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This note reviews the nature of the traditional (Mädler) lunar nomenclature and the recent developments based on the use of more than 2000 named provinces. It appears that the new nomenclature is less efficient than the old in many cases and may lead to an impossible publication situation. The unnecessary break with the past is especially critized.
The Pliocene and Pleistocene deposits of the Spanish Ebro margin overlie a regional unconformity and contain a major disconformity. These unconformities, named Reflector M and Reflector G, mark the bases of two seismic sequences. Except for close to the upper boundary where a few small channel deposits are recognized, the lower sequence lacks channels. The upper sequence contains nine channel-levee complexes as well as base-of-slope aprons that represent the proximal part of the Valencia turbidite system. Diverse geometries and variations in seismic units distinguish shelf, slope, base-of-slope and basin-floor facies. Four events characterize the late Miocene to Pleistocene evolution of the Ebro margin: (a) formation of a paleodrainage system and an extensive erosion-to-depositional surface during the latest Miocene (Messinian), (b) deposition of hemipelagic units during the early Pliocene, (c) development of canyons during the late Pliocene to early Pleistocene, and (d) deposition of slope wedges, channel-levee complexes, and base-of-slope aprons alternating with hemipelagic deposition during the Pleistocene. Sea-level fluctuations influenced the evolution of the sedimentary sequences of the Ebro margin, but the major control was the sediment supply from the Ebro River.
Despite the Arctic sea ice cover's recognized sensitivity to environmental change, the role of sediment inclusions in lowering ice albedo and affecting ice ablation is poorly understood. Sea ice sediment inclusions were studied in the central Arctic Ocean during the Arctic 91 expedition and in the Laptev Sea (East Siberian Arctic Region Expedition 1992). Results from these investigations are here combined with previous studies performed in major areas of ice ablation and the southern central Arctic Ocean. This study documents the regional distribution and composition of particle-laden ice, investigates and evaluates processes by which sediment is incorporated into the ice cover, and identifies transport paths and probable depositional centers for the released sediment. In April 1992, sea ice in the Laptev Sea was relatively clean. The sediment occasionally observed was distributed diffusely over the entire ice column, forming turbid ice. Observations indicate that frazil and anchor ice formation occurring in a large coastal polynya provide a main mechanism for sediment entrainment. In the central Arctic Ocean sediments are concentrated in layers within or at the surface of ice floes due to melting and refreezing processes. The surface sediment accumulation in central Arctic multi-year sea ice exceeds by far the amounts observed in first-year ice from the Laptev Sea in April 1992. Sea ice sediments are generally fine grained, although coarse sediments and stones up to 5 cm in diameter are observed. Component analysis indicates that quartz and clay minerals are the main terrigenous sediment particles. The biogenous components, namely shells of pelecypods and benthic foraminiferal tests, point to a shallow, benthic, marine source area. Apparently, sediment inclusions were resuspended from shelf areas before and incorporated into the sea ice by suspension freezing. Clay mineralogy of ice-rafted sediments provides information on potential source areas. A smectite maximum in sea ice sediment samples repeatedly occurred between 81°N and 83°N along the Arctic 91 transect, indicating a rather stable and narrow smectite rich ice drift stream of the Transpolar Drift. The smectite concentrations are comparable to those found in both Laptev Sea shelf sediments and anchor ice sediments, pointing to this sea as a potential source area for sea ice sediments. In the central Arctic Ocean sea ice clay mineralogy is significantly different from deep-sea clay mineral distribution patterns. The contribution of sea ice sediments to the deep sea is apparently diluted by sedimentary material provided by other transport mechanisms.
Outcrops of an ash bed at several localities in northern California and western Nevada belong to a single air-fall ash layer, the informally named Rockland ash bed, dated at about 400,000 yr B.P. The informal Rockland pumice tuff breccia, a thick, coarse, compound tephra deposit southwest of Lassen Peak in northeastern California, is the near-source equivalent of the Rockland ash bed. Relations between initial thickness of the Rockland ash bed and distances to eruptive source suggest that the eruption was at least as great as that of the Mazama ash from Crater Lake, Oregon. Identification of the Rockland tephra allows temporal correlation of associated middle Pleistocene strata of diverse facies in separate depositional basins. Specifically, marine, littoral, estuarine, and fluvial strata of the Hookton and type Merced formations correlate with fluvial strata of the Santa Clara Formation and unnamed alluvium of Willits Valley and the Hollister area, in northwestern and west-central California, and with lacustrine beds of Mohawk Valley, fluvial deposits of the Red Bluff Formation of the eastern Sacramento Valley, and fluvial and glaciofluvial deposits of Fales Hot Spring, Carson City, and Washoe Valley areas in northeastern California and western Nevada. Stratigraphic relations of the Rockland ash bed and older tephra layers in the Great Valley and near San Francisco suggest that the southern Great Valley emerged above sea level about 2 my ago, that its southerly outlet to the ocean was closed sometime after about 2 my ago, and that drainage from the Great Valley to the ocean was established near the present, northerly outlet in the vicinity of San Francisco Bay about 0.6 my ago. ?? 1985.
Multifrequency airborne radar image data of SP Mountain [Official name of feature (U.S. Geological Survey, 1970)] and SP flow (and vicinity) in north-central Arizona were obtained in diverse viewing directions and direct and cross-polarization, then compared with surface and aerial photography, LANDSAT multispectral scanner data, airborne thermal infrared imagery, surface geology, and surface roughness statistics. The extremely blocky, basaltic andesite of SP flow is significantly brighter on direct-polarization K-band (0.9-cm wavelength) images than on cross-polarized images taken simultaneously. Conversely, for the longer wavelength (25 cm) L-band radar images, the cross-polarization image returns from SP flow are brighter than the direct-polarized image. This effect is explained by multiple scattering and the strong wavelength dependence of polarization effects caused by the rectilinear basaltic andesite scatters. Two distinct types of surface relief on SP flow, one extremely blocky, the other subdued, are found to be clearly discriminated on the visible and thermal wavelength images but are separable only on the longer wavelength L-band radar image data. The inability of the K- and X- (3-cm wavelength) band radars to portray the differences in roughness between the two SP flow surface units is attributed to the radar frequency dependence of the surface-relief scale, which, described as the Rayleigh criterion, represents the transition between quasispecular and primarily diffuse backscatter.
The use of multispectral reflectance data as surrogates for land attributes must be done within strict rules of logic and with a recognition of judgmental factors such as the use of a priori or a posteriori classification schemes. The naming and describing of spectral classes as surrogates of information classes is a critical element in the logic of mapping and must be complete and logically consistent. Maps of information classes derived from multispectral data should be portrayed without class boundaries so as to indicate the degree of homogeneity or heterogeneity of classes on maps in which these characteristics are of major importance.
Sideritic lacustrine mudstone was found in drill core from a uranium deposit in the Death Valley area in the eastern part of the Seward Peninsula, Alaska. The precursor sediments for this rock were deposited in an unusual “iron-meromictic” Eocene lake, herein named Lake Tubutulik, which occupied part of the Boulder Creek basin, a structural graben that is probably a southern extension of the larger Death Valley basin. The Boulder Creek basin is bounded on the west by granite of the Late Cretaceous Darby Pluton, on the east by Precambrian to Paleozoic metasedimentary rocks. The lake basin was formed by basaltic flows that dammed the river valley of the ancestral Tubutulik River in early Eocene time. Lake Tubutulik contained a nearshore facies of fine-grained organic mud and an offshore facies of laminated sideritic mud. The offshore (profundal) laminated mudstone consists of alternating layers of authigenic siderite and detrital layers containing mostly quartz and clay minerals. Both lacustrine facies contain turbidities. The lacustrine sediments graded laterally into an onshore facies of colluvial and fluvial sandstone, paludal mudstone, and coal. The ancient lake apparently occupied a small deep basin in a tectonically active area of high relief. Meromixus was probably stabilized by reduced iron and bicarbonate dissolved in the monimolimnion. The intensity of meromixus decreased as the lake became shallower from sediment filling. The source of the iron, abundant in the monimolimnion of Lake Tubutulik, was probably the Eocene basalt. Based on carbon isotope analysis of the siderite, the dissolved bicarbonate in the profundal facies was largely inorganic. Sideritic carbon in one sample from the onshore paludal facies has an isotopic signature ( δ 13 C = +16.9) consistent with residual carbon formed during methanogenic fermentation.
The U.S. Geological Survey's Office of Resource Analysis is developing computer methods for the handling of mineral-resources data in order to provide improved means for addressing and manipulating data. These methods include: computerized data files and predictive resource models. Data files contain the raw or disaggregated information on mineral deposits and commodities. One operational data file is CRIB (Computerized Resources Information Bank) which is a general purpose inventory and reference file on metallic and nonmetallic mineral deposits. A computer file on resources should contain detailed information on the following main categories: record identification, name and location, description of deposit, analytical data, and production/reserves. A resource model employs postulates and inferences in conjunction with the data to make predictions about resources-as key variables concerning a mineral commodity are changed. The objective is to estimate the availability of minerals including: geological availability (occurrence models), technological availability (exploration and beneficiation models), and economic availability (economics models). ?? 1976.
In assessing the errors involved in reconstructing tectonic plate rotations, it is desirable to have confidence regions for the unknown rotation. This paper presents a method for graphing such confidence regions, which exhibits the dependence of the range of possible angles of rotation on the axis considered. Namely, the minimum and maximum angles of rotation are graphed as functions of axis longitude and latitude. A FORTRAN 77 program SPHEREREGRESS is given which, under a variety of probabilistic models for the data, generates grid matrices which are used to draw contour maps of the minimum and maximum angles of rotation. ?? 1990.
A general risk-analysis method was developed for petroleum-resource assessment and other applications. The triangular probability distribution is used as a model with an analytic aggregation methodology based on probability theory rather than Monte-Carlo simulation. Among the advantages of the analytic method are its computational speed and flexibility, and the saving of time and cost on a microcomputer. The input into the model consists of a set of components (e.g. geologic provinces) and, for each component, three potential resource estimates: minimum, most likely (mode), and maximum. Assuming a triangular probability distribution, the mean, standard deviation, and seven fractiles (F100, F95, F75, F50, F25, F5, and F0) are computed for each component, where for example, the probability of more than F95 is equal to 0.95. The components are aggregated by combining the means, standard deviations, and respective fractiles under three possible siutations (1) perfect positive correlation, (2) complete independence, and (3) any degree of dependence between these two polar situations. A package of computer programs named the TRIAGG system was written in the Turbo Pascal 4.0 language for performing the analytic probabilistic methodology. The system consists of a program for processing triangular probability distribution assessments and aggregations, and a separate aggregation routine for aggregating aggregations. The user's documentation and program diskette of the TRIAGG system are available from USGS Open File Services. TRIAGG requires an IBM-PC/XT/AT compatible microcomputer with 256kbyte of main memory, MS-DOS 3.1 or later, either two diskette drives or a fixed disk, and a 132 column printer. A graphics adapter and color display are optional. ?? 1991.
We studied peat in several geologic and climatic settings: (1) a glaciated terrain in cold-temperate Maine and Minnesota, U.S.A.; (2) an island in a temperate maritime climate in the Atlantic Ocean off the coast of Maine, U.S.A., where sea level is rising rapidly and changing the environment of peat accumulation; (3) swamps along the warm-temperate U.S. Atlantic and Gulf Coastal Plains, where sea level has changed often, thus creating sites for accumulation; and (4) in a tropical climate along the coast of Sarawak, Malaysia, and the delta of the Batang Hari River, Sumatra, Indonesia (Figs. 1 and 2). With the exception of the deposits on the Atlantic and Gulf Coastal Plains, most of the deposits described are domed bogs in which peat accumulation continued above the surface of the surrounding soil. The bogs of the U.S. Atlantic and Gulf Coastal Plains have almost level surfaces. All domed bogs are not entirely ombrotrophic (watered only from precipitation); multidomed bogs that rise from irregular or hilly surfaces may be crossed by streams that supply water to the bogs. The geologic processes or organic sedimentation, namely terrestrialization and paludification, are similar in all peat deposits considered here. Differences in geomorphology affecting the quantity and that quality of peat that has ash contents of less than 25%, which are desirable for commercial purposes, depend chiefly on: (1) high humidity, which is favorable to luxuriant growth of peat-forming vegetation; (2) a depositional setting that permits extensive accumulation relatively free from inorganic contamination from sea water and streams and from dust and volcanic ash; and (3) a stable regional water table that controls the rate of decomposition under aerobic conditions and protects the deposit against the ravages of fire. Differences in peat textures are due to the type of vegetation and to the degree of decomposition. The rate of decomposition is largely the result of the amount of oxidation and aerobic microbial activity. Stratigraphic distribution of various textures and amounts of inorganic components within a peat deposit is largely determined by the vertical positions occupied by peat-forming environments, such as pond, marsh, swamp and heath where vegetation accumulated, and the depth to zones of unoxygenated water. Peat also differs in the rate of accumulation. On the basis of carbon-14 dating, an estimated 8 m of peat in the tropical Batang Hari River deposit in Sumatra has been accumulating at the rate of about 1.5 m/1,000 yr, whereas peat in the cold-temperate deposit in Maine has been accumulating at the rate of 0.66 m/1,000 yr. Accumulation rates in domed deposits such as these are affected not only by factors controlling volume of biomass and aerobic decay but also by stream erosion and fires that remove peat. Such disconformities (see Fig. 2) within the deposit may be recognized by sudden vertical changes in degree of decomposition and/or the presence of charcoal. The trace-element content of peat deposits is affected by the environments of their settings. Samples of peat that have an ash content of less than 25% dry weight and that are from small, almost level swamp deposits along the Atlantic Coastal Plain of North Carolina were compared with similar samples from small domed bogs in Maine, a glaciated area. Samples from Nort Carolina, which are from deposits in thick fluvial and nearshore marine sediments far from the bedrock source, are generally higher in Ti, Cr and Pb. The Maine samples from deposits in glacial drift close to the bedrock source contain more Zn, Mn, P, Ca, Na and Fe. The kind and amount of trace elements within the deposits appear to relate largely to depositional setting, to kinds of bedrock source, and to the modes of transportation from source to peat swamp. Trace-element concentrations in the extensive Sumatra peat deposit, which represents a potentially commercial coal bed, are similar to those found in Appalachian coals except for As and Au, which are higher in the former. This similarity most likely implies that geochemical controls on mineral matter controlled the concentrations in both. Most peat deposits found in the world today are not precursors of economic coal beds because they are too local in extent, lack beds of commercial-quality peat greater than 6 m thick, and/or are too far from sea level to be rapidly by marine or marginal marine sediments before destruction by erosion and decomposition. However, the two domed deposits in Sarawak and Sumatra described above are parts of extensive, thick, low-sulfur, fuel-quality peat deposits, which have bases below the levels of rivers on coastal deltas. These are likely to be preserved in their lower part and to become precursors of tropical coal seams of potential economic importance. The lenticular and tabular peat deposits of the Atlantic and Gulf Coastal Plains, which have little chance of survival, have features resembling those in Tertiary peat deposits in alluvial settings of western North America. The quality, shape, and extent of modern and ancient peat deposits are controlled by the same factors - humidity, vegetation type, ground- and surface-water regimes, and physiographic and geologic setting. Thus, a study of modern peat deposits may help in studies of the areal distribution and the thickness and quality of ancient coal beds.
West Virginia is the only place in the United States where an entire section of Pennsylvanian age (Upper Carboniferous) strata can be seen. These strata occur within a wedge of rock that thins to the north and west from the southeastern part of the State. The progressive north-northwesterly termination of older Pennsylvanian geologic units beneath younger ones prominently outlines the center of the Appalachian basin of West Virginia. Over most of West Virginia, Lower and/or Middle Pennsylvanian strata unconformably overly Upper Mississippian (Lower Carboniferous) strata. Sediment deposition was accomplished by a complex system of deltas prograding north and west from an eastern and southeastern source area. More than 100 named coal beds occur within the Lower, Middle, and Upper Pennsylvanian rocks of West Virginia and at least 60 of these have been or are currently being mined commercially. Collectively, these coal beds account for original in-ground coal resources of almost 106.1×10 9 t (117×10 9 tons). West Virginia ranks fourth in the United States in demonstrated coal reserves. In 1988, West Virginia produced 131.4×10 6 t (144.9×10 6 T) of coal, third highest in the United States. Of this annual production, 75% was from underground mines. In 1988, West Virginia led the nation in the number of longwall mining sections currently in place. West Virginia's low-volatile coal beds are known worldwide as important metallurgical-grade coals, while the higher-volatile coal beds are utilized primarily for steam production.
The nucleotide sequences of the glycoprotein genes and all of the internal gene junctions of the fish pathogenic rhabdoviruses spring viremia of carp virus (SVCV) and hirame rhabdovirus (HIRRV) have been determined from cDNA clones generated from viral genomic RNA. The SVCV glycoprotein gene sequence is 1588 nucleotides (nt) long and encodes a 509 amino acid (aa) protein. The HIRRV glycoprotein gene sequence comprises 1612 nt, coding for a 508 aa protein. In sequence comparisons of 15 rhabdovirus glycoproteins, the SVCV glycoprotein gene showed the highest amino acid sequence identity (31.2-33.2%) with vesicular stomatitis New Jersey virus (VSNJV), Chandipura virus (CHPV) and vesicular stomatitis Indiana virus (VSIV). The HIRRV glycoprotein gene showed a very high amino acid sequence identity (74.3%) with the glycoprotein gene of another fish pathogenic rhabdovirus, infectious hematopoietic necrosis virus (IHNV), but no significant similarity with glycoproteins of VSIV or rabies virus (RABV). In phylogenetic analyses SVCV was grouped consistently with VSIV, VSNJV and CHPV in the Vesiculovirus genus of Rhabdoviridae. The fish rhabdoviruses HIRRV, IHNV and viral hemorrhagic septicemia virus (VHSV) showed close relationships with each other, but only very distant relationships with mammalian rhabdoviruses. The gene junctions are highly conserved between SVCV and VSIV, well conserved between IHNV and HIRRV, but not conserved between HIRRV/IHNV and RABV. Based on the combined results we suggest that the fish lyssa-type rhabdoviruses HIRRV, IHNV and VHSV may be grouped in their own genus within the family Rhabdoviridae. Aquarhabdovirus has been proposed for the name of this new genus.
This paper describes catastrophic eruptions of Mount St. Helens (1980), Bezymianny (1955–1956), and Shiveluch (1964) volcanoes. A detailed description of eruption stages and their products, as well as the quantitative characteristics of the eruptive process are given. The eruptions under study belong to the directed-blast type. This type is characterized by the catastrophic character of the climatic stage during which a directed blast, accompanied by edifice destruction, the profound ejection of juvenile pyroclastics and the formation of pyroclastic flows, occur. The climatic stage of all three eruptions has similar characteristics, such as duration, kinetic energy of blast (10 17 −10 18 J), the initial velocity of debris ejection, morphology and size of newly-formed craters. But there are also certain differences. At Mount St. Helens the directed blast was preceeded by failure of the edifice and these events produced separable deposits, namely debris avalanche and directed blast deposits which are composed of different materials and have different volumes, thickness and distribution. At Bezymianny, failure did not precede the blast and the whole mass of debris of the old edifice was outburst only by blast. The resulting deposits, represented by the directed blast agglomerate and sand facies, have characteristics of both the debris avalanche and the blast deposit at Mount St. Helens. At Shiveluch directed-blast deposits are represented only by the directed-blast agglomerate; the directed-blast sand facies, or blast proper, seen at Mount St. Helens is absent. During the period of Plinian activity, the total volumes of juvenile material erupted at Mount St. Helens and at Besymianny were roughly comparable and exceeded the volume of juvenile material erupted at Shiveluch, However, the volume of pyroclastic-flow deposits erupted at Mount St. Helens was much less. The heat energy of all three eruptions is comparable: 1.3 × 10 18 , 3.8−4.8 × 10 18 and 1 × 10 17 J for Shiveluch, Bezymianny, and Mount St. Helens, respectively.
A floristic summary and analysis was performed on a list of the plant species that have been studied for the effects of gaseous and chemical air pollutants on vegetation in order to compare the species with the flora of North America north of Mexico. The scientific names of 2081 vascular plant species were extracted from almost 4000 journal articles stored in two large literature databases on the effects of air pollutants on plants. Three quarters of the plant species studied occur in North America, but this was only 7% of the total North American flora. Sixteen percent and 56% of all North American genera and families have been studied. The most studied genus is Pinus with 70% of the North American species studied, and the most studied family is the grass family, with 12% of the species studied. Although Pinus is ranked 86th in the North American flora, the grass family is ranked third, indicating that representation at the family level is better than at the genus level. All of the top ten families in North America are represented in the top 20 families in the air pollution effects literature, but only one genus ( Lupinus ) in the top ten genera in North America is represented in the top thirteen genera in the air pollution literature.
Spatial and temporal variations in net above-ground primary production (NPP) and litter turnover rate were studied, from 1987 to 1993, in a mangrove forest bordering Laguna de Terminos, Mexico. NPP, the sum of total litter fall and wood production, was measured over the entire study period in three zones in a basin forest: zone I, where Rhizophora mangle (red mangrove) occurs but Avicennia germinans (black mangrove) is the dominant species; zone II, a scrub forest of A. germinans ; zone III, where larger A. germinans trees occur. In 1991, a fringe zone dominated by A. germinans and R. mangle was added to the study. Three distinctive climatic seasons occur in the region: rainy, dry, and cold front (locally named ‘nortes’). Average total litter fall in the fringe zone (793 g m −2 year −1 ) was significantly higher than in the basin forest (496, 307, and 410 g m −2 year −1 for basin zones I, II, and III, respectively). All zones showed significant differences among seasons with the norte season having significantly lower litter fall. Litter turnover rates were about 7 months in zones I and II and 10 months in zone III, reflecting the low tidal range that occurs in the basin forest. Low litter turnover rates in the basin forest were reflected in a high organic matter standing crop. Annual average stem growth was significantly higher in zones I and III (1.27 and 1.36 kg per tree year −1 , respectively) than in zone II (0.62 kg per tree year −1 ). Above-ground NPP rates in the basin forest (399–695 g m −2 year −1 ) were lower than in fringe and riverine forests, reflecting patterns of litter fall and wood production. There was no seasonal variation in soil salinity but the basin forest had significantly higher soil salinity than the fringe forest. Spatially, mean soil salinity was inversely related to litter fall. Long-term patterns in soil salinity, precipitation and air temperature explained 74% of the inter-annual litter fall variability. Over the 7 year study, productivity in zone II was more variable than in zones I and III, and productivity (litter fall and wood growth) were less variable than litter standing crop and turnover.
A reconnaissance geochemical survey was conducted in the southern Killik River quadrangle, central Brooks Range, northern Alaska. The Brooks Range lies within the zone of continuous permafrost which may partially inhibit chemical weathering and oxidation. The minus 30-mesh and nonmagnetic heavy-mineral concentrate fractions of sediment samples were chosen as the sample media for the survey so that mechanical rather than chemical dispersion patterns would be enhanced. A total of 263 sites were sampled within the southern half of the Killik River quadrangle at an average sample density of approximately one sample per 12 km 2 . All samples were submitted for multi-element analyses. In the western and central Brooks Range, several known sediment-hosted Zn-Pb-Ag(-Ba) deposits occur within a belt of Paleozoic rocks of the Endicott Mountains allochthon. Exploration for this type of deposit in the Brook Range is difficult, due to the inherently high background values for Ba, Zn and Pb in shale and the common occurrence of metamorphic quartz-calcite veins, many of which contain traces of sulfide minerals. Stream sediments derived from these sources produce numerous geochemical anomalies which are not necessarily associated with significant mineralization. R-mode factor analysis provides a means of distinguishing between element associations related to lithology and those related to possible mineralization. Factor analysis applied to the multi-element data from the southern Killik River quadrangle resulted in the discovery of two additional Zn-Pb-Ag mineral occurrences of considerable areal extent which are 80–100 km east of any previously known deposit. These have been informally named the Kady and Vidlee. Several lithogeochemical element associations, or factors, and three factors which represent sulfide mineralization were identified: Ag-Pb-Zn (galena and sphalerite) and Fe-Ni-Co-Cu (pyrite ± chalcopyrite) in the concentrate samples and Cd-Zn-Pb-As-Mn in the sediment samples. The distribution of high scores for each individual mineralization factor outlined several relatively large (200–250 km 2 ) geochemically favorable areas. When the distribution of high scores for all three factors were superimposed, samples characterized by high scores for one or both of the concentrate mineralization factors and the mineralization factor in sediments define basin areas of approximately 48 and 64 km 2 surrounding Kady and Vidlee, respectively.
The Pinal creek drainage basin in Arizona is a good example of the principal non-coal source of mining-related acid drainage in the U.S.A., namely copper mining. Infiltration of drainage waters from mining and ore refining has created an acid groundwater plume that has reacted with calcite during passage through the alluvium, thereby becoming less acid. Where O 2 is present and the water is partially neutralized, iron oxides have precipitated and, farther downstream where the pH of the stream water is near neutral, high-Mn crusts have developed. Trace metal composition of several phases in the Pinal Creek drainage basin illustrates the changes caused by mining activities and the significant control Mn-crusts and iron oxide deposits exert on the distribution and concentration of trace metals. The phases and locales considered are the dissolved phase of Webster Lake, a former acid waste disposal pond; selected sections of cores drilled in the alluvium within the intermittent reach of Pinal Creek; and the dissolved phase, suspended sediments, and streambed deposits at specified locales along the perennial reach of Pinal creek. In the perennial reach of Pinal Creek, manganese oxides precipitate from the streamflow as non-cemented particulates and coatings of streambed material and as cemented black crusts. Chemical and X-ray diffraction analyses indicate that the non-cemented manganese oxides precipitate in the reaction sequence observed in previous laboratory experiments using simpler solution composition, Mn 3 O 4 to MnOOH to an oxide of higher oxidation number usually <4.0, i.e. Na-birnessite, and that the black cemented crusts contain (Ca,Mn,Mg)CO 3 and a 7-Åphyllomanganate mixture of rancieite ((Ca,Mn)Mn 4 O 9 · (3H 2 O)) and takanelite ((Mn,Ca)Mn 4 O 9 · (3H 2 O)). In the laboratory, aerating and increasing the pH of Pinal Creek water to 9.00 precipitated (Ca,Mn,Mg)CO 3 from an anoxic groundwater that contained CO 2 HCO 3 , and precipitated Mn 3 O 4 and subsequently MnOOH from an oxic surface water from which most of the dissolved CO 2 had been removed. It is suggested that the black cemented crusts form by precipitation of Fe on the Mn-enriched carbonates, creating a site for the Mn Fe oxidation cycle and thus encouraging the conversion of the carbonates to 7-Åphysllomanganates. The non-magnetic <63-μm size-fractions of the black cemented crusts consisted mostly of the manganese-calcium oxides but also contained about 20% (Ca,Mn,Mg)CO 3 , 5% Fe (calculated as FeOOH), 2–4% exchangeable cations, and trace amounts of several silicates.