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Geology and coal deposits of the Dugger quadrangle, Sullivan County, Indiana

The accompanying maps and related material describing the geology and coal deposits of the Dugger quadrangle were prepared as part of a cooperative program to appraise the coal resources of Indiana initiated by the Division of Geology, Indiana Department of Conservation, and the Geological Survey, United States Department of the Interior. The field work on which the maps were based was done by the writer, assisted by E. D. McKay, between June 15 and August 31, 1949. The Dugger quadrangle covers nearly 58 square miles in east-central Sullivan County, Indiana, between latitude 39° and 39°07'30" N. and longitude 87°15' and 87°22'30" W. Dugger, the largest town in the quadrangle and the main shipping point, is 30 miles south of Terre Haute. The mines in the quadrangle are served by the Illinois Central, the Chicago, Milwaukee, St. Paul & Pacific, and the Pennsylvania Railroads.

Indiana↗

Emissions from coal fires and their impact on the environment

Self-ignited, naturally occurring coal fires and fires resulting from human activities persist for decades in underground coal mines, coal waste piles, and unmined coal beds. These uncontrolled coal fires occur in all coal-bearing parts of the world (Stracher, 2007) and pose multiple threats to the global environment because they emit greenhouse gases - carbon dioxide (CO 2 ), and methane (CH 4 ) - as well as mercury (Hg), carbon monoxide (CO), and other toxic substances (fig. 1). The contribution of coal fires to the global pool of atmospheric CO 2 is little known but potentially significant. For China, the world's largest coal producer, it is estimated that anywhere between 10 million and 200 million metric tons (Mt) of coal reserves (about 0.5 to 10 percent of production) is consumed annually by coal fires or made inaccessible owing to fires that hinder mining operations (Rosema and others, 1999; Voigt and others, 2004). At this proportion of production, coal amounts lost to coal fires worldwide would be two to three times that for China. Assuming this coal has mercury concentrations similar to those in U.S. coals, a preliminary estimate of annual Hg emissions from coal fires worldwide is comparable in magnitude to the 48 tons of annual Hg emissions from all U.S. coal-fired power-generating stations combined (U.S. Environmental Protection Agency, 2002). In the United States, the combined cost of coal-fire remediation projects, completed, budgeted, or projected by the U.S. Department of the Interior's Office of Surface Mining Reclamation and Enforcement (OSM), exceeds $1 billion, with about 90% of that in two States - Pennsylvania and West Virginia (Office of Surface Mining Enforcement and Reclamation, 2008; fig. 2). Altogether, 15 States have combined cumulative OSM coal-fire project costs exceeding $1 million, with the greatest overall expense occurring in States where underground coal fires are predominant over surface fires, reflecting the greater cost of extinguishing underground fires (fig. 2) (see 'Controlling Coal Fires'). In this fact sheet we review how coal fires occur, how they can be detected by airborne and remote surveys, and, most importantly, the impact coal-fire emissions may have on the environment and human health. In addition, we describe recent efforts by the U.S. Geological Survey (USGS) and collaborators to measure fluxes of CO 2 , CO, CH 4 , and Hg, using groundbased portable detectors, and combining these approaches with airborne thermal imaging and CO 2 measurements. The goal of this research is to develop approaches that can be extrapolated to large fires and to extrapolate results for individual fires in order to estimate the contribution of coal fires as a category of global emissions.

Fact Sheet↗

Hydrogeologic framework of the diabase aquifer at the Boarhead Farms Superfund site, Bridgeton Township, Bucks County, Pennsylvania

The hydrogeologic investigation at the Boarhead Farms Superfund site was done to characterize the framework of the diabase aquifer underlying the site. The primary water-producing fracture system is less than 30 feet below land surface. Water-bearing fractures were not found deeper than 50 feet below land surface. The overburden soil is thin and ranges from 4 to 14 feet thick. The overburden soil acts as a confining unit for the underlying bedrock aquifer. Weathered bedrock consisting of broken diabase ranged from 2 to 15 feet thick, and in some areas, fractures in the weathered bedrock zone were filled with clay. Due to the clay-rich overburden soil and the thick, clay filled weathered bedrock zone, little ground-water storage is available to supply the shallow fracture systems. The diabase aquifer is low yielding with low transmissivities. Five of 15 boreholes drilled as part of the U.S. Geological Survey's investigation produced no water. Estimates of transmisivity calculated from analyses of open-hole constant-discharge tests in five boreholes ranged from 3.1 to 100 square feet per day. Estimated discharge rates for these exists between boreholes. The fracture system is limited in areal extent. Dewatering of fractures supplying water to boreholes occurred during open-hole constant-discharge tests of three boreholes.

Water-Resources Investigations Report↗

Shorter contributions to general geology, 1917

Contents: A. Baked shale and slag formed by the burning of coal beds / G.S. Rogers B. The Newington moraine, Maine, New Hampshire, and Massachusetts / F.J. Katz and Arthur Keith C.A comparison of Paleozoic sections in southern New Mexico / N.H. Darton D. Wasatch fossils in so-called Fort Union beds of the Powder River Basin, Wyo., and their bearing on the stratigraphy of the region / C.H. Wegemann E. Geologic history indicated by the fossiliferous deposits of the Wilcox group at Meridian, Miss. / E.W. Berry F.A fossil flora from the Frontier formation of southwestern Wyoming / F.H. Knowlton G. The stratigraphic position and faunal associates of the orbitoid Foraminifera of the genus Orthophragmina from Georgia and Florida / C.W. Cooke G. Orbitoid Foraminifera of the genus Orthophragmina from Georgia and Florida / J.A. Cushman H. The Pliocene history of northern and central Mississippi / E.W. Shaw I. Stratigraphy in northwestern Maine and southeastern New Hampshire / F.J. Katz J. The Flaxville gravel and its relation to other terrace gravels of the northern Great Plains / A.J. Collier K. The Helderberg limestone of central Pennsylvania / J.B. Reeside L. Stratigraphy of the Hanna Basin, Wyo. / C.F. Bowen

Professional Paper↗

Evidence for the correlation of the upper part of the Llewellyn Formation (Pennsylvania Anthracite region), with the Monongahela Formation

A plant fossil assemblage from the roof shale of the No. 25 anthracite bed in Pennsylvania indicates that the upper part of the Llewellyn Formation is much younger than the lower part of the Allegheny Group or Conemaugh Group correlation that was indicated by Read and Mamay (1960). These results confirm the conclusions of Fontaine and White (1880), White (1900), and Darrah (1969) who suggested that the highest coals of the Llewellyn Formation could be equivalent to the Monongahela Group.

Northeastern Geology and Environmental Sciences↗

Groundwater withdrawals and regional flow paths at and near Willow Grove and Warminster, Pennsylvania—Data compilation and preliminary simulations for conditions in 1999, 2010, 2013, 2016, and 2017

In 2014, groundwater samples from residential and public supply wells in the vicinity of two former U.S. Navy bases at Willow Grove and Warminster, and an active Air National Guard Station at Horsham, Bucks and Montgomery Counties, Pennsylvania, were found to have concentrations of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS), which are per- and polyfluoroalkyl substances (PFAS), above U.S. Environmental Protection Agency (EPA) provisional health advisory (HA) levels for drinking water. Five supply wells near the bases were shut down because of PFAS contamination. In 2016, after EPA established a Lifetime HA for PFAS in drinking water that is lower than the provisional HA in place in 2014, at least 13 additional supply wells near the bases were shut down because of PFAS contamination. At the request of the U.S. Navy, and in consultation with other Federal and State agencies and local stakeholders, the U.S. Geological Survey used historical and recent data on well withdrawals, recharge rates, aquifer properties, groundwater levels, and stream base flow to evaluate regional groundwater-flow paths from identified areas of PFAS groundwater contamination or potential PFAS sources at the bases. Groundwater withdrawals near the bases from public supply and other large wells decreased substantially from the 1990s to 2017, increasing the proportion of groundwater recharge that discharged to local streams. A preliminary groundwater-flow model, calibrated using 1,009 groundwater levels and 17 stream base flow estimates, simulated regional flow paths from the bases and showed that recharge at the bases discharged to withdrawal wells and local streams, generally within a mile or two of the bases. Supply and remediation wells at the bases captured some of the recharge on base areas of possible PFAS contamination, whereas other base recharge was simulated to flow to nearby public supply wells and streams, depending on water use and aquifer recharge conditions between 1999 and 2017. The locations of many residential wells near the bases that were identified by the Navy and Air National Guard as having elevated PFAS concentrations were generally consistent with the simulated flow paths from possible sources at the bases. However, there are some areas of observed PFAS contamination where no flow paths from base sources were simulated. Additionally, no data were available on PFAS concentrations in groundwater in some areas of simulated flow paths from base sources. Data and models used for this study are provided in this report and in digital data releases to support further investigations and model revisions.

Pennsylvania↗

Changes in streamflow and water quality in selected nontidal sites in the Chesapeake Bay Basin, 1985-2003

Water-quality and streamflow data from 33 sites in nontidal portions of the Chesapeake Bay Basin were analyzed to document annual nutrient and sediment loads and trends for 1985 through 2003 as part of an annual evaluation of water-quality conditions by the Chesapeake Bay Program. As part of this study, different trend tests and methodologies were evaluated for future use in assessment of the effectiveness of management actions in reducing nutrients and sediments to the Chesapeake Bay. Trends in streamflow were tested at multiple time scales (daily, monthly, seasonal, and annual), resulting in only one significant trend (annual flow for Choptank River near Greensboro, Md.). Data summaries for observed concentrations indicate higher ranges in total-nitrogen concentrations in the northern five major river basins in Pennsylvania, Maryland, and Virginia compared to the southern five basins in Virginia. Similar comparisons showed no distinct differences for total phosphorus. Flow-weighted concentration is useful in evaluating changes through time for the Susquehanna, Potomac, and James Rivers. Results indicate the Potomac River had the highest flow-weighted concentrations (2.5 milligrams per liter) for total nitrogen, and the Potomac and James Rivers averaged about the same (0.15 milligram per liter) for total-phosphorus concentrations. Flow-weighted concentrations were lowest in the Susquehanna River for phosphorus and sediment because of the trapping efficiency of three large reservoirs upstream from the sampling point. Annual loads were estimated by use of the U.S. Geological Surveys ESTIMATOR model. Annual nutrient and sediment loads in 2003 were the second highest total nitrogen, total phosphorus, and sediment loads for the River Input Monitoring sites since 1990. Trends in concentrations, when adjusted for flow, can be used as an indicator of human activity and management actions. The flow-adjusted trends indicated significant decreasing trends at approximately 55, 75, and 48 percent of the sites for total nitrogen, total phosphorus, and sediment, respectively. This suggests management actions are having some effect in reducing nutrients and sediments. Sampling protocols for the river inputs to the bay have targeted high flows. Because this sampling strategy creates the potential for bias in estimated loads and trends, calculations are limited to flow-adjusted loads and trends in this report.

Scientific Investigations Report↗

An innovative carbonate coprecipitation process for the removal of zinc and manganese from mining impacted waters

Although mine drainage is usually thought of as acidic, there are many cases where the water is of neutral pH, but still contains metal species that can be harmful to human or aquatic animal health, such as manganese (Mn) and zinc (Zn). Typical treatment of mine drainage waters involves pH adjustment, but this often results in excessive sludge formation and removal of nontoxic species such as magnesium and calcium. Theoretical consideration of the stability of metal carbonate species suggests that the target metals could be removed from solution by coprecipitation with calcium carbonate. The U.S. Geological Survey has developed a limestone-based process for remediation of acid mine drainage that increases calcium carbonate saturation. This treatment could then be coupled with carbonate coprecipitation as an innovative method for removal of toxic metals from circumneutral mine drainage waters. The new process was termed the carbonate coprecipitation (CCP) process. The CCP process was tested at the laboratory scale using a synthetic mine water containing 50 mg/L each of Mn and Zn. Best results showed over 95% removal of both Mn and Zn in less than 2 h of contact in a limestone channel. The process was then tested on a sample of water from the Palmerton zinc superfund site, near Palmerton, Pennsylvania, containing over 300 mg/L Zn and 60 mg/L Mn. Treatment of this water resulted in removal of over 95% of the Zn and 40% of the Mn in the limestone channel configuration. Because of the potential economic advantages of the CCP process, further research is recommended for refinement of the process for the Palmerton water and for application to other mining impacted waters as well. ?? Mary Ann Liebert, Inc.

Environmental Engineering Science↗

The Areal Extent of Continuous Type Gas Accumulations in Lower Silurian Clinton Sands and Medina Group Sandstones of the Appalachian Basin and the Environments Affected by Their Development

In order to best preserve and manage our energy and natural resources we must understand the relationships between these resources and the impacts of their development. To further this understanding the U.S. Geological Survey is studying unconventional continuous-type and, to a lesser extent, conventional oil and gas accumulations and the environmental impacts associated with their development. Continuous-type gas accumulations are generally characterized by low matrix permeabilities, large areal extents, and no distinct water contacts. This basin scale map shows the overall extent of these accumulations and the general land use types that may be impacted by their development. The Appalachian Basin has the longest history of oil and gas exploration and production in the United States. Since Drake's Titusville discovery well was drilled in 1859, oil and gas has been continuously produced in the basin. While there is still a great deal of oil and gas production, new field discoveries are rare and relatively small. For most of the second half of the 20th century the Appalachian basin has been considered a mature petroleum province because most of the large plays have already been discovered and developed. One exception to this trend is the Lower Silurian Clinton Sands and Medina Group Gas play which is being developed in New York, Pennsylvania, and Ohio. This continuous-type gas play has been expanding since the early 1970's (see inset maps). In the 1980's economic incentives such as large increases in wellhead prices further stimulated continuous-type gas resource development. Continuous-type gas plays can be large in areal extent and in thickness. 'Sweetspots' (areas of greater prodcution) are hard to predict and generally associated with better than average permeabilities, and enhanced by natural fracture systems. With an overall success rate often approaching 90%, drilling most of the play with closely spaced wells is often the best way to maximize gas recovery. Some positive economic characteristics associated with the development of these continuous-type accumulations are high success rates, low drilling and development costs, and low water production, which results in low water disposal costs. Large areas within the Appalachian basin with good potential for this type of gas accumulation remain to be tested. Positive environmental characteristics include, a clean energy source, low water production, and relatively low surface impact. Some negative characteristics associated with these continuous -type accumulations are low individual well production rates and small well drainage area. Negative environmental characteristics are primarily related to the dense well spacing used to develop the resource to its full potential. Often negative environmental impacts such as surface disturbance can be greatly reduced. The number of well sites can be decreased by using a single centrally located surface location and associated facilities for several directionally or horizonatally drilled wells. This also minimizes the transportation infrastructure (access roads and pipelines) required to maintain the wells and deliver the gas. Visual impacts can be reduced by selecting well locations visible only over short distances. While the prospective area is large, potential decreases basin- ward and toward the northeast and southwest. These areas are represented by the lower potential plays 6727, 6730, and 6731. The U.S. Geological Survey landuse and landcover data was derived from USGS 1:250,000 and 1:100,000 scale maps. This information was collected between the mid 1970s to mid 1980s. The land use and land cover data was mapped and coded using the Anderson classification system (Anderson, 1975) which is a hierarchical system of general (level 1) to more specific (level 2) characterization. Level 1 characterization was used for this map; the land use and land cover designations are displayed below in the Explanation. T

Open-File Report↗

Effects of climate variability and human activities on Chesapeake Bay and the implications for ecosystem restoration

Chesapeake Bay, the Nation’s largest and most productive estuary (fig. 1), faces complex environmental issues related to nutrients and oxygen, turbidity and sedimentation, toxic dinoflagellates, sea-level rise, and coastal erosion. The Chesapeake Bay Program (CBP) is a partnership among the Chesapeake Bay Commission, the Federal Government, the District of Columbia, and the States of Maryland, Virginia, and Pennsylvania. The CBP is working to preserve, restore, and protect the bay’s living resources, vital habitats, and water quality, to protect human health, and to promote sound land-use policies in the watershed. The CBP began to set restoration goals for the ecosystem in the mid-1980’s and is now refining current goals and setting new ones as part of a new bay agreement— Chesapeake 2000. As the CBP sets restoration goals for the next 10–20 years, it will be critical to understand the long-term changes of the bay ecosystem due to climate variability and the influence of past and future human activities. For the past 4 years, the U.S. Geological Survey (USGS) has been engaged in research designed to provide objective scientific answers to questions about long-term changes in the bay ecosystem: What paleoecological and geochemical methods are best for documenting trends in the bay ecosystem? How does climate variability, including drought, affect the bay? What are historical trends in dissolved oxygen? What is the relationship between sedimentation and water clarity, and what is the effect of turbidity on living resources? How have past land-use changes affected bay habitats and living resources?

Chesapeake Bay Watershed↗

Hydrogeology of the Susquehanna River valley-fill aquifer system and adjacent areas in eastern Broome and southeastern Chenango Counties, New York

The hydrogeology of the valley-fill aquifer system along a 32-mile reach of the Susquehanna River valley and adjacent areas was evaluated in eastern Broome and southeastern Chenango Counties, New York. The surficial geology, inferred ice-marginal positions, and distribution of stratified-drift aquifers were mapped from existing data. Ice-marginal positions, which represent pauses in the retreat of glacial ice from the region, favored the accumulation of coarse-grained deposits whereas more steady or rapid ice retreat between these positions favored deposition of fine-grained lacustrine deposits with limited coarse-grained deposits at depth. Unconfined aquifers with thick saturated coarse-grained deposits are the most favorable settings for water-resource development, and three several-mile-long sections of valley were identified (mostly in Broome County) as potentially favorable: (1) the southernmost valley section, which extends from the New York–Pennsylvania border to about 1 mile north of South Windsor, (2) the valley section that rounds the west side of the umlaufberg (an isolated bedrock hill within a valley) north of Windsor, and (3) the east–west valley section at the Broome County–Chenango County border from Nineveh to East of Bettsburg (including the lower reach of the Cornell Brook valley). Fine-grained lacustrine deposits form extensive confining units between the unconfined areas, and the water-resource potential of confined aquifers is largely untested. Recharge, or replenishment, of these aquifers is dependent not only on infiltration of precipitation directly on unconfined aquifers, but perhaps more so from precipitation that falls in adjacent upland areas. Surface runoff and shallow groundwater from the valley walls flow downslope and recharge valley aquifers. Tributary streams that drain upland areas lose flow as they enter main valleys on permeable alluvial fans. This infiltrating water also recharges valley aquifers. Current (2012) use of water resources in the area is primarily through domestic wells, most of which are completed in fractured bedrock in upland areas. A few villages in the Susquehanna River valley have supply wells that draw water from beneath alluvial fans and near the Susquehanna River, which is a large potential source of water from induced infiltration.

New York↗

Rhode Island and Landsat

Rhode Island is an oasis of natural calm surrounded by heavily urbanized East Coast areas, which may explain why the smallest State in the United States is such a popular tourist destination for residents of New York, Pennsylvania, and New Jersey, or perhaps its popularity is a measure of the Ocean State’s abundant wildlife and picturesque views. Although small in land area, Rhode Island claims the largest estuary in New England in the 147-square-mile Narragansett Bay. Locals and visitors feast on clams caught in the bay, trek to glimpse shorebirds, or boat to 1 of 30 islands. As with any coastal State, the natural wonders of Rhode Island are affected by changes in sea levels and ocean temperatures. State agencies also work to fend off foes like the invasive Lymantria dispar (Linnaeus, 1758; spongy moth) and protect the forests that cover more than one-half of Rhode Island. The U.S. Geological Survey Landsat Program, with 54 plus years of recurring Earth observations from space, offers a unique and freely available public data source for the study of land and coastal change across Rhode Island and the United States. Here are just a few of the ways Landsat imagery has been used to benefit the State.

Rhode Island↗

Physiographic divisions and differential uplift in the Piedmont and Blue Ridge

The Piedmont and Blue Ridge are dynamic landscapes that have undergone substantial change since the orogenies that ended in late Paleozoic or, as some believe, early Mesozoic time. The southern Blue Ridge region south of Roanoke, Va., lies on the crest of a topographic uplift that corresponds to the eastern continental drainage divide. To the north, this uplift and divide cross the Appalachian Valley and form the crest of the Appalachian Plateaus as far north as central Pennsylvania. The northern Blue Ridge Mountains as well as parts of the Piedmont are on the eastern part of the uplift area. The southeastern margin of the uplift corresponds to a line within the Piedmont physiographic province that extends northeastward from the Tallapoosa River at the Fall Zone and crosses the Rappahannock River at the Fall Zone. The differential elevation on either side of this line is sharp in some places, as, for example, northeast of Atlanta, Ga. In other places, the difference in elevation is difficult to detect, and, in effect, the line becomes a broad monoclinal slope. The region as a whole can be divided into at least six broad subregions that have somewhat different histories in late geologic time. The Piedmont Lowlands subprovince, southeast of the uplifted area, is dominated by a monotonous topography of low rounded ridges and ravines largely underlain by saprolite on crystalline rocks. Isolated ranges of hills of greater relief are scattered across the region; those investigated are directly related to the presence of erosionally resistant rocks. Stream patterns as well as broad topographic forms indicate that although the southern part of the Piedmont Lowlands was probably once covered by younger sediments, this area has been exposed to erosion for a long time. In North Carolina, the inner part of the Piedmont Lowlands has strongly trellised stream patterns, which suggest that subaerial erosion was active for an even longer time period, perhaps since the latest orogeny. North of the Cape Fear River, the outer part of the Piedmont Lowlands was covered by either fluvial or marine sediments or both, probably during Miocene time. Tectonic activity has affected the Piedmont Lowlands in late geologic time. The Fall Zone that forms the southeast border is, at least in places, controlled by faults active in Tertiary time. Late faults have also been found in the Pine Mountain area of Georgia. Minor differences in relief affecting large regions within the Piedmont Lowlands may be related to different rates of uplift in addition to rock resistance, either past or present. The Piedmont northeast of the Potomac River (Northeastern Highlands) rises to more than 300 m in altitude. The major streams have convex profiles that steepen as they near the Coastal Plain. Unusually narrow valleys and broad upland surfaces indicate an increased rate of erosion and show that the relief is now or recently has been increasing because of uplift or tilting. West of the southern end of the Piedmont Lowlands is an area herein called the Southwestern Highlands that in some respects is similar. The area is crossed by two large streams that have convex profiles. The highest mountain ranges in the area rise to altitudes greater than 600 m. Northwest of the Piedmont Lowlands, the topography and relief are higher, and in some places, the rise is gradual, forming a Foothill zone between the Piedmont Lowlands and the high Blue Ridge. This zone is morphologically more complex than the Piedmont Lowlands. North of the Roanoke River, the foothills are commonly chains of isolated hills and ridges generally underlain by resistant rocks. The hills increase in height near the Blue Ridge, an indication that they owe their height to tectonism of late geologic age. South of the Yadkin River, the hills are believed to be residual, the remnants of a larger highland that has been only partially reduced to the lower relief of the general Piedmont surface. The

Professional Paper↗

Assessment of undiscovered oil and gas resources of the East Coast Mesozoic basins of the Piedmont, Blue Ridge Thrust Belt, Atlantic Coastal Plain, and New England Provinces, 2011

During the early opening of the Atlantic Ocean in the Mesozoic Era, numerous extensional basins formed along the eastern margin of the North American continent from Florida northward to New England and parts of adjacent Canada. The basins extend generally from the offshore Atlantic continental margin westward beneath the Atlantic Coastal Plain to the Appalachian Mountains. Using a geology-based assessment method, the U.S. Geological Survey estimated a mean undiscovered natural gas resource of 3,860 billion cubic feet and a mean undiscovered natural gas liquids resource of 135 million barrels in continuous accumulations within five of the East Coast Mesozoic basins: the Deep River, Dan River-Danville, and Richmond basins, which are within the Piedmont Province of North Carolina and Virginia; the Taylorsville basin, which is almost entirely within the Atlantic Coastal Plain Province of Virginia and Maryland; and the southern part of the Newark basin (herein referred to as the South Newark basin), which is within the Blue Ridge Thrust Belt Province of New Jersey. The provinces, which contain these extensional basins, extend across parts of Georgia, South Carolina, North Carolina, Virginia, Maryland, Delaware, Pennsylvania, New Jersey, New York, Connecticut, and Massachusetts.

East Coast Mesozoic Basins↗

Metadata for ReVA logistic regression dataset

The U.S. Geological Survey in cooperation with the U.S. Environmental Protection Agency's Regional Vulnerability Assessment Program, has developed a set of statistical tools to support regional-scale, ground-water quality and vulnerability assessments. The Regional Vulnerability Assessment Program goals are to develop and demonstrate approaches to comprehensive, regional-scale assessments that effectively inform water-resources managers and decision-makers as to the magnitude, extent, distribution, and uncertainty of current and anticipated environmental risks. The U.S. Geological Survey is developing and exploring the use of statistical probability models to characterize the relation between ground-water quality and geographic factors in the Mid-Atlantic Region. Available water-quality data obtained from U.S. Geological Survey National Water-Quality Assessment Program studies conducted in the Mid-Atlantic Region were used in association with geographic data (land cover, geology, soils, and others) to develop logistic-regression equations that use explanatory variables to predict the presence of a selected water-quality parameter exceeding specified management concentration thresholds. The resulting logistic-regression equations were transformed to determine the probability, P(X), of a water-quality parameter exceeding a specified management threshold. Additional statistical procedures modified by the U.S. Geological Survey were used to compare the observed values to model-predicted values at each sample point. In addition, procedures to evaluate the confidence of the model predictions and estimate the uncertainty of the probability value were developed and applied. The resulting logistic-regression models were applied to the Mid-Atlantic Region to predict the spatial probability of nitrate concentrations exceeding specified management thresholds. These thresholds are usually set or established by regulators or managers at national or local levels. At management thresholds of 1 milligram per liter, and 3 milligrams per liter, the probability of nitrate concentrations exceeding these levels is greater than 50 percent (.50) throughout much of the Mid-Atlantic Region. This includes extensive areas throughout central Maryland, southeastern Pennsylvania, northwestern Pennsylvania and the Delmarva Peninsula. In addition, extensive areas in North Carolina and Virginia also have high probabilities of nitrate concentrations in ground water exceeding management thresholds of 1 milligram per liter and 3 milligrams per liter. The mapped areas showing a high predicted probability of nitrate concentrations in ground water exceeding 1 milligram per liter and 3 milligrams per liter correspond to areas that are mapped as cultivated land cover overlying carbonate rocks. At a management threshold of 10 milligrams per liter (corresponding to the U.S. Environmental Protection Agency standard for nitrate in drinking water of 10 milligrams per liter), the predicted probability of nitrate concentrations in ground water exceeding this level are low for most of the Mid-Atlantic Region except for the Delmarva Peninsula, southeastern Pennsylvania, and areas mapped as carbonate rocks in Virginia, Maryland, and Pennsylvania.

Open-File Report↗

Simulation of ground-water flow and areas contributing recharge to extraction wells at the Drake Chemical Superfund Site, City of Lock Haven and Castanea Township, Clinton County, Pennsylvania

Extensive remediation of the Drake Chemical Superfund Site has been ongoing since 1983. Contaminated soils were excavated and incinerated on site between 1996 and 1999. After 1999, remedial efforts focused on contaminated ground water. A ground-water remediation system was started in November 2000. The source area of the contaminated ground water was assumed to be the zone 1 area on the Drake Chemical site. The remedial system was designed to capture ground water migrating from zone 1. Also, the remediation system was designed to pump and treat the water in an anoxic environment and re-infiltrate the treated water underground through an infiltration gallery that is hydrologically downgradient of the extraction wells. A numerical ground-water flow model of the surrounding region was constructed to simulate the areas contributing recharge to remedial extraction wells installed on the Drake Chemical site. The three-dimensional numerical flow model was calibrated using the parameter-estimation process in MODFLOW-2000. The model included three layers that represented three poorly sorted alluvial sediment units that were characterized from geologic well and boring logs. Steady-state ground-water flow was simulated to estimate the areas contributing recharge to three extraction wells for three different pumping scenarios--all wells pumping at 2 gallons per minute, at approximately 5 gallons per minute, and at 8 gallons per minute. Simulation results showed the contributing areas to the three extraction wells encompassed 92 percent of zone 1 at a pumping rate of approximately 5 gallons per minute. The contributing areas did not include a very small area in the southwestern part of zone 1 when the three extraction wells were pumped at approximately 5 gallons per minute. Pumping from a fourth extraction well in that area was discontinued early in the operation of the remediation system because the ground water in that area met performance standards. The areas contributing recharge to the three extraction wells did encompass zone 1 at a pumping rate of 8 gallons per minute. At pumping rates of 2 gallons per minute, the contributing areas for the three extraction wells did not encompass zone 1.

Pennsylvania↗

Water resources and shale gas/oil production in the Appalachian Basin: critical issues and evolving developments

Unconventional natural gas and oil resources in the United States are important components of a national energy program. While the Nation seeks greater energy independence and greener sources of energy, Federal agencies with environmental responsibilities, state and local regulators and water-resource agencies, and citizens throughout areas of unconventional shale gas development have concerns about the environmental effects of high volume hydraulic fracturing (HVHF), including those in the Appalachian Basin in the northeastern United States (fig. 1). Environmental concerns posing critical challenges include the availability and use of surface water and groundwater for hydraulic fracturing; the migration of stray gas and potential effects on overlying aquifers; the potential for flowback, formation fluids, and other wastes to contaminate surface water and groundwater; and the effects from drill pads, roads, and pipeline infrastructure on land disturbance in small watersheds and headwater streams (U.S. Government Printing Office, 2012). Federal, state, regional and local agencies, along with the gas industry, are striving to use the best science and technology to develop these unconventional resources in an environmentally safe manner. Some of these concerns were addressed in U.S. Geological Survey (USGS) Fact Sheet 2009–3032 (Soeder and Kappel, 2009) about potential critical effects on water resources associated with the development of gas extraction from the Marcellus Shale of the Hamilton Group (Ver Straeten and others, 1994). Since that time, (1) the extraction process has evolved, (2) environmental awareness related to high-volume hydraulic fracturing process has increased, (3) state regulations concerning gas well drilling have been modified, and (4) the practices used by industry to obtain, transport, recover, treat, recycle, and ultimately dispose of the spent fluids and solid waste materials have evolved. This report updates and expands on Fact Sheet 2009–3032 and presents new information regarding selected aspects of unconventional shale gas development in the Appalachian Basin (primarily Virginia, West Virginia, Maryland, Pennsylvania, Ohio, and New York). This document was prepared by the USGS, in cooperation with the U.S. Department of Energy, and reviews the evolving technical advances and scientific studies made in the Appalachian Basin between 2009 and the present (2013), addressing past and current issues for oil and gas development in the region.

Maryl;New York;Ohio;Pennsylvania;Virginia;West Vir↗

Statistical summaries of New Jersey streamflow records

In 1961 the U.S. Geological Survey prepared a report which was published by the State of New Jersey as Water Resources Circular 6, "New Jersey Streamflow Records analyzed with Electronic Computer" by Miller and McCall. Basic discharge data for periods of record through 1958 were analyzed for 59 stream-gaging stations in New Jersey and flow-duration, low-flow, and high-flow tables were presented. The purpose of the current report is to update and expand Circular 6 by presenting, with a few meaningful statistics and tables, the bulk of the information that may be obtained from the mass of streamflow records available. The records for 79 of approximately 110 stream-gaging stations presently or previously operated in New Jersey, plus records for three stations in Pennsylvania, and one in New York are presented in summarized form. In addition to inclusing a great number of stations in this report, more years of record and more tables are listed for each station. A description of the station, three arrangements of data summarizing the daily flow records and one table listing statistics of the monthly mean flows are provided. No data representing instantaneous extreme flows are given. Plotting positions for the three types of curves describing the characteristics of daily discharge are listed for each station. Statistical parameters are also presented so that alternate curves may be drawn. All stations included in this report have 5 or more years of record. The data presented herein are based on observed flow past the gaging station. For any station where the observed flow is affected by regulation or diversion, a "Remarks" paragraph, explaining the possible effect on the data, is included in the station description. Since any streamflow record is a sample in time, the data derived from these records can provide only a guide to expected future flows. For this reason the flow records are analyzed by statistical techniques, and the magnitude of sampling errors should be recognized. These analyzed data will be useful to a large number of municipal, state, and federal agencies, industries, utilities, engineers, and hydrologists concerned with the availability, conservation, control, and use of surface waters. The tabulated data and curves illustrated herein can be used to select sites for water supplies, to determine flood or drought storage requirements, and to appraise the adequacy of flows for dilution of wastes or generation of power. The statistical values presented herein can be used in computer programs available in many universities, Federal and State agencies, and engineering firms for a broad spectrum of research and other studies.

New Jersey↗