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USGS2005

Ground-water modeling of pumping effects near regional ground-water divides and river/aquifer systems - Results and implications of numerical experiments

Agreements between United States governors and Canadian territorial premiers establish water-management principles and a framework for protecting Great Lakes waters, including ground water, from diversion and consumptive uses. The issue of ground-water diversions out of the Great Lakes Basin by large-scale pumping near the divides has been raised. Two scenario models, in which regional ground-water flow models represent major aquifers in the Great Lakes region, were used to assess the effect of pumping near ground-water divides. The regional carbonate aquifer model was a generalized model representing northwestern Ohio and northeastern Indiana; the regional sandstone aquifer model used an existing calibrated ground-water flow model for southeastern Wisconsin. Various well locations and pumping rates were examined. Although the two models have different frameworks and boundary conditions, results of the models were similar. There was significant diversion of ground water across ground-water divides due to pumping within 10 miles of the divides. In the regional carbonate aquifer model, the percentage of pumped water crossing the divide ranges from about 20 percent for a well 10 miles from the divide to about 50 percent for a well adjacent to the divide. In the regional sandstone aquifer model, the percentages range from about 30 percent for a well 10 miles from the divide to about 50 percent for a well adjacent to the divide; when pumping on the west side of the divide, within 5 mi of the predevelopment divide, results in at least 10 percent of the water being diverted from the east side of the divide. Two additional scenario models were done to examine the effects of pumping near rivers. Transient models were used to simulate a rapid stage rise in a river during pumping at a well in carbonate and glacial aquifers near the river. Results of water-budget analyses indicate that induced infiltration, captured streamflow, and underflow were important for both glacial and carbonate aquifers; however, in many cases, traveltimes from the river to the well will limit river water from physically entering the well.

Scientific Investigations Report↗

USGS1995

Hydrogeology, simulated ground-water flow, and ground-water quality at two landfills in Bristol, Vermont

A study was done to describe the hydrogeology of unconsolidated deposits, simulated ground-water flow, and ground-water quality at two landfills in Bristol, Vermont. The study area is characterized by a glacial delta greater than 200 feet thick on the west flank of the Green Mountains. An upper unconfined, coarse-grained glacial aquifer and a lower fine-grained glacial aquifer are separated throughout most of the study area by a sand, silt, and clay confining unit. A two-layer ground-water flow model was designed and calibrated to estimate ground-water-flow paths form the aquifers beneath the landfills. Large upward head gradients of 0.03 to 0.30 foot per foot are the result of ground water leaking from the underlying bedrock aquifer, which caused ground-water flow to concentrate in the upper aquifer. Most simulated ground-water-flow paths in the lower glacial aquifer beneath the landfills crossed into the upper aquifer. Simulated ground- water-flow paths in the upper aquifer, beneath the landfills, remained in the upper aquifer. Ground water characterized as landfill leachate, or influenced by landfill leachate, has a median specific conductance of 700 microseimens per centimeter at 25 degrees Celsius. Landfill leachate contained mean concentrations 1.5 to 10 times the background concentrations of common constituents and metals, including calcium, potassium, sodium, chloride, iron, magnesium, and manganese. Trace metals detected in the leachate included copper, nickel, zinc, cobalt, lead, and arsenic. Ten volatile organic compounds were found at four observation wells associated with one landfill and three volatile organic compounds were found at two observation wells associated with the record landfill. No one volatile organic compound was consistently found and detections were generally at or near detection limits.

Water-Resources Investigations Report↗

USGS2003

Estimated Ground-Water Withdrawals from the Death Valley Regional Flow System, Nevada and California, 1913-98

Ground-water withdrawals from 1913 through 1998 from the Death Valley regional flow system have been compiled to support a regional, three-dimensional, transient ground-water flow model. Withdrawal locations and depths of production intervals were estimated and associated errors were reported for 9,300 wells. Withdrawals were grouped into three categories: mining, public-supply, and commercial water use; domestic water use; and irrigation water use. In this report, groupings were based on the method used to estimate pumpage. Cumulative ground-water withdrawals from 1913 through 1998 totaled 3 million acre-feet, most of which was used to irrigate alfalfa. Annual withdrawal for irrigation ranged from 80 to almost 100 percent of the total pumpage. About 75,000 acre-feet was withdrawn for irrigation in 1998. Annual irrigation withdrawals generally were estimated as the product of irrigated acreage and application rate. About 320 fields totaling 11,000 acres were identified in six hydrographic areas. Annual application rates for high water-use crops ranged from 5 feet in Penoyer Valley to 9 feet in Pahrump Valley. The uncertainty in the estimates of ground-water withdrawals was attributed primarily to the uncertainty of application rate estimates. Annual ground-water withdrawal was estimated at about 90,000 acre-feet in 1998 with an assigned uncertainty bounded by 60,000 to 130,000 acre-feet.

Water-Resources Investigations Report↗

USGS2003

Questa baseline and pre-mining ground-water quality investigation. 3. Historical ground-water quality for the Red River Valley, New Mexico

Historical ground-water quality data for 100 wells in the Red River Valley between the U.S. Geological Survey streamflow-gaging station (08265000), near Questa, and Placer Creek east of the town of Red River, New Mexico, were compiled and reviewed. The tabulation included 608 water-quality records from 23 sources entered into an electronic database. Groundwater quality data were first collected at the Red River wastewater-treatment facility in 1982. Most analyses, however, were obtained between 1994 and 2002, even though the first wells were developed in 1962. The data were evaluated by considering (a) temporal consistency, (b) quality of sampling methods, (c) charge imbalance, and (d) replicate analyses. Analyses that qualified on the basis of these criteria were modeled to obtain saturation indices for gypsum, calcite, fluorite, gibbsite, manganite, and rhodocrosite. Plots created from the data illustrate that water chemistry in the Red River Valley is predominantly controlled by calcite dissolution, congruent gypsum dissolution, and pyrite oxidation.

New Mexico↗

USGS2001

Hydrogeology, model description, and flow analysis of the Mississippi River alluvial aquifer in northwestern Mississippi

The Mississippi River alluvial aquifer underlies a 7,000-square-mile area of the Mississippi River alluvial plain in northwestern Mississippi, an area locally known as the Delta. The alluvial aquifer is the most heavily pumped aquifer in Mississippi, and wells yielding more than 2,000 gallons per minute are common. About 98 percent of the pumpage from the alluvial aquifer is for agriculture. The sand and gravel that form the alluvial aquifer averages about 110 feet in thickness. The aquifer is confined over most of the Delta, and the upper confining unit averages about 25 feet in thickness. The average depth to water in the alluvial aquifer during fall 1999 was about 25 feet. The alluvial aquifer receives lateral recharge at the western boundary from the Mississippi River and at the eastern boundary from aquifers that directly underlie the Bluff Hills. The alluvial aquifer receives water vertically from precipitation, internal streams and lakes, and locally from the Cockfield and Sparta aquifers where they directly underlie the alluvial aquifer. The alluvial aquifer also discharges water to the underlying aquifers, and during extended periods with no surface runoff, to the Mississippi River and to the internal streams and lakes. The magnitude of recharge from the Mississippi River, precipitation, and internal lakes and streams can vary greatly depending upon hydrologic and climatic conditions. The U.S. Geological Survey modular threedimensional finite-difference ground-water flow model, MODFLOW, was used to simulate the Mississippi River alluvial aquifer flow system in northwestern Mississippi. The model uses one layer with a rectangular-grid and 1-mile square cells to represent the alluvial aquifer. The model was calibrated and verified by using spring and fall water-level measurements from January 1988 through December 1996. The values of selected model calibration-derived parameters for the alluvial aquifer are hydraulic conductivity, 425 feet per day; specific yield, 0.32; and storage coefficient, 0.016. The model showed that the aquifer lost water from storage at an average rate of 404 cubic feet per second during the 9-year simulation period. During this period, the average pumpage rate was 1,270 million gallons per day (1,980 cubic feet per second). Simulated areal recharge from precipitation averaged 2.6 inches per year (1,360 cubic feet per second). Vertical recharge from the internal streams and lakes and lateral recharge from aquifers underlying the Bluff Hills averaged 113 and 108 cubic feet per second, respectively. Model results indicated that net recharge from the Mississippi River and from aquifers directly underlying the alluvial aquifer was small.

Mississippi↗

USGS1988

Recharge to the Eagle Valley ground-water basin by streamflow in Vicee Canyon, west-central Nevada

Recharge to groundwater could be increased by adding imported water to natural surface water flow in Vicee Canyon, in Eagle Valley, Nevada, where municipal pumping has caused as much as 50 ft of water level decline since 1972. Measurements of infiltration rates, percolation rates, and hydraulic conductivity indicate that the area could be conducive to artificial recharge from infiltration of augmented streamflow. Runoff creates natural infiltration beds on the floor of Vicee Canyon, but baseflow causes channelization and armoring of the stream channel, reducing infiltration rates from about 4 inches to 1 inch/hour. A water balance of the streamflow in Vicee Canyon indicates that 60 to 70% becomes recharge, and the remainder is lost to evaporation from a nearby gravel pit and evapotranspiration on the canyon floor. Estimates of recharge from measurements in the unsaturated and saturated zones account for about 45% of the total streamflow. Application of a groundwater flow model indicates that at present pumping rates, water levels below Vicee Canyon and at a nearby municipal well may rise about 15-30 ft after 5 years as a result of about 1 cu ft/sec of augmented streamflow infiltration. (USGS)

Water-Resources Investigations Report↗

USGS1978

Computer modeling of ground-water availability in the Pootatuck River Valley, Newtown, Connecticut

A hydrologic analysis of the stratified drift in Newtown, Conn., based on available data, test drilling, seismic refraction profiling, and the stream-aquifer connection was performed using a digital computer model. Simulated pumping indicates that a total of 4.0 million gallons of water per day (Mgal/d) can be withdrawn from the stream-aquifer system. A minimum of 2.5 Mgal/d is available for future development since Fairfield Hills Hospital is capable of withdrawing 1.5 Mgal/d. Induced recharge from the Pootatuck River supplies 65 percent, or 2.6 Mgal/d of the total pumpage, and captured ground-water outflow supplies the remaining 35 percent of 1.4 Mgal/d. The predicted yields are for long-term average hydrologic conditions; usually dry or extended drought periods would significantly reduce the water available from the aquifer. The quality of surface water in the valley as shown by seven samples from five sites, meets the Connecticut standards for public drinking water except for excessive coliform bacteria. Ground-water quality also meets these standards, as indicated by analyses of 20 samples from 14 wells and 1 spring, but high manganese (up to 15 mg/L) and iron (up to 1.7 mg/L) would require treatment prior to use. Trace metals from one surface-water and four ground-water samples are also within these standards, except for the high cadmium concentration of 26 micrograms per liter in water from one well. (Woodard-USGS)

Water-Resources Investigations Report↗

USGS2001

An estimate of chemical loads from ground water to the Grand Calumet River and Indiana Harbor Canal, northwestern Indiana

Chemical loads from ground water to the Grand Calumet River and the Indiana Harbor Canal in northwestern Indiana were estimated to aid in determining the total maximum daily load. Data from two previous studies, completed in 1987 and 1993, were used to compute loads. The first study included a ground-water-flow model. Results from this model were used to determine ground-water fluxes to eight distinct reaches of the Grand Calumet River and the Indiana Harbor Canal at assumed horizontal hydraulic conductivities of 50 and 100 feet per day. In addition, water quality data collected during the first study and a second study that further described the quality of water from wells screened in the Calumet aquifer, were used with the ground-water fluxes to compute estimates of chemical loads for selected constituents contributing to the Grand Calumet River and Indiana Harbor Canal. Constituents included trace elements, polychlorinated biphenyls, pesticides, polynuclear aromatic hydrocarbons, and selected general chemistry properties. Total dissolved solids, sulfate, chloride, and dissolved ammonia as nitrogen had the largest estimated loads to the Grand Calumet River and the Indiana Harbor Canal for any river reach. The estimated loads for total dissolved solids ranged from 239 to 12,800 kilograms per day. Dissolved iron had the largest estimated load for the trace elements and exceeded 1 kilogram per day for all river reaches for which data were available. The majority of ground-water concentrations for polychlorinated biphenyls, pesticides, and polynuclear aromatic hydrocarbons were reported as less than the method reporting limit, resulting in small computed loads to the river and canal.

Indiana↗

USGS1989

Modification of a method-of-characteristics solute-transport model to incorporate decay and equilibrium-controlled sorption or ion exchange

The U.S. Geological Survey computer model of two-dimensional solute transport and dispersion in ground water (Konikow and Bredehoeft, 1978) has been modified to incorporate the following types of chemical reactions: (1) first-order irreversible rate-reaction, such as radioactive decay; (2) reversible equilibrium-controlled sorption with linear, Freundlich, or Langmuir isotherms; and (3) reversible equilibrium-controlled ion exchange for monovalent or divalent ions. Numerical procedures are developed to incorporate these processes in the general solution scheme that uses method-of- characteristics with particle tracking for advection and finite-difference methods for dispersion. The first type of reaction is accounted for by an exponential decay term applied directly to the particle concentration. The second and third types of reactions are incorporated through a retardation factor, which is a function of concentration for nonlinear cases. The model is evaluated and verified by comparison with analytical solutions for linear sorption and decay, and by comparison with other numerical solutions for nonlinear sorption and ion exchange.

Water-Resources Investigations Report↗

USGS2002

Geohydrology, water quality, and simulation of ground-water flow in the vicinity of a former waste-oil refinery near Westville, Indiana, 1997–2000

Geohydrologic and water-quality data collected during 1997 through 2000 in the vicinity of a former waste-oil refinery near Westville, Indiana, define a plume of 1,4-dioxane in ground water that extends to the southwest approximately 0.8 miles from the refinery site. Concentrations of 1,4-dioxane in the plume ranged from 3 to 31,000 micrograms per liter. Ground water containing 1,4-dioxane is discharged to Crumpacker Ditch, approximately one-half mile west of the refinery site. Concentrations of 1,4-dioxane detected in surface water ranged from 8 to 140 micrograms per liter; 1,4-dioxane also is transported in ground water beneath the ditch. The study area is underlain by glacial deposits of sand and gravel that overlie lacustrine clay and shale. The sand and gravel deposits form an extensive aquifer ranging from 148 to 215 feet thick in the study area. Ground water generally flows from northeast to southwest and the depth to water ranges from about 3 to 36 feet below land surface. The average horizontal hydraulic conductivity of the aquifer, determined from a multiple-well aquifer test, was 121 feet per day, and the transmissivity was 18,600 feet squared per day. Vertical hydraulic conductivity ranged from 24 to 36 feet per day and specific yield ranged from 0.05 to 0.08. Analysis of single-well aquifer tests indicated that horizontal hydraulic conductivity ranged from 0.6 to 127 feet per day and was largest in the lower part of the aquifer. Horizontal gradients averaged about 0.001 feet per foot; estimated ground-water- flow velocities averaged about 0.1 feet per day in the upper and middle parts of the glacial aquifer and about 0.4 feet per day near the bottom of the aquifer. Analytical results of water samples indicate the ground water generally is a calcium-bicarbonate type with a nearly neutral pH. Specific conductivity ranged from 437 to 1,030 microsiemens per centimeter at 25 degrees Celsius in water from wells upgradient from the refinery site and 330 to 3,780 microsiemens per centimeter at 25 degrees Celsius in water from downgradient wells. Barium, iron, manganese, nickel, and zinc commonly were detected in samples of ground water. Volatile organic compounds (including chlorinated solvents and aromatic hydrocarbons) were consistently detected in samples from shallow wells near the boundaries of the former refinery site. Concentrations of 1,4-dioxane were detected in water from wells screened in the upper, middle, and lower parts of the aquifer downgradient from the site and in samples of surface water collected approximately 5 miles downstream from where the plume intersects Crumpacker Ditch. A three-dimensional, four layer groundwater- flow model was constructed and calibrated to match ground-water levels and streamflow measured during December 1997. The model was used to simulate possible mechanisms of contaminant release, the effect of increased pumpage from water-supply wells, and pumping at the leading edge of the plume as a possible means of remediation. Based on simulation of three waste-oil lagoons, a vertical hydraulic conductivity of 0.2 feet per day was required to move contaminants into the bottom layer of the model at a constant leakage rate of about 98 gallons per minute. Simulations of a disposal well in layer 3 of the model indicated an injection rate of 50 gallons per minute was necessary to spread contaminants vertically in the aquifer. Simulated pumping rates of about 300 and 1,000 gallons per minute were required for water supply wells at the Town of Westville and the Westville Correctional Facility to draw water from the plume of 1,4-dioxane. Simulated pumping from hypothetical wells at the leading edge of the plume indicated that three wells, each pumping 25 gallons per minute from model layer 3, would capture the plume of 1,4-dioxane.

Indiana↗

USGS1984

Appraisal of the water resources of the eastern part of the Tulare aquifer, Beadle, Hand, and Spink Counties, South Dakota

A system of glacial outwash aquifers lie in the central James Valley in east-central South Dakota. Within this system, the eastern part of the Tulare aquifer, which has an area of approximately 681 square miles, was simulated by means of a numerical ground-water flow model. The model estimates the yearly average recharge rate for that part of the aquifer lying west of the James River to be approximately 23,000 acre-feet per year. This rate is considerably more than the estimated 1978 yearly average irrigation pumpage rate of 9,800 acre-feet per year. It is expected that, since pumping will reduce discharge from the aquifer through evapotranspiration and flow to the James River, this part of the aquifer would be able to supply irrigation water at recent pumpage rates for an indefinite period. For that part of the aquifer lying east of the river, estimated recharge is 6,800 acre-feet per year; a rate slightly smaller than the estimated 1978 yearly average irrigation pumpage rate of 7,200 acre-feet per year. It is estimated that this part of the aquifer would be able to supply irrigation water at 7,200 acre-feet per year for approximately 50 years, at which time excessive drawdown would begin to cause reduced well yields at several locations. (USGS)

Water-Resources Investigations Report↗

USGS2020

Geologic map of the Homestake Reservoir 7.5′ quadrangle, Lake, Pitkin, and Eagle Counties, Colorado

The Homestake Reservoir 7.5' quadrangle lies at the northwestern end of the Upper Arkansas Valley, and headwaters of the Arkansas River, and the Roaring Fork, Fryingpan, and Eagle Rivers of the Colorado River system. The quadrangle lies within tectonic provinces of the 1.4 giga-annum (Ga) Picuris orogeny and includes the late Paleozoic Ancestral Rockies, Late Cretaceous-Paleocene Laramide orogeny, Oligocene-to-Miocene and Pliocene? volcanism, and Miocene to the present Rio Grande rift extensional tectonics. In the eastern half of the quadrangle, high-angle, east-dipping, Neogene normal faults displace Proterozoic rocks, and locally Miocene-to-Pliocene? volcanic rocks. Many quartz veins and hydrothermally altered zones are exposed along the eastern flank of the quadrangle, indicative of the multiple tectonic episodes the region has experienced. The main intent of the map is to unravel the structural complexity by partitioning the structures and volcanism within the appropriate geologic interval. This ultimately permits accurate identification of geomorphic features suitable for chronologies related to landscape evolution studies, seismic and other natural hazard identification, ground and surface water modeling, and paleoclimatic studies. Within the western half of the quadrangle, Mesoproterozoic and Paleoproterozoic igneous and metamorphic rocks of 1.4 Ga St. Kevin Granite and 1.8–1.7 Ga Biotite gneiss and schist, respectively, are uplifted along the generally east-dipping, high-angle Sawatch fault system. In the northwest portion of the quadrangle, strands of the Homestake shear zone have been mapped, dated and assigned to the 1.4 Ga Picuris orogeny of northern New Mexico. 10 Be and 26 Al cosmogenic nuclide ages of the youngest glacial deposits indicate a last glacial maximum age of about 22–21 kilo-annum (ka) and complete deglaciation by about 14 kilo-annum, supported by chronologic studies in adjacent drainages. The Turquoise Lake impounding lateral and terminal moraine complex was deposited during late Pleistocene glacial maximum ~22–21 ka. No late Pleistocene tectonic activity is apparent within the quadrangle.

Colorado↗

USGS2000

Determination of infiltration and percolation rates along a reach of the Santa Fe River near La Bajada, New Mexico

Two methods, one a surface-water method and the second a ground-water method, were used to determine infiltration and percolation rates along a 2.5-kilometer reach of the Santa Fe River near La Bajada, New Mexico. The surface-water method uses streamflow measurements and their differences along a stream reach, streamflow-loss rates, stream surface area, and evaporation rates to determine infiltration rates. The ground-water method uses heat as a tracer to monitor percolation through shallow streambed sediments. Data collection began in October 1996 and continued through December 1997. During that period the stream reach was instrumented with three streamflow gages, and temperature profiles were monitored from the stream-sediment interface to about 3 meters below the streambed at four sites along the reach. Infiltration is the downward flow of water through the stream- sediment interface. Infiltration rates ranged from 92 to 267 millimeters per day for an intense measurement period during June 26- 28, 1997, and from 69 to 256 millimeters per day during September 27-October 6, 1997. Investigators calculated infiltration rates from streamflow loss, stream surface-area measurements, and evaporation-rate estimates. Infiltration rates may be affected by unmeasured irrigation-return flow in the study reach. Although the amount of irrigation-return flow was none to very small, it may result in underestimation of infiltration rates. The infiltration portion of streamflow loss was much greater than the evaporation portion. Infiltration accounted for about 92 to 98 percent of streamflow loss. Evaporation-rate estimates ranged from 3.4 to 7.6 millimeters per day based on pan-evaporation data collected at Cochiti Dam, New Mexico, and accounted for about 2 to 8 percent of streamflow loss. Percolation is the movement of water through saturated or unsaturated sediments below the stream-sediment interface. Percolation rates ranged from 40 to 109 millimeters per day during June 26-28, 1997. Percolation rates were not calculated for the September 27-October 6, 1997, period because a late summer flood removed the temperature sensors from the streambed. Investigators used a heat-and-water flow model, VS2DH (variably saturated, two- dimensional heat), to calculate near-surface streambed infiltration and percolation rates from temperatures measured in the stream and streambed. Near the stream-sediment interface, infiltration and percolation rates are comparable. Comparison of infiltration and percolation rates showed that infiltration rates were greater than percolation rates. The method used to calculate infiltration rates accounted for net loss or gain over the entire stream reach, whereas the method used to calculate percolation was dependent on point measurements and, as applied in this study, neglected the nonvertical component of heat and water fluxes. In general, using the ground-water method was less labor intensive than making a series of streamflow measurements and relied on temperature, an easily measured property. The ground-water method also eliminated the difficulty of measuring or estimating evaporation from the water surface and was therefore more direct. Both methods are difficult to use during periods of flood flow. The ground-water method has problems with the thermocouple-wire temperature sensors washing out during flood events. The surface- water method often cannot be used because of safety concerns for personnel making wading streamflow measurements.

New Mexico↗

USGS2003

Use of Water-Quality Indicators and Environmental Tracers to Determine the Fate and Transport of Recycled Water in Angeles County, California

Tertiary-treated municipal wastewater (recycled water) has been used to replenish the Central Basin in Los Angeles County for over 40 years. Therefore, this area provides an excellent location to investigate (1) the fate and transport of wastewater constituents as they travel from the point of recharge to points of withdrawal, and (2) the long-term effects that artificial recharge using recycled water has on the quality of the ground-water basin. The U.S. Geological Survey has been conducting such investigations in this area for about 10 years, beginning in 1992. For this investigation, a variety of inorganic, organic, and isotopic constituents were analyzed in samples from 23 production wells within 500 feet of the San Gabriel and Rio Hondo Coastal Basin Spreading Grounds, and tritium/helium-3, chlorofluorocarbons, dissolved gases, and nitrogen isotopes were analyzed in five multiple-well monitoring sites along a 10-mile flow path extending from just upgradient of the spreading grounds southward through the Central Basin. Spearman rank-order correlation coefficients and level of significance calculated for about 40 water-quality indicators and several physical features show significant correlations between numerous inorganic and organic constituents that indicate the presence of wastewater. On the basis of a simple two-member mixing model, chloride, boron, ultraviolet absorbance at 254 nanometers, and excitation-emission fluorescence yielded the most reasonable estimates of wastewater percentages in the production wells. Tritium/helium-3 age determinations indicated that samples of ground water tested range in age from less than 2 to more than 50 years. Chloride and boron concentrations, along with tritium/helium-3 age determinations, indicate more rapid recharge and (or) displacement of pre-existing ground water at the San Gabriel Coastal Basin Spreading Grounds than at the Rio Hondo Coastal Basin Spreading Grounds. Nitrogen-15 enrichment of the ground-water nitrate and dissolved nitrogen indicates that denitrification, an important process for the removal of nitrate at the shallower depths beneath the spreading grounds, continues to occur at distances of several miles from the spreading grounds and over a period of many years. Analysis of dissolved gases shows that areas that contain recycled water have no detectable methane, whereas methane is present in the native ground water older than 50 years. The absence of methane in the younger ground water suggests that artificial recharge using recycled water has the desirable effect of increasing slightly the redox potential of the ground-water basin. Finally, measured chlorofluorocarbon concentrations and tritium/helium-3 age determinations indicate that chlorofluorocarbon concentrations are markedly elevated above atmosphere-water equilibrium in ground water older than about 20 years but still young enough to contain recycled water.

Water-Resources Investigations Report↗

USGS1995

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida↗

USGS2008

Use of Superposition Models to Simulate Possible Depletion of Colorado River Water by Ground-Water Withdrawal

According to the 'Law of the River', wells that draw water from the Colorado River by underground pumping need an entitlement for the diversion of water from the Colorado River. Consumptive use can occur through direct diversions of surface water, as well as through withdrawal of water from the river by underground pumping. To develop methods for evaluating the need for entitlements for Colorado River water, an assessment of possible depletion of water in the Colorado River by pumping wells is needed. Possible methods include simple analytical models and complex numerical ground-water flow models. For this study, an intermediate approach was taken that uses numerical superposition models with complex horizontal geometry, simple vertical geometry, and constant aquifer properties. The six areas modeled include larger extents of the previously defined river aquifer from the Lake Mead area to the Yuma area. For the modeled areas, a low estimate of transmissivity and an average estimate of transmissivity were derived from statistical analyses of transmissivity data. Aquifer storage coefficient, or specific yield, was selected on the basis of results of a previous study in the Yuma area. The USGS program MODFLOW-2000 (Harbaugh and others, 2000) was used with uniform 0.25-mile grid spacing along rows and columns. Calculations of depletion of river water by wells were made for a time of 100 years since the onset of pumping. A computer program was set up to run the models repeatedly, each time with a well in a different location. Maps were constructed for at least two transmissivity values for each of the modeled areas. The modeling results, based on the selected transmissivities, indicate that low values of depletion in 100 years occur mainly in parts of side valleys that are more than a few tens of miles from the Colorado River.

Scientific Investigations Report↗

USGS1984

Ground-water contamination by crude oil at the Bemidji, Minnesota, research site- An introduction: Chapter A in Ground-water contamination by crude oil at the Bemidji, Minnesota, research site; US Geological Survey Toxic Waste--ground-water contamination study

The U.S. Geological Survey has begun a research project to improve understanding of the mobilization, transport, and fate of petroleum contaminants in the shallow subsurface and to use this understanding to develop predictive models of contaminant behavior. The project site is near Bemidji in northern Minnesota where an accidental spill of 10,500 barrels of crude oil occurred when a pipeline broke on August 20, 1979. Regulatory and remedial actions have been completed. The site is in a remote area with neither man-made hydraulic stresses nor other anthropogenic sources of the compounds of interest. The spill is in the recharge area of a local flow system that discharges to a small closed lake approximately 1,000 feet down the hydraulic gradient. The aquifer is pitted outwash dissected by younger glacial channels and is underlain by poorly permeable till at a depth of about 80 feet. Ground water dissolves oil floating on the water table under the spill site and moves toward the lake. At the water table, ground water enters the lake through lacustrine sediments; at depth, flow may be underneath the lake through the outwash. Contaminant transport has been as rapid as 4 feet per day based on the rate of movement of contaminants monitored through wells installed within a few days of the spill, but average rates are undoubtedly much less.

Minnesota↗

USGS1998

Hydrogeology and water quality in the Cedar Rapids area, Iowa, 1992-96

The U.S. Geological Survey (USGS) and the city of Cedar Rapids conducted a cooperative study from 1992 to 1996 to assess the hydrogeology and water quality in the Cedar River, Cedar River alluvial aquifer, Devonian aquifer, and Silurian aquifer in a 231-square-mile area of Benton and Linn Counties near Cedar Rapids, Iowa. The city of Cedar Rapids withdrew an average of 34 million gallons per day between July 1,1995, and June 30, 1996, from the Cedar River alluvial aquifer for its drinking-water supply. The ground-water flow system in the 231-square-mile area was simulated using a modular, three-dimensional, finite-difference groundwater flow model (MODFLOW) under steady-state conditions. The three-layer groundwater flow model simulates ground-water flow in layer 1 for unconsolidated deposits that include the Cedar River alluvial aquifer; in layer 2 for the Devonian aquifer and buried-channel aquifer; and in layer 3 for the Silurian aquifer. Primary sources of inflow to the ground-water flow system in the model area include infiltration of precipitation (63.5 percent) and leakage from the Cedar River (34.7 percent). Pumpage from municipal, industrial, and private wells accounts for about 48.3 percent of system outflow. Primary sources of inflow to the Cedar River alluvial aquifer include leakage from the Cedar River (74.2 percent), leakage from adjacent or underlying hydrogeologic units (20.9 percent), and infiltration of precipitation (4.9 percent). Pumpage by municipal water-supply wells from the alluvial aquifer accounts for about 78.0 percent of system outflow. Simulations of two hypothetical conditions using the steady-state ground-water flow model were conducted to evaluate quantitative changes on sources of water to the Cedar River alluvial aquifer. Results for the scenario representing a period of less-than-average annual precipitation for 1961-90 indicate a 32.0-percent reduction of total ground-water flow and a 5.7-percent increase in river leakage to the Cedar River alluvial aquifer. Results for the scenario representing increased pumping from the Cedar River alluvial aquifer, with pumping increased 68.3 percent from about 41 million gallons per day (for the calibrated model) to about 70 million gallons per day, indicate a 70.9-percent increase in simulated river leakage. Commonly used herbicides in Iowa such as atrazine (and the metabolite products deethylatrazine and deisopropylatrazine), cyanazine, and metolachlor, when detected in the Cedar River alluvial aquifer, were typically at small concentrations (less than 1.0 microgram per liter). Atrazine concentrations in 26 of the 64 wells sampled were less than the 0.05 microgram per liter minimum reporting level. Most ground-water samples collected from the Devonian and Silurian aquifers had herbicide concentrations less than 0.05 microgram per liter. Nitrite-plus-nitrate nitrogen (nitrate) concentrations in ground-water samples varied from less than the minimum reporting level (0.05 milligram per liter) to 15.0 milligrams per liter. Nitrate was not detected in samples from 18 wells, and nitrate concentrations greater than the Maximum Contaminant Level for nitrate as nitrogen (10 milligrams per liter) were detected in samples from 4 wells. Several areas in the Cedar River alluvial aquifer with large iron and manganese concentrations could be related to the original depositional environment of the sediment. In general, large iron and manganese concentrations in ground water are often associated with abundant organic and argillaceous material in sediment near old meander channels and sloughs.

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