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At least 631 records · Page 35Linked to original sources

USGS2003

Water quality data at selected sites in the Mississippi Valley-type Zn-Pb ore district of upper Silesia, Poland, 1995-97

The water chemistry of aquifers and streams in the Upper Silesia Ore District, Poland are affected by their proximity to zinc, lead, and silver ores and by ongoing mining activities that date back to the 11th century. This report presents hydrologic and water-quality data collected as part of a collaborative research effort of the U.S. Geological Survey and the University of Mining and Metallurgy in Cracow, Poland to study Mississippi-Valley-Type lead-zinc deposits. MVT deposits in the Upper Silesia Ore District (Fig. 1) were selected for detailed study because the Polish mining industry allowed access to collect samples from underground mines and mine-land property. Water-quality samples were collected from streams, springs, wells, underground mine seeps and drains; and mine-tailings ponds. Data include field measurements of specific conductance, pH, water temperature, and dissolved oxygen and laboratory analyses of major and minor inorganic constituents and selected trace-element constituents.

Open-File Report↗

USGS2014

Small reservoir distribution, rate of construction, and uses in the upper and middle Chattahoochee basins of the Georgia Piedmont, USA, 1950-2010

Construction of small reservoirs affects ecosystem processes in numerous ways including fragmenting stream habitat, altering hydrology, and modifying water chemistry. While the upper and middle Chattahoochee River basins within the Southeastern United States Piedmont contain few natural lakes, they have a high density of small reservoirs (more than 7500 small reservoirs in the nearly 12,000 km2 basin). Policymakers and water managers in the region have little information about small reservoir distribution, uses, or the cumulative inundation of land cover caused by small reservoir construction. Examination of aerial photography reveals the spatiotemporal patterns and extent of small reservoir construction from 1950 to 2010. Over that 60 year timeframe, the area inundated by water increased nearly six fold (from 19 reservoirs covering 0.16% of the study area in 1950 to 329 reservoirs covering 0.95% of the study area in 2010). While agricultural practices were associated with reservoir creation from 1950 to 1970, the highest rates of reservoir construction occurred during subsequent suburban development between 1980 and 1990. Land cover adjacent to individual reservoirs transitioned over time through agricultural abandonment, land reforestation, and conversion to development during suburban expansion. The prolific rate of ongoing small reservoir creation, particularly in newly urbanizing regions and developing counties, necessitates additional attention from watershed managers and continued scientific research into cumulative environmental impacts at the watershed scale.

Georgia↗

USGS2012

Upper Clear Creek watershed aquatic chemistry and biota surveys, 2004-5, Whiskeytown National Recreation Area, Shasta County, California

The U.S. Geological Survey, in cooperation with the National Park Service and Whiskeytown National Recreation Area, performed a comprehensive aquatic biota survey of the upper Clear Creek watershed, Shasta County, California, during 2004-5. Data collected in this study can provide resource managers with information regarding aquatic resources, watershed degradation, and regional biodiversity within Whiskeytown National Recreation Area. Surveys of water chemistry, bed-sediment chemistry, algae assemblages, benthic macroinvertebrate assemblages, aquatic vertebrate assemblages, in-stream habitat characteristics, and sediment heterogeneity were conducted at 17 stream sites during both 2004 and 2005, with an additional 4 sites surveyed in 2005. A total of 67 bed-sediment samples were analyzed for major and trace inorganic element concentrations. Forty-six water samples were analyzed for trace metals and nutrients. A total of 224 taxa of invertebrates were collected during these surveys. Eleven fish species, seven of which were native, and two species of larval amphibians, were collected. A total of 24 genera of soft algae and 159 taxa of diatoms were identified. To date, this survey represents the most comprehensive inventory of aquatic resources within Whiskeytown National Recreation Area, and this information can serve as a baseline for future monitoring efforts and to inform management decisions.

California↗

USGS2009

Summary of surface-water quality data from the Illinois River Basin in Northeast Oklahoma, 1970-2007

The quality of streams in the Illinois River Basin of northeastern Oklahoma is potentially threatened by increased quantities of wastes discharged from increasing human populations, grazing of about 160,000 cattle, and confined animal feeding operations raising about 20 million chickens. Increasing numbers of humans and livestock in the basin contribute nutrients and bacteria to surface water and groundwater, causing greater than the typical concentrations of those constituents for this region. Consequences of increasing contributions of these substances can include increased algal growth (eutrophication) in streams and lakes; impairment of habitat for native aquatic animals, including desirable game fish species; impairment of drinking-water quality by sediments, turbidity, taste-and-odor causing chemicals, toxic algal compounds, and bacteria; and reduction in the aesthetic quality of the streams. The U.S. Geological Survey, in cooperation with the Oklahoma Scenic Rivers Commission, prepared this report to summarize the surface-water-quality data collected by the U.S. Geological Survey at five long-term surface-water-quality monitoring sites. The data summarized include major ions, nutrients, sediment, and fecal-indicator bacteria from the Illinois River Basin in Oklahoma for 1970 through 2007. General water chemistry, concentrations of nitrogen and phosphorus compounds, chlorophyll-a (an indicator of algal biomass), fecal-indicator bacteria counts, and sediment concentrations were similar among the five long-term monitoring sites in the Illinois River Basin in northeast Oklahoma. Most water samples were phosphorus-limited, meaning that they contained a smaller proportion of phosphorus, relative to nitrogen, than typically occurs in algal tissues. Greater degrees of nitrogen limitation occurred at three of the five sites which were sampled back to the 1970s, probably due to use of detergents containing greater concentrations of phosphorus than in subsequent periods. Concentrations of nitrogen, phosphorus, and sediment, and counts of bacteria generally increased with streamflow at the five sites, probably due to runoff from the land surface and re-suspension of streambed sediments. Phosphorus concentrations typically exceeded the Oklahoma standard of 0.037 milligrams per liter for Scenic Rivers. Concentrations of chlorophyll-a in phytoplankton in water samples collected at the five sites were not well correlated with streamflow, nor to concentrations of the nutrients nitrogen and phosphorus, probably because much of the algae growing in these streams are periphyton attached to streambed cobbles and other debris, rather than phytoplankton in the water column. Sediment concentrations correlated with phosphorus concentrations in water samples collected at the sites, probably due to sorption of phosphorus to soil particles and streambed sediments and runoff of soils and animal wastes at the land surface and resuspension of streambed sediments and phosphorus during wet, high-flow periods. Fecal coliform bacteria counts at the five sites sometimes exceeded the Oklahoma Primary Body Contact Standard of 400 colonies per 100 milliliters when streamflows were greater than 1000 cubic feet per second. Ultimately, Lake Tenkiller, an important ecological and economic resource for the region, receives the compounds that runoff the land surface or seep to local streams from groundwater in the basin. Because of eutrophication from increased nutrient loading, Lake Tenkiller is listed for impairment by diminished dissolved oxygen concentrations, phosphorus, and chlorophyll-a by the State of Oklahoma in evaluation of surface-water quality required by section 303d of the Clean Water Act. Stored phosphorus in soils and streambed and lakebed sediments may continue to provide phosphorus to local streams and lakes for decades to come. Steps are being made to reduce local sources of phosphorus, including upgrades in capacity and effective

Arkansas, Oklahoma↗

USGS2016

Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane. Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic concentrations were higher than the Health Advisory level of 2 µg/L in 27 of 89 samples (30 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 µg/L in 9 of 89 samples (10 percent). The pH ranged from 5.4 to 9.3 and did not meet the SMCL range of greater than 6.5 to less than 8.5 in 27 samples (30 percent); 22 samples had pH values less than 6.5, and 5 samples had pH values greater than 8.5. Total coliform bacteria were detected in 22 of 89 samples (25 percent); Escherichia coli were detected in only 2 of those 22 samples. Radon-222 activities ranged from 25 to 7,400 picocuries per liter (pCi/L), with a median of 2,120 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 86 of 89 samples (97 percent); radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 12 of 89 samples (13.5 percent). Water from 8 of the 89 wells (9 percent) had concentrations of methane greater than the reporting level of 0.24 milligrams per liter (mg/L) with the detectable methane concentrations ranging from 0.74 to 9.6 mg/L. Of 16 replicate samples submitted to another laboratory with a lower reporting level of 0.0002 mg/L, 15 samples had detectable methane concentrations that ranged from 0.0011 to 9.7 mg/L. Of these 15 samples, low levels of ethane (0.00032 to 0.0017 mg/L) were detected in 6 of 7 samples with methane concentrations greater than 0.75 mg/L. The isotopic composition of methane in 6 of 8 samples with sufficient dissolved methane (about 1 mg/L) for isotopic analysis is consistent with a predominantly thermogenic methane source (sample carbon isotopic ratio δ13C CH4 values ranging from -56.36 to -45.97 parts per thousand (‰) and hydrogen isotopic ratio δD CH4 values ranging from -233.1 to -141.1 ‰). However, the low levels of ethane relative to methane indicate that the methane may be of microbial origin and subsequently underwent oxidation. Isotopic compositions indicated a possibly mixed thermogenic and microbial source (carbon dioxide reduction process) for the methane in 1 of the 8 samples (δ 13 C CH4 of -63.72 and δD CH4 of -192.3 ‰) and potential oxidation of microbial and (or) thermogenic methane in the remaining sample (δ 13 C CH4 of -46.56 and δD CH4 of -79.7 ‰). Groundwater samples with relatively elevated methane concentrations (near or greater than 1 mg/L) had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with relatively low methane concentrations (less than 0.75 mg/L). The seven well-water samples with the highest methane concentrations (from about 1 to 9.6 mg/L) also had among the highest pH values (8.1 to 9.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less, by volume) similar in composition to that reported for gas and oil well brines in Pennsylvania. Most other samples with low methane concentrations (less than about 1 mg/L) had chloride/bromide ratios that indicate predominantly man-made sources of chloride, such as road salt, septic systems, and (or) animal waste. Although naturally occurring brines may originate from deeper parts of the aquifer system, the man-made sources are likely to affect shallow groundwater. Geochemical modeling showed that the water chemistry of samples with elevated pH, sodium, lithium, bromide, and alkalinity could result from dissolution of calcite (calcium carbonate) combined with cation exchange and mixing with a small amount of brine. Through cation exchange reactions (which are equivalent to processes in a water softener) calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. The spatial distribution of groundwater compositions generally shows that (1) relatively dilute, slightly acidic, oxygenated, calcium-carbonate type waters tend to occur in the uplands along the western border of Wayne County; (2) waters of near neutral pH with the highest amounts of hardness (calcium and magnesium) generally occur in areas of intermediate altitudes; and (3) waters with pH values greater than 8, low oxygen concentrations, and the highest arsenic, sodium, lithium, bromide, and methane concentrations can occur in deep wells in uplands but most frequently occur in stream valleys, especially at low elevations (less than about 1,200 ft above North American Vertical Datum of 1988) where groundwater may be discharging regionally, such as to the Delaware River. Thus, the baseline assessment of groundwater quality in Wayne County prior to gas-well development shows that shallow (less than about 1,000 ft deep) groundwater is generally of good quality, but methane and some constituents present in high concentrations in brine (and produced waters from gas and oil wells) may be present at low to moderate concentrations in some parts of Wayne County.

Pennsylvania↗

USGS2021

Groundwater and surface-water data from the C-aquifer monitoring program, Northeastern Arizona, 2012–2019

The Coconino aquifer (C aquifer) is a regionally extensive multiple-aquifer system supplying water for municipal, agricultural, and industrial use in northeastern Arizona, northwestern New Mexico, and southeastern Utah. This report focuses on the C aquifer in the arid to semi-arid area between St. Johns, Ariz., and Flagstaff, Ariz., along the Interstate-40 corridor where an increase in groundwater withdrawals coupled with ongoing drought conditions increase the potential for substantial water-level decline within the aquifer. The U.S. Geological Survey (USGS) C-aquifer Monitoring Program began in 2005 to establish baseline groundwater and surface-water conditions and to quantify physical and water-chemistry responses to pumping stresses and climate. This report presents data previously reported in Brown and Macy (2012) that extend back as far as the 1950s, along with new data collected from the USGS C-aquifer Monitoring Program since that publication, from water years 2012 to 2019. Water levels in 17 wells are measured quarterly as part of the C-aquifer Monitoring Program, and five of those are continuously monitored at 15-minute intervals. Water levels in an additional 18 wells in the study area are measured periodically by the USGS or other agencies. The largest historical change in water level in the study area was a decrease of 81.20 feet in Lake Mary 1 Well near Flagstaff between 1962 and 2018. Changes in water levels were greatest around major pumping centers and in the eastern extent of the study area. Surface-water water-quality parameters (pH, water temperature, specific conductance, and dissolved oxygen) and streamflow discharge measurements were collected and analyzed along perennial, groundwater-fed reaches of Clear Creek, Chevelon Creek, and the Little Colorado River during nine baseflow investigations of varying extent between 2005 and 2019. Both Clear Creek and Chevelon Creek gain in flow from the beginning of their perennial reaches to their outflow into the Little Colorado River. The Little Colorado River has relatively steady streamflow in the reach between where the two tributaries enter the river. Chevelon Creek showed an increase in median specific conductance during all baseflow investigations of nearly 4,000 microsiemens per centimeter (μS/cm) from near the headwaters to the confluence with the Little Colorado River; Clear Creek also showed an increase in median specific conductance of almost 5,000 μS/cm from headwaters to confluence. Water temperature, dissolved oxygen, and pH do not show substantial trends along the reaches of Clear Creek, Chevelon Creek, or the Little Colorado River.

Arizona↗

USGS2000

Hydrogeology of the regional aquifer near Flagstaff, Arizona, 1994-97

Sandstones, siltstones, and limestones that are Pennsylvanian to Permian in age underlie the southern part of the Colorado Plateau near Flagstaff, Arizona, and contain a complex regional aquifer that has become increasingly important as a source of water for domestic, municipal, and recreational uses. Ground-water flow in the regional aquifer is poorly understood in this area because (1) depth of the aquifer limits exploratory drilling and testing and (2) the geologic structure increases the complexity of the aquifer characteristics and the ground-water flow system. Four methods were used to improve the understanding of the hydrogeology of the regional aquifer near Flagstaff. • Remote-sensing techniques and geologic mapping provided data to identify many structural features that indicate a more complex structural environment and history than previously realized. • Data from surface-geophysical techniques that included ground-penetrating radar, seismic reflection and seismic refraction, and square-array resistivity, verified that some of the geologic structures expressed at land surface propagate deep into the subsurface and through the principal water-bearing zones of the regional aquifer at near-vertical angles. • A well and spring inventory, borehole-geophysical methods, and well and aquifer tests provided additional information relating aquifer and ground-water flow characteristics to geologic structure. • Water-chemistry data, which included major ion, nutrient, trace-element, and radioactive and stable-isotope analyses, provided an independent means of verifying the hydrogeologic characteristics of the aquifer and were used to determine recharge and discharge areas, groundwater movement, and ground-water age. Ground-water recharge occurs throughout the area but is greatest at higher altitudes where precipitation is greater and in areas where heavily fractured rock units of the aquifer are exposed. The estimated annual average recharge to the regional aquifer in the study area is about 290,000 acre-feet. Ground water flows laterally and vertically through pore spaces in the rock and along faults and other fractures from high-altitude areas in the southern part of the study area to regional drains north of the study area along the Little Colorado and Colorado Rivers, and to drains south of the study area along Oak Creek and the Verde Valley. Ground-water discharge in these areas—about 400,000 acre-feet per year—exceeds the annual recharge to the aquifer in the Flagstaff area, but ground water from areas outside the study area contributes to this discharge as well. The saturated thickness of the regional aquifer averages about 1,200 feet, and the amount of water in storage could be as much as 4,800,000 acrefeet, or about 10 percent of the total volume of the aquifer. The quality of water in the regional aquifer in terms of dissolved-solids concentrations is good for most uses throughout the area. Dissolvedsolids concentrations generally are less than 500 milligrams per liter. Water in the regional aquifer is primarily a calcium magnesium bicarbonate type. In some areas near the Rio de Flag, the water has significant nitrate and chloride components, which indicate direct recharge in these areas from the Rio de Flag. Oxygen and deuterium data indicate a common recharge source for water in the aquifer and that some sites receive recharge from surface waters where evaporation has occurred. Estimated carbon-14 ages and tritium activities indicate ground-water ages from less than 200 years in the Lake Mary area to more than 5,000 years in the Wupatki area. The regional aquifer is heterogeneous and anisotrophic and has a complex ground-water flow system. The most productive water-bearing material tends to be fine- to medium-grained sandstones, and ground-water flow and potential well yields are related to geologic structure. Fracturing associated with structural deformation increases recharge locally and also increases the potential for high well yields. Surface-geophysical techniques provided information on the orientation of high-angle, deep-seated structure in the saturated zone. Borehole-geophysical data identified horizontal to near-horizontal fractures as significant components of the fracture-flow system not apparent in the surface-geophysical data. Structural features that strike northwest appear to be areas that have the greatest potential for high well yields. A north-northeastward-striking structure may be just as promising, but additional data are needed to verify this relation.

Arizona↗

USGS2008

Benthic invertebrates and periphyton in the Elwha river basin: Current conditions and predicted response to dam removal

The impending removal of two dams on the Elwha River in Washington State offers a unique opportunity to study ecosystem restoration at a watershed scale. We examine how periphyton and benthic invertebrate assemblages vary across regulated and unregulated sections of the Elwha River and across different habitat types, and establish baseline data for tracking future changes following dam removal. We collected multiple years of data on physical habitat, water chemistry, periphyton, and benthic invertebrates from 52 sites on the Elwha River and a reference section on the Quinault River, a neighboring basin. We found that substrate in regulated river sections was coarser and less heterogeneous in size than in unregulated sections, and summer water temperature and specific conductivity higher. Periphyton biomass was also consistently higher in regulated than unregulated sections. Benthic invertebrate assemblage structure at sites above both dams was distinct from sites between and below the dams, due in large part to dominance of mayfly taxa compared to higher relative abundance of midges and non-insect taxa at downstream sites. Following dam removal, we anticipate that both periphyton and benthic invertebrate abundance and diversity will temporarily decrease between and below dams as a result of sediment released from behind the reservoirs. Over the long-term, increased floodplain heterogeneity and recolonization by anadromous fish will alter benthic invertebrate and periphyton assemblages via increases in niche diversity and inputs of marine-derived nutrients. The extended timeline predicted for Elwha River recovery and the complexities of forecasting ecological response highlights the need for more long-term assessments of dam removal and river restoration practices.

Northwest Science↗

USGS1983

Crassulacean acid metabolism in the seasonally submerged aquatic Isoetes howellii

Evidence to date is consistent with the hypothesis that the submerged aquatic Isoetes howellii Engelmann possesses crassulacean acid metabolism. Quantitative 14 C uptake studies indicate that CO 2 assimilation in both the light and dark are functions of pH and total inorganic carbon level. In both the light and dark, maximum uptake rates in 0.6 mM NaHCO 3 were double the rates in 0.3 mM NaHCO 3 . At both carbon levels there was a large drop in carbon assimilation rate between pH 6 and 8. In nature water pH and inorganic carbon level fluctuated diurnally thus complicating the determination of the contribution of light vs dark CO 2 uptake to the total carbon gain. On a sunny day between 0600 and 1200 h water chemistry changed markedly with ∼40% reduction in total carbon, ∼2 pH unit rise resulting from ∼100% depletion of free CO 2 . Under such conditions daytime deacidification in Isoetes leaves was 88% complete by noon. In contrast, on an overcast day, reduction of carbon in the water was much slower, deacidification was only 46% complete by noon and substantial malic acid levels remained in the leaves at the end of the day. Upon emergence crassulacean acid metabolism was largely lost in Isoetes leaves. Preliminary estimates suggest that under natural submerged conditions, early morning photosynthetic rates may be substantially higher than dark CO 2 uptake rates, though uptake rates throughout much of the day could be substantially lower than nightime CO 2 assimilation.

Oecologia↗

USGS2015

Influence of hardness on the bioavailability of silver to a freshwater snail after waterborne exposure to silver nitrate and silver nanoparticles

The release of Ag nanoparticles (AgNPs) into the aquatic environment is likely, but the influence of water chemistry on their impacts and fate remains unclear. Here, we characterize the bioavailability of Ag from AgNO 3 and from AgNPs capped with polyvinylpyrrolidone (PVP AgNP) and thiolated polyethylene glycol (PEG AgNP) in the freshwater snail, Lymnaea stagnalis , after short waterborne exposures. Results showed that water hardness, AgNP capping agents, and metal speciation affected the uptake rate of Ag from AgNPs. Comparison of the results from organisms of similar weight showed that water hardness affected the uptake of Ag from AgNPs, but not that from AgNO 3 . Transformation (dissolution and aggregation) of the AgNPs was also influenced by water hardness and the capping agent. Bioavailability of Ag from AgNPs was, in turn, correlated to these physical changes. Water hardness increased the aggregation of AgNPs, especially for PEG AgNPs, reducing the bioavailability of Ag from PEG AgNPs to a greater degree than from PVP AgNPs. Higher dissolved Ag concentrations were measured for the PVP AgNPs (15%) compared to PEG AgNPs (3%) in moderately hard water, enhancing Ag bioavailability of the former. Multiple drivers of bioavailability yielded differences in Ag influx between very hard and deionized water where the uptake rate constants ( k uw , l g -1 d -1 ± SE) varied from 3.1 ± 0.7 to 0.2 ± 0.01 for PEG AgNPs and from 2.3 ± 0.02 to 1.3 ± 0.01 for PVP AgNPs. Modeling bioavailability of Ag from NPs revealed that Ag influx into L. stagnalis comprised uptake from the NPs themselves and from newly dissolved Ag.

Nanotoxicology↗

USGS2013

Of travertine and time: otolith chemistry and microstructure detect provenance and demography of endangered humpback chub in Grand Canyon, USA

We developed a geochemical atlas of the Colorado River in Grand Canyon and in its tributary, the Little Colorado River, and used it to identify provenance and habitat use by Federally Endangered humpback chub, Gila cypha. Carbon stable isotope ratios (δ 13 C) discriminate best between the two rivers, but fine scale analysis in otoliths requires rare, expensive instrumentation. We therefore correlated other tracers (SrSr, Ba, and Se in ratio to Ca) to δ 13 C that are easier to quantify in otoliths with other microchemical techniques. Although the Little Colorado River’s water chemistry varies with major storm events, at base flow or near base flow (conditions occurring 84% of the time in our study) its chemistry differs sufficiently from the mainstem to discriminate one from the other. Additionally, when fish egress from the natal Little Colorado River to the mainstem, they encounter cold water which causes the otolith daily growth increments to decrease in size markedly. Combining otolith growth increment analysis and microchemistry permitted estimation of size and age at first egress; size at first birthday was also estimated. Emigrants < 1 year old averaged 51.2 ± 4.4 (SE) days and 35.5 ± 3.6 mm at egress; older fish that had recruited to the population averaged 100 ± 7.8 days old and 51.0 ± 2.2 mm at egress, suggesting that larger, older emigrants recruit better. Back-calculated size at age 1 was unimodal and large (78.2 ± 3.3 mm) in Little Colorado caught fish but was bimodally distributed in Colorado mainstem caught fish (49.9 ± 3.6 and 79 ± 4.9 mm) suggesting that humpback chub can also rear in the mainstem. The study demonstrates the coupled usage of the two rivers by this fish and highlights the need to consider both rivers when making management decisions for humpback chub recovery.

Arizona↗

USGS2003

Ecological indicators of water quality in the Spokane River, Idaho and Washington, 1998 and 1999

A water-quality investigation of the Spokane River was completed during summer low-flow conditions in 1998 and 1999 as part of the USGS NAWQA Program, in cooperation with the WDOE. (Abbreviations used in this report are defined on the last page.) Samples for analyses of water chemistry; bed sediment; aquatic communities (fish, macroinvertebrates, and algae); contaminants in tissue (fish and macroinvertebrates); and associated measures of habitat were collected at six sites downstream from Coeur d’Alene Lake between river miles 63 and 100. These data provided baseline information to evaluate the water-quality status of the Spokane River and can be used to determine the ecological risk to aquatic organisms from contaminants.

Washington;Idaho↗

USGS1989

Summary of hydrologic data for the San Gabriel River basin and Edwards Aquifer, Georgetown area, Texas, water year 1988

The Edwards aquifer is the principle source of freshwater for municipal, domestic, and industrial users in the Georgetown area. Other sources of freshwater are the streams draining the San Gabriel River basin and Lake Georgetown. Lake Georgetown, located on the North Fork San Gabriel River west of Georgetown, is a freshwater supply for some municipalities in the area, water in the San Gabriel River basin also supplies a variety of needs east of Georgetown. Because of the importance of the Edwards aquifer and the surface waters in the area, the U.S. Geological Survey, in cooperation with the city of Georgetown, conducted a monitoring program of the Edwards Aquifer and principal streams during water year 1988. The study area centered on Georgetown and encompassed an area of about 150 square miles (fig. 1). The freshwater resources in the Georgetown area have been the subject of three recent reports. Baker and others (1986) described the Edwards aquifer and the relation between recharge and discharge. Krietier and others (1987) provided fracture analysis, geologic mapping, ground-water chemistry, and the relation between rainfall and recharge in the study area. Land and Dorsey (1988) conducted an investigation to reassess the inclusion of the Georgetown Limestone as one of the geologic units comprising the Edwards aquifer. In addition, the Geological Survey publishes streamflow and water-quality data in the Water Resources Data for Texas report on an annual basis. The primary purpose of this report is to present a summary of the hydrologic data collected from the streams draining the San Gabriel River basin and from the Edwards aquifer during the 1988 water year (October 1987–September 1988). A secondary purpose is to add perspective to the 1988 data by including data from the previous 2 years (1986 and 1987) when available. The scope of the report is limited to the Georgetown area (fig. 1) and to data collected by the Geological Survey.

Texas↗

USGS2003

Questa baseline and pre-mining ground-water quality investigation. 3. Historical ground-water quality for the Red River Valley, New Mexico

Historical ground-water quality data for 100 wells in the Red River Valley between the U.S. Geological Survey streamflow-gaging station (08265000), near Questa, and Placer Creek east of the town of Red River, New Mexico, were compiled and reviewed. The tabulation included 608 water-quality records from 23 sources entered into an electronic database. Groundwater quality data were first collected at the Red River wastewater-treatment facility in 1982. Most analyses, however, were obtained between 1994 and 2002, even though the first wells were developed in 1962. The data were evaluated by considering (a) temporal consistency, (b) quality of sampling methods, (c) charge imbalance, and (d) replicate analyses. Analyses that qualified on the basis of these criteria were modeled to obtain saturation indices for gypsum, calcite, fluorite, gibbsite, manganite, and rhodocrosite. Plots created from the data illustrate that water chemistry in the Red River Valley is predominantly controlled by calcite dissolution, congruent gypsum dissolution, and pyrite oxidation.

New Mexico↗

USGS2005

Sampling colloids and colloid-associated contaminants in ground water

It has recently been recognized that mobile colloids may affect the transport of contaminants in ground water. To determine the significance of this process, knowledge of both the total mobile load (dissolved + colloid-associated) and the dissolved concentration of a ground-water contaminant must be obtained. Additional information regarding mobile colloid characteristics and concentrations are required to predict accurately the fate and effects of contaminants at sites where significant quantities of colloids are found. To obtain this information, a sampling scheme has been designed and refined to collect mobile colloids while avoiding the inclusion of normally immobile subsurface and well-derived solids. The effectiveness of this sampling protocol was evaluated at a number of contaminated and pristine sites. The sampling results indicated that slow, prolonged pumping of ground water is much more effective at obtaining ground-water samples that represent in situ colloid populations than bailing. Bailed samples from a coal tar-contaminated site contained 10–100 times greater colloid concentrations and up to 750 times greater polycyclic aromatic hydrocarbon concentrations as were detected in slowly pumped samples. The sampling results also indicated that ground-water colloid concentrations should be monitored in the field to determine the adequacy of purging if colloid and colloid-associated contaminants are of interest. To avoid changes in the natural ground-water colloid population through precipitation or coagulation, in situ ground-water chemistry conditions must be preserved during sampling and storage. Samples collected for determination of the total mobile load of colloids and low-solubility contaminants must not be filtered because some mobile colloids are removed by this process. Finally, suggestions that mobile colloids are present in ground water at any particular site should be corroborated with auxiliary data, such as colloid levels in “background” wells, colloid-size distributions, ground-water geochemistry, and colloid surface characteristics.

Connecticut, Delaware, Massachusetts, Nevada, New ↗

USGS1993

Properties and chemical constituents in ground water from the middle Wilcox aquifer, Gulf Coast regional aquifer systems, south-central United States

The Gulf Coast Regional Aquifer-System Analysis is a study of regional aquifers composed of sediments of mostly Cenozoic age that underlie about 230,000 sq mi of the Gulf Coastal Plain. These regional aquifers are part of three aquifer systems: (1) the Mississippi Embayment Aquifer System, (2) the Texas Coastal Uplands Aquifer System, and (3) the Coastal Lowlands Aquifer System. The water chemistry of the Middle Wilcox Aquifer, which is part of the Mississippi Embayment Aquifer System and the Texas Coastal Uplands Aquifer System is presented by a series of maps. These maps show the area1 distribution of (1) the concentration of dissolved solids and temperature, (2) the primary water types and pH, (3) the concentration of major ions and silica, and (4) the milliequivalent ratios of selected ions. Dissolved constituents, pH, temperature, and ratios are based on the median values of all samples in each 100-sq-mi area. The concentration of dissolved solids in water from the Middle Wilcox Aquifer ranges from 26 mg/L in the northern part of the Mississippi Embayment Aquifer System to 125,500 mg/L in a down-dip area in southeastern Texas. The primary water types, which are based on the most frequently observed type in each 100-sq-mi area, are calcium bicarbonate in the outcrop in Missouri, Kentucky, Mississippi, and southern Texas; sodium bicarbonate in the remaining outcrop areas and all areas from outcrop to mid-dip; and sodium chloride in all down-dip areas. The concentrations of major ions in water from the Middle Wilcox Aquifer generally increase from the outcrop area to the down-dip limit of the data. The milliequivalent ratio of magnesium plus calcium to bicarbonate ranges from less than 0.01 to 158 and generally decreases from outcrop to mid-dip and increases from mid-dip to the down-dip limit of the data. From the Sabine Uplift eastward to southwestern Alabama the ratio of bicarbonate to chloride generally decreases from outcrop to down-dip in the area west of the Mississippi River and shows localized trends east of the Mississippi River.

Alabama, Arkansas, Kentucky, Louisiana, Mississipp↗

USGS2002

Using chemical, hydrologic, and age dating analysis to delineate redox processes and flow paths in the riparian zone of a glacial outwash aquifer‐stream system

A combination of chemical and dissolved gas analyses, chlorofluorocarbon age dating, and hydrologic measurements were used to determine the degree to which biogeochemical processes in a riparian wetland were responsible for removing NO 3 − from groundwaters discharging to the Otter Tail River in west central Minnesota. An analysis of river chemistry and flow data revealed that NO 3 − concentrations in the river increased in the lower half of the 8.3 km study reach as the result of groundwater discharge to the river. Groundwater head measurements along a study transect through the riparian wetland revealed a zone of groundwater discharge extending out under the river. On the basis of combined chemical, dissolved gas, age date, and hydrologic results, it was determined that water chemistry under the riparian wetland was controlled largely by upgradient groundwaters that followed flow paths up to 16 m deep and discharged under the wetland, creating a pattern of progressively older, more chemically reduced, low NO 3 − water the farther one progressed from the edge of the wetland toward the river. These findings pose challenges for researchers investigating biogeochemical processes in riparian buffer zones because the progressively older groundwaters entered the aquifer in earlier years when less NO 3 − fertilizer was being used. NO 3 − concentrations originally present in the groundwater had also decreased in the upgradient aquifer as a result of denitrification and progressively stronger reducing conditions there. The resulting pattern of decreasing NO 3 − concentrations across the riparian zone may be incorrectly interpreted as evidence of denitrification losses there instead of in the upgradient aquifer. Consequently, it is important to understand the hydrogeologic setting and age structure of the groundwaters being sampled in order to avoid misinterpreting biogeochemical processes in riparian zones.

Water Resources Research↗

USGS2020

The role of warm, dry summers and variation in snowpack on phytoplankton dynamics in high-elevation lakes

Abstract Climate change is altering biogeochemical, metabolic, and ecological functions in lakes across the globe. Historically, mountain lakes in temperate regions have been unproductive due to brief ice-free seasons, a snowmelt-driven hydrograph, cold temperatures, and steep topography with low vegetation and soil cover. We tested the relative importance of winter and summer weather, watershed characteristics, and water chemistry as drivers of phytoplankton dynamics. Using boosted regression tree models for 28 mountain lakes in Colorado we examined regional, intra-seasonal, and inter-annual drivers of variability in chlorophyll a as a proxy for lake phytoplankton. Phytoplankton biomass was inversely related to the maximum snow water equivalent (SWE) of the previous winter, as others have found. However, even in years with average SWE, summer precipitation extremes and warming enhanced phytoplankton biomass. Peak seasonal phytoplankton biomass coincided with the warmest water temperatures and lowest nitrogen-to-phosphorus ratios. While links between snowpack, lake temperature, nutrients, and organic matter dynamics are increasingly recognized as critical drivers of change in high elevation lakes, our results highlight the additional influence of summer conditions on lake productivity in response to ongoing changes in climate. Continued changes in the timing, type, and magnitude of precipitation in combination with other global change drivers (e.g., nutrient deposition) will affect production in mountain lakes, potentially shifting these historically oligotrophic lakes toward new ecosystem states. Ultimately, a deeper understanding of these drivers and pattern at multiple scales will allow us to better anticipate ecological consequences of global change.

Colorado↗