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At least 613 records · Page 34Linked to original sources
USGS2023

Attenuation of acid rock drainage by stimulating sulfur-reducing bacteria

Iron-sulfide minerals found in shale formations are stable under anaerobic conditions. However, in the presence of oxygen and water, acid-loving chemolithotrophic bacteria can transform the iron-sulfide minerals into a toxic solution of sulfuric acid and dissolved iron and minerals known as acid rock drainage (ARD). The objective of this study was to disrupt chemolithotrophic bacteria responsible for ARD using chemical treatments and to foster an environment favorable for competing microorganisms to attenuate the biologically induced ARD. Chemical treatments were injected into flow-through microcosms consisting of 501 g of pyrite-rich shale pieces inoculated with ARD bacteria. Three treatments were tested in the microcosms: (1) a sodium hydroxide-bleach mix, (2) a sodium lactate solution, and (3) a sodium lactate-soy infant formula mix. The effectiveness of the treatments was assessed by monitoring pH, dissolved iron, and other geochemical constituents in the discharge waters. The optimal treatment was a sequential injection of 1.5 g sodium hydroxide, followed by 0.75 g lactate and 1.5 g soy formula dissolved in 20 mL water. The pH of the discharge water rose to 6.0 within 10 days, dissolved iron concentrations dropped below 1 mg/L, the median alkalinity increased to 98 mg/L CaCO 3 , and sulfur-reducing and slime-producing bacteria populations were stimulated. The ARD attenuating benefits of this treatment were still evident after 231 days. Other treatments provided a number of ARD attenuating effects but were tempered by problems such as high phosphate concentrations, short longevity, or other shortcomings. The results of these laboratory microcosm experiments were promising for the attenuation of ARD. Additional investigations and careful selection of treatment methods will be needed for field application.

Tennessee↗
USGS2007

Geology and Mineral Resources of the East Mojave National Scenic Area, San Bernardino County, California

The rocks of the East Mojave National Scenic Area (EMNSA) record a history of dynamic geologic events that span more than 1,800 million years (m.y.). These geologic events contributed significantly to development of the spectacular vistas and panoramas present in the area today. The oldest rocks underlie much of the northern part of the EMNSA. These rocks were subjected to extreme pressures and temperatures deep in the Earth's crust about 1,700 million years ago (Ma). They were subsequently intruded by granitic magmas from about 1,695 to 1,650 Ma, by additional granitic magmas at about 1,400 Ma and, later, at about 1,100 Ma, by iron-rich magmas that crystallized to form dark igneous rocks termed diabase. Unusual potassium- and magnesium-rich rocks, emplaced at about 1,400 Ma, crop out in a few places within and near the EMNSA. Their distinctive composition results from very small degrees of partial melting of mantle peridotite that was highly enriched in incompatible trace elements. At Mountain Pass, just outside the northeast boundary of the EMNSA, the potassium- and magnesium-rich rocks are accompanied by a rare type of carbonatite, an igneous rock composed of carbonate minerals, that contains high-grade rare earth element mineralization. Subsequent to these igneous-dominated events, sedimentary strata began to be deposited at about 1,000 Ma; mostly sandstone and shale were deposited initially in marine and, less commonly, in continental environments along the west edge of the core of the North American continent. Sedimentation eventually culminated in the widespread deposition of thick marine limestones from about 400 to about 245 Ma. These limestones represent a continental-shelf environment where shallow-water limestone formed to the east and deeper water limestone formed to the west. The end of the formation of these sedimentary deposits probably was caused by uplift of the shelf, which marked the beginning of a long period of tectonic upheaval. At about 170 Ma, widespread emplacement of coarse-grained granitic magmas began again in the region; some of these magmas also erupted as volcanic rocks. Additional episodes of magmatism took place at about 100 Ma and at 75 Ma. Most of the metallic-mineral occurrences in the EMNSA are associated with the igneous rocks that range in age from 170 to 75 Ma. During each of these magmatic events, the previously deposited sedimentary strata were buckled and broken as the entire region, part of a continental-scale fold and thrust belt, underwent crustal shortening and compression. A period of tectonic quiescence characterized the region from about 65 Ma to about 20 Ma. The quiet period ended abruptly with widespread volcanism along the southern and eastern parts of the EMNSA. The major gold deposits in the Castle Mountains are associated with this episode of volcanism. During this volcanic outburst, the crust extended laterally in several areas that border the EMNSA: along the lower Colorado River 65 km to the east, in the Kingston Range 20 km to the north, and in the central Mojave Desert 75 km to the southwest. This extensional deformation is characterized by the superposition of upper-crustal rocks over midcrustal rocks along large flat-lying faults, several of which project beneath rocks now exposed at the surface in the EMNSA. The near-surface rocks of the EMNSA, however, apparently escaped much of this intense extensional deformation. High-angle faults, which cut several of the mountain ranges, possibly have undergone several periods of movement, which date back to approximately 70 to 100 Ma. Some faults are of local importance to the physiographic development of the mountain ranges and intervening basins, and, in places, the faults seem to have localized various kinds of ore bodies and mineral occurrences. Volcanism and extensional deformation waned from 14 to 11 Ma. By approximately 10 Ma, widespread erosion had produced broad erosional dome-shaped mountains in the n

Bulletin↗
USGS2012

The 40Ar/39Ar thermochronology of the eastern Mojave Desert, California, and adjacent western Arizona with implications for the evolution of metamorphic core complexes

Mesozoic thickening and Cenozoic extension resulted in the juxtaposition of upper and middle crustal rocks in the eastern Mojave Desert, southeastern California and western Arizona. The application of 40 Ar/ 39 Ar thermochronology to rocks in this region provides information about the timing and nature of thrusting, plutonism, metamorphism, denudation, and detachment faulting. The 40 Ar/ 39 Ar ages of 175 to 125 Ma from the Clipper, Piute, Turtle, Mohave, Bill Williams, and Hualapai Mountains are interpreted to be the result of a middle Mesozoic thermal event(s) caused by crustal thickening. The 40 Ar/ 39 Ar data from the Clipper and Piute Mountains suggest that this thermal event was followed by a period of cooling at rates of 1°–5°C/m.y. Orogenesis culminated during the Late Cretaceous when rocks exposed in the Old Woman‐Piute, Chemehuevi, and Sacramento Mountains attained temperatures >500°C which reset the K–Ar systems of minerals from Proterozoic rocks. High‐grade metamorphism in the Old Woman Mountains area was caused by the intrusion of the Old Woman‐Piute batholith at 73±1 Ma. Cooling rates following batholith emplacement in the Old Woman Mountains were ∼100°C/m.y. between 73 and 70 Ma and 5°–10°C/m.y. from 70 to ∼30 Ma. Between 65 and 25 Ma the entire eastern Mojave Desert underwent a period of cooling at a rate of 2°–10°C/m.y. By 30 Ma, rocks exposed in the Old Woman‐Piute, Marble, Ship, Clipper, and Turtle Mountains were below ∼100°C. The 40 Ar/ 39 Ar ages from the Sacramento Mountains suggest that mylonitization caused by the onset of regional extension occurred at 23±1 Ma. When extension started in the Chemehuevi Mountains, rocks exposed in the southwestern and northeastern portions of footwall to the Chemehuevi detachment fault were at ∼180°C and ∼350°C, respectively. This suggests that the exposed part of the Chemehuevi detachment fault initiated at a dip of 5°–30° or as a series of higher‐angle faults that cut to a depth of 10–12 km and were later rotated to their present dip. Unroofing of the footwalls to detachment faults in the Sacramento and Chemehuevi Mountains resulted in average cooling rates of 10°–50°C/m.y. between 22 and 15 Ma.

California↗
USGS2005

Origin of secondary sulfate minerals on active andesitic stratovolcanoes

Sulfate minerals in altered rocks on the upper flanks and summits of active andesitic stratovolcanoes result from multiple processes. The origin of these sulfates at five active volcanoes, Citlalte??petl (Mexico), and Mount Adams, Hood, Rainier, and Shasta (Cascade Range, USA), was investigated using field observations, petrography, mineralogy, chemical modeling, and stable-isotope data. The four general groups of sulfate minerals identified are: (1) alunite group, (2) jarosite group, (3) readily soluble Fe- and Al-hydroxysulfates, and (4) simple alkaline-earth sulfates such as anhydrite, gypsum, and barite. Generalized assemblages of spatially associated secondary minerals were recognized: (1) alunite+silica??pyrite??kaolinite?? gypsum??sulfur, (2) jarosite+alunite+silica; (3) jarosite+smectite+silica??pyrite, (4) Fe- and Al-hydroxysulfates+silica, and (5) simple sulfates+silica??Al-hydroxysulfates??alunite. Isotopic data verify that all sulfate and sulfide minerals and their associated alteration assemblages result largely from the introduction of sulfur-bearing magmatic gases into meteoric water in the upper levels of the volcanoes. The sulfur and oxygen isotopic data for all minerals indicate the general mixing of aqueous sulfate derived from deep (largely disproportionation of SO2 in magmatic vapor) and shallow (oxidation of pyrite or H2S) sources. The hydrogen and oxygen isotopic data of alunite indicate the mixing of magmatic and meteoric fluids. Some alunite-group minerals, along with kaolinite, formed from sulfuric acid created by the disproportionation of SO2 in a condensing magmatic vapor. Such alunite, observed only in those volcanoes whose interiors are exposed by erosion or edifice collapse, may have ??34S values that reflect equilibrium (350??50 ??C) between aqueous sulfate and H2S. Alunite with ??34S values indicating disequilibrium between parent aqueous sulfate and H2S may form from aqueous sulfate created in higher level low-temperature environments in which SO2 is scrubbed out by groundwater or where H2S is oxidized. Jarosite-group minerals associated with smectite in only slightly altered volcanic rock are formed largely from aqueous sulfate derived from supergene oxidation of hydrothermal pyrite above the water table. Soluble Al- and Fehydroxysulfates form in low-pH surface environments, especially around fumaroles, and from the oxidation of hydrothermal pyrite. Anhydrite/gypsum, often associated with native sulfur and occasionally with small amounts of barite, also commonly form around fumaroles. Some occurrences of anhydrite/gypsum may be secondary, derived from the dissolution and reprecipitation of soluble sulfate. Edifice collapse may also reveal deep veins of anhydrite/gypsum??barite that formed from the mixing of saline fluids with magmatic sulfate and dilute meteoric water. Alteration along structures associated with both hydrothermal and supergene sulfates, as well as the position of paleo-water tables, may be important factors in edifice collapse and resulting debris flows at some volcanoes. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗
USGS1999

Map showing the potential for mineral deposits associated with Precambrian mafic and ultramafic rocks in the Blacktail and Henrys Lake Mountains and the Greenhorn and Ruby Ranges of southwestern Montana

In response to requests from the Bureau of Land Management (BLM) and the U.S. Forest Service (USFS), the U.S. Geological Survey (USGS) conducted a mineral resource assessment in the Dillon BLM Resource Area in Beaverhead and Madison Counties, southwestern Montana. These agencies use mineral resource data in creating and updating land-use management plans for federal lands for the reasonably foreseeable future. Mineral resources that have not been developed in the past may be developed in the future, based on changing commodity demands and market conditions. Therefore, federal land managers need geologic information on known mineral occurrences as well as on areas that are permissive for the occurrence of undiscovered mineral resources. This map was prepared to provide this type of geologic information for mineral deposits that can be associated with ultramafic rocks. Areas of exposed Precambrian ultramafic rocks are labeled with uppercase letters (A-F). Sources of geologic maps used to compile this map are shown on the smaller index map ("Index to Geologic Mapping"); lowercase letters (a-m) on the index map are keyed to the reference list.

Montana↗
USGS1983

Selected physical properties of rocks from the Baid al Jimalah West tungsten deposit, Kingdom of Saudi Arabia, and recommendations for geophysical surveys

Bulk density and magnetic susceptibility of 11 outcrop samples representing the Proterozoic lithologic units at the Baid al Jimalah West tungsten deposit, Kingdom of Saudi Arabia were measured. Induced polarization response, apparent resistivity, and electromagnetic conductivity were determined for four specimens of the sample suite. Measurements show that there is a negative density contrast of about -0.17 g-cm^-3 between metasedimentary rocks of the Murdama group and the Bald al Jimalah graaite and that this contrast decreases with increasing mineralization of the granite. Similarly, the bulk magnetic susceptibility of the granite is about one-third that of the Murdama rocks for this sample suite; however, magnetic susceptibility increases with increasing mineralization in the granite specimens. Electromagnetic conductivities are uniformly low, in part because the specimens are weathered, but probably also because intense silicification accompanies the mineralization. Induced polarization chargeability increases in the granitic specimens with increasing mineralization and reflects higher percentages of sulfide minerals. Chargeability for the mineralized rocks is about four times higher than for the Murdama host rocks, and apparent resistivity values are about one-fifth the values of host rocks. Based on these results, it is recommended that during reconnaissance exploration of the area 15 detailed high-precision gravity profiles at 10 m to 50 m station spacing and eight induced polarization dipole-dipole profiles at 25 m dipole spacing and maximum 'n' of 6 be measured. To help define subsurface structure, a high-precision, ground-magnetic survey (map at 2-gamma contour interval) and a four-channel gamma ray spectrometric survey on a 25x50 m grid covering the area of the profiles are recommended.

Open-File Report↗
USGS1957

Systematic variation of rare-earth elements in cerium-earth minerals

In a continuation of a study reported previously, rare-earth elements and thorium have been determined in monazite, allanite, cerite, bastnaesite, and a number of miscellaneous cerium-earth minerals. A quantity called sigma (∑), which is the sum of the atomic percentages of La, Ce, and Pr, is proposed as an index of composition of all cerium-earth minerals with respect to the rare-earth elements. The value of ∑ for all of the minerals analysed falls between 58 and 92 atomic per cent. Monazites, allanites, and cerites cover the entire observed range, whereas bastnaesites are sharply restricted to the range between 80 and 92 atomic per cent. The minimum value of ∑ for a cerium-earth mineral corresponds to the smallest possible unit-cell size of the mineral. In monazite, this structurally controlled minimum value of ∑ is estimated to be around 30 atomic per cent. Neodymium, because of its abundance, and yttrium, because of its small size, have dominant roles in contraction of the structure. In the other direction, the limit of variation in composition will be reached when lanthanum becomes the sole rare-earth element in a cerium-earth mineral. Cerium-earth minerals from alkalic rocks are all characterized by values of ∑ greater than 80 atomic per cent, indicating that the processes that formed these rocks were unusually efficient in fractionating the rare-earth elements—efficient in the sense that a highly selected assemblage is produced without eliminating the bulk of these elements. Analyses of inner and outer parts of two large crystals of monazite from different deposits show no difference in ∑ in one crystal and a slightly smaller value of ∑ in the outer part of the other crystal compared to the inner part. The ∑ of monazites from pegmatites that intrude genetically related granitic rocks in North Carolina is found to be either higher or lower than the ∑ of monazites in the intruded host rock. These results indicate that the fractionation of the rare-earth elements is not a simple unidirectional process. When a cerium-earth mineral undergoes replacement, its rare-earth elements may be fractionated into two parts, one forming a new mineral with ∑ that is smaller, and the other a second new mineral with ∑ that is larger than that of the original mineral. The complete analysis of a cerium-earth mineral to determine its ∑ is time consuming. The discovery of a direct relationship between ∑ and the Ce/(Nd + Y) atomic ratio in cerium earth minerals allows a rapid determination of ∑ from spectrograms obtained in a previously described method for determining thorium in these minerals.

Geochimica et Cosmochimica Acta↗
USGS2008

Metalliferous sediment and a silica-hematite deposit within the Blanco fracture zone, Northeast Pacific

A Tiburon ROV dive within the East Blanco Depression (EBD) increased the mapped extent of a known hydrothermal field by an order of magnitude. In addition, a unique opal-CT (cristobalite-tridymite)-hematite mound was discovered, and mineralized sediments and rock were collected and analyzed. Silica-hematite mounds have not previously been found on the deep ocean floor. The light-weight rock of the porous mound consists predominantly of opal-CT and hematite filaments, rods, and strands, and averages 77.8% SiO2 and 11.8% Fe2O3. The hematite and opal-CT precipitated from a low-temperature (???115?? C), strongly oxidized, silica- and iron-rich, sulfur-poor hydrothermal fluid; a bacterial mat provided the framework for precipitation. Samples collected from a volcaniclastic rock outcrop consist primarily of quartz with lesser plagioclase, smectite, pyroxene, and sulfides; SiO2 content averages 72.5%. Formation of these quartz-rich samples is best explained by cooling in an up-flow zone of silica-rich hydrothermal fluids within a low permeability system. Opal-A, opal-CT, and quartz mineralization found in different places within the EBD hydrothermal field likely reflects decreasing silica saturation and increasing temperature of the mineralizing fluid with increasing silica crystallinity. Six push cores recovered gravel, coarse sand, and mud mineralized variously by Fe or Mn oxides, silica, and sulfides. Total rare-earth element concentrations are low for both the rock and push core samples. Ce and Eu anomalies reflect high and low temperature hydrothermal components and detrital phases. A remarkable variety of types of mineralization occur within the EBD field, yet a consistent suite of elements is enriched (relative to basalt and unmineralized cores) in all samples analyzed: Ag, Au, S, Mo, Hg, As, Sb, Sr, and U; most samples are also enriched in Cu, Pb, Cd, and Zn. On the basis of these element enrichments, the EBD hydrothermal field might best be described as a base- and precious-metal-bearing, silica-Fe-oxide-barite deposit. Such deposits are commonly spatially and temporally associated with volcanogenic massive sulfide (VMS) ores. A plot of data for pathfinder elements shows a large hot spot at the northwestern margin of the field, which may mark a region where moderate to high temperature sulfide deposits are forming at depth; further exploration of the hydrothermal field to the northwest is warranted.

Marine Georesources and Geotechnology↗
USGS1997

Cross sections showing stratigraphic and depositional lithofacies of upper Cambrian rocks and the relation of lithofacies to potential for Mississippi Valley-type mineralization in the Harrison 1° x 2° quadrangle, Missouri and Arkansas (folio of the Harrison 1 degree by 2 degrees quadrangle, Missouri and Arkansas)

These cross sections are the fifth publication in a folio of maps of the Harrison 1° x 2° quadrangle, Missouri and Arkansas, prepared under the Conterminous United States Mineral Assessment Program (CUSMAP). Previously published maps in this folio relate to the geochemistry of the subsurface carbonate rocks (Erickson and others, 1989), the geophysics of the basement terranes (McCafferty and others, 1989), the sedimentary rocks and mineralization of the Caulfield district (Hayes and others, 1992), the mineral resource potential of the quadrangle (Pratt and others, 1993), and the bedrock geology of the quadrangle (Middendorf and others, 1994 and in press). A final set of maps showing locations of known Mississippi Valley-type deposits and occurrences relative to Late Cambrian shaly lithofacies and other shales in the Harrison and adjoining quadrangle is in preparation (Palmer and Hayes, in press).

Arkansas, Missouri↗
USGS1964

Mineral paragenesis and zoning in the central Kentucky mineral district

The Central Kentucky mineral district occupies the greater part of the Blue Grass lowland of Kentucky , which lies astride the Lexington dome and the Cincinnati arch. The oldest exposed rocks of the mineralized area are limestones of Middle Ordovician age. The paragenesis throughout the district is constant and traceable, although the relative abundance of minerals varies from vein to vein. The mineral association, areal distribution of the ore minerals, and comparison with other epithermal deposits indicate that the Central Kentucky veins are epithermal. The ore deposits have a district -wide lateral zoning in a concentric pattern. Near the middle of the district , and within the Lexington dome, are two centers of fluorite-calcite-dark sphalerite veins that form Zone 1. Surrounding these centers is a much larger Zone 2 in which nearly all the veins contain fluorite, barite, calcite, and two-colored (yellow-black) sphalerite. Galena is absent or present in very minute quantities in Zones 1 and 2. In Zone 3, which surrounds Zone 2, barite, galena, and bright-colored sphalerite are the principal minerals. Fluorite is absent, or present only in traces. Textures of the mineral veins change from bands of coarse comb crystals in Zone 1 to mostly colloform bands in the outer zones. Structural control of the ore is related to faults and fractures transecting the collapsed Lexington dome and is an important factor in the distribution of mineral veins. The district has many of the mineralogic, zonal, and structural features of the Central Tennessee, Kentucky -Illinois, and Pennine, England, mineral districts, which suggest that the origins of these districts were similar. The ores in the Central Kentucky district were probably deposited from ascending thermal solutions of slightly lower temperatures than those that formed the deposits in the Kentucky -Illinois district . The solutions are believed to have been derived from a deepseated magmatic source centered beneath the Lexington dome, but they may have been greatly diluted by ground waters within the dome. The innermost zone probably is nearest to the emanative centers.

Kentucky↗
USGS2012

Occurrence model for volcanogenic beryllium deposits

Current global and domestic mineral resources of beryllium (Be) for industrial uses are dominated by ores produced from deposits of the volcanogenic Be type. Beryllium deposits of this type can form where hydrothermal fluids interact with fluorine and lithophile-element (uranium, thorium, rubidium, lithium, beryllium, cesium, tantalum, rare earth elements, and tin) enriched volcanic rocks that contain a highly reactive lithic component, such as carbonate clasts. Volcanic and hypabyssal high-silica biotite-bearing topaz rhyolite constitutes the most well-recognized igneous suite associated with such Be deposits. The exemplar setting is an extensional tectonic environment, such as that characterized by the Basin and Range Province, where younger topaz-bearing igneous rock sequences overlie older dolomite, quartzite, shale, and limestone sequences. Mined deposits and related mineralized rocks at Spor Mountain, Utah, make up a unique economic deposit of volcanogenic Be having extensive production and proven and probable reserves. Proven reserves in Utah, as reported by the U.S. Geological Survey National Mineral Information Center, total about 15,900 tons of Be that are present in the mineral bertrandite (Be 4 Si 2 O 7 (OH) 2 ). At the type locality for volcanogenic Be, Spor Mountain, the tuffaceous breccias and stratified tuffs that host the Be ore formed as a result of explosive volcanism that brought carbonate and other lithic fragments to the surface through vent structures that cut the underlying dolomitic Paleozoic sedimentary rock sequences. The tuffaceous sediments and lithic clasts are thought to make up phreatomagmatic base surge deposits. Hydrothermal fluids leached Be from volcanic glass in the tuff and redeposited the Be as bertrandite upon reaction of the hydrothermal fluid with carbonate clasts in lithic-rich sections of tuff. The localization of the deposits in tuff above fluorite-mineralized faults in carbonate rocks, together with isotopic evidence for the involvement of magmatic water in an otherwise meteoric water-dominated hydrothermal system, indicate that magmatic volatiles contributed to mineralization. At the type locality, hydrothermal alteration of dolomite clasts formed layered nodules of calcite, opal, fluorite, and bertrandite, the latter occurring finely intergrown with fluorite. Alteration assemblages and elemental enrichments in the tuff and surrounding volcanic rocks include regional diagenetic clays and potassium feldspar and distinctive hydrothermal halos of anomalous fluorine, lithium, molybdenum, niobium, tin, and tantalum, and intense potassium feldspathization with sericite and lithium-smectite in the immediate vicinity of Be ore. Formation of volcanogenic Be deposits is due to the coincidence of multiple factors that include an appropriate Be-bearing source rock, a subjacent pluton that supplied volatiles and heat to drive convection of meteoric groundwater, a depositional site characterized by the intersection of normal faults with permeable tuff below a less permeable cap rock, a fluorine-rich ore fluid that facilitated Be transport (for example, BeF 4 2- complex), and the existence of a chemical trap that caused fluorite and bertrandite to precipitate at the former site of carbonate lithic clasts in the tuff.

Scientific Investigations Report↗
USGS1954

Radioactive deposits in California

Reconnaissance examination by Government geologists of many areas, mine properties, and prospects in California during the period between 1948 and 1953 has confirmed the presence of radioactive materials in place at more than 40 localities. Abnormal radioactivity at these localities is due to concentrations of primary and secondary uranium minerals, to radon gas, radium (?), and to thorium minerals. Of the known occurrences only three were thought to contain uranium oxide (uranitite or pitchblende), 4 contained uranium-bearing columbate, tantalate, or titanate minerals, 12 contained secondary uranium minerals, such as autunite, carnotite, and torbernite, one contained radon gas, 7 contained thorium minerals, and, at the remaining 16 localities, the source of the anomalous radiation was not positively determined. The occurrences in which uranium oxide has been tentatively identified include the Rathgeb mine (Calaveras County), the Yerih group of claims (San Bernardino County), and the Rainbow claim (Madera County). Occurrences of secondary uranium minerals are largely confined to the arid desert regions of south-eastern California including deposits in San Bernardino, Kern, Inyo, and Imperial Counties. Uranium-bearing columbate, tantalate, or titanate minerals have been reported from pegmatite and granitic rock in southeastern and eastern California. Thorium minerals have been found in vein deposits in eastern San Bernardino County and from pegmatites and granitic rocks in various parts of southeastern California; placer concentrations of thorium minerals are known from nearly all areas in the State that are underlain, in part, by plutonic crystalline rocks. The primary uranium minerals occur principally as minute accessory crystals in pegmatite or granitic rock, or with base-metal sulfide minerals in veins. Thorium minerals also occur as accessory crystals in pegmatite or granitic rock, in placer deposits derived from such rock, and, at Mountain Pass, in veins containing rare earths. Secondary uranium minerals have been found as fracture coatings and as disseminations in various types of wall rock, although they are largely confined to areas of Tertiary volcanic rocks. Probably the uranium in the uraniferous deposits in California is related genetically to felsic crystalline rocks and felsic volcanic rocks; the present distribution of the secondary uranium minerals has been controlled, in part, by circulating ground waters and probably, in part, by magmatic waters related to the Tertiary volcanic activity. The thorium minerals are genetically related to the intrusion of pegmatite and plutonic crystalline rocks. None of the known deposits of radioactive minerals in California contain marketable reserves of uranium or thorium ore under economic conditions existing in 1952. With a favorable local market small lots of uranium ore may be available in the following places: the Rosamund prospect, the Rafferty and Chilson properties, the Lucky Star claim, and the Yerih group. The commercial production of thorium minerals will be possible, in the near future, only if these minerals can be recovered cheaply as a byproduct either from the mining of rare earths minerals at Mountain Pass or as a byproduct of placer mining for gold.

California↗
USGS2012

Gold deposits of the Carolina Slate Belt, southeastern United States--Age and origin of the major gold producers

Gold- and iron sulfide-bearing deposits of the southeastern United States have distinctive mineralogical and geochemical features that provide a basis for constructing models of ore genesis for exploration and assessment of gold resources. The largest (historic) deposits, in approximate million ounces of gold (Moz Au), include those in the Haile (~ 4.2 Moz Au), Ridgeway (~1.5 Moz Au), Brewer (~0.25 Moz Au), and Barite Hill (0.6 Moz Au) mines. Host rocks are Late Proterozoic to early Paleozoic (~553 million years old) metaigneous and metasedimentary rocks of the Carolina Slate Belt that share a geologic affinity with the classic Avalonian tectonic zone. The inferred syngenetic and epithermal-subvolcanic quartz-porphyry settings occur stratigraphically between sequences of metavolcanic rocks of the Persimmon Fork and Uwharrie Formations and overlying volcanic and epiclastic rocks of the Tillery and Richtex Formations (and regional equivalents). The Carolina Slate Belt is highly prospective for many types of gold ore hosted within quartz-sericite-pyrite altered volcanic rocks, juvenile metasedimentary rocks, and in associated shear zones. For example, sheared and deformed auriferous volcanogenic massive sulfide deposits at Barite Hill, South Carolina, and in the Gold Hill trend, North Carolina, are hosted primarily by laminated mudstone and felsic volcanic to volcaniclastic rocks. The high-sulfidation epithermal style of gold mineralization at Brewer and low-sulfidation gold ores of the Champion pit at Haile occur in breccias associated with subvolcanic quartz porphyry and within crystal-rich tuffs, ash flows, and subvolcanic rhyolite. The Ridgeway and Haile deposits are primarily epithermal replacements and feeder zones within (now) metamorphosed crystal-rich tuffs, volcaniclastic sediments, and siltstones originally deposited in a marine volcanic-arc basinal setting. Recent discoveries in the region include (1) extensions of known deposits, such as at Haile where drilling has identified an extensive gold-rich feeder system; and (2) newly discovered prospects like the porphyry-style gold-copper-molybdenum occurrence reported at Deep River, N.C. Gold ores at Ridgeway and Haile represent the low-sulfidation, disseminated, shallow subaqueous tuffaceous equivalents of intrusion-related high-sulfidation ores such as those at Brewer. Haile also has mineralogical features that support a stockwork disseminated model of pyrite-gold-sericite mineralization in which a significant amount of ore was deposited in sediments at or near the surface. The potential is high for gold-rich ore at depth in the funnel-shaped feeder zones that likely underlie such surface variants of high sulfidation–low sulfidation epithermal systems and for new discoveries of similar deposits in areas undercover. Exploration strategies for large-scale gold-mineralizing systems applied to rocks of the Carolina Slate Belt, and by extension, the Carolinian-Avalonian tectonic zone of North America, benefit from applying subvolcanic and basinal epithermal models for gold mineralization.

North Carolina;South Carolina;Virginia;Georgia↗
USGS1992

Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: II. Some general geologic applications

The experimental metal solubilities for rock-buffered hydrothermal systems, reported by Hemley et al. (1992), provide important insights into the acquisition, transport, and deposition of metals in real hydrothermal systems that produced base metal ore deposits. Water-rock reactions that determine pH, together with total chloride and changes in temperature and fluid pressure, play significant roles in controlling the solubility of metals and determining where metals are fixed to form ore deposits.Hydrothermal systems circulate fluids and heat, and the transport path of a hydrothermal fluid is likely to lie somewhere between an adiabatic (no heat loss to adjacent rocks) and a geothermal (complete thermal equilibrium with adjacent rock) path. The transport path of the hydrothermal fluids emanating from, or circulating near, deep-seated crystallizing plutons can be approximated by a quasi-adiabatic pressure-temperature path. In such a quasi-adiabatic setting, the pressure effect on rock-buffered metal solubilities is significant and allows metal transport over long distances because the trend of decreasing metal solubility with decreasing temperature is compensated by the trend of increasing metal solubility with decreasing pressure. The high-temperature portion of a quasi-adiabatic hydrothermal system will tend to leach metals from the rock and fix K and Na in feldspars. The source of the extracted metals may be late-stage magmatic melt, trace metals distributed in the lattice of silicate minerals destroyed during rock metasomatism, and/or small amounts of base metal sulfides disseminated throughout a given rock.Deposition of metals in hydrothermal systems occurs where changes such as cooling, pH increase due to rock alteration, boiling, or fluid mixing cause the aqueous metal concentration to exceed saturation. Relative metal transport concentrations, the availability of sulfur, the disposition of the saturation surfaces relative to each other, and the interplay of these variables through time are the major factors controlling the pattern of metal deposition (and nondeposition).Metal zoning results from deposition occurring at successive saturation surfaces. Zoning is not a reflection simply of relative solubility but of the manner of intersection of transport concentration paths with those surfaces. The experimental results are consistent with the typical outward zonation of Cu-Zn-Pb observed in porphyry coppers, Butte-type base metal vein deposits, skarns, and massive sulfides. Implications to mineralization patterns in Mississippi Valley-type, sedimentary Cu, and other low-temperature deposits are also of interest, with due recognition of the greater uncertainty regarding speciation and attainment of equilibrium in those environments. In such deposits, a probable outward zoning of Cu-Zn-Pb-Fe is suggested from the results.Saturation surfaces will tend to migrate outward and inward in prograde and retrograde time, respectively, controlled by either temperature or chemical variables. This, in turn, gives rise to zone migration and, where one zone encroaches on another, the appropriate apparent paragenetic relations. Such textural implications are incorrect, however, unless viewed within the context of the overall mineralization process. Additional controls bearing on metal precipitation sequence and coprecipitation, the presence or absence of zoning, reversals in zoning, sulfidation state, and timing relations between alteration and metallization are implicit in the results and are discussed.

Economic Geology↗
USGS2014

Assessment of undiscovered sandstone copper deposits of the Kodar-Udokan area, Russia

Mineral resource assessments integrate and synthesize available information as a basis for estimating the location, quality, and quantity of undiscovered mineral resources. This probabilistic mineral resource assessment of undiscovered sandstone copper deposits within Paleoproterozoic metasedimentary rocks of the Kodar-Udokan area in Russia is a contribution to a global assessment led by the U.S. Geological Survey (USGS). The purposes of this study are to (1) delineate permissive areas (tracts) to indicate where undiscovered sandstone-hosted copper deposits may occur within 2 km of the surface, (2) provide a database of known sandstone copper deposits and significant prospects, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu) and mineralized rock that could be contained in undiscovered deposits within each tract. The workshop for the assessment, held in October 2009, used a three-part form of mineral resource assessment as described by Singer (1993) and Singer and Menzie (2010). Permissive tracts were delineated by estimating the volume of rock that contains the stratigraphic section ranging from the Chitkanda to the Sakukan Formations of the Udokan Complex to a depth of 2 km and then projecting this rock volume to the surface. The six permissive tracts delineated in this assessment occur in several domains, referred to as troughs in Russian literature, which represent remnants of a much larger basin that likely covered the Kodar-Udokan region. Tracts range in size from about 100 km 2 to 800 km 2 . The mapped distributions of rocks as shown on 1:200,000-scale geologic maps, supplemented in some areas by prospect mapping and drilling, were used to delineate the tracts. In this study area, data are insufficient to constrain the original basin geometry or the structural or stratigraphic traps that would have localized copper mineralization. Some alteration is described, and the types of sandstone cements vary; however, no patterns are known that provide evidence for regional flow paths of metal-bearing brines that could localize deposits. This probabilistic assessment indicates that a significant amount of undiscovered copper is associated with sediment-hosted stratabound copper deposits in the Kodar-Udokan Trough. In the assessment, a mean of 21 undiscovered deposits is estimated to occur within the Kodar-Udokan area. There are two known deposits in the area that contain drill-identified resources of 19.6 million metric tons of copper. Using Monte Carlo simulation, probabilistic estimates of the numbers of undiscovered sandstone copper deposits for these tracts were combined with tonnage and grade distributions of sandstone copper deposits to forecast an arithmetic mean of 20.6 million metric tons of undiscovered copper. Significant value can be expected from associated metals, particularly silver.

Scientific Investigations Report↗
USGS2008

238U-230Th-226Ra Disequilibria in Dacite and Plagioclase from the 2004–2005 Eruption of Mount St. Helens

Uranium-series disequilibria in whole-rock samples and mineral separates provide unique insights into the time scales and processes of magma mixing, storage, and crystallization. We present 238 U- 230 Th- 226 Ra data for whole-rock dacite and gouge samples and for plagioclase separated from two dacite samples, all erupted from Mount St. Helens between October 2004 and April 2005. We also present new 238 U- 230 Th disequilibria for a suite of four reference samples from the 1980-86 eruption of Mount St. Helens. We use the U-series data to evaluate the origin of the 2004-5 magma, its relation to the 1980-86 magma, and the relation of 2004-5 phenocrysts to their host magmas. Dacite samples from 2004-5 show variable ( 230 Th)/( 238 U), ranging from 238 U-enriched to 230 Th-enriched. ( 230 Th)/( 232 Th) ratios in 2004-5 dacite and gouge samples do not vary outside of analytical error and are within the range of ( 230 Th)/( 232 Th) measured for the 1980s reference suite. However, ( 230 Th)/( 232 Th) for plagioclase separates for dome samples erupted during October and November 2004 are significantly different from corresponding whole-rock values, which suggests that a large fraction (>30 percent) of crystals in each sample are foreign to the host liquid. Furthermore, plagioclase in the two 2004 samples have U-series characteristics distinct from each other and from plagioclase in dacite erupted in 1982, indicating that (1) the current eruption must include a component of crystals (and potentially associated magma) that were not sampled by the 1980-86 eruption, and (2) dacite magmas erupted only a month apart in 2004 contain different populations of crystals, indicating that this foreign component is highly heterogeneous within the 2004-5 magma reservoir.

Washington↗
USGS1997

Geochemical processes controlling uranium mobility in mine drainages

Comprehensive models of ore genesis incorporate metal sources, transport and concentration mechanisms, and preservation mechanisms. Analogous concepts apply to the problem of metal migration from mines, mine wastes, and mine tailings, including: the concentrations, mineralogical occurrence, and availability of metals in mineral deposits, host rocks, mine wastes, and tailings (the source); the mechanisms for metal mobilization and transport during weathering; the mechanisms for metal fixation and the permanence of the fixation. Similarly, undisturbed mineral deposits or alteration zones that are exposed at the Earth's surface may be natural sources from which metals can be solubilized during weathering. Uranium (U), a naturally-occurring radioactive element, may be present in mineral deposits in sufficient concentrations that in itself constitutes ore. It may also be present in ores of other metals at concentrations that exceed average crustal abundances. Any uranium that is not completely removed from these ores in the mining and milling process may be available for mobilization into ground or surface waters via the weathering and oxidation of solid tailings or mine waste piles. This chapter discusses the relative importance of various geochemical processes that control uranium mobility via weathering in both mined and unmined mineralized environments. The data presented in this paper focus on mined areas because the great extent of historic mining in the field areas examined for this study preclude extensive consideration of undisturbed areas.

Book chapter↗
USGS2015

Results of mineral, chemical, and sulfate isotopic analyses of water, soil, rocks, and soil extracts from the Pariette Draw Watershed, Uinta Basin, Utah

In 2010, Utah Department of Environmental Quality (DEQ) Division of Water Quality (UDWQ, 2010) determined that water quality in Pariette Draw was in violation of Federal and State water quality criteria for total dissolved solids (TDS), selenium (Se), and boron (B). The measure of total dissolved solids is the sum of all the major ion concentrations in solution and in this case, the dominant ions are sodium (Na) and sulfate (SO4), which can form salts like thenardite (Na2SO4) and mirabilite (Na2SO4⋅H2O). The Utah Department of Environmental Quality (2010) classified the contamination as natural background and from nonpoint sources related to regional lithology and irrigation practices. Although the daily loads of the constituents of concern and water chemistry have been characterized for parts of the watershed, little is known about the controls that bedrock and soil mineralogy have on salt, Se, and B storage and the water-rock interactions that influence the mobility of these components in ground and surface waters. Studies in the Uncompahgre River watershed in Colorado by Tuttle and others (2014a, 2014b) show that salt derived from weathering of shale in a semiarid climate is stored in a variety of minerals that contribute solutes to runoff and surface waters based on a complex set of conditions such as water availability, geomorphic position (for example, topography controls the depth of salt accumulation in soils), water-table fluctuations, redox conditions, mineral dissolution kinetics, ion-exchange reactions, and secondary mineral formation. Elements like Se and B commonly reside in soluble salt phases, so knowledge of the behavior of salt minerals also sheds light on the behavior of associated contaminants. The goal of this study was to establish a process-based understanding of salt, Se, and B behavior to address whether these contaminants can be better managed, or if uncontrollable natural processes will overwhelm any attempts to bring Pariette Draw into compliance with respect to recently established total maximum daily limits (TMDLs). We collected data to refine our knowledge about the role of rock weathering and soil formation in the transport and storage of salt in the watershed and to show how salt is cycled under irrigated and natural conditions. Our approach was to sample rock, soils, and sediment on irrigated and natural terrain for mineralogical analysis to determine the residence of salt and associated Se and B, classify minerals as primary (related to rock formation) or secondary weathering products, and characterize mineral dissolution kinetics. Mineral and chemical analyses and selective extractions of rocks and soils provide useful information in understanding solute movement and mineral dissolution/ formation. The resulting data are critical in determining residence of salt, Se, and B in weathered rock and soil and understanding the mobility during water-rock-soil interactions. This report summarizes our methods for sample and data collection and tabulates the mineral, chemical, and isotopic data collected.

Utah↗