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Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate (NO2+NO3-N) in ground water in the Idaho part of the upper Snake River basin

Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, cyanazine, metolachlor, and simazine. This study developed maps that the Idaho State Department of Agriculture might use to predict the probability of detecting atrazine and desethyl-atrazine (a breakdown product of atrazine) in ground water in the Idaho part of the upper Snake River Basin. These maps can be incorporated in the State Pesticide Management Plan and help provide a sound hydrogeologic basis for atrazine management in the study area. Maps showing the probability of detecting atrazine/desethyl-atrazine in ground water were developed as follows: (1) Ground-water monitoring data were overlaid with hydrogeologic and anthropogenic data using a geographic information system to produce a data set in which each well had corresponding data on atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Individual (univariate) relations between atrazine/desethyl-atrazine in ground water and atrazine use, depth to ground water, geology, land use, precipitation, soils, and well depth data were evaluated to identify those independent variables significantly related to atrazine/ desethyl-atrazine detections. (3) Several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected. (5) The multivariate models were entered into the geographic information system and the probability maps were constructed. Two models which best predicted the presence of atrazine/desethyl-atrazine in ground water were selected; one with and one without atrazine use. Correlations of the predicted probabilities of atrazine/desethyl-atrazine in ground water with the percent of actual detections were good; r-squared values were 0.91 and 0.96, respectively. Models were verified using a second set of groundwater quality data. Verification showed that wells with water containing atrazine/desethyl-atrazine had significantly higher probability ratings than wells with water containing no atrazine/desethylatrazine (p <0.002). Logistic regression also was used to develop a preliminary model to predict the probability of nitrite plus nitrate as nitrogen concentrations greater than background levels of 2 milligrams per liter. A direct comparison between the atrazine/ desethyl-atrazine and nitrite plus nitrate as nitrogen probability maps was possible because the same ground-water monitoring, hydrogeologic, and anthropogenic data were used to develop both maps. Land use, precipitation, soil hydrologic group, and well depth were significantly related with atrazine/desethyl-atrazine detections. Depth to water, land use, and soil drainage were signifi- cantly related with elevated nitrite plus nitrate as nitrogen concentrations. The differences between atrazine/desethyl-atrazine and nitrite plus nitrate as nitrogen relations were attributed to differences in chemical behavior of these compounds in the environment and possibly to differences in the extent of use and rates of their application.

Idaho↗

Geohydrology and water quality of stratified-drift aquifers in the Contoocook River basin, south-central New Hampshire

Stratified-drift aquifers discontinuously underlie 121 mi2 (square miles) of the Contoocook River Basin, which has a total drainage area of 776 mi2. Maps of these aquifers, showing water-table configurations, saturated thicknesses, and transmissivities were prepared from well and test-hole data and seismic-refraction profiles. The distribution of stratified-drift aquifers is largely controlled by the Pleistocene glaciation process and the formation of multiple glacial lakes along the main stem of the Contoocook River. Locally, saturated thickness of stratified drift within these aquifers are as great as 200 feet. Estimated transmissivities exceed 8,000 ft2/d (squared feet per day) at three locations and is as high as 22,800 ft2/d at one location. Stratified-drift aquifers that have the greatest potential to supply additional amounts of water include the aquifers at Greenfield-Otter Brook and Hancock-Norway Pond. Potential yields to hypothetical supply wells were estimated for the Greenfield-Otter Brook, Hillsborough-Contoocook River, and Andover- Blackwater River aquifers by use of a analytical ground-water-flow model. The model results predict that the potential yields are greatest from the Greenfield-Otter Brook aquifer, yielding up to 1.85 gallons per day during half-year periods of no recharge. The effective ground-water recharge to the entire basin, which includes recharge to the till, bedrock, and stratified drift, is 13.9 in./yr (inches per year) (521 million gallons per day) on the basis of hydrograph separation of streamflow. The quality of water obtained from 11 observation wells and 10 municipal supply wells is generally suitable for drinking and most other domestic purposes. Ground water in the region has low alkalinity, is slightly acidic, and has low concentrations of dissolved solids. Concentrations of dissolved constituents in ground-water samples were generally less than the U.S. Environmental Protection Agency's primary and secondary maximum contaminant levels except for elevated iron concentrations (in water from six wells) and manganese concentrations in water from seven wells.

Water-Resources Investigations Report↗

Induced infiltration from the Rockaway River and water chemistry in a stratified-drift aquifer at Dover, New Jersey, with a section on modeling ground-water flow in the Rockaway River Valley

The vertical hydraulic conductivity per unit thickness (streambed leakance) of unconsolidated sediment immediately beneath the channel of the Rockaway River near a municipal well field at Dover, N.J., is between 0.2 and 0.6 feet per day per foot and is probably near the low end of this range. This estimate is based on evaluation of three lines of evidence: (1) Streamflow measurements, which indicated that induced infiltration of river water near the well field averaged 0.67 cubic feet per second; (2) measurements of the rate of downward propagation of diurnal fluctuations in dissolved oxygen and water temperature at three piezometers, which indicated vertical Darcian flow velocities of 0.6 and 1.5 feet per day, respectively; and (3) chemical mixing models based on stable isotopes of oxygen and hydrogen, which indicated that 30 percent of the water reaching a well near the center of the well field was derived from the river. The estimated streambed-leakance values are compatible with other aquifer properties and with hydraulic stresses observed over a 2-year period, as demonstrated by a set of six alternative groundwater flow models of the Rockaway River valley. Simulated water levels rose 0.5 to 1.7 feet near the well field when simulated streambed leakance was changed from 0.2 to 0.6 feet per day per foot, or when a former reach of the Rockaway River valley that is now blocked by glacial drift was simulated as containing a continuous sand aquifer (rather than impermeable till). Model recalibration to observed water levels could accommodate either of these changes, however, by plausible adjustments in hydraulic conductivity of 35 percent or less. The ground-water flow models incorporate a new procedure for simulating areal recharge, in which water available for recharge in any time interval is accepted as recharge only where the water level in the uppermost model layer is below land surface. Water rejected as recharge on upland hillsides is allowed to recharge aquifers at the base of the hillsides. Inclusion of uplands in models of valley-fill aquifers and use of the new procedure increases model complexity and data requirements, but automates the simulation of recharge to those aquifers from the uplands, even in transient-state simulations with multiple periods of varied stresses, and facilitates delineation of upland areas that contribute water to well fields. The area from which ground water flowed toward the Dover well field decreased with an increase in simulated streambed leakance or an increase in simulated hydraulic conductivity of upland till. Concentrations of solutes in ground water near the Dover well field reflect the mixing of native ground water with water infiltrated from the Rockaway River. Chemical reactions in the aquifer, chiefly the weathering of carbonate minerals by dissolved carbon dioxide, affect the pH and the concentrations of both solutes and dissolved gases. Concentrations of sodium, chloride, and sulfate appear to be related to man's activities, such as road deicing, or to decay of organic matter in the aquifer.

New Jersey↗

Evapotranspiration of applied water, Central Valley, California, 1957-78

In the Central Valley, Calif., where 57% of the 20,000 square miles of land is irrigated, ground-water recharge from agricultural lands is an important input to digital simulation models of ground-water flow. Several methods of calculating recharge were explored for the Central Valley Aquifer Project and a simplified water budget was designed where net recharge (recharge minus pumpage) equals net surface water diverted minus evapotranspiration of applied water (ETAW). This equation eliminates the need to determine pumpage from the water-table aquifer, assuming that the time lag for infiltration is not longer than the time intervals of interest for modeling. This study evaluates only the evapotranspiration of applied water. Future reports will describe the other components of the water budget. ETAW was calculated by summing the products of ETAW coefficients and respective crop areas for each 7 1/2-minute quadrangle area in the valley, for each of three land-use surveys between 1957 and 1978. In 1975 total ETAW was 15.2 million acre-feet, a 43% increase since 1959. The largest increases were in the south, especially Kern County, which had a sixfold increase, which was caused by the import of surface water in the California Aqueduct. (USGS)

California↗

Estimating the Probability of Elevated Nitrate Concentrations in Ground Water in Washington State

Logistic regression was used to relate anthropogenic (manmade) and natural variables to the occurrence of elevated nitrate concentrations in ground water in Washington State. Variables that were analyzed included well depth, ground-water recharge rate, precipitation, population density, fertilizer application amounts, soil characteristics, hydrogeomorphic regions, and land-use types. Two models were developed: one with and one without the hydrogeomorphic regions variable. The variables in both models that best explained the occurrence of elevated nitrate concentrations (defined as concentrations of nitrite plus nitrate as nitrogen greater than 2 milligrams per liter) were the percentage of agricultural land use in a 4-kilometer radius of a well, population density, precipitation, soil drainage class, and well depth. Based on the relations between these variables and measured nitrate concentrations, logistic regression models were developed to estimate the probability of nitrate concentrations in ground water exceeding 2 milligrams per liter. Maps of Washington State were produced that illustrate these estimated probabilities for wells drilled to 145 feet below land surface (median well depth) and the estimated depth to which wells would need to be drilled to have a 90-percent probability of drawing water with a nitrate concentration less than 2 milligrams per liter. Maps showing the estimated probability of elevated nitrate concentrations indicated that the agricultural regions are most at risk followed by urban areas. The estimated depths to which wells would need to be drilled to have a 90-percent probability of obtaining water with nitrate concentrations less than 2 milligrams per liter exceeded 1,000 feet in the agricultural regions; whereas, wells in urban areas generally would need to be drilled to depths in excess of 400 feet.

Scientific Investigations Report↗

Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States

The ability of natural attenuation to mitigate agricultural nitrate contamination in recharging aquifers was investigated in four important agricultural settings in the United States. The study used laboratory analyses, field measurements, and flow and transport modeling for monitoring well transects (0.5 to 2.5 km in length) in the San Joaquin watershed, California, the Elkhorn watershed, Nebraska, the Yakima watershed, Washington, and the Chester watershed, Maryland. Ground water analyses included major ion chemistry, dissolved gases, nitrogen and oxygen stable isotopes, and estimates of recharge date. Sediment analyses included potential electron donors and stable nitrogen and carbon isotopes. Within each site and among aquifer-based medians, dissolved oxygen decreases with ground water age, and excess N 2 from denitrification increases with age. Stable isotopes and excess N 2 imply minimal denitrifying activity at the Maryland and Washington sites, partial denitrification at the California site, and total denitrification across portions of the Nebraska site. At all sites, recharging electron donor concentrations are not sufficient to account for the losses of dissolved oxygen and nitrate, implying that relict, solid phase electron donors drive redox reactions. Zero-order rates of denitrification range from 0 to 0.14 μmol N L −1 d −1 , comparable to observations of other studies using the same methods. Many values reported in the literature are, however, orders of magnitude higher, which is attributed to a combination of method limitations and bias for selection of sites with rapid denitrification. In the shallow aquifers below these agricultural fields, denitrification is limited in extent and will require residence times of decades or longer to mitigate modern nitrate contamination.

Journal of Environmental Quality↗

Simulated Effects of Alternative Pumping Strategies on Ground-Water-Flow Patterns and Areas Contributing Recharge to Selected Wells near Kenvil, Morris County, New Jersey

Ground-water-flow patterns and areas contributing recharge to supply wells change in response to new or altered pumping stresses. An understanding of these potential changes is essential for the effective evaluation of possible future water-supply alternatives, especially if the supply wells may be vulnerable to contamination from the land surface. Demand for water from a valley-fill and carbonate-rock aquifer system in the study area near Kenvil in Morris County, New Jersey, is expected to increase as the population of communities grows in and near the area. As withdrawals increase and new supplies are developed over time, ground-water-flow patterns and areas contributing recharge to supply wells in the area are expected to change. Flow patterns and areas contributing recharge to selected supply wells in the aquifer system in the study area, under a variety of hypothetical withdrawal conditions, were evaluated by use of numerical modeling techniques. Under the four alternative scenarios evaluated, withdrawals from selected wells are increased by a total of 1.3 to 2.4 million gallons per day, or 32 to 56 percent over the recent (1991-95) total withdrawals from the study area. The scenarios were incorporated in simulations of ground-water flow that were conducted by use of a previously developed three-dimensional numerical model. Flow-path comparisons indicate that ground-water-flow patterns change in response to changes in pumping rates and (or) new pumping stresses. Under the scenarios represented in the simulations, water levels (hydraulic heads) in the study area decline from 0 to as much as 63 ft. Under most of the scenarios evaluated, downward leakage of ground water increases and upward discharge to streams decreases. In some scenarios, supply wells intercept additional local flow, whereas in other scenarios additional regional flow is intercepted. Areas contributing recharge to wells also change or develop. Changes in flow patterns and in the location, size, and shape of areas contributing recharge to supply wells depend on the location and magnitude of the change in withdrawal stress and on other hydrogeologic factors, such as the configuration of aquifer boundaries and differences in aquifer properties.

Water-Resources Investigations Report↗

Predictive simulation of alternatives for managing the water resources of North Fork Solomon River Valley between Kirwin Dam and Waconda Lake, north-central Kansas

Since 1974 water levels in the alluvial aquifer of the North Fork Solomon River Valley in north-central Kansas have decreased due to increases in ground-water pumpage, decreases in availability of surface water for irrigation, and below-average precipitation. A finite-element model was developed in cooperation with the U.S. Bureau of Reclamation to simulate changing conditions between 1970-79. Model results indicate that annual recharge to the aquifer due to precipitation, applcation of water for irrigation, and canal leakage averaged about 22,825 acre-feet and that annual ground-wate discharge to the river averaged about 16,590 acre-feet. Predictive simulations for 1980-2000 were made using management alternatives that involved clay-lining of irrigation ditches, reduction of surface-water availability with and without an increase in ground-water pumping, and continuation of 1979 pumping conditions. The simulations indicated that as much as 5.5 feet of additional average water-level drawdown in wells would occur by 2000 if surface-water supply were reduced 100 percent and ground-water pumpage increased. The simulations also indicated that a decrease in average drawdown of 0.55 foot would occur by 2000 and that base flow to the river would decrease to 12,300 acre-feet per year if 1979 conditions remained constant. (USGS)

Water-Resources Investigations Report↗

Evaluating the effects of urbanization and land-use planning using ground-water and surface-water models

Why are the effects of urbanization a concern? As the city of Middleton, Wisconsin, and its surroundings continue to develop, the Pheasant Branch watershed (fig.l) is expected to undergo urbanization. For the downstream city of Middleton, urbanization in the watershed can mean increased flood peaks, water volume and pollutant loads. More subtly, it may also reduce water that sustains the ground-water system (called "recharge") and adversely affect downstream ecosystems that depend on ground water such as the Pheasant Branch Springs (hereafter referred to as the Springs). The relation of stormwater runoff and reduced ground-water recharge is complex because the surface-water system is coupled to the underlying ground-water system. In many cases there is movement of water from one system to the other that varies seasonally or daily depending on changing conditions. Therefore, it is difficult to reliably determine the effects of urbanization on stream baseflow and spring flows without rigorous investigation. Moreover, mitigating adverse effects after development has occurred can be expensive and administratively difficult. Overlying these concerns are issues such as stewardship of the resource, the rights of the public, and land owners' rights both of those developing their land and those whose land is affected by this development. With the often- contradictory goals, a scientific basis for assessing effects of urbanization and effectiveness of mitigation measures helps ensure fair and constructive decision-making. The U.S. Geological Survey, in cooperation with the City of Middleton and Wisconsin Department of Natural Resources, completed a study that helps address these issues through modeling of the hydrologic system. This Fact Sheet discusses the results of this work.

Wisconsin↗

Ground-water flow and the potential effects of remediation at Graces Quarters, Aberdeen Proving Ground, Maryland

Ground water in the east-central part of Graces Quarters, a former open-air chemical-agent test facility at Aberdeen Proving Ground, Maryland, is contaminated with chlorinated volatile organic compounds. The U.S. Geological Survey's finite- difference model was used to help understand ground-water flow and simulate the effects of alternative remedial actions to clean up the ground water. Scenarios to simulate unstressed conditions and three extraction well con- figurations were used to compare alternative remedial actions on the contaminant plume. The scenarios indicate that contaminants could migrate from their present location to wetland areas within 10 years under unstressed conditions. Pumping 7 gal/min (gallons per minute) from one well upgradient of the plume will not result in containment or removal of the highest contaminant concentrations. Pumping 7 gal/min from three wells along the central axis of the plume should result in containment and removal of dissolved contami- nants, as should pumping 7 gal/min from three wells at the leading edge of the plume while injecting 7 gal/min back into an upgradient well.

Water-Resources Investigations Report↗

Hydrogeology of the surficial and intermediate aquifer systems in Sarasota and adjacent counties, Florida

From 1991 to 1995, the hydrogeology of the surficial aquifer system and the major permeable zones and confining units of the intermediate aquifer system in southwest Florida was studied. The study area is a 1,400-square-mile area that includes Sarasota County and parts of Manatee, De Soto, Charlotte, and Lee Counties. Lithologic, geophysical, hydraulic property, and water-level data were used to correlate the hydrogeology and map the extent of the aquifer systems. Water chemistry was evaluated in southwest Sarasota County to determine salinity of the surficial and intermediate aquifer systems. The surficial aquifer is an unconfined aquifer system that overlies the intermediate aquifer system and ranges from a few feet to over 60 feet in thickness in the study area. Hydraulic properties of the surficial aquifer system determined from aquifer and laboratory tests, and model simulations vary considerably across the study area. The intermediate aquifer system, a confined aquifer system that lies between the surficial and the Upper Floridan aquifers, is composed of alternating confining units and permeable zones. The intermediate aquifer system has three major permeable zones that exhibit a wide range of hydraulic properties. Horizontal flow in the intermediate aquifer system is northeast to southwest. Most of the study area is in a discharge area of the intermediate aquifer system. Water ranges naturally from fresh in the surficial aquifer system and upper permeable zones of the intermediate aquifer system to moderately saline in the lower permeable zone. Water-quality data collected in coastal southwest Sarasota County indicate that ground-water withdrawals from major pumping centers have resulted in lateral seawater intrusion and upconing into the surficial and intermediate aquifer systems.

Florida↗

Digital model of the Hollister Valley ground-water basin, San Benito County, California

A two-dimensional finite-difference digital model was constructed to simulate effects of proposed pumping and recharge schemes on water levels in the Hollister Valley ground-water basin. Pumping rates in the valley are expected to increase from 24,000 acre-feet per year in 1968 to an ultimate rate of 38,500 acre-feet per year. The model was calibrated for the period 1940-51 and tested by simulating water-level changes from 1951 to 1968. Model-generated water levels were generally within 15 feet of observed water levels for the calibration period. For the testing period, computed and observed water levels differed by as much as 35 feet in parts of the study area. Discrepancies in the test results may be caused by errors in historical pumpage data or by unidentified faults or local semiconfined conditions. Under one proposed development scheme, model-predicted water levels to the year 2020 declined up to 170 feet in previously undeveloped areas. For developed areas near the city of Hollister, water-level declines of 100 to 125 feet were predicted for the same period. (Woodard-USGS)

California↗

Evaluation of selected model constraints and variables on simulated sustainable yield from the Mississippi River Valley alluvial aquifer system in Arkansas

An existing conjunctive use optimization model of the Mississippi River Valley alluvial aquifer was used to evaluate the effect of selected constraints and model variables on ground-water sustainable yield. Modifications to the optimization model were made to evaluate the effects of varying (1) the upper limit of ground-water withdrawal rates, (2) the streamflow constraint associated with the White River, and (3) the specified stage of the White River. Upper limits of ground-water withdrawal rates were reduced to 75, 50, and 25 percent of the 1997 ground-water withdrawal rates. As the upper limit is reduced, the spatial distribution of sustainable pumping increases, although the total sustainable pumping from the entire model area decreases. In addition, the number of binding constraint points decreases. In a separate analysis, the streamflow constraint associated with the White River was optimized, resulting in an estimate of the maximum sustainable streamflow at DeValls Bluff, Arkansas, the site of potential surface-water withdrawals from the White River for the Grand Prairie Area Demonstration Project. The maximum sustainable streamflow, however, is less than the amount of streamflow allocated in the spring during the paddlefish spawning period. Finally, decreasing the specified stage of the White River was done to evaluate a hypothetical river stage that might result if the White River were to breach the Melinda Head Cut Structure, one of several manmade diversions that prevents the White River from permanently joining the Arkansas River. A reduction in the stage of the White River causes reductions in the sustainable yield of ground water.

Arkansas↗

The potential for saltwater intrusion in the Potomac aquifers of the York-James Peninsula, Virginia

The most productive aquifers of the Virginia Coastal Plain are in the Potomac Formation. Water supplies in the Potomac aquifers are impaired, however, by saltwater in some areas. A two-dimensional, densitydependent, solute-transport model was used to investigate saltwater movement in the Potomac aquifers and the potential for saltwater intrusion or upward migration of saltwater. The model was designed to represent a simplified section of the Potomac aquifers and associated confining units near Lee Hall, Va. Solute-transport simulations show that the direction of ground-water flow and the hydrogeologic properties, particularly the permeability of aquifers and the distribution of confining sediments in the Potomac Formation, control the system hydrodynamics and saltwater movement in the Potomac aquifers. The simulations indicate lateral intrusion for the Lower Potomac aquifer near Lee Hall, Va. Velocity vectors of the simulations indicate that a hypothetical, but typical, production well in the Middle Potomac aquifer could induce upconing only within the immediate vicinity of the well. Migration of saltwater from the Middle and Lower Potomac aquifers east of the hypothetical well also was indicated by the simulations.

Virginia↗

Simulated effects of pumping irrigation wells on ground-water levels in western Saginaw County, Michigan

Success of agriculture in many areas of Michigan relies on withdrawal of large quantities of ground water for irrigation. In some areas of the State, water-level declines associated with large ground-water withdrawals may adversely affect nearby residential wells. Residential wells in several areas of Saginaw County, in Michigan's east-central Lower Peninsula, recently went dry shortly after irrigation of crop lands commenced; many of these wells also went dry during last year's agricultural cycle (summer 2000). In September 2000, residential wells that had been dry returned to function after cessation of pumping from large-capacity irrigation wells. To evaluate possible effects of groundwater withdrawals from irrigation wells on residential wells, the U.S. Geological Survey used hydrogeologic data including aquifer tests, water-level records, geologic logs, and numerical models to determine whether water-level declines and the withdrawal of ground water for agricultural irrigation are related. Numerical simulations based on representative irrigation well pumping volumes and a 3-month irrigation period indicate water-level declines that range from 5.3 to 20 feet, 2.8 to 12 feet and 1.7 to 6.9 feet at distances of about 0.5, 1.5 and 3 miles from irrigation wells, respectively. Residential wells that are equipped with shallow jet pumps and that are within 0.5 miles of irrigation wells would likely experience reduced yield or loss of yield during peak periods of irrigation. The actual 1 extent that irrigation pumping cause reduced function of residential wells, however, cannot be fully predicted on the basis of the data analyzed because many _other factors may be adversely affecting the yield of residential wells.

Michigan↗

Preliminary conceptual models of the occurrence, fate, and transport of chlorinated solvents in karst regions of Tennessee

Published and unpublished reports and data from 22 contaminated sites in Tennessee were reviewed to develop preliminary conceptual models of the behavior of chlorinated solvents in karst aquifers. Chlorinated solvents are widely used in many industrial operations. High density and volatility, low viscosity, and solubilities that are low in absolute terms but high relative to drinkingwater standards make chlorinated solvents mobile and persistent contaminants that are difficult to find or remove when released into the groundwater system. The major obstacle to the downward migration of chlorinated solvents in the subsurface is the capillary pressure of small openings. In karst aquifers, chemical dissolution has enlarged joints, bedding planes, and other openings that transmit water. Because the resulting karst conduits are commonly too large to develop significant capillary pressures, chlorinated solvents can migrate to considerable depth in karst aquifers as dense nonaqueous-phase liquids (DNAPL's). Once chlorinated DNAPL accumulates in a karst aquifer, it becomes a source for dissolved-phase contamination of ground water. A relatively small amount of chlorinated DNAPL has the potential to contaminate ground water over a significant area for decades or longer. Conceptual models are needed to assist regulators and site managers in characterizing chlorinated-solvent contamination in karst settings and in evaluating clean-up alternatives. Five preliminary conceptual models were developed, emphasizing accumulation sites for chlorinated DNAPL in karst aquifers. The models were developed for the karst regions of Tennessee, but are intended to be transferable to similar karst settings elsewhere. The five models of DNAPL accumulation in karst settings are (1) trapping in regolith, (2) pooling at the top of bedrock, (3) pooling in bedrock diffuse-flow zones, (4) pooling in karst conduits, and (5) pooling in isolation from active ground-water flow. More than one conceptual model of DNAPL accumulation may be applicable to a given site, depending on details of the contaminant release and geologic setting. Trapping in regolith is most likely to occur where the regolith is thick and relatively impermeable with few large cracks, fissures, or macropores. Accumulation at the top of rock is favored by flat-lying strata with few fractures or karst features near the bedrock surface. Fractures or karst features near the bedrock surface encourage migration of chlorinated DNAPL into karst conduits or diffuse-flow zones in bedrock. DNAPL can migrate through one bedrock flow regime into an underlying flow regime with different characteristics or into openings that are isolated from significant ground-water flow. As a general rule, the difficulty of finding and removing DNAPL increases with depth, lateral distance from the source, and complexity of the ground-water flow system. The prospects for mitigation are generally best for DNAPL accumulation in the regolith or at the bedrock surface. However, many such accumulations are likely to be difficult to find or remove. Accumulations in bedrock diffuse-flow zones or in fractures isolated from flow may be possible to find and partially mitigate, but will likely leave significant amounts of contaminant in small fractures or as solute diffused into primary pores.

Tennessee↗

Effects of Aquifer Development and Changes in Irrigation Practices on Ground-Water Availability in the Santa Isabel Area, Puerto Rico

The alluvial aquifer in the area of Santa Isabel is located within the South Coastal Plain aquifer of Puerto Rico. Variations in precipitation, changes in irrigation practices, and increasing public-supply water demand have been the primary factors controlling water-level fluctuations within the aquifer. Until the late 1970s, much of the land in the study area was irrigated using inefficient furrow flooding methods that required large volumes of both surface and ground water. A gradual shift in irrigation practices from furrow systems to more efficient micro-drip irrigation systems occurred between the late 1970s and the late 1980s. Irrigation return flow from the furrow-irrigation systems was a major component of recharge to the aquifer. By the early 1990s, furrow-type systems had been replaced by the micro-drip irrigation systems. Water levels declined about 20 feet in the aquifer from 1985 until present (February 2003). The main effect of the changes in agricultural practices is the reduction in recharge to the aquifer and total irrigation withdrawals. Increases in ground-water withdrawals for public supply offset the reduction in ground-water withdrawals for irrigation such that the total estimated pumping rate in 2003 was only 8 percent less than in 1987. Micro-drip irrigation resulted in the loss of irrigation return flow to the aquifer. These changes resulted in lowering the water table below sea level over most of the Santa Isabel area. By 2002, lowering of the water table reversed the natural discharge along the coast and resulted in the inland movement of seawater, which may result in increased salinity of the aquifer, as had occurred in other parts of the South Coastal Plain. Management alternatives for the South Coastal Plain aquifer in the vicinity of Santa Isabel include limiting groundwater withdrawals or implementing artificial recharge measures. Another alternative for the prevention of saltwater intrusion is to inject freshwater or treated sewage effluent into wells along the coast. A digital ground-water flow model was developed to provide information for water managers to evaluate some of these alternatives. After calibration of the ground-water model to historical data, four simulations of ground-water management strategies were performed: ground-water conservation, surface infiltration over existing agricultural fields, or infiltration along streams and canals, or injection wells along the coast. Simulations of four alternative water management strategies indicate that current condition of water levels below sea level near the coast can be reversed to raise water levels above sea level by either: (1) about a 27 percent reduction in 2003 ground-water withdrawal rates; (2) application of about 1,700 million gallons per year of artificial recharge over more than half of the current agricultural areas; (3) injection of about 3 million gallons per day (1,095 million gallons per year) of freshwater or treated wastewater in wells distributed along the coast; (4) injection of about 3.5 million gallons per day (1,280 million gallons per year) of freshwater or treated wastewater in wells distributed along canals and streams.

Water-Resources Investigations Report↗

Ground-water flow and saline water in the shallow aquifer system of the southern watersheds of Virginia Beach, Virginia

Population and tourism continues to grow in Virginia Beach, Virginia, but the supply of freshwater is limited. A pipeline from Lake Gaston supplies water for northern Virginia Beach, but ground water is widely used to water lawns in the north, and most southern areas of the city rely solely on ground water. Water from depths greater than 60 meters generally is too saline to drink. Concentrations of chloride, iron, and manganese exceed drinking-water standards in some areas. The U.S. Geological Survey, in cooperation with the city of Virginia Beach, Department of Public Utilities, investigated the shallow aquifer system of the southern watersheds to determine the distribution of fresh ground water, its potential uses, and its susceptibility to contamination. Aquifers and confining units of the southern watersheds were delineated and chloride concentrations in the aquifers and confining units were contoured. A ground-water-flow and solute-transport model of the shallow aquifer system reached steady state with regard to measured chloride concentrations after 31,550 years of freshwater recharge. Model simulations indicate that if freshwater is found in permeable sediments of the Yorktown-Eastover aquifer, such a well field could supply freshwater, possibly for decades, but eventually the water would become more saline. The rate of saline-water intrusion toward the well field would depend on the rate of pumping, aquifer properties, and on the proximity of the well field to saline water sources. The steady-state, ground-water-flow model also was used to simulate drawdowns around two hypothetical well fields and drawdowns around two hypothetical open-pit mines. The chloride concentrations simulated in the model did not approximate the measured concentrations for some wells, indicating sites where local hydrogeologic units or unit properties do not conform to the simple hydrogeology of the model. The Columbia aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer compose the hydrogeologic units of the shallow aquifer system of Virginia Beach. The Columbia and Yorktown-Eastover aquifers are poorly confined throughout most of the southern watersheds of Virginia Beach. The freshwater-to-saline-water distribution probably is in a dynamic equilibrium throughout most of the shallow aquifer system. Freshwater flows continually down and away from the center of the higher altitudes to mix with saline water from the tidal rivers, bays, salt marshes, and the Atlantic Ocean. Fresh ground water from the Columbia aquifer also leaks down through the Yorktown confining unit into the upper half of the Yorktown-Eastover aquifer and flows within the Yorktown-Eastover above saline water in the lower half of the aquifer. Ground-water recharge is minimal in much of the southern watersheds because the land surface generally is low and flat.

Water-Resources Investigations Report↗