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The relative importance of disturbance and exotic-plant abundance in California coastal sage scrub

Many ecosystems of conservation concern require some level of disturbance to sustain their species composition and ecological function. However, inappropriate disturbance regimes could favor invasion or expansion of exotic species. In southern California coastal sage scrub (CSS) fire is a natural disturbance, but because of human influence, frequencies may now be unnaturally high. Other anthropogenic disturbances such as grazing also occur in reserve areas. Managers charged with imposing or tolerating fire or other disturbance within their reserves are concerned that habitat quality may be degraded by an increasing abundance of exotic plants. We used vegetation monitoring data from Camp Pendleton, California, USA, to assess the correlation between past disturbances (frequent fire, agriculture, or grazing and mechanical disturbances) and current exotic species abundance in CSS. We found that disturbance history was only modestly related to exotic abundance overall, but fire frequency showed the strongest association. We also examined whether cover and richness of various native plant life forms (woody species, perennial herbs, and annual herbs) were more strongly influenced by disturbance history or by exotic-plant abundance. Native plant responses varied among life forms, but woody species and annual herbs were generally more strongly and negatively associated with exotic abundance than with disturbance. Effective CSS conservation will require developing means to curb the negative impacts of exotic plants, which may abound with or without severe or recent disturbance. Additionally, more focus should be given to understory herbs showing sensitivity to invasion. Though understudied, native herbs comprise the greatest portion of plant diversity in CSS and are critical to preservation of the community as a whole. ?? 2009 by the Ecological Society of America.

Ecological Applications↗

Daily patterns of river herring (Alosa spp.) spawning migrations: Environmental drivers and variation among coastal streams in Massachusetts

The timing of life history events in many plants and animals depends on the seasonal fluctuations of specific environmental conditions. Climate change is altering environmental regimes and disrupting natural cycles and patterns across communities. Anadromous fishes that migrate between marine and freshwater habitats to spawn are particularly sensitive to shifting environmental conditions and thus are vulnerable to the effects of climate change. However, for many anadromous fish species the specific environmental mechanisms driving migration and spawning patterns are not well understood. In this study, we investigated the upstream spawning migrations of river herring Alosa spp. in 12 coastal Massachusetts streams. By analyzing long-term data sets (8–28 years) of daily fish counts, we determined the local influence of environmental factors on daily migration patterns and compared seasonal run dynamics and environmental regimes among streams. Our results suggest that water temperature was the most consistent predictor of both daily river herring presence–absence and abundance during migration. We found inconsistent effects of streamflow and lunar phase, likely due to the anthropogenic manipulation of flow and connectivity in different systems. Geographic patterns in run dynamics and thermal regimes suggest that the more northerly runs in this region are relatively vulnerable to climate change due to migration occurring later in the spring season, at warmer water temperatures that approach thermal maxima, and during a narrower temporal window compared to southern runs. The phenology of river herring and their reliance on seasonal temperature patterns indicate that populations of these species may benefit from management practices that reduce within-stream anthropogenic water temperature manipulations and maintain coolwater thermal refugia.

Massachusetts↗

Neonicotinoid insecticide removal by prairie strips in row-cropped watersheds with historical seed coating use

Neonicotinoids are a widely used class of insecticides that are commonly applied as seed coatings for agricultural crops. Such neonicotinoid use may pose a risk to non-target insects, including pollinators and natural enemies of crop pests, and ecosystems. This study assessed neonicotinoid residues in groundwater, surface runoff water, soil, and native plants adjacent to corn and soybean crop fields with a history of being planted with neonicotinoid-treated seeds from 2008-2013. Data from six sites with the same crop management history, three with and three without in-field prairie strips, were collected in 2015-2016, 2-3 years after neonicotinoid (clothianidin and imidacloprid) seed treatments were last used. Three of the six neonicotinoids analyzed were detected in at least one environmental matrix: the two applied as seed coatings on the fields (clothianidin and imidacloprid) and another widely used neonicotinoid (thiamethoxam). Sites with prairie strips generally had lower concentrations of neonicotinoids: groundwater and footslope soil neonicotinoid concentrations were significantly lower in the sites with prairie strips than those without; mean concentrations for groundwater were 11 and 20 ng/L (p = 0.048) and <1 and 6 ng/g (p = 0.0004) for soil, respectively. Surface runoff water concentrations were not significantly (p = 0.38) different for control sites (44 ng/L) or sites with prairie strips (140 ng/L). Consistent with the decreased inputs of neonicotinoids, concentrations tended to decrease over the sampling timeframe. Two sites recorded concentration increases, however, potentially due to disturbance of previous applications or influence from nearby fields where use of seed treatments continued. There were no detections (limit of detection: 1 ng/g) of neonicotinoids in the foliage or roots of plants comprising prairie strips, indicating a low likelihood of exposure to pollinators and other insects visiting these plants following the cessation of seed coating use. Offsite transport of neonicotinoids to aquatic systems through the groundwater and surface water were furthermore reduced with prairie strips. This study demonstrates the potential for prairie strips comprising 10% of an agricultural catchment to mitigate the non-target impacts of neonicotinoids.

Agriculture, Ecosystems and Environment↗

Atmospheric dry deposition in the vicinity of the Salton Sea, California - II: Measurement and effects of an enhanced evaporation system

A study was conducted to determine the effects of salt spray drift from pilot technologies employed by the US Bureau of Reclamation on deposition rates of various air-born ions. An enhanced evaporation system (EES) was tested in the field at the Salton Sea, California. Dry deposition of NO3-, NH4+, SO42-, Cl-, Ca2+, Na+, K+ and Se was assessed by using nylon filters and branches of natural vegetation exposed for one-week long periods. The simultaneous exposure of both lyophilized branches and branches of live plants offered important information highlighting the dynamics of deposited ions on vegetation. The EES significantly increased the deposition rates of Cl-, SO42- and Na+ in an area of about 639-1062 m surrounding the sprayers. Similarly, higher deposition of Ca 2+ and K+ caused by the EES was detected only when deposition was assessed using nylon filters or lyophilized branches. Deposition fluxes of NO3-, NH4+ and Se were not affected by the spraying system. Techniques for measuring dry deposition and calculating landscape-level depositional loads in non-forested systems need further development. ?? 2005 Elsevier Ltd. All rights reserved.

Atmospheric Environment↗

Regional occurrence of aqueous tungsten and relations with antimony, arsenic and molybdenum concentrations (Sardinia, Italy)

T ungsten (W) is rarely found in natural waters, yet it can be introduced into the food chain and cause potentially toxic effects. Uptake of W by plants and vegetables, or trace presence of W in drinking water are possible vectors for ingestion of W by humans. The latter is recognized as a possible cause of lymphatic leukemia. Increased uses of W might result in a degradation of water resources, with attendant adverse effects on biota and human health. Therefore, this study was aimed at investigating regional occurrence and speciation of W in aquatic systems in Sardinia, Italy, factors affecting W mobility and possible relations with other oxyanion-forming trace elements such as Sb, As and Mo. Although our results are specifically from Sardinia, the implications are broader and should prompt future studies in other areas with known high W concentrations. A total of 350 sample sites are reported here, including surface waters, groundwaters, mine drainages, thermal waters and local seawater. The waters were analyzed for major and trace components, including W, Sb, As and Mo. The waters showed a variety of major chemical compositions and W concentrations. High concentrations of W were found in some mine waters and drainages from slag heaps, with W, Sb and As up to 140, 5000 and 800 μg L −1 , respectively. The highest concentrations of W occurred under slightly alkaline pH and oxygenated conditions, and were likely due to the dissolution of scheelite [CaWO 4 ] hosted in materials with which the water came into contact. High W concentrations also were observed in thermal waters, under alkaline pH and reducing conditions, and sometimes coincided with relatively high concentrations either of As or Mo. Previous studies of W geochemistry have focused on WO 4 2− as the major dissolved form of W. For this study, we have augmented the thermodynamic database in PHREEQC to include possible formation of many other W-bearing complexes gleaned from the literature. The results of the speciation calculations with the newly added complexation reactions shows that the neutral species CaWO 4 ° and MgWO 4 ° are particularly dominant in most W-bearing waters and lead to undersaturation with respect to scheelite and other W-bearing minerals. Assessing W contamination in water systems and establishing W limits in drinking water may prevent potential adverse effects of W on human and ecosystem health.

Sardinia↗

Recycling of construction debris as aggregate in the Mid-Atlantic Region, USA

Reclaimed asphalt pavement (RAP) and portland cement concrete (RPCC) are abundant and available substitutes for natural aggregate in many areas. This paper presents an overview of factors that affect recycled aggregate cost, availability, and engineering performance, and the results of a survey of business practices in the Mid-Atlantic region. For RAP, processing costs are less than those for virgin natural aggregate. Use of efficient asphalt pavement stripping technology, on-site reclamation, and linked two-way transport of asphalt debris and processed asphalt paving mix between asphalt mix plants and paving sites has led to extensive recycling of asphalt pavement in the Mid-Atlantic region of the US. Most of the sites that recycle asphalt pavement (RAP) are located in or near urban areas close to important transportation corridors. RPCC is a viable aggregate source in urban settings where unit costs for processed aggregate from RPCC and natural aggregate are comparable. Disposal fees charged at RPCC recycling sites help defray processing costs and the significantly lower tipping fees at recycling sites versus landfill disposal sites encourage recycling of construction debris as aggregate. Construction contractors and construction debris recycling centers, many of which have the ability to crush and process concrete debris at the job site, produce most RPCC. Production of RPCC aggregate from construction debris that is processed on site using portable equipment moved to the construction site eliminates transportation costs for aggregate and provides an economic incentive for RPCC use. Processing costs, quality and performance issues, and lack of large quantities where needed limit RPCC use. Most RPCC suppliers in the Mid-Atlantic area are located in counties with population densities greater than 400 people/km2 (1036 people/mile2) and that have high unit-value costs and limited local availability of natural aggregate. ?? 2004 Published by Elsevier B.V.

Conference Paper↗

Mathematical modeling relevant to closed artificial ecosystems

The mathematical modeling of ecosystems has contributed much to the understanding of the dynamics of such systems. Ecosystems can include not only the natural variety, but also artificial systems designed and controlled by humans. These can range from agricultural systems and activated sludge plants, down to mesocosms, microcosms, and aquaria, which may have practical or research applications. Some purposes may require the design of systems that are completely closed, as far as material cycling is concerned. In all cases, mathematical modeling can help not only to understand the dynamics of the system, but also to design methods of control to keep the system operating in desired ranges. This paper reviews mathematical modeling relevant to the simulation and control of closed or semi-closed artificial ecosystems designed for biological production and recycling in applications in space. Published by Elsevier Science Ltd on behalf of COSPAR.

Advances in Space Research↗

Mines and mineral processing facilities in the vicinity of the March 11, 2011, earthquake in northern Honshu, Japan

U.S. Geological Survey data indicate that the area affected by the March 11, 2011, magnitude 9.0 earthquake and associated tsunami is home to nine cement plants, eight iodine plants, four iron and steel plants, four limestone mines, three copper refineries, two gold refineries, two lead refineries, two zinc refineries, one titanium dioxide plant, and one titanium sponge processing facility. These facilities have the capacity to produce the following percentages of the world's nonfuel mineral production: 25 percent of iodine, 10 percent of titanium sponge (metal), 3 percent of refined zinc, 2.5 percent of refined copper, and 1.4 percent of steel. In addition, the nine cement plants contribute about one-third of Japan's cement annual production. The iodine is a byproduct from production of natural gas at the Miniami Kanto gas field, east of Tokyo in Chiba Prefecture. Japan is the world's second leading (after Chile) producer of iodine, which is processed in seven nearby facilities.

Open-File Report↗

Ground water in the Mohall area, Bottineau and Renville Counties, North Dakota

The Mohall area includes about 120 square miles in Bottineau and Renville Counties in northwestern North Dakota. Mohall, whose 1950 population was 1,073, is the only town in the area. The area is part of the Drift Prairie section of the Central Lowland physiographic province. It is characterized by the gently undulating ground moraine plain which slopes regionally to the northeast. It is drained by several southeast-trending intermittent streams which run almost at right angles to the regional slope. The geologic formations in the Mohall area may be conveniently grouped into three units: the alluvium or alluvial deposits, which are found in the valleys of the intermittent streams, the till and associated glaciofluvial deposits, and the bedrock formations. Ground water of reasonably good quality is obtained in the area only from the alluvial deposits. Because of the limited areal extent of these deposits, only a small number of farms obtain water supplies from them. However, the municipal water supply of the town of Mohall is obtained from these deposits in Spring Coulee northeast of the town, and much water for rural domestic use is hauled from the Becker well southwest of the town, in Little Deep Creek. The principal source of recharge to the alluvial deposits is seepage during the spring runoff period. Natural discharge occurs by underflow down the stream valleys, by evaporation from open water and marshy areas and transpiration by plants. The coefficient of transmissibility of the alluvium, n the basis of short pumping tests on Mohan wells 3 and 4, is indicated to be about 6,000 gallons a day per foot at well 3 and about 20,000 gallons a day per foot at well 4. The specific yield was computed as 0.25 from the pumping test on well 3. No gravel of importance was en countered in the two cross sections that were drilled across Spring Coulee near the municipal wells, and the greatest thickness of satu rated alluvial deposits found was only about 10 feet. A Saturated thickness of 20 feet of sand and gravel was penetrated in test drilling along Cut Bank Creek. This is the greatest thickness of saturated alluvial deposits penetrated anywhere in the area. Ground water in storage in these alluvial deposits has been estimated to be about 150 million gallons per mile. These deposits are favorably situated to receive recharge, as Cut Bank Creek drains a rather large area and contains long stretches of open water perennially, Therefore, it is believed that the alluvial deposits of Cut Bank Creek offer the best promise for the development of moderately large perennial ground-water supplies for the present and probable future needs of the town of Mohall. Test drilling in West Cut Bank Creek and in Little Deep Creek did not reveal alluvial deposits of such character and saturated thickness as to be considered favorable for the development of moderate to large water supplies, though some of the material encountered should yield adequate quantities for farm supplies. The till with its associated glaciofluvial deposits is the surface formation in the area except where covered by the alluvial deposits in the stream valleys. In the Mohall areas, this formation is not an important aquifer and fewer than half a dozen wells are known to obtain water from it. The glaciofluvial deposits penetrated by the test holes are not considered adequate sources for permanent municipal or industrial supplies because they are likely to have small-areal extent and the overlying, relatively impermeable till makes seasonal recharge to them practically impossible. Test drilling in the Souris River Valley about 12 miles west of Mohall penetrated as mutt as 58 feet of fluvial sediments, but practi-cally all the material is clay and silt. No important aquifers were found there. At least 50 percent of all the farm water supplies in the area are obtained from wells in the bedrock formations, which probably consist of the Fox Hills sandstone, the Cannonball formation, and the Ludlow and Tongue Rtter members of the Fort Union formation. Underlying these formations is approximately 2,600 feet of Cretaceous shale, which'is not water bearing. Water from the "Dakota" sandstone (including the possible equivalent of the Fuson shale and Lakota sandstone) may be obtained at depths of about 3,200 to 3,300 feet. The "Dakota sandstone" probably would yield water in sufficient quantity for municipal and many industrial purposes in this areas but the water is likely to be too highly mineralized for most domestic uses. Jurassic formations underlie the Cretaceous formations in the area. They do not constitute aquifers of importance, and, any water found in them is likely to be too highly mineralized for most purposes. In the Mohall area, by far the most suitable water for general purposes is obtained from the shallow alluvial deposits in the stream valleys. Of the seven samples of this water water analyzed, the highest concentration of dissolved solids was 1,242 parts per million and the lowest, 317 parts. The iron content was higher than desirable in two samples but satisfactory in all the others. Total hardness ranged from 196 to 570, which is higher than desirable. Nitrate was present in all samples analyzed and was excessively high in two samples. Water samples for analysis were not obtained from the till and associated glaciofluvial deposits but the water from these aquifers is likely to be more highly mineralized than the water from the alluvial. deposits. The water from the upper part of the bedrock is highly mineralized, but its mineral content varies considerably. The chloride concentration of the samples analyzed ranges from 608 to 3,740 parts per million and the bicarbonate concentration ranges from 160 to 860 parts per million. The specific conductance ranges from 3,190 to 11,120 micromhos and may represent total mineralization on the order of 1,500 to more than 6,000 parts per million in the water with high chloride and bicarbonate content.

North Dakota↗

Water resources of the Green Bay area, Wisconsin

The Green Bay area comprises an area of about 525 square miles in eastern Wisconsin at the south end of Green Bay. It includes the western three-fourths of Brown County and the eastern one-ninth of Outagamie County. In 1960, the population of the area was estimated at 124,000. The most prominent topographic feature is the northwest-facing, southwestward trending Niagara escarpment. The area northwest of the escarpment drains into Green Bay via the Fox River, Suamico River, Duck Creek, and their tributaries. The area southeast of the escarpment is drained by streams that flow into Lake Michigan. The chief sources of surface water in the Green Bay area are the Fox River, Green Bay, and Lake Michigan. Smaller amounts of water are available from the East and Suamico Rivers and other streams. A sandstone aquifer is the principal source of the ground-water supply. The Niagara dolomite, although largely undeveloped, is potentially an important aquifer in the eastern part of the area. Small amounts of water are obtained also from the Platteville formation and from deposits of Pleistocene and Recent age. Water from the surfaceand ground-water sources is moderately hard to very hard. The Fox River, tributary to Lake Michigan at Green Bay, is a significant source of water for industrial use in the Green Bay area. The Menasha Dam, which controls release of water from the Lake Winnebago pool, is the major regulation on the Fox River, and it has considerable effect in reducing peak flows and supplementing low flows in the lower Fox River. The average discharge of the lower Fox River for the period 1898-1959, as measured at the gaging station at Rapide Croche Dam, was 2,687 mgd (million gallons per day). The longest consecutive period during which the discharge averaged less than 500 mgd was 80 days. The average discharge can be expected to fall below 700 mgd about once every 5 years for a 7-day period. In 1959, the average withdrawal of water from the Fox River was about 62 mgd. The water in the river is of the calcium magnesium bicarbonate type and is hard. The small streams in the area are utilized chiefly for stock watering; some of the water, however, is used for irrigation. The water in the small streams is more highly mineralized than the water in the Fox River and is very hard. Large quantities of water are available from Green Bay, but the disposal of industrial waste into the bay has restricted the use of the water. The major withdrawal is for condenser cooling, and, in 1959, it averaged about 415 mgd. The water from Green Bay is moderately hard but is of better chemical quality than the water from the Fox River and the small streams in the area. The only withdrawals of water from Lake Michigan for use in the Green Bay area are made by the city of Green Bay. In 1959, these withdrawals averaged 7.8 mgd. The lower Fox River is not subject to extremes of flow owing to the dampening effect of the Lake Winnebago pool and the regulation of flow at Menasha Dam. Cloudbursts over the lower Fox River valley below Menasha Dam, however, have occasionally caused extremely high water, as in 1922, when the discharge at the mouth of the Fox River was estimated to be about 50,000 mgd. Daily discharges greater than about 13,000 mgd occurred only 7 times in the period 1918-59. The 50-year flood of 15,500 mgd represents an average runoff of less than 2.6 mgd per square mile of drainage area, a relatively low runoff for a 50-year flood in Wisconsin. The sandstone aquifer is the principal source of ground water in the Green Bay area and furnishes water for public supply and industrial use. This aquifer includes rocks of Late Cambrian age, and the Prairie du Chien group and St. Peter sandstone of Ordovician age; it ranges in thickness from 550 to 640 feet. Ground water is found in openings along fractures and bedding planes and in the interstices between sand grains. The sandstone aquifer can support additional development of large supplies of ground water. Wells can be developed in most of the area that will yield 500 gpm (gallons per minute) or more, provided they are properly spaced and penetrate the entire thickness of the aquifer. It is estimated that the perennial yield of the sandstone in the Green Bay area could be at least 30 mgd if the aquifer is properly developed; only 5.4 mgd was withdrawn in 1959. The water from this sandstone aquifer is of the calcium magnesium bicarbonate type, is very hard, and, at a few places, contains objectionable amounts of iron. The Niagara dolomite, potentially a source of moderate to large quantities of water in the eastern part of the area, probably will yield 500 gpm or more to wells. In 1959, the average withdrawal of water for all uses was estimated at 495 mgd, of which 98.2 percent was from surface-water sources and 1.8 percent was from wells. About 485 mgd of water was withdrawn for industrial use, 6 mgd for public supply, and 4 mgd for rural use. The industrial use of water averaged 441 mgd for condenser cooling, 38 mgd fot processing by the paper industry, and 6 mgd for other industrial uses. The city of Green Bay used 7.8 mgd of water from Lake Michigan; other public supplies in the area used 2.6 mgd from wells. Of the withdrawals of water for rural use, about 75 percent was from wells and about 25 percent was from streams. The discharge of wastes into the lower Fox River and its tributary streams has altered the quality of the natural water. The wastes consist chiefly of treated municipal sewage and treated and untreated wastes from the paper industry, rendering plants, a sugar mill, and other industries. The industrial waste makes up about 90 percent of the oxygen-demand loading in the lower Fox River, and treated municipal sewage accounts for about 10 percent. The dissolved-oxygen concentration of water in the lower Fox River decreases rapidly in the vicinity of Green Bay during the summer when the river water is warm. If the periods when the river water is warmest, generally during July and early August, were to coincide with periods of lowest annual streamflow, generally in late August, the river would be unable to assimilate the loading of decomposable organic matter. In an emergency, industrial and public supply wells could supply at least 6 mgd for a sustained period and probably as much as 10 mgd for a period of several days. Six of the wells that formerly supplied the city of Green Bay are maintained in operating condition and could furnish about the same quantity of water as the industrial and other public supply wells. Small streams in the area would be supplemental sources of water, and the water in the Fox River and Green Bay is easily accessible.

Wisconsin↗

Decomposing the Tea Bag Index and finding slower organic matter loss rates at higher elevations and deeper soil horizons in a minerogenic salt marsh

Environmental gradients can affect organic matter decay within and across wetlands and contribute to spatial heterogeneity in soil carbon stocks. We tested the sensitivity of decay rates to tidal flooding and soil depth in a minerogenic salt marsh using the Tea Bag Index (TBI). Tea bags were buried at 10 and 50 cm depths across an elevation gradient in a subtropical Spartina alterniflora marsh in Georgia (USA). Plant and animal communities and soil properties were characterized once, while replicate tea bags and porewaters were collected several times over 1 year. TBI decay rates were faster than prior litterbag studies in the same marsh, largely due to rapid green tea loss. Rooibos tea decay rates were more comparable to natural marsh litter, potentially suggesting that is more useful as a standardized organic matter proxy than green tea. Decay was slowest at higher marsh elevations and not consistently related to other biotic (e.g., plants, crab burrows) or abiotic factors (e.g., porewater chemistry), indicating that local hydrology strongly affected organic matter loss rates. TBI rates were 32 %–118 % faster in the 10 cm horizon than at 50 cm. Rates were fastest in the first 3 months and slowed 54 %–60 % at both depths between 3 and 6 months. Rates slowed further between 6 and 12 months, but this was more muted at 10 cm (17 %) compared to 50 cm (50 %). Slower rates at depth and with time were unlikely due to the TBI stabilization factor, which was similar across depths and decreased from 6 to 12 months. Slower decay at 50 cm demonstrates that rates were constrained by environmental conditions in the deeper horizon rather than the composition of this highly standardized litter. Overall, these patterns suggest that hydrological setting, which affects oxidant introduction and reactant removal and is often overlooked in marsh decomposition studies, may be a particularly important control on organic matter loss in the short term (3–12 months).

Georgia↗

Rehabilitation of gypsum-mined lands in the Indian desert

The economic importance of mining in the Indian Desert is second only to agriculture. Land disturbed by mining, however, has only recently been the focus of rehabilitation efforts. This research assesses the success of rehabilitation plans used to revegetate gypsum mine spoils within the environmental constraints of the north-west Indian hot-desert ecosystem. The rehabilitation plan first examined both mined and unmined areas and established assessments of existing vegetative cover and the quality of native soils and mine spoils. Tests were made on the effect of the use, and conservation, of available water through rainwater harvesting, amendment application (for physical and chemical spoil modification), plant establishment protocols, and the selection of appropriate germ plasm. Our results show that the resulting vegetative cover is capable of perpetuating itself under natural conditions while concurrently meeting the needs of farmers. Although the mine spoils are deficient in organic matter and phosphorus, they possess adequate amounts of all other nutrients. Total boron concentrations (>5.0 mg kg-1) in both the topsail and mine spoil indicate potentially phytotoxic conditions. Electrical conductance of mine spoil is 6-10 times higher than for topsail with a near-neutral pH. Populations of spoil fungi, Azotobactor, and nitrifying bacteria are low. The soil moisture storage in rainwater harvesting plots increased by 8% over the control and 48% over the unmined area. As a result of rehabilitation efforts, mine spoils show a steady buildup in organic carbon, and P and K due to the decomposition of farmyard manure and the contribution of nitrogen fixation by the established leguminous plant species. The rehabilitation protocol used at the site appears to have been successful. Following revegetation of the area with a mixture of trees, shrubs, and grasses, native implanted species have become established. Species diversity, measured in terms of species richness, increased after one year and then gradually declined over time; the decline was the result of the loss of annual species. The study not only develops methods of gypsum mine land rehabilitation but also helps in understanding processes of rehabilitation success in arid regions and emphasizes the importance of long-term monitoring of rehabilitation success. Copyright ?? 2001 Taylor & Francis.

Arid Soil Research and Rehabilitation↗

Anthropogenic and natural variation in ridge and slough pollen assemblages

We present pollen evidence documenting the response of sawgrass ridge and slough systems of the Florida Everglades to hydrologic changes during the last 3,500 years. Sediment cores and surface samples were collected in three transects across sawgrass ridges and sloughs in Water Conservation Area 3A to determine the age of the features, long-term variability in plant community composition, stability of sawgrass ridge and slough size, and their response to 20th century changes in hydrology. Statistically significant differences in abundance of Cladium pollen in surface samples collected throughout the system allow differentiation of these communities in the sedimentary pollen record. Analysis of pollen in cores from the three transects indicates that the general distribution of ridges and sloughs has remained distinct through time. There is evidence the vegetation has responded to past global-scale climate events, such as the Medieval Warm Period, as well as the 20th century anthropogenic alterations to the natural hydrology. The ridge community is more responsive and susceptible to perturbations in hydrology than the slough community. In contrast, the slough plant community is more stable and less likely to demonstrate long-term changes after perturbations to hydrology. Regardless, these data indicate that the ridge and slough landscape is resilient to changes in hydrology and posses the potential to return to a natural state with the return of natural hydrologic conditions.

Florida↗

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper↗

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗

Large-scale fire management restores grassland bird richness for a private lands ecoregion

Of all terrestrial biomes, grasslands are losing the most biodiversity the most rapidly, so there is a critical need to document and learn from large-scale restoration successes. In the Loess Canyons ecoregion of the Great Plains, USA, an association of private ranchers and natural resource agencies has led a multi-decadal, ecoregion-scale initiative to combat the loss of grasslands to woody plant encroachment by restoring large-scale fire regimes. Here, we use 14 years of fire treatment history with 6 years of grassland bird monitoring and remotely sensed tree cover data across 136,767 ha of privately owned grassland to quantify outcomes of large-scale grassland restoration efforts. Grassland bird richness increased across 65% (90,032 ha) of the Loess Canyons, and woody plant cover decreased up to 55% across 25% (7408 ha) of all fire-treated areas. This was accomplished with extreme fire treatments that killed mature trees, were large (mean annual area burned was 3100 ha), spatially clustered and straddled boundaries between invasive woodlands and remaining grasslands – not heavily infested woodlands. Findings from this study provide the first evidence of human management reversing the impacts of woody encroachment on grassland birds at an ecoregion scale.

Nebraska↗

Changes in concentrations of triazine and acetamide herbicides by bank filtration, ozonation, and chlorination in a public water supply

The changes in triazine and acetamide concentrations in water during natural and artificial treatment by bank filtration, ozonation, filtration, and chlorination were measured at the well field and drinking water treatment plant of Lincoln, Nebraska, USA. The city's groundwater supply is affected by induced infiltration and transport of triazines and acetamide herbicides from the Platte River in late spring and early summer. The objective of the study was to evaluate the effect of infiltration and treatment on the presence of triazines and acetamides in drinking water. Samples of river water, well water, and public supply water at various stages of water treatment were collected from 1997-1999 during spring-runoff when the presence of herbicides in the Platte River is largest. In 1999, parent compounds were reduced by 76% of the concentration present in river water (33% by bank filtration, 41% by ozonation, and 1.5% by chlorination). Metabolites of herbicides for which analytical techniques existed were reduced by 21% (plus 26% by bank filtration, minus 23% by ozonation, and minus 24% by chlorination). However, increases in concentrations of specific metabolite compounds were identified after bank filtration and ozonation. After bank filtration, increases in cyanazine amide, cyanazine acid, and deethylcyanazine acid were identified. After ozonation, concentrations of deisopropylatrazine, deethylatrazine, didealkylatrazine, atrazine amide-I, hydroxydeethylatrazine, hydroxydeisopopylatrazine, deethylcyanazine acid, and deethylcyanazine increased. Concentrations of cyanazine acid and ethanesulfonic and oxanilic acids of acetamides decreased during ozonation. Our findings suggest that bank filtration and ozonation of water in part can shift the assessment of risk to human health associated with the consumption of the water from the parent compounds to their degradation products.

Journal of Hydrology↗