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At least 595 records · Page 33Linked to original sources
USGS2024

Energy-related rare earth element sources

Energy-related materials such as coal, coal-bearing wastes, and coal combustion products are traditionally thought of as sources or by-products of electric power generation. Increasingly, these materials are considered resources for their content of rare earth elements (REEs) and other useful constituents. In this chapter, we examine the distribution, modes of occurrence, and relative extractability of REEs from coal-derived materials. We also consider economic factors associated with recovery of REEs from these sources. While several coal-derived sources show promise for REE recovery at the pilot scale, in all cases, REE contents are much below those of primary ores, such that extraction and concentrating the REEs require new and innovative approaches that are largely developmental. Among coal-related sources, fly ash is the most REE-enriched, as REEs from coal are strongly retained in these refractory solids remaining after coal combustion. Partitioning of coal-derived elements into fly ash has been known for decades but this has yet to be commercially exploited. A key drawback shown in this chapter is that a significant fraction of REEs in fly ash is contained in highly insoluble aluminosilicate glasses that make up the largest portion of this material. In addition to testing chemical or physical pretreatment approaches to help improve the extractability of REEs from fly ash, current research is applying modern analytical approaches to better understand the distribution of REEs on increasingly smaller scales, in the interest of targeting their recovery. Next-most REE-enriched among coal-related materials are solid waste products of coal mining and wastes from coal preparation, both of which are REE-enriched relative to coal itself. These waste coals concentrate mineralogical constituents that are excluded during mining or removed during coal preparation because they do not contribute to the heating value of coal for power generation. Recovery of REEs from coal waste has shown promise at the pilot scale and has the added benefit of converting a waste into useful constituents. Total REE contents of commercial coals are, on average, much below the 300 parts per million interest level for REE recovery set by the U.S. Department of Energy (DOE). However, as reviewed in this chapter, certain horizons within coal beds show preferential REE enrichment and could be targeted by selective mining. Beyond this, certain coals are REE-enriched overall due to their unique geologic histories involving derivation from REE-enriched sediment sources, deposition of volcanic ash during coal formation, or interaction of coal with REE-bearing fluids. Acidic drainage from abandoned coal mines is produced by the breakdown of pyrite (FeS 2 ), which is unstable in oxygenated conditions. While these acidic fluids have lower REE contents than any of the coal-based solids described above, they are proportionally enriched in certain heavy rare earths, especially yttrium (Y). Precipitates from coal-based acid-mine drainage concentrate REEs to levels that are of interest for recovery, and these are also promising sources for extraction at the pilot scale.

Book chapter↗
USGS2022

Determination and prediction of rare earth element eeochemical associations in acid mine drainage treatment wastes

Acid mine drainage (AMD) has been proposed by various researchers as a novel source of rare earth elements (REE), a group of elements that include critical metals for clean energy and modern technologies. REE tend to be sequestered in the Fe-Al-Mn-rich solids produced during the treatment of AMD. These solids are typically managed as waste, but could be a low-cost, readily available REE source. Here, results from field sampling, solids characterization, and geochemical modeling are presented to identify the mechanism(s) of REE attenuation and determine the minerals/solid phases in AMD solids that are enriched in REE. This study reveals that solids produced from low-pH AMD that was passively treated by limestone contain elevated concentrations of REE with Al, Fe, and/or Mn. AMD solid characterization via sequential extraction demonstrated that Al and Mn oxides were more abundant than Fe oxides and that the REEs are mainly associated with Al/Mn phases. Additionally, sequential extractions demonstrate that for the AMD solids evaluated, acidic and/or reducing extractions are required to mobilize the REE. Finally, the “CausticTitrationREYs.exe” geochemical equilibrium model demonstrated in this study indicates that the observed dissolved REE attenuation can be explained via surface complexation on Fe, Al, and Mn oxides/hydroxides and not by REE compound precipitation. The model accurately predicts the pH dependent removal of dissolved REE and that Al and Mn oxides/hydroxides are largely responsible for dissolved REE removal for the systems evaluated. The modeling results are consistent with the characterization results that show that Al and Mn hydroxides are important hosting phases of REEs in AMD treatment systems. The results presented here can be used to identify conditions favorable for accumulation of REE-enriched AMD solids and possible chemical treatment(s) to mobilize REE. The geochemical model can be applied to active and/or passive AMD treatment systems to predict REE attenuation with Fe, Al, and Mn during treatment and what phases may be enriched in REE. This information can be used to engineer AMD systems to produce specific phases enriched in REE. The recovery of REE from AMD solids is an opportunity to transform the environmental and economical challenge of polluted mine drainage into an asset.

Conference Paper↗
USGS2025

Assessing lunar rare earth element resources

Rare Earth Elements (REEs) are increasingly attracting attention globally due to their pivotal role in enhancing the performance of various hightech devices. Small amounts of these elements greatly improve the performance of materials, making magnets stronger, lenses clearer, lights brighter, batteries last longer, etc. Here we examine the notion that REEs from the Moon might compete with mining on Earth.

Conference Paper↗
USGS1951

List of current and planned projects of the trace elements program, U.S. Geological Survey

This summary lists the Geological Survey's current and future investigations of uranium and other elements of related interest. The titles of the investigations are grouped under the headings listed in the table of contents. Entries in each category are listed alphabetically, according to author or project leader, and numbered consecutively.

Trace Elements Investigations↗
USGS1952

Numerical list of U.S. Geological Survey trace elements reports to September 15, 1952

This report lists in numerical order U.S. Geological Survey Trace Elements Investigations and Memorandum Reports and supersedes a similar report issued in January 1952 (TEI-202). This report contains lists not only of reports that have been transmitted to the U.S. Atomic Energy Commission, that is, those reports followed by a date, but also those reports for which tentative titles were available prior to the date of completion of this list, September 14, 1952. The reports that are in preparation and subject to change in title are indicated by an asterisk. The classifications that are shown for some of the reports issued prior to 1947 are uncertain; classifications shown are based on the best information available at the time that this report was prepared. To keep the numerical lists up to date, periodic supplements will be issued. The supplementary pages will be prepared so that they can be substituted for the pages in the present report. The Geological Survey does not have additional copies for permanent distribution of most of the reports listed, but copies of many of the completed reports can be loaned to organizations or individuals who are cooperating with the Atomic Energy Commission.

Trace Elements Investigations↗
USGS1953

Numerical list of U.S. Geological Survey Trace Elements Reports to April 30, 1953

This report contains 1) a list in numerical order of U.S. Geological Survey Trace Elements Investigations and Memorandum Reports, and 2) an author index for these reports. It supercedes TEI-30, issued in November 1952. This report contains lists not only of reports that have been transmitted to the U.S Atomic Energy Commission, that is, those reports followed by a date, but also those reports for which tentative titles were available prior to the date of completion of this list, April 30, 1953. The reports that are in preparation and subject to change in title are indicated by an asterisk. The classifications that are shown for some of the reports issued prior to 1947 are uncertain: classifications shown are based on the best information available at the time that this report was prepared. The Geological Survey does not have additional copies for permanent distribution of most of the reports listed, but copies of many of the completed reports can be loaned to organizations or individuals who are cooperating with the Atomic Energy Commission.

Trace Elements Investigations↗
USGS2016

Bayesian nitrate source apportionment to individual groundwater wells in the Central Valley by use of elemental and isotopic tracers

Groundwater quality is a concern in alluvial aquifers that underlie agricultural areas, such as in the San Joaquin Valley of California. Shallow domestic wells (less than 150 m deep) in agricultural areas are often contaminated by nitrate. Agricultural and rural nitrate sources include dairy manure, synthetic fertilizers, and septic waste. Knowledge of the relative proportion that each of these sources contributes to nitrate concentration in individual wells can aid future regulatory and land management decisions. We show that nitrogen and oxygen isotopes of nitrate, boron isotopes, and iodine concentrations are a useful, novel combination of groundwater tracers to differentiate between manure, fertilizers, septic waste, and natural sources of nitrate. Furthermore, in this work, we develop a new Bayesian mixing model in which these isotopic and elemental tracers were used to estimate the probability distribution of the fractional contributions of manure, fertilizers, septic waste, and natural sources to the nitrate concentration found in an individual well. The approach was applied to 56 nitrate-impacted private domestic wells located in the San Joaquin Valley. Model analysis found that some domestic wells were clearly dominated by the manure source and suggests evidence for majority contributions from either the septic or fertilizer source for other wells. But, predictions of fractional contributions for septic and fertilizer sources were often of similar magnitude, perhaps because modeled uncertainty about the fraction of each was large. For validation of the Bayesian model, fractional estimates were compared to surrounding land use and estimated source contributions were broadly consistent with nearby land use types.

California↗
USGS2018

Quantifying postfire aeolian sediment transport using rare earth element tracers

Grasslands, which provide fundamental ecosystem services in many arid and semiarid regions of the world, are undergoing rapid increases in fire activity and are highly susceptible to postfire-accelerated soil erosion by wind. A quantitative assessment of physical processes that integrates fire-wind erosion feedbacks is therefore needed relative to vegetation change, soil biogeochemical cycling, air quality, and landscape evolution. We investigated the applicability of a novel tracer technique—the use of multiple rare earth elements (REE)—to quantify soil transport by wind and to identify sources and sinks of wind-blown sediments in both burned and unburned shrub-grass transition zone in the Chihuahuan Desert, NM, USA. Results indicate that the horizontal mass flux of wind-borne sediment increased approximately threefold following the fire. The REE tracer analysis of wind-borne sediments shows that the source of the horizontal mass flux in the unburned site was derived from bare microsites (88.5%), while in the burned site it was primarily sourced from shrub (42.3%) and bare (39.1%) microsites. Vegetated microsites which were predominantly sinks of aeolian sediments in the unburned areas became sediment sources following the fire. The burned areas showed a spatial homogenization of sediment tracers, highlighting a potential negative feedback on landscape heterogeneity induced by shrub encroachment into grasslands. Though fires are known to increase aeolian sediment transport, accompanying changes in the sources and sinks of wind-borne sediments may influence biogeochemical cycling and land degradation dynamics. Furthermore, our experiment demonstrated that REEs can be used as reliable tracers for field-scale aeolian studies.

Journal of Geophysical Research: Biogeosciences↗
USGS2001

Polycyclic aromatic hydrocarbons, aliphatic hydrocarbons, trace elements and monooxygenase activity in birds nesting on the North Platte River, Casper, Wyoming, USA

Tree swallow (Tachycineta bicolor) and house wren (Troglodytes aedon) eggs and chicks were collected near a refinery site on the North Platte River, Casper, Wyoming, USA and at a reference site 10 km upstream. Total polycylic aromatic hydrocarbon (PAH) concentrations in swallow and wren chicks were higher at the refinery site than at the reference site. Polycylic aromatic hydrocarbon concentrations in sediment and chick dietary samples were consistent with these findings. The general lack of methylated PAHs in sediment, diet, and bird carcasses suggested that the PAHs were derived from combustion and not from petroleum. The predominance of odd numbered aliphatic hydrocarbons and the low ratios (≤ 0.25) of pristane: n -C 17 and phytane: n -C 18 in chick and diet samples also suggested that swallow and wren chicks were not being chronically exposed to petroleum. Mean ethoxyresorufin- O -dealkylase and benzyloxyresorufin- O -dealkylase activities in tree swallow livers averaged nine times higher at the refinery site than at the reference site and were probably induced by exposure to PAHs. Trace element concentrations in eggs and livers of swallows and wrens were similar or greater at the reference site than at the refinery site. Selenium, strontium, and boron concentrations were elevated in eggs and livers of swallows and wrens at both the refinery and reference sites.

Wyoming↗
USGS2016

Finite-element modelling of physics-based hillslope hydrology, Keith Beven, and beyond

Keith Beven is a voice of reason on the intelligent use of models and the subsequent acknowledgement/assessment of the uncertainties associated with environmental simula-tion. With several books and hundreds of papers, Keith’s work is widespread, well known, and highly referenced. Four of Keith’s most notable contributions are the iconic TOPMODEL (Beven and Kirkby, 1979), classic papers on macropores and preferential flow (Beven and Germann, 1982, 2013), two editions of the rainfall-runoff modelling bible (Beven, 2000a, 2012), and the selection/commentary for the first volume from the Benchmark Papers in Hydrology series (Beven, 2006b). Remarkably, the thirty-one papers in his benchmark volume, entitled Streamflow Generation Processes, are not tales of modelling wizardry but describe measurements designed to better understand the dynamics of near-surface systems (quintessential Keith). The impetus for this commentary is Keith’sPhD research (Beven, 1975), where he developed a new finite-element model and conducted concept-development simu-lations based upon the processes identified by, for example, Richards (1931), Horton (1933), Hubbert (1940), Hewlett and Hibbert (1963), and Dunne and Black (1970a,b). Readers not familiar with the different mechanisms of streamflow generation are referred to Dunne (1978).

Hydrological Processes↗
USGS2010

A 15 000-year record of climate change in northern New Mexico, USA, inferred from isotopic and elemental contents of bog sediments

Elemental (C, N, Pb) and isotopic ( δ 13 C, δ 15 N) measurements of cored sediment from a small bog in northern New Mexico reveal changes in climate during the Late Pleistocene and Holocene. Abrupt increases in Pb concentration and δ 13 C values ca. 14 420 cal. YBP indicate significant runoff to the shallow lake that existed at that time. Weathering and transport of local volcanic rocks resulted in the delivery of Pb-bearing minerals to the basin, while a 13 C-enriched terrestrial vegetation source increased the δ 13 C values of the sedimentary material. Wet conditions developed over a 300 a period and lasted for a few hundred years. The Younger Dryas period (ca. 12 700–11 500 cal. YBP) caused a reduction in terrestrial productivity reflected in decreasing C/N values, δ 15 N values consistently greater than 0‰ and low organic content. By contrast, aquatic productivity increased during the second half of this period, evidenced by increasing δ 13 C values at the time of highest abundance of algae. Dry conditions ca. 8 000–6 000 cal. YBP were characterised by low organic carbon content and high Pb concentrations, the latter suggesting enhanced erosion and aeolian transport of volcanic rock. The range in δ 13 C, δ 15 N and C/N values in the sedimentary record fall within the range of modern plants, except during the periods of runoff and drought. The sedimentary record provides evidence of natural climate variability in northern New Mexico, including short- (multi-centennial) and long-(millennial) term episodes during the Late Pleistocene and Holocene.

Journal of Quaternary Science↗
USGS2005

The complex variable boundary element method: Applications

The complex variable boundary element method (CVBEM) is used to approximate several potential problems where analytical solutions are known: A modelling result produced from the CVBEM is a measure of relative error in matching the known boundary condition values of the problem. A CVBEM error-reduction algorithm is used to reduce the relative error of the approximation by adding nodal points in boundary regions where error is large. From the-test problems, overall error is reduced significantly by utilizing the adaptive integration algorithm.

International Journal for Numerical Methods in Eng↗
USGS2010

Applying the silver-tube introduction method for thermal conversion elemental analyses and a new δ 2 H value for NBS 22 oil

The δ 2 H VSMOW–SLAP value of total hydrogen of the international measurement standard NBS 22 oil was determined by a new method of sealing water in silver tubes for use in a thermal conversion elemental analysis (TC/EA) reduction unit. The isotopic fractionation of water due to evaporation is virtually non-existent in this silver-tube method. A new value for the δ 2 H VSMOW–SLAP of NBS 22 oil, calibrated with isotopic reference waters, was determined to be −116.9 ± 0.8‰ (1σ and n = 31).

Rapid Communications in Mass Spectrometry↗
USGS2017

Optimization of on-line hydrogen stable isotope ratio measurements of halogen- and sulfur-bearing organic compounds using elemental analyzer–chromium/high-temperature conversion isotope ratio mass spectrometry (EA-Cr/HTC-IRMS)

Rationale: Accurate hydrogen isotopic analysis of halogen- and sulfur-bearing organics has not been possible with traditional high-temperature conversion (HTC) because the formation of hydrogen-bearing reaction products other than molecular hydrogen (H2) is responsible for non-quantitative H2 yields and possible hydrogen isotopic fractionation. Our previously introduced, new chromium-based EA-Cr/HTC-IRMS (Elemental Analyzer–Chromium/High-Temperature Conversion Isotope Ratio Mass Spectrometry) technique focused primarily on nitrogen-bearing compounds. Several technical and analytical issues concerning halogen- and sulfur-bearing samples, however, remained unresolved and required further refinement of the reactor systems. Methods: The EA-Cr/HTC reactor was substantially modified for the conversion of halogen- and sulfur-bearing samples. The performance of the novel conversion setup for solid and liquid samples was monitored and optimized using a simultaneously operating dual-detection system of IRMS and ion trap MS. The method with several variants in the reactor, including the addition of manganese metal chips, was evaluated in three laboratories using EA-Cr/HTC-IRMS (on-line method) and compared with traditional uranium-reduction-based conversion combined with manual dual-inlet IRMS analysis (off-line method) in one laboratory. Results: The modified EA-Cr/HTC reactor setup showed an overall H2-recovery of more than 96% for all halogen- and sulfur-bearing organic compounds. All results were successfully normalized via two-point calibration with VSMOW-SLAP reference waters. Precise and accurate hydrogen isotopic analysis was achieved for a variety of organics containing F-, Cl-, Br-, I-, and S-bearing heteroelements. The robust nature of the on-line EA-Cr/HTC technique was demonstrated by a series of 196 consecutive measurements with a single reactor filling. Conclusions: The optimized EA-Cr/HTC reactor design can be implemented in existing analytical equipment using commercially available material and is universally applicable for both heteroelement-bearing and heteroelement-free organic-compound classes. The sensitivity and simplicity of the on-line EA-Cr/HTC-IRMS technique provide a much needed tool for routine hydrogen-isotope source tracing of organic contaminants in the environment. Copyright © 2016 John Wiley & Sons, Ltd.

Rapid Communications in Mass Spectrometry↗
USGS2000

Hazard assessment of selenium and other trace elements in wild larval razorback sucker from the Green River, Utah

Contaminant investigations of the Green River in northeastern Utah have documented selenium contamination at sites receiving irrigation drainage. The Green River provides critical habitat for four endangered fishes including the largest extant riverine population of endangered razorback sucker. Although 2175 larval razorback suckers were collected from the river between 1992 and 1996, very few juveniles have been captured within recent decades. Selenium concentrations were measured in larval razorback suckers collected from five sites in the Green River (Cliff Creek, Stewart Lake Drain, Sportsman's Drain, Greasewood Corral, and Old Charlie Wash) to assess the potential for adverse effects on recruitment of larvae to the juvenile stage and the adult population. Larvae from all sites contained mean selenium concentrations ranging from 4.3 to 5.8 ??g/g. These values were at or above the proposed toxic threshold of 4 ??g/g for adverse biological effects in fish, which was derived from several laboratory and field studies with a wide range of fish species. At two sites, Cliff Creek and Stewart Lake Drain, selenium concentrations in larvae increased over time as fish grew, whereas selenium concentrations decreased as fish grew at Sportsman's Drain. Evaluation of a 279-larvae composite analyzed for 61 elements demonstrated that selenium and, to a lesser extent, vanadium were elevated to concentrations reported to be toxic to a wide range of fish species. Elevated selenium concentrations in larval razorback suckers from the five sites suggest that selenium contamination may be widespread in the Green River, and that survival and recruitment of larvae to the juvenile stage may be limited due to adverse biological effects. Selenium contamination may be adversely affecting the reproductive success and recruitment of endangered razorback sucker.

Ecotoxicology and Environmental Safety↗
USGS2021

Spatial data reduction through element -of-interest (EOI) extraction

Any large, multifaceted data collection that is challenging to handle with traditional management practices can be branded ‘Big Data.’ Any big data containing geo-referenced attributes can be considered big geospatial data. The increased proliferation of big geospatial data is currently reforming the geospatial industry into a data-driven enterprise. Challenges in the big spatial data domain can be summarized as the ‘Big Vs’ – variety, volume, velocity, veracity and value. Big spatial data sources can be considered in two broad classes, active and passive, as each is impacted to varying degrees. Some of these challenges may be alleviated by reducing unprocessed, or minimally processed, (raw) data to features, which we refer to as the extraction of Elements of Interest (EOI). In fact, many applications require EOI extraction from raw data to enable their basic employment. This chapter presents current state-of-the-art methods to create EOI from some types of georeferenced big data. We classify the data types into two realms: active and passive. Active data are those collected specifically for the purpose to which they are applied. Passive data are those collected for purposes other than those for which they are utilized, included those ‘collected’ for no particular purpose at all. The chapter then presents use cases from both the active and passive spatial realms, including the active applications of terrain feature extraction from digital elevation models and vegetation mapping from remotely-sensed imagery and passive applications like building identification from VGI and point-of-interest data mining from social networks for land use classification. Finally, the chapter concludes with future research needs.

Book chapter↗
USGS1989

Can we determine the biological availability of sediment-bound trace elements?

It is clear from available data that the susceptibility of biological communities to trace element contamination differs among aquatic environments. One important reason is that the bioavailability of metals in sediments appears to be altered by variations in sediment geochemistry. However, methods for explaining or predicting the effect of sediment geochemistry upon metal bioavailability are poorly developed. Experimental studies demonstrate that ingestion of sediments and uptake from solution may both be important pathways of metal bioaccumulation in deposit/detritus feeding species. Relative importance between the two is geochemistry dependent. Geochemical characteristics of sediments also affect metal concentrations in the tissues of organisms collected from nature, but the specific mechanisms by which these characteristics influence metal bioavailability have not been rigorously demonstrated. Several prerequisites are necessary to better understand the processes that control metal bioavailability from sediments. 1) improved computational or analytical methods for analyzing distribution of metals among components of the sediments; 2) improved computational methods for assessing the influences of metal form in sediments on sediment-water metal exchange; and 3) a better understanding of the processes controlling bioaccumulation of metals from solution and food by metazoan species directly exposed to the sediments. Such capabilities would allow mechanistic explanations essential to the development of practical tools sought for determining sediment quality criteria for metals.

Hydrobiologia↗
USGS1983

Platinum-group elements in rocks from the voikar-syninsky ophiolite complex, Polar Urals, U.S.S.R.

Analyses of platinum-group elements (PGE) in rocks collected from the Voikar-Syninsky ophiolite in the Polar Urals suggest that the distribution and geochemistry of PGE in this Paleozoic ophiolite are similar to those in Mesozoic ophiolites from elsewhere. Chondrite-normalized PGE patterns for chromitite, the tectonite unit, and ultramafic and mafic cumulate unit have negative slopes. These results are similar to those found for chromitites from other ophiolites; stratiform chromities show positive slopes. If the magmas that form both types of chromitite originate from similar mantle source material with respect to PGE content, the processes involved must be quite different. However, the distinct chondrite-normalized PGE patterns may reflect differing source materials. ?? 1983 Springer-Verlag.

Mineralium Deposita↗