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At least 613 records · Page 34Linked to original sources

Magma transport and metasomatism in the mantle: a critical review of current geochemical models

Conflicting geochemical models of metasomatic interactions between mantle peridotite and melt all assume that mantle reactions reflect chromatographic processes. Examination of field, petrological, and compositional data suggests that the hypothesis of chromatographic fractionation based on the supposition of large-scale percolative processes needs review and revision. Well-constrained rock and mineral data from xenoliths indicate that many elements that behave incompatibly in equilibrium crystallization processes are absorbed immediately when melts emerge from conduits into depleted peridotite. After reacting to equilibrium with the peridotite, melt that percolates away from the conduit is largely depleted of incompatible elements. Continued addition of melts extends the zone of equilibrium farther from the conduit. Such a process resembles ion-exchange chromatography for H2O purification, rather than the model of chromatographic species separation. -from Authors

American Mineralogist↗

Hawaii scientific drilling protect: Summary of preliminary results

Petrological, geochemical, geomagnetic, and volcanological characterization of the recovered core from a 1056-m-deep well into the flank of the Mauna Kea volcano in Hilo, Hawaii, and downhole logging and fluid sampling have provided a unique view of the evolution and internal structure of a major oceanic volcano unavailable from surface exposures. Core recovery was ~90%, yielding a time series of fresh, subaerial lavas extending back to ~400 ka. Results of this 1993 project provide a basis for a more ambitious project to core drill a well 4.5 km deep in a nearby location with the goal of recovering an extended, high-density stratigraphic sequence of lavas.

Hawaii↗

Porphyry deposits of the Canadian Cordillera

Porphyry deposits are intrusion-related, large tonnage low grade mineral deposits with metal assemblages that may include all or some of copper, molybdenum, gold and silver. The genesis of these deposits is related to the emplacement of intermediate to felsic, hypabyssal, generally porphyritic intrusions that are commonly formed at convergent plate margins. Porphyry deposits of the Canadian Cordillera occur in association with two distinctive intrusive suites: calc-alkalic and alkalic. In the Canadian Cordillera, these deposits formed during two separate time periods: Late Triassic to Middle Jurassic (early Mesozoic), and Late Cretaceous to Eocene (Mesozoic-Cenozoic). Deposits of the early Mesozoic period occur in at least three different arc terranes (Wrangellia, Stikinia and Quesnellia) with a single deposit occurring in the oceanic assemblage of the Cache Creek terrane. These terranes were located outboard from continental North America during formation of most of their contained early Mesozoic porphyry deposits. Some of the deposits of this early period may have been emplaced during terrane collisions. Metal assemblages in deposits of the calc-alkalic suite include Mo-Cu (Brenda), Cu-Mo (Highland Valley, Gibraltar), Cu-Mo-Au-Ag (Island Copper, Schaft Creek) and Cu-Au (Kemess, Kerr).The alkalic suite deposits are characterized by a Cu-Au assemblage (Copper Mountain, Afton-Ajax, Mt. Milligan, Mount Polley, Galore Creek). Although silver is recovered from calc-alkalic and alkalic porphyry copper mining operations, silver data are seldom included in the published reserve figures. Those available are in the range of 1-2 grams per tonne (g??t-1). Alkalic suite deposits are restricted to the early Mesozoic and display distinctive petrology, alteration and mineralization that suggest a similar tectonic setting for both Quesnellia and Stikinia in Early Jurassic time. The younger deposits, late Mesozoic to Cenozoic in age, formed in an intracontinental setting, after the outboard host arc and related terranes accreted to the western margin of North America. These deposits are interpreted to occur in continental arc settings, and individual deposits are hosted by a variety of older country rocks. These younger deposits also show a spectrum of metal associations: Cu-Mo (Huckleberry, Berg), Cu-Au (-Mo) (Bell, Granisle, Fish Lake, Casino), Mo (Endako, Boss Mountain, Kit-sault, Quartz Hill), Mo-W (Logtung), Au-W (Dublin Gulch) and Au (Ft. Knox). There may be a continuum between Mo, Mo-W, Au-Mo-W and Au deposits. The distribution and timing of these post-accretion deposits likely reflect major crustal structures and subduction geometry. Cordilleran porphyry metallic deposits show the full range of morphological and depth relationships found in porphyry deposits worldwide. In addition, the Cordillera contains numerous alkalic suite deposits, which are rare worldwide: the unusual, possibly syntectonic Gibraltar deposit; and end-member gold-rich granite-hosted deposits, such as Ft. Knox (Alaska).

Geoscience Canada↗

Late Pleistocene-Holocene cataclysmic eruptions at Nevado de Toluca and Jocotitlan volcanoes, central Mexico

This field guide describes a five day trip to examine deposits of Late Pleistocene-Holocene cataclysmic eruptions at Nevado de Toluca and Jocotitlan volcanoes in central Mexico. We will discuss the stratigraphy, petrology, and sedimentological characteristics of these deposits which provide insights into the eruptive history, type of volcanic activity, and transport and emplacement mechanisms of pyroclastic materials. These parameters will allow us to discuss the kinds of hazards and the risk that they pose to populations around these volcanoes. The area to be visited is tectonically complex thus we will also discuss the location of the volcanoes with respect to the tectonic environment. The first four days of the field trip will be dedicated to Nevado de Toluca Volcano (19 degrees 09'N; 99 degrees 45'W) located at 23 km. southwest of the City of Toluca, and is the fourth highest peak in the country, reaching an elevation of 4,680 meters above sea level (m.a.s.l.). Nevado de Toluca is an andesitic-dacitic stratovolcano, composed of a central vent excavated upon the remains of older craters destroyed by former events. Bloomfield and Valastro, (1974, 1977) concluded that the last cycle of activity occurred nearly equal 11,600 yr. ago. For this reason Nevado de Toluca has been considered an extinct volcano. Our studies, however, indicate that Nevado de Toluca has had at least two episodes of cone destruction by sector collapse as well as several explosive episodes including plinian eruptions and dome-destruction events. These eruptions occurred during the Pleistocene but a very young eruption characterized by surge and ash flows occurred ca. 3,300 yr. BP. This new knowledge of the volcano's eruptive history makes the evaluation of its present state of activity and the geological hazards necessary. This is important because the area is densely populated and large cities such as Toluca and Mexico are located in its proximity.

Brigham Young University Geology Studies↗

Bimodal magmatism, basaltic volcanic styles, tectonics, and geomorphic processes of the eastern Snake River Plain, Idaho

Geology presented in this field guide covers a wide spectrum of internal and surficial processes of the eastern Snake River Plain, one of the largest components of the combined late Cenozoic igneous provinces of the western United States. Focus is on widespread Quaternary basaltic plains volcanism that produced coalescent shields and complex eruptive centers that yielded compositionally evolved magmas. The guide is constructed in several parts beginning with discussion sections that provide an overview of the geology followed by road directions, with explanations, for specific locations. The geology overview briefly summarizes the collective knowledge gained, and petrologic implications made, over the past few decades. The field guide covers plains volcanism, lava flow emplacement, basaltic shield growth, phreatomagmatic eruptions, and complex and evolved eruptive centers. Locations and explanations are also provided for the hydrogeology, groundwater contamination, and environmental issues such as range fires and cataclysmic floods associated with the region.

Brigham Young University Geology Studies↗

Long-period seismicity at Redoubt Volcano, Alaska, 1989-1990 related to magma degassing

The mass of exsolved magmatic H2O is estimated and compared to the mass of superheated steam (25-50 Mtons) released through the resonating crack producing the December 13-14, 1989 swarm of long-period seismic events at Redoubt Volcano. Results indicate degassing of a H2O-CO2-SO2-saturated magma upon ascending from at least 12 km to 3-4 km beneath the crater as the source of the superheated steam. The mass of exsolved H2O (3.2-250 Mtons) is estimated from solubility diagrams of H2O-CO2-saturated silicate melts for the ascent history of the Redoubt magmas. Crystal size distribution, seismological, petrological, and geochemical data are used to constrain the ascent history of the two andesitic magmas prior to the eruption. Two stages of crystallization are inferred from crystal size distributions of plagioclase crystals in andesites erupted in December 1989. The first stage occurred 30-150 years before the eruption in both magmas and the second stage occurred at least 8 years and 15 years before the eruption in the dacitic andesite and rhyolitic andesite, respectively. The depths of crystallization are constrained from the spatial and temporal variations of volcano-tectonic earthquakes locations (Lahr et al., 1994) and from the P-wave and S-wave velocity structures (Benz et al., 1996). These data suggest that the rhyolitic andesite magma ascended to a depth of 7-8 km within at least 15 years of the eruption. Within at least 8 years of the eruption, the dacitic andesite magma migrated to a depth just below the other magma body where it resided until hours to days of the eruption. At this time, the dacitic andesite magma mixed with the rhyolitic andesite magma and established the reservoir for the eruption. Near the top of the reservoir, some of the mixed magma was displaced into fractures which extended 4-5 km toward the surface. This displaced magma created the eruption conduit and released the fluids related to the resonating crack. This scenario is consistent with the trends in major-and trace-element chemistry, and the stability of hornblende in the pre-eruption Redoubt magmas. It also provides a source for the SO2 and CO2 emissions measured during the eruption.

Journal of Volcanology and Geothermal Research↗

Simmonsite, Na2LiAlF6, a new mineral from the Zapot amazonite-topazzinnwaldite pegmatite, Hawthorne, Nevada, U.S.A

Simmonsite, Na2LiAlF6, a new mineral of pegmatitic-hydrothermal origin, occurs in a late-stage breccia pipe structure that cuts the Zapot amazonite-topaz-zinnvvaldite pegmatite located in the Gillis Range, Mineral Co., Nevada, U.S.A. The mineral is intimately intergrown with cryolite, cryolithionite and trace elpasolite. A secondary assemblage of other alumino-fluoride minerals and a second generation of cryolithionite has formed from the primary assemblage. The mineral is monoclinic, P21 or P21/m, a = 7.5006(6) A??, b = 7.474(1) A??, c = 7.503(1) A??, ??= 90.847(9) ??, V=420.6(1) A??3, Z = 4. The four strongest diffraction maxima [d(A??), likl, I/I100] are (4.33, 111 and 111, 100); (1.877, 400 and 004, 90); (2.25, 13T, 113, 131 and 311, 70); and (2.65, 220, 202, 022, 60). Simmonsite is pale buff cream with white streak, somewhat greasy, translucent to transparent, Mohs hardness of 2.5-3, no distinct cleavage, subconchoidal fracture, no parting, not extremely brittle, Dm is 3.05(2) g/cm3, and Dc is 3.06(1) g/cm3. The mineral is biaxial, very nearly Isotropie, N is 1.359(1) for ?? = 589 nm, and birefringence is 0.0009. Electron microprobe analyses gave (wt%) Na = 23.4, Al = 13.9, F = 58.6, Li = 3.56 (calculated), with a total of 99.46. The empirical formula (based on 6 F atoms) is Na1.98Li1.00 ooAl|ooF6. The crystal structure was not solved, presumably because of unit-cell scale twinning, but similarities to the perovskite-type structure exist. The mineral is named for William B. Simmons, Professor of Mineralogy and Petrology, University of New Orleans, New Orleans.

American Mineralogist↗

The petrographic microscope: Evolution of a mineralogical research instrument

The petrographic microscope, designed to observe and measure the optical properties of minerals as a means of identifying them, has provided a foundation for mineralogical and petrological research for more than 120 years. Much of what is known today in these fields is attributable to this instrument, the development of which paralleled an evolution of fundamental optical theory and its correlation with mineral structure and composition. This instrument and its related accessories have evolved through a range of models and designs, which are in themselves distinctive for their scientific function and elegant construction, and are today prized by collectors of scientific instruments.

Mineralogical Record↗

The Coso EGS project - Recent developments

An Engineered Geothermal System (EGS) field experiment will be conducted to hydraulically stimulate injection well 34-9RD2, located on the east flank of the Coso geothermal reservoir, with the objective of increasing the injection rate of this well to 750 gpm at a wellhead pressure of 100 psi or less. The stimulation of this well is expected to create hydraulic communication with the recently drilled production well 38C-9, which is directly south of 34-9RD2. We summarize the results of fracture and stress analyses based upon borehole image logs of 38C-9; petrographic and petrologic analyses of cuttings from both the injection well 34-9RD2 and the production well 38C-9; and plans for the redrilling and stimulation of 34-9RD2.

California↗

Petrography and character of the bedrock surface beneath western Cape Cod, Massachusetts

Cores collected during recent drilling in western Cape Cod, Massachusetts provide insight into the topography and petrology of the underlying bedrock. 62 drill sites spread over a ???140 km2 study area produced cores of granitoids (31), orthogneisses (20), basalts/diabases (4), amphibolites (3), felsic mylonites (2), and dolomitic rock (2). Granitoid cores range in composition from granite to tonalite to quartz diorite, but are dominated by single-mica granites. Alteration is common in nearly all cores examined in this study, and is evidenced by the secondary growth of chlorite and epidote. The granitoids resemble rocks of the Dedham and Fall River terranes (Wones and Goldsmith 1991). Gneisses from the study area generally contain the mineral assemblage hornblende+plagioclase+quartz+biotite+epidote??chlorite?? sphene??K-feldspar??sericite+oxides. Based on mineral assemblages, we estimate peak metamorphic grade to be of lower amphibolite facies. X-ray powder diffraction of unmetamorphosed dolomitic cores shows presence of layered silicates (clays), plagioclase, and possible magnesite. Contours of the bedrock surface show locally irregular topography suggesting erosion by glacial scour. The distribution of lithologies suggests a possible continuation of the New Bedford gneissic terrane that outcrops 25 km to the west. Dolomitic rocks may represent a lithified fault gouge material at the eastern edge of the gneissic zone. Basalts/diabases are interpreted to be post-metamorphic dikes of Late Paleozoic age, or possibly associated with Mesozoic rifting.

Massachussets↗

Deep Europe today: Geophysical synthesis of the upper mantle structure and lithospheric processes over 3.5 Ga

We present a summary of geophysical models of the subcrustal lithosphere of Europe. This includes the results from seismic (reflection and refraction profiles, P- and S-wave tomography, mantle anisotropy), gravity, thermal, electromagnetic, elastic and petrological studies of the lithospheric mantle. We discuss major tectonic processes as reflected in the lithospheric structure of Europe, from Precambrian terrane accretion and subduction to Phanerozoic rifting, volcanism, subduction and continent-continent collision. The differences in the lithospheric structure of Precambrian and Phanerozoic Europe, as illustrated by a comparative analysis of different geophysical data, are shown to have both a compositional and a thermal origin. We propose an integrated model of physical properties of the European subcrustal lithosphere, with emphasis on the depth intervals around 150 and 250 km. At these depths, seismic velocity models, constrained by body-and surface-wave continent-scale tomography, are compared with mantle temperatures and mantle gravity anomalies. This comparison provides a framework for discussion of the physical or chemical origin of the major lithospheric anomalies and their relation to large-scale tectonic processes, which have formed the present lithosphere of Europe. ?? The Geological Society of London 2006.

Geological Society Memoir↗

Research on genesis of pyrite near the Permian-Triassic boundary in meishan, Zhejiang, China

The content and crystal forms of pyrite and sulfur isotope composition of pyrite sulfur as well as its vertical distribution near the Permian-Triassic (P/T) boundary in the Meishan section, Changxing county, Zhejiang province, China were studied using geological, petrological, mineralogical and geochemical methods (techniques). The result showed that the genesis of abundant pyrites in bed 24e2 at the uppermost part of the Changxing Formation in the Meishan section may be related to volcanic activity. In bed 24e2 of the Meishan section, pyrite has its highest content of 1.84% and the sulfur isotope composition has the highest ??34S value at + 2.2??? which is very similar to that of the average value of volcanic gas. There are some volcanic products such as ??-quartz, siliceous cylinders and siliceous spherules which coexisted with pyrites in beds 24e2 and 24f. It can be concluded that a large quantity of volcanic ash fell into the South China Sea and was incorporated into marine sediments during the formation of limestone at the uppermost part of the Changxing Formation. The volcanic eruption with massive amounts of H2S and S02 gas at the end of the Permian period resulted in the enrichment of H2S in the South China Sea areas. The reaction of H2S with reactive iron minerals formed the mass of abundant pyrites.

Journal of China University of Mining and Technolo↗

Paleokarst and reservoir porosity in the Ordovician Beekmantown Dolomite of the central Appalachian basin

A karst-unconformity play at the top of the Ordovician Beekmantown Dolomite is judged to have great petroleum potential in Ohio and adjacent states; wells have high ultimate reserves and large areas remain untested. To better understand the origin, development, and distribution of Beekmantown porosity, we conducted a petrologic-stratigraphic study of cores and thin sections from 15 oil and gas wells. The massive dolomite, characterized by a hypidiotopic-idiotopic texture, formed by the replacement of stacked peritidal carbonate cycles. Secondary porosity occurs at two scales: (1) mesoscopic - breccia porosity, solution-enlarged fractures, large vugs, and caverns, and (2) microscopic - intercrystalline, intracrystalline, molds, small vugs, and microfractures. Mesoscopic pores (providing the major storage capacity in this reservoir) were produced by intrastratal solution and collapse of carbonate layers, whereas microscopic pores (connecting the larger pores) generally formed by the leaching of individual carbonate grains and crystals. Most pore types developed during periods of subaerial exposure across the carbonate bank, tied to either the numerous, though brief falls of relative sea level during Beekmantown deposition or more importantly the prolonged Knox unconformity at the close of sedimentation. The distribution of reservoir-quality porosity is quite heterogeneous, being confined vertically to a zone immediately below the unconformity and best developed laterally beneath buried hills and noses of this erosion surface. The inferred, shallow flow of ground water in the Beekmantown karst, primarily below topographic highs and above a diagenetic base level close to the water table, led to this irregular distribution of porosity.

Carbonates and Evaporites↗

Iron Hill (Powderhorn) carbonatite complex, Gunnison County, CO - A potential source of several uncommon mineral resources

The Iron Hill (Powderhorn) carbonatite complex is a 31-kM2 (12-sq mile) alkalic intrusion located about 35 km (22 miles) south-southwest of Gunnison, CO. The intrusion has been well studied and described because of its classic petrology and architecture ofa carbonatite-alkalic complex. The complex is also noteworthy because it contains enrichments of titanium, rare earth elements, thorium, niobium (columbium), vanadium and deposits of vermiculite and nepheline syenite. In particular, the complex is thought to host the largest titanium and niobium resources in the United States, although neither has been developed. It may be economic to extract multiple resources from this complex with a well-coordinated mine and mill plan.

Mining Engineering↗

Mercury in coals and fly ashes from Republika and Bobov dol thermoelectric power plants

Feed coal and y ash samples were collected at Republika and Bobov Dol thermoelectric power plants (TPPs). The y ashes (FAs) were collected fromthree rows of the hot-side electrostatic precipitators (ESPs) array. Each sam- ple was wet-screened at 100, 200, 325 and 500 mesh. The coals and y ashes were characterized with regard to their petrological and chemical composition (including mercury content) and to their surface area properties. The calculated enrichment factor (EF) shows that the Hg concentrations in the bulk coal samples from Republika and Bobov Dol TPPs are 2.19 and 1.41, respectively. In some coal size fractions the EF can be up to 4 times higher than the Clarke value. The calculated EF for fly ashes shows that the Hg concentrations in the bulk samples studied are lower (between 0.03 and 0.32) than the Clarke value. The most enriched in Hg are the fly ashes from the 3rd ESP row of Republika TPP. The Hg distribution in bulk FAs taken from dierent rows of the electrostatic precipitators of both TPPs studied shows well established tendency of gradual increase in the Hg content from the 1st to the 2nd and 3rd ESP rows. The correlation between Hg content and surface area, mesopore and micropore volume of y ashes was also done in the present investigation.

Comptes Rendus de L'Academie Bulgare des Sciences↗

Preliminary evaluation of the shale gas prospectivity of the Lower Cretaceous Pearsall Formation in the onshore Gulf Coast region, United States

Recent work by the U.S. Geological Survey indicated that the Lower Cretaceous Pearsall Formation contains an estimated mean undiscovered, technically recoverable unconventional gas resource of 8.8 trillion cubic ft in the Maverick Basin, South Texas. Cumulative gas production from horizontal wells in the core area of the emerging play has exceeded 5 billion cubic ft since 2008. However, very little information is available to characterize the Pearsall Formation as an unconventional gas resource beyond the Maverick Basin in the greater Gulf Coast region. Therefore, this reconnaissance study examines spatial distribution, thickness, organic richness and thermal maturity of the Pearsall Formation in the onshore U.S. Gulf states using wireline logs and drill cuttings sample analysis. Spontaneous potential and resistivity curves of approximately forty wireline logs from wells in five Gulf Coast states were correlated to ascertain the thickness of the Pearsall Formation and delineate its three members: Pine Island Shale, James Limestone or Cow Creek Limestone, and Bexar Shale, in ascending stratigraphic order. In Florida and Alabama the Pearsall Formation is up to about 300 ft thick; in Mississippi, Louisiana, Arkansas, and East Texas, thickness is up to as much as 800 ft. Drill cuttings sampled from 11 wells at depths ranging from 4600 to 19,600 feet subsurface indicate increasingly oxygenated depositional environments (predominance of red shale) towards the eastern part of the basin. Cuttings vary widely in lithology but indicate interbedded clastics and limestones throughout the Pearsall Formation, consistent with previous regional studies. Organic petrographic and geochemical analyses of 17 cutting samples in the Pearsall Formation indicate a wide range in thermal maturity, from immature (0.43% Ro [vitrinite reflectance]) in paleo-high structural locations to the peak oil window (0.99% Ro) in the eastern portion of the Gulf Coast Basin. This is in contrast to dry gas thermal maturity throughout the Pearsall Formation in the South Texas Maverick Basin. Organic carbon content is low overall, even in immature samples, with a range of 0.17 to 1.08 wt.% by Leco in 22 Pearsall Formation samples. The pyrolysis output range was 0.23 to 2.33 mg hydrocarbon/g rock. The thermal maturity and Rock-Eval pyrolysis data and organic petrologic observations from this study will be used to better focus specific areas of investigation where the Pearsall Formation may be prospective as an unconventional hydrocarbon source and reservoir.

Alabama;Arkansas;Louisiana;Mississippi;Oklahoma;Te↗

Annual fluxes of sediment-associated trace/major elements, carbon, nutrients, and sulfur from US coastal rivers

About 260–270 Mt of suspended sediment are discharged annually from the conterminous USA; approximately 69% derives from Gulf rivers (n = 36), 24% from Pacific rivers (n = 42), and 7% from Atlantic rivers (n = 54). Elevated sediment-associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges: Atlantic rivers (49%) > Pacific rivers (40%) > Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Zn) tend to occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated nutrient concentrations occur along both the Atlantic and Gulf coasts, but are dominated by rivers in the urban northeast and by southeastern and Gulf coast “blackwater” streams. Elevated Ca, Mg, K and Na levels appear to reflect local petrology whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have both natural and anthropogenic sources. Almost all the elevated sediment-associated chemical concentrations/fluxes are lower than worldwide averages.

United States coastal rivers↗

Platinum, palladium, and rhodium in volcanic and plutonic rocks from the Gravina-Nutzotin belt, Alaska

The Gravina-Nutzotin belt of Middle (?) Jurassic to middle Cretaceous sedimentary and volcanic rocks in south and southeastern Alaska includes concentrically zoned ultramafic complexes known to contain platinum-group metals. Previous isotopic, petrologic, and geologic studies suggested a close relation in time and space between the volcanic rocks and the ultramafic complexes. Interpretation of 40 analyses for platinum, palladium, and rhodium in volcanic and plutonic rocks of the belt indicates a strong geochemical correlation between the two groups of rocks and is in support of their being cogenetic either from directly connected magma chambers and flows or indirectly by selective concentration processes from similar mantle material.

Alaska↗