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Nutrient concentrations, loads, and yields in the Eucha-Spavinaw Basin, Arkansas and Oklahoma, 2002-2006

The City of Tulsa, Oklahoma, uses Lake Eucha and Spavinaw Lake in the Eucha-Spavinaw basin in northwestern Arkansas and northeastern Oklahoma for public water supply. Taste and odor problems in the water attributable to blue-green algae have increased in frequency. Changes in the algae community in the lakes may be attributable to increases in nutrient levels in the lakes, and in the waters feeding the lakes. The U.S. Geological Survey, in cooperation with the City of Tulsa, investigated and summarized nitrogen and phosphorus concentrations and provided estimates of nitrogen and phosphorus loads, yields, and flow-weighted concentrations in the Eucha-Spavinaw basin for three 3-year periods—2002–2004, 2003–2005, and 2004–2006, to update a previous report that used data from water-quality samples for a 3-year period from January 2002 through December 2004. This report provides information needed to advance knowledge of the regional hydrologic system and understanding of hydrologic processes, and provides hydrologic data and results useful to multiple agencies for interstate agreements. Nitrogen and phosphorus concentrations were significantly greater in runoff samples than in base-flow samples for all three periods at Spavinaw Creek near Maysville, Arkansas; Spavinaw Creek near Colcord, Oklahoma, and Beaty Creek near Jay, Oklahoma. Runoff concentrations were not significantly greater than base-flow concentrations at Spavinaw Creek near Cherokee, Arkansas; and Spavinaw Creek near Sycamore, Oklahoma except for phosphorus during 2003–2005. Nitrogen concentrations in base-flow samples significantly increased downstream in Spavinaw Creek from the Maysville to Sycamore stations then significantly decreased from the Sycamore to the Colcord stations for all three periods. Nitrogen in base-flow samples from Beaty Creek was significantly less than in samples from Spavinaw Creek. Phosphorus concentrations in base-flow samples significantly increased from the Maysville to Cherokee stations in Spavinaw Creek for all three periods, probably because of a wastewater-treatment plant point source between those stations, and then significantly decreased downstream from the Cherokee to Colcord stations. Phosphorus in base-flow samples from Beaty Creek was significantly less than phosphorus in base-flow samples from Spavinaw Creek downstream from the Maysville station. Nitrogen concentrations in runoff samples were not significantly different among the stations on Spavinaw Creek for most of the three periods, except during 2003–2005 when runoff samples at the Colcord station were less than at the Sycamore station; however, the concentrations at Beaty Creek were significantly less than at all other stations. Phosphorus concentrations in runoff samples were not significantly different among the three downstream stations on Spavinaw Creek and were significantly different at the Maysville station on Spavinaw Creek and the Beaty Creek station, only during 2004–2006. Phosphorus and nitrogen concentrations in runoff samples from all stations generally increased with increasing streamflow.

Arkansas, Oklahoma

Estimated Nutrient Concentrations and Continuous Water-Quality Monitoring in the Eucha-Spavinaw Basin, Northwestern Arkansas and Northeastern Oklahoma, 2004-2007

The Eucha-Spavinaw basin is the source of water for Lake Eucha and Spavinaw Lake, which are part of the water supply for the City of Tulsa. The City of Tulsa has received complaints of taste and odor in the finished drinking water because of deteriorating water quality. The deterioration is largely because of algal growth from the input of nutrients from the Eucha-Spavinaw basin. The U.S. Geological Survey, in cooperation with the City of Tulsa, implemented a continuous, real-time water-quality monitoring program in the Eucha-Spavinaw basin to better understand the source of the nutrient loading. This program included the manual collection of samples analyzed for nutrients and the collection of continuous, in-stream data from water-quality monitors. Continuous water-quality monitors were installed at two existing continuous streamflow-gaging stations - Spavinaw Creek near Colcord, Oklahoma, and Beaty Creek near Jay, Oklahoma, from October 2004 through September 2007. Total nitrogen concentrations for manually collected water samples ranged from 2.08 to 9.66 milligrams per liter for the water samples collected from Spavinaw Creek near Colcord, Oklahoma, and from 0.67 to 5.12 milligrams per liter for manually collected water samples from Beaty Creek near Jay, Oklahoma. Total phosphorus concentrations ranged from 0.04 to 1.5 milligrams per liter for the water samples collected from Spavinaw Creek near Colcord and from 0.028 to 1.0 milligram per liter for the water samples collected from Beaty Creek near Jay. Data from water samples and in-stream monitors at Spavinaw and Beaty Creeks (specific conductance and turbidity) were used to develop linear regression equations relating in-stream water properties to total nitrogen and total phosphorus concentrations. The equations developed for the Spavinaw and Beaty sites are site specific and only valid for the concentration ranges of the explanatory variables used in the analysis. The range in estimated and measured phosphorus is not representative for the range of historic streamflow at the Beaty site and that regression equation would benefit from more high flow and high turbidity samples. In addition, all three study years had below average annual precipitation for the area, and streamflow was especially low in Water Year 2006. Average nutrient concentrations from October 2004 through September 2007, which were drier than others, may not be a good indication of conditions in future wetter years. The equations for the Spavinaw and Beaty sites may be used to estimate instantaneous nutrient concentrations, which can be used to compute loads and yields in real time in order to better characterize the effect of land-management practices in these watersheds on the transport of nutrients to Lake Eucha and Spavinaw Lake. The methods used in this study show promise for monitoring future effectiveness of implemented best management practices, development and monitoring of total maximum daily loads, early detection of taste-and-odor occurrences, and to anticipate treatment needs for water suppliers.

Scientific Investigations Report

Map of Distribution of Bottom Sediments on the Continental Shelf, Gulf of Alaska

Introduction The U.S. Geological Survey has a long history of exploring marine geology in the Gulf of Alaska. As part of a cooperative program with other federal and state agencies, the USGS is investigating the relations between ocean-floor geology and benthic marine biohabitats. This bottom sediment map, compiled from published literature will help marine biologists develop an understanding of sea-floor geology in relation to various biological habitats. The pattern of sea-floor sedimentation and bottom morphology in the Gulf of Alaska reflects a complex interplay of regional tectonism, glacial advances and retreats, oceanic and tidal currents, waves, storms, eustatic change, and gravity-driven processes. This map, based on numerous cruises during the period of 1970-1996, shows distribution of bottom sediments in areas of study on the continental shelf. The samples were collected with piston, box, and gravity corers, and grab samplers. The interpretations of sediment distribution are the products of sediment size analyses combined with interpretations of high-resolution seismic reflection profiles. The sea floor was separated into several areas as follows: Cook Inlet -- Hazards studies in this embayment emphasized sediment distribution, sediment dynamics, bedforms, shallow faults, and seafloor stability. Migrating mega-sandwaves, driven by strong tidal currents, influence seabed habitats and stability of the seafloor, especially near pipelines and drilling platforms. The coarseness of the bottom sediment reinforces the influence of the strong tidal currents on the seafloor habitats. Kodiak Shelf -- Tectonic framework studies demonstrate the development of an accretionary wedge as the Pacific Plate underthrusts the Alaskan landmass. Seismic data across the accretionary wedge reveal anomalies indicative of fluid/gas vent sites in this segment of the continental margin. Geologic hazards research shows that movement along numerous shallow faults poses a risk to sea floor structures. Sea-floor sediment on shallow banks is eroded by seasonal wave-generated currents. The winnowing action of the large storm waves results in concentrations of gravel over broad segments of the Kodiak shelf. Northeastern Gulf of Alaska -- Tectonic framework studies demonstrate that rocks of distant origin (Yakutat terrane) are currently attached to and moving with the Pacific Plate, as it collides with and is subducted beneath southern Alaska. This collision process has led to pronounced structural deformation of the continental margin and adjacent southern Alaska. Consequences include rapidly rising mountains and high fluvial and glacial sedimentation rates on the adjacent margin and ocean floor. The northeastern Gulf of Alaska shelf also has concentrations of winnowed (lag) gravel on Tarr Bank and on the outer shelf southeast of Yakutat Bay. Between Kayak Island and Yakutat Bay the outer shelf consists of pebbly mud (diamict). This diamict is a product of glacial marine sedimentation during the Pleistocene and is present today as a relict sediment. A prograding wedge of Holocene sediment consisting of nearshore sand grading seaward into clayey silt and silty clay covers the relict pebbly mud to mid-shelf and beyond. Shelf and slope channel systems transport glacially derived sediment across the continental margin into Surveyor Channel, an abyssal fan and channel system that reaches over 1,000 km to the Aleutian Trench.

Miscellaneous Field Studies Map

Two-dimensional hydraulic model for the Chain of Lakes on the Fox River near McHenry, Illinois

Forecasts of flows entering and leaving the Chain of Lakes on the Fox River in northeastern Illinois are critical information to water-resource managers operating the Stratton Dam at McHenry, Illinois. These managers determine the optimal operation of the Stratton Dam at McHenry, Ill., to manage Chain of Lakes pool levels and to help mitigate flooding in the Chain of Lakes system. In 2020, the U.S. Geological Survey (USGS) and the Illinois Department of Natural Resources–Office of Water Resources (IDNR–OWR) began a cooperative study to develop a system to enable engineers and planners to simulate and communicate water-surface elevations and flows and to proactively prepare for runoff events forecasted for the Chain of Lakes. The hydraulic model described in this report may be helpful to the IDNR–OWR for optimizing the operation of the Stratton Dam and includes the implementation of three newly installed torque-tube crest gates that became operational in 2020. The hydraulic model for the Chain of Lakes was developed using the Hydrologic Engineering Center–River Analysis System program (version 6.5). The hydraulic model was used to simulate water-surface elevations and flows through the 18.5-mile Chain of Lakes system to 1.7 miles downstream from the Stratton Dam. Five USGS streamgages within the study area were used as reference points for model calibration and initial water-surface elevations for beginning a simulation. The hydraulic model was calibrated to three runoff events that incorporated the design specifications and observed gate operations of the Stratton Dam; furthermore, the hydraulic model simulated a validation event and a substantial flooding event during July 2017. The July 2017 event predated the torque-tube crest gate installation but nevertheless tested the performance of the model for such a substantial event. The model simulation results were a good fit to observed records at USGS streamgages with simulated peak water-surface elevations within −0.36–0.15 foot of observed events. The hydraulic model was then implemented into a forecast workflow that streamlines implementation of model inputs and documents the model outputs tailored to IDNR–OWS Stratton Dam operations and interpretations of simulated water-surface elevations and flows.

Illinois

Ground water in the Cuyama Valley, California

This is the fourth of a series of interpretive reports on the water resources of the major valleys of Santa Barbara County, Calif., prepared by the Geological Survey, United States Department of the Interior, in cooperation with Santa Barbara County. The first three reports described the other major valleys in the county: the south-coast basins, Goleta and Carpinteria, and the Santa Maria and Santa Ynez River valleys. This report deals with the Cuyama Valley in the northeastern part of the county and adjoining parts of San Luis Obispo, Kern, and Ventura Counties. It includes estimates of natural discharge, pumpage, and yield of ground water, and all data on water levels, well records, and water quality that were available up to June 1946.

California

Ground water in the Oklahoma Panhandle

An investigation begun in 1937 by the United States and the Oklahoma Geological Surveys, has shown that the depth to the water table in the Oklahoma Panhandle ranges from less than 25 feet in parts of major valleys to about 3oo feet in parts of the uplands. In 8 upland areas the depth is between 50 and 100 feet. The thi kness of the zone of saturation differs widely in these areas, the most promising of which totals about 80 square miles in northeastern Texas County. The pervious sands and gravels of the Ogallala formation, of Pliocene age, furnish most of the ground water, and one well yielding 960 gallons a minute from them has been used for irrigation since x937. The formation ranges from less than xoo to more than 500 feet thick, the differences being due to relief on the pre-Ogallala topography and to post-Ogallala erosion. The alluvium is also an important source of water, as are the Dakota and Cheyenne sandstones, of Cretaceous age. A few wells yield water of variable quality from Jurassic and Triassic rocks, and many wells in the valleys of the eastern part of the area yield small supplies of highly mineralized water from Permian red beds. © 1940 Society of Economic Geologists, Inc

Oklahoma

Geology and ground-water resources of the Fort Berthold Indian Reservation, North Dakota, with a section on chemical quality of the ground water

The Fort Berthold Indian Reservation occupies about 1,000 square miles in west- central North Dakota. The Missouri and Little Missouri Rivers flow through the area and form part of its boundaries. Garrison Dam, which is under construction on the Missouri River 30 miles downstream from the east boundary of the reservation, will impound water in Garrison Reservoir and flood the valleys of both rivers throughout the area. The reservoir will divide the reservation into five parts, herein referred to as the eastern, northeastern, northern, western, and southern segments. Rock formations ranging in age from Paleocene to Recent are exposed. The Fort Union formation of Paleocene age underlies the entire reservation, and it crops out along the Missouri and Little Missouri Rivers. Relatively thin glacial till and outwash deposits of late Pleistocene age mantle much of the upland in all of the segments. The glacial de. posits commonly are less than 10 feet thick; in many places they consist only of scattered boulders on the bedrock surface. The major valleys have terrace deposits of Pleistocene and Recent age and alluvium of Recent age. The principal mineral resources of the reservation are lignite, sand, and gravel. The lignite beds range in thickness from a few inches to about 30 feet. At least four separate beds, which range in thickness from 4 feet to more than 7 feet, are mined locally. Although many mines will be flooded after Garrison Dam is completed, many suitable mine sites will remain above the proposed reservoir level. Sand and gravel deposits are found in glacial outwash and in stream-terrace deposits. On upland areas of the reservation ground water is available principally from the lignite and the associated fine- to medium-grained sandstone beds of the Fort Union formation. Few wells on the reservation are known to produce water from glacial material, although the recessional moraines are possible sources of shallow-water supplies. Small quantities of ground water are available from thin alluvial deposits in some places on the upland. Most wells in the valleys produce water from the alluvium or the terrace deposits. However, several wells penetrate the underlying Fort Union formation. A few flowing wells in the Missouri River valley near Elbowoods produce water from either the lower part of the Fort Union formation or from the Cannonball formation, also of Paleocene age. The chemical character of water from the Fort Union formation and the outwash and river gravels was determined from analyses of 39 samples from wells and springs. Water from bedrock may be either hard or soft, and it is moderately to highly mineralized. Water from the surficial deposits is uniformly hard, but it is less mineralized. Shallow wells in the eastern and northeastern segments produce water of good quality. Wells in these segments, and several springs in the western segment, could be used satisfactorily as domestic supplies. Spring water from lignite deposits on the reservation generally is colored and contains objectionable amounts of iron. Treatment of the water would improve its quality for domestic use. The filling of Garrison Reservoir will cause a rise of the water levels in wells that tap aquifers now discharging below the operating level of the reservoir. All the permeable strata below this level will become saturated, and ground-water bodies that are now separated will become hydraulically united. In addition to providing subsurface information, the drilling program of the U. S. Bureau of Indian Affairs provided wells for domestic and stock-water supplies. All test holes that tapped an adequate supply of potable water were reamed to a larger diameter, equipped with casing and well screen, and gravel-packed. The test-drilling program was completed in 1951; however, the drilling of domestic wells was continued under the supervision of the U. S. Geological Survey.

North Dakota

Resource report for proposed OCS lease sale no. 70, St. George Basin, shelf area, Alaska

St. George basin is a long (300 km), narrow (30-50 km) graben whose long axis strikes northwestward, parallel to the continental margin of the southern Bering Sea. Located near the Pribilof Islands, and beneath the virtually featureless Bering Sea shelf, the basin is filled with more than 10 km of sedimentary deposits. These sedimentary rocks are ruptured by normal faults associated with the sides of the graben; these ruptures commonly correlate with offsets in the basement surface. Offset along these faults increases with depth implying that they are growth-type structures. Basement rocks, that floor and flank St. George basin are part of an assemblage of Mesozoic eugeosynclinal rocks that extends from southern Alaska to eastern Siberia beneath the Bering Sea margin and outer shelf. A parallel belt of igneous rocks of late Mesozoic and earliest Tertiary age may also extend from western Alaska to northeastern Siberia beneath the inner Bering Sea shelf. The Bering Sea margin and adjacent shelf were apparently uplifted by the end of Mesozoic time, resulting in deep subaerial erosion• Following uplift, the outer Bering Sea shelf has undergone extensional rifting and regional subsidence. Differential subsidence has resulted in the formation of a series of basement ridges and basins whose axes parallel the Bering Sea margin. Some of these basins are very large to gigantic in size, e.g., St. George basin, and involve crustal subsidence exceeding 10 km. Such large scale crustal collapse suggests deep crustal or upper mantle processes, such as thermal metamorphism or stress-induced crustal migration. Nine wells drilled along the northern coast of the Alaska Peninsula, as well as several onshore Soviet wells in northeastern Siberia, relate directly to the submerged basins of the Bering Sea shelf. Although all of the wells on the Alaska Peninsula were abandoned as dry holes, shows of oil and gas were found. In addition, Soviet drilling resulted in the discovery of oil and gas shows in Oligocene and Miocene sandstone. Regional geologic and geophysical mapping suggests that there are suitable source beds, reservoir rocks, and traps within St. George basin. However, it is not known if hydrocarbons are present or if the possible reservoirs are of commercial size. A resource appraisal of St. George basin out to 200 meters water depth indicates that, at 5 percent probability, 6.4 billion barrels of oil and 18.6 trillion cubic feet of gas may be in the basin; at 95 percent probability 0.8 billion barrels of oil and 4.5 trillion cubic feet of gas may be in the basin. The statistical mean of the appraisal is 2.7 billion barrels of oil and 10.3 trillion cubic feet of gas. A large number of faults, evidence for recent movement along some of the faults, and high seismicity all indicate that faulting is a major environmental concern for the outer continental shelf region of the southern Bering Sea, especially in St. George basin. Most of the faults are potentially active and their movement is probably influenced by the local geology, including basement structures and sediment loading. Unstable sediment masses pose potential threats to resource development in the vicinity of the Pribilof Canyon. Volcanic activity along the Aleutian arc south of St. George basin may also pose an environmental hazard to petroleum development in the area. Another environmental hazard is the presence of shallow gas pockets, which could pose such problems during drilling as blowouts and liquefaction of bottom sediment.

Alaska

Nutrient Concentrations, Loads, and Yields in the Eucha-Spavinaw Basin, Arkansas and Oklahoma, 2002-2004

The City of Tulsa, Oklahoma, uses Lake Eucha and Spavinaw Lake in the Eucha-Spavinaw basin in northwestern Arkansas and northeastern Oklahoma for public water supply. Taste and odor problems in the water attributable to blue-green algae have increased in frequency over time. Changes in the algae community in the lakes may be attributable to increases in nutrient levels in the lakes, and in the waters feeding the lakes. The U.S. Geological Survey, in cooperation with the City of Tulsa, conducted an investigation to summarize nitrogen and phosphorus concentrations and provide estimates of nitrogen and phosphorus loads, yields, and flow-weighted concentrations in the Eucha-Spavinaw basin for a 3-year period from January 2002 through December 2004. This report provides information needed to advance knowledge of the regional hydrologic system and understanding of hydrologic processes, and provides hydrologic data and results useful to multiple parties for interstate compacts. Nitrogen and phosphorus concentrations were significantly greater in runoff samples than in base-flow samples at Spavinaw Creek near Maysville, Arkansas; Spavinaw Creek near Colcord, Oklahoma, and Beaty Creek near Jay, Oklahoma. Runoff concentrations were not significantly greater than in base-flow samples at Spavinaw Creek near Cherokee, Arkansas; and Spavinaw Creek near Sycamore, Oklahoma. Nitrogen concentrations in base-flow samples significantly increased in the downstream direction in Spavinaw Creek from the Maysville to Sycamore stations then significantly decreased from the Sycamore to the Colcord stations. Nitrogen in base-flow samples from Beaty Creek was significantly less than in those from Spavinaw Creek. Phosphorus concentrations in base-flow samples significantly increased from the Maysville to Cherokee stations in Spavinaw Creek, probably due to a point source between those stations, then significantly decreased downstream from the Cherokee to Colcord stations. Phosphorus in base-flow samples from Beaty Creek was significantly less than phosphorus in base-flow samples from Spavinaw Creek downstream from the Maysville station. Nitrogen concentrations in runoff samples were not significantly different among the stations on Spavinaw Creek; however, the concentrations at Beaty Creek were significantly less than at all other stations. Phosphorus concentrations in runoff samples were not significantly different among the three downstream stations on Spavinaw Creek, and not significantly different at the Maysville station on Spavinaw Creek and the Beaty Creek station. Phosphorus and nitrogen concentrations in runoff samples from all stations generally increased with increasing streamflow. Estimated mean annual nitrogen total loads from 2002-2004 were substantially greater at the Spavinaw Creek stations than at Beaty Creek and increased in a downstream direction from Maysville to Colcord in Spavinaw Creek, with the load at the Colcord station about 2 times that of Maysville station. Estimated mean annual nitrogen base-flow loads at the Spavinaw Creek stations were about 5 to 11 times greater than base-flow loads at Beaty Creek. The runoff component of the annual nitrogen total load for Beaty Creek was 85 percent, whereas, at the Spavinaw Creek stations, the range in the runoff component was 60 to 66 percent. Estimated mean annual phosphorus total loads from 2002-2004 were greater at the Spavinaw Creek stations from Cherokee to Colcord than at Beaty Creek and increased in a downstream direction from Maysville to Colcord in Spavinaw Creek, with the load at the Colcord station about 2.5 times that of Maysville station. Estimated mean annual phosphorus base-flow loads at the Spavinaw Creek stations were about 2.5 to 19 times greater than at Beaty Creek. Phosphorus base-flow loads increased about 8 times from Maysville to Cherokee in Spavinaw Creek; the base-flow loads were about the same at the three downstream stations. The runoff component

Scientific Investigations Report

Linear regression model documentation for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River above Topeka Weir at Topeka, Kansas, November 2018 through June 2021

The Kansas River and its associated alluvial aquifer provide drinking water to more than 950,000 people in northeastern Kansas. Water suppliers that rely on the Kansas River as a water-supply source use physical and chemical processes to treat and remove contaminants before public distribution. An early-notification system of changing water-quality conditions allows water suppliers to proactively make decisions that affect water treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, WaterOne, and Evergy, began collecting water-quality data at the Kansas River above Topeka Weir at Topeka, Kansas (USGS site 06888990, hereafter referred to as the “Topeka site”), during November 2018 to develop linear regression models that relate continuous in situ water-quality sensor measurements to discretely sampled water-quality constituent concentrations or densities. The addition of the Topeka site expanded an existing water-quality monitoring network, which included the upstream Kansas River at Wamego, Kans., and downstream Kansas River at De Soto, Kans., sites. Linear regression analysis was used to develop models that compute real-time concentrations or densities for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and Escherichia coli at the Topeka site using data collected during November 2018 through June 2021. Water-quality constituent concentrations or densities computed from the models documented in this report are available at the USGS National Real-Time Water-Quality website (https://nrtwq.usgs.gov), are useful to the public for cultural and recreational purposes, and can be used to guide water-treatment processes, compare conditions with Federal and State water-quality criteria, and characterize changes in Kansas River water-quality conditions through time.

Kansas

Metallogeny of the nikolai large igneous province (LIP) in southern alaska and its influence on the mineral potential of the talkeetna mountains

Recent geologic mapping has identified areas of extrusive basalts of the Middle to Late Triassic Nikolai Greenstone within the Wrangellia terrane that extend at least 80 km southwest of their previously known extent. Abundant dolerite sills of similar composition intrude Paleozoic and Mesozoic stratigraphy below the Nikolai throughout the central Talkeetna Mountains. The Talkeetna Mountains, therefore, have newly identified potential for copper, nickel, and platinum-group elements (PGEs) as disseminated, net-textured, or massive magmatic sulfide deposits hosted in mafic and ultramafic sill-form complexes related to emplacement of the Nikolai. Because of their potential high grades, similar magmatic sulfide targets have been the focus of increasing mineral exploration activity over the last decade in the Amphitheater Mountains and central Alaska Range, 100-200 km to the northeast. The Nikolai Greenstone, associated intrusions, and their metamorphosed equivalents also have potential to host stratabound disseminated "basaltic copper" deposits. Sedimentary and metasedimentary rocks overlying the Nikolai have the potential to host stratabound, disseminated, or massive "reduced-facies" type Cu-Ag deposits. Ultramafic rocks have been identified only in the extreme northeastern Talkeetna Mountains to date. However, coincident gravity and magnetic highs along the leading (northwestern) edge of and within Wrangellia in the Talkeetna and Clearwater Mountains suggest several areas that are highly prospective for ultramafic rocks related to extrusion of Nikolai lavas. In particular, the distribution, geometry, and composition of sills within the pre-Nikolai stratigraphy and the structural and tectonic controls on intrusive versus extrusive rock distribution deserve serious examination. Copyright ?? 2007 The Geological Society of America.

Special Paper of the Geological Society of America

Interpretation of aeromagnetic anomalies bearing on the origin of upper Chesapeake Bay and river course changes in the Central Atlantic Seaboard Region: Speculations

On an aeromagnetic map of the Chesapeake Bay area, the northeastern part of the bay coincides well with a deep, “flat” magnetic low, and the upper part of the Delmarva Peninsula east of the bay coincides with detailed magnetic highs; the two areas are separated by a steep, straight gradient that matches the eastern shore of the bay. On the basis of magnetic and geologic evidence, we interpret the Chesapeake Bay magnetic low as a buried Baltimore Gneiss dome, bounded on the southeast by a normal or reverse fault marked by the steep, straight gradient; mafic and ultramafic plutonic rocks probably underlie the southeast side of the fault zone. The flatness of the Chesapeake Bay magnetic low, as opposed to the detail of the anomalies on either side, however, suggests that an abnormal thickness of nonmagnetic sedimentary rocks also coincides with the low. This could reflect a buried Triassic basin or, more probably, a thickened section of Coastal Plain sedimentary rocks deposited in the fault-bounded basin. The present course of the upper part of Chesapeake Bay is probably inherited from the pre-Pleistocene course of the Susquehanna River, but the river's course may have been determined by the fault zone. Thus, this zone and similar en echelon fault zones along strike may explain the sudden change in course of major rivers in the central Atlantic Seaboard region.

Delaware, Maryland, Pennsylvania, Virginia

Reconnaissance of arsenic concentrations in ground water from bedrock and unconsolidated aquifers in eight northern-tier counties of Pennsylvania

Samples of ground water for analysis of total-arsenic concentrations were collected in eight counties--Potter, Tioga, Bradford, Susquehanna, Wayne, Pike, Sullivan, and Wyoming--and from eight bedrock formations (bedrock aquifers) and overlying glacial aquifers in the north-central and northeastern parts of Pennsylvania in July 2005 and from March through June 2006. The samples were collected from a total of 143 domestic wells, 2 stock wells, 4 non-community wells, 2 community water-system wells, and 3 domestic springs by well or spring owners using sampling kits provided by the U.S. Geological Survey (USGS). An additional 15 domestic wells were sampled by the USGS for analysis of total arsenic. These 15 samples were collected using the same methods and sampling kits provided to the homeowners. Samples were analyzed for total arsenic by the Pennsylvania Department of Environmental Protection Laboratory using a minimum reporting level of 4.0 µg/L (micrograms per liter). Arsenic was detected in water from 18 domestic wells in four counties--Bradford (3 wells), Sullivan (1 well), Tioga (13 wells), and Wayne (1 well). The median concentration of total arsenic was less than 4.0 µg/L, and the maximum concentration was 188 µg/L. Water from 10 wells had concentrations of total arsenic greater than the U.S. Environmental Protection Agency Maximum Contaminant Level of 10 µg/L. Detectable concentrations of total arsenic were measured in water from wells that ranged in depth from 29 to 400 feet, and that were completed in three aquifers--Lock Haven Formation, Catskill Formation, and unconsolidated glacial sediments; no springs had detectable concentrations of total arsenic. Water samples representing the Lock Haven Formation were collected from 60 wells; water from 12 of these wells had detectable concentrations of total arsenic. Water samples representing the Catskill Formation were collected from 57 wells; water from 4 wells had detectable concentrations of total arsenic. Water samples representing the unconsolidated glacial sediments were collected from 17 wells; 2 wells had water with detectable concentrations of total arsenic. Contingency tables tested for significant differences in total arsenic between aquifers, topographic settings, and well depths. Concentrations of total arsenic were significantly greater (95-percent confidence level) in the Lock Haven Formation than in the other bedrock units. Concentrations of total arsenic also varied significantly by topographic setting. Wells completed in the Lock Haven Formation and located in valleys had significantly greater concentrations of total arsenic than similar wells located on hilltops or slopes. Concentrations of total arsenic did not vary significantly by topographic setting in the Catskill Formation. Concentrations of total arsenic did not vary significantly by well depth for any aquifer. Iron staining, hydrogen-sulfide odor, or both were common complaints of well owners. Iron staining was a complaint of 44 well owners. Hydrogen-sulfide odor was a complaint of 35 well owners. Fourteen well owners complained of both iron staining and hydrogen sulfide. No correlation to the presence of arsenic in the wells sampled was found with iron staining, hydrogen-sulfide odor, or both. Water from 8 of the 10 wells that contained concentrations of total arsenic greater than 10 µg/L were sampled by USGS personnel for the determination of concentrations of dissolved arsenic (minimum reporting level 0.3 µg/L) and arsenic species {arsenite [As (III)], arsenate [As (V)], monomethylarsonate (MMA), and dimethylarsinate (DMA)} at the USGS National Water Quality Laboratory. Analytical results from these samples showed a median concentration of 38.7 µg/L dissolved arsenic in water and a maximum of 178 µg/L. As (III) was the most common arsenic species present in the water for seven of the eight wells and was found in water characteristic of reducing environments [pH 8.2 to 9.1, dissolved oxygen 0.06 to 0.29 milligrams per liter (mg/L), and oxidation reduction potential -63 to -203 millivolts (mv)]. As (V) was the dominant arsenic species in water characteristic of an oxidizing environment (pH 4.8, dissolved oxygen 2.15 mg/L, oxidation reduction potential 265 mv). The arsenic species MMA and DMA were detected in the water from two wells. The arsenic species MMA was detected at an estimated concentration of 0.9 µg/L in water from one well; the concentration was less than 1.2 µg/L in water from seven wells. The arsenic species DMA was detected at concentrations of 1.0 and 1.5 µg/L in water from two wells; the concentration was less than 0.6 µg/L in water from six wells. Both wells that contained detectable concentrations of MMA and DMA produced water that was characteristic of reducing environments.

Pennsylvania

Linear regression model documentation and updates for computing water-quality constituent concentrations or densities using continuous real-time water-quality data for the Kansas River, Kansas, July 2012 through September 2019

The Kansas River provides drinking water to about 800,000 people in northeastern Kansas. Water-treatment facilities that use the Kansas River as a water-supply source use chemical and physical processes during water treatment to remove contaminants before public distribution. Advanced notification of changing water-quality conditions near water-supply intakes allows water-treatment facilities to proactively adjust treatment. The U.S. Geological Survey (USGS), in cooperation with the Kansas Water Office (funded in part through the Kansas Water Plan), the Kansas Department of Health and Environment, The Nature Conservancy, the City of Lawrence, the City of Manhattan, the City of Olathe, the City of Topeka, and Johnson County WaterOne, collected water-quality data at the Kansas River at Wamego (USGS site 06887500; hereafter referred to as the “Wamego site”) and De Soto (USGS site 06892350; hereafter referred to as the “De Soto site”) monitoring sites to update previously published regression models relating continuous water-quality sensor measurements, streamflow, and seasonal components to discretely sampled water-quality constituent concentrations or densities. Linear regression analysis was used to update and develop models for total dissolved solids, major ions, hardness as calcium carbonate, nutrients (nitrogen and phosphorus species), chlorophyll a , total suspended solids, suspended sediment, and fecal indicator bacteria at the Wamego and De Soto monitoring sites using data collected during July 2012 through September 2019. The water-quality information documented in this report can be used as guidance for water-treatment processes and to characterize changes in water-quality conditions in the Kansas River over time that would not be otherwise possible.

Kansas

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2018–2019

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents results of data collected as part of the monitoring program in the Black Mesa area from calendar year 2019, and additionally uses streamflow statistics from November and December 2018. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2019, total groundwater withdrawals were estimated to be 3,070 acre-feet (acre-ft), industrial withdrawals were 670 acre-ft, and municipal withdrawals were estimated to be 2,400 acre-ft. Total withdrawals during 2019 were about 58 percent less than total withdrawals in 2005 because of Peabody Western Coal Company’s discontinued use of water to transport coal in a coal slurry pipeline after 2005 and cessation of mining operations in 2019. Water levels measured in 2019 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 10 of 16 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 16 wells ranged from +8.2 feet (ft) to −40.0 ft, and the median change was −1.7 ft. Water levels also showed decline in 16 of 18 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −38.8 ft, with changes across all 18 wells ranging from +12.9 ft to −185.0 ft. Spring flow was measured at four springs in 2019. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976 to 2019), Dinnebito Wash near Sand Springs 09401110 (1993 to 2019), Polacca Wash near Second Mesa 09400568 (1994 to 2019), and Pasture Canyon Springs 09401265 (2004 to 2019). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was indicated at Moenkopi Wash and Dinnebito Wash. In 2019, water samples collected from four springs and three wells in the Black Mesa area were analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Concentrations of dissolved solids, chloride, and sulfate increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids, chloride, and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids and chloride at Burro Spring have varied for the period of record, but there is no statistical trend in the data; however, concentrations of sulfate from Burro Spring now show a trend towards lower concentrations. No statistical trend tests were performed for the three wells sampled in 2019 since less historical water-quality data were available for comparison.

Arizona

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Characteristics of discrete and basin-centered parts of the Lower Silurian regional oil and gas accumulation, Appalachian basin: Preliminary results from a data set of 25 oil and gas fields

Oil and gas trapped in Lower Silurian "Clinton" sands and Medina Group sandstone constitute a regional hydrocarbon accumulation that extends 425 mi in length from Ontario, Canada to northeastern Kentucky. The 125-mi width of the accumulation extends from central Ohio eastward to western Pennsylvania and west-central New York. Lenticular and intertonguing reservoirs, a gradual eastward decrease in reservoir porosity and permeability, and poorly segregated gas, oil, and water in the reservoirs make it very difficult to recognize clear-cut geologic- and production-based subdivisions in the accumulation that are relevant to resource assessment. However, subtle variations are recognizable that permit the regional accumulation to be subdivided into three tentative parts: a western gas-bearing part having more or less discrete fields; an eastern gas-bearing part having many characteristics of a basin-centered accumulation; and a central oil- and gas-bearing part with "hybrid" fields that share characteristics of both discrete and basin-centered accumulation. A data set of 25 oil and gas fields is used in the report to compare selected attributes of the three parts of the regional accumulation. A fourth part of the regional accumulation, not discussed here, is an eastern extension of basin-centered accumulation having local commercial gas in the Tuscarora Sandstone, a proximal facies of the Lower Silurian depositional system. A basin-centered gas accumulation is a regionally extensive and commonly very thick zone of gas saturation that occurs in low-permeability rocks in the central, deeper part of a sedimentary basin. Another commonly used term for this type of accumulation is deep-basin gas accumulation. Basin-centered accumulation is a variety of continuous-type accumulation. The "Clinton" sands and Medina Group sandstone part of the basin-centered gas accumulation is characterized by: a) reservoir porosity ranging from about 5 to 10 percent; b) reservoir permeability equal to or less than 0.1 mD; c) low reservoir water saturation and an average water yield per well less than about 9 to 13 BW/MMCFG; d) a broadly defined updip water-block trap; e) underpressured reservoirs with a gradient ranging from 0.25 to 0.35 psi/ft; and f) reservoir temperature of at least 125° F (52° C). Other than for historical and location purposes, the term field has little or no meaning as an assessment unit for the regional accumulation. In practice, each designated field represents a production sweet spot having relatively high EURs per well that in turn merges with surrounding gas-productive regions that are generally larger in area but have lower EURs per well. This important feature of the Lower Silurian regional accumulation, whereby most wells drilled into it are gas productive, must be considered when assessing its potential for remaining recoverable gas resources. Most of the remaining gas resources reside in "Clinton" sands and Medina Group sandstone in the basin-centered part of the accumulation where as much as several tens of TCF of natural gas may be technically recoverable. The Tuscarora Sandstone in the eastern extension of the basin-centered part of the accumulation underlies a very large area and, although commonly characterized by very low porosity and permeability and low-Btu gas, probably contains additional gas resources. Remaining undiscovered recoverable gas and oil resources in the discrete and hybrid parts of the accumulation are primarily located beneath Lake Erie.

Maryland, New York, Ohio, Ontario, Pennsylvania, V

Precipitation runoff modeling system (PRMS) as part of an integrated hydrologic model for the Osage Nation, northeastern Oklahoma, 1915–2014

Executive Summary The Osage Nation lacks a comprehensive tribal water plan to describe the quality and quantity of water resources in the Osage Nation, a 2,304-square-mile (mi 2 ) area of rolling pastures, tallgrass prairie, and mixed woodlands in northeastern Oklahoma. A tribal water plan can be used to help manage the sustainable development of surface and groundwater resources, thereby helping to provide a better future for the Osage Nation and their neighbors, while preserving water resources for the benefit of the surrounding environment and future generations. To help meet these goals and contribute to increased knowledge of the quantity and quality of water resources and the hydrologic processes and factors affecting those resources, the U.S. Geological Survey (USGS) in cooperation with the Osage Nation began studies to evaluate the surface-water and groundwater resources of the Osage Nation. An important component of these studies is the development and application of numerical models to improve quantification and understanding of the hydrologic system. These models are needed to estimate and quantify the effects of historical and potential future water resource development for the Osage Nation. This report describes the development and application of a precipitation-runoff model, the Osage Nation watershed model (ONWM). The ONWM is needed as a component of the Osage Nation integrated hydrologic model (ONIHM). At the time of this study, the ONIHM was being developed using the USGS computer software MODFLOW-One Water Hydrologic Flow Model (MODFLOW-OWHM). The intended use of the ONIHM is to simulate all surface-water and groundwater components of the hydrologic system for a 2,905-mi 2 study area centered on the Osage Nation. The ONWM was developed using the USGS Precipitation Runoff Modeling System, version 4 (PRMS-IV) computer software, also referred to as PRMS in this report, for an 8,343-mi 2 study area in northeastern Oklahoma and southeastern Kansas, centered on and including the areas of the Osage Nation and the ONIHM. The ONWM is to be used as part of the ONIHM to provide a direct coupling with spatially and temporally varying daily climate conditions affecting the ONIHM study area. As an integral part of the ONIHM, the ONWM (1) simulates the inflow boundary conditions from tributary basins in the region outside and surrounding the ONIHM area; (2) provides estimates of spatially and temporally distributed precipitation, air temperature, potential evapotranspiration (PET), actual evapotranspiration (ET), soil moisture, recharge, and streamflow in the ONIHM area; and (3) provides a preliminary water budget for the ONIHM area and the surrounding region, including tributary drainage basins outside of and next to the ONIHM. The specific objectives of this study were to use the ONWM to (1) provide a systematic inventory of the historical distribution of water inflows from precipitation (rain or snow) falling on the land surface and flowing through the surface-water network, (2) provide a historical context of the variability and spatial and temporal distribution of these waters, and (3) provide estimates of water inflows and potential observations to the ONIHM. The application of the ONWM as a component of the ONIHM is needed for planned simulations using the ONIHM to improve the understanding of the hydrologic system and to develop a fully comprehensive water budget, including the use and movement of water across the landscape, in the surface-water network, and in groundwater aquifers under historical and potential future conditions.

Oklahoma