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Tidal calibration of Plate Boundary Observatory borehole strainmeters: Roles of vertical and shear coupling

A multicomponent borehole strainmeter directly measures changes in the diameter of its cylindrical housing at several azimuths. To transform these measurements to formation strains requires a calibration matrix, which must be estimated by analyzing the installed strainmeter's response to known strains. Typically, theoretical calculations of Earth tidal strains serve as the known strains. This paper carries out such an analysis for 12 Plate Boundary Observatory (PBO) borehole strainmeters, postulating that each of the strainmeters' four gauges responds ("couples") to all three horizontal components of the formation strain tensor, as well as to vertical strain. Orientation corrections are also estimated. The fourth extensometer in each PBO strainmeter provides redundant information used to reduce the chance that coupling coefficients could be misleadingly fit to inappropriate theoretical tides. Satisfactory fits between observed and theoretically calculated tides were obtained for three PBO strainmeters in California, where the calculated tides are corroborated by other instrumentation, as well as for six strainmeters in Oregon and Washington, where no other instruments have ever recorded Earth tidal strain. Several strainmeters have unexpectedly large coupling coefficients for vertical strain, which increases the strainmeter's response to atmospheric pressure. Vertical coupling diminishes, or even changes the sign of, the apparent response to areal strain caused by Earth tides or deep Earth processes because near the free surface, vertical strains are opposite in sign to areal strain. Vertical coupling does not impair the shear strain response, however. PBO borehole strainmeters can provide calibrated shear strain time series of transient strain associated with tectonic or magmatic processes.

Journal of Geophysical Research

Sustainability in a materials world

Many adverse impacts on the environment can be directly related to the materials dispersed to the environment during processing or use, or after use as refuse and waste. Some materials, such as toxic wastes, are a major concern because they create immediate problems with longer-term effects. Gases released by major manufacturing industries can contribute to long-term regional and global problems such as acid rain or increased carbon dioxide in the atmosphere. The use of other materials, however, appears to be more benign or strictly localized in their impacts. If the current per capita level of material consumption in the United States was achieved worldwide, it would create major stresses on both resource adequacy and the environment. In fact, stresses have been created and will continue from this consumption style (developed countries) even if others don't achieve them.

Natural Resources Research

Direct estimation of diffuse gaseous emissions from coal fires: current methods and future directions

Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques. Overview of these methods for direct estimation of diffuse gas emissions from coal fires is presented in this paper. Here we take advantage of stochastic Gaussian simulation to interpolate CO 2 fluxes measured using a dynamic closed chamber at the Ruth Mullins coal fire in Perry County, Kentucky. This approach allows for preparing a map of diffuse gas emissions, one of the two primary ways that gases emanate from coal fires, and establishing the reliability of the study both locally and for the entire fire. Future research directions include continuous and automated sampling to improve quantification of gaseous coal fire emissions.

International Journal of Coal Geology

Origin and distribution of carbon dioxide in the unsaturated zone of the southern High Plains of Texas

Partial pressures of CO 2 , O 2 , N 2 , and Ar were monitored at two locations in the Ogallala aquifer system on the Southern High Plains of Texas. Samples were collected monthly during parts of 1980–1981 from nine depths ranging from 0.6 to 36 meters below land surface. P CO 2 was observed to be greater at depth than in the active soil zone and thus appears to contradict the normal process in which CO 2 is generated in the soil zone and diffuses upward to the atmosphere and downward to the water table. The δ 13 C of the CO 2 gas was quite uniform and averaged −17.9 per mil. P O 2 declined with depth, suggesting in situ generation of CO 2 by the oxidation of carbon. Several hypotheses were considered to explain the origin of the CO 2 at depth. It was concluded that the most probable hypothesis was that dissolved and particulate organic carbon introduced by recharging water was oxidized to CO 2 by the aerobic microbial community that utilized oxygen diffusing in from the atmosphere. This hypothesis is consistent with the CO 2 concentration profile, calculated production profile of CO 2 , δ 13 C values of CO 2 gas, caliche, soil humic acid fraction, and dissolved carbonate in groundwater. The abundance of CO 2 , its concentration profile, and its probable origin provide information for evaluating the observed complex sequence of caliche dissolution and precipitation known to occur in the aquifer.

Texas

The ecology of methane in streams and rivers: Patterns, controls, and global significance

Streams and rivers can substantially modify organic carbon (OC) inputs from terrestrial landscapes, and much of this processing is the result of microbial respiration. While carbon dioxide (CO 2 ) is the major end-product of ecosystem respiration, methane (CH 4 ) is also present in many fluvial environments even though methanogenesis typically requires anoxic conditions that may be scarce in these systems. Given recent recognition of the pervasiveness of this greenhouse gas in streams and rivers, we synthesized existing research and data to identify patterns and drivers of CH 4 , knowledge gaps, and research opportunities. This included examining the history of lotic CH 4 research, creating a database of concentrations and fluxes (MethDB) to generate a global-scale estimate of fluvial CH 4 efflux, and developing a conceptual framework and using this framework to consider how human activities may modify fluvial CH 4 dynamics. Current understanding of CH 4 in streams and rivers has been strongly influenced by goals of understanding OC processing and quantifying the contribution of CH 4 to ecosystem C fluxes. Less effort has been directed towards investigating processes that dictate in situ CH 4 production and loss. CH 4 makes a meager contribution to watershed or landscape C budgets, but streams and rivers are often significant CH 4 sources to the atmosphere across these same spatial extents. Most fluvial systems are supersaturated with CH 4 and we estimate an annual global emission of 26.8 Tg CH 4 , equivalent to ~15-40% of wetland and lake effluxes, respectively. Less clear is the role of CH 4 oxidation, methanogenesis, and total anaerobic respiration to whole ecosystem production and respiration. Controls on CH 4 generation and persistence can be viewed in terms of proximate controls that influence methanogenesis (organic matter, temperature, alternative electron acceptors, nutrients) and distal geomorphic and hydrologic drivers. Multiple controls combined with its extreme redox status and low solubility result in high spatial and temporal variance of CH 4 in fluvial environments, which presents a substantial challenge for understanding its larger-scale dynamics. Further understanding of CH 4 production and consumption, anaerobic metabolism, and ecosystem energetics in streams and rivers can be achieved through more directed studies and comparison with knowledge from terrestrial, wetland, and aquatic disciplines.

Ecological Monographs

Effects of biotic disturbances on forest carbon cycling in the United States and Canada

Forest insects and pathogens are major disturbance agents that have affected millions of hectares in North America in recent decades, implying significant impacts to the carbon (C) cycle. Here, we review and synthesize published studies of the effects of biotic disturbances on forest C cycling in the United States and Canada. Primary productivity in stands was reduced, sometimes considerably, immediately following insect or pathogen attack. After repeated growth reductions caused by some insects or pathogens or a single infestation by some bark beetle species, tree mortality occurred, altering productivity and decomposition. In the years following disturbance, primary productivity in some cases increased rapidly as a result of enhanced growth by surviving vegetation, and in other cases increased slowly because of lower forest regrowth. In the decades following tree mortality, decomposition increased as a result of the large amount of dead organic matter. Net ecosystem productivity decreased immediately following attack, with some studies reporting a switch to a C source to the atmosphere, and increased afterward as the forest regrew and dead organic matter decomposed. Large variability in C cycle responses arose from several factors, including type of insect or pathogen, time since disturbance, number of trees affected, and capacity of remaining vegetation to increase growth rates following outbreak. We identified significant knowledge gaps, including limited understanding of carbon cycle impacts among different biotic disturbance types (particularly pathogens), their impacts at landscape and regional scales, and limited capacity to predict disturbance events and their consequences for carbon cycling. We conclude that biotic disturbances can have major impacts on forest C stocks and fluxes and can be large enough to affect regional C cycling. However, additional research is needed to reduce the uncertainties associated with quantifying biotic disturbance effects on the North American C budget.

Global Change Biology

Controls on stable methane isotope signatures in northern peatlands and potential shifts in signatures under permafrost thaw scenarios

Northern peatlands are a globally significant source of methane (CH 4 ), and emissions are projected to increase due to warming and permafrost loss. Understanding the microbial mechanisms behind patterns in CH 4 production in these systems will be key to predicting annual emissions changes, with stable carbon isotopes (δ 13 C-CH 4 ) being a powerful tool for characterizing these drivers. Given that δ 13 C signatures of CH 4 are used in top-down atmospheric inversion models to partition sources, our ability to model CH 4 production pathways and associated δ 13 C-CH 4 signatures in peatland types impacted by a changing climate is critical. We sought to characterize the role of environmental conditions, including both hydrologic and vegetation patterns associated with permafrost thaw, on δ 13 C-CH 4 signatures from a diverse set of high-latitude peatlands. We measured porewater and emitted CH 4 stable isotopes, pH, and vegetation composition from five boreal-Arctic peatlands. Porewater δ 13 C-CH 4 was strongly associated with peatland type, with δ 13 C enriched values obtained from more minerotrophic fens (-61.2 ± 9.1‰) compared to permafrost-free bogs (-74.1 ± 9.4‰) and raised permafrost bogs (-81.6 ± 11.5‰). Variation in porewater δ 13 C-CH 4 was best explained by sedge cover, CH 4 concentration, and the interactive effect of peatland type and pH ( r 2 = 0.50, p < 0.001). Emitted δ 13 C-CH 4 varied greatly but was positively correlated with porewater δ 13 C-CH 4 , suggesting that porewater data can be used to predict changing emissions signatures from these systems. We calculated a weighted mean mixed atmospheric CH 4 signature for northern peatlands of -65.3 ± 7‰ and show that this signature is more sensitive to landscape drying (4 to 10 % depletion in δ 13 C) than wetting (1.5 to 5% enrichment in δ 13 C) under permafrost thaw scenarios. Our results suggest northern peatland δ 13 C-CH 4 signatures are likely to shift in the future which has important implications for source partitioning in atmospheric inversion models.

Journal of Geophysical Research: Biogeosciences

Spatial variability of CO2 concentrations and biogeochemistry in the Lower Columbia River

Carbon dioxide (CO 2 ) emissions from rivers and other inland waters are thought to be a major component of regional and global carbon cycling. In large managed rivers such as the Columbia River, contemporary ecosystem changes such as damming, nutrient enrichment, and increased water residence times may lead to reduced CO 2 concentrations (and emissions) due to increased primary production, as has been shown in another large North American river (Upper Mississippi). In this work, spatial patterns of water quality, including dissolved CO 2 concentrations, were assessed in the Lower Columbia River (LCR) and major tributaries using underway measurements from a small research vessel during July 2016. We observed near-equilibrium CO 2 conditions and overall weak supersaturation of CO 2 in the main channel (average 133.8% saturation) and tributaries. We observed only weak correlations between CO 2 saturation, chlorophyll a fluorescence, and turbidity, thus not strongly supporting our hypothesis of primary productivity controls. In general, the LCR was clear (low turbidity, mean = 1.48 FNU) and had low chlorophyll fluorescence (mean = 0.177 RFU) during the sampling period. As a whole, the LCR was homogeneous with respect to biogeochemical conditions and showed low spatial variability at >100 km scales. Overall, we find that the LCR is likely a weak summertime source of CO 2 to the atmosphere, in line with findings from other altered rivers such as the Upper Mississippi.

Columbia River

Nutrient concentrations and yields in undeveloped stream basins of the United States

Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow-weighted concentrations during 1990-1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow-weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid-Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow-weighted concentrations during 1990-1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow-weighted concentration of nitrate exceeded 0.6 mg/L in only three basins, Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid-Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.Data collected across the US from 85 streams draining relatively undeveloped basins were used to identify broad regional and national patterns in nutrient concentrations and yields. The basins of interest were selected from three USGS programs: the Hydrologic Benchmark Network, the National Water-Quality Assessment, and the Research Program. Water samples from most basins were collected on a weekly to bimonthly schedule. While the flow-weighted concentrations of nutrients varied, concentrations were low in most basins. Median flow-weighted concentrations of ammonia, nitrate, total nitrogen, orthophosphate, and total phosphorus were 0.020, 0.087, 0.26, 0.010, and 0.022 mg/l, respectively. Nitrate concentrations tended to be highest in the northeastern US, while southeastern and north-central basins had some of the highest NH3 concentrations. Flow-weighted concentrations of total P were generally highest in the Rocky Mountain and Central Plain states and in parts of the southeast.

Journal of the American Water Resources Associatio

Coherence between coastal and river flooding along the California coast

Water levels around river mouths are intrinsically determined by sea level and river discharge. If storm-associated coastal water-level anomalies coincide with extreme river discharge, landscapes near river mouths will be flooded by the hydrodynamic interactions of these two water masses. Unfortunately, the temporal relationships between ocean and river water masses are not well understood. The coherence between extreme river discharge and coastal water levels at six California river mouths across different climatic and geographic regions was examined. Data from river gauges, wave buoys, and tide gauges from 2007 to 2014 were integrated to investigate the relationships between extreme river discharge and coastal water levels near the mouths of the Eel, Russian, San Lorenzo, Ventura, Arroyo Trabuco, and San Diego rivers. Results indicate that mean and extreme coastal water levels during extreme river discharge are significantly higher compared with background conditions. Elevated coastal water levels result from the combination of nontidal residuals (NTRs) and wave setups. Mean and extreme (>99th percentile of observations) NTRs are 3–20 cm and ∼30 cm higher during extreme river discharge conditions, respectively. Mean and extreme wave setups are up to 40 cm and ∼20–90 cm higher during extreme river discharge than typical conditions, respectively. These water-level anomalies were generally greatest for the northern rivers and least for the southern rivers. Time-series comparisons suggest that increases in NTRs are largely coherent with extreme river discharge, owing to the low atmospheric pressure systems associated with storms. The potential flooding risks of the concurrent timing of these water masses are tempered by the mixed, semidiurnal tides of the region that have amplitudes of 2–2.5 m. In summary, flooding hazard assessments for floodplains near California river mouths for current or future conditions with sea-level rise should include the temporal coherence of fluvial and oceanic water levels.

California

Delta-Flux: An eddy covariance network for a climate-smart Lower Mississippi Basin

Networks of remotely monitored research sites are increasingly the tool used to study regional agricultural impacts on carbon and water fluxes. However, key national networks such as the National Ecological Observatory Network and AmeriFlux lack contributions from the Lower Mississippi River Basin (LMRB), a highly productive agricultural area with opportunities for soil carbon sequestration through conservation practices. The authors describe the rationale to create the new Delta-Flux network, which will coordinate efforts to quantify carbon and water budgets at seventeen eddy covariance flux tower sites in the LMRB. The network structure will facilitate climate-smart management strategies based on production-scale and continuous measurements of carbon and water fluxes from the landscape to the atmosphere under different soil and water management conditions. The seventeen instrumented field sites are expected to monitor fluxes within the most characteristic landscapes of the target area: row-crop fields, pasture, grasslands, forests, and marshes. The network participants are committed to open collaboration and efficient regionalization of site-level findings to support sustainable agricultural and forestry management and conservation of natural resources.

Arkansas, Louisiana, Mississippi

Seasonality of stable isotope composition of atmospheric water input at the southern slopes of Mt. Kilimanjaro, Tanzania

To understand the moisture regime at the southern slopes of Mt. Kilimanjaro, we analysed the isotopic variability of oxygen (δ 18 O) and hydrogen (δD) of rainfall, throughfall, and fog from a total of 2,140 samples collected weekly over 2 years at 9 study sites along an elevation transect ranging from 950 to 3,880 m above sea level. Precipitation in the Kilimanjaro tropical rainforests consists of a combination of rainfall, throughfall, and fog. We defined local meteoric water lines for all 3 precipitation types individually and the overall precipitation, δD prec = 7.45 (±0.05) × δ 18 O prec + 13.61 (±0.20), n = 2,140, R 2 = .91, p < .001. We investigated the precipitation-type-specific stable isotope composition and analysed the effects of amount, altitude, and temperature. Aggregated annual mean values revealed isotope composition of rainfall as most depleted and fog water as most enriched in heavy isotopes at the highest elevation research site. We found an altitude effect of δ 18 O rain = −0.11‰ × 100 m −1 , which varied according to precipitation type and season. The relatively weak isotope or altitude gradient may reveal 2 different moisture sources in the research area: (a) local moisture recycling and (b) regional moisture sources. Generally, the seasonality of δ 18 O rain values follows the bimodal rainfall distribution under the influences of south- and north-easterly trade winds. These seasonal patterns of isotopic composition were linked to different regional moisture sources by analysing Hybrid Single Particle Lagrangian Integrated Trajectory backward trajectories. Seasonality of d excess values revealed evidence of enhanced moisture recycling after the onset of the rainy seasons. This comprehensive dataset is essential for further research using stable isotopes as a hydrological tracer of sources of precipitation that contribute to water resources of the Kilimanjaro region.

Mt. Kilimanjaro

Decadal oscillation of lakes and aquifers in the upper Great Lakes region of North America: hydroclimatic implications

We report a unique hydrologic time-series which indicates that water levels in lakes and aquifers across the upper Great Lakes region of North America have been dominated by a climatically-driven, near-decadal oscillation for at least 70 years. The historical oscillation (~13y) is remarkably consistent among small seepage lakes, groundwater tables and the two largest Laurentian Great Lakes despite substantial differences in hydrology. Hydrologic analyses indicate that the oscillation has been governed primarily by changes in the net atmospheric flux of water (P-E) and stage-dependent outflow. The oscillation is hypothetically connected to large-scale atmospheric circulation patterns originating in the mid-latitude North Pacific that support the flux of moisture into the region from the Gulf of Mexico. Recent data indicate an apparent change in the historical oscillation characterized by a ~12y downward trend beginning in 1998. Record low water levels region-wide may mark the onset of a new hydroclimatic regime.

Upper Great Lakes Region

Spatiotemporal analysis of black spruce forest soils and implications for the fate of C

Post-fire storage of carbon (C) in organic-soil horizons was measured in one Canadian and three Alaskan chronosequences in black spruce forests, together spanning stand ages of nearly 200 yrs. We used a simple mass balance model to derive estimates of inputs, losses, and accumulation rates of C on timescales of years to centuries. The model performed well for the surface and total organic soil layers and presented questions for resolving the dynamics of deeper organic soils. C accumulation in all study areas is on the order of 20–40 gC/m 2 / yr for stand ages up to ∼200 yrs. Much larger fluxes, both positive and negative, are detected using incremental changes in soil C stocks and by other studies using eddy covariance methods for CO 2 . This difference suggests that over the course of stand replacement, about 80% of all net primary production (NPP) is returned to the atmosphere within a fire cycle, while about 20% of NPP enters the organic soil layers and becomes available for stabilization or loss via decomposition, leaching, or combustion. Shifts toward more frequent and more severe burning and degradation of deep organic horizons would likely result in an acceleration of the carbon cycle, with greater CO 2 emissions from these systems overall.

Journal of Geophysical Research

Variability in winter mass balance of Northern Hemisphere glaciers and relations with atmospheric circulation

An analysis of variability in the winter mass balance (WMB) of 22 glaciers in the Northern Hemisphere indicates two primary modes of variability that explain 46% of the variability among all glaciers. The first mode of variability characterizes WMB variability in Northern and Central Europe and the second mode primarily represents WMB variability in northwestern North America, but also is related to variability in WMB of one glacier in Europe and one in Central Asia. These two modes of WMB variability are explained by variations in mesoscale atmospheric circulation which are driving forces of variations in surface temperature and precipitation. The first mode is highly correlated with the Arctic Oscillation Index, whereas the second mode is highly correlated with the Southern Oscillation Index. In addition, the second mode of WMB variability is highly correlated with variability in global winter temperatures. This result suggests some connection between global temperature trends and WMB for some glaciers.

Arctic, Antarctic, and Alpine Research

Tritium and radioactive carbon (14C) analyses of gas collected from unsaturated sediments next to a low-level radioactive-waste burial site south of Beatty, Nevada, April 1994 and July 1995

Tritium activities in water vapor and radioactive carbon ( 14 C) activities in carbon dioxide were determined in gas samples pumped from small-diameter air ports installed in a test hole within the unsaturated sediments next to a commercial burial site for low-level radioactive waste south of Beatty, Nevada. In April 1994, gas samples were collected from test hole UZB-2, which was drilled about 350 feet south of the southwest corner of the fence enclosing the burial site. The test hole is part of a study to determine the depth to which atmospheric air circulates through the unsaturated sediments at the desert site. Laboratory results completed in May 1995 show activities of tritium and 14 C were greater than expected, with measured tritium in the water vapor as high as 762 tritium units at a depth of 79 feet and measured 14 C in carbon dioxide as high as 1,700 percent modern carbon at a depth of 18 feet. In July 1995, the uppermost five air ports in test hole UZB-2 were resampled. In addition, water vapor was collected for tritium analyses at a distant test hole, and water vapor for tritium analyses and carbon dioxide for 14 C analyses were collected from three depths at the research shaft about 200 feet north of test hole UZB-2, and at two shallow probes (depth of 5.5 feet) next to the fence enclosing the burial site. Analyses of samples collected in the upper 112 feet from test hole UZB-2 in July 1995 show the same distribution of tritium and 14 C as analyses of samples collected in April 1994, except that activities were somewhat greater in July. The greatest activities of tritium and 14 C were measured from a shallow probe next to the fence with activities of 29,400 tritium units and 517,000 percent modern carbon, respectively.

Nevada

Precipitation regime change in Western North America: The role of atmospheric rivers

Daily precipitation in California has been projected to become less frequent even as precipitation extremes intensify, leading to uncertainty in the overall response to climate warming. Precipitation extremes are historically associated with Atmospheric Rivers (ARs). Sixteen global climate models are evaluated for realism in modeled historical AR behavior and contribution of the resulting daily precipitation to annual total precipitation over Western North America. The five most realistic models display consistent changes in future AR behavior, constraining the spread of the full ensemble. They, moreover, project increasing year-to-year variability of total annual precipitation, particularly over California, where change in total annual precipitation is not projected with confidence. Focusing on three representative river basins along the West Coast, we show that, while the decrease in precipitation frequency is mostly due to non-AR events, the increase in heavy and extreme precipitation is almost entirely due to ARs. This research demonstrates that examining meteorological causes of precipitation regime change can lead to better and more nuanced understanding of climate projections. It highlights the critical role of future changes in ARs to Western water resources, especially over California.

California

Estimated global nitrogen deposition using NO 2 column density

Global nitrogen deposition has increased over the past 100 years. Monitoring and simulation studies of nitrogen deposition have evaluated nitrogen deposition at both the global and regional scale. With the development of remote-sensing instruments, tropospheric NO 2 column density retrieved from Global Ozone Monitoring Experiment (GOME) and Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) sensors now provides us with a new opportunity to understand changes in reactive nitrogen in the atmosphere. The concentration of NO 2 in the atmosphere has a significant effect on atmospheric nitrogen deposition. According to the general nitrogen deposition calculation method, we use the principal component regression method to evaluate global nitrogen deposition based on global NO2 column density and meteorological data. From the accuracy of the simulation, about 70% of the land area of the Earth passed a significance test of regression. In addition, NO2 column density has a significant influence on regression results over 44% of global land. The simulated results show that global average nitrogen deposition was 0.34 g m −2 yr −1 from 1996 to 2009 and is increasing at about 1% per year. Our simulated results show that China, Europe, and the USA are the three hotspots of nitrogen deposition according to previous research findings. In this study, Southern Asia was found to be another hotspot of nitrogen deposition (about 1.58 g m −2 yr −1 and maintaining a high growth rate). As nitrogen deposition increases, the number of regions threatened by high nitrogen deposits is also increasing. With N emissions continuing to increase in the future, areas whose ecosystem is affected by high level nitrogen deposition will increase.

International Journal of Remote Sensing