes of 60–100 km 3 and 200 km 3 , respectively. Eruption of the ash flows was preceded by widespread extrusion of precaldera comendite domes and was followed by extrusion of postcollapse peralkaline lavas and tuffs within and outside the caldera complex. Lava flows and tuffs were also deposited between the two major ash flow sheets. Rocks of the Silent Canyon center vary significantly in silica content and peralkalinity. The most mafic rocks are precollapse and postcollapse trachytes (65–69% SiO 2 ). Low-silica comendites (69–73% SiO 2 ) were erupted as the mafic upper part of the chemically zoned Grouse Canyon Member and as postcollapse lavas. The lower part of the Grouse Canyon Member and the underlying rhyolite of Split Ridge are moderately peralkaline comendite (PI is molar ratio Na + K/Al is 1.17–1.26). These comendites have major element characteristics and trace element enrichments approaching those of pantellerites. The Tub Spring Member, by contrast, is a weakly peralkaline chemically unzoned silicic comendite (75–76% SiO 2 ) ash flow tuff. Weakly peralkaline silicic comendites (PI 1.0–1.1) are the most abundant precaldera lavas. Postcollapse lavas range from trachyte to silicic comendite; some have anomalous light rare earth element (LREE) enrichments. Silent Canyon rocks follow a common petrologic evolution from trachyte to low-silica comendite; above 73% SiO 2 , compositions of the moderately peralkaline comendites diverge from those of the weakly peralkaline silicic comendites. These contrasting differentiation paths are shown in the behavior of Fe and other transition metals, Al, Na, K; the trace elements Ba, Zr, Nb; and probably F and Cl. Weakly peralkaline silicic comendites show a LREE/heavy REE crossover in early erupted/late erupted rocks; moderately peralkaline comendites are enriched in all REE. The development of divergent peralkaline magmas, toward both pantelleritic and weakly peralkaline compositions, is unusual in a single volcanic center.

Journal of Geophysical Research Solid Earth↗

High geologic slip rates since early Pleistocene Initiation of the San Jacinto and San Felipe fault zones in the San Andreas fault system: southern California, USA

The San Jacinto right-lateral strike-slip fault zone is crucial for understanding plate-boundary dynamics, regional slip partitioning, and seismic hazards within the San Andreas fault system of southern California, yet its age of initiation and long-term average slip rate are controversial. This synthesis of prior and new detailed studies in the western Salton Trough documents initiation of structural segments of the San Jacinto fault zone at or slightly before the 1.07-Ma base of the Jaramillo subchron. The dextral faults changed again after ca. 0.5–0.6 Ma with creation of new fault segments and folds. There were major and widespread basinal changes in the early Pleistocene when these new faults cut across the older West Salton detachment fault. We mapped and analyzed the complex fault mesh, identified structural segment boundaries along the Clark, Coyote Creek, and San Felipe fault zones, documented linkages between the major dextral faults, identified previously unknown active strands of the Coyote Creek fault 5 and 8 km NE and SW of its central strands, and showed that prior analyses of these fault zones oversimplify their complexity. The Clark fault is a zone of widely distributed faulting and folding SE of the Santa Rosa Mountains and unequivocally continues 20–25 km SE of its previously inferred termination point to the San Felipe Hills. There the Clark fault zone has been deforming basinal deposits at an average dextral slip rate of ≥10.2 +6.9/−3.3 mm/yr for ~0.5–0.6 m.y. Five new estimates of displacement are developed here using offset successions of crystalline rocks, distinctive marker beds in the late Cenozoic basin fill, analysis of strike-slip–related fault-bend folds, quantification of strain in folds at the tips of dextral faults, and gravity, magnetic, and geomorphic data sets. Together these show far greater right slip across the Clark fault than across either the San Felipe or Coyote Creek faults, despite the Clark fault becoming “hidden” in basinal deposits at its SE end as strain disperses onto a myriad of smaller faults, strike-slip ramps and flats, transrotational systems of cross faults with strongly domain patterns, and a variety of fault-fold sets. Together the Clark and Buck Ridge–Santa Rosa faults accumulated ~16.8 +3.7/−6.0 km of right separation in their lifetime near Clark Lake. The Coyote Ridge segment of the Coyote Creek fault accumulated ~3.5 ± 1.3 km since roughly 0.8–0.9 Ma. The San Felipe fault accumulated between 4 and 12.4 km (~6.5 km preferred) of right slip on its central strands in the past 1.1–1.3 Ma at Yaqui and Pinyon ridges. Combining the estimates of displacement with ages of fault initiation indicates a lifetime geologic slip rate of 20.1 +6.4/−9.8 mm/yr across the San Jacinto fault zone (sum of Clark, Buck Ridge, and Coyote Creek faults) and about ~5.4 +5.9/−1.4 mm/yr across the San Felipe fault zone at Yaqui and Pinyon ridges. The NW Coyote Creek fault has a lifetime slip rate of ~4.1 +1.9/−2.1 mm/yr, which is a quarter of that across the Clark fault (16.0 +4.5/−9.8 mm/yr) nearby. The San Felipe fault zone is not generally regarded as an active fault in the region, yet its lifetime slip rate exceeds those of the central and southern Elsinore and the Coyote Creek fault zones. The apparent lower slip rates across the San Felipe fault in the Holocene may reflect the transfer of strain to adjacent faults in order to bypass a contractional bend and step at Yaqui Ridge. The San Felipe, Coyote Creek, and Clark faults all show evidence of major structural adjustments after ca. 0.6–0.5 Ma, and redistribution of strain onto new right- and left-lateral faults and folds far removed from the older central fault strands. Active faults shifted their locus and main central strands by as much as 13 km in the middle Pleistocene. These changes modify the entire upper crust and were not localized in the thin sedimentary basin fill, which is only a few kilometers thick in most of the western Salton Trough. Steep microseismic alignments are well developed beneath most of the larger active faults and penetrate basement to the base of the seismogenic crust at 10–14 km. We hypothesize that the major structural and kinematic adjustments at ca. 0.5–0.6 Ma resulted in major changes in slip rate within the San Jacinto and San Felipe fault zones that are likely to explain the inconsistent slip rates determined from geologic (1–0.5 m.y.; this study), paleoseismic, and geodetic studies over different time intervals. The natural evolution of complex fault zones, cross faults, block rotation, and interactions within their broad damage zones might explain all the documented and implied temporal and spatial variation in slip rates. Co-variation of slip rates among the San Jacinto, San Felipe, and San Andreas faults, while possible, is not required by the available data. Together the San Jacinto and San Felipe fault zones have accommodated ~25.5 mm/yr since their inception in early Pleistocene time, and were therefore slightly faster than the southern San Andreas fault during the same time interval. If the westward transfer of plate motion continues in southern California, the southern San Andreas fault in the Salton Trough may change from being the main plate boundary fault to defining the eastern margin of the growing Sierra Nevada microplate, as implied by other workers.

California↗

Rio Grande transboundary integrated hydrologic model and water-availability analysis, New Mexico and Texas, United States, and Northern Chihuahua, Mexico

Errata **September 28, 2018: The purpose of a USGS Open-file report (OFR) is dissemination of information that must be released immediately to fill a public need or information that is not sufficiently refined to warrant publication in one of the other USGS series. As part of that refinement process, an error was discovered in one of the input data sets of the Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) that this OFR was based upon. The error involved the assignment of storage properties to “phantom cells.” Phantom cells are required for most variants of MODFLOW that use a structured finite-difference grid when individual stratigraphic layers are represented as separate layers. Using phantom cells is a common practice that allows separate model layers to be maintained without having to combine stratigraphic layers into equivalent model layers or to use an unstructured grid. Typically, phantom cell horizontal hydraulic conductivities and storage properties are set to a small number and vertical hydraulic conductivities are set to a number large enough to allow vertical flow between the vertically adjacent layers. In the RGTIHM, the specific storage properties of the phantom cells for the upper (RGTIHM layers 3 and 4), middle (RGTIHM layers 5 and 6), and lower (RGTIHM layers 7 and 8) members of the Santa Fe Group were inadvertently assigned a value of 1 feet -1 . The revision of these specific storage values to a small number (1.0 x 10 -09 feet -1 ) required additional trial-and-error model calibration and a new sensitivity analysis. After calibration, the overall model fit remained similar to the fit described in the OFR, but the fit for many individual features such as project water available for diversions at the American Canal and Acequia Madre improved due to the reduction in flow coming from lower layers. Overall, there is still an average net depletion of groundwater flow, and the conclusions of the report are not changed. The revised average annual groundwater flow depletion simulated for the period 1953-2014 is -1,480 acre-feet/year for the entire model region, and -3,660 acre-feet/year for the portion of the model in the United States. The final version of the model will be the basis of the USGS Scientific Investigations Report that will supersede this OFR. An updated Model Archive of RGTIHM is available upon request to the USGS California Water Science Center. The corrected version of the model WAS the basis for the USGS Scientific Investigations Report that SUPERSEDED this Open-File Report.** Abstract Changes in population, agricultural development and practices (including shifts to more water-intensive crops), and climate variability are increasing demands on available water resources, particularly groundwater, in one of the most productive agricultural regions in the Southwest—the Rincon and Mesilla Valley parts of Rio Grande Valley, Doña Ana and Sierra Counties, New Mexico, and El Paso County, Texas. The goal of this study was to produce an integrated hydrological simulation model to help evaluate water-management strategies, including conjunctive use of surface water and groundwater for historical conditions, and to support long-term planning for the Rio Grande Project. This report describes model construction and applications by the U.S. Geological Survey, working in cooperation and collaboration with the Bureau of Reclamation. This model, the Rio Grande Transboundary Integrated Hydrologic Model, simulates the most important natural and human components of the hydrologic system, including selected components related to variations in climate, thereby providing a reliable assessment of surface-water and groundwater conditions and processes that can inform water users and help improve planning for future conditions and sustained operations of the Rio Grande Project (RGP) by the Bureau of Reclamation. Model development included a revision of the conceptual model of the flow system, construction of a Transboundary Rio Grande Watershed Model (TRGWM) water-balance model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (referred to as One Water). The hydrologic models were developed for and calibrated to historical conditions of water and land use, and parameters were adjusted so that simulated values closely matched available measurements (calibration). The calibrated model was then used to assess the use and movement of water in the Rincon Valley, Mesilla Basin, and northern part of the Conejos-Médanos Basin, with the entire region referred to as the “Transboundary Rio Grande” or TRG. These tools provide a means to understand hydrologic system response to the evolution of water use in the region, its availability, and potential operational constraints of the RGP. The conceptual model identified surface-water and groundwater inflows and outflows that included the movement and use of water both in natural and in anthropogenic systems. The groundwater-flow system is characterized by a layered geologic sedimentary sequence combined with the effects of groundwater pumping, operation of the RGP, natural runoff and recharge, and the application of irrigation water at the land surface that is captured and reused in an extensive network of canals and drains as part of the conjunctive use of water in the region. Historical groundwater-level fluctuations followed a cyclic pattern that were aligned with climate cycles, which collectively resulted in alternating periods of wet or dry years. Periods of drought that persisted for one or more years are associated with low surface-water availability that resulted in higher rates of groundwater-level decline. Rates of groundwater-level decline also increased during periods of agricultural intensification, which necessitated increasing use of groundwater as a source of irrigation water. Agriculture in the area was initially dominated by alfalfa and cotton, but since 1970 more water-intensive pecan orchards and vegetable production have become more common. Groundwater levels substantially declined in subregions where drier climate combined with increased demand, resulting in periods of reduced streamflows. Most of the groundwater was recharged in the Rio Grande Valley floor, and most of the pumpage and aquifer storage depletion was in Mesilla Basin agricultural subregions. A cyclic imbalance between inflows and outflows resulted in the modeled cyclic depletion (groundwater withdrawals in excess of natural recharge) of the groundwater basin during the 75-year simulation period of 1940–2014. Changes in groundwater storage can vary considerably from year to year, depending on land use, pumpage, and climate conditions. Climatic drivers of wet and dry years can greatly affect all inflows, outflows, and water use. Although streamflow and, to a minor extent, precipitation during inter-decadal wet-year periods replenished the groundwater historically, contemporary water use and storage depletion could have reduced the effects of these major recharge events. The average net groundwater flow-rate deficit for 1953–2014 was estimated to be about 8,990 acre-feet per year.

New Mexico, Northern Chihuahua, Texas↗

Rio Grande transboundary integrated hydrologic model and water-availability analysis, New Mexico and Texas, United States, and northern Chihuahua, Mexico

Changes in population, agricultural development and practices (including shifts to more water-intensive crops), and climate variability are increasing demands on available water resources, particularly groundwater, in one of the most productive agricultural regions in the Southwest—the Rincon and Mesilla Valley parts of Rio Grande Valley, Doña Ana and Sierra Counties, New Mexico, and El Paso County, Texas. The goal of this study was to produce an integrated hydrological simulation model to help evaluate water-management strategies, including conjunctive use of surface water and groundwater for historical conditions, and to support long-term planning for the Rio Grande Project. This report describes model construction and applications by the U.S. Geological Survey, working in cooperation and collaboration with the Bureau of Reclamation. This model, the Rio Grande Transboundary Integrated Hydrologic Model, simulates the most important natural and human components of the hydrologic system, including selected components related to variations in climate, thereby providing a reliable assessment of surface-water and groundwater conditions and processes that can inform water users and help improve planning for future conditions and sustained operations of the Rio Grande Project (RGP) by the Bureau of Reclamation. Model development included a revision of the conceptual model of the flow system, construction of a Transboundary Rio Grande Watershed Model (TRGWM) water-balance model using the Basin Characterization Model, and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model version 2 (referred to as MF-OWHM2). The hydrologic models were developed for and calibrated to historical conditions of water and land use, and parameters were adjusted so that simulated values closely matched available measurements (calibration). The calibrated model was then used to assess the use and movement of water in the Rincon Valley, Mesilla Basin, and northern part of the Conejos-Médanos Basin, with the entire region referred to as the “Transboundary Rio Grande” or TRG. These tools provide a means to understand hydrologic system response to the evolution of water use in the region, its availability, and potential operational constraints of the RGP. The conceptual model identified surface-water and groundwater inflows and outflows that included the movement and use of water both in natural and in anthropogenic systems. The groundwater-flow system is characterized by a layered geologic sedimentary sequence combined with the effects of groundwater pumping, operation of the RGP, natural runoff and recharge, and the application of irrigation water at the land surface that is captured and reused in an extensive network of canals and drains as part of the conjunctive use of water in the region. Historical groundwater-level fluctuations followed a cyclic pattern that were aligned with climate cycles, which collectively resulted in alternating periods of wet or dry years. Periods of drought that persisted for one or more years are associated with low surface-water availability that resulted in higher rates of groundwater-level decline. Rates of groundwater-level decline also increased during periods of agricultural intensification, which necessitated increasing use of groundwater as a source of irrigation water. Agriculture in the area was initially dominated by alfalfa and cotton, but since 1970 more water-intensive pecan orchards and vegetable production have become more common. Groundwater levels substantially declined in subregions where drier climate combined with increased demand, resulting in periods of reduced streamflows. Most of the groundwater was recharged in the Rio Grande Valley floor, and most of the pumpage and aquifer storage depletion was in Mesilla Basin agricultural subregions. A cyclic imbalance between inflows and outflows resulted in the modeled cyclic depletion (groundwater withdrawals in excess of natural recharge) of the groundwater basin during the 75-year simulation period of 1940–2014. Changes in groundwater storage can vary considerably from year to year, depending on land use, pumpage, and climate conditions. Climatic drivers of wet and dry years can greatly affect all inflows, outflows, and water use. Although streamflow and, to a minor extent, precipitation during inter-decadal wet-year periods replenished the groundwater historically, contemporary water use and storage depletion could have reduced the effects of these major recharge events. The average net groundwater flow-rate deficit for 1953–2014 was estimated to be about 1,090 acre-feet per year.

Chihuahua, New Mexico, Texas↗

Making ‘chemical cocktails’ – Evolution of urban geochemical processes across the periodic table of elements

Urbanization contributes to the formation of novel elemental combinations and signatures in terrestrial and aquatic watersheds, also known as ‘chemical cocktails.’ The composition of chemical cocktails evolves across space and time due to: (1) elevated concentrations from anthropogenic sources, (2) accelerated weathering and corrosion of the built environment, (3) increased drainage density and intensification of urban water conveyance systems, and (4) enhanced rates of geochemical transformations due to changes in temperature, ionic strength, pH, and redox potentials. Characterizing chemical cocktails and underlying geochemical processes is necessary for: (1) tracking pollution sources using complex chemical mixtures instead of individual elements or compounds; (2) developing new strategies for co-managing groups of contaminants; (3) identifying proxies for predicting transport of chemical mixtures using continuous sensor data; and (4) determining whether interactive effects of chemical cocktails produce ecosystem-scale impacts greater than the sum of individual chemical stressors. First, we discuss some unique urban geochemical processes which form chemical cocktails, such as urban soil formation, human-accelerated weathering, urban acidification-alkalinization, and Freshwater Salinization Syndrome. Second, we review and synthesize global patterns in concentrations of major ions, carbon and nutrients, and trace elements in urban streams across different world regions and make comparisons with reference conditions. In addition to our global analysis, we highlight examples from watersheds in the Baltimore-Washington DC area, USA, which show increased transport of major ions, trace metals, and nutrients across streams draining a well-defined land-use gradient. Urbanization increased the concentrations of multiple major and trace elements in streams draining human-dominated watersheds compared to reference conditions. Chemical cocktails of major and trace elements were formed over diurnal cycles coinciding with changes in streamflow, dissolved oxygen, pH, and other variables measured by high-frequency sensors. Some chemical cocktails of major and trace elements were also significantly related to specific conductance (p < 0.05), which can be measured by sensors. Concentrations of major and trace elements increased, peaked, or decreased longitudinally along streams as watershed urbanization increased, which is consistent with distinct shifts in chemical mixtures upstream and downstream of other major cities in the world. Our global analysis of urban streams shows that concentrations of multiple elements along the periodic table significantly increase when compared with reference conditions. Furthermore, similar biogeochemical patterns and processes can be grouped among distinct mixtures of elements of major ions, dissolved organic matter, nutrients, and trace elements as chemical cocktails. Chemical cocktails form in urban waters over diurnal cycles, decades, and throughout drainage basins. We conclude our global review and synthesis by proposing strategies for monitoring and managing chemical cocktails using source control, ecosystem restoration, and green infrastructure. We discuss future research directions applying the watershed chemical cocktail approach to diagnose and manage environmental problems. Ultimately, a chemical cocktail approach targeting sources, transport, and transformations of different and distinct elemental combinations is beneficial to more holistically monitor and manage the emerging impacts of chemical mixtures in the world's fresh waters.

Applied Geochemistry↗

Development of on-shore behavior among polar bears (Ursus maritimus) in the southern Beaufort Sea: Inherited or learned?

Polar bears ( Ursus maritimus ) are experiencing rapid and substantial changes to their environment due to global climate change. Polar bears of the southern Beaufort Sea (SB) have historically spent most of the year on the sea ice. However, recent reports from Alaska indicate that the proportion of the SB subpopulation observed on-shore during late summer and early fall has increased. Our objective was to investigate whether this on-shore behavior has developed through genetic inheritance, asocial learning, or through social learning. From 2010 to 2013, genetic data were collected from SB polar bears in the fall via hair snags and remote biopsy darting on-shore and in the spring from captures and remote biopsy darting on the sea ice. Bears were categorized as either on-shore or off-shore individuals based on their presence on-shore during the fall. Levels of genetic relatedness, first-order relatives, mother–offspring pairs, and father–offspring pairs were determined and compared within and between the two categories: on-shore versus off-shore. Results suggested transmission of on-shore behavior through either genetic inheritance or social learning as there was a higher than expected number of first-order relatives exhibiting on-shore behavior. Genetic relatedness and parentage data analyses were in concurrence with this finding, but further revealed mother–offspring social learning as the primary mechanism responsible for the development of on-shore behavior. Recognizing that on-shore behavior among polar bears was predominantly transmitted via social learning from mothers to their offspring has implications for future management and conservation as sea ice continues to decline.

Alaska↗

The unmarked R package: Twelve years of advances in occurrence and abundance modelling in ecology

Species distribution models (SDMs) are widely applied to understand the processes governing spatial and temporal variation in species abundance and distribution but often do not account for measurement errors such as false negatives and false positives. We describe unmarked , a package for the freely available and open-source R software that provides a complete workflow for modelling species distribution and abundance while explicitly accounting for measurement errors. Here we focus on recent advances in unmarked functionality to support multi-species, multi-state, and multi-season data, as well as support for fitting models with random effects. For illustration, we present an analysis of Acadian Flycatcher Empidonax virescens abundance on Roanoke River National Wildlife Refuge, North Carolina, USA, over 18 years. We found that Acadian Flycatcher abundance was initially greater in hardwood plantation habitat relative to bottomland hardwood forest along river levees but that abundance declined over time in both habitats. We plan for unmarked development to keep pace with advances in hierarchical modelling in ecology, including better handling of continuous-time data from camera trap and automated recording units and integrated models for multiple data streams.

Methods in Ecology & Evolution↗

Natural and human-induced variability in barrier-island response to sea level rise

Storm-driven sediment fluxes onto and behind barrier islands help coastal barrier systems keep pace with sea level rise (SLR). Understanding what controls cross-shore sediment flux magnitudes is critical for making accurate forecasts of barrier response to increased SLR rates. Here, using an existing morphodynamic model for barrier island evolution, observations are used to constrain model parameters and explore potential variability in future barrier behavior. Using modeled drowning outcomes as a proxy for vulnerability to SLR, 0%, 28%, and 100% of the barrier is vulnerable to SLR rates of 4, 7, and 10 mm/yr, respectively. When only overwash fluxes are increased in the model, drowning vulnerability increases for the same rates of SLR, suggesting that future increases in storminess may increase island vulnerability particularly where sediment resources are limited. Developed sites are more vulnerable to SLR, indicating that anthropogenic changes to overwash fluxes and estuary depths could profoundly affect future barrier response to SLR.

New Jersey↗

Modeling the influence of organic acids on soil weathering

Biological inputs and organic matter cycling have long been regarded as important factors in the physical and chemical development of soils. In particular, the extent to which low molecular weight organic acids, such as oxalate, influence geochemical reactions has been widely studied. Although the effects of organic acids are diverse, there is strong evidence that organic acids accelerate the dissolution of some minerals. However, the influence of organic acids at the field-scale and over the timescales of soil development has not been evaluated in detail. In this study, a reactive-transport model of soil chemical weathering and pedogenic development was used to quantify the extent to which organic acid cycling controls mineral dissolution rates and long-term patterns of chemical weathering. Specifically, oxalic acid was added to simulations of soil development to investigate a well-studied chronosequence of soils near Santa Cruz, CA. The model formulation includes organic acid input, transport, decomposition, organic-metal aqueous complexation and mineral surface complexation in various combinations. Results suggest that although organic acid reactions accelerate mineral dissolution rates near the soil surface, the net response is an overall decrease in chemical weathering. Model results demonstrate the importance of organic acid input concentrations, fluid flow, decomposition and secondary mineral precipitation rates on the evolution of mineral weathering fronts. In particular, model soil profile evolution is sensitive to kaolinite precipitation and oxalate decomposition rates. The soil profile-scale modeling presented here provides insights into the influence of organic carbon cycling on soil weathering and pedogenesis and supports the need for further field-scale measurements of the flux and speciation of reactive organic compounds.

California↗

Green‐wave surfing increases fat gain in a migratory ungulate

Each spring, migratory herbivores around the world track or ‘surf’ green waves of newly emergent vegetation to distant summer or wet‐season ranges. This foraging tactic may help explain the great abundance of migratory herbivores on many seasonal landscapes. However, the underlying fitness benefits of this life‐history strategy remain poorly understood. A fundamental prediction of the green‐wave hypothesis is that migratory herbivores obtain fitness benefits from surfing waves of newly emergent vegetation more closely than their resident counterparts. Here we evaluate whether this behavior increases body‐fat levels – a critically important correlate of reproduction and survival for most ungulates – in elk Cervus elaphus of the Greater Yellowstone Ecosystem. Using satellite imagery and GPS tracking data, we found evidence that migrants (n = 23) indeed surfed the green wave, occupying sites 12.7 days closer to peak green‐up than residents (n = 16). Importantly, individual variation in surfing may help account for up to 6 kg of variation in autumn body‐fat levels. Our findings point to a pathway for anthropogenic changes to the green wave (e.g. climate change) or migrants’ ability to surf it (e.g. development) to impact migratory populations. To explore this possibility, we evaluated potential population‐level consequences of constrained surfing with a heuristic model. If green‐wave surfing deteriorates by 5–15 days from observed, our model predicts up to a 20% decrease in pregnancy rates, a 2.5% decrease in population growth, and a 30% decrease in abundance over 50 years. By linking green‐wave surfing to fitness and illustrating potential effects on population growth, our study provides new insights into the evolution of migratory behavior and the prospects for the persistence of migratory ungulate populations in a changing world.

Wyoming↗

VS2DRTI: Simulating heat and reactive solute transport in variably saturated porous media

Variably saturated groundwater flow, heat transport, and solute transport are important processes in environmental phenomena, such as the natural evolution of water chemistry of aquifers and streams, the storage of radioactive waste in a geologic repository, the contamination of water resources from acid-rock drainage, and the geologic sequestration of carbon dioxide. Up to now, our ability to simulate these processes simultaneously with fully coupled reactive transport models has been limited to complex and often difficult-to-use models. To address the need for a simple and easy-to-use model, the VS2DRTI software package has been developed for simulating water flow, heat transport, and reactive solute transport through variably saturated porous media. The underlying numerical model, VS2DRT, was created by coupling the flow and transport capabilities of the VS2DT and VS2DH models with the equilibrium and kinetic reaction capabilities of PhreeqcRM. Flow capabilities include two-dimensional, constant-density, variably saturated flow; transport capabilities include both heat and multicomponent solute transport; and the reaction capabilities are a complete implementation of geochemical reactions of PHREEQC. The graphical user interface includes a preprocessor for building simulations and a postprocessor for visual display of simulation results. To demonstrate the simulation of multiple processes, the model is applied to a hypothetical example of injection of heated waste water to an aquifer with temperature-dependent cation exchange. VS2DRTI is freely available public domain software.

Groundwater↗

Development of a process-based littoral sediment transport model for Dauphin Island, Alabama

Dauphin Island, Alabama, located in the Northern Gulf of Mexico just outside of Mobile Bay, is Alabama’s only barrier island and provides an array of historical, natural, and economic resources. The dynamic island shoreline of Dauphin Island evolved across time scales while constantly acted upon by waves and currents during both storms and calm periods. Reductions in the vulnerability and enhancements to the resiliency of Dauphin Island—through offshore sand placement, breach closure, berm construction, and other means—have been used to protect the island and its vital resources. Planning for a resilient Dauphin Island requires predicting the long-term evolution of the barrier island system and the dominant, temporally varying processes that influence it, including littoral alongshore sediment transport under typical wave conditions, beach and dune erosion, the island overwash and breaching that occur rapidly during storm events, and the recovery of primary sand dunes through Aeolian transport over decadal time scales. Littoral sediment transport within the Dauphin Island decadal-scale framework was simulated using the Delft-3D modeling software suite. The influences of wind, waves, water levels, and sediment transport are incorporated into the model. Model skill in the prediction of waves, water levels, currents, volumetric flow rates through inlets, and shoreline position was assessed by using a set of deterministic and statistical hindcast simulations. The Delft-3D modeling application described here can be coupled with validated models of storm-response and dune recovery to predict the evolution of Dauphin Island on decadal time scales.

Alabama↗

Segmentation of plate coupling, fate of subduction fluids, and modes of arc magmatism in Cascadia, inferred from magnetotelluric resistivity

Five magnetotelluric (MT) profiles have been acquired across the Cascadia subduction system and transformed using 2-D and 3-D nonlinear inversion to yield electrical resistivity cross sections to depths of ∼200 km. Distinct changes in plate coupling, subduction fluid evolution, and modes of arc magmatism along the length of Cascadia are clearly expressed in the resistivity structure. Relatively high resistivities under the coasts of northern and southern Cascadia correlate with elevated degrees of inferred plate locking, and suggest fluid- and sediment-deficient conditions. In contrast, the north-central Oregon coastal structure is quite conductive from the plate interface to shallow depths offshore, correlating with poor plate locking and the possible presence of subducted sediments. Low-resistivity fluidized zones develop at slab depths of 35–40 km starting ∼100 km west of the arc on all profiles, and are interpreted to represent prograde metamorphic fluid release from the subducting slab. The fluids rise to forearc Moho levels, and sometimes shallower, as the arc is approached. The zones begin close to clusters of low-frequency earthquakes, suggesting fluid controls on the transition to steady sliding. Under the northern and southern Cascadia arc segments, low upper mantle resistivities are consistent with flux melting above the slab plus possible deep convective backarc upwelling toward the arc. In central Cascadia, extensional deformation is interpreted to segregate upper mantle melts leading to underplating and low resistivities at Moho to lower crustal levels below the arc and nearby backarc. The low- to high-temperature mantle wedge transition lies slightly trenchward of the arc.

Geochemistry, Geophysics, Geosystems↗

Implications of the miocene(?) crooked ridge river of northern arizona for the evolution of the colorado river and grand canyon

The southwesterly course of the probably pre–early Miocene and possibly Oligocene Crooked Ridge River can be traced continuously for 48 km and discontinuously for 91 km in northern Arizona (United States). The course is visible today in inverted relief. Pebbles in the river gravel came from at least as far northeast as the San Juan Mountains (Colorado). The river valley was carved out of easily eroded Jurassic and Cretaceous rocks whose debris overloaded the river with abundant detritus, probably steepening the gradient. After the river became inactive, the regional drainage network was rearranged three times, and the nearby Four Corners region was lowered 1–2 km by erosion. The river provides constraints on the early evolution of the Colorado River and Grand Canyon. Continuation of this river into lakes in Arizona or Utah is unlikely, as is integration through Grand Canyon by lake spillover. The downstream course of the river probably was across the Kaibab arch in a valley roughly coincident with the present eastern Grand Canyon. Beyond this point, the course may have continued to the drainage basin of the Sacramento River, or to the proto–Snake River drainage. Crooked Ridge River was beheaded by the developing San Juan River, which pirated its waters and probably was tributary to a proto–Colorado River, flowing roughly along its present course west of the Monument upwarp.

Geosphere↗

Sources of variation in breeding-ground fidelity of mallards (Anas platyrhynchos)

Generalizations used to support hypotheses about the evolution of fidelity to breeding areas in birds include the tendency for fidelity to be greater in adult birds than in yearlings. In ducks, in contrast to most bird species, fidelity is thought to be greater among females than males. Researchers have suggested that fidelity in ducks is positively correlated with pond availability. However, most estimates of fidelity on which these inferences have been based represent functions of survival and recapture-resighting probabilities in addition to fidelity. We applied the modeling approach developed by Burnham to recapture and band recovery data of mallard ducks to test the above hypotheses about fidelity. We found little evidence of sex differences in adult philopatry, with females being slightly more philopatric than males in one study area, but not in a second study area. However, yearling females were more philopatric than yearling males in both study areas. We found that adults were generally more philopatric than yearlings. We could find no relationship between fidelity and pond availability. Our results, while partially supporting current theory concerning sex and age differences in philopatry, suggest that adult male mallards are more philopatric than once thought, and we recommend that other generalizations about philopatry be revisited with proper estimation techniques.

Behavioral Ecology↗

Simulation of daily streamflow for 12 river basins in western Iowa using the Precipitation-Runoff Modeling System

The U.S. Geological Survey, in cooperation with the Iowa Department of Natural Resources, constructed Precipitation-Runoff Modeling System models to estimate daily streamflow for 12 river basins in western Iowa that drain into the Missouri River. The Precipitation-Runoff Modeling System is a deterministic, distributed-parameter, physical-process-based modeling system developed to evaluate the response of streamflow and general drainage basin hydrology to various combinations of climate and land use. Calibration periods for each basin varied depending on the period of record available for daily mean streamflow measurements at U.S. Geological Survey streamflow-gaging stations. A geographic information system tool was used to delineate each basin and estimate initial values for model parameters based on basin physical and geographical features. A U.S. Geological Survey automatic calibration tool that uses a shuffled complex evolution algorithm was used for initial calibration, and then manual modifications were made to parameter values to complete the calibration of each basin model. The main objective of the calibration was to match daily discharge values of simulated streamflow to measured daily discharge values. The Precipitation-Runoff Modeling System model was calibrated at 42 sites located in the 12 river basins in western Iowa. The accuracy of the simulated daily streamflow values at the 42 calibration sites varied by river and by site. The models were satisfactory at 36 of the sites based on statistical results. Unsatisfactory performance at the six other sites can be attributed to several factors: (1) low flow, no flow, and flashy flow conditions in headwater subbasins having a small drainage area; (2) poor representation of the groundwater and storage components of flow within a basin; (3) lack of accounting for basin withdrawals and water use; and (4) limited availability and accuracy of meteorological input data. The Precipitation-Runoff Modeling System models of 12 river basins in western Iowa will provide water-resource managers with a consistent and documented method for estimating streamflow at ungaged sites and aid in environmental studies, hydraulic design, water management, and water-quality projects.

Iowa↗