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At least 595 records · Page 33Linked to original sources
USGS2019

The Kulanaokuaiki-3 tephra, 900 CE: Products of a remarkably energetic pyroclastic eruption at Kīlauea Volcano, Hawaiʻi, USA

Eruptions of Kīlauea Volcano, Hawaiʻi, USA, can be more powerful than previously recognized. The Kulanaokuaiki-3 (K-3) eruption, ca. 900 CE, consisted of two episodes that dispersed lithic wall-rock clasts (Episode 1) and dominantly scoria (Episode 2; VEI-3) across >65 km 2 southeast of the summit. Dense 12 cm blocks of Episode 1 fell 8–10 km from the summit vent, and 2–4 cm lithic lapilli reached the coastline, 17 km from the vent. The Episode 2 deposit is chemically zoned, indicating orderly eruption from a layered magma body analogous to the 1959 Kīlauea Iki lava lake. Olivine-hosted melt inclusions suggest a magma body within 1 km of the surface. Some Episode 1 lithic clasts have magmatic rinds chemically similar to the early Episode 2 scoria, suggesting a genetic link, although each had a distinct eruption mechanism. Southeastward tephra dispersal counter to NE trade winds implies dispersal by jet-stream winds. The dispersal of lithic clasts in Episode 1 cannot be explained by ballistic trajectories or by transport in a buoyant plume. Calculations instead indicate that a jet from a vent with a minimum diameter of 50 m, a velocity of at least 300 m/s, and a duration of ∼60 s could have lifted the lithic clasts into the jet stream. Isopach and isopleth maps for Episode 2 indicate a subplinian column height of 14–18 km and a duration of 2–3 h, assuming constant flux. The Episode 1 conduit probably intersected or otherwise lowered pressure within a compositionally zoned magma body, triggering eruption of the Episode 2 scoria.

Hawaii↗
USGS1994

Seawater as the source of minor elements in black shales, phosphorites and other sedimentary rocks

Many of the minor elements in seawater today have a concentration-depth profile similar to that of the biologically essential nutrients, NO-3 and PO3-4. They show a relative depletion in the photic zone and enrichment in the deep ocean. The difference between their surface- and deep-ocean values, normalized to the change in PO3-4, approaches the average of measured minor-element: P ratios in marine plankton, although individual analyses of the latter show extreme scatter for a variety of reasons. Despite this scatter in the minor-element analyses of plankton, agreement between the two sets of data shows unequivocally that an important marine flux of many minor elements through the ocean is in the form of biogenic matter, with a composition approaching that of plankton. This interpretation is further supported by sediment studies, particularly of sediments which accumulate in shelf-slope environments where biological productivity in the photic zone is exceptionally high and organic carbon contents of the underlying sediment elevated. The interelement relations observed for some of these sediments approach the average values of plankton. These same interelement relations are observed in many marine sedimentary rocks such as metalliferous black shales and phosphorites, rocks which have a high content of marine fractions (e.g., organic matter, apatite, biogenic silica and carbonates). Many previous studies of the geochemistry of these rocks have concluded that local hydrothermal activity, and/or seawater with an elemental content different from that of the modern ocean, was required to account for their minor-element contents. However, the similarity in several of the minor-element ratios in many of these formations to minor-element ratios in modern plankton demonstrates that these sedimentary rocks accumulated in environments whose marine chemistry was virtually identical to that seen on continental shelf-slopes, or in marginal seas, of the ocean today. The accumulation of the marine fraction of minor elements on these ancient sea floors was determined largely by the accumulation of organic matter, settling from the photic zone and with a composition of average plankton. A second marine fraction of minor elements in these rocks accumulated through precipitation and adsorption from seawater. The suite of elements in this fraction reflects redox conditions in the bottom water, as determined by bacterial respiration. For example, high Mn, high Cr+V and high Mo concentrations, above those which can be attributed to the accumulation of planktonic matter, characterize accumulation under bottom-water oxidizing, denitrifying and sulfate-reducing conditions, respectively. ?? 1994.

Chemical Geology↗
USGS1967

Shock effects in certain rock-forming minerals

Shock effects in quartz, plagioclase, biotite, amphibole, and some accessory minerals have been observed in rocks subjected to various degrees of meta morphism by meteoritic impact. The shock features described are unique; they are never observed in rocks from normal geologic environments. Such features are described: 1) Multiple sets of closely spaced planar microstructures occur in quartz, plagioclase, and other rock-forming minerals. Those characteristic of shock consist of alternating platelets, with a range of reduced mean index of re fraction and birefringence; they con sist of platelets that have been partially or completely transformed to an amor phous phase. 2) Quartz and plagioclase are selec tively and completely transformed to silica glass and plagioclase glass in the solid state, whereas the associated mafic minerals remained crystalline. There is no reaction between adjacent minerals. 3) High-pressure polymorphs occur, such as coesite or stishovite. Coesite oc Curs exclusively within silica glass; it has not been observed as a reaction or breakdown product. 4) Nickel-iron spherules occur in the fused glass or impactites. 5) The occurrence of droplets of ilmenite, rutile, pseudobrookite, and baddaleyite in impactites indicates a temperature of formation exceeding 150°C. 6) Dense glass occurs, similar in composition to bulk rock, in which iron oxide, such as fine particles of mag netite, is completely dissolved. All these features are characteristic of a process involving the rapid rise and fall of extremiiely high pressures and temperatures. Minerals and mineral as semblages experiencing such high strain rates and sudden changes of pressures and temperatures react and change in dependently to the bulk chemical com position, under nonequilibrium condi tions. Many aspects of shock features re quire careful study. Kink bands in biotite and deformation lamellae in quartz occur in tectonically deformed rocks. These features should be studied with great care in order to determine whether reduction in mean index of refraction and total birefringence along the planar structures have resulted from vitrification or phase transition; their presence is additional evidence in favor of a shock mechanism. Vitreous phases or glasses formed by shock also have many unique prop erties; they have not been studied by such methods as thermoluminescence, electron spin resonance, low-angle x ray diffraction, or infrared spectroscopy. Shock-fused glass of high density needs to be studied in detail in carefully con trolled laboratory conditions. Experimental shock-wave studies of the equation-of-state of single minerals and mineral assemblages, under care fully controlled conditions, must pre cede estimates of peak pressures and peak and residual temperatures of shocked natural mineral assemblages. Detailed petrographic and mineralogic studies, however, have provided useful and definitive criteria for characteriza tion of impact events. Such data should be of paramount importance in the study of samples brought back from Moon.

Science↗
USGS2005

Hydrogeologic framework, ground-water quality, and simulation of ground-water flow at the Fair Lawn Well Field Superfund site, Bergen County, New Jersey

Production wells in the Westmoreland well field, Fair Lawn, Bergen County, New Jersey (the 'Fair Lawn well field Superfund site'), are contaminated with volatile organic compounds, particularly trichloroethylene, tetrachloroethylene, and 1,1,1-trichloroethane. In 1983, the U.S. Environmental Protection Agency (USEPA) placed the Westmoreland well field on its National Priority List of Superfund sites. In an effort to determine ground-water flow directions, contaminant-plume boundaries, and contributing areas to production wells in Fair Lawn, and to evaluate the effect of present pump-and-treat systems on flowpaths of contaminated ground water, the U.S. Geological Survey (USGS), in cooperation with the USEPA, developed a conceptual hydrogeologic framework and ground-water flow model of the study area. MODFLOW-2000, the USGS three-dimensional finite-difference model, was used to delineate contributing areas to production wells in Fair Lawn and to compute flowpaths of contaminated ground water from three potential contaminant sources to the Westmoreland well field. Straddle-packer tests were used to determine the hydrologic framework of, distribution of contaminants in, and hydrologic properties of water-bearing and confining units that make up the fractured-rock aquifer underlying the study area. The study area consists of about 15 square miles in and near Fair Lawn. The area is underlain by 6 to 100 feet of glacial deposits and alluvium that, in turn, are underlain by the Passaic Formation. In the study area, the Passaic Formation consists of brownish-red pebble conglomerate, medium- to coarse-grained feldspathic sandstone, and micaceous siltstone. The bedrock strata strike N. 9o E. and dip 6.5o to the northwest. The bedrock consists of alternating layers of densely fractured rocks and sparsely fractured rocks, forming a fractured-rock aquifer. Ground-water flow in the fractured-rock aquifer is anisotropic as a result of the interlayering of dipping water-bearing and confining units. Wells of similar depth aligned along the strike of the bedding intersect the same water-bearing units, but wells aligned along the dip of the bedding may intersect different water-bearing units. Consequently, wells aligned along strike are in greater hydraulic connection than wells aligned along dip. The Borough of Fair Lawn pumps approximately 770 million gallons per year from 13 production wells. Hydrographs from six observation wells ranging in depth from 162 to 505 feet in Fair Lawn show that water levels in much of the study area are affected by pumping. Straddle packers were used to isolate discrete intervals within six open-hole observation wells owned by the Fair Lawn Water Department. Transmissivity, water-quality, and static-water-level data were obtained from the isolated intervals. Measured transmissivity ranged from near 0 to 8,900 feet squared per day. The broad range in measured transmissivity is a result of the heterogeneity of the fractured-rock aquifer. Eight water-bearing units and eight confining units were identified in the study area on the basis of transmissivity. The water-bearing units range in thickness from 21 to 95 feet; the mean thickness is 50 feet. The confining units range in thickness from 22 to 248 feet; the mean thickness is 83 feet. Water-level and water-quality data indicate effective separation of water-bearing units by the confining units. Water-quality samples were collected from the six observation wells at 16 depth intervals isolated by the straddle packers in 2000 and 2001. Concentrations of volatile organic compounds generally were low in samples from four of the wells, but were higher in samples from a well in Fair Lawn Industrial Park and in a well in the Westmoreland well field. The digital ground-water flow model was used to simulate steady-state scenarios representing conditions in the study area in 1991 and 2000. These years were chosen because during the intervening period,

Scientific Investigations Report↗
USGS2003

Potential for deep basin-centered gas accumulation in Travis Peak (Hosston) Formation, Gulf Coast Basin, U.S.A.

The potential of Lower Cretaceous sandstones of the Travis Peak Formation in the northern Gulf Coast Basin to harbor a basin-centered gas accumulation was evaluated by examining (1) the depositional and diagenetic history and reservoir properties of Travis Peak sandstones, (2) the presence and quality of source rocks for generating gas, (3) the burial and thermal history of source rocks and time of gas generation and migration relative to tectonic development of Travis Peak traps, (4) gas and water recoveries from drill-stem and formation tests, (5) the distribution of abnormal pressures based on shut-in-pressure data, and (6) the presence or absence of gas-water contacts associated with gas accumulations in Travis Peak sandstones. The Travis Peak Formation (and correlative Hosston Formation) is a basinward-thickening wedge of terrigenous clastic sedimentary rocks that underlies the northern Gulf Coast Basin from eastern Texas across northern Louisiana to southern Mississippi. Clastic influx was focused in two main fluvial-deltaic depocenters—one located in northeastern Texas and the other in southeastern Mississippi and northeastern Louisiana. Across the main hydrocarbon-productive trend in eastern Texas and northern Louisiana, the Travis Peak Formation is about 2,000 ft thick. Most Travis Peak hydrocarbon production in eastern Texas comes from drilling depths between 6,000 and 10,000 ft. Significant decrease in porosity and permeability occurs through that depth interval. Above 8,000-ft drilling depth in eastern Texas, Travis Peak sandstone matrix permeabilities often are significantly higher than the 0.1-millidarcy (mD) cutoff that characterizes tight-gas reservoirs. Below 8,000 ft, matrix permeability of Travis Peak sandstones is low because of pervasive quartz cementation, but abundant natural fractures impart significant fracture permeability. Although pressure data within the middle and lower Travis Peak Formation are limited in eastern Texas, overpressured reservoirs caused by thermal generation of gas, typical of basin-centered gas accumulations, are not common in the Travis Peak Formation. Significant overpressure was found in only one Travis Peak sandstone reservoir in 1 of 24 oil and gas fields examined across eastern Texas and northern Louisiana. The presence of gas-water contacts is perhaps the most definitive criterion indicating that a gas accumulation is conventional rather than a “sweet spot” within a basin-centered gas accumulation. Hydrocarbon-water contacts within Travis Peak sandstone reservoirs were documented in 17 fields and probably occur in considerably more fields across the productive Travis Peak trend in eastern Texas and northern Louisiana. All known hydrocarbon-water contacts in Travis Peak reservoirs in eastern Texas, however, occur within sandstones in the upper 500 ft of the formation. Although no gas-water contacts have been reported within the lower three-fourths of the Travis Peak Formation in northeastern Texas, gas production from that interval is limited. The best available data suggest that most middle and lower Travis Peak sandstones are water bearing in northeastern Texas. Insufficient hydrocarbon charge relative to permeability of Travis Peak reservoirs might be responsible for lack of overpressure and basin-centered gas within the Travis Peak Formation. Shales interbedded with Travis Peak sandstones in eastern Texas are primarily oxidized flood-plain deposits with insufficient organic-carbon content to be significant sources of oil and gas. The most likely source rocks for hydrocarbons in Travis Peak reservoirs are two stratigraphically lower units, the Jurassic-age Bossier Shale of the Cotton Valley Group, and laminated, lime mudstones of the Jurassic Smackover Formation. Hydrocarbon charge, therefore, might be sufficient for development of conventional gas accumulations, but it is insufficient for development of basin-centered gas as a result of the absence of proximal source rocks and a lack of effective migration pathways from stratigraphically or geographically distant source rocks.

Louisiana, Mississippi, Texas↗
USGS1967

Ground water in the Eola-Amity Hills area, northern Willamette Valley, Oregon

The Eola-Amity Hills area ,comprises about 230 square miles on the west side of the Willamette Valley between Salem and McMinnville, Oreg. The area is largely rural, and agriculture is the principal occupation. Rocks ranging in age from Eocene to Recent underlie the area. The oldest rocks are a sequence more than 5,000 feet thick of marine-deposited shale and siltstone strata, with thin interbeds of sandstone that range in age from Eocene to middle Oligocene. They are widely exposed in and west of the Eola-Amity Hills and underlie younger sedimentary and volcanic rocks throughout the study area. In the Eola-Amity Hills and Red Hills of Dundee, the Columbia River Group, a series of eastward-dipping basaltic lava flows locally of Miocene age, and conformably overlies the marine sedimentary rocks. The Columbia River Group ranges in thickness from less than 1 foot to about 900 feet and has an average thickness of about 200 feet. The formation is exposed in the Eola-Amity Hills and Red Hills of Dundee and, at places, extends to the east beneath younger rocks. Overlying the Columbia River Group and marine sedimentary rocks are nonmarine sedimentary deposits that range in thickness from less than 1 foot, where they lap up (to an altitude of about 200 ft) on the flanks of the higher hills, to several hundred feet along the east margin of the study area. These deposits include the Troutdale Formation of Pliocene age, the Willamette Silt of late Pleistocene age, and alluvium of the Willamette River and its tributaries. The Troutdale Formation and the alluvium of the Willamette River contain the most productive aquifers in the Eola-Amity Hills area. These aquifers, which consist mainly of sand and gravel, generally yield moderate to large quantities of water to properly constructed wells. Basalt of the Columbia River Group yields small to moderate quantities of water to wells, and the marine sedimentary rocks and Willamette Silt generally yield small but adequate quantities of water for domestic and stock supplies. Ground water from the Columbia River Group and nonmarine sedimentary rocks is chemically suitable for irrigation and other uses, as is the water from shallow depths in the marine sedimentary rocks. However, water from depths of more than several hundred feet in the marine sedimentary rocks contains large amounts of chloride and other dissolved mineral constitutents that make it unsuitable for most uses. Samples from three fairly closely spaced wells obtaining water from depth zones of 50 to 77, 191 to 201, and about 2,000 feet contained 172, 1,160, and 26,000 ppm (parts per million) of chloride, respectively. About 6,100 acre-feet of ground water was pumped from wells and withdrawn from springs for various uses during 1964; of this amount about 4,800 acre-feet was used for irrigation. The total volume of ground water withdrawn and put to beneficial use each year is small compared with the amount that discharges naturally by evapotranspiration and through undeveloped seeps and springs. Much of the natural discharge could be intercepted and put to beneficial use by pumping from wells. Major problems affecting the development of ground water in the area include a) uneven areal distribution of permeable rocks, (b) undesirable chemical quality of the ground water locally in the marine sedimentary rocks, and (c) fine sand entering wells that tap the Troutdale Formation and thereby causing loss of well efficiency and costly wear on pumps and water-supply systems.

Water Supply Paper↗
USGS2004

Preliminary geologic map of the Big Bear City 7.5' Quadrangle, San Bernardino County, California

This data set maps and describes the geology of the Big Bear City 7.5' quadrangle, San Bernardino County, California. Created using Environmental Systems Research Institute's ARC/INFO software, the data base consists of the following items: (1) a rock-unit coverage and attribute tables (polygon and arc) containing geologic contacts, units and rock-unit labels as annotation which are also included in a separate annotation coverage, bbc_anno (2) a point coverage containing structural point data and (3) a coverage containing fold axes. In addition, the data set includes the following graphic and text products: (1) A PostScript graphic plot-file containing the geologic map, topography, cultural data, a Correlation of Map Units (CMU) diagram, a Description of Map Units (DMU), an index map, a regional geologic and structure map, and an explanation for point and line symbols; (2) PDF files of the Readme (including the metadata file as an appendix), and a screen graphic of the plot produced by the PostScript plot file. The geologic map describes a geologically complex area on the north side of the San Bernardino Mountains. Bedrock units in the Big Bear City quadrangle are dominated by (1) large Cretaceous granitic bodies ranging in composition from monzogranite to gabbro, (2) metamorphosed sedimentary rocks ranging in age from late Paleozoic to late Proterozoic, and (3) Middle Proterozoic gneiss. These rocks are complexly deformed by normal, reverse, and thrust faults, and in places are tightly folded. The geologic map database contains original U.S. Geological Survey data generated by detailed field observation and by interpretation of aerial photographs. The map data was compiled on base-stable cronoflex copies of the Big Bear City 7.5' topographic map, transferred to a scribe-guide and subsequently digitized. Lines, points, and polygons were edited at the USGS using standard ARC/INFO commands. Digitizing and editing artifacts significant enough to display at a scale of 1:24,000 were corrected. Within the database, geologic contacts are represented as lines (arcs), geologic units as polygons, and site-specific data as points. Polygon, arc, and point attribute tables (.pat, .aat, and .pat, respectively) uniquely identify each geologic datum.

Open-File Report↗
USGS2014

Pb-Sr-Nd-O isotopic characterization of Mesozoic rocks throughout the northern end of the Peninsular Ranges batholith: Isotopic evidence for the magmatic evolution of oceanic arc–continental margin accretion during the Late Cretaceous of southern California

Within the duration of the U.S. Geological Survey (USGS)–based Southern California Areal Mapping Project (SCAMP), many samples from the northern Peninsular Ranges batholith were studied for their whole-rock radioisotopic systematics (rubidium-strontium [Rb-Sr], uranium-thorium-lead [U-Th-Pb], and samarium-neodymium [Sm-Nd]), as well as oxygen (O), a stable isotope. The results of three main studies are presented separately, but here we combine them (>400 analyses) to produce a very complete Pb-Sr-Nd-O isotopic profile of an arc-continent collisional zone—perhaps the most complete in the world. In addition, because many of these samples have U-Pb zircon as well as argon mineral age determinations, we have good control of the timing for Pb-Sr-Nd-O isotopic variations. The ages and isotopic variations help to delineate at least four zones across the batholith from west to east—an older western zone (126–108 Ma), a transitional zone (111–93 Ma), an eastern zone (94–91 Ma), and a much younger allochthonous thrust sheet (ca. 84 Ma), which is the upper plate of the Eastern Peninsular Ranges mylonite zone. Average initial 87 Sr/ 86 Sr (Sr i ), initial 206 Pb/ 204 Pb ( 206 Pb i ), initial 208 Pb/ 204 Pb (average 208 Pb i ), initial epsilon Nd (average ε Ndi ), and δ 18 O signatures range from 0.704, 18.787, 38.445, +3.1, and 4.0‰–9.0‰, respectively, in the westernmost zone, to 0.7071, 19.199, 38.777, −5, and 9‰–12‰, respectively, in the easternmost zone. The older western zone is therefore the more chemically and isotopically juvenile, characterized mostly by values that are slightly displaced from a mantle array at ca. 115 Ma, and similar to some modern island-arc signatures. In contrast, the isotopic signatures in the eastern zones indicate significant amounts of crustal involvement in the magmatic plumbing of those plutons. These isotopic signatures confirm previously published results that interpreted the Peninsular Ranges batholith as a progressively contaminated magmatic arc. The Peninsular Ranges batholith magmatic arc was initially an oceanic arc built on Panthalassan lithosphere that eventually evolved into a continental margin magmatic arc collision zone, eventually overriding North American cratonic lithosphere. Our Pb-Sr-Nd data further suggest that the western arc rocks represent a nearshore or inboard oceanic arc, as they exhibit isotopic signatures that are more enriched than typical mid-ocean-ridge basalt (MORB). Isotopic signatures from the central zone are transitional and indicate that enriched crustal magma sources were becoming involved in the northern Peninsular Ranges batholith magmatic plumbing. As the oceanic arc–continental margin collision progressed, a mixture of oceanic mantle and continental magmatic sources transpired. Magmatic production in the northern Peninsular Ranges batholith moved eastward and continued to tap enriched crustal magmatic sources. Similar modeling has been previously proposed for two other western margin magmatic arcs, the Sierra Nevada batholith of central California and the Idaho batholith. Calculated initial Nd signatures at ca. 100 Ma for Permian–Jurassic and Proterozoic basement rocks from the nearby San Gabriel Mountains and possible source areas along the southwestern Laurentian margin of southern California, southwestern Arizona, and northern Sonora strongly suggest their involvement with deep crustal magma mixing beneath the eastern zones of the Peninsular Ranges batholith, as well as farther east in continental lithospheric zones. Last, several samples from the allochthonous, easternmost upper-plate zone, which are considerably younger (ca. 84 Ma) than any of the rocks from the northern Peninsular Ranges batholith proper, have even more enriched average Sr i , 206 Pb i , 208 Pb i , and ε Ndi signatures of 0.7079, 19.344, 38.881, and −6.6, respectively, indicative of the most-evolved magma sources in the northern Peninsular Ranges batholith and similar to radioisotopic values for rocks from the nearby Transverse Ranges, suggesting a genetic connection between the two.

Book chapter↗
USGS2001

Holocene geomagnetic secular variation recorded by volcanic deposits at Mount St. Helens, Washington

A compilation of paleomagnetic data from volcanic deposits of Mount St. Helens is presented in this report. The database is used to determine signature paleomagnetic directions of products from its Holocene eruptive events, to assign sampled units to their proper eruptive period, and to begin the assembly of a much larger database of paleomagnetic directions from Holocene volcanic rocks in western North America. The paleomagnetic results from Mount St. Helens are mostly of high quality, and generally agree with the division of its volcanic deposits into eruptive episodes based on previous geologic mapping and radiocarbon dates. The Muddy River andesite's paleomagnetic direction, however, indicates that it is more likely part of the Pine Creek eruptive period rather than the Castle Creek period. In addition, the Two-Fingers andesite flow is more likely part of the Middle Kalama eruptive period and not part of the Goat Rocks period. The paleomagnetic data from Mount St. Helens and Mount Hood document variation in the geomagnetic field's pole position over the last ~2,500 years. A distinct feature of the new paleosecular variation (PSV) record, similar to the Fish Lake record (Oregon), indicates a sudden change from rapid clockwise movement of the pole about the Earth's spin axis to relatively slow counterclockwise movement at ???800 to 900 years B.P.

Bulletin of Volcanology↗
USGS1983

Sm-Nd age and isotopic systematics of the bimodal suite, ancient gneiss complex, Swaziland

Studies of the development and stabilization of the Archaean crust often focus on the relative temporal relationships between the metamorphosed basaltic to ultramafic volcanic units (greenstone belts) and the sialic gneiss terrains that make up the oldest sections of the terrestrial crust. At the heart of this interest are the questions of the processes responsible for crust formation in the Archaean and whether or not the various units of an Archaean crustal section represent new additions to the crust from the mantle or are products of the reprocessing of even older crustal materials. One area where this controversy has been particularly pronounced is the Archaean crustal section of south-west Africa1-6. The oldest rocks in the Kaapvaal craton consist of the Onverwacht Group of mafic to ultramafic metavolcanics of the Barberton greenstone belt and a grey-gneiss complex termed the ancient gneiss complex (AGC) of Swaziland. We report here the results of a whole-rock Sm-Nd isotopic study of the AGC and the implications these data may have for crustal evolution in the Kaapvaal craton. ?? 1983 Nature Publishing Group.

Nature↗
USGS1968

Hypogene veins of gibbsite, pyrolusite, and lithiophorite in Nye County, Nevada

Gibbsite, lithiophorite, pyrolusite, and goethite, plus discrete mixtures of gibbsite and lithiophorite and of gibbsite and iron oxide, occur as replacement veins in limestone. Minor accessories are barite, alunite, opal. Minerals of wall-rock alteration are garnet, idocrase, K-feldspar, prehnite, sericite, and quartz. These silicates formed at higher temperature than the vein minerals, but the whole sequence is considered to be a product of the same solutions, of deep-seated origin, deposited over a long period of time.

Nevada↗
USGS2021

Geologic assessment of undiscovered oil and gas resources in the Cherokee Platform area of Kansas, Oklahoma, and Missouri

In 2015, the U.S. Geological Survey completed a geology-based assessment to estimate the volumes of undiscovered, technically recoverable petroleum resources in the Cherokee Platform Province area of southeastern Kansas, northeastern Oklahoma, and southwestern Missouri. The U.S. Geological Survey identified four stratigraphic intervals that contain petroleum source rocks: (1) thin shales in the Middle to Upper Ordovician Simpson Group, (2) shales within the Upper Devonian to Lower Mississippian Woodford Shale and stratigraphically equivalent Chattanooga Shale, (3) coals and coal-associated shales and mudstones in the Middle Pennsylvanian (Desmoinesian) Cherokee and Marmaton Groups, and (4) thin marine shales within the Marmaton Group and the Upper Pennsylvanian (Missourian) Kansas City and Lansing Groups. Based on the nature of the petroleum accumulations, the characterization of the compositions and thermal maturity of the organic matter in the rocks, and the compositions of the produced petroleum, the U.S. Geological Survey identified three total petroleum systems (TPS) containing four assessment units (AU): the Paleozoic Composite TPS with the Paleozoic Conventional Assessment Unit (AU), the Woodford/Chattanooga TPS with the Woodford Shale Oil AU and the Woodford Biogenic Gas AU, and the Desmoinesian Coal TPS with the Desmoinesian Coalbed Gas AU. Assessment unit summaries follow 1. Three source rock intervals have contributed geochemically distinct oils to reservoirs within the Paleozoic Conventional AU. These intervals are the Simpson Group; the Woodford and Chattanooga Shales; and the Marmaton, Kansas City, and Lansing Groups. The major petroleum source rocks are the Woodford and Chattanooga Shales. The Paleozoic Conventional AU includes reservoirs that range in age from the Upper Cambrian Arbuckle Group to the lower Permian Chase Group. Most oil production in the province has been from Pennsylvanian sandstone reservoirs. Estimated undiscovered petroleum resources for this AU are a mean of 3 million barrels of oil (MMBO), 140 billion cubic feet of gas (BCFG), and 4 million barrels of natural gas liquids (MMBNGL). 2. The Woodford Shale Oil AU contains undiscovered continuous petroleum resources within the Woodford Shale and Chattanooga Shale. The geologic model for the AU assumes that petroleum resources remain trapped within the shale following petroleum migration. For most of the AU, organic matter within the Woodford Shale and Chattanooga Shale is thermally mature with respect to petroleum generation as shown by vitrinite reflectance values between 0.6 and 1 percent. Petroleum has been produced from the Woodford Shale and Chattanooga Shale. Estimated undiscovered petroleum resources for this AU are means of 460 MMBO, 640 BCFG, and 7 MMBNGL. 3. The Woodford Shale Biogenic Gas AU contains undiscovered continuous petroleum resources in the east-central portion of the Cherokee Platform Province near the Ozark uplift where the Woodford Shale and Chattanooga Shale are at depths of 1,250 ft or shallower. At those depths, methanogenesis and(or) biodegradation of thermogenic natural gases can be found where the shale may be more fractured and more susceptible to groundwater penetrations. The mean assessed volume of undiscovered gas for this assessment unit is 416 BCFG and 1 MMBNGL. 4. The Desmoinesian Coalbed Gas AU contains undiscovered continuous petroleum resources within the Middle Pennsylvanian coals and coal-associated shales and mudstones. The boundaries for the Desmoinesian Coalbed Gas AU are, in part, defined by the extent, depth, and thickness of the coals. Within the Desmoinesian Coalbed Gas AU, a sweet spot area was delineated based on a 10 foot or greater net coal thickness. Gas analytical data show that natural gas produced from the coals has a mixed biogenic and thermogenic origin and that there is significant migration of natural gas into the coals from adjacent conventional sandstone reservoirs. The estimated mean volume of undiscovered gas is 10.0 trillion cubic ft of gas (TCFG), and 23 MMBNGL. For the three continuous (unconventional) assessment units and one conventional assessment unit in the Cherokee Platform Province, total mean volumes of undiscovered petroleum resources are estimated to be 463 MMBO, 11.2 TCFG and 35 MMBNGL.

Kansas, Missouri, Oklahoma↗
USGS1996

Long-term geochemical surveillance of fumaroles at Showa-Shinzan dome, Usu volcano, Japan

This study investigates 31 years of fumarole gas and condensate (trace elements) data from Showa-Shinzan, a dacitic dome-cryptodome complex that formed during the 1943-1945 eruption of Usu volcano. Forty-two gas samples were collected from the highest-temperature fumarole, named A-1, from 1954 (800??C) to 1985 (336??C), and from lower-temperature vents. Condensates were collected contemporaneously with the gas samples, and we reanalyzed ten of these samples, mostly from the A-1 vent, for 32 cations and three anions. Modeling using the thermochemical equilibrium program, SOLVGAS, shows that the gas samples are mild disequilibrium mixtures because they: (a) contain unequilibrated sedimentary CH4 and NH3; (b) have unequilibrated meteoric water; or (c) lost CO, either by air oxidation or by absorption by the sodium hydroxide sampling solution. SOLVGAS also enabled us to restore the samples by removing these disequilibrium effects, and to estimate their equilibrium oxygen fugacities and amounts of S2 and CH4. The restored compositions contain > 98% H2O with minor to trace amounts of CO2, H2, HCl, SO2, HF, H2S, CO, S2 and CH4. We used the restored gas and condensate data to test the hypotheses that these time-series compositional data from the dome's fumaroles provide: (1) sufficient major-gas data to analyze long-term degassing trends of the dome's magma-hydrothermal system without the influence of sampling or contamination effects; (2) independent oxygen fugacity-versus-temperature estimates of the Showa-Shinzan dacite; (3) the order of release of trace elements, especially metals, from magma; and (4) useful information for assessing volcanic hazards. The 1954-1985 restored A-1 gas compositions confirm the first hypothesis because they are sufficient to reveal three long-term degassing trends: (1) they became increasingly H2O-rich with time due to the progressive influx of meteoric water into the dome; (2) their C/S and S/Cl ratios decreased dramatically while their Cl/F ratios stayed roughly constant, indicating the progressive outgassing of less soluble components (F ??? Cl > S > C) from the magma reservoir; and (3) their H2O/H2, CO2/CO and H2S/SO2 ratios increased significantly in concert with equilibrium changes expected for the ??? 500??C temperature drop. When plotted against reciprocal temperature, the restored-gas log oxygen fugacities follow a tight linear trend from < NNO + 0.5 at > 800??C to NNO + 2.5 at ??? 400??C. This trend largely disproves the second hypothesis because the oxygen fugacities for the < 800??C restored gases can only be explained by mixing of hot magmatic gases with ??? 350??C steam from superheated meteoric water. But above 800??C this trend intersects the opposing linear trend for other Usu eruptive products, implying a log oxygen fugacity of -11.45 at 902??C for the Showa-Shinzan magma. The time-series trace-element data also disprove the third hypothesis because rock- and incrustation-particle contaminants in the condensates account for most of the trace-element variation. Nonetheless, highly volatile elements like B and As are relatively unaffected by this particle contamination, and they show similar time-series trends as Cl and F. Finally, except for infrequent sampling around the 1977 Usu eruption, the results generally confirm the fourth hypothesis, since the time-series trends for the major gases and selected trace elements indicate that, with time, the system cooled, degassed and was infiltrated by meteoric water, all of which are positive signs that volcanic activity declined over the 31-year history. This study also suggests that second boiling of shallow magma within and possibly beneath the cryptodome sustained magmatic degassing for at least 20 years after emplacement.

Journal of Volcanology and Geothermal Research↗
USGS1973

Ground water in the Eugene-Springfield area, southern Willamette Valley, Oregon

The cities of Eugene and Springfield and their outlying suburban and rural districts constitute an area of rapid population growth where progressively greater volumes of ground water are being required for irrigation and industrial and public supplies. The area is also one of diverse geologic and hydrologic conditions. As used in this report, the Eugene-Springfield area covers about 450 square miles and includes a part of the lower foothills of the Coast and Cascade Ranges and a strip of the main valley plain of the southern Willamette Valley. Volcanic and sedimentary rock units exposed in the foothills range in age from Eocene to Miocene. In the main valley plain the older units are overlain by Pleistocene and Holocene alluvial deposits. Marine-deposited sandstone, siltstone, shale, and mudstone of the older sedimentary units are fine grained and poorly permeable and yield water slowly to wells. The volcanic rocks, primarily of dacitic and andesitic composition, yield small quantities of water that are generally adequate only for domestic use. The alluvial deposits (sand and gravel) of the valley plain (central lowland) contain the most productive aquifers in the area and are considered to be the only ground-water reservoir for which large-scale development of ground-water supplies is feasible. Aquifers in the area are recharged principally by direct infiltration of precipitation. Most of the precipitation, which averages about 4C inches per year, occurs during late autumn and winter. Minimum recharge by infiltration of precipitation to the alluvial aquifers beneath the valley plain is estimated to be about 100,000 acre-feet. Ground water is discharged naturally from the central lowland by seepage and spring flow to small streams, by subsurface outflow to adjacent areas, and by evapotranspiration. Storage capacity of the central lowland in the Eugene-Springfield area is estimated to be about 2.1 million acre-feet in the zone 10-150 feet below land surface. The quantity of ground water available annually from this area is far greater than the 23,000 acre-feet pumped for all uses in 1968. This pumpage was about 23 percent of the perennial yield (100,000 acre-ft), and about 77,000 acre-feet of water was left available for additional withdrawal. If annual withdrawals of water were increased to 100,000 acre-feet per year, the levels in the ground-water reservoir would be lowered. Once new equilibriums are established, increased withdrawals could be accommodated without progressive losses in aquifer storage or excessive losses in flow of the larger streams. Ground water from the alluvial deposits of the valley plain is chemically suitable for irrigation and other uses, as is most of the water obtained from perched-water bodies in the sedimentary and volcanic rocks. However, the mineral content of water from the older sedimentary rocks, particularly from deeper producing zones, is greater than the mineral content of water from the alluvial deposits. Locally, some of the water from the older rocks is too saline for most uses. Increased use of ground water may result in certain problems pertaining to waste-disposal practices, local overdraft of aquifers, well interference, and well construction. Present data are adequate to evaluate some of the factors relating to foreseeable problems but allow only tentative conclusions to be drawn about other factors, which include local direction of flow, rate of ground-water movement, and areas of possible ground-water contamination. Additional information obtained through systematic study will be needed to deal with these problems.

Oregon↗
USGS2004

Geochemical models of metasomatism in ultramafic systems: Serpentinization, rodingitization, and sea floor carbonate chimney precipitation

In a series of water-rock reaction simulations, we assess the processes of serpentinization of harzburgite and related calcium metasomatism resulting in rodingite-type alteration, and seafloor carbonate chimney precipitation. At temperatures from 25 to 300??C (P = 10 to 100 bar), using either fresh water or seawater, serpentinization simulations produce an assemblage commonly observed in natural systems, dominated by serpentine, magnetite, and brucite. The reacted waters in the simulations show similar trends in composition with decreasing water-rock ratios, becoming hyper-alkaline and strongly reducing, with increased dissolved calcium. At 25??C and w/r less than ???32, conditions are sufficiently reducing to yield H2 gas, nickel-iron alloy and native copper. Hyperalkalinity results from OH- production by olivine and pyroxene dissolution in the absence of counterbalancing OH- consumption by alteration mineral precipitation except at very high pH; at moderate pH there are no stable calcium minerals and only a small amount of chlorite forms, limited by aluminum, thus allowing Mg2+ and Ca2+ to accumulate in the aqueous phase in exchange for H+. The reducing conditions result from oxidation of ferrous iron in olivine and pyroxene to ferric iron in magnetite. Trace metals are computed to be nearly insoluble below 300??C, except for mercury, for which high pH stabilizes aqueous and gaseous Hg??. In serpentinization by seawater at 300??C, Ag, Au, Pd, and Pt may approach ore-forming concentrations in sulfide complexes. Simulated mixing of the fluid derived from serpentinization with cold seawater produces a mineral assemblage dominated by calcite, similar to recently discovered submarine, ultramafic rock-hosted, carbonate mineral deposits precipitating at hydrothermal vents. Simulated reaction of gabbroic or basaltic rocks with the hyperalkaline calcium- and aluminum-rich fluid produced during serpentinization at 300??C yields rodingite-type mineral assemblages, including grossular, clinozoisite, vesuvianite, prehnite, chlorite, and diopside. ?? 2004 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗
USGS2013

Descriptive and geoenvironmental model for Co-Cu-Au deposits in metasedimentary rocks

Introduction This report is a revised model for a specific type of cobalt-copper-gold (Co-Cu-Au) deposit that will be evaluated in the next U.S. Geological Survey (USGS) assessment of undiscovered mineral resources in the United States (see Ferrero and others, 2012). Emphasis is on providing an up-to-date deposit model that includes both geologic and geoenvironmental aspects. The new model presented here supersedes previous USGS models by Earhart (1986) and Evans and others (1995), which are based solely on deposits in the Blackbird mining district of central Idaho. This report is a broader synthesis of information on 19 Co-Cu-Au deposits occurring in predominantly metasedimentary successions worldwide (table 1–1) that generally share common geologic, mineralogical, and geochemical features; preliminary summary versions were presented in Slack and others (2010) and Slack and others (2011), which are superseded by this report. As defined herein, the individual Co-Cu-Au deposits are located more than 500 meters from similar deposits and contain 0.1 percent or more by weight of Co in ore or mineralized rock; some deposits included in the database lack reported average Co grades, but they contain high Co concentrations, at least locally. Most of the deposits also have high As contents, present in Co arsenide and sulfarsenide minerals. Type examples of the Co-Cu-Au deposits are those in the Blackbird district, Skuterud in Norway, and Kouvervarra and Juomasuo in Finland. Some deposits in the database have low grades for Cu (for example, NICO in Canada) or Au (for example, Lemmonlampi in Finland), but these deposits are included because their geological, mineralogical, and alteration features are similar to those of the type examples. Several deposits included in the model are partly hosted by metavolcanic or metaigneous rocks (including granite), but regionally these deposits are within metasedimentary successions; no deposits are wholly within granite or other plutonic igneous intrusions. Despite having a lower average Co grade, the Mt. Cobalt deposit in Australia is included here because it has past Co production from higher-grade ore zones (Nisbet and others, 1983). The Black Pine deposit in the Idaho cobalt belt is included because it contains mineable Co- and Au-rich lenses within Cu-rich mineralized zones (Formation Metals, Inc., 2012). Six deposits that lack data for average Co grades are also included because each reportedly contains abundant Co (>0.1 weight percent Co), at least locally. Many of the deposits are noteworthy as possible resources of Ag, Bi, W, Ni, Y, REE, and (or) U. Detailed data on the deposits listed in table 1–1, including references, are available in appendix 1. Significantly, the grouping in this report of Co-Cu-Au deposits in metasedimentary rocks into a single model includes deposits that other workers have previously classified in different ways. For background information, a global overview of different types of Co deposits worldwide is given in Smith (2001). Additional geologically and compositionally similar deposits are known, but have average Co grades less than 0.1 percent. Most of these deposits contain cobalt-rich pyrite and lack appreciable amounts of distinct Co sulfide and (or) sulfarsenide minerals. Such deposits are not discussed in detail in the following sections, but these deposits may be relevant to the descriptive and genetic models presented below. Examples include the Scadding Au-Co-Cu deposit in Ontario, Canada; the Vähäjoki Co-Cu-Au deposit in Finland; the Tuolugou Co-Au deposit in Qinghai Province, China; the Lala Co-Cu-UREE deposit in Sichuan Province, China; the Guelb Moghrein Cu-Au-Co deposit in Mauritania; and the Great Australia Co-Cu, Greenmount Cu-Au-Co, and Monakoff Cu-Au-Co-UAg deposits in Queensland, Australia. Detailed information on these deposits is presented in appendix 2.

Scientific Investigations Report↗
USGS1951

Antimony ore in the Fairbanks district, Alaska

Antimony-bearing ores in the Fairbanks district, Alaska, are found principally in two areas, the extremities of which are at points 10 miles west and 23 miles northeast of Fairbanks; and one of two minor areas lies along this same trend 30 miles farther to the northeast. These areas are probably only local manifestations of mineralization that affected a much broader area and formed antimony-bearing deposits in neighboring districts, the closest of which is 50 miles away. The ores were exposed largely as a result of lode gold mining, but at two periods in the past, high prices for antimony ore warranted an independent production and about 2500 tons of stibnite ore was shipped. The sulfide deposits occupy the same fractures along which a gold-quartz mineralization of greater economic importance occurred; and both are probably genetically related to igneous rocks which intrude the schistose country rock. The sulfide is in part contemporaneous with some late-stage quartz in which it occurs as disseminated crystals; and in part the latest filling in the mineralized zones where it forms kidney-shaped masses of essentially solid sulfide. One extremely long mass must have contained nearly 100 tons of ore, but the average of the larger kidneys is closer to several tons. Much of the ore is stibnite, with quartz as a minor impurity, and assays show the tenor to vary from 40 to 65 percent antimony. Sulphantimonites are less abundant but likewise occur as disseminated crystals and as kidney-shaped bodies. Antimony oxides appear on the weathered surface and along fractures within the sulfide ore. Deposits containing either stibnite or sulphantimonite are known at more than 50 localities, but only eighteen have produced ore and the bulk of this came from the mines. The geology of the deposit, and the nature, extent, and period of the workings are covered in the detailed descriptions of individual occurrences. Several geologic and economic factors, which greatly affect prospecting and mining for stibnite ore in the area, are outlined. The principal available ore and reserves are considered to be ores earlier mined but never shipped, ore minable from near-surface deposits, and ores recoverable as a by-product of future gold mining. The outlook for stibnite production in the district is very uncertain. Apparently the greater portion of stibnite ore has already been recovered and present operations will strip the two principal areas of the district. This conclusion is based on the scanty discoveries since the last war and the fact that the areas are so pock-marked with prospects that there is little likelihood that any other large near-surface bodies remain to be discovered. Future prospecting would essentially be limited to attempts to seek the continuation of lodes previously having high yields of stibnite.

Open-File Report↗
USGS1979

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report↗