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At least 613 records · Page 34Linked to original sources

Ground water and geology of Baraga County, Michigan

Most wells In Baraga County obtain water from beds of sand and gravel in morainal and lakebed deposits or from the Jacobsville Sandstone. Yields of wells range from a few to as much as 115 gallons per minute, but most wells probably yield less than 10 gpm. Large areas, where igneous and metamorphic rocks crop out or are covered only by thin drift, are unfavorable for obtaining enough ground water for even a domestic supply. Quality of water from most wells is satisfactory, although most water supplies are hard and some are high in iron content. Some of the deeper wells in the Jacobsville Sandstone may yield salty water. Most large public water supplies are obtained from Lake Superior, but some smaller supplies are obtained from wells and springs.

Michigan↗

Water resources of Branch County, Michigan

Branch County has abundant water resources throughout most of its area. Almost all the water used is supplied by wells that obtain water from glacial drift deposits and locally from fractures and sandy beds in the Coldwater Shale. Glacial drift in buried bedrock valleys may yield large quantities of water to wells. Well yields are generally adequate for domestic and farm supplies. Properly developed large-diameter wells tapping thick beds of sand and gravel of the glacial drift can yield up to several thousands of gallons per minute locally. The hundreds of lakes and the many perennial streams have great recreational value. They are also a large potential source of water for some supplies. For example, it is estimated that 88 billion gallons of water runs off in streams of the county in an average year, and the lakes o the county hold about 42billion gallons of water in storage. Problems of water supply to wells exist locally in some moraine and till areas of where the glacial drift is thin and the underlying bedrock yields only small quantities of water or none at all. Ground water is generally hard to very hard and often contains excessive iron. Salty water is mainly a problem in areas where bedrock is the chief source. Floods are not a serious problem largely because of the storage capacity of the lakes and the permeable materials in some stream basins. Based on measurements at eight stream sites the estimated amount of flow for 90 percent of the time ranges from 80,000 to 150,000 gallons per day per square mile of drainage area. A special study of low levels in land-locked Gilead Lake indicated that this lake is semiperched and mostly dependent upon the water table for tits levels.

Michigan↗

Understanding impacts of sea-level rise and land management on critical coastal marsh habitat

Coastal wetlands in the Louisiana Mississippi River Deltaic Plain (MRDP) experience some of the highest rates of relative sea-level rise (SLR) in the world, leading to elevated surface water salinity and prolonged flooding. Elevated salinity causes a shift toward more salt-tolerant vegetation communities, associated with changes in ecosystem function and services. As sea level continues to rise, even salt-tolerant plant communities succumb to impacts of excessive flooding through submergence and conversion to open water. To better characterize the impacts of SLR on coastal wetland health and sustainability, we focused on two key landscape transitions in this project: 1) freshwater marsh transition to saltwater marsh, and 2) saltwater marsh transition to open water. We investigated these transitions using data with greater spatial and temporal resolution than previous studies in this region, allowing us to identify the mechanisms underlying widely observed landscape changes.

Louisiana↗

Simultaneous flow of water and solutes through geological membranes-I. Experimental investigation

The relative retardation by geological membranes of cations and anions generally present in subsurface waters was investigated using a high pressure and high temperature ‘filtration cell’. The solutions were forced through different clays and a disaggregated shale subjected to compaction pressures up to 9500 psi and to temperatures from 20 to 70°C. The overall efficiences measured increased with increase of exchange capacity of the material used and with decrease in concentration of the input solution. The efficiency of a given membrane increased with increasing compaction pressure but decreased slightly at higher temperatures for solutions of the same ionic concentration. The results further show that geological membranes are specific for different dissolved species. The retardation sequences varied depending on the material used and on experimental conditions. The sequences for monovalent and divalent cations at laboratory temperatures were generally as follows: Li < Na < NH 3 < K < Rb < Cs Mg < Ca < Sr < Ba. The sequences for anions at room temperature were variable, but at 70°C, the sequence was: HCO 3 < I < B < SO 4 < Cl < Br. Monovalent cations contrary to some field data were generally retarded with respect to divalent cations. The differences in the filtration ratios among the divalent cations were smaller than those between the monovalent cations. The passage rate of B, HCO 3 , I and NH 3 was greatly increased at 70°C.

Geochimica et Cosmochimica Acta↗

The physical behavior and geologic control of radon in mountain streams

Radon distribution ratio determinations in an all-water system were made. They checked very closely with those done by Kofler in 1913. The distribution of radon in stream waters and related springs was investigated in the Wasatch Mountains adjacent to Salt Lake City, Utah, and in a part of the Weber River near Ogden, Utah. The radon distribution in the stream waters studied forms a definite pattern which is dependent upon the local influx Of relatively large amounts of radon-bearing ground water into the stream, and, in turn, the ability of the stream to lose its radon to the atmosphere through turbulence. The ability of the stream to lose its radon is governed largely by the gradient and rate of flow of the stream and the nature of the stream channel, and tends to reach an equilibrium value of less than one micro-micro Curie per liter. This loss of radon generally occurs as an exponential function with respect to distance of stream flow. The slope of the function varies with different streams. The stream waters investigated contain from one limit of the sensitivity of theinstrument to about 450 micro-micro Curies of radon per liter. The radon content of spring waters is generally higher than that of stream waters. The large radon contents mark the areas of ground water influx into the stream, although, in most cases, no spring activity in these areas was observed. The high-radon anomalies can usually be related to definite stratigraphic horizons or structural features. The amount of ground water being added to the stream can be estimated in some cases by radon measurements of stream waters and related springs. Almost complete disequilibrium occurs between radon and its parent radium in stream and spring waters in this area.

Open-File Report↗

Activities of the Water Resources Division in Arizona, 1986-91

Water-resources activities of the U.S. Geological Survey in Arizona consist of collecting water- resources data and conducting interpretive hydrologic investigations and research. The water- resources data and the results of the interpretive investigations and research are published or released by the U.S. Geological Survey or by cooperating agencies. The report describes the data-collection activities and water-resources investigations in Arizona for fiscal years 1986-91 (October 1, 1985, to September 30, 1991). The report includes a brief description of the origin of the U.S. Geological Survey, the basic mission of the Water Resources Division, organization of the Arizona District, sources of funding, and a summary of water conditions in Arizona. Information is given for each project and includes the objective, approach, progress and results, and plans for the following year. The report also includes a list of publications prepared by the Arizona District, Water Resources Division, U.S. Geological Survey, that were published from 1984 to 1991.

Open-File Report↗

Investigating the effects of point source and nonpoint source pollution on the water quality of the East River (Dongjiang) in South China

Understanding the physical processes of point source (PS) and nonpoint source (NPS) pollution is critical to evaluate river water quality and identify major pollutant sources in a watershed. In this study, we used the physically-based hydrological/water quality model, Soil and Water Assessment Tool, to investigate the influence of PS and NPS pollution on the water quality of the East River (Dongjiang in Chinese) in southern China. Our results indicate that NPS pollution was the dominant contribution (>94%) to nutrient loads except for mineral phosphorus (50%). A comprehensive Water Quality Index (WQI) computed using eight key water quality variables demonstrates that water quality is better upstream than downstream despite the higher level of ammonium nitrogen found in upstream waters. Also, the temporal (seasonal) and spatial distributions of nutrient loads clearly indicate the critical time period (from late dry season to early wet season) and pollution source areas within the basin (middle and downstream agricultural lands), which resource managers can use to accomplish substantial reduction of NPS pollutant loadings. Overall, this study helps our understanding of the relationship between human activities and pollutant loads and further contributes to decision support for local watershed managers to protect water quality in this region. In particular, the methods presented such as integrating WQI with watershed modeling and identifying the critical time period and pollutions source areas can be valuable for other researchers worldwide.

Dongjiang↗

Arsenate adsorption mechanisms at the allophane: Water interface

We investigated arsenate (As(V)) reactivity and surface speciation on amorphous aluminosilicate mineral (synthetic allophane) surfaces using batch adsorption experiments, powder X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS). The adsorption isotherm experiments indicated that As(V) uptake increased with increasing [As(V)] o from 50 to 1000 μM (i.e., Langmuir type adsorption isotherm) and that the total As adsorption slightly decreased with increasing NaCl concentrations from 0.01 to 0.1 M. Arsenate adsorption was initially (0−10 h) rapid followed by a slow continuum uptake, and the adsorption processes reached the steady state after 720 h. X-ray absorption spectroscopic analyses suggest that As(V) predominantly forms bidentate binuclear surface species on aluminum octahedral structures, and these species are stable up to 11 months. Solubility calculations and powder XRD analyses indicate no evidence of crystalline Al−As(V) precipitates in the experimental systems. Overall, macroscopic and spectroscopic evidence suggest that the As(V) adsorption mechanisms at the allophane−water interface are attributable to ligand exchange reactions between As(V) and surface-coordinated water molecules and hydroxyl and silicate ions. The research findings imply that dissolved tetrahedral oxyanions (e.g., H 2 PO 4 2 - and H 2 AsO 4 2 - ) are readily retained on amorphous aluminosilicate minerals in aquifer and soils at near neutral pH. The inner-sphere adsorption mechanisms might be important in controlling dissolved arsenate and phosphate in amorphous aluminosilicate-rich low-temperature geochemical environments.

Environmental Science & Technology↗

Ground-water areas and well logs, Central Sevier Valley, Utah

Between September 1959 and June 1960 the United States Geological Survey and the Utah State Engineer, with financial assistance from Garfield, Millard, Piute, Sanpete, and Sevier Counties and from local water-users' associations, cooperated in an investigation to determine the structural framework of the central Sevier Valley and to evaluate the valley's ground-water potential. An important aspect of the study was the drilling of 22 test holes under private contract. These data and other data collected during the course of the larger ground-water investigation of which the test drilling was a part will be evaluated in a report on the geology and ground-water resources of the central Sevier Valley. The present report has been prepared to make available the logs of the test holes and to describe in general terms the availability of ground water in the different areas of the valley. The test holes were located to determine the subsurface geology of the valley, but of principal interest for this report is the water-bearing materials that were penetrated by the test holes. Ten of the holes penetrated materials capable of yielding sufficient water for irrigation; 10 holes penetrated water-yielding materials that could supply water for domestic or stock use; 2 holes were unsuccessful as water prospects but supplied geologic information. Generally, the water in the test holes was of good quality for stock, domestic, or irrigation use, except in test holes 1, 2, 4, 5, 16, 17, and 19 where water from some beds was highly mineralized. Water from the upper water-bearing bed in test holes 1, 2, 4, 5 and 16 and from the 6 upper water-bearing beds in test hole 19 was high in sodium chloride and sodium sulphate and would be unpalatable to humans and stock. The upper water in test hole 17 would be palatable to stock accustomed to brackish water, but the water from below 78 feet is too saline for any use. The central Sevier Valley has been divided into arbitrary ground-water areas that are based in part on topographic and geologic boundaries. The test holes are described by areas downstream from south to north, and the logs of table 1 are arranged from south to north.

Utah↗

Ground-water areas and well logs, central Sevier Valley, Utah

Between September 1959 and June 1960 the United States Geological Survey and the Utah State Engineer, with financial assistance from Garfield, Millard, Piute, Sanpete, and Sevier Counties and from local water-users’ associations, cooperated in an investigation to determine the structural framework of the central Sevier Valley and to evaluate the valley’s ground-water potential. An important aspect of the study was the drilling of 22 test holes under private contract. These data and other data collected during the course of the larger ground-water investigation of which the test drilling was a part will be evaluated in a report on the geology and ground-water resources of the central Sevier Valley. The present report has been prepared to make available the logs of test holes and to describe in general terms the availability of ground water in the different areas of the valley.

Utah↗

Bibliography of publications relating to ground water in Connecticut

The United States Geological Survey is currently investigating the ground-water resources of Connecticut in cooperation with the State Water Commission. As part of this cooperative project, in order to summarize the knowledge already gained about ground water in the State, a bibliography of reports dealing with ground water in Connecticut has been prepared. A compilation entitled "Bibliography and index of publications relating to ground water prepared by the Geological Survey and cooperating agencies", by G. A. Waring and O. E. Neinzer, was issued as U.S. Geological Survey Water-Supply Paper 992 in 1947. The following compilation lists all the papers in Water-Supply Paper 992 that refer to Connecticut plus other short reports not included in the letter. The first studies of ground water in Connecticut were begun in 1903 by Professor H. E. Gregory of Yale University under the auspices of the U.S. Geological Survey. The early studies were of the reconnaissance type, covering large sections of the State, and were concerned mainly with the relation of the bedrock geology to the water supply. The results were published in several Water-Supply Papers of the Geological Survey. In 1911 a cooperative agreement for the study of the ground-water resources of Connecticut in which each party shared equally in the expenses was made between the Federal Survey and the Connecticut State Geological and Natural History Survey. As a result more detailed studies in smaller areas were undertaken. Active field work covering more than half the State was continued through 1923 under this arrangement and the results published in eight U.S. Geological Survey Water-Supply Papers. After an eleven year period of inactivity and with the inauguration of the Federal Emergency Relief Commission, detailed studies of ground water in Connecticut were begun again in October 1934 as a project of the Emergency Relief Commission (later the Works Progress Administration). The project was sponsored by the Connecticut State Water Commission, the State Planning Board, and the U.S. Geological Survey. The technical direction of the work was undertaken by the Geological Survey. The project consisted of an inventory and mapping of wells and springs in the State by towns and the recording of weekly observations of water levels in selected wells. The data collected through October 1939 were published in six mimeographed bulletins and one typewritten bulletin by the Works Program Administration. In 1939, when it became necessary to curtail the work being carried on by the Works Progress Administration, cooperation was arranged between the Federal Ecological Survey and the State Water Commission to continue investigations relative to the over-development of ground-water supplies in the New Haven area. From time to time additional funds have been made available to meet growing demands by the State for data on its ground-water supplied and the present cooperative program between the U.S. Geological Survey and the State Water Commission is a continuation of the original arrangement. It is estimated that about 14 per cont of the State has been covered by recent ground-water surveys and in addition some data are available for another 20 per cent of he State.

Connecticut↗

Simulation of advective flow under steady-state and transient recharge conditions, Camp Edwards, Massachusetts Military Reservation, Cape Cod, Massachusetts

The U.S. Geological Survey has developed several ground-water models in support of an investigation of ground-water contamination being conducted by the Army National Guard Bureau at Camp Edwards, Massachusetts Military Reservation on western Cape Cod, Massachusetts. Regional and subregional steady-state models and regional transient models were used to (1) improve understanding of the hydrologic system, (2) simulate advective transport of contaminants, (3) delineate recharge areas to municipal wells, and (4) evaluate how model discretization and time-varying recharge affect simulation results. A water-table mound dominates ground-water-flow patterns. Near the top of the mound, which is within Camp Edwards, hydraulic gradients are nearly vertically downward and horizontal gradients are small. In downgradient areas that are further from the top of the water-table mound, the ratio of horizontal to vertical gradients is larger and horizontal flow predominates. The steady-state regional model adequately simulates advective transport in some areas of the aquifer; however, simulation of ground-water flow in areas with local hydrologic boundaries, such as ponds, requires more finely discretized subregional models. Subregional models also are needed to delineate recharge areas to municipal wells that are inadequately represented in the regional model or are near other pumped wells. Long-term changes in recharge rates affect hydraulic heads in the aquifer and shift the position of the top of the water-table mound. Hydraulic-gradient directions do not change over time in downgradient areas, whereas they do change substantially with temporal changes in recharge near the top of the water-table mound. The assumption of steady-state hydraulic conditions is valid in downgradient area, where advective transport paths change little over time. In areas closer to the top of the water-table mound, advective transport paths change as a function of time, transient and steady-state paths do not coincide, and the assumption of steady-state conditions is not valid. The simulation results indicate that several modeling tools are needed to adequately simulate ground-water flow at the site and that the utility of a model varies according to hydrologic conditions in the specific areas of interest.

Massachusetts↗

Water-quality and algal conditions in the North Umpqua River Basin, Oregon, 1992-95, and implications for resource management

This report describes the results of a synoptic water-quality and algal investigation during July 1995 at 36 stream sites in a 1,350 square-mile area of the North Umpqua River Basin, Oregon. The study area includes a headwaters hydroelectric project area, a Wild and Scenic reach in the main stem immediately downstream, and the watersheds of several major tributaries. Additional data from previous investigations are reviewed, and impacts on water quality in the Wild and Scenic reach from resource management, including forestry and reservoir operations, are inferred where sufficient data exist. Water-quality standards were occasionally exceeded for dissolved oxygen and pH, and daily maximum stream temperatures in the Wild and Scenic reach were higher than both the 1996 standard for the State of Oregon and the optimal temperature ranges for many anadromous fish. Dissolved oxygen in the basin was controlled more by stream temperature and reaeration than by primary production. Arsenic concentrations in the river during low flow (1 &micro;g/L [microgram per liter]) indicate a potential cancer risk of between 1:5,000 and 1:20,000 for people using the river as a source of drinking water and fish for consumption. Streambed-sediment concentrations of arsenic, chromium, copper, manganese, and nickel were approximately double the sediment-quality criteria values adopted by New York State and by the Ontario Ministry of the Environment. High concentrations of phosphorus in bed sediments indicated that much of the phosphorus observed in the water column throughout the basin (medians: 32, 9, and 50 &micro;g/L in the main stem, tributaries, and hydroelectric project areas, respectively) could have been geologically derived. Inorganic and organic nitrogen concentrations in water were mostly below minimum reporting limits (5 and 200 &micro;g/L, respectively), indicating severe nitrogen limitation at most locations. Benthic algal biomass, biovolume, and chlorophyll a concentrations were highest at the sites directly below impoundments and at one headwater tributary (medians: 46 grams per square meter, 821 million cubic micrometers per square centimeter, and 126 milligrams per square meter, respectively), and were also somewhat elevated downstream in the Wild and Scenic reach compared with those in similar streams in the Pacific Northwest. Classification of the algal taxa indicated that, among all sites sampled, alkaliphilic taxa, nitrogen fixing taxa, and eutrophic taxa were the most abundant on the basis of biovolume and density. Cold-water taxa, facultative nitrogen heterotrophs, and oligotrophic taxa constituted the remainder of the taxa. Multivariate analyses indicated that algal communities at the hydroelectric-project-affected sites were distinct from communities at sites on the main stem and Steamboat Creek. At many locations, the river&rsquo;s algal community might be compensating for the low nitrogen concentrations by fixation of atmospheric nitrogen or through heterotrophic assimilation of organic nitrogen. Water quality in the Wild and Scenic reach is dominated by water released from the hydroelectric project area during summer. Effects of the hydroelectric project include seasonal control of streamflow, water temperature, and phosphorus concentrations, and the possible release of low but ecologically important concentrations of organic nitrogen. A review of available data and literature suggests that the reservoirs can increase the interception of sediments and large organic debris, and promote their conversion into fine-grained particulate and dissolved organic matter for downstream transport. These effects could be compounded by the effects of forestry in the basin, including alteration of hydrologic cycles, changes in sediment and nutrient runoff, reductions of the transport of large woody debris, and degradation of habitat quality. It is hypothesized that, in the North Umpqua River, these processes have induced a fundamental shift in the river&rsquo;s food web, from a detritus-based system to a system with a 2 higher emphasis on algal production. Confirmation of these changes and their effects on higher trophic levels are needed to properly manage the aquatic resources for all designated beneficial uses in the basin.

Oregon↗

Ground water in Pavant Valley

The users of wells for irrigation in Pavant Valley, particularly in the Flowell district, have long been cognizant of their utter dependency upon ground water for livelihood, and were among the first in the State to make an organized effort to conserve supplies by prevention of waste. Since passage of the State ground-water law in 1935, the State Engineer has not approved applications for new wells in the areas of most concentrated development, and has deferred adjudication of existing water rights until adequate data concerning the ground-water resources become available. The investigation of ground-water resources in Pavant Valley was suggested by the State Engineer and constitutes one of a series that are being made in the important groundwater basins of Utah by the Federal Geological Survey in cooperation with the State Engineer. The investigation was under the general supervision of Oscar E. Meinzer, geologist in charge of the ground-water division of the Federal Geological Survey. H. E. Thomas, in charge of groundwater investigations in Utah, returned from military service overseas in time to assist in the completion of the manuscript, and edited the report.

Utah↗

Hydraulic and water-quality data collection for the investigation of Great Lakes tributaries for Asian carp spawning and egg-transport suitability

If the invasive Asian carps (bighead carp Hypophthalmichthys nobilis and silver carp Hypophthalmichthys molitrix ) migrate to the Great Lakes, in spite of the efforts to stop their advancement, these species will require the fast-flowing water of the Great Lakes tributaries for spawning and recruitment in order to establish a growing population. Two Lake Michigan tributaries (the Milwaukee and St. Joseph Rivers) and two Lake Erie tributaries (the Maumee and Sandusky Rivers) were investigated to determine if these tributaries possess the hydraulic and water-quality characteristics to allow successful spawning of Asian carps. To examine this issue, standard U.S. Geological Survey sampling protocols and instrumentation for discharge and water-quality measurements were used, together with differential global positioning system data for georeferencing. Non-standard data-processing techniques, combined with detailed laboratory analysis of Asian carp egg characteristics, allowed an assessment of the transport capabilities of each of these four tributaries. This assessment is based solely on analysis of observed data and did not utilize the collected data for detailed transport modeling. All four tributaries exhibited potential settling zones for Asian carp eggs both within the estuaries and river mouths and within the lower 100 kilometers (km) of the river. Dams played a leading role in defining these settling zones, with the exception of dams on the Sandusky River. The impoundments created by many of the larger dams on these rivers acted to sufficiently decelerate the flows and allowed the shear velocity to drop below the settling velocity for Asian carp eggs, which would allow the eggs to fall out of suspension and settle on the bottom where it is thought the eggs would perish. While three rivers exhibited these settling zones upstream of the larger dams, not all settling zones are likely to have such effects on egg transport. The Milwaukee River exhibited only a short settling zone upstream of the Grafton Dam, whereas the St. Joseph and Maumee Rivers both had extensive settling zones (>5 km) behind major dams. These longer settling zones are likely to capture more eggs than shorter settling reaches. All four rivers exhibited settling zones at their river mouths, with the Lake Erie tributaries having much larger settling zones extending more than 10 km up the tributaries. While hydraulic data from all four rivers indicated settling of eggs is possible in some locations, all four rivers also exhibited sufficient temperatures, water-quality characteristics, turbulence, and transport times outside of settling zones for successful suspension and development of Asian carp eggs to the hatching stage before the threat of settlement. These observed data indicate that these four Great Lakes tributaries have sufficient hydraulic and water-quality characteristics to support successful spawning and recruitment of Asian carps. The data indicate that with the right temperature and flow conditions, river reaches as short as 25 km may allow Asian carp eggs sufficient time to develop to hatching. Additionally, examining the relation between critical shear velocity and mean velocity, egg settling appears to take place at mean velocities in the range of 15&ndash;25 centimeters per second, a much lower value than is generally cited in the literature. A first-order estimate of the minimum transport velocity for Asian carp eggs in a river can be obtained by using mean flow depth and river substrate data, and curves were constructed to show this relation. These findings would expand the number of possible tributaries suitable for Asian carp spawning and contribute to the understanding of how hydraulic and water-quality information can be used to screen additional rivers in the future.

Great Lakes↗

Hydrogeology and water quality of the Nutmeg Valley area, Wolcott and Waterbury, Connecticut

Hydrogeologic investigations in an industrial area in Wolcott and Waterbury, Connecticut, have provided information on the geology, ground-water flow, and water quality of the area. Ground-water contamination by volatile organic compounds was discovered in the 1980?s in the Nutmeg Valley area, where approximately 43 industries and 25 residences use ground water for industrial and domestic supply. Unconsolidated surficial deposits, including glacial stratified deposits and till, are more than 85 feet thick and are interconnected with the underlying bedrock. The horizontal hydraulic conductivity of the stratified deposits ranges from 0.8 to 21 feet per day. Water in the surficial aquifer generally flows toward discharge points along Old Tannery Brook and the Mad River. Water in the bedrock aquifer flows through low-angle unroofing joints, high-angle fractures, and foliation-parallel fractures. Most high-angle water-bearing fractures strike north with an easterly dip. Most of the water pumped from bedrock wells in the study area comes from shallow fractures that are probably in hydraulic connection with the surficial aquifer. Short-circuit flow between fracture zones in wells is a likely pathway for contaminant transport. During periods of low streamflow, only a small amount of ground water discharges directly to Old Tannery Brook or to the Mad River. The amount of discharge is on the same order of magnitude as the estimated ground-water withdrawals. In northern parts of the valley bottom within the study area, downward vertical hydraulic gradients were present between wells in the surficial and bedrock aquifers. In southern parts of the valley, however, vertical gradients were upward from the bedrock to the surficial aquifer. Vertical gradients can change seasonally in response to different amounts of ground-water recharge and to stresses caused by ground-water withdrawals, which can in turn facilitate the spread of contamination. Vapor-diffusion samplers were installed in streambeds to identify zones where water containing volatile organic compounds was discharging to streams in the study area. Three areas with high vapor concentrations of trichloroethene and tetrachloroethene were identified. Concentrations of trichloroethene as high as 30,000 parts per billion by volume were detected. Three of 44 wells sampled contained concentrations of volatile organic compounds, including trichloroethene and tetrachloroethene, above primary drinking water standards. Based on the findings of this and previous investigations, water in the bedrock aquifer in the southern part of the study area is likely to contain trichloroethene, tetrachloroethene, and 1,1,1-trichloroethane. Volatile organic compounds also were detected in stream samples from the downstream end of Old Tannery Brook and the Mad River. Concentrations of major ions and trace elements (with one exception) did not exceed primary drinking water standards in any ground-water or surface-water samples collected. Ground-water samples collected downgradient from the Waterbury North End Disposal Area contained ethyl ether, chlorobenzene, and elevated concentrations of dissolved solids, similar to samples of landfill leachate and groundwater samples collected from springs and wells adjacent to the landfill.

Water-Resources Investigations Report↗

Use of soil-streamwater relationships to assess regional patterns of acidic deposition effects in the northeastern USA

Declines of acidic deposition levels by as much as 50% since 1990 have led to partial recovery of surface waters in the northeastern USA but continued depletion of soil calcium through this same period suggests a disconnection between soil and surface water chemistry. To investigate the role of soil-surface water interactions in recovery from acidification, the first regional survey to directly relate soil chemistry to stream chemistry during high flow was implemented in a 4144-km 2 area of the Catskill region of New York, where acidic deposition levels are among the highest in the East. More than 40% of 95 streams sampled in the southern Catskill Mountains were determined to be acidified and had inorganic monomeric aluminum concentrations that exceeded a threshold that is toxic to aquatic biota. More than 80% likely exceeded this threshold during the highest flows, but less than 10% of more than 100 streams sampled were acidified in the northwestern portion of the region. Median Oa horizon soil base saturation ranged from 50% to 80% at 200 sites across the region, but median base saturation in the upper 10 cm of the B horizon was less than 20% across the region and was only 2% in the southern area. Aluminum is likely to be interfering with root uptake of calcium in the mineral horizon in approximately half the sampled watersheds. Stream chemistry was highly variable over the Catskill region and, therefore, did not always reflect the calcium depletion of the B horizon that our sampling suggested was nearly ubiquitous throughout the region. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.

New York↗

Application of borehole geophysics in defining the wellhead protection area for a fractured crystalline bedrock aquifer

Wellbore geophysical techniques were used to characterize fractures and flow in a bedrock aquifer at a site near Blackwater Brook in Dover, New Hampshire. The primary focus ofthis study was the development of a model to assist in evaluating the area surrounding a planned water supply well where contaminants introduced at the land surface might be induced to flow towards a pumping well. Well logs and geophysical surveys used in this study included lithologic logs based on examination of cuttings obtained during drilling; conventional caliper and natural gamma logs; video camera and acoustic televiewer surveys; highresolution vertical flow measurements under ambient conditions and during pumping; and borehole fluid conductivity logs obtained after the borehole fluid was replaced with deionized water. These surveys were used for several applications: 1) to define a conceptual model of aquifer structure to be used in groundwater exploration; 2) to estimate optimum locations for test and observation wells; and 3) to delineate a wellhead protection area (WHPA) for a planned water supply well. Integration of borehole data with surface geophysical and geological mapping data indicated that the study site lies along a northeast-trending intensely fractured contact zone between surface exposures of quartz monzonite and metasedimentary rocks. Four of five bedrock boreholes at the site were estimated to produce more than 150 gallons per minute (gpm) (568 L/min) of water during drilling. Aquifer testing and other investigations indicated that water flowed to the test well along fractures parallel to the northeast-trending contact zone and along other northeast and north-northwest-trending fractures. Statistical plots of fracture strikes showed frequency maxima in the same northeast and north-northwest directions, although additional maxima occurred in other directions. Flowmeter surveys and borehole fluid conductivity logging after fluid replacement were used to identify water-producing zones in the boreholes; fractures associated with inflow into boreholes showed a dominant northeast orientation. Borehole fluid conductivity logging after fluid replacement also gave profiles of such water-quality parameters as fluid electrical conductivity (FEC), pH, temperature, and oxidation-reduction potential, strengthening the interpretation of crossconnection of boreholes by certain fracture zones. The results of this study showed that the application of these borehole geophysical techniques at the Blackwater Brook site led to an improved understanding of such parameters as fracture location, attitude, flow direction and velocity, and water quality; all of which are important in the determination of a WHPA.

Log Analyst↗