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At least 613 records · Page 34Linked to original sources

Recharge area, base-flow and quick-flow discharge rates and ages, and general water quality of Big Spring in Carter County, Missouri, 2000-04

Exploration for lead deposits has occurred in a mature karst area of southeast Missouri that is highly valued for its scenic beauty and recreational opportunities. The area contains the two largest springs in Missouri (Big Spring and Greer Spring), both of which flow into federally designated scenic rivers. Concerns about potential mining effects on the area ground water and aquatic biota prompted an investigation of Big Spring. Water-level measurements made during 2000 helped define the recharge area of Big Spring, Greer Spring, Mammoth Spring, and Boze Mill Spring. The data infer two distinct potentiometric surfaces. The shallow potentiometric surface, where the depth-to-water is less than about 250 feet, tends to mimic topographic features and is strongly controlled by streams. The deep potentiometric surface, where the depth-to-water is greater than about 250 feet represents ground-water hydraulic heads within the more mature karst areas. A highly permeable zone extends about 20 mile west of Big Spring toward the upper Hurricane Creek Basin. Deeper flowing water in the Big Spring recharge area is directed toward this permeable zone. The estimated sizes of the spring recharge areas are 426 square miles for Big Spring, 352 square miles for Greer Spring, 290 square miles for Mammoth Spring, and 54 square miles for Boze Mill Spring. A discharge accumulation curve using Big Spring daily mean discharge data shows no substantial change in the discharge pattern of Big Spring during the period of record (water years 1922 through 2004). The extended periods when the spring flow deviated from the trend line can be attributed to prolonged departures from normal precipitation. The maximum possible instantaneous flow from Big Spring has not been adequately defined because of backwater effects from the Current River during high-flow conditions. Physical constraints within the spring conduit system may restrict its maximum flow. The largest discharge measured at Big Spring during the period of record (water years 1922 through 2004) was 1,170 cubic feet per second on December 7, 1982. The daily mean water temperature of Big Spring was monitored during water years 2001 through 2004 and showed little variability, ranging from 13 to 15° C (degree Celsius). Water temperatures generally vary less than 1° C throughout the year. The warmest temperatures occur during October and November and decrease until April, indicating Big Spring water temperature does show a slight seasonal variation. The use of the traditional hydrograph separation program HYSEP to determine the base flow and quick flow or runoff components at Big Spring failed to yield base-flow and quick-flow discharge curves that matched observations of spring characteristics. Big Spring discharge data were used in combination with specific conductance data to develop an improved hydrograph separation method for the spring. The estimated annual mean quick flow ranged from 15 to 48 cubic feet per second for the HYSEP analysis and ranged from 26 to 154 cubic feet per second for the discharge and specific conductance method for water years 2001 to 2004. Using the discharge and specific conductance method, the estimated base-flow component rises abruptly as the spring hydrograph rises, attains a peak value on the same day as the discharge peak, and then declines abruptly from its peak value. Several days later, base flow begins to increase again at an approximately linear trend, coinciding with the time at which the percentage of quick flow has reached a maximum after each recharge-induced discharge peak. The interval between the discharge peak and the peak in percentage quick flow ranges from 8 to 11 days for seven hydrograph peaks, consistent with quick-flow traveltime estimates by dye-trace tests from the mature karst Hurricane Creek Basin in the central part of the recharge area. Concentrations of environmental tracers chlorofluorocarbons (CFCs: CFC-11, CFC-12, CFC-113), and sulfur hexafluoride in discharge from Big Spring vary approximately linearly with percent quick flow from about 5 to 45 percent of discharge. Linear extrapolation to 100 percent quick flow implies CFC and SF 6 concentrations nearly identical to those in the 2002 atmosphere and indicates a modern age for the quick-flow component. Tracer concentrations for less than about 5 percent quick flow are increasingly lower than those expected from linear extrapolation to zero percent quick flow, indicating that the reservoir of older water in the Big Spring watershed may be a series of water mixtures with piston-flow ages greater than those obtained by extrapolation to zero percent quick flow. Each sample point with a low percentage of quick flow (less than 5 percent) may be a unique mixture. Environmental tracer data from Big Spring plot intermediate to the simple binary mixing of modern and old, pre-tracer water and results from the exponential mixture model. The mean ages of waters in the base-flow component approximately range from 30 to 200 years. The mean age of the base-flow component is youngest (30 to 40 years) in samples containing the highest quick-flow component (45 percent quick flow) and increases to 200 years or more as the fraction of quick flow decreases to less than 5 percent. Tritium data are consistent with a model of dilution of a modern component with an old, pre-tracer component and indicates that the old fraction is mostly pre-1960s in age with mean residence time of more than several hundred years. All of the samples from Big Spring and Greer Spring have water temperatures warmer than their nitrogen-argon recharge temperature, which range from approximately 10.5 to 14° C, suggesting recharge to the Big Spring watershed occurs primarily in late winter to early spring. The water temperatures at Big Spring are consistent with relatively shallow circulation (less than about 600 feet), and the water does not appear to be warmed by deep circulation along a geothermal gradient. Specific conductance values and concentrations of most inorganic constituents in water samples from Big Spring generally decrease with increasing discharge because of dilution with quick-flow water of lower ionic strength. Concentrations of some constituents such as chloride and nitrite plus nitrate, and fecal coliform densities, however, did not decrease with increasing discharge, indicating that quick flow probably is a more important source of these constituents compared to base flow. Water samples from Big Spring plot along the line of dolomite dissolution by carbonic acid, are at equilibrium with dolomite and calcite, and have a molar ratio of Ca:Mg of near 1, indicating dissolution of the mineral dolomite as the primary control on concentrations of calcium, magnesium, and bicarbonate. The flux of calcium and magnesium from Big Spring represents the dissolution of about 1,950 cubic feet of dolomite per day. The suspended sediment load of Big Spring was estimated to range from about 1 to about 70 tons per day, and the sediment load during base-flow periods ranged from about 1 to about 7 tons per day.

Missouri↗

Benzotriazole concentrations in airport runoff are reduced following changes in airport deicer formulations

A comparison of the presence of additives in airport deicers commonly used in the United States and in airport runoff was conducted with data collected before and after changes in deicer formulations. Three isomers of benzotriazoles (BTs)—4-methyl-1H-benzotriazole (4-MeBT), 5-methyl-1H-benzotriazole (5-MeBT), and 1H-benzotriazole (1H-BT)—are corrosion inhibitors added to some formulations of airport deicers and are reported to be a source of aquatic toxicity in streams receiving airport runoff. Concentrations of BT in aircraft deicers and anti-icing fluids (ADAF) were reduced over time but were not reduced in potassium acetate airfield-pavement deicer material (PDM) that was used throughout the study period. Streams receiving runoff from Milwaukee Mitchell International Airport, Milwaukee, Wisconsin, USA, were monitored from 2004 to 2019 for BTs, with concentrations of 4-MeBT varying from <0.35 to 4600 µg/L, 5-MeBT varying from <0.25 to 6600 µg/L, and 1H-BT varying from <0.25 to 150 µg/L. Median 4-MeBT concentrations at sites downstream from the airport decreased by approximately 74%, 5-MeBT by 69%, and 1H-BT by 82% following reduction in BTs in ADAF formulations, resulting in a reduction in the potential for aquatic toxicity in receiving streams. A change in residuals from regression analysis between freezing point depressants and BTs indicate that the reduction in BT concentrations in airport runoff was a result of BT reduction in ADAF formulations, but PDM may still be a substantial source of BTs in airport runoff. Because BTs are a source of aquatic toxicity in airport deicers, the reductions in BTs in the common deicers observed in this study can be used to demonstrate the potential for a reduction in the effects to aquatic organisms in airport runoff, resulting in greater likelihood of meeting aquatic toxicity requirements in airport stormwater permits, and potentially driving airports, airlines, and permit holders to advocate further reduction or elimination of BTs and other harmful contaminants in airport deicers.

Wisconsin↗

Contaminant exposure and reproductive success of Ospreys (Pandion haliaetus) nesting in Chesapeake Bay regions of concern

The Chesapeake Bay osprey population has more than doubled in size since restrictions were placed on the production and use of DDT and other toxic organochlorine contaminants in the 1970s. Ospreys are now nesting in the most highly polluted portions of the Bay. In 2000 and 2001, contaminant exposure and reproduction were monitored in ospreys nesting in regions of concern, including Baltimore Harbor and the Patapsco River, the Anacostia and middle Potomac rivers, and the Elizabeth River, and a presumed reference site consisting of the South, West, and Rhode rivers. A 'sample egg' from each study nest was collected for contaminant analysis, and the fate of eggs remaining in each nest (n = 14-16/site) was monitored at 7- to 10-day intervals from egg incubation through fledging of young. Ospreys fledged young in regions of concern (observed success: 0.88 -1.53 fledglings/active nest), although productivity was marginal for sustaining local populations in Baltimore Harbor and the Patapsco River and in the Anacostia and middle Potomac rivers. Concentrations of p,p'DDE and many other organochlorine pesticides or metabolites, total PCBs, some arylhydrocarbon receptor-active PCB congeners and polybrominated diphenyl ether congeners, and perfluorooctanesulfonate were often greater in sample eggs from regions of concern compared to the reference site. Nonetheless, logistic regression analyses did not provide evidence linking marginal productivity to p,p' -DDE, total PCBs, or arylhydrocarbon receptor-active PCB congener exposure in regions of concern. In view of the moderate concentrations of total PCBs in eggs from the reference site, concerns related to new and emerging toxicants, and the absence of ecotoxicological data for terrestrial vertebrates in many Bay tributaries, a more thorough spatial evaluation of contaminant exposure in ospreys throughout the Chesapeake may be warranted.

Archives of Environmental Contamination and Toxico↗

Elucidation of taste- and odor-producing bacteria and toxigenic cyanobacteria in a Midwestern drinking water supply reservoir by shotgun metagenomics analysis

While commonplace in clinical settings, DNA-based assays for identification or enumeration of drinking water pathogens and other biological contaminants remain widely unadopted by the monitoring community. In this study, shotgun metagenomics was used to identify taste-and-odor producers and toxin-producing cyanobacteria over a 2-year period in a drinking water reservoir. The sequencing data implicated several cyanobacteria, including Anabaena spp ., Microcystis spp ., and an unresolved member of the order Oscillatoriales as the likely principal producers of geosmin, microcystin, and 2-methylisoborneol (MIB), respectively. To further demonstrate this, quantitative PCR (qPCR) assays targeting geosmin-producing Anabaena and microcystin-producing Microcystis were utilized, and these data were fitted using generalized linear models and compared with routine monitoring data, including microscopic cell counts, sonde-based physicochemical analyses, and assays of all inorganic and organic nitrogen and phosphorus forms and fractions. The qPCR assays explained the greatest variation in observed geosmin (adjusted R 2 = 0.71) and microcystin (adjusted R 2 = 0.84) concentrations over the study period, highlighting their potential for routine monitoring applications. The origin of the monoterpene cyclase required for MIB biosynthesis was putatively linked to a periphytic cyanobacterial mat attached to the concrete drinking water inflow structure. We conclude that shotgun metagenomics can be used to identify microbial agents involved in water quality deterioration and to guide PCR assay selection or design for routine monitoring purposes. Finally, we offer estimates of microbial diversity and metagenomic coverage of our data sets for reference to others wishing to apply shotgun metagenomics to other lacustrine systems.

Kansas↗

Dissolved-solids sources, loads, yields, and concentrations in streams of the conterminous United States

Recent studies have shown that excessive dissolved-solids concentrations in water can have adverse effects on the environment and on agricultural, domestic, municipal, and industrial water users. Such effects motivated the U.S. Geological Survey&rsquo;s National Water Quality Assessment Program to develop a SPAtially-Referenced Regression on Watershed Attributes (SPARROW) model that has improved the understanding of sources, loads, yields, and concentrations of dissolved solids in streams of the conterminous United States. Using the SPARROW model, long-term mean annual dissolved-solids loads from 2,560 water-quality monitoring stations were statistically related to several spatial datasets that are surrogates for dissolved-solids sources and land-to-water delivery processes. Specifically, sources in the model included variables representing geologic materials, road deicers, urban lands, cultivated lands, and pasture lands. Transport of dissolved solids from these sources was modulated by land-to-water delivery variables that represent precipitation, streamflow, soil, vegetation, terrain, population, irrigation, and artificial drainage characteristics. Where appropriate, the load estimates, source variables, and transport variables were statistically adjusted to represent conditions for the base year 2000. The nonlinear least-squares estimated SPARROW model was used to predict long-term mean annual conditions for dissolved-solids sources, loads, yields, and concentrations in a digital hydrologic network representing nearly 66,000 stream reaches and their corresponding incremental catchments that drain the Nation. Nationwide, the predominant source of dissolved solids yielded from incremental catchments and delivered to local streams is geologic materials in 89 percent of the catchments, road deicers in 5 percent of the catchments, pasture lands in 3 percent of the catchments, urban lands in 2 percent of the catchments, and cultivated lands in 1 percent of the catchments. Whereas incremental catchments with dissolved solids that originated predominantly from geologic sources or from urban lands are found across much of the Nation, incremental catchments with dissolved solids yields that originated predominantly from road deicers are largely found in the Northeast, and incremental catchments with dissolved solids that originated predominantly from cultivated or pasture lands are largely found in the West. The total amount of dissolved solids delivered to the Nation&rsquo;s streams is 271.9 million metric tons (Mt) annually, of which 194.2 million Mt (71.4%) come from geologic sources, 37.7 million Mt (13.9%) come from road deicers, 18.2 million Mt (6.7%) come from pasture lands, 13.9 million Mt (5.1%) come from urban lands, and 7.9 million Mt (2.9%) come from cultivated lands. Nationwide, the median incremental-catchment yield delivered to local streams is 26 metric tons per year per square kilometer [(Mt/yr)/km 2 ]. Ten percent of the incremental catchments yield less than 4 (Mt/yr)/km 2 , and 10 percent yield more than 90 (Mt/yr)/km 2 . Incremental-catchment yields greater than 50 (Mt/yr)/km 2 mostly occur along the northern part of the West Coast and in a crescent shaped band south of the Great Lakes. For example, the median incremental-catchment yield is 81 (Mt/yr)/km 2 for the Great Lakes, 78 (Mt/yr)/km 2 for the Ohio, and 74 (Mt/yr)/km 2 for the Upper Mississippi water-resources regions. Incremental-catchment yields less than 10 (Mt/yr)/km 2 mostly occur in a wide band across the arid lowland of the interior West that excludes areas along the coast and the extensive, higher mountain ranges. For example, the median incremental-catchment yield is 3 (Mt/yr)/km 2 for the Lower Colorado, 5 (Mt/yr)/km 2 for the Rio Grande, and 8 (Mt/yr)/km 2 for the Great Basin water-resources regions. Predicted incremental loads were cascaded down through the reach network, with loads accumulating from reach to reach. For most stream reaches, the entire incremental load of dissolved solids delivered to the reach was transported to either the ocean or to one of the large streams flowing along the U.S. international boundary without losses occurring along the way. The exceptions to this include streams in the southwestern part of the country, such as the Colorado River, Rio Grande, and streams of internally drained drainages in the Great Basin, where dissolved-solids loads decreased through streamflow diversion for off-stream use, or by infiltration through the streambed. Long-term mean annual flow-weighted concentrations were derived from the predicted accumulated-load and stream-discharge data. Widespread low concentrations, generally less than 100 milligrams per liter (mg/L), occur in many reaches of the New England, South Atlantic-Gulf, and Pacific Northwest water-resources regions as a result of moderate dissolved-solids yields and high runoff rates. Widespread moderate concentrations, generally between 100 and 500 mg/L, occur in many reaches of the Great Lakes, Ohio, and Upper Mississippi River water-resources regions. Whereas dissolved-solids yields are generally high in these regions, runoff rates are also high, which helps moderate concentrations in these regions. Widespread higher concentrations, generally greater than 500 mg/L, occur across a belt of reaches that extends almost continuously from Canada to Mexico in the Midwest, cutting through the Souris-Red-Rainy, Missouri, Arkansas-White-Red, Texas-Gulf, and Rio Grande water-resources regions. Although dissolved-solids yields are moderate to low in these areas, low runoff rates result in the high concentrations for these areas. In 12.6 percent of the Nation&rsquo;s stream reaches, predicted concentrations of dissolved solids exceed 500 mg/L, the U.S. Environmental Protection Agency&rsquo;s secondary, nonenforceable drinking water standard. While this standard provides a metric for evaluating predicted concentrations in the context of drinking-water supplies, it should be noted that it only applies to drinking water actually served to customers by water utilities, and it does not apply to all stream reaches in the Nation nor does it apply during times when water is not being withdrawn for use. Exceedance of 500 mg/L is more pronounced in certain water-resources regions than others. For example, about half of the reaches in the Souris-Red-Rainy region have concentrations predicted to exceed 500 mg/L, and between 25 and 37 percent of the reaches in the Missouri, Arkansas-White-Red, Texas-Gulf, Rio Grande, and Lower Colorado regions are predicted to exceed 500 mg/L. Development of stream-load data for use in the SPARROW model also provided long-term temporal trend information in dissolved-solids concentrations at the monitoring stations for their period of record, which was constrained between 1980 and 2009. For the 2,560 monitoring stations used in this study, long-term trends in flow-adjusted dissolved-solids concentrations increased over time at 23 percent of the stations, decreased at 18 percent of the stations, and did not change over time at 59 percent of the stations. Long-term trends show a strong regional spatial pattern where from the western parts of the Great Plains to the West Coast, concentrations mostly either did not change or decreased over time, and from the eastern parts of the Great Plains to the East Coast, concentrations mostly either did not change or increased over time. Results from the trend analysis and from the SPARROW model indicate that, compared to monitoring stations with no trends or decreasing trends, stations with increasing trends are associated with a smaller percentage of the predicted dissolved-solids load originating from geologic sources, and a larger percentage originating from urban lands and road deicers. Conversely, compared to stations with increasing trends or no trends, stations with decreasing trends have a larger percentage of the predicted dissolved-solids load originating from geologic sources and a smaller percentage originating from urban lands and road deicers. Stations with decreasing trends also have larger percentages of predicted dissolved-solids load originating from cultivated lands and pasture lands, compared to stations with increasing trends or no trends.

Scientific Investigations Report↗

Statewide water-quality network for Massachusetts

A water-quality monitoring program is proposed that would provide data to meet multiple information needs of Massachusetts agencies and other users concerned with the condition of the State's water resources. The program was designed by the U.S. Geological Survey and the Massachusetts Department of Environmental Protection, Division of Watershed Management, with input from many organizations involved in water-quality monitoring in the State, and focuses on inland surface waters (streams and lakes). The proposed monitoring program consists of several components, or tiers, which are defined in terms of specific monitoring objectives, and is intended to complement the Massachusetts Watershed Initiative (MWI) basin assessments. Several components were developed using the Neponset River Basin in eastern Massachusetts as a pilot area, or otherwise make use of data from and sampling approaches used in that basin as part of a MWI pilot assessment in 1994. To guide development of the monitoring program, reviews were conducted of general principles of network design, including monitoring objectives and approaches, and of ongoing monitoring activities of Massachusetts State agencies. Network tiers described in this report are primarily (1) a statewide, basin-based assessment of existing surface-water-quality conditions, and (2) a fixed-station network for determining contaminant loads carried by major rivers. Other components, including (3) targeted programs for hot-spot monitoring and other objectives, and (4) compliance monitoring, also are discussed. Monitoring programs for the development of Total Maximum Daily Loads for specific water bodies, which would constitute another tier of the network, are being developed separately and are not described in this report. The basin-based assessment of existing conditions is designed to provide information on the status of surface waters with respect to State water-quality standards and designated uses in accordance with the reporting requirements [Section 305(b)] of the Clean Water Act (CWA). Geographic Information System (GIS)-based procedures were developed to inventory streams and lakes in a basin for these purposes. Several monitoring approaches for this tier and their associated resource requirements were investigated. Analysis of the Neponset Basin for this purpose demonstrated that the large number of sites needed in order for all the small streams in a basin to be sampled (about half of stream miles in the basin were headwater or first-order streams) pose substantial resource-based problems for a comprehensive assessment of existing conditions. The many lakes pose similar problems. Thus, a design is presented in which probabilistic monitoring of small streams is combined with deterministic or targeted monitoring of large streams and lakes to meet CWA requirements and to provide data for other information needs of Massachusetts regulatory agencies and MWI teams. The fixed-station network is designed to permit the determination of contaminant loads carried by the State's major rivers to sensitive inland and coastal receiving waters and across State boundaries. Sampling at 19 proposed sites in 17 of the 27 major basins in Massachusetts would provide information on contaminant loads from 67 percent of the total land area of the State; unsampled areas are primarily coastal areas drained by many small streams that would be impossible to sample within realistic resource limitations. Strategies for hot-spot monitoring, a targeted monitoring program focused on identifying contaminant sources, are described with reference to an analysis of the bacteria sampling program of the 1994 Neponset Basin assessment. Finally, major discharge sites permitted under the National Pollutant Discharge Elimination System (NPDES) were evaluated as a basis for ambient water-quality monitoring. The discharge sites are well distributed geographically among basins, but are primarily on large rivers (two-thirds or more on fourth- or higher order streams). Thus, NPDES sites alone would provide a biased estimate of existing water-quality conditions, but might be useful for some loads determinations if data of sufficient quality could be collected.

Massachusetts↗

Monitoring biodegradation of ethene and bioremediation of chlorinated ethenes at a contaminated site using compound-specific isotope analysis (CSIA)

Chlorinated ethenes are commonly found in contaminated groundwater. Remediation strategies focus on transformation processes that will ultimately lead to nontoxic products. A major concern with these strategies is the possibility of incomplete dechlorination and accumulation of toxic daughter products (cis-1,2-dichloroethene (cDCE), vinyl chloride (VC)). Ethene mass balance can be used as a direct indicator to assess the effectiveness of dechlorination. However, the microbial processes that affect ethene are not well characterized and poor mass balance may reflect biotransformation of ethene rather than incomplete dechlorination. Microbial degradation of ethene is commonly observed in aerobic systems but fewer cases have been reported in anaerobic systems. Limited information is available on the isotope enrichment factors associated with these processes. Using compound-specific isotope analysis (CSIA) we determined the enrichment factors associated with microbial degradation of ethene in anaerobic microcosms (ε = −6.7‰ ± 0.4‰, and −4.0‰ ± 0.8‰) from cultures collected from the Twin Lakes wetland area at the Savannah River site in Georgia (United States), and in aerobic microcosms (ε = −3.0‰ ± 0.3‰) from Mycobacterium sp. strain JS60. Under anaerobic and aerobic conditions, CSIA can be used to determine whether biotransformation of ethene is occurring in addition to biodegradation of the chlorinated ethenes. Using δ13C values determined for ethene and for chlorinated ethenes at a contaminated field site undergoing bioremediation, this study demonstrates how CSIA of ethene can be used to reduce uncertainty and risk at a site by distinguishing between actual mass balance deficits during reductive dechlorination and apparent lack of mass balance that is related to biotransformation of ethene.

Environmental Science & Technology↗

Hydrogeologic and geochemical characterization of groundwater resources in Deep Creek Valley and adjacent areas, Juab and Tooele Counties, Utah, and Elko and White Pine Counties, Nevada

The water resources of Deep Creek Valley were assessed during 2012&ndash;13 with an emphasis on better understanding the groundwater flow system and groundwater budget. Surface-water resources are limited in Deep Creek Valley and are generally used for agriculture. Groundwater is the predominant water source for most other uses and to supplement irrigation. Most groundwater withdrawal in Deep Creek Valley occurs from the unconsolidated basin-fill deposits, in which conditions are generally unconfined near the mountain front and confined in the lower-altitude parts of the valley. Productive aquifers are also present in fractured bedrock that occurs along the valley margins and beneath the basin-fill deposits. The consolidated-rock and basin-fill aquifers are hydraulically connected in many areas with much of the recharge occurring in the consolidated-rock mountain blocks and most of the discharge occurring from the lower-altitude basin-fill deposits. Average annual recharge to the Deep Creek Valley hydrographic area was estimated to be between 19,000 and 29,000 acre-feet. Groundwater recharge occurs mostly from the infiltration of precipitation and snowmelt at high altitudes. Additional, but limited recharge occurs from the infiltration of runoff from precipitation near the mountain front, infiltration along stream channels, and possible subsurface inflow from adjacent hydrographic areas. Groundwater moves from areas of recharge to springs and streams in the mountains, and to evapotranspiration areas, springs, streams, and wells in the basins. Discharge may also occur as subsurface groundwater outflow to adjacent hydrographic areas. Average annual discharge from the Deep Creek Valley hydrographic area was estimated to be between 21,000 and 22,000 acre-feet, with the largest portion of discharge occurring as evapotranspiration. Groundwater samples were collected from 10 sites for geochemical analysis. Dissolved-solids concentrations ranged from 126 to 475 milligrams per liter, and none of the sites sampled during this study had dissolved-solids concentrations that exceeded the Environmental Protection Agency secondary standard for drinking water of 500 milligrams per liter. Tritium concentrations from 1.6 to 10.1 tritium units at 3 of the 10 sample sites indicate the presence of modern (less than 60 years old) groundwater, and apparent tritium/helium-3 ages calculated for these sites ranged from 7 to 29 years. The other seven sample sites had tritium concentrations less than or equal to 0.4 tritium units and are assumed to be pre-modern. Adjusted minimum radiocarbon ages of these seven pre-modern water samples ranged from 1,000 to 8,000 years with the ages of at least four of the samples being more than 3,000 years. Noble-gas recharge temperatures indicate that groundwater sampled along the valley axis recharged at both mountain and valley altitudes, providing evidence for both mountain-block and mountain-front recharge. Water-level altitude contours and groundwater ages indicate the potential for a long flow path from southwest to northeast between northern Spring and Deep Creek Valleys through Tippett Valley. Although information gathered during this study is insufficient to conclude whether or not groundwater travels along this interbasin flow path, dissolved sulfate and chloride data indicate that a small fraction of the lower altitude, northern Deep Creek Valley discharge may be sourced from these areas. Despite the uncertainty due to limited data collection points, a hydraulic connection between northern Spring Valley, Tippett Valley, and Deep Creek Valley appears likely, and potential regional effects resulting from future groundwater withdrawals in northern Spring Valley warrant ongoing monitoring of groundwater levels across this area.

Nevada, Utah↗

Use of Water-Quality Indicators and Environmental Tracers to Determine the Fate and Transport of Recycled Water in Angeles County, California

Tertiary-treated municipal wastewater (recycled water) has been used to replenish the Central Basin in Los Angeles County for over 40 years. Therefore, this area provides an excellent location to investigate (1) the fate and transport of wastewater constituents as they travel from the point of recharge to points of withdrawal, and (2) the long-term effects that artificial recharge using recycled water has on the quality of the ground-water basin. The U.S. Geological Survey has been conducting such investigations in this area for about 10 years, beginning in 1992. For this investigation, a variety of inorganic, organic, and isotopic constituents were analyzed in samples from 23 production wells within 500 feet of the San Gabriel and Rio Hondo Coastal Basin Spreading Grounds, and tritium/helium-3, chlorofluorocarbons, dissolved gases, and nitrogen isotopes were analyzed in five multiple-well monitoring sites along a 10-mile flow path extending from just upgradient of the spreading grounds southward through the Central Basin. Spearman rank-order correlation coefficients and level of significance calculated for about 40 water-quality indicators and several physical features show significant correlations between numerous inorganic and organic constituents that indicate the presence of wastewater. On the basis of a simple two-member mixing model, chloride, boron, ultraviolet absorbance at 254 nanometers, and excitation-emission fluorescence yielded the most reasonable estimates of wastewater percentages in the production wells. Tritium/helium-3 age determinations indicated that samples of ground water tested range in age from less than 2 to more than 50 years. Chloride and boron concentrations, along with tritium/helium-3 age determinations, indicate more rapid recharge and (or) displacement of pre-existing ground water at the San Gabriel Coastal Basin Spreading Grounds than at the Rio Hondo Coastal Basin Spreading Grounds. Nitrogen-15 enrichment of the ground-water nitrate and dissolved nitrogen indicates that denitrification, an important process for the removal of nitrate at the shallower depths beneath the spreading grounds, continues to occur at distances of several miles from the spreading grounds and over a period of many years. Analysis of dissolved gases shows that areas that contain recycled water have no detectable methane, whereas methane is present in the native ground water older than 50 years. The absence of methane in the younger ground water suggests that artificial recharge using recycled water has the desirable effect of increasing slightly the redox potential of the ground-water basin. Finally, measured chlorofluorocarbon concentrations and tritium/helium-3 age determinations indicate that chlorofluorocarbon concentrations are markedly elevated above atmosphere-water equilibrium in ground water older than about 20 years but still young enough to contain recycled water.

Water-Resources Investigations Report↗

Estimation of late twentieth century land-cover change in California

We present the first comprehensive multi-temporal analysis of land-cover change for California across its major ecological regions and primary land-cover types. Recently completed satellite-based estimates of land-cover and land-use change information for large portions of the United States allow for consistent measurement and comparison across heterogeneous landscapes. Landsat data were employed within a pure-panel stratified one-stage cluster sample to estimate and characterize land-cover change for 1973–2000. Results indicate anthropogenic and natural disturbances, such as forest cutting and fire, were the dominant changes, followed by large fluctuations between agriculture and rangelands. Contrary to common perception, agriculture remained relatively stable over the 27-year period with an estimated loss of 1.0% of agricultural land. The largest net declines occurred in the grasslands/shrubs class at 5,131 km 2 and forest class at 4,722 km 2 . Developed lands increased by 37.6%, composing an estimated 4.2% of the state’s land cover by 2000.

California↗

Composite samples for perfluorooctanesulfonate in fish may change contaminant threshold decisions

The widespread occurrence and persistence of the per- and polyfluoroalkyl substances (PFAS) in the environment may pose significant health risks to humans. Fish consumption is a direct pathway for exposure, prompting extensive monitoring. In the United States and Europe, fish consumption advisories for PFAS generally focus on perfluorooctanesulfonate (PFOS), the most frequent and abundant PFAS compound reported in fish. However, PFAS analysis is costly, leading monitoring programs to frequently use composite samples (i.e., combining different fish of the same species). This financial saving comes at an analytical cost of lost information on individual variation. It is unclear how this may influence threshold-based decisions. To test this, we used a modeling approach (i.e., Monte Carlo) based on aggregated data distributions from freshwater fish species. We simulated the measurement of PFOS for individual fish compared to composite means (three, five, and 10 fish) at different levels of error structure. These values were then compared to a typical do-not-eat threshold of 200 ng•g wet mass −1 and four metrics were estimated: (i) the probability of detecting a PFOS concentration above the threshold, (ii) the maximum simulated PFOS concentration, (iii) the number of false negative samples, and (iv) the rate of false negative samples. These results show that the probability of assigning PFOS levels above or below the threshold is shifted by masking individual value contributions in a composite sample. Because true individual contaminant loads are variable, composite sampling is a more conservative metric for contaminant thresholds. The model suggested that the greater the variability, the lower the detection probability for truly contaminated samples. Our study may help to inform sampling for monitoring programs aimed at managing human exposure to PFAS.

Integrated Environmental Assessment and Management↗

Neotropical migratory bird monitoring study at Marine Corps Base Camp Pendleton, California—2021 annual data summary

Executive Summary Two Monitoring Avian Productivity and Survivorship (MAPS) stations were operated at Marine Corps Base Camp Pendleton (MCBCP), California, in 2021: one at De Luz Creek and one at the Santa Margarita River. The stations were established to provide data on Neotropical migratory birds at MCBCP to support the dual missions of environmental stewardship and military readiness. A total of 1,227 individual birds were captured in 2021 between the two stations: 395 at De Luz and 832 at Santa Margarita (both 15 banding days). Of these 1,227 individuals captured, 955 were newly banded (273 at De Luz and 682 at Santa Margarita), 150 were recaptures banded before 2021 (28 at De Luz and 122 at Santa Margarita, excluding recaptures released before reading band number [1 at De Luz and 3 at Santa Margarita]), and 118 were unbanded (93 at De Luz and 25 at Santa Margarita). Return rate in 2021 was much lower than the annual mean at De Luz (1995–2019) and similar to the annual mean at the Santa Margarita station (1998–2020). The sex ratio of known-sex adult birds was skewed toward males at both stations in 2021. Species richness was similar at De Luz from 2019 to 2021, increased at Santa Margarita from 2020 to 2021 and was above annual means at both sites (1995–2019 and 1998–2020, respectively). The most abundant species at De Luz were Wrentit ( Chamaea fasciata ) and Allen’s Hummingbird ( Selasphorus sasin ). Song Sparrow ( Melospiza melodia ) and Common Yellowthroat ( Geothlypis trichas ) were most abundant at Santa Margarita. Since 2002, we have examined the population trends of 12 species at De Luz and 13 species at Santa Margarita for which numbers of known-age individuals were adequate for statistical analysis. We estimated population size and calculated indices of productivity and survival for a subset of these species with sufficient captures and recaptures for valid parameter estimation—four at De Luz and six at Santa Margarita. We determined that in 2021, abundance of 42 percent (5 of 12) of focal species at De Luz and 38 percent (5 of 13) of focal species at Santa Margarita was below the annual mean abundance. Of the focal species below mean abundance, 40 percent (2 of 5) at De Luz and 60 percent (3 of 5) at Santa Margarita were migrant populations. Of the focal species, 25 (3 of 12) percent at De Luz and 31 percent (4 of 13) at Santa Margarita had declining population trends during the span of station operation. With few exceptions, these declines appeared to be associated with conditions on the breeding grounds. Annual productivity (calculated as the ratio of juveniles to adults among individual captures) was zero for all focal species at De Luz in 2021. At Santa Margarita, productivity increased from year 2020 to 2021 for Common Yellowthroat, Song Sparrow, and Yellow Warbler ( Setophaga petechia ) and declined from year 2020 to 2021 for Least Bell’s Vireo ( Vireo bellii pusillus ), but productivity was above the 1998–2020 mean for all four species, whereas productivity was maintained for Orange-crowned Warbler ( Leiothlypis celata ) and Yellow-breasted Chat ( Icteria virens ). Winter precipitation affected productivity of Black-headed Grosbeak ( Pheucticus melanocephalus ), Common Yellowthroat, and Song Sparrow at De Luz and affected productivity of Common Yellowthroat, Orange-crowned Warbler, Song Sparrow, Yellow-breasted Chat, and Yellow Warbler at Santa Margarita. We calculated the mean annual adult survival for 1998–2020 at Santa Margarita, excluding years when the station was not operated. Survival could not be calculated for De Luz in 2021 because the station was not operated in 2020. Model-averaged annual adult survival ranged from 42 to 66 percent for residents and from 30 to 66 percent for migrants at Santa Margarita. Survival of Common Yellowthroat, Song Sparrow, and possibly Yellow Warbler was found to be affected by winter precipitation. Sex was a significant predictor of survival for Common Yellowthroat, Least Bell’s Vireo, Orange-crowned Warbler, and Yellow-breasted Chat at Santa Margarita, where females were found to have lower survival than males. At Santa Margarita, multiple regression analyses examining adult survival and productivity as predictors of future population size indicated that resident Song Sparrow and migrant Yellow Warbler populations were affected by population size from the previous year, migrant Yellow-breasted Chat populations were affected by productivity from the previous year, and migrant Orange-Crowned Warbler populations were affected by survival from the previous year. Updated previous-year population size predictions could not be calculated for De Luz because the station was not operated in 2020.

California↗

A multivariate analysis of biophysical parameters of tallgrass prairie among land management practices and years

Six treatments of eastern Kansas tallgrass prairie - native prairie, hayed, mowed, grazed, burned and untreated - were studied to examine the biophysical effects of land management practices on grasslands. On each treatment, measurements of plant biomass, leaf area index, plant cover, leaf moisture and soil moisture were collected. In addition, measurements were taken of the Normalized Difference Vegetation Index (NDVI), which is derived from spectral reflectance measurements. Measurements were taken in mid-June, mid-July and late summer of 1990 and 1991. Multivariate analysis of variance was used to determine whether there were differences in the set of variables among treatments and years. Follow-up tests included univariate t-tests to determine which variables were contributing to any significant difference. Results showed a significant difference (p < 0.0005) among treatments in the composite of parameters during each of the months sampled. In most treatment types, there was a significant difference between years within each month. The univariate tests showed, however, that only some variables, primarily soil moisture, were contributing to this difference. We conclude that biomass and % plant cover show the best potential to serve as long-term indicators of grassland condition as they generally were sensitive to effects of different land management practices but not to yearly change in weather conditions. NDVI was insensitive to precipitation differences between years in July for most treatments, but was not in the native prairie. Choice of sampling time is important for these parameters to serve effectively as indicators.

Environmental Monitoring and Assessment↗

Hydrosalinity studies of the Virgin River, Dixie Hot Springs, and Littlefield Springs, Utah, Arizona, and Nevada

The Virgin River contributes a substantial amount of dissolved solids (salt) to the Colorado River at Lake Mead in the lower Colorado River Basin. Degradation of Colorado River water by the addition of dissolved solids from the Virgin River affects the suitability of the water for municipal, industrial, and agricultural use within the basin. Dixie Hot Springs in Utah are a major localized source of dissolved solids discharging to the Virgin River. The average measured discharge from Dixie Hot Springs during 2009–10 was 11.0 cubic feet per second (ft 3 /s), and the average dissolved-solids concentration was 9,220 milligrams per liter (mg/L). The average dissolved-solids load—a measurement that describes the mass of salt that is transported per unit of time—from Dixie Hot Springs during this period was 96,200 tons per year (ton/yr). Annual dissolved-solids loads were estimated at 13 monitoring sites in the Virgin River Basin from streamflow data and discrete measurements of dissolved-solids concentrations and (or) specific conductance. Eight of the sites had the data needed to estimate annual dissolved-solids loads for water years (WYs) 1999 through 2010. During 1999–2010, the smallest dissolved-solids loads in the Virgin River were upstream of Dixie Hot Springs (59,900 ton/yr, on average) and the largest loads were downstream of Littlefield Springs (298,200 ton/yr, on average). Annual dissolved-solids loads were smallest during 2002–03, which was a period of below normal precipitation. Annual dissolved-solids loads were largest during 2005—a year that included a winter rain storm that resulted in flooding throughout much of the Virgin River Basin. An average seepage loss of 26.7 ft 3 /s was calculated from analysis of monthly average streamflow from July 1998 to September 2010 in the Virgin River for the reach that extends from just upstream of the Utah/Arizona State line to just above the Virgin River Gorge Narrows. Seepage losses from three river reaches in the Virgin River Gorge containing known fault zones accounted for about 48 percent of this total seepage loss. An additional seepage loss of 6.7 ft 3 /s was calculated for the reach of the Virgin River between Bloomington, Utah, and the Utah/Arizona State line. This loss in flow is small compared to total flow in the river and is comparable to the rated error in streamflow measurements in this reach; consequently, it should be used with caution. Littlefield Springs were studied to determine the fraction of its discharge that originates as upstream seepage from the Virgin River and residence time of this water in the subsurface. Geochemical and environmental tracer data from groundwater and surface-water sites in the Virgin River Gorge area suggest that discharge from Littlefield Springs is a mixture of modern (post-1950s) seepage from the Virgin River upstream of the springs and older groundwater from a regional carbonate aquifer. Concentrations of the chlorofluorocarbons (CFCs) CFC-12 and CFC-113, chloride/fluoride and chloride/bromide ratios, and the stable isotope deuterium indicate that water discharging from Littlefield Springs is about 60 percent seepage from the Virgin River and about 40 percent discharge from the regional carbonate aquifer. The river seepage component was determined to have an average subsurface traveltime of about 26 ±1.6 years before discharging at Littlefield Springs. Radiocarbon data for Littlefield Springs suggest groundwater ages from 1,000 to 9,000 years. Because these are mixed waters, the component of discharge from the carbonate aquifer is likely much older than the groundwater ages suggested by the Littlefield Springs samples. If the dissolved-solids load from Dixie Hot Springs to the Virgin River were reduced, the irrigation water subsequently applied to agricultural fields in the St. George and Washington areas, which originates as water from the Virgin River downstream of Dixie Hot Springs, would have a lower dissolved-solids concentration. Dissolved-solids concentrations in excess irrigation water draining from the agricultural fields are about 1,700 mg/L higher than the concentrations in the Virgin River water that is currently (2014) used for irrigation that contains inflow from Dixie Hot Springs; this increase results from evaporative concentration and dissolution of mineral salts in the irrigated agricultural fields. The water samples collected from drains downgradient from the irrigated areas are assumed to include the dissolution of all available minerals precipitated in the soil during the previous irrigation season. Based on this assumption, a change to more dilute irrigation water will not dissolve additional minerals and increase the dissolved-solids load in the drain discharge. Following the hypothetical reduction of salts from Dixie Hot Springs, which would result in more dilute Virgin River irrigation water than is currently used, the dissolution of minerals left in the soil from the previous irrigation season would result in a net increase in dissolved-solids concentrations in the drain discharge, but this increase should only last one irrigation season. After one (or several) seasons of irrigating with more dilute irrigation water, mineral precipitation and subsequent re-dissolution beneath the agricultural fields should be greatly reduced, leading to a reduction in dissolved-solids load to the Virgin River below the agricultural drains. A mass-balance model was used to predict changes in the dissolved-solids load in the Virgin River if the salt discharging from Dixie Hot Springs were reduced or removed. Assuming that 33.4 or 26.7 ft 3 /s of water seeps from the Virgin River to the groundwater system upstream of the Virgin River Gorge Narrows, the immediate hypothetical reduction in dissolved-solids load in the Virgin River at Littlefield, Arizona is estimated to be 67,700 or 71,500 ton/yr, respectively. The decrease in dissolved-solids load in seepage from the Virgin River to the groundwater system is expected to reduce the load discharging from Littlefield Springs in approximately 26 years, the estimated time lag between seepage from the river and discharge of the seepage water, after subsurface transport, from Littlefield Springs. At that time, the entire reduction in dissolved solids seeping from the Virgin River is expected to be realized as a reduction in dissolved solids discharging from Littlefield Springs, resulting in an additional reduction of 24,700 ton/yr (based on 33.4 ft 3 /s of seepage loss) or 21,000 ton/yr (based on 26.7 ft 3 /s of seepage loss) in the river’s dissolved-solids load at Littlefield.

Arizona, Nevada, Utah↗

Microbial infections are associated with embryo mortality in Arctic-nesting geese.

To address the role of bacterial infection in hatching failure of wild geese, we monitored embryo development in a breeding population of Greater white-fronted geese ( Anser albifrons ) on the Arctic Coastal Plain of Alaska. During 2013, we observed mortality of normally developing embryos and collected 36 addled eggs for analysis. We also collected 17 infertile eggs for comparison. Using standard culture methods and gene sequencing to identify bacteria within collected eggs, we identified a potentially novel species of Neisseria in 33 eggs, Macrococcus caseolyticus in 6 eggs, and Streptococcus uberis and Rothia nasimurium in 4 eggs each. We detected seven other bacterial species at lower frequencies. Sequences of the 16S rRNA genes from the Neisseria isolates most closely matched sequences from N. animaloris and N. canis (96 to 97% identity), but phylogenetic analysis suggested substantial genetic differentiation between egg isolates and known Neisseria species. Although definitive sources of the bacteria remain unknown, we detected Neisseria DNA from swabs of eggshells, nest contents, and cloacae of nesting females. To assess the pathogenicity of bacteria identified in contents of addled eggs, we inoculated isolates of Neisseria , Macrococcus , Streptococcus , and Rothia at various concentrations into developing chicken eggs. Seven-day mortality rates varied from 70 to 100%, depending on the bacterial species and inoculation dose. Our results suggest that bacterial infections are a source of embryo mortality in wild geese in the Arctic.

Alaska↗

Pesticide mixtures in the Sacramento–San Joaquin Delta, 2016–17: Results from year 2 of the Delta Regional Monitoring Program

The Delta Regional Monitoring Program was developed by the Central Valley Regional Water Quality Control Board in response to the decline of pelagic fish species in the Sacramento–San Joaquin Delta that was observed in the early 2000s. The U.S. Geological Survey, in cooperation with the Delta Regional Monitoring Program, has been responsible for collecting and analyzing surface-water samples for a suite of 154 pesticides and pesticide degradates in surface water and in suspended sediment. Additional samples were collected for the analysis of dissolved organic carbon, dissolved copper, particulate organic carbon, particulate inorganic carbon, total particulate carbon, and total particulate nitrogen; and field water-quality indicators (water temperature, specific conductance, dissolved oxygen, pH, and turbidity) were measured at each site. Five integrator sites on streams draining mixed land-use watersheds were sampled monthly from July 2016 to June 2017. Two sites were sampled in the San Joaquin River watershed and one site was sampled in each of the Mokelumne River, Sacramento River, and Ulatis Creek watersheds. A total of 53 out of 154 pesticides (18 herbicides, 14 insecticides, 13 fungicides, 7 breakdown products, and 1 synergist) were detected in surface-water samples and 95 percent of samples contained mixtures of 2 or more pesticides. The most frequently detected pesticides were the herbicides hexazinone, metolachlor, and diuron (present in 83 percent, 72 percent, and 67 percent of water samples, respectively), the insecticide methoxyfenozide (present in 83 percent of samples), and the fungicides boscalid and azoxystrobin (present in 67 percent and 58 percent of samples, respectively). Pesticide concentrations detected in water samples ranged from below method detection limits to 1,300 nanograms per liter (ng/L) for the insecticide chlorantraniliprole. A total of 4 pesticides (2 herbicides and 2 insecticides) were detected in suspended-sediment samples and 13 percent of suspended-sediment samples contained at least 1 pesticide. Pesticide concentrations detected in suspended-sediment samples ranged from 4.1 to 750 ng/L, both for the herbicide pendimethalin. Six samples contained the insecticide imidacloprid at concentrations above the U.S. Environmental Protection Agency (EPA) Aquatic Life Benchmark (10 ng/L) for chronic toxicity to aquatic invertebrates. Three samples contained bifenthrin at concentrations above the EPA Aquatic Life Benchmark (1.3 ng/L) for chronic toxicity to invertebrates. One sample contained cyhalothrin at a concentration above the U.S. Aquatic Life Benchmark (3.5 ng/L) for acute toxicity to invertebrates.

California↗

Acoustic mapping as an environmental management tool: I. detection of barrels of low-level radioactive waste, Gulf of the Farallones National Marine Sanctuary, California

The oceans have been and will continue to be disposal sites for a wide variety of waste products. Often these wastes are not dumped at the designated sites or transport occurs during or after dumping, and, subsequent attempts to monitor the effects the waste products have on the environment are inadequate because the actual location of the waste is not known. Acoustic mapping of the seafloor with sidescan sonar is a very effective technique for locating and monitoring dredge-spoil material and other debris. Sidescan sonar provides an acoustic image or sonograph of the sea floor that is similar to a satellite image of the Earth's land surface. In effect sidescan sonar allows the water column to be stripped from the sea floor, thereby providing a clear, unobstructed view of the sea bed. An example of the potential of this technique is summarized herein for the Gulf of the Farallones region. More than 47 800 drums (55 gallon) and other containers of low-level radioactive waste were dumped on the continental margin offshore the San Francisco Bay between 1946 and 1970. These drums now litter a large area (1200 km 2 ) of the sea floor within the Gulf of the Farallones National Marine Sanctuary (GFNMS). The exact location of the drums and the potential hazard the drums pose to the environment are unknown. To evaluate the risk, samples of the sediment, biota and water must be collected near and distant from the concentrations of barrels. To do this the exact location of the barrels must be known prior to sampling. The USGS, through a cooperative research agreement with GFNMS, used sidescan sonar to map two areas within the sanctuary. Total sea-floor coverage was obtained and computer-processed sonographic mosaics were constructed on board ship. Many small nongeologic targets were distributed throughout the survey areas that covered about 70 km 2 on the shelf and 120 km 2 on the slope. Analysis of the sidescan data suggests that the targets are 55-gallon drums. This interpretation was confirmed at one site with an underwater video and 35-mm camera system. Data were collected with both a 30-kHz and a 120-kHz sidescan system within a 15-km 2 area on the shelf. We found that the barrels were more easily detected with the mid-range 30-kHz system than with the higher resolution 120-kHz system. Maps of barrel distribution derived from the sonographs are being used to design sampling schemes to evaluate the risk that the radioactivity may have on the biota and environment.

California↗

Invasive species and coal bed methane development in the Powder River Basin, Wyoming

One of the fastest growing areas of natural gas production is coal bed methane (CBM) due to the large monetary returns and increased demand for energy from consumers. The Powder River Basin, Wyoming is one of the most rapidly expanding areas of CBM development with projections of the establishment of up to 50,000 wells. CBM disturbances may make the native ecosystem more susceptible to invasion by non-native species, but there are few studies that have been conducted on the environmental impacts of this type of resource extraction. To evaluate the potential effects of CBM development on native plant species distribution and patterns of non-native plant invasion, 36 modified Forest Inventory and Analysis plots (each comprised of four 168-m2 subplots) were established in the Powder River Basin, Wyoming. There were 73 168-m2 subplots on control sites; 42 subplots on secondary disturbances; 14 on major surface disturbances; eight on well pads; and seven on sites downslope of CBM wells water discharge points. Native plant species cover ranged from 39.5 ?? 2.7% (mean ?? 1 SE) in the secondary disturbance subplots to 17.7 ?? 7.5% in the pad subplots. Non-native plant species cover ranged from 31.0 ?? 8.4% in the discharge areas to 14.7 ?? 8.9% in the pad subplots. The control subplots had significantly less non-native species richness than the combined disturbance types. The combined disturbance subplots had significantly greater soil salinity than the control sites. These results suggest that CBM development and associated disturbances may facilitate the establishment of non-native plants. Future research and management decisions should consider the accumulative landscape-scale effects of CBM development on preserving native plant diversity. ?? Springer Science+Business Media B.V. 2006.

Environmental Monitoring and Assessment↗