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At least 595 records · Page 33Linked to original sources

Sea state from single optical images: A methodology to derive wind-generated ocean waves from cameras, drones and satellites

Sea state is a key variable in ocean and coastal dynamics. The sea state is either sparsely measured by wave buoys and satellites or modelled over large scales. Only a few attempts have been devoted to sea state measurements covering a large domain; in particular its estimation from optical images. With optical technologies becoming omnipresent, optical images offer incomparable spatial resolution from diverse sensors such as shore-based cameras, airborne drones (unmanned aerial vehicles/UAVs), or satellites. Here, we present a standalone methodology to derive the water surface elevation anomaly induced by wind-generated ocean waves from optical imagery. The methodology was tested on drone and satellite images and compared against ground truth. The results show a clear dependence on the relative azimuth view angle in relation to the wave crest. A simple correction is proposed to overcome this bias. Overall, the presented methodology offers a practical way of estimating ocean waves for a wide range of applications.

Remote Sensing

Late 20th Century benthic foraminiferal distribution in Central San Francisco Bay, California: Influence of the Trochammina hadai invasion

The distribution of foraminifera in most of San Francisco Bay is well documented, but this is not the case for the subembayment known as Central Bay. To resolve this, 55 grab samples obtained in 1998 were analyzed to characterize the foraminiferal fauna in the surface sediments of the area. Thirty-five species were identified, including the invasive Japanese species Trochammina hadai that was introduced into the bay in the early 1980s. A cluster analysis of the samples from Central Bay produced three groups (biofacies) and one outlier. The Shallow Subtidal Biofacies is characterized by a marsh to shallow-subtidal agglutinated fauna, dominated by T. hadai but also including T. inflata , T. macrescens , Haplophragmoides subinvolutum , and Miliammina fusca . The Intermediate Subtidal Biofacies, the Intermediate Subtidal Outlier, and the Deep Subtidal Biofacies are dominated by calcareous taxa, most notably Ammonia tepida , Elphidium excavatum , and Elphidiella hannai . Ammonia tepida is most abundant in the warmer, intermediate depths of eastern Central Bay, abundances of E. excavatum peak in the cooler estuarine water near Alcatraz Island, and E. hannai thrives in the cold water west of Angel Island in a transitional setting between the deep subtidal estuarine and the nearshore marine environments. The recovery of oceanic species as far east as Angel Island indicate that western Central Bay is the most marine-influenced region of San Francisco Bay. Samples collected from 1965 onward were also compared with those from 1998 to investigate how the distribution of benthic foraminifera in Central Bay has changed over the latter half of the 20th Century, particularly in response to the invasion by Trochammina hadai . In 1998, T. hadai was recovered at 46 of 55 sites in Central Bay, comprising from 0.3 to 97% (mean = 23%) of the foraminiferal fauna. With the species’ affiliation for shallow environments, it is not unexpected that it dominated the fauna of the Shallow Subtidal Biofacies (68-97%, mean = 77%) and was also a significant component of the Intermediate Subtidal Biofacies (7-51%, averaging 28%). In the deeper waters west of Alcatraz Island, the abundance of T. hadai was significantly less (mean = 8%), most likely reflecting allochthonous specimens that were the result of post-mortem transport. A cluster analysis clearly distinguishes pre- and post-invasion biofacies, illustrating how dominant T. hadai has become in Central Bay.

California

Use of short-term (5-Minute) and long-term (18-Hour) leaching tests to characterize, fingerprint, and rank mine-waste material from historical mines in the Deer Creek, Snake River, and Clear Creek Watersheds in and around the Montezuma Mining District, Colorado

Precipitation-induced runoff from historical mine-waste located adjacent to the headwaters of the Snake River, Deer Creek, Saints John Creek, Grizzly Gulch, Stevens Gulch, and Leavenworth Creek contributes to the degradation of water quality in these streams. Because historical mine-waste piles have had long-term exposure to the atmosphere, it is surmised that runoff from these piles, induced by meteorological events such as cloudbursts and snowmelt, may cause mobility of acid and metals into a watershed due to dissolution of soluble minerals. For this study, 13 mine-waste composite samples from various mine-wastes in these drainage basins were leached using both a short-term and a long-term leach test. Analytical results from this combination of leach tests are tools that allow the investigator to quantify (fingerprint) which geochemical components could be expected in runoff from these piles if they were leached by a cloudburst (5-minute leach test), as well as what the ?worst-case? geochemical profile would look like if the material were subject to extended leaching and breakdown of the mine-waste material (18-hour leach test). Also, this combination of leach tests allows the geoscientist the ability to see geochemical changes in the mine-waste leachate over time. That is, does the leachate become more or less acidic over time; does the specific conductance increase or decrease; and are there changes in the concentrations of major or trace elements? Further, use of a ranking scheme described herein will aid in prediction of which historical mine-waste piles have the greatest potential for impact on a watershed should runoff occur. Because of long-term weathering of these historical mine-waste piles, geochemical profiles, leachate time-trends, and relative ranking of the mine-wastes produced from analysis of the leachates are Hageman_SIR_2508.doc 1 7/21/2004 2:50 PM indicative of how the mine-waste piles can be expected to act in the environment and may help to identify the ?bad actors??this may aid in understanding the reasons for water-quality differences between the drainages.

Scientific Investigations Report

Successful water quality monitoring: The right combination of intent, measurement, interpretation, and a cooperating ecosystem

Water quality monitoring is invaluable to ensure compliance with regulations, detect trends or patterns, and advance ecological understanding. However, monitoring typically measures only a few characteristics in a small fraction of a large and complex system, and thus the information contained in monitoring data depends upon which features of the ecosystem are actually captured by the measurements. Difficulties arise when these data contain something other than intended, but this can be minimized if the purpose of the sampling is clear, and the sampling design, measurements, and data interpretations are all compatible with this purpose. The monitoring program and data interpretation must also be properly matched to the structure and functioning of the system. Obtaining this match is sometimes an iterative process that demands a close link between research and monitoring. This paper focuses on water quality monitoring that is intended to track trends in aquatic resources and advance ecological understanding. It includes examples from three monitoring programs and a simulation exercise that illustrate problems that arise when the information content of monitoring data differs from expectation. The examples show (1) how inconsistencies among, or lack of information about, the basic elements of a monitoring program (intent, design, measurement, interpretation, and the monitored system) can produce a systematic difference (bias) between monitoring measurements and sampling intent or interpretation, and (2) that bias is not just a statistical consideration, but an insidious problem that can undermine the scientific integrity of a monitoring program. Some general suggestions are provided and hopefully these examples will help those engaged in water quality monitoring to enhance and protect the value of their monitoring investment.

Lake and Reservoir Management

Assessing ecological infrastructure investments

Conventional markets can underprovide ecosystem services. Deliberate creation of a market for ecosystem services [e.g., a payments for ecosystem services (PES) scheme] can close the gap. The new ecosystem service market alters behaviors and quantities of ecosystem service provided and reveals prices for the ecosystems service: a market-clearing equilibrium. Assessing the potential for PES programs, which often act as ecological infrastructure investment mechanisms, requires forecasting the market-clearing equilibrium. Forecasting the equilibrium is complicated, especially at relevant social and ecological scales. It requires greater disciplinary integration than valuing ecosystem services or computing the marginal cost of making a land-use change to produce a service. We conduct an ex ante benefit–cost assessment and forecast market-clearing prices and quantities for ecological infrastructure investment contracts in the Panama Canal Watershed. The Panama Canal Authority could offer contracts to private farmers to change land use to increase dry-season water flow and reduce sedimentation. A feasible voluntary contracting system yields a small program of about 1,840 ha of land conversion in a 279,000-ha watershed and generates a 4.9 benefit–cost ratio. Physical and social constraints limit market supply and scalability. Service delays, caused by lags between the time payments must be made and the time services stemming from ecosystem change are realized, hinder program feasibility. Targeting opportunities raise the benefit–cost ratio but reduce the hectares likely to be converted. We compare and contrast our results with prior state-of-the-art assessments on this system.

Proceedings of the National Academy of Sciences

Spatial and temporal patterns of endocrine active chemicals in small streams indicate differential exposure to aquatic organisms

Alkylphenolic chemicals (APCs) and hormones were measured six times from February through October 2007 in three Minnesota streams receiving wastewater to identify spatial and temporal patterns in concentrations and in estrogen equivalency. Fish were collected once during the study to evaluate endpoints indicative of endocrine disruption. The most commonly detected APCs were 4-tert-octylphenol and 4-nonylphenol and the most commonly detected hormones were estrone and androstenedione. Chemical concentrations were greatest for nonylphenol ethoxycarboxylates (NPECs) (5,000-140,000 ng/l), followed by 4-nonlylphenol and 4-nonylphenolethoxylates (50-880 ng/l), 4-tert-octylphenol and 4-tert-octylphenolethoxylates with concentrations as great as 130 ng/l, and hormones (0.1-54 ng/l). Patterns in chemicals and estrogen equivalency indicated that wastewater effluent is a pathway of APCs and hormones to downstream locations in this study. However, upstream contributions can be equally or more important indicating alternative sources. This study indicates that aquatic organisms experience both spatially and temporally variable exposures in the number of compounds, total concentrations, and estrogenicity. This variability was evident in fish collected from the three rivers as no clear upstream to downstream pattern of endocrine disruption endpoints emerged.

Minnesota

Hydrothermal monitoring in a quiescent volcanic arc: Cascade Range, northwestern United States

Ongoing (1996–present) volcanic unrest near South Sister, Oregon, is accompanied by a striking set of hydrothermal anomalies, including elevated temperatures, elevated major ion concentrations, and 3 He/ 4 He ratios as large as 8.6 R A in slightly thermal springs. These observations prompted the US Geological Survey to begin a systematic hydrothermal-monitoring effort encompassing 25 sites and 10 of the highest-risk volcanoes in the Cascade volcanic arc, from Mount Baker near the Canadian border to Lassen Peak in northern California. A concerted effort was made to develop hourly, multiyear records of temperature and/or hydrothermal solute flux, suitable for retrospective comparison with other continuous geophysical monitoring data. Targets included summit fumarole groups and springs/streams that show clear evidence of magmatic influence in the form of high 3 He/ 4 He ratios and/or anomalous fluxes of magmatic CO 2 or heat. As of 2009–2012, summit fumarole temperatures in the Cascade Range were generally near or below the local pure water boiling point; the maximum observed superheat was <2.5°C at Mount Baker. Variability in ground temperature records from the summit fumarole sites is temperature-dependent, with the hottest sites tending to show less variability. Seasonal variability in the hydrothermal solute flux from magmatically influenced springs varied from essentially undetectable to a factor of 5–10. This range of observed behavior owes mainly to the local climate regime, with strongly snowmelt-influenced springs and streams exhibiting more variability. As of the end of the 2012 field season, there had been 87 occurrences of local seismic energy densities approximately ≥ 0.001 J/m 3 during periods of hourly record. Hydrothermal responses to these small seismic stimuli were generally undetectable or ambiguous. Evaluation of multiyear to multidecadal trends indicates that whereas the hydrothermal system at Mount St. Helens is still fast-evolving in response to the 1980–present eruptive cycle, there is no clear evidence of ongoing long-term trends in hydrothermal activity at other Cascade Range volcanoes that have been active or restless during the past century (Baker, South Sister, and Lassen). Experience gained during the Cascade Range hydrothermal-monitoring experiment informs ongoing efforts to capture entire unrest cycles at more active but generally less accessible volcanoes such as those in the Aleutian arc.

California;Oregon;Washington

Effects of forest harvesting on ecosystem health in the headwaters of the New York City Water Supply, Catskill Mountains, New York

The effects of forest clearcutting and selective harvesting on forest soils, soil and stream water chemistry, forest regrowth, and aquatic communities were studied in four small headwater catchments. This research was conducted to identify the sensitivity of forested ecosystems to forest disturbance in the northeastern United States. The study area was in the headwaters of the Neversink Reservoir watershed, part of the New York City water supply system, in the Catskill Mountains of southeastern New York. Two sub-catchments of the Shelter Creek watershed were selectively harvested, one in its northern half and one more heavily in its southern half in 1995?96, the Dry Creek watershed was clearcut in the winter of 1996?97, and the Clear Creek watershed was left undisturbed and monitored as a control site. Monitoring was conducted from 4 years before the harvests until 4 years after the harvests. Clearcutting caused a large release of nitrate (NO3-) from watershed soils and a concurrent release of inorganic monomeric aluminum (Alim), which is toxic to some aquatic biota. The increased soil NO3- concentrations measured after the harvest could be completely accounted for by the decrease in nitrogen (N) uptake by watershed trees, rather than an increase in N mineralization and nitrification. The large increase in stream water NO3- and Alim concentrations caused 100-percent mortality of caged brook trout (Salvelinus fontinalis) during the first year after the clearcut and adversely affected macroinvertebrate communities for 2 years after the harvest. Nutrient uptake and biomass accumulation increased in uncut mature trees after the two selective harvests. There was no increase in stream-water NO3- or Alim concentrations, and so there were no adverse affects on macroinvertebrate or trout communities. The amount of tree biomass that can be removed without causing a sharp increase in stream-water NO3- and Alim stream-water concentrations is unknown, but probably depends on the history of forest-disturbance and acid deposition and the level of soil acidification. Results of this study indicate that macroinvertebrate and brook trout communities were sensitive to clearcutting and that deer browsing may affect water quality by suppressing forest regeneration and nutrient uptake. Further studies of selective harvests could identify the harvesting threshold below which changes in water quality and soil chemistry are minimized, and nutrient retention is maximized, thus reducing the damage that logging can inflict on stream and aquatic communities.

New York

Scale-dependent gas hydrate saturation estimates in sand reservoirs in the Ulleung Basin, East Sea of Korea

Through the use of 2-D and 3-D seismic data, several gas hydrate prospects were identified in the Ulleung Basin, East Sea of Korea and thirteen drill sites were established and logging-while-drilling (LWD) data were acquired from each site in 2010. Sites UBGH2–6 and UBGH2–10 were selected to test a series of high amplitude seismic reflections, possibly from sand reservoirs. LWD logs from the UBGH2–6 well indicate that there are three significant sand reservoirs with varying thickness. Two upper sand reservoirs are water saturated and the lower thinly bedded sand reservoir contains gas hydrate with an average saturation of 13%, as estimated from the P-wave velocity. The well logs at the UBGH2–6 well clearly demonstrated the effect of scale-dependency on gas hydrate saturation estimates. Gas hydrate saturations estimated from the high resolution LWD acquired ring resistivity (vertical resolution of about 5–8 cm) reaches about 90% with an average saturation of 28%, whereas gas hydrate saturations estimated from the low resolution A40L resistivity (vertical resolution of about 120 cm) reaches about 25% with an average saturation of 11%. However, in the UBGH2–10 well, gas hydrate occupies a 5-m thick sand reservoir near 135 mbsf with a maximum saturation of about 60%. In the UBGH2–10 well, the average and a maximum saturation estimated from various well logging tools are comparable, because the bed thickness is larger than the vertical resolution of the various logging tools. High resolution wireline log data further document the role of scale-dependency on gas hydrate calculations.

East Sea Of Korea;Ulleung Basin

Uncertainty reduction for subaerial landslide-tsunami hazards

Subaerial rock slopes may generate a tsunami by rapidly moving into the water. Large uncertainty in landslide characteristics propagates into large uncertainty in tsunami hazard, making hazard assessment more difficult for land and emergency managers. Once a potentially tsunamigenic landslide is identified, it may not be clear which landslide characteristics contribute most significantly to uncertainty in the tsunami hazard. Our aim is to document the relative worth of different landslide characteristics (e.g., size, material properties) for reducing uncertainty in landslide-tsunami hazard assessments. Isolating the relative importance of specific landslide characteristics may inform prioritization of data collection and improve efficiency in understanding hazard. To accomplish this, we generated a set of 288 landslide-tsunami simulations in which we systematically varied the size and material properties of possible failure extents at the Barry Arm landslide complex in northwestern Prince William Sound, Alaska, USA. We find that for landslides smaller than the receiving waterbody, the landslide volume has the strongest effect on resulting wave characteristics and thus the highest leverage on reducing uncertainty in tsunami hazard. In contrast, for landslides substantially larger than the waterbody, the duration of rapid movement of the landslide has the highest leverage. Based on our results, we propose a classification scheme for subaerial landslides based on the relative size of the landslide and waterbody. Additionally, our results support the generation of a tsunami height transfer function between existing tide gages and a nearby coastal city. These results have direct implications for the practice of operational early warning.

Alaska

The anatomy of a drought in the upper San Francisco Estuary: Water quality and lower-trophic responses to multi-year droughts

Multi-year droughts are important and impactful features of California’s Mediterranean climate and can fundamentally affect the water quality and the ecosystem response of the San Francisco Estuary (Estuary) and the Sacramento-San Joaquin Delta (Delta). This study assesses data collected by long-term monitoring programs over the past 46 years (1975-2021) to evaluate how water quality in the Estuary changes during multi-year droughts. We found that multi-year droughts alter multiple physical and chemical parameters in the Estuary, increasing water temperature, salinity, water clarity, and nutrient levels. This trend was consistent across regions and seasons, with few exceptions. Increases in these parameters during droughts are likely caused by reduced Delta inflows that intensified in each successive dry year because of reduced precipitation and reservoir releases. Droughts did not substantially effect on tidal velocities within the Estuary, which remained mostly consistent across wet and dry periods. Trends in chlorophyll concentrations during droughts were more nuanced with higher concentrations occurring in the South-Central Delta region and during the winter and spring. Together, these results paint a picture of drought in the Estuary as warm, clear, high in nutrients, with patchy phytoplankton blooms (as indexed by chlorophyll), all of which have implications for higher trophic levels. Considering that droughts are expected to increase in frequency and intensity in California with climate change, it is imperative to understand the effects of multi-year droughts on the water quality conditions of the Estuary when making water management decisions.

California

Diversity, distribution, and conservation status of the native freshwater fishes of the southern United States

The Southeastern Fishes Council Technical Advisory Committee reviewed the diversity, distribution, and status of all native freshwater and diadromous fishes across 51 major drainage units of the southern United States. The southern United States supports more native fishes than any area of comparable size on the North American continent north of Mexico, but also has a high proportion of its fishes in need of conservation action. The review included 662 native freshwater and diadromous fishes and 24 marine fishes that are significant components of freshwater ecosystems. Of this total, 560 described, freshwater fish species are documented, and 49 undescribed species are included provisionally pending formal description. Described subspecies (86) are recognized within 43 species, 6 fishes have undescribed subspecies, and 9 others are recognized as complexes of undescribed taxa. Extinct, endangered, threatened, or vulnerable status is recognized for 28% (187 taxa) of southern freshwater and diadromous fishes. To date, 3 southern fishes are known to be extinct throughout their ranges, 2 are extirpated from the study region, and 2 others may be extinct. Of the extant southern fishes, 41 (6%) are regarded as endangered, 46 (7%) are regarded as threatened, and 101 (15%) are regarded as vulnerable. Five marine fishes that frequent fresh water are regarded as vulnerable. Our assessment represents a 75% increase in jeopardized southern fishes since 1989 and a 125% increase in 20 years. The trend for fishes in the southern United States is clear; jeopardized fishes are successively being moved from the vulnerable category to that of imminent threat of extinction.

Fisheries

A hierarchical model of daily stream temperature using air-water temperature synchronization, autocorrelation, and time lags

Water temperature is a primary driver of stream ecosystems and commonly forms the basis of stream classifications. Robust models of stream temperature are critical as the climate changes, but estimating daily stream temperature poses several important challenges. We developed a statistical model that accounts for many challenges that can make stream temperature estimation difficult. Our model identifies the yearly period when air and water temperature are synchronized, accommodates hysteresis, incorporates time lags, deals with missing data and autocorrelation and can include external drivers. In a small stream network, the model performed well (RMSE = 0.59°C), identified a clear warming trend (0.63 °C decade −1 ) and a widening of the synchronized period (29 d decade −1 ). We also carefully evaluated how missing data influenced predictions. Missing data within a year had a small effect on performance (∼0.05% average drop in RMSE with 10% fewer days with data). Missing all data for a year decreased performance (∼0.6 °C jump in RMSE), but this decrease was moderated when data were available from other streams in the network.

PeerJ

Base flow (1966-2009) and streamflow gain and loss (2010) of the Brazos River from the New Mexico-Texas State line to Waco, Texas

During 2010&ndash;11, the U.S. Geological Survey (USGS), in cooperation with the Texas Water Development Board, used hydrograph separation to quantify historical base flow at 11 USGS streamflow-gaging stations between water years 1966&ndash;2009 and streamflow gains and losses from two sets of synoptic measurements of streamflow and specific conductance (the first in June 2010, followed by another set in October 2010) in the upper Brazos River Basin from the New Mexico&ndash;Texas State line to Waco, Texas. The following subbasins compose the study area: Salt Fork Brazos River Basin, Double Mountain Fork Brazos River Basin, Clear Fork Brazos River Basin, North Bosque River Basin, and the Brazos River Basin (main stem) (including its tributaries). Base-flow analysis was done using historical streamflow data from 11 USGS streamflow-gaging stations in the upper Brazos River Basin to compute yearly base-flow indexes (base flow divided by total streamflow) for each station. The base-flow index was used to indicate the fraction of flow consisting of base flow on an annual basis for the period of record evaluated at each streamflow-gaging station. At nine stations there were long-term streamflow data from water years 1966&ndash;2009 (October 1965 through September 2009); at two stations slightly shorter periods of record (water years 1967&ndash;2009 and 1969&ndash;2009) were available. The median base-flow indexes were 0.16 and 0.15 at USGS streamflow-gaging stations 08082000 Salt Fork Brazos River near Aspermont, Tex., and 08080500 Double Mountain Fork Brazos River near Aspermont, Tex., respectively. The amount of the total streamflow consisting of base flow was larger at sites in the Clear Fork Brazos River Basin compared to sites in the Salt Fork Brazos River Basin or Double Mountain Fork Brazos River Basin; at USGS streamflow-gaging stations 08084000 Clear Fork Brazos River at Nugent, Tex., and at 08085500 Clear Fork Brazos River at Fort Griffin, Tex., the median base-flow indexes were 0.28 and 0.23, respectively. The largest median base-flow index for any station was 0.35 at USGS streamflow-gaging station 08091500 Paluxy River at Glen Rose, Tex. The second largest base-flow index was 0.30 at USGS streamflow-gaging station 08095000 North Bosque River near Clifton, Tex. Median base-flow indexes on the main stem of the Brazos River upstream from Possum Kingdom Lake were 0.22 at USGS streamflow-gaging station 08082500 Brazos River at Seymour, Tex., and 0.24 at USGS streamflow-gaging station 08088000 Brazos River near South Bend, Tex. The base-flow indexes for stations between Possum Kingdom Lake and Lake Granbury were 0.19 and 0.27 at USGS streamflow-gaging stations 08089000 Brazos River near Palo Pinto, Tex., and 08090800 Brazos River near Dennis, Tex., respectively. A median base-flow index of 0.19 was also measured at USGS streamflow-gaging station 08091000 Brazos River near Glen Rose, Tex., located between Lake Granbury and Lake Whitney. A Mann-Kendall trend analysis test was performed on annual base-flow index values from each of the 11 streamflow records that were analyzed. Upward trends in base-flow index values indicating increasing flows during the study period were found for USGS streamflow-gaging stations 08080500 Double Mountain Fork Brazos River near Aspermont, Tex., 08089000 Brazos River near Palo Pinto, Tex., and 08090800 Brazos River near Dennis, Tex. Flows at these three streamflow-gaging stations are regulated by reservoir releases, and additional analyses are needed before these streamflow trends can be characterized as indicative of changes in base flow over time. Streamflow was measured at 66 sites from June 6&ndash;9, 2010, and at 68 sites from October 16&ndash;19, 2010, to identify reaches in the upper Brazos River Basin that were gaining or losing streamflow. Gaining reaches were identified in each of the five subbasins. The gaining reach in the Salt Fork Brazos River Basin began at USGS streamflow-gaging station 08080940 Salt Fork Brazos River at State Highway 208 near Clairemont, Tex. (site SF&ndash;6), upstream from where Duck Creek flows into the Salt Fork Brazos River and continued downstream past USGS streamflow-gaging station 08082000 Salt Fork Brazos River near Aspermont, Tex. (site SF&ndash;9), to the outlet of the basin. In the Double Mountain Fork Brazos River Basin, a gaining reach from near Post, Tex., downstream to the outlet of the basin was identified. Two gaining reaches were identified in the Clear Fork Brazos River Basin&mdash;one from near Roby, Tex., downstream to near Noodle, Tex., and second from Hawley, Tex., downstream to Nugent, Tex. Most of the North Bosque River was characterized as gaining streamflow. Streamflow gains were identified in the main stem of the Brazos River from where the Brazos River main stem forms at the confluence of the Salt Fork Brazos River and Double Mountain Fork Brazos River near Knox City, Tex., downstream to near Seymour, Tex.

New Mexico, Texas

Amino-acid diagenesis and its implication for late Pleistocene lacustrine sediment, Clear Lake, California

The diagenesis of amino acids in sediments from Clear Lake core CL-80-1 is indicated by changes in amino acid concentrations, compositions, and stereochemistry. Concentrations of total amino acids decrease with depth, but the decrease is not systematic, possibly reflecting a nonuniformity in sedimentary and postdepositional processes affecting the amino acids. Ratios of neutral/acidic amino acids may indicate that the pH of interstitial water is slightly alkaline to slightly acidic and that the organic matter is well humified. Ratios of nonprotein/protein amino acids suggest that some changes in amino acids with depth result from microbial degradations. The extent of racemization of alanine increases with depth; the trends of these data may be explained, in part, by rapid sedimentation within the lake. Agreement between extents of alanine racemization for sediments from equivalent depths in two cores from the lake suggests that diagenetic temperatures are uniform within the sediments of the northern basin of Clear Lake.

California

Local to landscape-level controls of water fluxes through Hawaiian forests: Effects of invasive animals and plants on soil infiltration capacity across substrate and moisture gradients

Given the potential effect of invasive plants and animals to water fluxes through forests, the invasive-driven degradation of native ecosystems is a topic of great concern for many downstream land and water managers. The infiltration rate determines the partitioning between runoff and infiltration into soil in Hawaiian forests and beyond. Thus, to explore the ecohydrological effects of plant and animal invasion in mesic and wet forests in Hawaii, we measured soil infiltration capacity in multiple fenced (i.e., ungulate-free)/unfenced and native/invaded forest sites along moisture and substrate age gradients across the islands of Hawai‘i and Kaua‘i. We also characterized forest composition and structure and soil characteristics at these sites to assess the direct and vegetation-mediated impacts of invasive species on infiltration capacity. Infiltration capacity is highly variable across forested sites and the wider landscape. Much of this variability is determined by a complex set of soil, vegetation, and disturbance factors that affect infiltration capacity at the immediate surrounding of measurement plots. Consequently, the effect of any given factor can be masked by variability in other factors. However, by controlling for variability in soil and vegetation conditions at a local plot level, we found that the presence of invasive species in forests has complex and sometimes non-intuitive effects on infiltration. Our final models showed that invasive ungulates negatively affect soil infiltration capacity consistently across the wide moisture and substrate age gradients considered. Additionally, because several soil characteristics known to be affected by ungulates were associated with local infiltration rates (e.g., soil organic matter, bare soil cover, soil depth), the long-term secondary effects of high ungulate densities in Hawaiian forests may be higher than effects observed in this study. These results provide clear evidence for land managers that ungulate control efforts likely improve ecohydrologic function to mesic and wet forest systems critical to protecting downstream and nearshore resources and maintaining groundwater recharge. Compared to ungulate effects, the effect of invasive plants on water infiltration capacity in Hawaiian forests appeared much more complex. In general, elements of forest structure including increased canopy, understory and floor cover, greater presence of large roots, and lower grass and bare soil covers were positively associated with water infiltration. Whether native or not, a plant species’ potential to alter infiltration rates in Hawaiian forests was likely to depend on its physiognomy and how it affects forest community structure. For instance, while the cover of native dominant tree ‘ōhi‘a, Metrosideros polymorpha, was found to be positively associated with infiltration capacity (perhaps as an indicator of overall forest integrity), invasive Himalayan ginger, Hedychium gardnerianum, was also positively correlated with infiltration capacity, possibly due to preferential flow channels created by the presence of large root mats. Few studies have conducted comprehensive integrated ecological and hydrological sampling in forests of high conservation value. While we show there are large benefits to understanding how conservation efforts may help shape water fluxes, we also found that the commonly used study design for infiltration studies used here and elsewhere (i.e., adjacent paired sites) could be modified to provide more accurate effects of invasion in future studies for ecosystems in Hawaii and beyond.

Hawaii

Dominance of 'Gallionella capsiferriformans' and heavy metal association with Gallionella -like stalks in metal-rich pH 6 mine water discharge

Heavy metal-contaminated, pH 6 mine water discharge created new streams and iron-rich terraces at a creek bank in a former uranium-mining area near Ronneburg, Germany. The transition from microoxic groundwater with ~5 m m Fe(II) to oxic surface water may provide a suitable habitat for microaerobic iron-oxidizing bacteria (FeOB). In this study, we investigated the potential contribution of these FeOB to iron oxidation and metal retention in this high-metal environment. We (i) identified and quantified FeOB in water and sediment at the outflow, terraces, and creek, (ii) studied the composition of biogenic iron oxides ( Gallionella -like twisted stalks) with scanning and transmission electron microscopy (SEM, TEM) as well as confocal laser scanning microscopy (CLSM), and (iii) examined the metal distribution in sediments. Using quantitative PCR, a very high abundance of FeOB was demonstrated at all sites over a 6-month study period. Gallionella spp. clearly dominated the communities, accounting for up to 88% of Bacteria , with a minor contribution of other FeOB such as Sideroxydans spp. and &lsquo; Ferrovum myxofaciens &rsquo;. Classical 16S rRNA gene cloning showed that 96% of the Gallionella -related sequences had &ge;97% identity to the putatively metal-tolerant &lsquo; Gallionella capsiferriformans ES-2&rsquo;, in addition to known stalk formers such as Gallionella ferruginea and Gallionellaceae strain R-1. Twisted stalks from glass slides incubated in water and sediment were composed of the Fe(III) oxyhydroxide ferrihydrite, as well as polysaccharides. SEM and scanning TEM-energy-dispersive X-ray spectroscopy revealed that stalk material contained Cu and Sn, demonstrating the association of heavy metals with biogenic iron oxides and the potential for metal retention by these stalks. Sequential extraction of sediments suggested that Cu (52&ndash;61% of total sediment Cu) and other heavy metals were primarily bound to the iron oxide fractions. These results show the importance of &lsquo; G. capsiferriformans &rsquo; and biogenic iron oxides in slightly acidic but highly metal-contaminated freshwater environments.

Geobiology

Hydrogeology and ground-water-quality conditions at the Emporia- Lyon County Landfill, eastern Kansas, 1988

Hydrogeology and water-quality conditions at the Emporia-Lyon County Landfill, eastern Kansas, were investigated from April 1988 through April 1989. Potentiometric-surface maps indicated groundwater movement from the northeast and northwest towards the landfill and then south through the landfill to the Cottonwood River. The maps indicate that during periods of low groundwater levels, groundwater flows northward in the north-west part of the landfill, which may have been induced by water withdrawal from wells north of the landfill or by water ponded in waste lagoons south and west of the landfill. Chemical analysis of water samples from monitoring wells upgradient and downgradient of the landfill indicate calcium bicarbonate to be the dominant water type. No inorganic or organic chemical concentrations exceeded Kansas or Federal primary drinking-water standards. Kansas secondary drinking-water standards were equaled or exceeded, however, in water from some or all wells for total hardness, dissolved solids, iron, and manganese. Water from one upgradient well contained larger concentrations of dissolved oxygen and nitrate, and smaller concentrations of bicarbonate, alkalinity, ammonia, arsenic, iron, and manganese as compared to all other monitoring wells. Results of this investigation indicate that groundwater quality downgradient of well MW-2 has increased concentrations of some inorganic and organic compounds. Due to the industrial nature of the area and the changing directions of groundwater flow, it is not clear what the source of these compounds might be. Long-term monitoring, additional wells, and access to nearby waste lagoons and waste-lagoon monitoring wells would help define the sources of increased inorganic and organic compounds. (USGS)

Water-Resources Investigations Report